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USGS1975

A brief history of the U.S. Geological Survey

Established by an Act of Congress in 1879 and charged with responsibility for "classification of the public lands, and examination of the geological structure, mineral resources, and products of the national domain," the U. S. Department of the Interior's Geological Survey has been the Nation's principal source of information about its physical resources the configuration and character of the land surface, the composition and structure of the underlying rocks, and the quality, extent, and distribution of water and mineral resources. Although primarily a research and fact-finding agency, it has responsibility also for the classification of Federal mineral lands and waterpower sites, and since 1926 it has been responsible for the supervision of oil and mining operations authorized under leases on Federal land. From the outset, the Survey has been concerned with critical land and resource problems. Often referred to as the Mother of Bureaus, many of its activities led to the formation of new organizations where a management or developmental function evolved. These included the Reclamation Service (1902), the Bureau of Mines (1910), the Federal Power Commission (1920), and the Grazing Service (1934, since combined with other functions as the Bureau of Land Management). Mrs. Rabbitt's summary of the Survey's history in the following pages brings out well the development of these diverse activities and the Survey's past contributions to national needs related to land and resources.

General Information Product↗

USGS2008

Geological, geochemical, and geophysical studies by the U.S. Geological Survey in Big Bend National Park, Texas

Big Bend National Park (BBNP), Tex., covers 801,163 acres (3,242 km 2 ) and was established in 1944 through a transfer of land from the State of Texas to the United States. The park is located along a 118-mile (190-km) stretch of the Rio Grande at the United States-Mexico border. The park is in the Chihuahuan Desert, an ecosystem with high mountain ranges and basin environments containing a wide variety of native plants and animals, including more than 1,200 species of plants, more than 450 species of birds, 56 species of reptiles, and 75 species of mammals. In addition, the geology of BBNP, which varies widely from high mountains to broad open lowland basins, also enhances the beauty of the park. For example, the park contains the Chisos Mountains, which are dominantly composed of thick outcrops of Tertiary extrusive and intrusive igneous rocks that reach an altitude of 7,832 ft (2,387 m) and are considered the southernmost mountain range in the United States. Geologic features in BBNP provide opportunities to study the formation of mineral deposits and their environmental effects; the origin and formation of sedimentary and igneous rocks; Paleozoic, Mesozoic, and Cenozoic fossils; and surface and ground water resources. Mineral deposits in and around BBNP contain commodities such as mercury (Hg), uranium (U), and fluorine (F), but of these, the only significant mining has been for Hg. Because of the biological and geological diversity of BBNP, more than 350,000 tourists visit the park each year. The U.S. Geological Survey (USGS) has been investigating a number of broad and diverse geologic, geochemical, and geophysical topics in BBNP to provide fundamental information needed by the National Park Service (NPS) to address resource management goals in this park. Scientists from the USGS Mineral Resources and National Cooperative Geologic Mapping Programs have been working cooperatively with the NPS and several universities on several research studies within BBNP. Because the last geologic map of the entire BBNP was published in the 1960s, one of the primary goals of the USGS is to provide a new geologic map of BBNP at a scale 1:100,000; this work is ongoing among the USGS, NPS, the Texas Bureau of Economic Geology, and university scientists. This USGS Circular summarizes eight studies funded and primarily carried out by the USGS, but it is not intended to be a comprehensive reference of work conducted in BBNP. This Circular describes topical research of the recently completed interdisciplinary USGS project, which has provided information leading to a more complete understanding of the following topics in BBNP: Tectonic and geologic history (Chapters 1, 2, and 3), Age and formation processes of a skarn mineral deposit (Chapter 4), Geoenvironmental effects of abandoned mercury mines (Chapter 5), Age, source, and geochemistry of surface and subsurface water resources (Chapter 6), Isotopic tracing of food sources of bears (Chapter 7), and Geophysical characteristics of surface and subsurface geology (Chapter 8). Additional information and the geochemical and geophysical data of the USGS studies in BBNP are available on line at http://minerals.cr.usgs.gov/projects/big_bend/index.html.

Texas↗

USGS2004

Multistage hydrothermal silicification and Fe-Tl-As-Sb-Ge-REE enrichment in the Red Dog Zn-Pb-Ag district, northern Alaska: Geochemistry, origin, and exploration applications

Geochemical analyses of major, trace, and rare earth elements (REE) in more than 200 samples of variably silicified and altered wall rocks, massive and banded sulfide, silica rock, and sulfide-rich and unmineralized barite were obtained from the Main, Aqqaluk, and Anarraaq deposits in the Red Dog Zn-Pb-Ag district of northern Alaska. Detailed lithogeochemical profiles for two drill cores at Aqqaluk display an antithetic relationship between SiO2/Al2O3 and TiO2/Zr which, together with textural information, suggest preferential silicification of carbonate-bearing sediments. Data for both drill cores also show generally high Tl, Sb, As, and Ge and uniformly positive Eu anomalies (Eu/Eu* > 1.0). Similar high Tl, Sb, As, Ge, and Eu/Eu* values are present in the footwall and shallow hanging wall of Zn-Pb-Ag sulfide intervals at Anarraaq but are not as widely dispersed. Net chemical changes for altered wall rocks in the district, on the basis of average Al-normalized data relative to unaltered black shales of the host Kuna Formation, include large enrichments (>50%) of Fe, Ba, Eu, V, S, Co, Zn, Pb, Tl, As, Sb, and Ge at both Red Dog and Anarraaq, Si at Red Dog, and Sr, U, and Se at Anarraaq. Large depletions (>50%) are evident for Ca at both Red Dog and Anarraaq, for Mg, P, and Y at Red Dog, and for Na at Anarraaq. At both Red Dog and Anarraaq, wall-rock alteration removed calcite and minor dolomite during hydrothermal decarbonation reactions and introduced Si, Eu, and Ge during silicification. Sulfidation reactions deposited Fe, S, Co, Zn, Pb, Tl, As, and Sb; barite mineralization introduced Ba, S, and Sr. Light REE and U were mobilized locally. This alteration and mineralization occurred during Mississippi an hydrothermal events that predated the Middle Jurassic-Cretaceous Brookian orogeny. Early hydrothermal silicification at Red Dog took place prior to or during massive sulfide mineralization, on the basis of the dominantly planar nature of Zn-Pb veins, which suggests filling of fractures that developed in previously lithified rock. Uniformly low Ca and Mg and uniformly negative Ce anomalies in highly siliceous Red Dog wall rocks reflect hydrothermal decarbonation reactions and pervasive silicification owing to conductive cooling of oxidized metalliferous fluids. Similar Ca and Mg depletions are evident at Anarraaq but generally lack associated silicification, possibly because temperatures of the hydrothermal fluids were too low (<180??C) or because the thermal contrast between the fluids and wall rocks was smaller owing to the greater depth of alteration and mineralization there, compared with Red Dog. Chalcophile element anomalies (Fe, Zn, Pb, Tl, As, Sb) in wall rocks at both Red Dog and Anarraq are attributed to sulfidation reactions, coeval with subsurface Zn-Pb-Ag mineralization, during the mixing of oxidized metalliferous fluids with H2S-rich fluids derived locally within the Kuna Formation. Sedimentary wall rocks in the Red Dog district are characterized by a distinctive suite of geochemical anomalies, especially for Zn, Pb, Tl, As, Sb, Ge, and Eu/Eu*. At the Aqqaluk deposit, wall rocks without visible sphalerite or galena (<300 ppm Zn + Pb) have anomalous Eu/Eu*, Tl, Sb, and As for up to ???100 m stratigraphically below Zn-rich silica rock. At Anarraaq, the Tl anomaly is most extensively developed, and enrichment relative to unaltered black shale of the Kuna Formation is present up to 62 m above the highest Zn-Pb sulfide zones. The magnitude of the enrichment and systematic behavior of Tl in the district make Tl a promising geochemical exploration guide for Red Dog-type Zn-Pb-Ag deposits elsewhere. ?? 2004 by Economic Geology.

Economic Geology↗

USGS2025

Rapid emplacement of the Keaiwa Lava Flow of 1823 from the Great Crack in the Southwest Rift Zone of Kilauea volcano

The Keaīwa Lava Flow of 1823 in the Southwest Rift Zone of Kīlauea volcano is unusual for its expansive pāhoehoe sheet flow morphology and lack of constructive vent topography, despite having a similar tholeiitic basalt composition to other lavas erupted from Kīlauea. This lava flow issued from a ∼10-km-long continuous fissure now known as the Great Crack, and has an unusually thin sheet flow morphology with margin thicknesses of ∼15–110 cm (average of 42 cm). Based on field observations of the lava flow at its fissure vent (e.g., drain-back features), we propose that the Great Crack formed, or at least significantly widened, just prior to and syn-eruptively with this 1823 eruption. The absence of pyroclastic cones or spatter ramparts indicates that the eruption consisted of a rapid outpouring of relatively degassed lava as the fissure unzipped. The rapidly moving lava flow overtopped pre-existing tumuli and scoria cones (e.g., Lava Plastered Cones) up to ∼10 m tall. Glass and whole-rock chemistry yield homogeneous compositions for the lavas erupted from the Great Crack, with glass compositions of 6.40 ± 0.10 wt% MgO and whole-rock compositions of 7.39 ± 0.07 wt% MgO. Lava pads erupted from a short western fissure system are richer in mafic minerals (e.g., olivine and clinopyroxene), and show slightly more MgO-rich whole-rock compositions (7.79 ± 0.05 wt%). MgO-in-glass thermometry on juvenile spatter yield eruption temperatures of 1153 ± 13°C that are typical of Kīlauea lavas. Thus, the extensive sheet-like lava flow morphology is not a direct consequence of unusual magmatic or rheological conditions (i.e., low viscosity). Instead, the flow morphology is associated with high effusion rates caused by sudden drainage of uprift magma as it erupted from the Great Crack. Lava flow modeling on a 2-m-resolution digital elevation model indicates that a minimum bulk effusion rate of ∼5800 m 3 /s (∼3500 m 3 /s dense rock equivalent) and a minimum flow velocity of ∼11 m/s are required for the lava flow to overcome the topography of the Lava Plastered Cones. This effusion rate is among the highest inferred for eruptions in Hawaiʻi and around the world. This study highlights a less frequent eruption style at Hawaiian volcanoes characterized by a sudden outpouring of lava from an unusual fissure system. Local eyewitness accounts indicate that the 1823 eruption was preceded by seismicity. Given the complex magmatic-volcanic-tectonic relations across Kīlauea, we speculate that the south flank could have slipped over one or more events that ultimately triggered unzipping of the Great Crack and passive release of briefly stored uprift magma. An eruption similar to 1823 at Kīlauea or Mauna Loa, with an eruptive timeframe that could be as short as an hour, with high effusion rates and rapid flow front velocities, would not easily allow for a timely response.

Hawaii↗

USGS2007

Major- and Trace-Element Concentrations in Rock Samples Collected in 2006 from the Taylor Mountains 1:250,000-scale Quadrangle, Alaska

Introduction The Kuskokwim mineral belt of Bundtzen and Miller (1997) forms an important metallogenic region in southwestern Alaska that has yielded more than 3.22 million ounces of gold and 400,000 ounces of silver. Precious-metal and related deposits in this region associated with Late Cretaceous to early Tertiary igneous complexes extend into the Taylor Mountains 1:250,000-scale quadrangle. The U.S. Geological Survey is in the process of conducting a mineral resource assessment of this region. This report presents analytical data collected during the third year of this multiyear study. A total of 138 rock geochemistry samples collected during the 2006 field season were analyzed using the ICP-AES/MS42, ICP-AES10, fire assay, and cold vapor atomic absorption methods described in more detail below. Analytical values are provided in percent (% or pct: 1 gram per 100 grams), parts per million (ppm: 1 gram per 1,000,000 grams), or parts per billion (ppb: 1 gram per 1,000,000,000 grams) as indicated in the column heading of the data table. Data are provided for download in Excel (*.xls), comma delimited (*.csv), dBase 4 (*.dbf) and as a point coverage in ArcInfo interchange (*.e00) formats available at http://pubs.usgs.gov/of/2007/1386/.

Open-File Report↗

USGS1994

Thermal history of the periphery of the Junggar Basin, Northwestern China

Geochemical analysis of rock core samples show that the basin periphery has experienced low thermal stress; present-day heat flows are in the range of 25–35 mW/m 2 and have not been significantly higher than the worldwide mean of approx. 63 mW/m 2 since the mid-Permian. Present day heat flows were determined from corrected borehole temperatures and rock thermal conductivities. Paleo-heat flows were determined by first-order reaction kinetic modeling of several geochemical paleothermometers (vitrinite reflectance, clay mineral diagenesis and relative proportions of sterane and hopane biological marker diastereomers).

Junggar Basin, northwestern China↗

USGS1948

Mineralogy and petrology of the currant creek magnesite deposits and associated rocks of Nevada

Cryptocrystalline magnesite occurs as relatively small dense, white masses in a Tertiary volcanic tuff, here named the Currant tuff, in White Pine and Nye counties, 29 miles southwest of Ely, Nevada. The deposits are small, but some of the magnesite is of very high quality with almost no iron or aluminum. However, much of the magnesite is mixed with dolomite and calcite, and a serpentinelike mineral occurs in one of the deposits in sufficient abundance to be of possible use in ceramics. In scattered areas the tuff has been altered by solutions rich in magnesium and bicarbonic acid to dolomite, magnesite, magnesium silicate, and calcite. Mineral and chemical characteristics are the same throughout the entire rock assemblage of flows and tuffs, suggesting that all the rocks have been derived from the same parent magma. The tuff formation, which ranges in thickness from a few feet to over 400 feet, occurs between two groups of volcanic flows here referred to as the lower volcanics and the upper volcanics. The lower volcanics is composed mainly of flows of hypersthene dacite, but in the southwestern part of the area flows of a hypersthene andesite of balsaltic habit occur between the dacite and the overlying Currant tuff. The upper volcanics which overlie the Currant tuff consist of porphyritic quartz latite and an overlying massive latite crystal tuff. The Currant tuff containing the magnesite has both unmodified and reworked tuff members. The formation of hydrothermal dolomite, magnesite, and deweylite is discussed in detail, and the physical chemistry of solutions containing calcium, magnesium, and carbon dioxide is applied in an explanation of the origin of magnesium-rich solutions.

Nevada↗

USGS2021

Geology, mineralogy, and cassiterite geochronology of the Ayawilca Zn-Pb-Ag-In-Sn-Cu deposit, Pasco, Peru

The Ayawilca deposit in Pasco, Peru, represents the most significant recent base-metal discovery in the central Andes and one of the largest undeveloped In resources globally. As of 2018, it hosts an 11.7 Mt indicated resource grading 6.9% Zn, 0.16% Pb, 15 g/t Ag, and 84 g/t In, an additional 45.0 Mt inferred resource grading 5.6% Zn, 0.23% Pb, 17 g/t Ag, and 67 g/t In, and a separate Sn-Cu-Ag inferred resource of 14.5 Mt grading 0.63% Sn, 0.21% Cu, and 18 g/t Ag. Newly obtained U–Pb dates for cassiterite by LA-ICP-MS (22.77 ± 0.41 and 23.05 ± 2.06 Ma) assign the Ayawilca deposit to the Miocene polymetallic belt of central Peru. The polymetallic mineralization occurs as up to 70-m-thick mantos hosted by carbonate rocks of the Late Triassic to Early Jurassic Pucará Group, and subordinately, as steeply dipping veins hosted by rocks of the Pucará Group and overlying Cretaceous sandstones-siltstones of the Goyllarisquizga Group. Relicts of a distal retrograde magnesian skarn and cassiterite (stage pre-A) were identified in the deepest mantos. The volumetrically most important mineralization at Ayawilca comprises a low-sulfidation assemblage (stage A) with quartz, pyrrhotite, arsenopyrite, chalcopyrite, Fe-rich sphalerite, and traces of stannite and herzenbergite. Stage A sphalerite records progressive Fe depletion, from 33 to 10 mol% FeS, which is compatible with the observed transition from low- to a subsequent intermediate-sulfidation stage (B) marked by the crystallization of abundant pyrite and marcasite. Finally, during a later intermediate-sulfidation stage (C) sphalerite (up to 11 mol% FeS), galena, native bismuth, Cu-Pb-Ag sulfosalts, siderite, Mn-Fe carbonates, kaolinite, dickite, and sericite were deposited. This paragenetic evolution shows striking similarities with that at the Cerro de Pasco Cordilleran-type polymetallic deposit, even if at Ayawilca stage C did not reach high-sulfidation conditions. The occurrence of an early retrograde skarn assemblage suggests that the manto bodies at Ayawilca formed at the transition between distal skarn and skarn-free (Cordilleran-type) carbonate-replacement mineralization. Mineral assemblages define a T- f S 2 evolutionary path close to the pyrrhotite-pyrite boundary. Buffering of hydrothermal fluids by underlying Devonian carbonaceous phyllites of the Excelsior Group imposed highly reduced conditions during stage A mineralization (log f O 2 < − 30 atm). The low f O 2 favored efficient Sn mobility during stages pre-A and A, in contrast to other known ore deposits in the polymetallic belt of central Peru, in which the occurrence of Sn minerals is minor. Subsequent cooling, progressive sealing of vein walls, and decreasing buffering potential of the host rocks promoted the shift from low- (stage A) to intermediate-sulfidation (stages B and C) states. LA-ICP-MS analyses reveal significant In contents in Fe-rich sphalerite (up to 1.7 wt%), stannite (up to 1908 ppm), and chalcopyrite (up to 1185 ppm). The highest In content was found in stage A sphalerite that precipitated along with chalcopyrite and stannite, thus pointing to the early, low-sulfidation assemblage as prospective for this high-tech metal in similar mineral systems. Indium was likely incorporated into the sphalerite crystal lattice via Cu + + In 3+ ↔ 2 Zn 2+ and (Sn, Ge) 4+ + (Ga, In) 3+ + (Cu + Ag) + ↔ 4 Zn 2+ coupled substitutions. Indium incorporation mechanisms into the stannite and chalcopyrite crystal lattices remain unclear.

Pasco↗

USGS1963

Studies of fluid inclusions; [Part] 2, Freezing data and their interpretation

Aqueous and non-aqueous inclusions in 84 samples of various minerals from a wide range of geologic environments were studied with the freezing stage in order to gain an insight into the range of concentrations and compositions of fluid inclusions . Inclusions in most Mississippi Valley-type ore minerals contain highly concentrated saline solutions, showing freezing temperatures between -23.4° and -10.5° C; minerals from ore deposits of more typically hydrothermal affiliations mainly show temperatures of -9.4° to nearly 0° C; and inclusions in quartz crystals from sedimentary, metamorphic, and igneous rock environments show a wide range of freezing temperatures. Inclusions in pegmatite minerals in particular vary over a wide range, from the most concentrated solutions found in any inclusion (> 40% salts) to fairly dilute solutions (< 5% salts). Most inclusions in quartz from Swiss Alpine-type veins, and from Brazilian quartz veins and pegmatites, show freezing temperatures in the range -8.5° to - 2 .5°, and considerable free C02. Other geologic environments sampled include Colombian emerald, pegmatitic topaz and fluorite, the Triassic traprock zeolite assemblage, and sedimentary halite beds. Not all the phenomena exhibited by inclusions at low temperature are completely understood at present but several crystalline hydrate phases, such as NaCl-2H,0 and CO,-5%H,0 (structural formula 8C02-46H20), are shown to be stable in inclusions of appropriate composition even at temperatures above 0° C, and probably exist in the inclusions in natural rocks in polar regions. More significantly, the formation and recognition of such phases aid in establishing the gross composition of individual inclusions far too small for chemical analysis. The data obtained are useful in a variety of ways, such as: discriminating among gas, liquid, and supercritical fluid , and among liquid water, liquid oil, and liquid C02 in inclusions ; improving precision of the pressure corrections applied to inclusion filling temperature determinations; proving the general lack of leakage into or out of inclusions ; estimating the minimum pressure at the time of deposition of certain samples; verifying the lack of extraneous solid crystallization nuclei in the inclusions and hence their formation from exceedingly quiet, clean solutions; determining the total equivalent NaCl concentrations and some information concerning the composition of the fluids from which ores have formed; and determining changes in the composition of the fluids bathing a single crystal during its growth, and at certain times throughout its history.

Economic Geology↗

USGS2002

Geology, mineralization, and hydrothermal alteration and relationships to acidic and metal-bearing surface waters in the Palmetto Gulch area, southwestern Colorado

The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study. The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study.

Colorado↗

USGS1957

Geology of Saipan, Mariana Islands; Part 2, Petrology and soils

The rocks that comprise the volcanic formations of Saipan are of two principal types: dacites, which are characteristically glassy, and andesites, which are comparatively crystalline. The dacites consist primarily of silicic glass, oligoclase, and silica minerals (quartz, tridymite, cristobalite, chalcedony, and opal). Minor constituents in these rocks are green hornblende, biotite, magnetite, and hematite. The andesites are composed principally of labradorite, hypersthene, augite, and subcalcrc augite. Minor but also characteristic constituents of the andesites are quartz, tridymite, cristobalite, anorthoclase, and accessory magnetite, ilmenite, rutile, and apatite. Nine varieties of dacite and andesite are recognized on the basis of chemical composition, mineralogy, and texture. These are dacite, dacite vitrophyre, dacite perlite, hornblende-bearing dacite porphyry, augite-hypersthene andesite, quartz-bearing augite-hypersthene andesite, quartz-bearing augite-hypersthene andesite porphyry, augite andesite, and hypersthene andesite.

Professional Paper↗

USGS2021

Weakening of peridotite sheared at hydrothermal conditions

We conducted triaxial friction tests at hydrothermal conditions (25°C–350°C) on gouges of peridotite and its principal mineral constituents olivine and orthopyroxene. Pore-fluid chemistry was varied by the use of peridotite, granite, or quartzite driving blocks (representing wall rock) housing the gouge layer. Samples sheared at slow rates initially strengthen to a peak value, and then weaken toward a residual strength. The transition is accompanied by a change from velocity-weakening to velocity-strengthening behavior marked by a series of small stress drops. The extent of weakening varies with the ultramafic mineralogy and with the chemical environment established by the driving block lithology. The strengths of olivine and olivine-rich peridotite gouges decrease substantially (to μ ∼ 0.25–0.30), and that of orthopyroxene to a lesser extent, at temperatures ≥200°C when sheared between crustal driving blocks. Less weakening is observed in the peridotite-block experiments; the minimum strength of the peridotite gouges ( μ ∼ 0.5) occurs at 250°C, the temperature at which olivine hydration rates are near their maximum in ultramafic rocks. The strength reductions in all experiments are attributed to solution-transfer (pressure solution) processes that come to predominate over cataclastic mechanisms during shear. The lower pH of fluids in contact with silica-saturated crustal rocks enhances the weakening of olivine-rich gouges. In these short-duration experiments, secondary phyllosilicate mineral growth was of a limited extent and varied with gouge and wall-rock mineralogy and with temperature. Over geologic time spans, however, the alteration assemblages will assume an increasingly important role in fault-zone behavior.

Geochemistry, Geophysics, Geosystems↗

USGS1980

A generalized garnet-forming reaction for metaigneous rocks in the Adirondacks

A generalized reaction is presented to account for garnet formation in a variety of Adirondack metaigneous rocks. This reaction, which is the sum of five partial reactions written in aluminum-fixed frames of reference, is given by: 4(y+1+w)Anorthite+4 k(y+1+2 w)Olivine +4(1-k)(y+1+2 w)Fe-oxide+(8(y+1) -4 k(y+1+2 w))Orthopyroxene = 2(y+1)Garnet +2(y+1+2 w)Clinopyroxene+4 wSpinel where y is a function of plagioclase composition, k refers to the relative amounts of olivine and Fe-oxide participating in the reaction, and w is a measure of silicon mobility. When mass balanced for Mg and Fe, this reaction is found to be consistent with analyzed mineral compositions in a wide range of Adirondack metaigneous rocks. The reaction applies equally well whether the garnets were formed directly from the rectants given above or went through an intermadiate stage involving the formation of spinel, orthopyroxene, and clinopyroxene. The actual reactions which have produced garnet in both undersaturated and quartz-bearing rocks are special cases of the above general reaction. The most important special cases appear to be those in which the reactants include either olivine alone (k=1) or Fe-oxide alone (k=0). Silicon is relatively immobile (w =2) in olivine bearing, magnesium-rich rocks (k???1), and this correlates with the increased intensity in spinel clouding of plagioclase in these rocks. Silicon mobility apparently increases in the more iron-rich rocks, which also tend to contain clear or lightly clouded plagioclase. In all the rocks studied the most common composition of metamorphic plagioclase is close to An33 (i.e., y=1). Plagioclase of lower anorthite content may be too sodic to participate in garnet formation at the P-T conditions involved. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2009

U.S. Geological Survey research in Handcart Gulch, Colorado—An alpine watershed with natural acid-rock drainage

Handcart Gulch is an alpine watershed along the Continental Divide in the Colorado Rocky Mountain Front Range. It contains an unmined mineral deposit typical of many hydrothermal mineral deposits in the intermountain west, composed primarily of pyrite with trace metals including copper and molybdenum. Springs and the trunk stream have a natural pH value of 3 to 4. The U.S. Geological Survey began integrated research activities at the site in 2003 with the objective of better understanding geologic, geochemical, and hydrologic controls on naturally occurring acid-rock drainage in alpine watersheds. Characterizing the role of groundwater was of particular interest because mountain watersheds containing metallic mineral deposits are often underlain by complexly deformed crystalline rocks in which groundwater flow is poorly understood. Site infrastructure currently includes 4 deep monitoring wells high in the watershed (300– 1,200 ft deep), 4 bedrock (100–170 ft deep) and 5 shallow (10–30 ft deep) monitoring wells along the trunk stream, a stream gage, and a meteorological station. Work to date at the site includes: geologic mapping and structural analysis; surface sample and drill core mineralogic characterization; geophysical borehole logging; aquifer testing; monitoring of groundwater hydraulic heads and streamflows; a stream tracer dilution study; repeated sampling of surface and groundwater for geochemical analyses, including major and trace elements, several isotopes, and groundwater age dating; and construction of groundwater flow models. The unique dataset collected at Handcart Gulch has yielded several important findings about bedrock groundwater flow at the site. Most importantly, we find that bedrock bulk permeability is nontrivial and that bedrock groundwater apparently constitutes a substantial fraction of the hydrologic budget. This means that bedrock groundwater commonly may be an underappreciated component of the hydrologic system in studies of alpine watersheds. Additionally, despite the complexity of the fracture controlled aquifer system, it appears that it can be represented with a relatively simple conceptual model and can be treated as an equivalent porous medium at the watershed scale. Interpretation of existing data, collection of new monitoring data, and efforts to link geochemical and hydrologic processes through modeling are ongoing at the site.

Colorado↗

USGS1983

Mineral resource potential map of the Blanco Mountain and Black Canyon Roadless Areas, Inyo and Mono Counties, California

On the basis of geologic, geochemical, and geophysical investigations and a survey of mines and prospects, the mineral resource potential for gold, silver, lead, zinc, tungsten, and barite of the Blanco Mountain and Black Canyon Roadless Areas is judged to be low to moderate, except for one local area that has high potential for gold and tungsten resources. A geochemical survey detected moderately anomalous amounts of lead, copper, and zinc and less anomalous concentrations of tungsten, gold, and silver. Elements in anomalous samples were grouped as suites known to form in various ore deposits. Four element suites that may be indicative of mineralization are recognized in the White Mountains: (1) lead, zinc, and silver in carbonate rocks; (2) copper, barite, and lead in veins and replacement bodies; (3) tungsten, molybdenum, and bismuth in skarns; and (4) gold and arsenic in mineralized quartz veins. The assessment of the areas of resource potential was made in part by the application of ore deposit models to the geochemical results. A mineral deposit survey by the U.S. Bureau of Mines indicates that there are no properties with identified mineral resources in the Blanco Mountain Roadless Area. There is one active placer claim. In the Black Canyon Roadless Area, two properties have 40,000 tons of indicated and inferred low-grade gold, silver, or lead-bearing rock. Five properties near this roadless area have 150,000 tons of indicated and inferred low-grade gold, silver, lead, zinc, or tungsten-bearing rock. About 90 percent of this tonnage is estimated to occur at the Mirage-Mariposa and the Hope mines. The roadless areas have no known resource potential for geothermal energy, coal, oil, or gas.

California↗

USGS1967

Specific yield: compilation of specific yields for various materials

Specific yield is defined as the ratio of (1) the volume of water that a saturated rock or soil will yield by gravity to (2) the total volume of the rock or soft. Specific yield is usually expressed as a percentage. The value is not definitive, because the quantity of water that will drain by gravity depends on variables such as duration of drainage, temperature, mineral composition of the water, and various physical characteristics of the rock or soil under consideration. Values of specific yields nevertheless offer a convenient means by which hydrologists can estimate the water-yielding capacities of earth materials and, as such, are very useful in hydrologic studies. The present report consists mostly of direct or modified quotations from many selected reports that present and evaluate methods for determining specific yield, limitations of those methods, and results of the determinations made on a wide variety of rock and soil materials. Although no particular values are recommended in this report, a table summarizes values of specific yield, and their averages, determined for 10 rock textures. The following is an abstract of the table. [Table]

Water Supply Paper↗

USGS1996

Chronology of Late Cretaceous igneous and hydrothermal events at the Golden Sunlight gold-silver breccia pipe, southwestern Montana

Gold mineralization at the Golden Sunlight breccia pipe, southwestern Montana, is related to emplacement of Late Cretaceous alkali-calcic rhyolite and subsequent collapse of the Belt Supergroup wallrock and rhyolite in the pipe. The pipe is inferred to grade downward into an alkalic porphyry molybdenum system. The pipe is cut by alkalic to sub-alkalic lamprophyre dikes and sills, which locally contain high-grade gold where emplaced along late shear zones and vein systems. Determination of the emplacement age of the rhyolite is hampered by inherited lead or inherited Late Archean zircon from the source region of the rhyolite. An emplacement age of about 80 Ma for the rhyolite can be inferred if a basement age of 2,600 Ma is assumed. This Late Archean age is in agreement with basement ages determined in many parts of southwestern Montana. A 206 Pb- 238 U whole-rock date of 84 ? 18 Ma from altered and mineralized Belt Supergroup strata and rhyolite in the breccia pipe indicates hydrothermal alteration related to gold mineralization in Late Cretaceous time. Although sericite is a relatively widespread hydrothermal mineral, attempts to date the very fine grained material by the 40 Ar- 39 Ar method did not provide a spectra that could be interpreted unambiguously. A 40 Ar- 39 Ar plateau date of 76.9 ? 0.5 Ma from biotite phenocrysts in the lamprophyre indciates intrusion of mafic magma and attendant CO 2 metasomatism in the Late Cretaceous. Fission-track data from zircon in the rhyolite are permissive of slow uplift of the Belt Supergroup strata, 1U.S. Geological Survey, Box 25046, Denver Federal Center, Denver, CO 80225. 2Golden Sunlight Mines, Inc., 453 MT Highway 2 East, Whitehall, MT 59759. rhyolite, and lamprophyre between 55 and 50 Ma, but the data are not definitive. Rhyolitic welded tuff in the informally named units 7, 9, and 11 of the Elkhorn Mountains Volcanics is most similar in chemistry and age to the rhyolite at the Golden Sunlight mine. Trachybasalt in the Adel Mountains Volcanics and andesitic basalt in the informally named unit 8 of the Elkhorn Mountains Volcanics are the most analogous in chemistry and age to lamprophyres at the mine. The rhyolitic rocks appear to be derived from deep crustal sources, but data for the lamprophyres and mafic rocks in the Elkhorn Mountains Volcanics indicate that they were derived from the mantle.

Bulletin↗

USGS2006

Geology and mineral deposits of the Snow Camp-Saxapahaw area, central North Carolina

The Snow Camp-Saxapahaw study area, in the Carolina slate belt in the Southeastern United States, is notable for large zones of high-sulfidation alteration in arc-related metavolcanic rocks. The area has potential for additional significant pyrophyllite and related aluminosilicate refractory mineral deposits and may have potential for small- to medium-size gold deposits also associated with the high-sulfidation hydrothermal systems. The Carolina slate belt is an elongate zone of mostly low-grade metamorphic rocks of Neoproterozoic to early Paleozoic age that extends from northeastern Georgia to southern Virginia. It is dominated by volcanic rocks but locally consists of fine-grained epiclastic sedimentary rocks. Plutons and subvolcanic bodies have intruded the rocks of the Carolina slate belt in many places and have been important in controlling the metamorphism and in localizing hydrothermal alteration. The Snow Camp-Saxapahaw area is mostly underlain by volcanic and volcaniclastic rocks and lesser amounts of intrusive shallow plutons. The volcanic rocks range in composition from basalt to rhyolite; however andesites, dacites, and rhyodacites are the most abundant. The intrusive bodies are largely granite and quartz monzonite; gabbroic bodies also are common. It was possible to establish the relative ages of only part of these rocks. Two northeast-trending fault zones and fractures divide the map area into three structural blocks; the central block was tilted down to the southwest to form a grabenlike structure. Most of the hydrothermally altered rocks and all of the intensely altered zones are confined to the downdropped block, which we think may have been calderalike in origin. A major volcanic unit, the Reedy Branch Tuff, is limited to the southwestern part of the graben and may be the youngest volcanic rock in the area. Layered rocks record one or more strong folding events, but the diversity of rock types, lack of recognizable stratigraphic markers, and uneven distribution of outcrops prevented comprehensive structural studies. Except for a few late plutons and dikes, all of the rocks of the area have been metamorphosed in middle to upper greenschist facies, and contact aureoles were recognized around some of the plutons. Several relatively small bodies of granitic rock contain plagioclase grains in which primary oscillatory zoning was unaffected by metamorphism. These were interpreted to be post-metamorphic. We think that there were three separate stages of hydrothermal alteration in the complex volcanic terrane in the area. The oldest, an area of at least 8.5 square miles (22 square kilometers), was subjected to an intense hydrothermal alteration, ranging from peripheral zones of quartz-sericite-paragonite through a patchy marginal zone of pyrophyllite, andalusite, and other high-alumina minerals, to almost totally silicified core zones. The second event resulted in large areas of weak to moderate sericitic and propylitic alteration recognizable only in the Reedy Branch Tuff. The last event was related to post-metamorphic plutons. All of the pyrophyllite-andalusite deposits and perhaps most of the gold and silver mineralization can be related to the first period of hydrothermal alteration. The subsequent metamorphism did not produce significant changes in mineral species in the zones of most intense hydrothermal alteration. Gold- and silver-bearing sulfide minerals in fracture zones along the southeastern margin of the graben may also have been deposited during this earliest alteration stage. No metallic mineralization appears to have occurred during the second event. A group of molybdenum-bearing greisenlike bodies formed during the emplacement of the youngest plutons during the post-metamorphic event. One gold-bearing sulfide zone occurs in the exocontact of one such porphyritic stock.

North Carolina↗