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USGS2003

Comparison of two methods for delineating land use near monitoring wells used for assessing quality of shallow ground water

Two methods were compared for delineating land use near shallow monitoring wells. These wells were used to assess the effects of agricultural cropland on the quality of recently recharged ground water in two sand and gravel aquifers located near land surface. The two methods for delineating land use near wells were (1) the sector method, which used potentiometric-surface maps to estimate average flow direction and a ground-water-flow model to estimate maximum length of contributing area to the monitoring well within an upgradient sector; and (2) the circle method, which used a 500- meter radius circle around the well based on a national empirical analysis. Land uses were compiled for 29 wells in each of two surficial aquifers in the Red River of the North Basin within the area defined by each method. Land use near each well was interpreted from orthorectified photographs and site inspection for both delineation methods. Land use near individual wells characterized by each method varied greatly, which can affect the results of statistical correlations between land use and water quality. Land use determined by the circle method related more closely to the land use for each entire study area. Land use determined by the sector method (within 200 meters from the wells) compared more favorably to ground-water quality based on nitrate concentrations. The maximum length of contributing areas to wells estimated in this study may be of value for other studies of unconsolidated sand and gravel aquifers with similar hydrogeological characteristics of permeability, water-table slopes, recharge, and depth to water. The additional effort required for estimating the model delineation of land use and land cover for the sector method must be weighed against the improved confidence in statistical correlation between land use and the quality of shallow ground water. Improved scientific confidence and understanding of relations between land use and quality of ground water may encourage more effective implementation of land and water management for protecting water quality

Minnesota, North Dakota↗
USGS2003

Influence of local riparian cover and watershed runoff potential on invertebrate communities in agricultural streams in the Minnesota River Basin

During the summer of 1997, 23 streams in the highly agricultural Minnesota River Basin were studied to determine the influence of local riparian cover conditions (wooded or open) and watershed runoff potential (high or low) on invertebrate community composition. A two by two-factorial analysis of variance was used to determine differences in invertebrate community measures among the design classes While it is difficult to determine the relative influence of watershed runoff potential and local riparian cover, invertebrate communities may be more strongly influenced by local wooded riparian cover than by watershed runoff potential. Invertebrate community measures indicate greater degradation at the open riparian cover, high runoff potential sites and less degradation at the wooded riparian cover, low runoff potential sites. In addition, differences between streams with wooded riparian cover and sites with open riparian cover were greater in watersheds with high runoff potential. The variance explained by riparian cover and runoff potential is relatively independent of other land-use effects. Wooded riparian cover influences invertebrate community composition by its relation to the other physical environmental variables. This study indicates that wooded riparian cover may be effective in maintaining stream biotic integrity in watersheds dominated by agricultural land use.

Iowa, Minnesota, South Dakota↗
USGS2003

Geologic Setting, Geohydrology, and Ground-Water Quality near the Helendale Fault in the Mojave River Basin, San Bernardino County, California

The proximity of the Mojave River ground-water basin to the highly urbanized Los Angeles region has resulted in rapid population growth and, consequently, an increase in the demand for water. The Mojave River, the primary source of surface water for the region, normally is dry--except for periods of flow after intense storms; therefore, the region relies almost entirely on ground water to meet its agricultural and municipal needs. The area where the Helendale Fault intersects the Mojave River is of particular hydrogeologic interest because of its importance as a boundary between two water-management subareas of the Mojave Water Agency. The fault is the boundary between the upper Mojave River Basin (Oeste, Alto, and Este subareas) and the lower Mojave River Basin (Centro and Baja subareas); specifically, the fault is the boundary between the Alto and the Centro subareas. To obtain the information necessary to help better understand the hydrogeology of the area near the fault, multiple-well monitoring sites were installed, the surface geology was mapped in detail, and water-level and water-quality data were collected from wells in the study area. Detailed surficial geologic maps and water-level measurements indicate that the Helendale Fault impedes the flow of ground water in the deeper regional aquifer, but not in the overlying floodplain aquifer. Other faults mapped in the area impede the flow of ground water in both aquifers. Evidence of flowing water in the Mojave River upgradient of the Helendale Fault exists in the historical record, suggesting an upward gradient of ground-water flow. However, water-level data from this study indicate that pumping upstream of the Helendale Fault has reversed the vertical gradient of ground-water flow since predevelopment conditions, and the potential now exists for water to flow downward from the floodplain aquifer to the regional aquifer. Sixty-seven ground-water samples were analyzed for major ions, nutrients, and stable isotopes of oxygen and hydrogen from 34 wells within the study area between May 1990 and November 1999. Dissolved-solids concentrations in water samples from 14 wells in the floodplain aquifer ranged from 339 to 2,330 milligrams per liter (mg/L) with a median concentration of 825 mg/L. Concentrations in water from 11 of these wells exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 mg/L. Dissolved-solids concentrations of water from nine wells sampled in the regional aquifer ranged from 479 to 946 mg/L with a median concentration of 666 mg/L. Concentrations in at least one sample of water from each of the wells in the regional aquifer exceeded the USEPA SMCL for dissolved solids. Arsenic concentrations in water from 14 wells in the floodplain aquifer ranged from less than the detection limit of 2 micrograms per liter (?g/L) to a maximum of 34 ?g/L with a median concentration of 6 ?g/L. Concentrations in water from six of the 14 wells exceeded the USEPA Maximum Contaminant Level (MCL) for arsenic of 10 ?g/L. Arsenic concentrations in water from nine wells in the regional aquifer ranged from less than the detection limit of 2 to 130 ?g/L with a median concentration of 11 ?g/L. Concentrations in water from five of these nine wells exceeded the USEPA MCL for arsenic. Dissolved-solids concentrations in water from seven wells completed in the igneous and metamorphic basement rocks that underlie the floodplain and regional aquifers ranged from 400 to 3,190 mg/L with a median concentration of 1,410 mg/L. Concentrations in water from all but one of the seven wells sampled exceeded the USEPA SMCL for dissolved solids. Concentrations in water from the basement rocks exceeded the USEPA SMCL for arsenic of 10 ?g/L in five of the seven wells. The high concentrations of arsenic, dissolved solids, and other constituents probably occur naturally. Stable isotopes of oxygen and hydrogen indicate that before pumping began in

Water-Resources Investigations Report↗
USGS2003

Low streamflow conditions in Washington, Oregon, and Idaho during water year 2001

Below-normal precipitation levels and abovenormal temperatures across most of the Columbia River Basin in the Pacific Northwest (Washington, Oregon, and Idaho) resulted in streamflows that, at times, approached long-term minimums. The period from October 1, 2000, through September 30, 2001 (water year 2001), was the second driest on record (1895–2001) for the three-State area. In addition, average temperatures during the April through September 2001 period were the twelfth highest since 1895. Conditions in the part of Canada included in the Columbia River Basin were similar. Streamflow levels at several locations approached those during water year 1977, when several minimum-flow records were set. The drought of 1977 commonly is considered the drought of record in the region. Low streamflows were most noticeable in rivers east of the Cascade Range, where most of the streamflow above base flow is a direct result of snowmelt runoff. Because of below-normal precipitation across the region, snowpack levels in the three States were only about 59 to 62 percent of the long-term (1961–90) average. Miscellaneous low-flow measurements were made at more than 700 locations across the three- State region and in some adjacent States. These measurements were made in late summer and early fall of 2001 during base-flow conditions. In general, these low-flow measurements were similar to those made at the same locations during water year 1977. Reservoir storage values for seven major river basins in the three-State region were all below the 30-year average at the end of water year 2001. Reservoir storages were at average levels at the end of water year 2000; thus, the below-average levels in water year 2001 can be related directly to low streamflows during water year 2001. Near the end of water year 2001, the Palmer Drought Severity Index ranked much of the region in the severe or extreme drought categories. Only the coastal area of Washington and Oregon and part of the mountain region in Idaho were in the near-normal category. The National Oceanic and Atmospheric Administration classified most of the area as exhibiting adverse agricultural, hydrological, and fire-danger effects from the drought. Lack of available water for recharge and increased pumpage needed to augment the reduced surface-water supply likely reduced ground-water levels throughout the region. Twenty-five wells across the region were selected for extended monitoring to help define the possible short- and longterm relation between low streamflows and ground-water levels.

Idaho;Oregon;Washington↗
USGS2003

Vulnerability of ground water to contamination, northern Bexar County, Texas

The Trinity aquifer, composed of Lower Cretaceous carbonate rocks, largely controls the ground-water hydrology in the study area of northern Bexar County, Texas. Discharge from the Trinity aquifer recharges the downgradient, hydraulically connected Edwards aquifer one of the most permeable and productive aquifers in the Nation and the sole source of water for more than a million people in south-central Texas. The unconfined, karstic outcrop of the Edwards aquifer makes it particularly vulnerable to contamination resulting from urbanization that is spreading rapidly northward across an "environmentally sensitive" recharge zone of the Edwards aquifer and its upgradient "catchment area," composed mostly of the less permeable Trinity aquifer. A better understanding of the Trinity aquifer is needed to evaluate water-management decisions affecting the quality of water in both the Trinity and Edwards aquifers. A study was made, therefore, in cooperation with the San Antonio Water System to assess northern Bexar County's vulnerability to ground-water contamination. The vulnerability of ground water to contamination in this area varies with the effects of five categories of natural features (hydrogeologic units, faults, caves and (or) sinkholes, slopes, and soils) that occur on the outcrop and in the shallow subcrop of the Glen Rose Limestone. Where faults affect the rates of recharge or discharge or the patterns of ground-water flow in the Glen Rose Limestone, they likewise affect the risk of water-quality degradation. Caves and sinkholes generally increase the vulnerability of ground water to contamination, especially where their occurrences are concentrated. The slope of land surface can affect the vulnerability of ground water by controlling where and how long a potential contaminant remains on the surface. Disregarding the exception of steep slopes which are assumed to have no soil cover the greater the slope, the less the risk of ground-water contamination. Because most soils in the study area are uniformly thin, they have only minimal effect on the vulnerability of ground water to contamination. The results of hydrogeologic mapping during the present study divide the outcrop of the Glen Rose Limestone into five mappable intervals, labeled (youngest to oldest) A through E. Of these intervals, only the middle (C) and the lowermost (E) generally provide appreciable permeability. The vulnerability assessment provided herein was determined by combining the presumed effects of selected natural features (with individual vulnerability ratings ranging from 0 through 35) using a grid-based, multilayer system of digital datasets and geographic information system analysis. The resulting vulnerability map comprises composite vulnerability ratings that range from 26 through 104. The relatively less vulnerable areas those containing no faults, sinkholes, or caves occupy about 92 percent of the study area. The most vulnerable areas are those containing both a fault and one or more caves. The distribution of the most vulnerable areas which trend from southwest to northeast, roughly parallel to the Balcones fault zone occur mainly where faults intersect caves.

Texas↗
USGS2003

Hydrology and water-quality characteristics of Muddy Creek and Wolford Mountain Reservoir near Kremmling, Colorado, 1990 through 2001

A water-quality monitoring program was begun in March 1985 on Muddy Creek in anticipation of the construction of a reservoir water-storage project. Wolford Mountain Reservoir was constructed by the Colorado River Water Conservation District during 1992-94. The reservoir began to be filled in 1995. Water quality generally was good in Muddy Creek and Wolford Mountain Reservoir throughout the period of record (collectively, 1990 through 2001), with low concentrations of nutrients (median total nitrogen less than 0.6 and median total phosphorus less than 0.05 milligrams per liter) and trace elements (median dissolved copper less than 2, median dissolved lead less than 1, and median dissolved zinc less than 20 micrograms per liter). Specific conductance ranged from 99 to 1,720 microsiemens per centimeter. Cation compositions at Muddy Creek sites were mixed calcium-magnesium-sodium. Anion compositions were primarily bicarbonate and sulfate. Suspended-sediment concentrations ranged from less than 50 milligrams per liter during low-flow periods to hundreds of milligrams per liter during snowmelt. Turbidity in prereservoir Muddy Creek generally was measured at less than 10 nephelometric turbidity units during low-flow periods and ranged to more than 360 nephelometric turbidity units during snowmelt. Compared to prereservoir conditions, turbidity in Muddy Creek downstream from the reservoir was substantially reduced because the reservoir acted as a sediment trap. During most years, peak flows were slightly reduced by the reservoir or similar to peaks upstream from the reservoir. The upper first to fifteenth percentiles of flows were decreased by operation of the reservoir compared to prereservoir flows. Generally, the fifteenth to one-hundredth percentiles of flow were increased by operation of the reservoir outflow compared to prereservoir flows. Nutrient transport in the inflow is proportional to the amount of inflow-water discharge in a given year. Some nitrogen was stored in the water column and gain/loss patterns for total nitrogen were somewhat related to reservoir storage. Nitrogen tended to move through the reservoir, whereas phosphorus was mostly trapped within the reservoir in bottom sediments. The reservoir gained phosphorus every year (1996- 2001) and, as a percentage, more phosphorus was retained than nitrogen in years when both were retained in the reservoir due to stronger phosphorus tendencies for adsorption, coprecipitation, and settling. Only small amounts of phosphorus were available in the water column at the outflow, and reservoir water-column storage did not influence phosphorus outflowloading patterns as much as settling further upstream in the reservoir. From 1990 to 2001, upstream from the reservoir, concentrations and values of dissolved solids, turbidity, some major ions, and dissolved iron increased (p-value less than 0.10), and acid-neutralizing capacity decreased. From 1990 to 2001, there were no significant (p-value less than 0.10) trends in nutrient concentrations upstream from the reservoir. From 1990 to 2001, downstream from the reservoir, trends in concentrations and values of dissolved solids, turbidity, major ions, total ammonia plus organic nitrogen, dissolved and total-recoverable iron, and total-recoverable manganese were downward. Upstream and downstream water-quality constituents for the prereservoir (1990 to 1995) period were compared. Concentrations and values of dissolved solids, major ions, turbidity, and manganese were greater (p-value less than 0.10) at the downstream site. From 1995 to 2001 (postconstruction), upstream and downstream water-quality constituents also were compared. Concentrations of specific conductance and major ions increased at the downstream site when compared to the upstream site (p-value less than 0.10), except for acid-neutralizing capacity and silica, which decreased. Turbidity, concentrations of total-recoverable and dissolved manganese, and

Water-Resources Investigations Report↗
USGS2003

Water-quality assessment of the eastern Iowa Basins: Selected pesticides and pesticide degradates in streams, 1996-98

Water samples were collected in streams of the Eastern Iowa Basins study unit from 1996 to 1998 as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. More than 350 samples were collected to document the occurrence, distribution, and transport of pesticides and pesticide degradates. The Eastern Iowa Basins study unit encompasses about 50,500 square kilometers (19,500 square miles) in eastern Iowa and southern Minnesota and is drained by four major rivers—the Wapsipinicon, Cedar, Iowa, and Skunk—which flow into the Mississippi River at the eastern border of Iowa. The most commonly detected pesticides— acetochlor, alachlor, atrazine, cyanazine, and metolachlor—were those most heavily used on crops during the study. Atrazine and metolachlor were detected in 100 percent, and acetochlor, alachlor and cyanazine were detected in more than 70 percent of all surface-water samples. Four pesticide degradates—metolachlor ethane sulfonic acid, alachlor ethane sulfonic acid, metolachlor oxanilic acid, and acetochlor ethane sulfonic acid were detected in more than 75 percent of the samples. Only one nonagricultural herbicide, prometon, was detected in more than 80 percent of the samples. Carbofuran, the most commonly detected insecticide, was found in 16 percent of all samples. Mixtures of pesticide compounds commonly occurred in the samples. Five or more parent pesticide compounds were detected in 50 percent of the samples. Four or more pesticide degradates were detected in 68 percent and seven or more pesticide degradates were detected in 17 percent of the samples. Acetochlor, alachlor, atrazine, cyanazine, and metolachlor were generally present at low concentrations; median concentrations ranged from 0.01 to 0.22 microgram per liter. However, median concentrations for the pesticide degra-dates, 0.07 to 3.7 micrograms per liter, were larger than their parent compounds. Acetochlor, alachlor, atrazine, cyanazine, and metolachlor pesticide compounds were detected at an order of magnitude or higher in the late spring and summer than at other times of the year. Pesticide concentrations generally peak following application in May and June and decrease during the growing season. A small secondary peak of atrazine, acetochlor, alachlor, cyanazine, and metolachlor concentrations occurred in late winter at all sites. The seasonal patterns for the triazine (atrazine and cyanazine) degradates were similar to the parent compounds (increasing in the spring), but the triazine degra-dates often had higher median concentrations than their parent compounds in the fall and winter. The chloroacetanilide (acetochlor, alachlor, and metolachlor) degradates did not follow a strong seasonal pattern like their parent compounds. In general, the chloroacetanilide degradates had constant and higher median concentrations when compared to their parent compounds throughout the year. The median concentrations for the chloroacetanilide pesticide degradates were often an order of magnitude higher than their parent compounds. Concentrations of pesticides varied by land-form region. Atrazine and cyanazine and their degradates were present in significantly greater concentrations in streams of the Southern Iowa Drift Plain than streams of either the Des Moines Lobe or the Iowan Surface.

Iowa, Minnesota↗
USGS2003

Aquatic assemblages and their relation to temperature variables of least-disturbed streams in the Salmon River basin, central Idaho, 2001

In the late 1990s, Idaho’s established stream temperature criteria for the protection of coldwater biota and salmonid spawning were considered inadequate because the criteria did not agree with observed biological conditions in many instances and did not allow for variability in environmental condition or species diversity across a broad area such as the entire State of Idaho. In 2001, benthic invertebrate and fish assemblages in 34 least-disturbed streams in the Salmon River Basin, central Idaho, were evaluated in relation to stream temperature and other environmental variables. The Salmon River Basin retains watersheds that are minimally affected by human activities. These “natural” stream conditions provide a basis for deriving attainable stream temperatures that can be used to set new, and revise existing, water-quality criteria for stream habitats affected by human activities. During July through September 2001, data were collected to document the thermal regime of least-disturbed streams, characterize the distribution of aquatic biota at streams representing a gradient of temperature, and describe the relations between environmental variables and benthic invertebrate and fish assemblages. Nine stream temperature metrics were compared with the U.S. Environmental Protection Agency’s criterion of 10 ° C (degrees Celsius) for bull trout spawning and juvenile rearing. The maximum weekly-maximum temperature at all 33 sites where temperature data were available exceeded this criterion. The maximum daily-maximum temperature (MDMT) at 30 of the sites exceeded the Idaho Department of Environmental Quality (IDEQ) criterion of 13.0 ° C for the protection of salmonid spawning; and the maximum daily-average temperature at all 33 sites exceeded the 9.0 ° C criterion for the protection of salmonid spawning. The thermal regime at most sites did not exceed the IDEQ criteria for the protection of coldwater biota. Nine environmental variables—water-surface gradient, discharge, wetted channel width, width:depth ratio, aspect, total seasonal thermal input, open canopy, riparian canopy density, and elevation were selected for correlation with the nine stream temperature metrics. Elevation showed the strongest inverse correlation with the stream temperature metrics. Two hundred and one benthic invertebrate taxa from the 34 sampling sites were identified. The most abundant taxa were Baetis tricaudatus , Oligochaeta, Tvetenia bavarica gr., Acari, Rhithrogena , Cinygmula , Heterlimnius , Micropsectra , Eukiefferiella devonica gr., Drunella doddsi , and Cricotopus . Of the 201 benthic invertebrate taxa collected during this study, 57 taxa (present at a minimum of 5 sampling sites) were significantly correlated with one or more of the stream temperature metrics. Among the invertebrate taxa collected, 32 were identified as coldwater taxa. Of the coldwater taxa collected, Zapada oregonensis gr. showed the strongest inverse correlation with the stream temperature metrics and was collected at sites where maximum weekly-maximum temperature (based on date of sample and 6 days prior) ranged from 11.3 ° to 18.5 °C. Ten species of fish in the families Salmonidae, Cottidae, and Cyprinidae were collected. Two species (bull trout and chinook salmon) listed as threatened under the U.S. Fish and Wildlife Service Endangered Species Act were collected. Among all species, bull trout showed the strongest inverse correlation between relative fish abundance and stream temperature. Bull trout and juvenile bull trout densities were inversely correlated with stream temperature. The probability of occurrence of juvenile bull trout was significantly correlated with MDMT on the basis of results from a logistic regression model developed during this study. However, this model differed from a similar model developed by the U.S. Forest Service on the basis of regional data collected in the Pacific Northwest. The regression model based on data collected during this study showed higher probabilities of occurrence of bull trout at colder stream temperatures (10 ° to 15 ° C) and lower probabilities of occurrence at warmer stream temperatures (16 ° to 21 ° C) than did the model based on regional data. The model comparisons suggest that regional or local differences need to be considered when deriving stream temperature criteria.

Idaho↗
USGS2003

Simulation of hydrodynamics, temperature, and dissolved oxygen in Bull Shoals Lake, Arkansas, 1994-1995

Outflow from Bull Shoals Lake and other White River reservoirs supports a cold-water trout fishery of substantial economic yield in north-central Arkansas and south-central Missouri. The Arkansas Game and Fish Commission has requested an increase in existing minimum flows through the Bull Shoals Lake dam to increase the amount of fishable waters downstream. Information is needed to assess the impact of increased minimum flows on temperature and dissolved-oxygen concentrations of reservoir water and the outflow.A two-dimensional, laterally averaged, hydrodynamic, temperature, and dissolved-oxygen model was developed and calibrated for Bull Shoals Lake, located on the Arkansas-Missouri State line. The model simulates water-surface elevation, heat transport, and dissolved- oxygen dynamics. The model was developed to assess the impacts of proposed increases in minimum flow from 4.6 cubic meters per second (the existing minimum flow) to 22.6 cubic meters per second (the increased minimum flow). Simulations included assessing the impact of (1) increased minimum flows and (2) increased minimum flows with increased initial water-surface elevation of 1.5 meters in Bull Shoals Lake on outflow temperatures and dissolved-oxygen concentrations.The increased minimum flow simulation (without increasing initial water-surface elevation) increased the water temperature and dissolved-oxygen concentration in the outflow. Conversely, the increased minimum flow and increased initial water-surface elevation (1.5 meters) simulation decreased outflow water temperature and dissolved-oxygen concentration through time. However, results from both scenarios for water temperature and dissolved-oxygen concentration were within the boundaries of the error between measured and simulated water column profile values.

Water-Resources Investigations Report↗
USGS2003

Reconnaissance of mercury in lakes, wetlands, and rivers in the Red River of the North Basin, North Dakota, March through August 2001

Devils Lake rose dramatically during the 1990's, causing extensive flood damages. Because of the potential for continued flooding, the U.S. Army Corps of Engineers has been conducting studies to evaluate the feasibility of constructing and operating an outlet from Devils Lake. The occurrence of mercury in lakes, wetlands, and rivers and the potential for increased loading of mercury into the Sheyenne River as a result of a Devils Lake outlet needed to be evaluated as part of the studies. Sixteen lake, wetland, and river sites in the Devils Lake, Sheyenne River, Red River of the North, and Red Lake River Basins were sampled and analyzed for mercury constituents and other selected properties and constituents relevant to mercury aquatic chemistry. For the lake and wetland sites, whole-water methylmercury concentrations ranged from less than 0.04 to 3.53 nanograms per liter and whole-water total mercury concentrations ranged from 0.38 to 7.02 nanograms per liter. Conditions favorable for methylation of mercury generally exist at the lake and wetland sites, as indicated by larger dissolved methylmercury concentrations in near-bottom samples than in near-surface samples and by relatively large ratios of methylmercury to total mercury (generally greater than 10 percent for the summer sampling period). Total mercury concentrations were larger for the summer sampling period than for the winter sampling period for all lake and wetland sites. A wetland site in the upper Devils Lake Basin had the largest mercury concentrations for the lake and wetland sites. For the river sites, whole-water methylmercury concentrations ranged from 0.15 to 1.13 nanograms per liter and whole-water total mercury concentrations ranged from 2.00 to 26.90 nanograms per liter. Most of the mercury for the river sites occurred in particulate inorganic phase. Summer ratios of whole-water methylmercury to whole-water total mercury were 35 percent for Starkweather Coulee (a wetland-dominated site), near or less than 10 percent for the Sheyenne River sites, and less than 8 percent for the Red River of the North and Red Lake River sites. Although the number of samples collected during this investigation is small, results indicated an outlet from Devils Lake probably would not have adverse effects on mercury concentrations in the Sheyenne River upstream from Lake Ashtabula. However, because discharges in the Sheyenne River would increase during some periods, loads of mercury entering Lake Ashtabula also would increase. Lake Ashtabula probably serves as a sink for suspended sediment and mercury. Thus, a Devils Lake outlet probably would not have substantial effects on mercury concentrations and loads in the downstream part of the Sheyenne River or in the Red River of the North. More substantial effects could occur for Lake Ashtabula.

North Dakota↗
USGS2003

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of gasoline oxygenates, selected degradates, and BTEX in water by heated purge and trap/gas chromatography/mass spectrometry

A method for determination of the alkyl ethers u sed as gasoline oxygenates [ethyl tert -butyl ether (ETBE), methyl tert -butyl ether (MTBE), diisopropyl ether (DIPE), and tert -amyl methyl ether (TAME)], some of their main degradates [acetone, methyl acetate, tert -butyl alcohol (tBA), and tert -amyl alcohol (tAA)], and BTEX (benzene, toluene, ethylbenzene, and xylenes) at low concentrations (<5 micrograms per liter) in water samples was developed. The compounds are determined using heated extraction to improve purging of polar compounds in a standard gas chromatography/ mass spectrometry (GC/MS) method for volatile compounds. Volatile compounds in this method are extracted (purged) from the sample b y bubbling helium through a 25-mL (milliliter) sample heated at about 65°C. Volatile compounds are trapped on a sorbent and then thermally desorbed into a GC/MS system for identification and quantitation. The calibration range for this method is 0.1 to 200 μg/L (micrograms per liter). Mean gasoline oxygenate recoveries from volatile-grade blank-water samples analyzed at concentrations from 0.5 to 5.0 μg/L were 95 to 105 percent, with relative standard deviations (RSDs) from 1.9 to 3.2 percent. Mean oxygenate degradate recoveries ranged from 88 to 107 percent, with RSDs of 3.2 to 7.4 percent, at concentrations from 1 to 50 μg/ L. Mean BTEX recoveries ranged from 91 to 107 percent, with RSDs of 1.1 to 6.6 percent, at concentrations from 0.5 to 10 μg/L . The method detection limits range from 0.035 to 0.052 μg/L for the gasoline oxygenates, 0.216 to 0.62 μg/L for the oxygenate degradates, and 0.005 to 0.036 μg/L for BTEX. Calculated holding times using American Society for Testing and Materials (ASTM) procedure D 4841-88 indicate that all of the analytes are stable for a minimum of 40 days at pH 2 and pH 7, except for methyl acetate, which is only stable for 7 days at pH 2.

Water-Resources Investigations Report↗
USGS2003

Simulation of ground-water flow in the Cedar River alluvium, northwest Black Hawk County and southwest Bremer County, Iowa

Flooding and high ground-water levels after large or frequent rainstorms have occurred in an area of about 30 square miles along the eastern bank of the Cedar River from Cedar Falls in northwest Black Hawk County to Janesville in southwest Bremer County, Iowa. The U.S. Geological Survey, in cooperation with Black Hawk County, conducted a hydrologic study of the Cedar River alluvium in the northwest Black Hawk and southwest Bremer Counties, to improve understanding of the ground-water flow system and evaluate the effects of hypothetical variations in recharge and discharge conditions. A steady-state ground-water flow model was constructed for the area using November 2001 hydrologic conditions. The model was discretized into an 83-row by 47-column grid of cells measuring approximately 500 feet by 500 feet. Two model layers, one for the alluvium and one for the underlying bedrock units, were used to represent flow in the area. Precipitation during 2001 was similar to historical normals. Precipitation during 1999, especially during the summer when flooding occurred, was well above the historical normals. Borings in the unconsolidated deposits in the study area confirmed the presence of a bedrock valley dipping to the south in the central part of the study area. Water-level measurements in 2001 indicate that ground-water flow in much of the alluvial aquifer parallels the direction of flow in the Cedar River toward the south rather than following shorter flow paths to the west toward the Cedar River. Under steady-state conditions and 2001 pumpage, primary sources of inflow to the ground-water flow system are the Cedar River (65.5 percent), recharge through infiltration of precipitation and upland runoff (31.4 percent), and subsurface flow across the lateral boundaries (3.1 percent). The primary components of outflow from the ground-water flow system are intermittent streams (56.0 percent) and the Cedar River (43.7 percent). Two hypothetical scenarios were used to assess the potential effects of higher river levels and increased recharge compared to the steadystate conditions. For one scenario, river levels were set to bankfull conditions, and a recharge of 1.2 times the steady-state rate was applied. This simulation was used to evaluate the effects of wet conditions. This scenario led to increased water levels, in general, and large areas of shallow (0 to 10 feet) depths to water along the eastern part of the model area near Highway 218. For the second scenario, conditions were the same as for the first scenario, but streambed conductance of intermittent streams modeled as drains was increased to 10 times the steady-state value to simulate increased flow of water from the shallow groundwater flow system. The area with depth to water of 0 to 10 feet along the eastern part of the model area was substantially smaller than that of the first scenario. In general, once high ground-water levels occur, either because of high Cedar River water Abstract levels or above normal local precipitation or both, ground-water in the central part of the study area along Highway 218 flows toward the south rather than following shorter flow paths to the Cedar River. Intermittent streams in the study area discharge substantial amounts of water from the ground-water flow system.

Iowa↗
USGS2003

Geologic framework and hydrogeologic features of the Glen Rose Limestone, Camp Bullis Training Site, Bexar County, Texas

The Glen Rose Limestone crops out over most of the Camp Bullis Training Site in northern Bexar County, Texas, where it consists of upper and lower members and composes the upper zone and the upper part of the middle zone of the Trinity aquifer. Uncharacteristically permeable in northern Bexar County, the Glen Rose Limestone can provide avenues for recharge to and potential contamination of the downgradient Edwards aquifer, which occupies the southeastern corner of Camp Bullis. The upper member of the Glen Rose Limestone characteristically is thin-bedded and composed mostly of soft limestone and marl, and the lower Glen Rose typically is composed mostly of relatively massive, fossiliferous limestone. The upper member, about 410 to 450 feet thick at Camp Bullis, was divided in this study into five hydrogeologic subdivisions, A through E (youngest to oldest). The approximately 120-foot-thick Interval A has an abundance of caves, which is indicative of its generally well developed fracture, channel, and cavern porosity that in places provides appreciable permeability. The 120- to 150-foot-thick Interval B is similar to Interval A but with less cave development and considerably less permeability. The 10- to 20-foot-thick Interval C, a layer of partly to mostly dissolved soluble carbonate minerals, is characterized by breccia porosity, boxwork permeability, and collapse structures that typically divert ground water laterally to discharge at land surface. The 135- to 180-foot-thick Interval D generally has low porosity and little permeability with some local exceptions, most notably the caprinid biostrome just below the top of the interval, which appears to be permeable by virtue of excellent moldic, vug, fracture, and cavern porosity. The 10- to 20-foot-thick Interval E, a layer of partly to mostly dissolved evaporites similar to Interval C, has similar hydrogeologic properties and a tendency to divert ground water laterally.

Texas↗
USGS2003

Chemical quality of water, sediment, and fish in Mountain Creek Lake, Dallas, Texas, 1994-97

The occurrence, trends, and sources of numerous inorganic and organic contaminants were evaluated in Mountain Creek Lake, a reservoir in Dallas, Texas. The study, done in cooperation with the Southern Division Naval Facilities Engineering Command, was prompted by the Navy’s concern for potential off-site migration of contaminants from two facilities on the shore of Mountain Creek Lake, the Naval Air Station Dallas and the Naval Weapons Industrial Reserve Plant. Sampling of stormwater (including suspended sediment), lake water, bottom sediment (including streambed sediment), and fish was primarily in Mountain Creek Lake but also was in stormwater outfalls from the Navy facilities, nearby urban streams, and small streams draining the Air Station. Volatile organic compounds, predominantly solvents from the Reserve Plant and fuel-related compounds from the Air Station, were detected in stormwater from both Navy facilities. Fuel-related compounds also were detected in Mountain Creek Lake at two locations, one near the Air Station inlet where stormwater from a part of the Air Station enters the lake and one at the center of the lake. Concentrations of volatile organic compounds at the two lake sites were small, all less than 5 micrograms per liter. Elevated concentrations of cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc, from 2 to 4 times concentrations at background sites and urban reference sites, were detected in surficial bottom sediments in Cottonwood Bay, near stormwater outfalls from the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls, compared to background and urban reference sites, were detected in surficial sediments in Cottonwood Bay. Elevated concentrations of polycyclic aromatic hydrocarbons, indicative of urban sources, also were detected in Cottonwood Creek, which drains an urbanized area apart from the Navy facilities. Elevated concentrations of polychlorinated biphenyls were detected in two inlets near the Air Station shoreline. Polycyclic aromatic hydrocarbon and heavy metal concentrations near the Air Station shoreline were not elevated compared to urban reference sites. Much larger concentrations of selected heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were detected in deeper, older sediments than in surficial sediments in Cottonwood Bay. The decreases in concentrations coincide with changes in wastewater discharge practices at the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls also were detected in older sediments in the Air Station inlet. On the basis of dated sediment cores and contaminant discharge histories, contaminant accumulation rates in Cottonwood Bay were much greater historically than recently. Most heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls that accumulated in the central and eastern parts of Cottonwood Bay appear to have come from the west lagoon on the Reserve Plant. Treated sewage and industrial-process wastewater were discharged to the west lagoon from about 1941 to 1974. Estimated annual contaminant accumulation rates in Cottonwood Bay decreased by from 1 to 2 orders of magnitude after 1974, when most point-source discharges to the west lagoon ceased. Polychlorinated biphenyls were detected in 61 of 62 individual fish-tissue samples. The largest average concentrations were in eviscerated channel catfish and the smallest were in largemouth bass fillets. Polychlorinated biphenyl and selenium concentrations from analyses of this study were large enough to prompt the Texas State Department of Health to issue a fish-possession ban for Mountain Creek Lake in 1996. Suspended sediments in stormwater at the lagoon outfalls and at sites on Cottonwood Creek were sampled and analyzed for major and trace elements, polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls. The suspended sediments from the outfalls contained about the same mixture of heavy metals and organic compounds, in elevated concentrations compared to reference sites, as bottom sediments from the lagoons and surficial bottom sediments in Cottonwood Bay. Diagnostic ratios of polycyclic aromatic hydrocarbons indicate that uncombusted fuel sources contribute to older sediments and that pyrogenic sources of polycyclic aromatic hydrocarbons dominate recently deposited sediments in Cottonwood Bay and along the Air Station shoreline.

Texas↗
USGS2004

Estimates of hydraulic properties from a one-dimensional numerical model of vertical aquifer-system deformation, Lorenzi site, Las Vegas, Nevada

Land subsidence related to aquifer-system compaction and ground-water withdrawals has been occurring in Las Vegas Valley, Nevada, since the 1930's, and by the late 1980's some areas in the valley had subsided more than 5 feet. Since the late 1980's, seasonal artificial-recharge programs have lessened the effects of summertime pumping on aquifer-system compaction, but the long-term trend of compaction continues in places. Since 1994, the U.S. Geological Survey has continuously monitored water-level changes in three piezometers and vertical aquifer-system deformation with a borehole extensometer at the Lorenzi site in Las Vegas, Nevada. A one-dimensional, numerical, ground-water flow model of the aquifer system below the Lorenzi site was developed for the period 1901-2000, to estimate aquitard vertical hydraulic conductivity, aquitard inelastic skeletal specific storage, and aquitard and aquifer elastic skeletal specific storage. Aquifer water-level data were used in the model as the aquifer-system stresses that controlled simulated vertical aquifer-system deformation. Nonlinear-regression methods were used to calibrate the model, utilizing estimated and measured aquifer-system deformation data to minimize a weighted least-squares objective function, and estimate optimal property values. Model results indicate that at the Lorenzi site, aquitard vertical hydraulic conductivity is 3 x 10-6 feet per day, aquitard inelastic skeletal specific storage is 4 x 10-5 per foot, aquitard elastic skeletal specific storage is 5 x 10-6 per foot, and aquifer elastic skeletal specific storage is 3 x 10-7 per foot. Regression statistics indicate that the model and data provided sufficient information to estimate the target properties, the model adequately simulated observed data, and the estimated property values are accurate and unique.

Water-Resources Investigations Report↗
USGS2003

Bathymetric mapping, sediment quality, and water quality of Lake Delhi, Iowa, 2001-02

Lake Delhi was formed in 1929 when the Interstate Power Company dammed the Maquoketa River near Delhi, Iowa, for generation of hydroelectric power. The resulting 450-acre lake became a popular area in eastern Iowa for boating, swimming, and fishing. Hydroelectric power generation ended in 1973, and lakeside residents purchased the dam to maintain the recreational opportunities of the lake. Increasing concerns about sediment deposition and water quality by lakeside residents led to a 2-year study that included a bathymetric survey, an assessment of sediment quality, and an assessment of water quality of Lake Delhi. A bathymetric map of Lake Delhi was constructed using more than 300,000 data points from echo sounding results and GIS (geographic information system) software. Results of bathymetric mapping showed that the upstream reach through most of the upstream-middle reach of Lake Delhi (approximately 3 miles) from about 0.25 mile upstream from the Greenslades coring site through Clair View Acres were particularly affected by sedimentation, with water depths ranging from less than 1 foot to a few areas that were as much as 10 feet deep. Numerous areas in the upstream-most 1-mile of the lake (about 0.25 mile upstream from the Greenslades coring site to just downstream from The Cedars coring site) had depths of only 1 to 2 feet and were nearly impassable by boats. The middle reach of Lake Delhi (an approximately 2.5-mile segment) from about one-half mile upstream from the Linden Acres coring site to just downstream from the Hartwick Dredge coring site was less affected by sedimentation with water depths from less than 1 to 16 feet. The deepest section (26 feet) of the lake was near the dam. Eleven trace metals and phosphorus were analyzed in 20 samples from seven lake-bottom sediment cores. The median and average traceelement concentrations from the sediment cores were less than the U.S. Environmental Protection Agency threshold-effects-level and probableeffects-level guidelines for toxic biological effects. Water-quality samples from eight sites (Maquoketa River, three lake sites, and four tributaries) were collected for five sampling periods (June 2001&ndash;July 2002). Water-quality samples were analyzed for physical properties (specific conductance, pH, temperature, turbidity, dissolved oxygen, and alkalinity), nutrients (nitrate, ammonia, and phosphorus), bacteria (total coliform and E. coli ), and suspended sediment. Selected water samples were analyzed for major ions, trace elements, and pesticides. Water-quality sampling results indicate areas affected by elevated nutrient and bacteria concentrations in the lake and tributary streams. The tributary streams had the highest median nitrate concentrations (12.1 milligrams per liter) when compared to median nitrate concentrations in the lake (8.7 milligrams per liter) or the Maquoketa River (10.5 milligrams per liter). The maximum nitrate concentrations detected for Maquoketa River, lake, and tributary sites were 13.5, 13.5, and 18.6 milligrams per liter, respectively. Nitrate concentrations in the late summer decreased from 2 Bathymetric Mapping, Sediment Quality, and Water Quality of Lake Delhi, Iowa, 2001&ndash;02 the upstream (7.8 milligrams per liter) to the downstream (5.0 milligrams per liter) one-third of Lake Delhi and most likely were the result of uptake of nitrate by algae and aquatic biota in the lake. Median concentrations of total coliform and E. coli bacteria for the lake sites were 450 and 17 colonies per 100 milliliters of sample, respectively. The U.S. Environmental Protection Agency criteria for full body contact (swimming or bathing) are 200 colonies per 100 milliliters for fecal bacteria and 126 colonies per 100 milliliters for E. coli bacteria. The highest bacteria concentrations in the lake occurred after a rain and were 25,000 colonies per 100 milliliters total coliform and 1,900 colonies per 100 milliliters E. coli .

Iowa↗
USGS2003

Changes in streamflow and summary of major-ion chemistry and loads in the North Fork Red River basin upstream from Lake Altus, northwestern Texas and western Oklahoma, 1945-1999

Upstream from Lake Altus, the North Fork Red River drains an area of 2,515 square miles. The quantity and quality of surface water are major concerns at Lake Altus, and water-resource managers and consumers need historical information to make informed decisions about future development. The Lugert-Altus Irrigation District relies on withdrawals from the lake to sustain nearly 46,000 acres of agricultural land. Kendall's tau tests of precipitation data indicated no statistically significant trend over the entire 100 years of available record. However, a significant increase in precipitation occurred in the last 51 years. Four streamflow-gaging stations with more than 10 years of record were maintained in the basin. These stations recorded no significant trends in annual streamflow volume. Two stations, however, had significant increasing trends in the base-flow index, and three had significant decreasing trends in annual peak flows. Major-ion chemistry in the North Fork Red River is closely related to the chemical composition of the underlying bedrock. Two main lithologies are represented in the basin upstream from Lake Altus. In the upper reaches, young and poorly consolidated sediments include a range of sizes from coarse gravel to silt and clay. Nearsurface horizons commonly are cemented as calcium carbonate caliche. Finer-grained gypsiferous sandstones and shales dominate the lower reaches of the basin. A distinct increase in dissolved solids, specifically sodium, chloride, calcium, and sulfate, occurs as the river flows over rocks that contain substantial quantities of gypsum, anhydrite, and dolomite. These natural salts are the major dissolved constituents in the North Fork Red River.

Oklahoma, Texas↗
USGS2003

Streamwater quality at selected sites in the Fraser River basin, Grand County, Colorado, water years 1991-2000

To determine the effect of population growth on streamwater quality in the Fraser River Basin, the U.S. Geological Survey did a study in cooperation with the Grand County Commissioners and the East Grand County Water Quality Board. During water years 1991 through 2000, the study determined that concentrations of un-ionized ammonia and nitrite plus nitrate in the streamwater of the basin are within Colorado State streamwater?quality standards. The study also found that concentrations of chloride are largest at the headwaters and decrease downstream; however, chloride loading in the stream has the opposite relation. Most nutrient loading to the Fraser River happens January through May. Concentrations of ammonia at Fraser River downstream from Vasquez Creek at Winter Park had a downward trend through the period of the study. Nitrite plus nitrate had upward and downward trends at different sites and over different time spans. Orthophosphorus concentrations had upward trends at two sites. In general, the streamwater quality in the Fraser River Basin is good and is not out of compliance with State standards.

Water-Resources Investigations Report↗