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At least 1,369 records · Page 76Linked to original sources
USGS2021

Multivariate classification of the crude oil petroleum systems in southeast Texas, USA, using conventional and compositional data analysis of biomarkers

Chemically, petroleum is an extraordinarily complex mixture of different types of hydrocarbons that are now possible to isolate and identify because of advances in geochemistry. Here, we use biomarkers and carbon isotopes to establish genetic differences and similarities among oil samples. Conventional approaches for evaluating biomarker and carbon isotope relative abundances include statistical techniques such as principal component and cluster analysis. Considering that proportions of the different hydrocarbon molecules are relative parts of a laboratory sample, the data are compositional in nature, thus requiring the use of log-ratio approaches for adequate mathematical modeling. We apply both traditional and compositional modeling approaches to crude oil samples from an onshore area of about 50,000 square miles in southeast Texas. The data comprise 177 crude oil samples from producing oil fields that include key biomarkers, elemental, and isotopic values commonly used in source rock correlation studies. Our results indicate that compositional modeling has higher discriminating power and lower uncertainty than the traditional approach, allowing the identification of up to 16 clusters. Each cluster represents one oil family from a source rock organofacies ranging from Carboniferous to Paleogene. The families provide new insights into important petroleum systems in the Texas onshore region of the Gulf of Mexico sedimentary basin.

Texas↗
USGS2021

Permafrost thaw in northern peatlands: Rapid changes in ecosystem and landscape functions

Peatlands within the northern permafrost region cover approximately 2 million km 2 and are characterized by organic soils that can be several meters thick, and a fine-scale mosaic of permafrost and non-permafrost landforms interspersed by shallow ponds and lakes. Ongoing permafrost thaw is transforming these peatlands, causing abrupt changes to their morphology, hydrology, ecology, and biogeochemistry. In this review we show how changes to individual peatlands depend on both their Holocene developmental history and their location within current permafrost zones. Permafrost thaw in peatlands often leads to land surface collapse between 0.5 and 5 m, the so-called thermokarst. Thermokarst in peatlands can lead to the development of ice-wedge troughs, waterlogged thermokarst bogs and fens, and the initiation, expansion, and drainage of thermokarst lakes. Permafrost thaw in peatlands can thus completely alter vegetation composition and shift patterns of landscape inundation and hydrological connectivity. These changes in turn have implications for magnitude and timing of runoff, downstream water quality, habitat suitability for birds and larger mammals, traditional land-use, and the exchange of greenhouse gases with the atmosphere. Ongoing permafrost thaw is largely irreversible at relevant human time-scales, and peatland thermokarst has been accelerating over the last few decades. Complete permafrost loss is expected this century for peatlands in relatively warmer permafrost zones, and all peatlands in the northern permafrost region will be profoundly transformed by permafrost thaw.

Book chapter↗
USGS2022

Spatially integrating microbiology and geochemistry to reveal complex environmental health issues: Anthrax in the contiguous United States

Maxent models were run using the B. anthracis presence data and/or the animal outbreak presence data. Models run using the animal outbreak data alone utilized two scales: the Outbreak State scale which included only states reporting animal anthrax outbreaks from 2001 to 2013 and the National scale which included all states in the contiguous United States. Three iterations of the environmental data were used and included the Sample Location dataset which utilized the environmental variable data with assigned latitude and longitude locations from the USGS NASGLP project; the Normalized dataset which scaled the environmental variables so that the values fell between 0 and 1; and the Interpolated dataset which provided an interpolation of the environmental variables averaged for each county and assigned to a point for that county at the centroid (rather than using the NASGLP latitude and longitude location). Two metrics were used to measure model performance including the widely used area under the curve (AUC) and an alternative method, the True Skill Statistic (TSS). The AUC gives the probability that a randomly chosen presence location has been correctly ranked higher than the absence/background site. AUC values at 0.5 or lower mean the ranking is no better than random, while the AUC values nearer to 1 mean the model is a better predictor. The TSS provides a comparison of how well the background predictions made by the model match the model results at the test dataset (presence) locations. TSS values near +1 means the model approaches perfect agreement, while values near −1 indicate the model is no better than random. Maxent models to determine the influence of environmental factors on the B. anthracis distribution using the PCR data yielded a low TSS, which suggested the model might be underfitting the data. This was not surprising due to the difficulty in recovering B. anthracis in soil samples as well as the samples themselves being discrete in nature and only capturing a snapshot in time. Therefore, the distribution of B. anthracis and its niche in the contiguous United States could not be determined in this study. However, efforts to investigate environmental factors that would have a higher potential of supporting an anthrax outbreak in wildlife and livestock yielded better results. Results showed that most of the Maxent models in this study performed best when using the Outbreak State scale. When the models were scaled up to the National scale, model performance declined, except for the Normalized variable dataset. At the Outbreak State scale, a large proportion of the area was predicted to be of higher probability for wildlife/livestock anthrax outbreaks, and the statistical measures assumed the model was underfitting the data. The model with the highest AUC and TSS scores for this study was the Outbreak State scale using Sample Location dataset (AUC = 0.918 and TSS = 0.82). Some of the variables found to be closely related to the occurrence of B. anthracis in this study included pH, drainage potential, and concentration of elements including Na, Ca, Sr, and Mg, which have also been found to be related to animal outbreaks or to the occurrence of B. anthracis in previous studies. The models in the current study indicated possible regions that have not had recent wildlife/livestock anthrax outbreaks but contained environmental conditions that could potentially support an outbreak if one were to occur (Michigan and Maine). This work provides an extension to the use of ecological niche modeling to outbreak potential in livestock/wildlife in the United States because it utilizes additional soil geochemistry data and has shown that further validation techniques, such as the TSS, should be considered in addition to AUC. Results from this study could be used by animal and public health officials to identify areas with a higher potential for anthrax outbreak in wildlife and livestock due to naturally occurring soil and environmental conditions.

Book chapter↗
USGS2021

Fire and forests in the 21st century: Managing resilience under changing climates and fire regimes in USA forests

Higher temperatures, lower snowpacks, drought, and extended dry periods have contributed to increased wildfire activity in recent decades. Climate change is expected to increase the frequency of large fires, the cumulative area burned, and fire suppression costs and risks in many areas of the USA. Fire regimes are likely to change due to interactions among climate, fire, and other stressors and disturbances; resulting in persistent changes in forest structure and function. The remainder of the twenty-first century will present substantial challenges, as natural resource managers are faced with higher fire risk and the difficult task of maintaining ecological function in a rapidly changing biophysical and social landscape. Fuel treatments will continue to be important for minimizing the undesirable ecological effects of fire, and for enhancing firefighter safety; however, treatments must be implemented strategically across large areas. Collaboration among agencies, private landowners, and other organizations will be critical for ensuring resilience and sustainable forest management.

Book chapter↗
USGS2021

International importance of Percids: Summary and looking forward

Research presented in the preceding chapters emphasizes recent advancements in the research, management, and aquaculture of Walleye, Sauger, and Yellow Perch in North America. These percid fishes, along with the European Perch and Pikeperch, are economically and ecologically important fishes in their native geographic range. Advances in techniques to evaluate current habitat and predict future habitat conditions provide managers with detailed baseline information and biophysical models useful for evaluating adaptive management practices. Current habitat use and movement assessments have improved substantially with technological advancements in acoustic tags and extensive receiver array networks, which, combined with genetic and genomic tools, are improving percid stock assessments and management. Advances in percid aquaculture techniques have improved growth, survival, and disease resistance, enhancing percid stocking efforts and the production of marketable fish. The exchange of information between researchers and managers will continue to advance techniques of percid management for commercial and recreational exploitation and improve aquaculture practices to provide a lucrative commercial aquaculture industry.

Book chapter↗
USGS2022

The use of boundary-spanning organizations to bridge the knowledge-action gap in North America

The goals of boundary-spanning organizations include communicating among researchers, stakeholders, and resource managers to improve decision-making. These efforts span public agencies, environmental non-governmental organizations, and private stakeholders and occur throughout Canada, the USA, and Mexico. We describe how the core philosophy of boundary-spanning organizations may help address conservation challenges in these countries. We profile a subset of the more than 100 boundary-spanning organizations, identifying some of their core accomplishments and the challenges they face. Scientific information generally is acknowledged as useful to resource management by recipients of the information. It is more difficult to infer whether the information transmitted by boundary-spanning organizations contributed to conservation decisions or whether the outcomes of those decisions differed from the potential outcomes in the absence of such information. Several examples of sustained enthusiasm for boundary-spanning efforts indicate that the organizations help to bridge the knowledge to action gap in North America.

Book chapter↗
USGS2022

A review of the exploration, discovery, and characterization of highly concentrated gas hydrate accumulations in coarse-grained reservoir systems along the Eastern Continental Margin of India

The analysis of 3-D seismic data has become one of the most powerful ways to identify sand-rich gas hydrate reservoir systems and to directly identify highly concentrated gas hydrate prospects. Scientific drilling programs have shown that the occurrence of highly concentrated gas hydrate accumulations in coarse-grained, sand-rich, reservoir systems has a significant impact on the physical properties of sediments, allowing gas hydrates to be “directly detected” by conventional seismic analysis techniques. One of the most diagnostic responses of a gas hydrate-bearing sand reservoir is that of a high-velocity sedimentary section and an associated high-amplitude seismic response with a reflection polarity matching that of the seafloor. Knowledge of this physical relationship guided the Indian National Gas Hydrate Program Expedition 02 (NGHP-02) in their pre-drill site review and selection effort along the eastern continental margin of India in 2016. Within the planning, operational and post-operational data analysis phases of the NGHP-02 Expedition, scientists relied heavily on the analyses of the (1) pre-expedition acquired 3-D seismic data from offshore India, (2) downhole logging data acquired during NGHP-02 and (3) core samples and data obtained from NGHP-02 conventional- and pressure-cores to identify gas hydrates and assess the geologic controls on the formation and stability of these accumulations. Data analysis has confirmed the presence of extensive sand-rich depositional systems throughout the deepwater portions of the Krishna-Godavari and Mahanadi Basins in the Bay of Bengal. Two areas of the Krishna-Godavari Basin contain substantial gas hydrate accumulations in sand-rich systems, representing candidate sites for future potential energy exploitation.

Bay of Bengal, Krishna-Godavari Basin, Mahanadi Ba↗
USGS2022

Alaska North Slope terrestrial gas hydrate systems: Insights from scientific drilling

A wealth of information has been accumulated regarding the occurrence of gas hydrates in nature, leading to significant advancements in our understanding of the geologic controls on their occurrence in both the terrestrial and marine settings of the Arctic. Gas hydrate accumulations discovered in the Alaska North Slope have been the focus of several important geoscience and production testing research programs. The Mount Elbert Gas Hydrate Stratigraphic Test Well of 2007 yielded one of the most complete geologic datasets on Arctic gas hydrate systems and important reservoir engineering data. The 2011/2012 field test of the Iġnik Sikumi gas hydrate production test well provided important insight into gas hydrate production technologies, yielding additional information on the petrophysical properties of gas hydrate reservoir systems. The Hydrate-01 Stratigraphic Test Well, drilled late in 2018, confirmed the geologic conditions at an Alaska North Slope drill site that was selected for an extended gas hydrate production test. In 2018, the US Geological Survey used information derived from previous scientific drilling programs to assess the volume of undiscovered, technically recoverable gas resources at a mean estimate of about 54 trillion cubic feet (~1.5 trillion cubic meters) within the gas hydrates in the North Slope of Alaska. This assessment has shown that the amount of gas stored as gas hydrates in this area is equal to about half of the known volume of conventional natural gas resources in the region.

Alaska↗
USGS2022

Gas hydrates on Alaskan marine margins

Gas hydrate distributions on the marine margins of the U.S. state of Alaska are more poorly known than those on other U.S. margins, where bottom simulating reflections have been systematically mapped on marine seismic data to support modern, quantitative assessments of gas-in-place in gas hydrates. The extent of bottom simulating reflections in the U.S. Beaufort Sea has been known since the late 1970s, and researchers have investigated the possibility that remnant gas hydrate persists in association with decaying subsea permafrost on both the U.S. and Canadian Beaufort continental shelves. In the Bering Sea, possible gas hydrate-related features have been widely mapped, revealing zones of free gas and concentrated gas hydrate within the hydrate stability zone in features called velocity amplitude anomalies (VAMPs). However, there are few reports on bottom simulating reflections along the more than 2500 km of the Aleutian arc and along the transform plate margin in southeast Alaska. Here we examine selected seismic profiles from southeast Alaska, along the Aleutian margin, and on the Bering continental slope, emphasizing surveys acquired with large airgun arrays, and review the results obtained from Bering Sea’s Aleutian Basin and from the U.S. Beaufort Sea. In the new analyses, we detect hydrate-related bottom simulating reflections in southeastern Alaska and the eastern and central parts of the Aleutian arc, but not in the western Aleutian arc or beneath the continental slope from the island arc north into the Aleutian Basin. In the Bering Sea, recognition of hydrate-related bottom simulating reflections is complicated by the widespread existence of a bottom simulating reflector associated with a diagenetic transition (opal CT). Our detection of continental slope hydrate-related bottom simulating reflections in southeast Alaska and the eastern and central Aleutian arcs expands the area of potential gas hydrate distribution on Alaskan margins and underscores the need for more systematic analysis of existing seismic data to inform quantitative evaluation of gas-in-place.

Alaska↗
USGS2022

U.S. Atlantic margin gas hydrates

The minimum distribution of gas hydrates on the U.S. Atlantic margin is from offshore South Carolina northward to the longitude of Shallop Canyon on the southern New England margin. Few wells have logged or sampled the gas hydrate zone on this margin, meaning that the presence of gas hydrates is inferred primarily based on seismic data that reveal bottom simulating reflections, mostly at water depths greater than 2000 m. The highest hydrate saturations most likely exist in sandy sediments of the Whale Prospect offshore New Jersey, New York, and the western part of Cape Cod, an area characterized by strong bottom simulating reflections. Such reflections are also imaged on the well-studied Blake Ridge, where fine-grained sediments host lower hydrate saturations that have been constrained by drilling. Within the section of the margin stretching from south of Cape Hatteras to nearly Hudson Canyon, the diagnostic seismic reflections are hard to discern, making inferences about gas hydrate distributions more uncertain. The recognition of as-yet unmapped bottom simulating reflections or top of gas features seaward of the 2000 m bathymetric contour (e.g., Cape Fear Slide, Currituck slide, beneath deepwater gas seeps) within the Mid-Atlantic Bight expands the area of probable gas hydrates on this margin.

Delaware, Maryland, New Jersey, New York, North Ca↗
USGS2022

Northern Cascadia Margin gas hydrates — Regional geophysical surveying, IODP drilling leg 311, and cabled observatory monitoring

This article reviews extensive geophysical survey data, ocean drilling results and long-term seafloor monitoring that constrain the distribution and concentration of gas hydrates within the accretionary prism of the northern Cascadia subduction margin, located offshore Vancouver Island in Canada. Seismic surveys and geologic studies conducted since the 1980s have mapped the bottom simulating reflector (BSR), detected gas hydrate occurrence and estimated gas hydrate and free gas concentrations. Additional constraints were obtained from seafloor-towed, controlled-source electromagnetic surveying. A component of these studies has been the examination of low-temperature seafloor vents and seeps that emit gas and fluids into the ocean. These features are identified seismically as chimney-like zones of reduced acoustic reflectivity within the sediment stratigraphy, functioning as conduits for gas and fluid migration from below the BSR to the seafloor. Gas hydrates have been recovered from the seafloor and from sediment cores at vent sites, mostly in massive (nodular) form and as a vein-like fracture filling. The Ocean Networks Canada cabled NEPTUNE observatory has gathered extensive continuous, long-term observations on gas hydrate dynamics at the seafloor and in boreholes at two nodes on the continental slope featuring high gas hydrate concentrations. Measurements taken at the observatory include a time-series of gas bubble emission rates, changes in the near-seafloor electromagnetic structure and seafloor compliance linked to gas hydrate formation and dissociation. Two Integrated Ocean Drilling Program (IODP) expeditions collected cores, measured downhole properties and deployed downhole instruments within the central accretionary prism. At IODP Site U1364, pore pressures are being monitored above and below the base of the gas hydrate stability zone at a slope setting using an “Advanced Circulation Obviation Retrofit Kit” (A-CORK). Downhole pore pressures, temperatures and electrical resistivities also are being monitored at IODP Site U1416 using the “Simple Cabled Instrument for Measuring Parameters In Situ” (SCIMPI) tool at a vent site from near-seafloor to just above the base of the gas hydrate stability zone.

British Columbia↗
USGS2022

Estimates of metals contained in abyssal manganese nodules and ferromanganese crusts in the global ocean based on regional variations and genetic types of nodules

Deep-ocean ferromanganese crusts and manganese nodules are important marine repositories for global metals. Interest in these minerals as potential resources has led to detailed sampling in many regions of the global ocean, allowing for updated estimates of their global extent. Here, we present global estimates of total tonnage as well as contained metal concentrations and tonnages for ferromanganese crusts and manganese nodules using the most extensive compilation of geochemical data collected to date, along with updated boundaries of regions of interest for these minerals. We present results from mean composition calculated in two ways: first, a global flat average of regional mean compositions, and second, a regionally weighted average that considers differences in chemistry among genetic types and/or oceanographic and geologic settings for these mineral occurrences. For nodules, we use the three genetic types: (1) hydrogenetic, typified by nodules from the West Pacific Nodule Field and Penrhyn Basin; (2) diagenetic, typified by nodules from the Peru Basin; (3) mixed hydrogenetic-diagenetic, typified by nodules from the Clarion–Clipperton Zone and the Central Indian Ocean Basin, and Atlantic Ocean regional type hydrogenetic nodules. All crusts considered here are of hydrogenetic origin, which we divide into seven regional types that reflect a combination of ocean basin and other source inputs. Crust types include Arctic Ocean, Atlantic Ocean, Indian Ocean, Continental Margin, Prime Crust Zone (PCZ), North Pacific (non PCZ), and South Pacific. Based on our areal estimates, we find that abyssal regions likely to contain hydrogenetic-type nodules are by far the most widespread in the global ocean (47% of total area), Atlantic Ocean (28%) are next, followed by mixed diagenetic-hydrogenetic (22%) and diagenetic (3%) types. For crusts, the Prime Crust Zone is the most extensive global region (27% of total area) followed by South Pacific (20%), Indian Ocean (18%), North Pacific (12%), Continental Margins (11%), Atlantic Ocean (10%), and Arctic Ocean (2%) types. The global total tonnage estimates that we calculated from this method are 21 × 10 10 dry tons for manganese nodules, within the range of previous estimates, and 93 × 10 10 dry tons for ferromanganese crusts, which is 4.5 times higher than the 20 × 10 10 dry tons reported by Hein et al. (2003). This geology and oceanography driven approach to marine mineral quantification contrasts with estimates typically carried out for terrestrial mineral resource deposits. Nevertheless, these estimates and the data that support them demonstrate that marine minerals are an impressive repository for global metals.

Book chapter↗
USGS2022

Pollution and wildlife health

Pollution is a pervasive and growing threat to wildlife health. This chapter discusses two broad groups of pollution, those whose abatement could have immediate beneficial effects including light, air, and noise pollution, and those that will take relatively longer to address due to their environmental persistence or their continuing discharge. Whilst we are very good at detecting the presence of pollutants in tissues or the environment, making a convincing link between the presence of these compounds and mortality events in the field or population effects will remain a challenge for the foreseeable future. Creative new approaches are also being considered to mitigate the effects of pollution on wildlife and ecosystems. Depending on the source of pollution, the beneficial outcomes of mitigation measures, if properly implemented, could have immediate effects. Given the plethora of potential adverse pollution effects, frameworks to prioritize which threats are most likely to cause adverse effects and develop means to address or manage them are an imperative. In the interim, focusing on preserving existing habitats and reducing our footprint by adjusting human activities to minimize the release of pollutants into the environment will go a long way toward promoting healthy wildlife and ecosystems.

Book chapter↗
USGS2022

Leading change with diverse stakeholders

The shift to holistic approaches to managing wildlife health, and the complex landscape of partners and stakeholders, has led to a focus on the development of leadership skills in addition to technical expertise. This chapter introduces key elements and core skills for successful cross-sectoral and transdisciplinary leadership that will help wildlife health practitioners effectively lead change toward integrated, mutually beneficial health outcomes for all sectors. Leading change benefits from having good individual leadership skills, including emotional intelligence or the capacity to be aware of, control, and express one’s emotions, and to handle interpersonal relationships judiciously and empathetically. Driving multi-sectoral change is facilitated by wildlife health professionals becoming champions for change and being empowered to form and lead teams and participate effectively on governance structures such as interagency committees or working groups. Finally, the four main elements in leading change are envisioning the future state, engaging key stakeholders and coalition building, identifying barriers and breaking down resistance to change, and institutionalizing change. Effective leadership can be enabled by being open to new ideas, constantly questioning the effectiveness of one’s approach, and a commitment to lifelong learning. Application of these leadership skills and approaches can help effect change, resulting in improved wildlife population health.

Book chapter↗
USGS2022

Diving and foraging behaviors

Manatees and dugongs live in tropical and semi-tropical regions around the world. Their preferred habitats are seagrass beds, rivers, lakes, and estuaries. Manatees live in both freshwater and marine systems although habitat preferences vary across the three species, while the dugong is entirely marine. Sirenians are shallow water divers, and their dive durations are short compared to most other marine mammals. The maximum recorded manatee dive duration is 24 min, with the maximum recorded duration of a dugong dive being about half that. Even though the durations of dugong dives are shorter than those of manatees, current data indicate that dugongs dive deeper than manatees. Dive depths for manatees generally do not exceed 5 m, other than during occasional travel over deeper water; however, this may be an artifact of water depth in areas where diving data were recorded, or where manatees live. In some parts of their range, dugongs are found over deep-water seagrass beds and dives have been recorded to more than 30 m. All extant sirenians eat diverse plant-based diets: collectively they have been documented feeding on at least 55 genera of marine and freshwater plants. Although not confirmed for the Amazonian manatee, it is likely that all extant sirenians eat animal, as well as plant, matter. West Indian and African manatees have been documented eating marine and freshwater fish and invertebrates , and for African manatees, these food resources are a regular part of their diet, arguably making them omnivores . Dugongs have been recorded targeting invertebrates at the high latitude limits of their range in winter. All manatees like to drink fresh water, in contrast to dugongs, which live entirely in marine systems and apparently meet the water requirements from their food.

Book chapter↗
USGS2022

Social and reproductive behaviors

Sirenian social and reproductive behaviors lack much complexity or diversity. Whereas sirenians are usually sighted as solitary, or as cows with single calves, aggregations of many individuals can occur. Persistent social groupings are unknown. Home ranges are widely overlapping. Mating systems of dugongs ( Dugong dugon ) have been variously described as leks or as scramble promiscuity (mating herds ) and lone mating pairs have been observed in areas of low density, but further research into the hypothesized leks is needed (especially because scramble promiscuity has been observed in the same region). Dugongs and all manatees ( Trichechus ) show scramble promiscuity, wherein males form groups that escort single females with much physical contact for many days. The strongest social bonds are between females and nursing calves. Florida manatees ( Trichechus manatus latirostris ) show natal philopatry for years after weaning. Socially transmitted knowledge (tradition) appears important to Florida manatees and perhaps all species of sirenians, particularly in regions where seasonal movements during winter are necessary for survival, such as in winter for Florida manatees, and dugongs at the high latitude limits of their range. Some populations of Antillean, Amazonian, and African manatees have regular movements in response to seasonal flooding and access to food, which also may be learned through tradition . Dugongs may rely on group movements based on traditional knowledge in response to regional loss of food supply from extreme weather events. Communication is most obvious through vocalizations, which can show individual distinctiveness. Vocal communication is most prevalent between mothers and calves. Allomaternal care occurs in Florida manatees at shared aggregation sites. Florida manatees occupying a given region can consist of multiple matrilines that develop through the early bonding of calves to mothers and subsequent natal philopatry. Population genetics research supports male-biased dispersal and possible female-based philopatry in other trichechids, but perhaps not as strongly in dugongids. Considerable further research is needed on these and related topics to more comprehensively understand sirenian social and reproductive behavior.

Book chapter↗
USGS2022

Hot spots and hot moments in the Critical Zone: Identification of and incorporation into reactive transport models

Biogeochemical processes are often spatially discrete (hot spots) and temporally isolated (hot moments) due to variability in controlling factors like hydrologic fluxes, lithological characteristics, bio-geomorphic features, and external forcing. Although these hot spots and hot moments (HSHMs) account for a high percentage of carbon, nitrogen and nutrient cycling within the Critical Zone, the ability to identify and incorporate them into reactive transport models remains a significant challenge. This chapter provides an overview of the hot spots hot moments (HSHMs) concepts, where past work has largely focused on carbon and nitrogen dynamics within riverine systems. This work is summarized in the context of process-based and data-driven modeling approaches, including a brief description of recent research that casts a wider net to incorporate Hg, Fe and other Critical Zone elements, and focuses on interdisciplinary approaches and concepts. The broader goal of this chapter is to provide an overview of the gaps in our current understanding of HSHMs, and the opportunities therein, while specifically focusing on the underlying parameters and processes leading to their prognostic and diagnostic representation in reactive transport models.

Book chapter↗
USGS2022

Biofilms in the Critical Zone: Distribution and mediation of processes

Microbial biofilms occur in all levels of the Critical Zone (CZ); they are on and in the vegetation, throughout the soil-saprolite zone, and along fractures in deep subsurface. Here we discuss biofilms in each level of the CZ with a focus in the soil-saprolite continuum. We show how scanning electron microscope (SEM) images provide an appropriate scale to explore microbe mineral interactions in the CZ and can be used without extensive sample preparation. Through SEM imaging, we show that biofilms weather primary minerals, that macropores and fractures are hotspots of biofilm development, that biologic precipitation of short-range-order minerals (SROs) occurs in biofilms, and that biofilms are important in the process of organic matter stabilization.

Book chapter↗