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USGS2013

Status and understanding of groundwater quality in the South Coast Range-Coastal study unit, 2008: California GAMA Priority Basin Project

Groundwater quality in the South Coast Range–Coastal (SCRC) study unit was investigated from May through November 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in the Southern Coast Range hydrologic province and includes parts of Santa Barbara and San Luis Obispo Counties. The GAMA Priority Basin Project is conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board and the Lawrence Livermore National Laboratory. The GAMA Priority Basin Project was designed to provide a statistically unbiased, spatially distributed assessment of untreated groundwater quality within the primary aquifer system. The primary aquifer system is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the SCRC study unit. The assessments for the SCRC study unit were based on water-quality and ancillary data collected in 2008 by the USGS from 55 wells on a spatially distributed grid, and water-quality data from the CDPH database. Two types of assessments were made: (1) status, assessment of the current quality of the groundwater resource, and (2) understanding, identification of the natural and human factors affecting groundwater quality. Water-quality and ancillary data were collected from an additional 15 wells for the understanding assessment. The assessments characterize untreated groundwater quality, not the quality of treated drinking water delivered to consumers by water purveyors. The first component of this study, the status assessment of groundwater quality, used data from samples analyzed for anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring inorganic constituents such as major ions and trace elements. Although the status assessment applies to untreated groundwater, Federal and California regulatory and non-regulatory water-quality benchmarks that apply to drinking water are used to provide context for the results. Relative-concentrations (sample concentration divided by benchmark concentration) were used for evaluating groundwater. A relative-concentration greater than (>) 1.0 indicates a concentration greater than the benchmark and is classified as high. Inorganic constituents are classified as moderate if relative-concentrations are >0.5 and less than or equal to (≤) 1.0, or low if relative-concentrations are ≤0.5. For organic constituents, the boundary between moderate and low relative-concentrations was set at 0.1. Aquifer-scale proportion was used in the status assessment as the primary metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the areal percentage of the primary aquifer system with a high relative-concentration for a particular constituent or class of constituents. Moderate and low aquifer-scale proportions were defined as the areal percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable for the study (within 90 percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high for at least one constituent for 33 percent of the primary aquifer system in the SCRC study unit. Arsenic, molybdenum, and nitrate were the primary inorganic constituents with human-health benchmarks that were detected at high relative-concentrations. Inorganic constituents with aesthetic benchmarks, referred to as secondary maximum contaminant levels (SMCLs), had high relative-concentrations for 35 percent of the primary aquifer system. Iron, manganese, total dissolved solids (TDS), and sulfate were the inorganic constituents with SMCLs detected at high relative-concentrations. In contrast to inorganic constituents, organic constituents with human-health benchmarks were not detected at high relative-concentrations in the primary aquifer system in the SCRC study unit. Of the 205 organic constituents analyzed, 21 were detected—13 with human-health benchmarks. Perchloroethene (PCE) was the only VOC detected at moderate relative-concentrations. PCE, dichlorodifluoromethane (CFC-12), and chloroform were detected in more than 10 percent of the primary aquifer system. Of the two special-interest constituents, one was detected; perchlorate, which has a human-health benchmark, was detected at moderate relative-concentrations in 29 percent of the primary aquifer system and had a detection frequency of 60 percent in the SCRC study unit. The second component of this study, the understanding assessment, identified the natural and human factors that may have affected groundwater quality in the SCRC study unit by evaluating statistical correlations between water-quality constituents and potential explanatory factors. The potential explanatory factors evaluated were land use, septic tank density, well depth and depth to top-of-perforations, groundwater age, density and distance to the nearest formerly leaking underground fuel tank (LUFT), pH, and dissolved oxygen (DO) concentration. Results of the statistical evaluations were used to explain the occurrence and distribution of constituents in the study unit. DO was the primary explanatory factor influencing the concentrations of many inorganic constituents. Arsenic, iron, and manganese concentrations increased as DO concentrations decreased, consistent with patterns expected as a result of reductive dissolution of iron and (or) manganese oxides in aquifer sediments. Molybdenum concentrations increased in anoxic conditions and in oxic conditions with high pH, reflecting two mechanisms for the mobilization of molybdenum—reductive dissolution and pH-dependent desorption under oxic conditions from aquifer sediments. Nitrate concentrations decreased as DO concentrations decreased which would be consistent with degradation of nitrate under anoxic conditions (denitrification). It also is possible that nitrate concentrations decreased in relation to increasing depth and groundwater age and not as a result of denitrification. Groundwater age was another explanatory factor frequently correlated to several inorganic constituents. Iron and manganese concentrations were higher in pre-modern (water recharged before 1952) or mixed-age groundwater. This correlation is one indication that iron and manganese are from natural sources. Nitrate, TDS, and sulfate concentrations were higher in modern groundwater (water recharged since 1952) and may indicate that human activities increase concentrations of nitrate, TDS, and sulfate. Land use was a third explanatory factor frequently correlated with inorganic constituents. Nitrate, TDS, and sulfate concentrations were higher in agricultural land-use areas than in natural land-use areas, indicating that increased concentrations may be a result of agricultural practices. Organic constituents usually were detected at low relative-concentrations; therefore, statistical analyses of relations to explanatory factors usually were done for classes of constituents (for example, pesticides or solvents) as well as for selected constituents. The number of VOCs detected in a well was not correlated to any of the explanatory factors evaluated. The number of pesticide and solvent detections and PCE and CFC-12 concentrations were higher in modern groundwater than in pre-modern groundwater. PCE and CFC-12 also were positively correlated to the density of LUFTs. PCE was negatively correlated to natural land use. Chloroform concentrations were positively correlated to the density of septic systems. Perchlorate concentrations were greater in agricultural areas than in urban or natural areas. Correlation of perchlorate with DO may indicate that perchlorate biodegradation under anoxic conditions may occur. Anthropogenic sources have contributed perchlorate to groundwater in the SCRC study unit, although low levels of perchlorate may occur naturally.

California↗
USGS2013

Estimation of total nitrogen and total phosphorus in streams of the Middle Columbia River Basin (Oregon, Washington, and Idaho) using SPARROW models, with emphasis on the Yakima River Basin, Washington

The watershed model SPARROW (Spatially Related Regressions on Watershed attributes) was used to predict total nitrogen (TN) and total phosphorus (TP) loads and yields for the Middle Columbia River Basin in Idaho, Oregon, and Washington. The new models build on recently published models for the entire Pacific Northwest, and provide revised load predictions for the arid interior of the region by restricting the modeling domain and recalibrating the models. Results from the new TN and TP models are provided for the entire region, and discussed with special emphasis on the Yakima River Basin, Washington. In most catchments of the Yakima River Basin, the TN and TP in streams is from natural sources, specifically nitrogen fixation in forests (TN) and weathering and erosion of geologic materials (TP). The natural nutrient sources are overshadowed by anthropogenic sources of TN and TP in highly agricultural and urbanized catchments; downstream of the city of Yakima, most of the load in the Yakima River is derived from anthropogenic sources. Yields of TN and TP from catchments with nearly uniform land use were compared with other yield values and export coefficients published in the scientific literature, and generally were in agreement. The median yield of TN was greatest in catchments dominated by agricultural land and smallest in catchments dominated by grass and scrub land. The median yield of TP was greatest in catchments dominated by forest land, but the largest yields (90th percentile) of TP were from agricultural catchments. As with TN, the smallest TP yields were from catchments dominated by grass and scrub land.

Idaho;Oregon;Washington↗
USGS2014

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

Groundwater resources from alluvial and bedrock aquifers of the Denver Basin are critical for municipal, domestic, and agricultural uses in Colorado along the eastern front of the Rocky Mountains. Rapid and widespread urban development, primarily along the western boundary of the Denver Basin, has approximately doubled the population since about 1970, and much of the population depends on groundwater for water supply. As part of the National Water-Quality Assessment Program, the U.S. Geological Survey conducted groundwater-quality studies during 2003–5 in the Denver Basin aquifer system to characterize water quality of shallow groundwater at the water table and of the bedrock aquifers, which are important drinking-water resources. For the Denver Basin, water-quality constituents of concern for human health or because they might otherwise limit use of water include total dissolved solids, fluoride, sulfate, nitrate, iron, manganese, selenium, radon, uranium, arsenic, pesticides, and volatile organic compounds. For the water-table studies, two monitoring-well networks were installed and sampled beneath agricultural (31 wells) and urban (29 wells) land uses at or just below the water table in either alluvial material or near-surface bedrock. For the bedrock-aquifer studies, domestic- and municipal-supply wells completed in the bedrock aquifers were sampled. The bedrock aquifers, stratigraphically from youngest (shallowest) to oldest (deepest), are the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers. The extensive dataset collected from wells completed in the bedrock aquifers (79 samples) provides the opportunity to evaluate factors and processes affecting water quality and to establish a baseline that can be used to characterize future changes in groundwater quality. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating constituents and tracers. This report discusses spatial and statistical distributions of chemical constituents and evaluates natural and human-related processes that affect water quality. Findings are synthesized to assess the vulnerability of the Denver Basin aquifer system to groundwater contamination. The chemistry of groundwater samples collected from the water-table wells was generally different from that of samples collected from the bedrock-aquifer wells. Samples from the water-table wells tended to have higher concentrations of total dissolved solids and most major ions. Concentrations of several constituents with potential human-health concerns, including nitrate, selenium, uranium, and arsenic, decreased with depth and were highest in samples from the water-table wells. Exceedances of drinking-water standards and water-quality benchmarks were more frequently associated with shallow groundwater samples; concentrations of total dissolved solids and sulfate exceeded water-quality benchmarks for about half or more of samples from the water-table wells. The sediments and rocks of the Denver Basin are natural sources of the trace elements selenium, uranium, and arsenic, which affect their concentrations in groundwater. Detections of organic contaminants, which are typically indicative of human sources of contamination to groundwater, were more frequent in samples from the water-table wells. Pesticide compounds and volatile organic compounds were detected in 33 and 62 percent, respectively, of water-table well samples. Detected organic contaminant concentrations were much less than the associated drinking-water standards. Samples collected from the bedrock aquifers had lower concentrations of total dissolved solids than did samples collected from the water-table wells, although within the bedrock-aquifer samples, concentrations increased from the Dawson to Denver to Arapahoe to Laramie-Fox Hills aquifers. Concentrations of total dissolved solids and many constituents varied spatially and with depth in the bedrock aquifers, likely as a result of ion-exchange and oxidation-reduction reactions, which are important processes affecting water quality. Major-ion chemistry generally evolved from a calcium-bicarbonate to calcium-sulfate composition, with some sodium-bicarbonate and sodium-sulfate facies in the deeper bedrock aquifers, likely resulting from longer residence times and more extensive water-rock interaction. Oxidation-reduction conditions generally evolved from oxic at the water table to anoxic with increasing depth in the bedrock aquifers. Most samples from the bedrock aquifers were anoxic. Exceedances of drinking-water standards and water-quality benchmarks for the bedrock aquifers occurred in 1 percent or less of samples for nitrate, selenium, or arsenic; there were no exceedances for uranium. Exceedances for total dissolved solids, sulfate, manganese, and iron were generally between about 10 and 20 percent for the bedrock-aquifer samples. Radon concentrations, which were only measured in samples collected from two of the bedrock aquifers, exceeded the lower proposed drinking-water standard for more than 90 percent of samples but exceeded the higher alternative standard for less than 5 percent of samples. Pesticide compounds and volatile organic compounds were detected in 3 and 22 percent, respectively, of bedrock-aquifer samples, all at concentrations that were that were much less than drinking-water standards. Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor or degraded water quality in shallow groundwater decreased with depth; many of these constituents are not geochemically conservative and are affected by geochemical reactions such as oxidation-reduction reactions. Groundwater age tracers provide additional insight into aquifer vulnerability and help determine if young groundwater of potentially poor quality has migrated to deeper parts of the bedrock aquifers used for drinking-water supply. Age-tracer results were used to group samples into categories of young, mixed, and old groundwater. Groundwater ages transitioned from mostly young in the water-table wells to mostly mixed in the shallowest bedrock aquifer, the Dawson aquifer, to mostly old in the deeper bedrock aquifers. Although the bedrock aquifers are mostly old groundwater of good water quality, several lines of evidence indicate that young, contaminant-bearing recharge has reached shallow to moderate depths in some areas of the bedrock aquifers. The Dawson aquifer is the most vulnerable of the bedrock aquifers to contamination, but results indicate that the older (deeper) bedrock aquifers are also vulnerable to groundwater contamination and that mixing with young recharge has occurred in some areas. Heavy pumping has caused water-level declines in the bedrock aquifers in some parts of the Denver Basin, which has the potential to enhance the transport of contaminants from overlying units. Results of this study are consistent with the existing conceptual understanding of aquifer processes and groundwater issues in the Denver Basin and add new insight into the vulnerability of the bedrock aquifers to groundwater contamination.

Colorado↗
USGS2014

Integrated hydrologic model of Pajaro Valley, Santa Cruz and Monterey Counties, California

Increasing population, agricultural development (including shifts to more water-intensive crops), and climate variability are placing increasingly larger demands on available groundwater resources in the Pajaro Valley, one of the most productive agricultural regions in the world. This study provided a refined conceptual model, geohydrologic framework, and integrated hydrologic model of the Pajaro Valley. The goal of this study was to produce a model capable of being accurate at scales relevant to water management decisions that are being considered in the revision and updates to the Basin Management Plan (BMP). The Pajaro Valley Hydrologic Model (PVHM) was designed to reproduce the most important natural and human components of the hydrologic system and related climatic factors, permitting an accurate assessment of groundwater conditions and processes that can inform the new BMP and help to improve planning for long-term sustainability of water resources. Model development included a revision of the conceptual model of the flow system, reevaluation of the previous model transformed into MODFLOW, implementation of the new geohydrologic model and conceptual model, and calibration of the transient hydrologic model. The PVHM model, using MODFLOW with the Farm Process (MF-FMP2), is capable of being accurate at seasonal to interannual time frames and subregional to valley-wide spatial scales for the assessment of the groundwater hydrologic budget for water years 1964–2009, as well as potential assessment of the BMP components and sustainability analysis of conjunctive use. The model provides a good representation of the regional flow system and the use and movement of water throughout the valley. Simulated changes in storage over time show that, prior to the 1984–92 dry period, significant withdrawals from storage occurred only during drought years. Since about 1993, growers in the Pajaro Valley have shifted to more water intensive crops, such as strawberries, bushberries, and vegetable row crops, as well as making additional rotational plantings, which have increased demand on limited groundwater resources. Simulated groundwater flow indicates that vertical hydraulic gradients between horizontal layers fluctuate and even reverse in several parts of the basin as recharge and pumpage rates change seasonally and annually. The majority of recharge predominantly enters the Alluvial aquifer system, and along with pumpage and the largest fractions of storage depletion, occurs in the inland regions. Coastal inflow as seawater intrusion replaces much of the potential storage depletion in the coastal regions. The simulated long-term imbalance between inflows and outflows indicates overdraft of the groundwater basin averaging about 12,950 acre-feet per year (acre-ft/yr) over the 46-year period of water years (1964–2009). Annual overdraft varies considerably from year to year, depending on land use, pumpage, and climate conditions. Climatically driven factors can affect inflows, outflows, and water use by as much as a factor of two between wet and dry years. Coastal inflows and outflows vary by year and by aquifer; the net coastal inflow, or seawater intrusion, ranges from about 1,000 to more than 6,000 acre-ft/yr. Maps of simulated and measured water-level elevations indicate regions with water levels below sea level in the alluvium and Aromas layers. Ongoing expansion of local hydrologic monitoring networks indicates the importance of these networks to the understanding of changes in groundwater flow, streamflow, and streamflow infiltration. In particular, the monitoring of streamflow, groundwater pumpage, and groundwater levels throughout the valley not only indicates the state of the resources, but also provides valuable information for model calibration and for model-based evaluation of management actions. The HS-ASR was simulated for the years 2002–09, and replaced about about 1,290 acre-ft of coastal pumpage. This was combined with the simulation of additional 6,200 acre-ft of deliveries from supplemental wells, recycled water, and city connection deliveries through the CDS that also supplanted some coastal pumpage. Total simulated deliveries were 7,350 acre-ft of the 7,500 acre-ft of reported deliveries for the period 2002-09. The completed CDS should be capable of delivering about 8.8 million cubic meters (7,150 acre-ft) of water per year to coastal farms within the Pajaro Valley, if all the local supply components were fully available for this purpose. This would represent about 15 percent of the 48,300 acre-ft (59.6 million cubic meters) average agricultural pumpage for the period 2005 to 2009. Combined with the potential capture and reuse of some of the return flows and tile-drain flows, this could represent an almost 70 percent reduction of average overdraft for the entire valley and a large part of the coastal pumpage that induces seawater intrusion.

California↗
USGS2014

Documentation of a groundwater flow model (SJRRPGW) for the San Joaquin River Restoration Program study area, California

To better understand the potential effects of restoration flows on existing drainage problems, anticipated as a result of the San Joaquin River Restoration Program (SJRRP), the U.S. Geological Survey (USGS), in cooperation with the U.S. Bureau of Reclamation (Reclamation), developed a groundwater flow model (SJRRPGW) of the SJRRP study area that is within 5 miles of the San Joaquin River and adjacent bypass system from Friant Dam to the Merced River. The primary goal of the SJRRP is to reestablish the natural ecology of the river to a degree that restores salmon and other fish populations. Increased flows in the river, particularly during the spring salmon run, are a key component of the restoration effort. A potential consequence of these increased river flows is the exacerbation of existing irrigation drainage problems along a section of the river between Mendota and the confluence with the Merced River. Historically, this reach typically was underlain by a water table within 10 feet of the land surface, thus requiring careful irrigation management and (or) artificial drainage to maintain crop health. The SJRRPGW is designed to meet the short-term needs of the SJRRP; future versions of the model may incorporate potential enhancements, several of which are identified in this report. The SJRRPGW was constructed using the USGS groundwater flow model MODFLOW and was built on the framework of the USGS Central Valley Hydrologic Model (CVHM) within which the SJRRPGW model domain is embedded. The Farm Process (FMP2) was used to simulate the supply and demand components of irrigated agriculture. The Streamflow-Routing Package (SFR2) was used to simulate the streams and bypasses and their interaction with the aquifer system. The 1,300-square mile study area was subdivided into 0.25-mile by 0.25-mile cells. The sediment texture of the aquifer system, which was used to distribute hydraulic properties by model cell, was refined from that used in the CVHM to better represent the natural heterogeneity of aquifer-system materials within the model domain. In addition, the stream properties were updated from the CVHM to better simulate stream-aquifer interactions, and water-budget subregions were refined to better simulate agricultural water supply and demand. External boundary conditions were derived from the CVHM. The SJRRPGW was calibrated for April 1961 to September 2003 by using groundwater-level observations from 133 wells and streamflow observations from 19 streamgages. The model was calibrated using public-domain parameter estimation software (PEST) in a semi-automated manner. The simulated groundwater-level elevations and trends (including seasonal fluctuations) and surface-water flow magnitudes and trends reasonably matched observed data. The calibrated model is planned to be used to assess the potential effects of restoration flows on agricultural lands and the relative capabilities of proposed SJRRP actions to reduce these effects.

California↗
USGS2014

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas↗
USGS2014

An overview comparing results from two decades of monitoring for pesticides in the Nation’s streams and rivers, 1992-2001 and 2002-2011

This report provides an overview of the U.S. Geological Survey National Water-Quality Assessment program and National Stream Quality Accounting Network findings for pesticide occurrence in U.S. streams and rivers during 2002–11 and compares them to findings for the previous decade (1992–2001). In addition, pesticide stream concentrations were compared to Human Health Benchmarks (HHBs) and chronic Aquatic Life Benchmarks (ALBs). The comparisons between the decades were intended to be simple and descriptive. Trends over time are being evaluated separately in a series of studies involving rigorous trend analysis. During both decades, one or more pesticides or pesticide degradates were detected more than 90 percent of the time in streams across all types of land uses. For individual pesticides during 2002–11, atrazine (and degradate, deethylatrazine), carbaryl, fipronil (and degradates), metolachlor, prometon, and simazine were detected in streams more than 50 percent of the time. In contrast, alachlor, chlorpyrifos, cyanazine, diazinon, EPTC, Dacthal, and tebuthiuron were detected less frequently in streams during the second decade than during the first decade. During 2002–11, only one stream had an annual mean pesticide concentration that exceeded an HHB. In contrast, 17 percent of agriculture land-use streams and one mixed land-use stream had annual mean pesticide concentrations that exceeded HHBs during 1992–2001. The difference between the first and second decades in terms of percent of streams exceeding HHBs was attributed to regulatory changes. During 2002–11, nearly two-thirds of agriculture land-use streams and nearly one-half of mixed land-use streams exceeded chronic ALBs. For urban land use, 90 percent of the streams exceeded a chronic ALB. Fipronil, metolachlor, malathion, cis-permethrin, and dichlorvos exceeded chronic ALBs for more than 10 percent of the streams. For agriculture and mixed land-use streams, the overall percent of streams that exceeded a chronic ALB was very similar between the decades. For urban land-use streams, the percent of streams exceeding a chronic ALB during 2002–11 nearly doubled that seen during 1992–2001. The reason for this difference was the inclusion of fipronil monitoring during the second decade. Across all land-use streams, the percent of streams exceeding a chronic ALB for fipronil during 2002–11 was greater than all other insecticides during both decades. The percent of streams exceeding a chronic ALB for metolachlor, chlorpyrifos, diazinon, malathion, and carbaryl decreased from the first decade to the second decade. The results of the 2002–11 summary and comparison to 1992–2001 are consistent with the results from more rigorous trend analysis of pesticide stream concentrations for individual streams in various regions of the U.S.

Scientific Investigations Report↗
USGS2015

Areas contributing recharge to production wells and effects of climate change on the groundwater system in the Chipuxet River and Chickasheen Brook Basins, Rhode Island

The Chipuxet River and Chickasheen Brook Basins in southern Rhode Island are an important water resource for public and domestic supply, irrigation, recreation, and aquatic habitat. The U.S. Geological Survey, in cooperation with the Rhode Island Department of Health, began a study in 2012 as part of an effort to protect the source of water to six large-capacity production wells that supply drinking water and to increase understanding of how climate change might affect the water resources in the basins. Soil-water-balance and groundwater-flow models were developed to delineate the areas contributing recharge to the wells and to quantify the hydrologic response to climate change. Surficial deposits of glacial origin ranging from a few feet to more than 200 feet thick overlie bedrock in the 24.4-square mile study area. These deposits comprise a complex and productive aquifer system. Simulated areas contributing recharge to the production wells covered a total area of 0.63 square miles for average well withdrawal rates from 2007 through 2011 (total rate of 583 gallons per minute). Simulated areas contributing recharge for the maximum well pumping capacities (total rate of 3,700 gallons per minute) covered a total area of 2.55 square miles. Most simulated areas contributing recharge extend upgradient of the wells to morainal and upland till deposits and to groundwater divides. Some simulated areas contributing recharge include small, isolated areas remote from the wells. Relatively short groundwater traveltimes from recharging locations to discharging wells indicated that the wells are vulnerable to contamination from land-surface activities; median traveltimes ranged from 3.5 to 8.6 years for the production wells examined, and 57 to 91 percent of the traveltimes were 10 years or less. Land cover in the areas contributing recharge includes a substantial amount of urban and agriculture land use for five wells adjacent to the Chipuxet River; for one well adjacent to a tributary stream, land use is less developed. The calibrated groundwater-flow model provided a single, best representation of the areas contributing recharge to a production well. The parameter variance-covariance matrix from model calibration was used to create parameter sets that reflect the uncertainty of the parameter estimates and the correlation among parameters to evaluate the uncertainty associated with the predicted contributing areas to the wells. A Monte Carlo analysis led to contributing areas expressed as a probability distribution that differed from a single deterministic contributing area. Because of the effects of parameter uncertainty, the size of the probabilistic contributing areas for both average and maximum pumping rates was larger than the size of the deterministic contributing areas for the wells. Thus, some areas not in the deterministic contributing area might actually be in the contributing area, including additional areas of urban and agricultural land use that has the potential to contaminate groundwater. Additional areas that might be in the contributing area included recharge originating near the pumping wells that have relatively short groundwater-flow paths and traveltimes. At the maximum pumping rates, areas associated with low probabilities extended long distances along groundwater divides in the uplands remote from the wells. Climate projections for the Chipuxet River and Chickasheen Brook Basins from downscaled output from general circulation models indicate that mean annual temperature might increase by 4.7 degrees Fahrenheit and 8.0 degrees Fahrenheit by the late 21st century (2070–99) compared with the late 20th century (1970–99) under scenarios of lower and higher emissions of greenhouse gases, respectively. By the late 21st century, winter and spring precipitation is projected to increase by 12 to 17 percent, summer precipitation to increase by about the same as mean annual precipitation (8 percent), and fall precipitation to decrease by 5 percent for both emission scenarios compared with the late 20th century. Soil-water-balance simulations indicate that, although precipitation is expected to increase in three seasons, only in winter do precipitation increases exceed actual evapotranspiration increases. Recharge is projected to decrease in fall and generally change little in spring and summer. By the late 21st century, winter recharge is expected to increase by 13 percent for the lower emissions scenario and by 15 percent for the higher emissions scenario. In fall, recharge is projected to diminish by 13 percent for the lower emissions scenario and by 24 percent for the higher emissions scenario. Although recharge is projected to change seasonally in the 21st century, mean annual recharge changes minimally. Soil moisture is projected to decrease in the 21st century from spring through fall because of increases in potential evapotranspiration, and in fall because of decreases in precipitation in addition to increases in potential evapotranspiration. By the late 21st century, soil moisture for the lower emissions scenario is expected to decrease by 11 percent in summer and 15 percent in fall, and for the higher emissions scenario, decrease by 23 percent for both seasons. These decreases in soil moisture during the growing season might have implications for agriculture in the study area. Predicted changes in the magnitude and seasonal distribution of recharge in the 21st century increase simulated base flows and groundwater levels in the winter months for both emission scenarios, but because of less recharge in the fall and less or about the same recharge in the preceding months of spring and summer, base flows and groundwater levels in the fall months decrease for both emission scenarios. October has the largest base flow and groundwater level decreases. By the late 21st century, base flows at the Chipuxet River in October are projected to decrease by 9 percent for the lower emissions scenario and 18 percent for the higher emissions scenario. For a headwater stream in the upland till with shorter groundwater-flow paths and lower storage properties in its drainage area, base flows in October are projected to diminish by 28 percent and 42 percent for the lower and higher emissions scenarios by the late 21st century. Groundwater level changes in the uplands show substantial decreases in fall, but because of the large storage capacity of stratified deposits, water levels change minimally in the valley. By the late 21st century, water levels in large areas of upland till deposits in October are projected to decrease by up to 2 feet for the lower emissions scenario, whereas large areas decrease by up to 5 feet, with small areas with decreases of as much as 10 feet, for the higher emissions scenario. For both emission scenarios, additional areas of till go dry in fall compared with the late 20th century. Thus projected changes in recharge in the 21st century might extend low flows and low water levels for the year later in fall and there might be more intermittent headwater streams compared with the late 20th century with corresponding implications to aquatic habitat. Finally, the size and location of the simulated areas contributing recharge to the production wells are minimally affected by climate change because mean annual recharge, which is used to determine the contributing areas to the production wells, is projected to change little in the 21st century.

Rhode Island↗
USGS2015

Characterization of streamflow, salinity, and selenium loading and land-use change in Montrose Arroyo, western Colorado, from 1992 to 2013

Salinity and dissolved selenium are known water-quality impairments in the lower Gunnison River watershed of western Colorado. Salinity is a concern because of its adverse effects on agricultural land and equipment, and on municipal and industrial users. The Montrose Arroyo watershed in Montrose, Colorado, contains agricultural and residential areas as well as undeveloped land and has undergone substantial land-use change since the early 1990s. Previous sampling efforts indicated salinity concentrations and loads have remained constant since land-use change began in the early 1990s; however, recent sampling also indicated that dissolved-selenium concentrations and loads have begun to increase. In response to the potential increasing dissolved-selenium concentrations and loads, the U.S. Geological Survey—in cooperation with the Bureau of Reclamation; Colorado River Basin Salinity Control Forum; and Colorado River Water Conservation District—continued to monitor salinity and dissolved-selenium concentrations and loads in the Montrose Arroyo watershed. This report characterizes salinity and dissolved-selenium loads in Montrose Arroyo from 1992 to 2013 at three sites: Montrose Arroyo at East Niagara Street (MA2, U.S. Geological Survey site identification number 382802107513301), Montrose Arroyo at 6700 Road (MA3, U.S. Geological Survey site identification number 382711107500501), and Montrose Arroyo at 6750 and Ogden Roads (MA4, U.S. Geological Survey site identification number 382702107493701). A detailed land-use change analysis was also characterized in the MA3 subwatershed. The three sites were used to monitor salinity and dissolved-selenium concentrations and loads in Montrose Arroyo. Over a period from December 2011 through September 2013, 46 water-quality samples and streamflow measurements were collected at sites MA2, MA3, and MA4. Streamflow, salinity concentrations and loads, and selenium concentrations and loads were characterized and compared between the pre-lateral (before April 1999) and post-growth periods (March 2008 through September 2013) and between post-lateral (April 1999 through October 2000) and post-growth periods. Results from a previous USGS study on the characterization of salinity and selenium loading and land-use change in Montrose Arroyo from 1992 to 2010 indicated that there was no change in salinity load at site MA2 and a significant increase in dissolved-selenium load from the pre-lateral period to the post-growth period. Data associated with this report indicate the selenium loads at site MA2 show no significant change from the pre-lateral period to the post-growth period. In addition, both salinity load and dissolved-selenium load at site MA3 show significant decreases in salinity and dissolved-selenium load for both periods that are potentially associated with land-use change. Land use was characterized for 1992, 2002, and 2009 for site MA3. The common land-use change in the MA3 subwatershed was a conversion from previously irrigated agricultural land to urban land use. The MA3 subwatershed had 124 acres of irrigated land use converted to urban land use and 27.1 acres of unirrigated desert converted to urban land use from 1992 to 2009. Consistent with findings in previous land-use change reports, salinity and dissolved-selenium loading at site MA3 showed significant decreases as irrigated land was converted to urban land use.

Colorado↗
USGS2015

Management of conservation reserve program grasslands to meet wildlife habitat objectives

Numerous studies document environmental and social benefits of the Conservation Reserve Program (CRP). This report offers a synopsis of findings regarding effects of establishing CRP conservation practices on the quality and distribution of wildlife habitat in agricultural landscapes. On individual farms, year-round provision of wildlife habitat by the CRP may appear relatively insignificant. However, considered from multi-farm to National scales, such improvements in habitat and wildlife response have proven to be extensive and profound. Because CRP acres historically have been dominated by plantings of introduced and native grasses, this report focuses on issues pertaining to wildlife response to grass-dominated conservation practices. While the majority of CRP acres have been concentrated largely in the Great Plains and Corn Belt regions, 47 states (and Puerto Rico) have participated, resulting in measurable environmental benefits throughout the United States. Numerous investigations of habitat use by a wide range of wildlife species reveal that periodic management of CRP lands can enhance benefits through and beyond a typical 10 year general CRP contract. Over its 28-year existence, the CRP has evolved into an effective integration of conservation and agricultural policies targeting fragile and environmentally-valuable lands. Landowners with fields enrolled in the CRP often are the first to observe improvement in the landscape, greater numbers and kinds of wildlife, cleaner water and air, less erosion, and they have the satisfaction of seeing fragile lands serve better purposes. There is persistent concern that improvement seen in wildlife habitat and other environmental profits delivered by the CRP are ephemeral and last only as long as funding supports the existence of the program and its vegetative cover is properly managed. An involved American population will continue to expect governmental policies to enhance long-term protection of natural resources and public health. Recent investigations furnish evidence that the collective economic value of environmental benefits delivered by the CRP likely exceed program costs. The mounting significance placed on environmentally-responsible land management is based in part on public recognition that social, aesthetic, and recreational values enhance the traditional uses of agricultural land.

Scientific Investigations Report↗
USGS2016

Streamflow and estimated loads of phosphorus and dissolved and suspended solids from selected tributaries to Lake Ontario, New York, water years 2012–14

This report presents results of the evaluation and interpretation of hydrologic and water-quality data collected as part of a cooperative program between the U.S. Geological Survey and the U.S. Environmental Protection Agency. Streamflow, phosphorus, and solids dissolved and suspended in stream water were the focus of monitoring by the U.S. Geological Survey at 10 sites on 9 selected tributaries to Lake Ontario during the period from October 2011 through September 2014. Streamflow yields (flow per unit area) were the highest from the Salmon River Basin due to sustained yields from the Tug Hill aquifer. The Eighteenmile Creek streamflow yields also were high as a result of sustained base flow contributions from a dam just upstream of the U.S. Geological Survey monitoring station at Burt. The lowest streamflow yields were measured in the Honeoye Creek Basin, which reflects a decrease in flow because of withdrawals from Canadice and Hemlock Lakes for the water supply of the City of Rochester. The Eighteenmile Creek and Oak Orchard Creek Basins had relatively high yields due in part to groundwater contributions from the Niagara Escarpment and seasonal releases from the New York State Barge Canal. Annual constituent yields (load per unit area) of suspended solids, phosphorus, orthophosphate, and dissolved solids were computed to assess the relative contributions and allow direct comparison of loads among the monitored basins. High yields of total suspended solids were attributed to agricultural land use in highly erodible soils at all sites. The Genesee River, Irondequoit Creek, and Honeoye Creek had the highest concentrations and largest mean yields of total suspended solids (165 short tons per square mile [t/mi 2 ], 184 t/mi 2 , and 89.7 t/mi 2 , respectively) of the study sites. Samples from Eighteenmile Creek, Oak Orchard Creek at Kenyonville, and Irondequoit Creek had the highest concentrations and largest mean yields of phosphorus (0.27 t/mi 2 , 0.26 t/mi 2 , and 0.20 t/mi 2 , respectively) and orthophosphate (0.17 t/mi 2 , 0.13 t/mi 2 , and 0.04 t/mi 2 , respectively) of the study sites. These results were attributed to a combination of sources, including discharges from wastewater treatment plants, diversions from the New York State Barge Canal, and manure and fertilizers applied to agricultural land. Yields of phosphorus also were high in the Genesee River Basin (0.17 t/mi 2 ) and were presumably associated with nutrient and sediment transport from agricultural land and from streambank erosion. The Salmon and Black Rivers, which drain a substantial amount of forested land and are influenced by large groundwater discharges, had the lowest concentrations and yields of phosphorus and orthophosphate of the study sites. Mean annual yields of dissolved solids were the highest in Irondequoit Creek due to a high percentage of urbanized area in the basin and in Oak Orchard Creek at Kenyonville and in Eighteenmile Creek due to groundwater contributions from the Niagara Escarpment. High yields of dissolved solids of 840 t/mi 2 , 829 t/mi 2 , and 715 t/mi 2 , respectively, from these basins can be attributed to seasonal chloride yields associated with use of road deicing salts. The Niagara Escarpment can produce large amounts of dissolved solids from the dissolution of minerals (a continual process reflected in base flow samples). Groundwater inflows in the Salmon River have very low concentrations of dissolved solids due to minimal bedrock interaction along the Tug Hill Plateau and discharge from the Tug Hill sand and gravel aquifer, which has minimal mineralization.

New York↗
USGS2017

Multiple-source tracking: Investigating sources of pathogens, nutrients, and sediment in the Upper Little River Basin, Kentucky, water years 2013–14

The South Fork Little River (SFLR) and the North Fork Little River (NFLR) are two major headwater tributaries that flow into the Little River just south of Hopkinsville, Kentucky. Both tributaries are included in those water bodies in Kentucky and across the Nation that have been reported with declining water quality. Each tributary has been listed by the Kentucky Energy and Environment Cabinet—Kentucky Division of Water in the 303(d) List of Waters for Kentucky Report to Congress as impaired by nutrients, pathogens, and sediment for contact recreation from point and nonpoint sources since 2002. In 2009, the Kentucky Energy and Environment Cabinet—Kentucky Division of Water developed a pathogen total maximum daily load (TMDL) for the Little River Basin including the SFLR and NFLR Basins. Future nutrient and suspended-sediment TMDLs are planned once nutrient criteria and suspended-sediment protocols have been developed for Kentucky. In this study, different approaches were used to identify potential sources of fecal-indicator bacteria (FIB), nitrate, and suspended sediment; to inform the TMDL process; and to aid in the implementation of effective watershed-management activities. The main focus of source identification was in the SFLR Basin. To begin understanding the potential sources of fecal contamination, samples were collected at 19 sites for densities of FIB ( E. coli ) in water and fluvial sediment and at 11 sites for Bacteroidales genetic markers (General AllBac, human HF183, ruminant BoBac, canid BacCan, and waterfowl GFD) during the recreational season (May through October) in 2013 and 2014. Results indicated 34 percent of all E. coli water samples ( n =227 samples) did not meet the U.S. Environmental Protection Agency 2012 recommended national criteria for primary recreational waters. No criterion currently exists for E. coli in fluvial sediment. By use of the Spearman’s rank correlation test, densities of FIB in fluvial sediments were observed to have a statistically significant positive correlation with drainage area. As drainage area increased, so did the densities of FIB in the fluvial sediments. There was no statistically significant correlation between drainage area and FIB in water. The human-associated marker (HF183) was found above the detection limit in 26 percent of the samples ( n =120 samples); a higher proportion of positive samples was in the NFLR Basin. The ruminant-associated marker (BoBac) was above the detection limit in 65 percent of samples; a higher proportion of positive samples was in the headwaters of the SFLR Basin. Nutrient yields differed between the SFLR and NFLR Basins. Comparatively, the SFLR Basin produced the largest estimated mean yields of total nitrogen (16,000 pounds per year per square mile (lb/yr/mi 2 ) and nitrite plus nitrate nitrogen (12,500 lb/yr/mi 2 ), and the NFLR Basin produced the largest estimated mean yields of ammonia plus organic nitrogen (4,700 lb/yr/mi 2 ), total phosphorus (1,100 lb/yr/mi 2 ), and orthophosphorus (590 lb/yr/mi 2 ). Nitrate sources in surface water were assessed in both basins using dual-nitrate isotope (nitrogen and oxygen) ratios. Data from the different land uses in the SFLR Basin showed differences in nitrate concentrations and overlapping, but moderately distinct, isotopic signatures. Predominantly forested sites consistently had low nitrate concentrations (median = 0.233 milligrams per liter) with minimal variability, and agricultural sites had the highest nitrate concentrations (median = 7.55 milligrams per liter) with the greatest variability. The median nitrate concentration for sites with mixed land use was 2.66 milligrams per liter. Dual-isotope data for forested sites plotted within ranges characteristic of soil-derived nitrate with possible but minimal influence from recycled atmospheric nitrate. Ranges of dual-isotope data for sites with agricultural and mixed land uses were characteristic of possible mixtures of chemical fertilizer, soil-derived nitrate, and manure and septic wastes. In the NFLR Basin, a positive linear relation was observed between nitrate concentrations and nitrogen isotope ratios (δ 15 N NO3 ) (R 2 =0.56; p -value <0.001) that potentially suggests the NFLR Basin has a higher proportion of δ 15 N NO3 -enriched sources, such as manure and sewage. However, mixing of other nitrate-derived sources cannot be excluded, because many values of δ 15 N NO3 and concentrations of nitrate showed minimal variation and plotted within dual-nitrate isotope ranges characteristic of fertilizer and soil-derived nitrate sources. A sediment-fingerprinting approach was used to quantify the relative contribution of four upland sources in the SFLR Basin (agricultural, pasture, riparian/forest, and streambank) to understand how land management affects suspended-sediment concentration. Carbon isotope ratios (δ 13 C), together with calcium and carbon concentrations, were the best indicators of sediment source; the uncertainty was less than 11 percent. Fine-sediment samples collected at the SFLR Basin outlet indicated streambanks as the largest source of the fine sediment to the stream followed by cropland and riparian/forest-source areas, respectively; pasture was a minor contributing source. Streambanks and cropland were essentially equal contributors of fine sediment at the NFLR Basin outlet.

Kentucky↗
USGS2020

Hydrogeologic characterization, groundwater chemistry, and vulnerability assessment, Ute Mountain Ute Reservation, Colorado and Utah

The U.S. Geological Survey, in cooperation with the Ute Mountain Ute Tribe (UMUT), initiated a study in 2016 to increase understanding of the hydrogeology and chemistry of groundwater within select areas of the Ute Mountain Ute Reservation (UMUR) in Colorado and Utah, identify vulnerabilities to the system and other natural resources, and outline information needs to aid in the understanding and protection of groundwater resources. The results presented for this study can be used to support the UMUT’s goal of protecting their vital groundwater resources on the UMUR. Hydrogeologic conditions were characterized for the surficial aquifer contained in Quaternary-age unconsolidated surficial deposits and the Dakota aquifer contained in the Cretaceous-age Dakota Sandstone. In the surficial aquifer, median depth to water ranges from about 5.4 to 17.2 feet below land surface in the Farm and Ranch Enterprise area and 11 to 34 feet below land surface in the Towaoc area, and the water table slopes generally southwest or south. A map of depth to the top of the Dakota Sandstone was constructed from existing well data. Depths range from zero in outcrop areas to more than 3,000 feet below land surface on mesas in the southeastern part of the UMUR. Groundwater-chemistry data were collected by the UMUT from 13 springs and 31 wells from 1996 through 2017. Specific conductance was much lower for samples from springs than from wells; median values were 512 and 6,024 microsiemens per centimeter at 25 degrees Celsius, respectively. Spring samples were well oxygenated. A few well samples were anoxic (dissolved oxygen concentrations less than 0.5 milligrams per liter [mg/L]), indicating reducing conditions in the aquifer. About 75 percent of spring samples had fresh water (total dissolved solids concentrations less than 1,000 mg/L), and about 85 percent of well samples had brackish or highly saline water (total dissolved solids concentrations greater than 1,000 mg/L). Water type for springs on the Ute Mountains was calcium bicarbonate. Lower-altitude springs had a calcium-sulfate water type. Most well samples had sodium as the dominant cation, and sulfate, bicarbonate, and chloride as the dominant anions. Fluoride concentrations in about 45 percent of well samples were greater than an agricultural-use standard of 2 mg/L. Nitrate plus nitrite concentrations in most spring and well samples were less than about 1.6 mg/L per liter. Concentrations in samples from wells in the irrigated agricultural area were elevated; the maximum concentration was 78.5 mg/L. About one-half of the trace-element samples had concentrations that were less than laboratory reporting limits. Only aluminum, arsenic, and selenium in spring samples, and boron and selenium in well samples, were detected at concentrations greater than surface-water standards or water-quality standards for agricultural use of groundwater. Only three organic compounds, the pesticides alachlor and atrazine and the volatile organic compound di(2-ethylhexyl) phthalate, were detected in well samples. The Escherichia coli bacteria was detected in 47 and 23 percent of samples from wells and springs, respectively. The E. coli detections included samples from three culturally significant springs, which did not meet the UMUT cultural-use standard of total absence of E. coli. Tritium and carbon-14 were the primary environmental tracers used for interpreting groundwater ages for Lopez 2 Spring and five wells (AP–1, 5000 Block, Cottonwood Spring, Goodknight, and SE Toe). Water from the AP–1 well contained a mixture of pre- and post-1950s recharge. Tritium and carbon-14 recharge ages for Lopez 2 Spring (post-1950s in age), Goodknight and SE Toe wells (pre-1950s in age), and Cottonwood Spring well (primarily pre-1950s in age) are supported by helium-4 data. The helium-4 data for the 5000 Block well are inconsistent with the tritium and carbon-14 age of pre-1950s recharge because of interference caused by high methane concentrations in the water. Springs and surficial deposits are more vulnerable to contamination from anthropogenic chemicals than deeper bedrock wells. Bedrock aquifers are vulnerable in areas where the geologic formations containing the aquifers are exposed at the land surface. Groundwater in deep bedrock aquifers is likely thousands of years old and is not currently affected by present-day land uses. Both shallow and deep groundwater are vulnerable to naturally occurring salts and minerals, such as of total dissolved solids, major ions, nitrate, and trace elements. Effects of a changing climate on water resources and other ecological characteristics of the UMUR could include changes in evapotranspiration, a decrease in snowpack, decreased aquifer recharge and flow of springs, a decrease in soil moisture, and increased occurrence of wildfires and forest mortality. Of particular interest for the UMUT are possible effects of a changing climate on medicinal and culturally important plants and springs Several information needs were identified during this study that would aid in the understanding and protection of groundwater resources on the UMUR. These include well-completion information for bedrock wells, the collection of environmental tracer data at additional wells, the addition of methane and hydrocarbon analysis to well sampling plans, and the resampling of springs and wells that were last sampled in 2002 or earlier.

Colorado↗
USGS2020

Spatially referenced models of streamflow and nitrogen, phosphorus, and suspended-sediment loads in the southeastern United States

Spatially Referenced Regression On Watershed attributes (SPARROW) models were applied to describe and estimate mean-annual streamflow and transport of total nitrogen (TN), total phosphorus (TP), and suspended sediment (SS) in streams and delivered to coastal waters of the southeastern United States on the basis of inputs and management practices centered near 2012, the base year of the model. Previously published TN and TP models for 2002 served as a starting point and reference for comparison. The datasets developed for the 2012 models not only represent updates of previous conditions but also incorporate new approaches for characterizing sources and transport processes that were not available for previous models. Variability in streamflow across the southeastern United States was explained as a function of precipitation adjusted for evapotranspiration, spring discharge, and municipal and domestic wastewater discharges to streams. Results from the streamflow model were used as input to the water-quality SPARROW models, and areas with large streamflow prediction errors—urban areas and karst areas—were used to provide guidance on where additional data are needed to improve routing of flow. Variability in TN transport in Southeast streams was explained by the following five sources in order of decreasing mass contribution to streams: atmospheric deposition, agricultural fertilizer, municipal wastewater, manure from livestock, and urban land. Variable rates of TN delivery from source to stream were attributed to variation among catchments in climate, soil texture, and vegetative cover, including the extent of cover crops in the watershed. Variability in TP transport in Southeast streams was explained by the following six sources in order of decreasing mass contribution to streams: parent-rock minerals, urban land, manure from livestock, municipal wastewater, agricultural fertilizer, and phosphate mining. Varying rates of TP delivery were attributed to variation in climate, soil erodibility, depth to water table, and the extent of conservation tillage practices in the watershed. Variability in SS transport in Southeast streams was explained by variable sediment export rates for different combinations of land cover and geologic setting (for upland sources of sediment) and by gains in stream power caused by longitudinal changes in channel hydraulics (for channel sources of sediment). Sediment yields for the transitional land cover (shrub, scrub, herbaceous, and barren) varied widely depending on geologic setting and on agricultural land cover. Varying rates of SS delivery, like those for TP, were attributed to variation in climate, soil erodibility, and the extent of conservation tillage practices in the watershed, as well as to areal extent of canopy land cover in the 100-meter buffer along the channel. Relatively large uncertainty, compared to the other three models, for almost all the SS source coefficients indicates the need for caution when interpreting the results from the sediment model. TN, TP, and SS inputs to streams from sources were balanced in the models with losses from physical processes in streams and reservoirs and with water withdrawals. The losses in streams and reservoirs along with withdrawals removed 35, 44, and 65 percent of the TN, TP, and SS load, respectively, that entered streams before reaching coastal waters.

Scientific Investigations Report↗
USGS2020

Hydrogeology, numerical simulation of groundwater flow, and effects of future water use and drought for reach 1 of the Washita River alluvial aquifer, Roger Mills and Custer Counties, western Oklahoma, 1980–2015

The Washita River alluvial aquifer is a valley-fill and terrace alluvial aquifer along the valley of the Washita River in western Oklahoma that provides a productive source of groundwater for agricultural irrigation and water supply. The Oklahoma Water Resources Board (OWRB) has designated the westernmost section of the aquifer in Roger Mills and Custer Counties, Okla., as reach 1 of the Washita River alluvial aquifer; reach 1 is the focus of this report. The OWRB issued an order on November 13, 1990, that established the maximum annual yield (MAY; 120,320 acre-feet per year [acre-ft/yr]) and equal-proportionate-share (EPS) pumping rate (2.0 acre-feet per acre per year [(acre-ft/acre)/yr]) for reach 1 of the Washita River alluvial aquifer. The MAY and EPS were based on hydrologic investigations that evaluated the effects of potential groundwater withdrawals on groundwater availability in the Washita River alluvial aquifer. Every 20 years, the OWRB is statutorily required to update the hydrologic investigation on which the MAY and EPS were based. Because 30 years have elapsed since the last order was issued, the U.S. Geological Survey, in cooperation with the OWRB, conducted a new hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater flow and availability in the Washita River alluvial aquifer. The Washita River is the primary source of inflow to Foss Reservoir, a Bureau of Reclamation reservoir constructed in 1961 for flood control, water supply, and recreation. Foss Reservoir provides water for Bessie, Clinton, New Cordell, and Hobart, Okla. Nearly 98 percent of the total groundwater use from the Washita River alluvial aquifer during 1967 to 2015 was for irrigation; other uses of groundwater in the study area include public supply, mining, and agriculture. A hydrogeologic framework was developed for the Washita River alluvial aquifer and included the physical characteristics of the aquifer, the geologic setting, the hydraulic properties of hydrogeologic units, the potentiometric surface (water table), and groundwater-flow directions at a scale that captures the regional controls on groundwater flow. The Washita River alluvial aquifer consists of alluvium and terrace deposits that were transported primarily by water and range from clay to gravel in size. The terrace includes windblown deposits of silt size and, in some cases, contains gravel laid down at several levels along former courses of present-day rivers. A conceptual flow model is a simplified description of the aquifer system that includes hydrologic boundaries, major inflow and outflow sources of the groundwater-flow system, and a conceptual water budget with the estimated mean flows between those hydrologic boundaries. During the study period 1980–2015, mean annual groundwater withdrawals, predominantly used for agricultural irrigation, totaled 5,502 acre-ft/yr, or 14 percent of aquifer outflows. When applied across the 132-square-mile aquifer area used for modeling purposes (84,366 acres), mean annual recharge of 3.15 inches per year corresponds to a mean annual recharge volume of 22,169 acre-ft/yr, or 56 percent of aquifer inflows. The annual saturated-zone evapotranspiration outflow was 11,828 acre-ft/yr for the Washita River alluvial aquifer, or about 30 percent of aquifer outflows. For the Washita River alluvial aquifer, lateral flow was 17,157 acre-ft/yr, or 44 percent of the aquifer inflows. The conceptual flow model and hydrogeologic framework were used to conceptualize, design, and build the numerical groundwater-flow model. A numerical groundwater-flow model of the Washita River alluvial aquifer was constructed by using MODFLOW-2005. The Washita River alluvial aquifer groundwater-model grid was spatially discretized into 350-foot (ft) cells and two layers. Layer 1 represented the undifferentiated alluvium and terrace deposits of Quaternary age, and layer 2 represented the bedrock of Permian age, which was given a uniform nominal thickness of 100 ft. The groundwater-simulation period was temporally discretized into 433 monthly transient stress periods, representing January 1980 to December 2015. An initial 365-day steady-state stress period was configured to represent mean annual inflows and outflows from the Washita River alluvial aquifer for the study period. The groundwater-flow model was calibrated manually and by automated adjustment of model inputs by using PEST++. Calibration targets for the Washita River alluvial aquifer model included groundwater-level observations and reservoir-stage observations, as well as base-flow and stream-seepage estimates. Three groundwater-availability scenarios were used in the calibrated groundwater model to (1) estimate the EPS pumping rate that retains the saturated thickness that meets the minimum 20-year life of the aquifer, (2) quantify the effects of projected pumping rates on groundwater storage over a 50-year period, and (3) evaluate how projected pumping rates extended 50 years into the future and sustained hypothetical drought conditions over a 10-year period affect base flow and groundwater in storage. The results of the groundwater-availability scenarios could be used by the OWRB to reevaluate the established MAY of groundwater from the Washita River alluvial aquifer. EPS scenarios for the Washita River alluvial aquifer were run for periods of 20, 40, and 50 years. The 20-, 40-, and 50-year EPS pumping rates under normal recharge conditions were 1.7, 1.6, and 1.6 (acre-ft/acre)/yr, respectively. Given the aquifer area used for modeling purposes (84,366 acres), these rates correspond to annual yields of 142,579, 134,986, and 134,986 acre-ft/yr, respectively. Groundwater storage at the end of the 20-year EPS scenario was about 281,000 acre-feet (acre-ft), or about 306,000 acre-ft (52 percent) less than the starting storage. Considering the land-surface area of the Washita River alluvial aquifer and using a specific yield of 0.12, this decrease in storage was equivalent to a mean groundwater-level decline of about 30 ft. The Washita River downstream from Foss Reservoir and most of the streams in the study area were dry at the end of the 20-year EPS scenario. Foss Reservoir stage was below the dead-pool stage of 1,597 ft after about 7 years of pumping in the 20-year EPS scenario. Four projected 50-year groundwater-use scenarios were used to simulate the effects of selected well withdrawal rates on groundwater storage in the Washita River alluvial aquifer. These four scenarios used (1) no groundwater use, (2) groundwater use at the 2015 pumping rate, (3) mean groundwater use for the simulation period, and (4) increasing groundwater use. Groundwater storage after 50 years with no groundwater use was 545,249 acre-ft, or 693 acre-ft (0.1 percent) greater than the initial groundwater storage; this groundwater storage increase is equivalent to a mean groundwater-level increase of 0.1 ft. Groundwater storage at the end of the 50-year period with 2015 pumping rates was 543,831 acre-ft, or 723 acre-ft (0.1 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage after 50 years with the mean pumping rate for the study period was 543,202 acre-ft, or 1,349 acre-ft (0.2 percent) less than the initial groundwater storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage at the end of the 50-year period with an increasing demand groundwater-pumping rate, which was 38 percent greater than the 2015 groundwater-pumping rate, was 542,584 acre-ft, or 1,967 acre-ft (0.4 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.2 ft. A hypothetical 10-year-drought scenario was used to simulate the effects of a prolonged period of reduced recharge on groundwater storage in the Washita River alluvial aquifer and Foss Reservoir stage and storage. To simulate the hypothetical drought, recharge in the calibrated model was reduced by 50 percent during the simulated drought period (1983–1992). Groundwater storage at the end of the drought period in December 1992 was 562,000 acre-ft, or 36,000 acre-ft (6 percent) less than the groundwater storage of the calibrated groundwater model (598,000 acre-ft). At the end of the hypothetical drought, the largest changes in saturated thickness (as great as 43.5 ft) were in the area upgradient from Foss Reservoir, particularly in the terrace at the model boundary. Substantial decreases in the Foss Reservoir stage began during the fall of 1985 in conjunction with base-flow decreases of up to 100 percent at U.S. Geological Survey streamgage 07324200 Washita River near Hammon, Okla. These lake-stage declines outpaced groundwater-level declines in the surrounding aquifer. The minimum Foss Reservoir storage simulated during the drought period was 77,954 acre-ft, which was a decrease of 46 percent from the nondrought storage.

Oklahoma↗
USGS2022

Areas contributing recharge to selected production wells in unconfined and confined glacial valley-fill aquifers in Chenango River Basin, New York

In the Chenango River Basin of central New York, unconfined and confined glacial valley-fill aquifers are an important source of drinking-water supplies. The risk of contaminating water withdrawn by wells that tap these aquifers might be reduced if the areas contributing recharge to the wells are delineated and these areas protected from land uses that might affect the water quality. The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation and the New York State Department of Health, began an investigation in 2019 to improve understanding of groundwater flow and delineate areas contributing recharge to 16 production wells clustered in three study areas in the basin as part of an effort to protect the source of water to these wells. Areas contributing recharge were delineated on the basis of numerical steady-state groundwater-flow models representing long-term average hydrologic conditions. In the Cortland study area, four water suppliers operate 10 production wells that withdraw a total average rate of 2,480 gallons per minute from an unconfined aquifer consisting of well-sorted sand and gravel deposits. Simulated areas contributing recharge to these wells at their average pumping rates covered a total area of 6.93 square miles. Simulated areas contributing recharge extend upgradient from the wells to upland till deposits and to groundwater divides. Some simulated areas contributing recharge include isolated areas remote from the wells. Short simulated groundwater traveltimes from recharging locations to discharging wells indicated that the wells are vulnerable to contamination from land-surface activities; 50 percent of the traveltimes were 10 years or less. Land cover in some of the areas contributing recharge included a substantial amount of urban and agriculture land use. The groundwater-flow model of the Cortland study area was calibrated to available hydrologic data by inverse modeling using nonlinear regression. The parameter variance-covariance matrix from model calibration was used to create parameter sets that reflect the uncertainty of the parameter estimates and the correlation among parameters to evaluate the uncertainty associated with the single, predicted contributing areas to the wells. This analysis led to contributing areas expressed as a probability distribution. Because of the effects of parameter uncertainty, the size of the probabilistic contributing areas was larger than the size of the single, predicted contributing area for the wells. Thus, some areas not in the single, predicted contributing area might actually be in the contributing area, including additional areas of urban and agriculture land use that have the potential to contaminate groundwater. Additional areas that might be in the contributing area included recharge originating near the pumping wells that have relatively short groundwater-flow paths and traveltimes. In each of the Greene and Cincinnatus study areas, one water supplier operates three wells that are screened near the top of the bedrock surface in a confined aquifer consisting of poorly to well-sorted sand and gravel deposits. This confined aquifer is overlain by a lacustrine confining unit of very fine sand, silt, and clay, which in turn is overlain by a thin unconfined aquifer of sand and gravel. The groundwater-flow models for these two areas were manually calibrated because of the limited hydrologic data. Simulated areas contributing recharge to the Greene study area wells covered a total area of 0.35 square mile for the average pumping rate of 170 gallons per minute. The contributing areas extended southeastward of the wells to the groundwater divide in the till uplands. The contributing areas also included remote, isolated areas on the opposite side of the Chenango River from the wells primarily in the till uplands. For the Cincinnatus study area wells, which have a low average pumping rate (34 gallons per minute), the simulated contributing areas totaled 0.06 square mile and were on the same side of the river as the wells, but they are isolated areas remote from the wells primarily in the till-covered bedrock uplands. Land cover in these contributing areas for both study areas is primarily agriculture and forested, with the contributing areas to the Greene study area wells also including some urban land uses. Because the Greene and Cincinnatus study area wells are screened relatively deep and some flow paths to the wells partly travel through the confining unit, which impedes the connection with surface sources of recharge, overall groundwater traveltimes are greater than for wells in the Cortland study area. Fifty percent of Cortland study area wells, but only 9 and 44 percent of Greene and Cincinnatus study area wells, respectively, have groundwater traveltimes of 10 years or less.

New York↗
USGS2022

Status and understanding of groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit, 2017—California GAMA Priority Basin Project

Groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit (SacMetro-DSA) was studied from August to November 2017 as part of the second phase of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in parts of Amador, Placer, Sacramento, and Sutter Counties, and the extent of the study unit was defined by the location of three California Department of Water Resources groundwater subbasins: the North American, the South American, and the Cosumnes. The SacMetro-DSA focused on groundwater resources used for domestic drinking-water supply, which generally correspond to shallower parts of aquifer systems than those of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included two components: (1) a status assessment, which characterized the status of the quality of the groundwater resources used for domestic supply and (2) an understanding assessment, which evaluated the natural and human factors potentially affecting water quality in those resources. The first component of this study—the status assessment—was based on water-quality data collected from 49 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2017. The samples were analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that had concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. The second component of this study—the understanding assessment—identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, groundwater age, and geochemical and hydrologic conditions of the domestic-supply aquifer and related these data to constituents identified in the status assessment for further evaluation. In the SacMetro-DSA study unit, arsenic was the only inorganic constituent detected above health-based benchmarks and was detected in 10 percent of the domestic-supply aquifer system. Inorganic constituents were detected above the non-health-based California State Water Resources Control Board—Division of Drinking Water secondary maximum contaminant levels (SMCL-CA) in 16 percent of the system. The inorganic constituents detected above the SMCL-CA were chloride, iron, manganese, and total dissolved solids (TDS). Organic constituents (volatile organic compounds and pesticides) with health-based benchmarks were not detected above health-based benchmarks; however, chloroform was detected at concentrations higher than 10 percent of the health-based benchmark (80 micrograms per liter) in 2 percent of the domestic-supply aquifer system. Of the 310 organic constituents analyzed, 16 constituents were detected; however, only bentazon and chloroform had detection frequencies greater than 10 percent. Inorganic constituents with health-based benchmarks that were evaluated in the understanding assessment included arsenic and hexavalent chromium. Arsenic and hexavalent chromium are natural constituents of aquifer sediments in the study unit and did not appear to be influenced by anthropogenic processes; rather, the presence of arsenic and hexavalent chromium appeared to be related to geochemical conditions controlled by oxidation–reduction reactions in the aquifer system. Naturally occurring inorganic constituents with SMCL-CAs evaluated in the understanding assessment were the trace elements iron and manganese, the major ion chloride, and TDS. Like arsenic and hexavalent chromium, the presence of iron and manganese was most strongly related to geochemical conditions in the aquifer system, specifically reducing conditions, which were most common near the western edge of the study unit close to the Sacramento River. Concentrations of chloride and TDS are indicators of salinity and were correlated with variables related to well location and included redox, agricultural land use, and elevation. Chloride and TDS were positively correlated to reducing conditions, and agricultural land use was negatively correlated to elevation and well depth. Observed correlations among variables were likely driven by the characteristics of the western part of the study unit, such as its higher proportion of agricultural land use and its relatively low elevation. A large portion of the western edge of the study unit is located in the center of the Sacramento Valley, defined by the location of the Sacramento River. The special-interest constituent perchlorate, also included in the understanding assessment, has natural and anthropogenic sources. Perchlorate was detected frequently and at moderate relative concentrations. In some areas of the study unit, concentrations of perchlorate were higher than what might be expected in nature; therefore, anthropogenic introduction of perchlorate or anthropogenically induced migration of native perchlorate could be occurring.

California↗
USGS2022

Update and recalibration of the Rio Grande Transboundary Integrated Hydrologic Model, New Mexico and Texas, United States, and northern Chihuahua, Mexico

The Rio Grande Transboundary Integrated Hydrologic Model (RGTIHM) was developed through an interagency effort between the U.S. Geological Survey and the Bureau of Reclamation to provide a tool for analyzing the hydrologic system response to the historical evolution of water use and potential changes in water supplies and demands in the Hatch Valley (also known as Rincon Valley in the study area) and Mesilla Basin, New Mexico and Texas, United States, and northern Chihuahua, Mexico. Reclamation operates the Rio Grande Project (RGP) to store and deliver surface water for irrigation and municipal use within the study area and in the El Paso Valley south of the El Paso Narrows. Biases in the RGTIHM’s simulation of streamflow and aquifer storage depletion and the availability of new estimates of historical agricultural consumptive use in the study area initiated an update and recalibration of the RGTIHM. In addition to the new estimates of historical agricultural consumptive use, updates were made to more accurately represent the natural system and included adjustments to the initial groundwater levels; streamflow rating tables; Rio Grande, canal, and drain streambed elevations; tributary streambed elevations; surface-water inflows and diversions; RGP surface-water deliveries and canal waste; on-farm efficiency; the routing of surface-water runoff within the MODFLOW Farm Process; and general head boundaries used to simulate interbasin groundwater flow. Model settings, including the assignment of hydraulic conductivity and storage properties to model layers and the MODFLOW solver package, were adjusted to improve numerical stability, and the model was recalibrated to better simulate the natural system. The updated and recalibrated RGTIHM demonstrates a robust ability to simulate the spatially and temporally variable measurements, estimates, or reports of hydraulic head, surface-water flows, agricultural pumping, RGP surface-water deliveries and canal waste, and decadal aquifer storage changes, with improvements over the previous version of the model.

Chihuahua, New Mexico, Texas↗