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Distribution of hydrogeologic units in the Black Hills area, South Dakota

This report is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. The map in this report is part of a series of 1:100,000-scale maps that are being produced for the study. Other maps include structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers). The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills.

Hydrologic Atlas↗

Ground-water conditions in the Milwaukee-Waukesha area, Wisconsin

Three major aquifers underlie the Milwaukee-Waukesha area: sandstones of Cambrian and Ordovician age, Niagara dolomite of Silurian age, and sand and gravel deposits of Pleistocene age. The Maquoketa shale of Ordovician age acts as a more or less effective seal between the Pleistocene deposits and Niagara dolomite above and the sandstone aquifer below. Crystalline rocks of pre-Cambrian age form an impermeable basement complex below the Paleozoic sedimentary rocks. The Paleozoic strata dip east at 25 to 30 feet to the mile. There is no evidence that any of the faults and folds known or surmised to be present acts as a barrier to the movement of ground water. The bedrock surface underlying the Milwaukee-Waukesha area is formed by the Niagara dolomite except in northeastern Milwaukee County, where it is dolomite and shale of the Milwaukee formation of Devonian age, and in some of the preglacial valleys where the uppermost bedrock formation is the Maquoketa shale. Unconsolidated deposits of glacial drift cover the surface of the bedrock almost completely. Buried valleys in the bedrock surface contain as much as 150 feet of water-bearing sand and gravel deposits. These deposits, along with the Niagara dolomite, could be developed as sources of water supplemental to that of the sandstone aquifer. The Niagara dolomite is an important aquifer; it yields water from crevices and solution channels. The sandstone aquifer consists of the Galena dolomite, the Platteville limestone, and the St. Peter sandstone of Ordovician age, and the Eau Claire and Mount Simon sandstones of Cambrian age. The St. Peter and Mount Simon are the most productive formations but the others supply some water to wells. Static water levels in the shallow aquifers have not declined to any great extent except in downtown Milwaukee, where a 50-foot-deep cone of depression exists. Static water levels in the sandstone aquifer declined as much as 350 feet in the Milwaukee area from 1880 through 1950. Recharge to the two shallow aquifers occurs locally from precipitation within the area. The major recharge area of the sandstone aquifer lies about 25 miles west of Wauwatosa. Some ground water is recharged to the sandstone aquifer locally by leakage from the Niagara dolomite, mostly through deep uncased wells. Ground water is the source of six municipal supplies and many industrial and commercial supplies in the area. Pumpage from deep wells has increased from about 2.5 mgd in 1900 to about 25 mgd in 1949, of which 6.0 mgd was derived from the shallow aquifers. The total withdrawal from the shallow aquifers, including the 6.0 mgd from the deep wells, was about 19.5 mgd in 1949. Thus the total in 1949 was 38.5 mgd for the area as a whole. Coefficients of transmissibility and storage for the sandstone aquifer were obtained by means of controlled pumping tests at Wauwatosa, Waukesha, Greendale, Town of Lake, and Jefferson. The coefficients were used to calculate the amount of water recharged from the Niagara dolomite to the sandstone aquifer in the area. About 5.5 mgd of the 23 mgd pumped from deep wells in 1950 was supplied locally by leakage from the Niagara dolomite. The coefficients, with corrections for boundaries, were also applied to past records of pumpage to calculate the water-level decline in the sandstone aquifer at Wauwatosa from 1880 through 1950. The calculated decline was 317 feet, and the actual decline was 307 feet. The future water-level decline in the sandstone aquifer at Wauwatosa resulting from estimated future pumping conditions was computed. If the pumpage in the area as ?. whole increases from about 23 mgd in 1950 to about 28 mgd in 1960, the water levels at Wauwatosa will decline as much as 65 feet more by 1960. It is estimated that the available recharge to the sandstone aquifer underlying the Milwaukee-Waukesha area is approximately 60 mgd. It is recommended that new deep wells be located to the west toward the recharge area and that the shallow aquifers be used as auxiliary sources to void excessive lowering of water levels in the sandstone aquifers. Conservation should be practiced by all users of ground water to avoid waste resulting in lower water levels and higher pumping costs.

Wisconsin↗

Ultra-high chlorine in submarine Kı̄lauea glasses: Evidence for direct assimilation of brine by magma

Basaltic glass grains from the submarine south flank of Kı̄lauea, Hawai′i, have Cl concentrations of 0.01–1.68 wt%, the latter being the highest Cl content yet recorded for a Hawaiian glass. The high-Cl glass grains are products of brine assimilation by tholeiite magma. The glasses are grains in a sandstone clast from bedded breccias draping the southwestern margin of Kı̄lauea’s submarine midslope bench. The clast contains two distinct suites of glass grains: abundant degassed tholeiites, perhaps derived from subaerial lavas of Mauna Loa that shattered upon ocean entry, and a smaller population of Kea-type tholeiite ( n =17 analyzed) that erupted subaqueously, based on elevated S (780–1050 ppm), H 2 O (0.42–1.27 wt%), and CO 2 (<30–120 ppm), probably early in Kı̄lauea’s shield-building stage. Ten grains in this group have Cl>1000 ppm, six >5000 ppm, and two grains have >10 000 ppm dissolved Cl. Abundances of H 2 O, Na 2 O, K 2 O, and several trace elements increase regularly with Cl concentration, and we estimate that Cl enrichment was due to up to 13 wt% addition of a brine consisting of 78% H 2 O (wt), 13% Cl, 4.4% Na, 2.6% K, 2.6% Ca, 620 ppm Ba, 360 ppm Sr, 65 ppm Rb, and 7 ppm Pb. The large amounts of brine addition argue against bulk assimilation of low-porosity brine-bearing rock. The brine’s composition is appropriate for a seawater-derived hydrothermal fluid that reacted with basaltic wall rocks at T >100°C, losing Mg and S and gaining K, Ca, Rb, Ba, Sr, and Pb, followed by phase separation near 500°C and ∼50 MPa (5 km below sea level at hydrostatic pressure). Brine was assimilated at or near the depth it formed, as estimated on petrologic grounds, but under lithostatic conditions. The highest extents of assimilation either forced volatile saturation of the magma or enriched already coexisting magmatic vapor in H 2 O. Possible mechanisms for assimilation are: (1) forcible injection of brine into magma during bursting of overpressured pockets heated by new dikes, or (2) intrusion of magma into lenses or sills occupied by trapped brine.

Hawaii↗

Deep-ocean polymetallic nodules and cobalt-rich ferromanganese crusts in the global ocean: New sources for critical metals

The transition from a global hydrocarbon economy to a green energy economy and the rapidly growing middle class in developing countries are driving the need for considerable new sources of critical materials. Deep-ocean minerals, namely cobalt-rich ferromanganese crusts and polymetallic nodules, are two such new resources generating interest. Polymetallic nodules are essentially two-dimensional mineral deposits sitting on abyssal plain sediments at about 3,500–6,000 m water depths. Metals of economic interest enriched in nodules include nickel, copper, manganese, cobalt and molybdenum. Cobalt-rich ferromanganese crusts are also two-dimensional deposits forming pavements on rock outcrops on seamounts and ridges at water depths of 400–7,000 m. Metals of economic interest for crusts include cobalt, manganese, nickel, molybdenum, tellurium, platinum, vanadium and rare earth elements. A conservative estimate is that 21.1 billion dry tons of polymetallic nodules exist in the Clarion-Clipperton Zone ( CCZ ) manganese nodule field, the largest in area and tonnage of the known global nodule fields. Based on that estimate, tonnages of many critical metals in the CCZ nodules are greater than those found in global terrestrial reserves. About 7.5 billion dry tons of cobalt-rich ferromanganese crusts are estimated to occur in the Pacific Ocean Prime Crust Zone, the area with the highest tonnage of critical-metal-rich crust deposits, with many elements contained therein estimated to be greater than those found in global terrestrial reserves. Deep-ocean mining has not yet been carried out in the Exclusive Economic Zone of any nation, nor in the Areas beyond national jurisdiction, although extensive mineral exploration and environmental studies are being conducted and exploitation regulations codified, indicating that mining activities will likely begin in the near future. If deep-ocean mining follows the evolution of offshore production of petroleum, we can expect that about 35–45 per cent of the demand for critical metals will come from deep-ocean mines by 2065.

Book chapter↗

Double-diffusive convection in geothermal systems: the Salton Sea, California, geothermal system as a likely candidate

Much has been published about double-diffusive convection as a mechanism for explaining variations in composition and temperature within all-liquid natural systems. However, relatively little is known about the applicability of this phenomenon within the heterogeneous rocks of currently active geothermal systems where primary porosity may control fluid flow in some places and fractures may control it in others. The main appeal of double-diffusive convection within hydrothermal systems is-that it is a mechanism that may allow efficient transfer of heat mainly by convection, while at the same time maintaining vertical and lateral salinity gradients. The Salton Sea geothermal system exhibits the following reservoir characteristics: (1) decreasing salinity and temperature from bottom to top and center toward the sides, (2) a very high heat flow from the top of the system that seems to require a major component of convective transfer of heat within the chemically stratified main reservoir, and (3) a relatively uniform density of the reservoir fluid throughout the system at all combinations of subsurface temperature, pressure, and salinity. Double-diffusive convection can account for these characteristics very nicely whereas other previously suggested models appear to account either for the thermal structure or for the salinity variations, but not both. Hydrologists, reservoir engineers, and particularly geochemists should consider the possibility and consequences of double-diffusive convection when formulating models of hydrothermal processes, and of the response of reservoirs to testing and production.

Geothermics↗

Porphyry copper assessment of the Tethys region of western and southern Asia: Chapter V in Global mineral resource assessment

A probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in the Tethys region of western and southern Asia was carried out as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The purpose of the study was to delineate geographic areas as permissive tracts for the occurrence of porphyry copper deposits at a scale of 1:1,000,000 and to provide probabilistic estimates of amounts of copper likely to be contained in undiscovered porphyry copper deposits in those tracts. The team did the assessment using the USGS three-part form of mineral resource assessment, which is based on (1) mineral deposit and grade-tonnage models constructed from known deposits as analogs for undiscovered deposits, (2) delineation of permissive tracts based on geoscientific information, and (3) estimation of numbers of undiscovered deposits. The assessment area includes the Asian part of Turkey and Georgia, Armenia, Azerbaijan, Iran, western Pakistan, and southwestern Afghanistan. Selected tracts also extend marginally into southwesternmost Russia and northeasternmost Iraq. This region is located in the central part of the larger Tethyan Eurasian Metallogenic Belt, which extends from western Europe to eastern Asia. Mining in this part of the Tethyan Eurasian Metallogenic Belt has occurred for thousands of years; in 2011 the region produced 420,000 metric tons (t) of copper (2.6 percent of global production), 8,300 t of molybdenum (3 percent), and 29,600 kilograms of gold (1 percent). The assessment team defined 26 tracts permissive for Late Triassic to Holocene porphyry copper-molybdenum and porphyry copper-gold deposits. Permissive tracts range in extent from 2,960 to 194,000 square kilometers (km 2 ) and cover a total area of 924,000 km 2 . Younger tracts overlap older tracts in several areas. Three permissive tracts include sub-tracts in order to separate tract segments on the basis of geography, data quality, or likelihood of occurrence of undiscovered deposits. About 65 percent of all known porphyry sites occur in only five tracts, which also host most of the identified copper resources. In terms of tectonic setting, 58 percent of the permissive tracts are related to continental arcs; 19 percent to island arcs or back arcs; and 24 percent to postcollisional settings. Of the known porphyry copper deposits, subequal fractions are spread among these three settings. The spatial distribution of known porphyry deposits and prospects is also related to the level of erosion. Magmatic belts with numerous known porphyry sites exhibit subequal areas of coeval plutonic and volcanic units and lesser amounts of cover rocks. Belts with fewer known porphyry sites display either high or low volcanic-to-plutonic ratios and (or) greater cover, indicating crustal levels that are too shallow or too deep for exposure of porphyry deposits. Probabilistic estimates of numbers of undiscovered porphyry copper deposits were made for 18 of the 26 tracts. The undiscovered porphyry copper endowment for 8 tracts is discussed qualitatively. The assessment estimates that the Tethys region contains 47 undiscovered deposits within 1 kilometer of the surface. Probabilistic estimates of numbers of undiscovered deposits were combined with grade and tonnage models in a Monte Carlo simulation to estimate probable amounts of contained metal. The 47 undiscovered deposits are estimated to contain a mean of 180 million metric tons (Mt) of copper distributed among the 18 tracts for which probabilistic estimates were made, in addition to the 62 Mt of copper already identified in the 42 known porphyry deposits in the study area. Results of Monte Carlo simulations show that 80 percent of the estimated undiscovered porphyry copper resources in the Tethys region are located in four tracts or sub-tracts.

Scientific Investigations Report↗

Fish Lake limnology and watershed aqueous geochemistry, Fish Lake Plateau, Utah

Fish Lake is located at 2696 m elevation on the Fish Lake Plateau with a bedrock geology of Oligocene to Pliocene age volcanics and Cretaceous to Eocene age sedimentary rocks. Lake bathymetry indicates a maximum depth of ~27 m and volume of 2.31 x 108 m3. The lake is dimictic with summer water column temperature declines of 13˚C between 7 to 15 m depth, whereas in spring and fall water column is isothermal. Numerous surface streams flow into the lake and there is one surface outflow stream, Lake Creek, which drains to the northeast into Johnson Valley Reservoir and the Fremont River, which is a tributary of the upper Colorado River. Surface inflow streams and spring waters are generally dilute and ionic compositions are consistent with bedrock geology. Spring and creek water oxygen and hydrogen stable isotope compositions indicate snowmelt is the predominant water source to the lake. High evaporative enrichment is indicated by lake water stable oxygen and hydrogen compositions and conservative ions, which suggest evaporative water loss equal or greater than inflow. The ionic and isotope data combined with preliminary discharge measurements provide a preliminary estimated lake-water residence time between approximately 15 and 30 years, although groundwater flux is currently unknown. Dissolved silica concentrations decline by two orders of magnitude between inflowing waters and summer lake waters, indicating substantial uptake by freshwater diatoms and high biological productivity. During summer, epilimnion pH values of 8.7 contribute to slight oversaturation with respect to calcite/aragonite, which suggests that precipitates could form in minor concentration. Below the thermocline pH is near neutral and carbonate mineral dissolution within the water column is likely.

Utah↗

Review of Aquifer Test Results for the Lansdale Area, Montgomery County, Pennsylvania, 1980–95

Aquifer and aquifer-isolation test results in and around North Penn Area 6 Superfund site, Lansdale, Montgomery County, Pennsylvania are reviewed to provide estimated aquifer properties for use in a numerical model of ground-water flow. This review was made to support of remedial action investigations by U.S. Environmental Protection Agency (USEPA), Region III, Philadelphia. The data reviewed are from files of the U.S. Geological Survey, USEPA, and water companies, and from unpublished consultant reports prepared for USEPA and corporations in the Lansdale area. Tested wells are in fractured sedimentary rocks of the Brunswick Formation, which are Triassic-aged, dipping shales and sandstones. Review procedures include, in some cases, new analyses of drawdown during pumping and recovery by use of analytical models of flow to wells. Estimated aquifer transmissivities (T) range from zero to about 1,300 m 2 /d (meters squared per day); most tests indicate T between 10 and 100 m 2 /d. Aquifer-isolation testing results indicate that most flow enters wells at a few discrete zones, probably fractures or bedding-plane openings. The vertical connection between the zones in a single borehole with multiple producing zones commonly is negligible. This suggests that the formation is vertically anisotropic; the hydraulic conductivity is much larger in the horizontal direction than in the vertical direction. Some evidence of well-field-scale horizontal anisotropy exists, with maximum transmissivity aligned with the regional northeast strike of bedding, but this evidence is weak because of the small number of observation wells, particularly wells screened in isolated depth intervals. Analysis of recovery data after constant-pumping-rate aquifer tests and of drawdown during step tests suggests that a significant fraction, perhaps as much as 85 percent, of the drawdown in some production wells is due to well loss or skin effects in or very near the pumped well and is not caused by resistance to flow in the surrounding formations.

Pennsylvania↗

Geology of tight oil and potential tight oil reservoirs in the lower part of the Green River Formation, Uinta, Piceance, and Greater Green River Basins, Utah, Colorado, and Wyoming

The recent successful development of a tight oil play in the Eocene-age informal Uteland Butte member of the lacustrine Green River Formation in the Uinta Basin, Utah, using modern horizontal drilling and hydraulic fracturing techniques has spurred a renewed interest in the tight oil potential of lacustrine rocks. The Green River Formation was deposited by two large lakes, Lake Uinta in the Uinta and Piceance Basins and Lake Gosiute in the Greater Green River Basin. These three basins contain the world’s largest in-place oil shale resources with recent estimates of 1.53 trillion, 1.33 trillion, and 1.44 trillion barrels of oil in place in the Piceance, Uinta, and Greater Green River Basins, respectively. The Uteland Butte member was deposited during an early freshwater stage of the lake in the Uinta Basin prior to deposition of the assessed oil shale intervals. This report only presents information on the early freshwater interval and overlying brackish-water interval in all three basins because these intervals are most likely to have tight oil potential. Burial histories of the three basins were reconstructed to study (1) variations in subsidence and lake development, and (2) post deposition burial that led to the development of a petroleum system in only the Uinta Basin. The Uteland Butte member is a successful tight oil play because it is thermally mature for hydrocarbon generation and contains organic-rich shale, brittle carbonate, and porous dolomite. Abnormally high pressure in parts of the Uteland Butte is also important to production. Variations in organic richness of the Uteland Butte were studied using Fischer assay analysis from oil shale assessments, and pressures were studied using drill-stem tests. Freshwater lacustrine intervals in the Piceance and Greater Green River Basins are immature for hydrocarbon generation and contain much less carbonate than the Uteland Butte member. The brackish-water interval in the Uinta Basin is thermally mature for hydrocarbon generation but is clay-rich and contains little carbonate, and thus is a poor prospect for tight oil development.

Colorado, Utah, Wyoming↗

Multispectral digital image mapping of Antarctic ice features

Landsat multispectral images of the Antarctic ice sheet have been digitally enhanced by the US Geological Survey to show ice surface features not seen in earlier photographic products of the same scenes. Now for the first time it is worthwhile to prepare image maps at scales of up to 1:250 000 of ice sheet areas even where no nunataks are visible. Derivatives of the data can be stretched to bring out glaciologically significant features in smooth areas that traditionally have been described as featureless. Over large tracts of the ice sheet, the direction of ice flow can be revealed as clearly as it is by the medial moraines of an Alpine glacier system. Ice streams, ice divides, ice rises, ice rumples, grounding lines, crevasses, and rifts are seen where none had been identified before. In the same way that Seasat altimetry of the surface of the ocean has much to tell about the bed of the ocean, Landsat has much to tel! about the bed of the ice. Not only major structural features but also many details of the sub-glacial landscape are unmasked by their subtle reflection on the ice sheet surface. Ground control on ice sheets can be obtained by Doppler satellite observations tied to image-identifiable surface features. Because of ice movement, the standard of geodetic control can never approach that of conventional surveys based on rock stations. But the precise standards of conventional surveys are unnecessary for ice sheet maps.

Annals of Glaciology↗

Volcanic processes and geology of Augustine Volcano, Alaska

Augustine Island (volcano) in lower Cook Inlet, Alaska, has erupted repeatedly in late-Holocene and historical times. Eruptions typically beget high-energy volcanic processes. Most notable are bouldery debris avalanches containing immense angular clasts shed from summit domes. Coarse deposits of these avalanches form much of Augustine's lower flanks. A new geologic map at 1:25,000 scale depicts these deposits, these processes. We correlate deposits by tephra layers calibrated by many radiocarbon dates.Augustine Volcano began erupting on the flank of a small island of Jurassic clastic-sedimentary rock before the late Wisconsin glaciation (late Pleistocene). The oldest known effusions ranged from olivine basalt explosively propelled by steam, to highly explosive magmatic eruptions of dacite or rhyodacite shed as pumice flows. Late Wisconsin piedmont glaciers issuing from the mountainous western mainland surrounded the island while dacitic eruptive debris swept down the south volcano flank.Evidence is scant for eruptions between the late Wisconsin and about 2,200 yr B.P. On a few south-flank inliers, thick stratigraphically low pumiceous pyroclastic-flow and fall deposits probably represent this period from which we have no radiocarbon dates on Augustine Island. Eruptions between about 5,350 and 2,200 yr B.P. we know with certainty by distal tephras. On Shuyak Island 100 km southeast of Augustine, two distal fall ashes of Augustinian chemical provenance (microprobe analysis of glass) date respectively between about 5,330 and 5,020 yr B.P. and between about 3,620 and 3,360 yr B.P. An Augustine ash along Kamishak Creek 70 km southwest of Augustine dates between about 3,850 and 3,660 yr B.P. A probably Augustinian ash lying within peat near Homer dates to about 2,275 yr B.P.From before 2,200 yr B.P. to the present, Augustine eruptive products abundantly mantle the island. During this period, numerous coarse debris avalanches swept beyond Augustine's coast, most recently in A.D. 1883. The decapitated summit after the 1883 eruption, replaced by andesite domes of six eruptions since, shows a general process: collapse of steep summit domes, then the summit regrown by later dome eruptions. The island's stratigraphy is based on six or seven coarse-pumice tephra "marker beds." In upward succession they are layers G (2,100 yr B.P.), I (1,700 yr B.P.), H (1,400 yr B.P.), C (1,200-1,000 yr B.P.), M (750 yr B.P.), and B (390 yr B.P.).A coarse, hummocky debris-avalanche deposit older than about 2,100 yr B.P.-or perhaps a stack of three of them-lies along the east coast, the oldest exposed such bouldery diamicts on Augustine Island. Two large debris avalanches swept east and southeast into the sea between about 2,100 and 1,800 yr B.P. A large debris avalanche shed east and east-northeast into the sea between 1,700 and 14,00 yr B.P.Between about 1,400 and 1,100 yr B.P. debris avalanches swept into the sea on the volcano's south, southwest, and north-northwest. Pumiceous pyroclastic fans spread to the southeast and southwest, lithic pyroclastic flows and lahars (?) to the south and southeast. Pyroclastic flows, pyroclastic surges, and lahars swept down the west and south flanks between about 1,000 and 750 yr B.P.A debris avalanche swept into the sea on the west, and a small one on the south-southeast, between about 750 and 400 yr B.P. Large lithic pyroclastic flows shed to the southeast; smaller ones descended existing swales on the southwest and south.Between about 400 yr B.P. and historical time (late 1770s), three debris avalanches swept into the sea on the west-northwest, north-northwest, and north flanks. One of them (West Island) was large and fast: most of it rode to sea far beyond a former sea cliff, and its surface includes geomorphic evidence of having initiating a tsunami. Augustine's only conspicuous lava flow erupted on the north flank.During this prehistoric period numerous domes grew at the volcano's summit, remnants of which form the east and south sides of the present summit-dome complex. Three domes grew below the summit area on the upper south and northwest flanks. In between large eruptions that deposited coarse pumiceous fall beds, many smaller eruptions emplaced beds of sand-sized ash on the volcano flanks.During the past 750 years, beach and back-beach eolian dunes accreted at the southwest coast, forming a ribbed coastwise topography. Lesser dunes grew at the backs of beaches in coves on other flanks.An eruption in 1883 shed a debris avalanche swiftly into the sea on the north-northeast, followed by pyroclastic flows and surges. Eruptions in 1935 and 1963-64 grew summit domes that spilled over the southwest and south flanks and shed coarse rubbly lithic pyroclastic flows down those flanks. Eruptions and 1976 and 1986 grew domes that draped down the north flank and shed voluminous pyroclastic flows to the northeast through north-northwest flanks, when smaller pyroclastic flows and (or) lahars swept down other flanks. A small dome-building eruption in January-March 2006 after this report was all but complete we treat only fleetingly. The largest debris avalanches sweep into the sea at Augustine's coast at speeds inferred between 60 and 80 m/s. Augustine is capable of initiating damaging tsunami to lower Cook Inlet, but geologic evidence for them on the mainland is sporadic and sparse.

Alaska↗

Ground-water quality in unmined areas and near reclaimed surface coal mines in the northern and central Appalachian coal regions, Pennsylvania and West Virginia

Findings are presented from investigations during 1996-1998 by the U.S. Geological Survey National Water-Quality Assessment Program. Ground-water quality in 58 wells downgradient of reclaimed surface coal mines is compared to ground-water quality from 25 wells in unmined areas (background concentrations) in the bituminous coal fields of the northern Appalachian coal region (high-sulfur coal region) in Pennsylvania, Maryland, and West Virginia and the central Appalachian coal region (low-sulfur coal region) in West Virginia. Ground water in the mined high-sulfur coal region has significantly greater median concentrations of sulfate, hardness, calcium, and specific conductance compared to the unmined high-sulfur coal region and to both mined and unmined areas in the low-sulfur coal region. Ground water in mined areas had median values of mine-drainage constituents (sulfate, iron, manganese, aluminum, hardness, calcium, magnesium, turbidity, and specific conductance) that were significantly greater than medians for wells in unmined areas. Mine-drainage constituents include cations such as calcium and magnesium that become elevated compared to levels in unmined areas because of exposure of acidic mine drainage to calcareous materials. The transport of pyrite-oxidation products from the mined site and subsequent neutralization reactions by calcareous materials at the mine site or along the flow path are likely processes that result in greater concentrations of mine-drainage constituents in mined areas compared to unmined areas. Mine-drainage constituents generally exceeded unmined-area background concentrations within about 500 feet of mined sites but were at or below background levels in wells more than 1,000 feet downgradient of mined sites. Concentrations of sulfate, hardness, and total dissolved solids were greatest at well depths of 50 to 150 feet but generally were less than background concentrations in wells deeper than 150 feet. Concentrations of iron, manganese, and aluminum exceeded background concentrations in many wells less than 150 feet deep. In mined areas, median ground-water ages are nearly as old in hill locations as in valley locations. Older ground-water age correlates with increased distance from mined areas. The lack of significant correlation among mine-drainage-constituent concentrations, ground-water age, distance from mined areas, and topographic locations may be the result of factors such as (1) mixing of ground-water ages in wells open to fractures with variable depths, lengths, and interconnections; (2) disturbance of rock from blasting; and (3) variations in slope and terrain relief in the study area.

Pennsylvania, West Virginia↗

Geology and ground-water resources of Webster County, Iowa

Webster County, comprising an area of 718 square miles just northwest of the center of Iowa, had a population of 44,241 in 1950, with 25,115 in Fort Dodge, the principal city. Some 94.4 percent of the county is in farm land; corn is the principal crop and is used in the raising of hogs and cattle, an important occupation in this part of the country. Mineral products include gypsum, clay, coal, sand, gravel and limestone. The mean annual precipitation at Fort Dodge is 31.21 inches, of which more than 3 inches normally occurs during each of the months May, June, July, August, and September. The average number of growing days is 150. The warmest month generally is July; during December, January, and February the average temperature normally is below freezing. The upland area, comprising over 80 percent of the county, is mostly a gently undulating, slightly eroded glacial-drift plain. Morainal hills of low relief occur in the extreme southern and northern parts of the county. The Des Moines River flows through the county from north to south and, together with its tributaries, drains the entire county except the southwestern part, which is tributary to the Raccoon River. The Des Moines River has cut a deep, narrow valley about 90 feet below the upland in the northern part of the county and about 220 feet below the upland in the southern part. The tributary streams commonly have shallow valleys more than a few miles back from the Des Moines River. Glacial deposits of Pleistocene age, ranging in thickness from 50 feet in the north to 175 feet in the south, mantle the indurated rocks over all the upland area, but indurated rocks ranging in age from Mississippian to Cretaceous are exposed in places along the valleys of the Des Moines River and its tributaries.

Iowa↗

Whitings, a sedimentologic dilemma

Whitings, drifting clouds of water, milky because of suspended carbonate, have been claimed to originate from either the action of bottom-feeding fish or direct precipitation of calcium carbonate. Five cruises during different seasons were made to the Great Bahama Bank to collect data pertinent to the controversy. Measurements of particulate concentrations average 10 mg/liter with a maximum of 20 mg/liter of carbonate sediment suspended in whiting water, compared with an average of 1.5 mg/liter for clear water outside the whitings. The particles are dominantly acicular aragonite, but Mg calcite composes as much as 20 percent of some whitings. Sedimentation rates, measured with fixed and drifting sediment traps, were as great as 34 g/m 2 /hr. Sediment suspended in whitings aggregated into silt- and sand-size fioccules and settled to the bottom of settling tanks within six hours, even on a rocking ship. Sediment in artificial whitings, created by stirring sediment from the bottom with a shrimp trawl, settled to the bottom in about the same time. Natural whitings, on the other hand, were never observed to dissipate. Because sedimentation from whitings occurs at rates sufficient to cause dissipation of the whitings within six hours, we conclude that the natural whitings are continually replenished by direct precipitation. The search for fish in whitings utilized sidescan sonar and fathometer imaging, shrimp trawls, rotenone, remote video, and direct scuba observation. These methods and 25 years of casual observations leading to this study indicate that fish are not involved in the formation of most Bahamian whitings. Several whitings were found over rocky or sandy bottoms where there was no mud available for fish to suspend. The distance of these whitings from areas of muddy bottom precluded their having been made elsewhere by fish. Stable carbon- and oxygen-isotopic analyses and Delta 14 C activity are interpreted to indicate that the suspended sediment in whitings contains some precipitated calcium carbonate and is not merely bottom sediment stirred into suspension. Estimates indicate that the amount of new carbonate produced in whitings on the Great Bahama Bank is substantially higher than that arising from algal production. Consequently, the amount of sediment transported to deep water may be much greater than previously thought.

Journal of Sedimentary Petrology↗

Gold placers of the historical Fortymile River region, Alaska

The Fortymile River region in east-central Alaska has a long and colorful history as the site of the first major gold discovery in interior Alaska. Placer gold has been mined in the region nearly every year since its original discovery in 1886. Total gold production is approximately 500,000 troy ounces. Although many of the rich deposits have been mined, there still exist areas that contain gold. Areas of mined and unmined gold-bearing creek and terrace gravels are outlined on the accompanying geologic map. The early history of the Fortymile area centered on the small frontier settlement of Fortymile City located at the junction of the Fortymile and Yukon Rivers in Canadian territory. This was the supply and jumping-off point for prospectors who worked their way into Alaska up the Fortymile River and found gold on many of its tributaries. Hand mining, both underground and surface, using sluice boxes and (or) rockers were the earliest methods; later, hydraulicking, dredging, and draglining methods were used. More recently, bulldozers and elevated trammels have been used, as well as very portable floating suction dredges. The rich mining lore of the area is closely associated with events of the nearby world-famous Klondike District. Bedrock and placer geology and mining history of individual gold-rich creeks are herein updated. The Fortymile area, which is part of the Yukon-Tanana Upland, contains quartzite, schist, gneiss, amphibolite, marble, serpentinite, and granite overlain by basalt, sandstone, conglomerate, shale, tuff, and coal; overlying these rocks are several deposits of varying ages consisting of gold-bearing gravel and colluvium. The close spatial association of creeks containing placer gold and the gneiss, schist, amphibolite, and marble unit strongly suggests this metamorphic unit is the gold source. High terrace gravels record a time from the late Tertiary to early Pleistocene when the ancestral Fortymile River and its major tributaries, the North and South Forks, had floodplains roughly 1 to 2 miles (2-3 kilometers) wide and gradients of about 4 feet per mile (0.75 meters per kilometer). Base-level lowering during the post-early Pleistocene caused the rivers to cut into their floodplains and to develop the youthful characteristics they have today such as V-shaped canyons, narrow floodplains, and gradients of at least twice those of the old river. Colluvium marginal to creek deposits in steep-sided valleys is often gold bearing. Much of the unconsolidated gravel within the major drainages of the Fortymile River, South Fork, North Fork, and Mosquito Fork is colluvium. Heavy-mineral-concentrate samples from the gold-producing creeks and high terrace gravels contain varying amounts of magnetite (20 to 80 percent) and ilmenite (10 to 30 percent), and samples from creeks draining areas principally composed of metamorphic rocks contain abundant garnet (10 to 30 percent). Gold fineness ranges from 620 to 927, but it is difficult to attach any geologic significance to the fineness data. Most placer gold in the Fortymile River area has been recovered at, or near, the gravelbedrock contact. The lowermost 3.3 feet (1 meter) of gravel and the uppermost 1.6 feet (0.5 meter) of bedrock may contain as much as 80 to 90 percent of the gold that is ultimately recovered. Gold nuggets are rare and most of the gold recovered is in the form of flattened fragments less than .2 inches (5 millimeters) in greatest dimension. However, large gold nuggets have been found on Wade Creek; examples are ones of 25,33,56, and 70 ounces. Occasionally, large nuggets may still be found in the tailing piles along the creek. The Fortymile River and its tributaries the South Fork, Walker Fork, and Mosquito Fork, all of which at one time were the sites of bucket-line dredge operations, now are almost exclusively mined using floating suction dredges. Unmined gold-bearing gravel is present in the floodplain of the Walker Fork valley below Cherry Creek and in low (about 100 to 130 feet or 30 to 40 meters) terraces along the north side of Walker Fork and east side of Cherry Creek. Considering the locations of where most gold has been found in the South Fork valley both by the older bucket dredges and the modern suction dredges, it seems likely that the tributary drainages of Lost Chicken, Napoleon, Franklin, and Buckskin Creeks have supplied the bulk of the gold to the South Fork valley. A quarter acre (0.10 hectare), 130-foot-thick ( 40 meters) section of the high terrace gravels on the north side of Napoleon Creek was mined for placer gold and yielded values estimated to be $8.50 per cubic yard (or $6.50 per cubic meter) at $350 per troy ounce. The unmined high terrace gravels on the south side of Buckskin Creek contain gold; however, this gravel is only 3 to 6.5 feet (1 to 2 meters) thick. The search for a lode gold source in the Fortymile River region may be in vain, because substantially more gold than has been recovered from the placers can be derived by the gradual erosion of large volumes of source rocks that contain background mean gold amounts. Using Leon's mass balance equation, 5,167 metric tons of gold may exist in the placers of the Fortymile River region, less than 1 percent of the recovered amount of 15.6 tons. The largest gold resource remaining in the Fortymile River region is probably in the high terrace gravels exposed along many of the creeks and rivers. Until there is exploratory drilling or a comprehensive sampling program, the amount of gold in these gravels will remain unknown. Environmental constraints imposed by Federal and State agencies have slowed, but not stopped, placer mining in the Fortymile River area, and a significant gold price rise would result in more mining.

Alaska↗

Deep root activity overprints weathering of petrogenic organic carbon in shale

The oxidation of organic carbon in sedimentary bedrock (petrogenic OC, OC p e t r o "> petro ) is increasingly recognized as a potential source of CO 2 to the atmosphere. Recent studies provide evidence for the mobilization and oxidation of OC p e t r o "> petro in sedimentary bedrock during rock weathering. However, the mechanisms and rates remain uncertain, particularly where overlying soils and vegetation drive contemporaneous oxidation of recently fixed organic carbon. Here, we quantify OC p e t r o "> petro weathering across a 16 m shale depth profile in a steep, rapidly eroding forested hillslope in the Northern California Coast Ranges. We report solid and gas phase radiocarbon and stable isotope analyses of samples extracted from specialized in-situ samplers, and a supporting laboratory incubation experiment of the shale regolith. OC p e t r o "> petro is removed from the weathered bedrock at a rate of approximately 0.12 gC/m 3 yr, which is orders of magnitude lower than the rate of OC p e t r o "> petro oxidation we achieved in the laboratory with crushed samples (557.1 gC/m 3 /yr). This disparity occurs despite high O 2 ( g ) "> 2(g) content across the depth profile, indicating that physical accessibility of OC p e t r o "> petro can regulate oxidative weathering. There is no direct radiocarbon evidence of OC p e t r o "> petro oxidation in CO 2 ( g ) "> 2(g) across the upper 13 m of the weathering profile during both wet and dry seasons. Instead, vadose zone CO 2 ( g ) "> 2(g) production at the site is dominated by respiration of recently fixed carbon associated with deep rooting. OC p e t r o "> petro is clearly mobilized across the vadose zone during weathering in this rapidly eroding, oxygen-rich, biologically dynamic hillslope, but at rates far below what can be measured given the contribution of root-derived CO 2 ( g ) "> 2(g) .

California↗

Evidence for low-grade metamorphism, hydrothermal alteration, and diagenesis on Mars from phyllosilicate mineral assemblages

The enhanced spatial and spectral resolution provided by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on the Mars Reconnaissance Orbiter (MRO) has led to the discovery of numerous hydrated silicate minerals on Mars, particularly in the ancient, cratered crust comprising the southern highlands. Phases recently identified using visible/near-infrared spectra include: smectite, chlorite, prehnite, high-charge phyllosilicates (illite or muscovite), the zeolite analcime, opaline silica, and serpentine. Some mineral assemblages represent the products of aqueous alteration at elevated temperatures. Geologic occurrences of these mineral assemblages are described using examples from west of the Isidis basin near the Nili Fossae and with reference to differences in implied temperature, fluid composition, and starting materials during alteration. The alteration minerals are not distributed homogeneously. Rather, certain craters host distinctive alteration assemblages: (1) prehnite-chlorite-silica, (2) analcime-silica-Fe,Mg-smectite-chlorite, (3) chlorite-illite (muscovite), and (4) serpentine, which furthermore has been found in bedrock units. These assemblages contrast with the prevalence of solely Fe,Mg-smectites in most phyllosilicate-bearing terrains on Mars, and they represent materials altered at depth then exposed by cratering. Of the minerals found to date, prehnite provides the clearest evidence for subsurface, hydrothermal/metamorphic alteration, as it forms only under highly restricted conditions ( T = 200–400ºC). Multiple mechanisms exist for forming the other individual minerals; however, the most likely formation mechanisms for the characteristic mineralogic assemblages observed are, for (1) and (2), low-grade metamorphism or hydrothermal (<400ºC) circulation of fluids in basalt; for (3), transformation of trioctahedral smectites to chlorite and dioctahedral smectites to illite during diagenesis; and for (4), low-grade metamorphism or hydrothermal (<400ºC) circulation of fluids in ultramafic rocks. Evidence for high-grade metamorphism at elevated pressures or temperatures >400ºC has not been found.

Clays and Clay Minerals↗

Water-resources appraisal of Crater Lake National Park, Oregon

Crater Lake National Park is on the crest of the Cascade Range in southwestern Oregon. Except for small areas of glacial deposits, the area is underlain by volcanic rocks of Tertiary and Quaternary age. The principal rock types are andesitic and basaltic lavas, pumiceous volcanic flow breccias, tuffs, and airborne and flow pumice. The pumice is an excellent medium for the infiltration of much of the 67 inches of annual precipitation. The pumice and underlying lava flows and pyroclastic material transmit a large quantity of ground water which percolates to the water table and to various spring outlets. In many areas of the park, the occurrence of perched ground water at altitudes below 6,500 feet is shown by numerous springs that drain water from ground-water bodies perched above the regional water table. Most of the streams and springs in the area flow throughout the year. The quality of the water is excellent. It is soft, has a low mineral content, and contains insignificant amounts of objectionable constituents. During 1962, test drilling in the northern part of the park failed to locate perched-water bodies capable of supplying quantities of water adequate for proposed facilities. However, test drilling indicated that the regional water table is below an altitude of 4,960 feet and that wells at high altitudes may have to be drilled to depths exceeding a thousand feet to obtain water. Because the water table is at undetermined depth and the existence of productive perched ground-water bodies above the regional water table at a specific site cannot be predicted, the possibility of obtaining productive wells in the area is speculative.

Open-File Report↗