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Zirconium and hafnium in the southeastern Atlantic States

The principal source of zirconium and hafnium is zircon, though a minor source is baddeleyite, mined only in Brazil. Zircon is an accessory mineral in igneous, metamorphic, and sedimentary rocks, but rarely occurs in hardrock in minable quantities. The principal sources of zircon are therefore alluvial deposits, which are mined in many countries of five continents. The principal commercial deposits in the United States are in Florida, though others exist elsewhere in the southeastern Coastal Plain. The evidence indicates that conditions for the accumulation of workable deposits of heavy minerals were more favorable during the interglacial stages of the Pleistocene epoch than during Recent time. Therefore detrital ores of large volume and high tenor are more likely to be found in the terrace deposits than along the present beaches. Other concentrations of heavy minerals, however, are possible at favored sites close to the Fall Line where the Tuscaloosa formation rests upon the crystalline rocks of the Piedmont province. A score of heavy and semiheavy minerals occur in the detrital deposits of Florida, but the principal salable minerals are ilmenite, leucoxene, rutile, and zircon, though monazite and staurolite are saved at some mining plants. Commercial deposits of heavy minerals are generally required to have a tenor of 4 percent, though ores with a lower tenor can be mined at a profit if the content of monazite is notably high. The percentages of zircon in the concentrates ranges from 10 to 16 percent, and in eastern Florida from 13 to 15 percent. Thus the tenor in zircon of the ore-bearing sands ranges from 0.4 to 0.6 percent. The content of hafnium in zircon is immaterial for many uses, but for some purposes very high or very low tenors in hafnium are required. Alluvial zircon cannot be separated into such varieties, which, if needed, must be obtained from sources in bedrock. It thus becomes necessary to determine the Hf : Zr ratios in zircon from many kinds of bedrock. Granitic rocks are the principal sources of zircon, though not the best sources of zircon with a high tenor in hafnium. A general study by the Geological Survey of the granitic rocks of the Southeastern Atlantic States has been in progress for 10 years, and hundreds of samples of granitic accessory minerals have been acquired. Thirty samples of zircon from these collections were selected for spectrographic and X-ray determinations of their tenors in hafnium. Nine other samples of alluvial zircon were included, of which three are from Florida and six from foreign countries. No domestic zircon was discovered with very high or very low tenors in hafnium. The volume of zircon in the southeastern Coastal Plain is enormous, but most of it is not recoverable. The minable reserves of heavy minerals, however, are very large, and from these it is estimated conservatively that 10 million short tons of zircon can be obtained. The corresponding amounts of zirconium and hafnium, using the mean Hf:Zr ratio of the deposits in Florida, are 4,868,000 and 112,000 tons, respectively. These reserves could be delivered, if needed, at the rate of 100,000 tons a year.

Florida, Georgia, North Carolina, South Carolina, ↗

Archive of bathymetry data collected in South Florida from 1995 to 2015

Description Land development and alterations of the ecosystem in south Florida over the past 100 years have decreased freshwater and increased nutrient flows into many of Florida's estuaries, bays, and coastal regions. As a result, there has been a decrease in the water quality in many of these critical habitats, often prompting seagrass die-offs and reduced fish and aquatic life populations. Restoration of water quality in many of these habitats will depend partly upon using numerical-circulation and sediment-transport models to establish water-quality targets and to assess progress toward reaching restoration targets. Application of these models is often complicated because of complex sea floor topography and tidal flow regimes. Consequently, accurate and modern sea-floor or bathymetry maps are critical for numerical modeling research. Modern bathymetry data sets will also permit a comparison to historical data in order to help assess sea-floor changes within these critical habitats. New and detailed data sets also support marine biology studies to help understand migratory and feeding habitats of marine life. This data series is a compilation of 13 mapping projects conducted in south Florida between 1995 and 2015 and archives more than 45 million bathymetric soundings. Data were collected primarily with a single beam sound navigation and ranging (sonar) system called SANDS developed by the U.S. Geological Survey (USGS) in 1993. Bathymetry data for the Estero Bay project were supplemented with the National Aeronautics and Space Administration's (NASA) Experimental Advanced Airborne Research Lidar (EAARL) system. Data from eight rivers in southwest Florida were collected with an interferometric swath bathymetry system. The projects represented in this data series were funded by the USGS Coastal and Marine Geology Program (CMGP), the USGS South Florida Ecosystem Restoration Project- formally named Placed Based Studies, and other non-Federal agencies. The purpose of the data collection for all these projects was to support one or more of the following scientific aspects: numerical model applications, sea floor change analysis, or marine habitat investigations. This report serves as an archive of processed bathymetry sounding data, digital bathymetric contours, digital bathymetric maps, sea floor surface grids, and formal Federal Geographic Data Committee (FGDC) metadata. Refer to the Abbreviations page for explanations of acronyms and abbreviations used in this report. Since 2006, the USGS St. Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier or Field Activity Number (FAN) for each field data collection. Projects described in this report conducted prior to 2006 do not have a FAN. Data from the 13 projects presented in this report provided critical hydrographic information to support multiple science projects in south Florida. The projects and the types of sounding data collected are: Florida Bay (1995-1999) - single-beam Lake Okeechobee (2001) - single-beam Tampa Bay (2001-2004) - single-beam Caloosahatchee River (2002)- single-beam Estero Bay to Matlacha Pass and offshore to Wiggins Pass (2003) - single-beam and airborne lidar North and Northwest Forks of the Loxahatchee and Lower St. Lucie Rivers (2003) - single-beam South Charlotte Harbor and offshore Sanibel Island (2003-2004) - single-beam Shark River and Trout Creek (2004) - single-beam and interferometric swath Southwest Florida Rivers (2004) - interferometric swath Offshore from Wiggins Pass to Cape Romano (2005) - single-beam Ten Thousand Islands (2009) - single-beam Lemon Bay (2011) - single-beam Southwest Florida Rivers (2015) - interferometric swath

Florida↗

Forest and flooding with special reference to the White River and Ouachita River basins, Arkansas

The observed response of trees to hydrologic stress and distribution of trees in relation to habitat indicate that flooding, ground-water level, soil moisture, soil factors, and drainage characteristics exert a strong influence on bottomland forest species distribution. The dominant hydrologic factor influencing the distribution of bottomland tree species is flooding. Individual tree species are distributed as a function of frequency and duration of flooding. In the lower White and Ouachita River basins, the flood plains consist of a series of terraces, progressively higher terraces having less frequent flooding and less duration of flooding, and a significantly different composition of forest tree species. The sites studied can be divided into four basic groups and several subgroups on the basis of flood characteristics. On Group I (water hickory-overcup oak) sites, flooded near annually 32 to 40 percent of the time, the dominant species are water hickory and overcup oak. On Group II (nuttall oak) sites, flooded near annually 10 to 21 percent of the time, a more varied flora exists including nuttall oak, willow oak, sweetgum, southern hackberry, and American elm. The third group (Group III or shagbark hickory-southern red oak) of sites is flooded at intervals from 2 to 12 years. This group includes southern red oak, shagbark hickory, and black gum. The presence of blackjack oak in addition to Group III species marks Group IV (not flooded in historic time). (Kosco-USGS)

Arkansas↗

Net Ecosystem Production (NEP) of the Great Plains, United States

Gross primary production (GPP) and ecosystem respiration (Re) are the fundamental environmental characteristics that promote carbon exchanges with the atmosphere (Chapin and others, 2009), although other exchanges of carbon, such as direct oxidation (Lovett and others, 2006), can modify net ecosystem production (NEP). The accumulation of carbon in terrestrial ecosystems results in systems in which soil organic matter (SOM) carbon often exceeds biomass carbon (Post and Kwon, 2000). This SOM pool exists at a steady state between GPP and Re in ecosystems unless drivers change or the ecosystem endures environmental perturbations (for example, climatic). As indicated by Wilhelm and others (2011), conversion of grasslands to agriculture and cultivation can result in reduced soil carbon, with the release of carbon dioxide (CO 2 ) to the atmosphere by stimulated oxidation and higher Re; therefore, land-use and land management practices have clear effects on NEP, with potential repercussions on ecosystems. The recent demand for biofuels has changed land-use and cropping patterns, especially in Midwestern United States (Wilhelm and others, 2011). It is important to ensure the sustainability of these and other land uses and to assess the effects on NEP. Flux tower networks, such as AmeriFlux and FLUXNET, consist of a growing number of eddy covariance flux tower sites that provide a synoptic record of the exchange of carbon, water, and energy between the ecosystem and atmosphere at various temporal frequencies. These towers also detect and measure certain site characteristics, such as wind, temperature, precipitation, humidity, atmospheric pressure, soil features, and phenological progressions. Efforts are continuous to combine flux tower network data with remote sensing data to upscale the conditions observed at specific sites to a regional and, ultimately, worldwide scale. Data-driven regression tree models have the ability to incorporate flux tower records and remote sensing data to quantify exchanges of carbon with the atmosphere (Wylie and others, 2007; Xiao and others, 2010; Zhang and others, 2010; Zhang and others, 2011). Previous study results demonstrated the dramatic effect weather has on NEP and revealed specific ecoregions and times acting as carbon sinks or sources. As of 2012, more than 100 site-years of flux tower measurements, represented by more than 50 individual cropland or grassland sites throughout the Great Plains and surrounding area, have been acquired, quality controlled, and partitioned into gross photosynthesis (Pg) and ecosystem Re using detailed light-response, soil temperature, and vapor pressure deficit (VPD) based analysis.

Great Plains↗

Program for monitoring the chemical quality of ground water in Utah – Summary of data collected through 1984

The U.S. Geological Survey formally started a program for monitoring ground-water quality in Utah during 1957 in cooperation with the State of Utah. Most observation wells in the monitoring network are privately owned. Initially, the network consisted of fewer than 50 wells; by 1984, however, it had expanded to include more than 200 wells. Chemical analyses are available for water from some of the wells from as early as 1927, long before those wells were formally added to the network. The monitoring program was initiated to detect any changes in chemical quality that might be associated with the withdrawal of water from wells. Dissolved-solids concentrations in water samples collected from the observation wells through 1984 ranged from 92 to 19,000 milligrams per liter. An observation well in the Uinta Basin yielded the sample with the smallest dissolved-solids concentration, and another well in the Uinta Basin yielded the sample with the largest dissolved-solids concentration. There was a progressive increase in salinity of water produced by several of the observation wells in Pahvant Valley and in the Milford and Beryl-Enterprise areas. The increases in salinity occurred during 1950-84, coinciding with the decline of water levels due to pumping for irrigation. Water-quality changes related either to ground-water withdrawals or ground-water recharge also were detected in several other areas, including Curlew Valley, Cedar City Valley, Northern Utah Valley, the lower Bear River valley, and the Sevier Desert. Water produced from wells in Goshen Valley and the upper Fremont River valley had short term increases in chloride, sulfate, and dissolved-solids concentrations, indicating possible local contamination of the ground water. Also, since the late 1950's, dissolved-solids concentrations have increased in water produced by a well completed in the principal aquifer in Salt Lake Valley downgradient from areas where extensive use has been made of road salt.

Utah↗

Magma transfer at Campi Flegrei caldera (Italy) before the 1538 AD eruption

Calderas are collapse structures related to the emptying of magmatic reservoirs, often associated with large eruptions from long-lived magmatic systems. Understanding how magma is transferred from a magma reservoir to the surface before eruptions is a major challenge. Here we exploit the historical, archaeological and geological record of Campi Flegrei caldera to estimate the surface deformation preceding the Monte Nuovo eruption and investigate the shallow magma transfer. Our data suggest a progressive magma accumulation from ~1251 to 1536 in a 4.6 ± 0.9 km deep source below the caldera centre, and its transfer, between 1536 and 1538, to a 3.8 ± 0.6 km deep magmatic source ~4 km NW of the caldera centre, below Monte Nuovo; this peripheral source fed the eruption through a shallower source, 0.4 ± 0.3 km deep. This is the first reconstruction of pre-eruptive magma transfer at Campi Flegrei and corroborates the existence of a stationary oblate source, below the caldera centre, that has been feeding lateral eruptions for the last ~5 ka. Our results suggest: 1) repeated emplacement of magma through intrusions below the caldera centre; 2) occasional lateral transfer of magma feeding non-central eruptions within the caldera. Comparison with historical unrest at calderas worldwide suggests that this behavior is common.

Pozzuoli Bay↗

Summary appraisals of the nation's ground-water resources – Pacific Northwest region

The Pacific Northwest Region's ground-water reservoirs are capable of providing large additional fresh-water supplies; these reservoirs become more important as undeveloped surface-storage sites and unapportioned surface-water supplies dwindle. Withdrawals of fresh water from all surface and underground sources are increasing; they may rise from the rate of 30 billion gallons per day in 1970 to about 60 billion gallons per day in 2020. By 1975 the withdrawal of ground water had increased 70 percent over the 1970 rate and accounted for 22 percent of total fresh-water withdrawal. Substantial increases in ground-water withdrawal must continue if projected water demands are to be met in the future. Large variations exist in the availability of and needs for ground water in the region, largely because of the great variety of landforms, climate, and earth materials. More than one-half the region is underlain by rock materials capable of yielding ground water to wells at moderate to large rates; six extensive areas are identified as major ground-water reservoirs. The most significant current problems pertaining to one or more of these ground-water reservoirs are: (1) Progressively declining water levels; (2) water-quality problems; (3) waterlogging; (4) inadequate information; and (5) competition for available supplies. In the future these same problems are expected to persist and generally worsen (especially water-quality deterioration) in most of the major reservoir areas. Management opportunities in the region include: (1) Development of new supplies and additional uses of ground water; (2) protection and enhancement of water quality; (3) reduction of waterlogging; (4) energy development from some ground-water reservoirs; (5) improving access to the ground water; (6) increased use of underground space for storage and disposal; and (7) greater use of advanced management and conservation techniques. Conjunctive use of surface and ground water to provide greater available supplies probably is the most promising water-management opportunity. However, if the full potential of the ground-water resources is to be realized, important constraints, including present water-right structures and serious deficiencies in information, must be overcome.

Idaho, Montana, Oregon, Washington↗

Geologic controls on the formation of lakes in north-central Florida

Fluid exchange between surficial waters and groundwater, as well as the processes that control this exchange, are of critical concern to water management districts and planners. Digital high-resolution seismic systems were used to collect geophysical data from 30 lakes of north-central Florida. Although using seismic profile data in the past has been less than successful, the use of digital technology has increased the potential for success. Seismic profiles collected from the lakes of north-central Florida have shown the potential application of these techniques in understanding the formation of individual lakes. In each case study, lake structure and geomorphology were controlled by solution and/or mechanical processes. Processes that control lake development are twofold: 1) karstification or dissolution of the underlying limestone, and 2) me collapse, subsidence, or slumping of overburden to form sinkholes. Initial lake formation is directly related to the karst topography of the underlying host limestone. Lake size and shape are a factor of the thickness of overburden and size of the collapse or subsidence and/or clustering of depressions allowing for lake development. Lake development is through progressive sequence stages to maturity that can be delineated into geomorphic types. Case studies have shown that lakes can be divided by geomorphic types into progressive developmental phases: (1) active subsidence or collapse phase (young) - the open to partially filled collapse structures typically associated with sink holes; (2) transitional phase (middle age) - the sinkhole is plugged as the voids within the collapse are filled with sediment, periodic reactivation may occur; (3) baselevel phase (mature) - active sinkholes are progressively plugged by the continual erosion of material into the basin, and eventually sediment fills the basins; and (4) polje (drowned prairie) - broad flat-bottom basins located within the epiphreatic zone that are inundated at high stages of the water table and have one or all phases of sinkhole development and many types of karst and karren features. Most lakes in this study have a small diameter (<1 km) making stratigraphic correlations from lake to lake difficult. Seismic profiles of subsurface features were used to define the lake geologic history and to locate possible breaches in the confining layer that maintains these lakes. Nine types of acoustical signatures were identified from the profiles to describe the structural history of each lake. Using these criteria, Florida lakes can be classified by size, fill, subsurface features, and geomorphology. Classification of the lakes has led to a better understanding of the relation between the geology and hydrology of Florida.

Florida↗

Hayward Fault rocks: porosity, density, and strength measurements

Porosity, density and strength measurements were conducted on rock samples collected from the Hayward Fault region in Northern California as part of the Hayward Fault Working Group’s efforts to create a working model of the Hayward Fault. The rocks included in this study were both fine and coarse grained gabbros, altered keratophyre, basalt, sandstone, and serpentinite from various rock formations adjacent to the Hayward Fault. Densities ranged from a low of 2.25 gm/cc (altered keratophyre) to 3.05 gm/cc (fine gabbro), with an average of 2.6 gm/cc, typical of many other rocks. Porosities were generally around 1% or less, with the exception of the sandstone (7.6%) and altered keratophyre (13.5%). Failure and frictional sliding tests were conducted on intact rock cylinders at room temperature under effective pressure conditions of up to 192 MPa, simulating depths of burial to 12 km. Axial shortening of the samples progressed at a rate of 0.1 µm/sec (fine samples) or 0.2 µm/sec (porous samples) for 6 mm of displacement. Velocity stepping tests were then conducted for an additional 2 mm of displacement, for a total of 8 mm. Both peak strength (usually failure strength) and frictional strength, determined at 8 mm of displacement, increased systematically with effective pressure. Coefficients of friction, based on the observed fracture angles, ranged from 0.6 to 0.85, consistent with Byerlee’s Law. Possible secondary influences on the strength of the Hayward rock samples may be surface weathering, or a larger number of pre-existing fractures due to the proximity to the Hayward Fault. All samples showed velocity strengthening, so that the average a-b values were all strongly positive. There was no systematic relation between a-b values and effective pressure. Velocity strengthening behavior is associated with stable sliding (creep), as observed in the shallow portions of the Hayward Fault.

California↗

Geology and underground waters of the Arkansas Valley in eastern Colorado

In the valley of Arkansas River in southeastern Colorado there is an area of considerable extent in which artesian flows are available. During the last ten years numerous wells have been sunk to develop this important resource and, in most cases in the lower lands, abundant water supplies have been obtained. The principal water-bearing bed is the "Dakota" formation, which consists of two sheets of porous sandstone separated by a small body of clay and overlain in the greater portion of the area by a mass of impervious shales. The sandstones receive their waters from, rainfall and from the sinking of streams along the foothills of the Rocky Mountains and on some of the higher slopes south of the Arkansas Valley. In the passage of this sandstone underground, the waters which it contains are held down by the overlying shales, but, as some of the sandstone outcrops are at relatively low levels to the east only a moderate head or pressure is sustained. On account of this low head, artesian flows are available only in the lower lands, and one of the principal objects of this investigation has been the determination of the area in which flows are to be expected. The "Dakota" sandstone and associated formations do not lie level, or even slope regularly to the east, but are flexed into low arches and shallow troughs of considerable complexity of configuration. Accordingly, in investigating this source of water supply, it has been necessary to ascertain the structure and distribution of the various formations in order to indicate the variations in depth to the water-bearing stratum. The principal results of these investigations are set forth: (1) In the geologic map (Pl. VI), which shows the distribution of the formations on the surface; (2) in the map, Pl. XXV, which shows the depth to the water-bearing horizon, the area in which flows are expected, the head of the underground waters, and other features, and (3) in the cross sections (Pls. VII and XXIII), which show the principal underground features. The investigation has been in progress for several years and is an extension of the preliminary examination of the region by G. K. Gilbert in 1894 and 1895. For the western portion of the area the maps and texts of the Pueblo, Elmoro, Walsenburg, Spanish Peaks, and Pikes Peak folios have been utilized as far as practicable. For the central and eastern portions the larger features of the geology have been specially mapped, and considerable detailed mapping has been done in the region south and southeast of Canyon and Colorado Springs. In the field work I have been assisted by Mr. C. A. Fisher, who has examined in detail the Nepesta quadrangle and contributed numerous other data. Dr. W. S. Tangier Smith and Messrs. C. E. Sicbenthal and W. T. Lee have made observations in certain areas. Much valuable information respecting wells has been furnished by Mr. William Archer, of the Atchison, Topeka and Santa Fe Railway Company, and Mr. C. H. McVay, well driller at Rocky Ford.

Colorado↗

Recent (2008-10) water quality in the Barton Springs segment of the Edwards aquifer and its contributing zone, central Texas, with emphasis on factors affecting nutrients and bacteria

The Barton Springs zone, which comprises the Barton Springs segment of the Edwards aquifer and the watersheds to the west that contribute to its recharge, is in south-central Texas, an area with rapid growth in population and increasing amounts of land area affected by development. During November 2008-March 2010, an investigation of factors affecting the fate and transport of nutrients and bacteria in the Barton Springs zone was conducted by the U.S. Geological Survey (USGS), in cooperation with the Texas Commission on Environmental Quality. The primary objectives of the study were to characterize occurrence of nutrients and bacteria in the Barton Springs zone under a range of flow conditions; to improve understanding of the interaction between surface-water quality and groundwater quality; and to evaluate how factors such as streamflow variability and dilution affect the fate and transport of nutrients and bacteria in the Barton Springs zone. The USGS collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge and Buda), and the main orifice of Barton Springs in Austin, Texas. During the period of the study, during which the hydrologic conditions transitioned from exceptional drought to wetter than normal, water samples were collected routinely (every 3 to 4 weeks) from the streams, wells, and spring and, in response to storms, from the streams and spring. All samples were analyzed for major ions, nutrients, the bacterium Escherichia coli, and suspended sediment. During the dry period, the geochemistry of groundwater at the two wells and at Barton Springs was dominated by flow from the aquifer matrix and was relatively similar and unchanging at the three sites. At the onset of the wet period, when the streams began to flow, the geochemistry of groundwater samples from the Marbridge well and Barton Springs changed rapidly, and concentrations of most major ions and nutrients and densities of Escherichia coli became more similar to those of samples from the streams relative to concentrations and densities during the dry period. Geochemical modeling indicated that the proportion of Barton Springs discharge composed of stream recharge increased from about 0-8 percent during the dry period to about 80 percent during the wet period. The transition from exceptional drought to wetter-than-normal conditions resulted in a number of marked changes that highlight factors affecting the fate and transport of nutrients and bacteria and the strong influence of stream recharge on water quality in the Barton Springs segment of the Edwards aquifer and had a pronounced effect on the fate of nitrogen species. Organic nitrogen loaded to and stored in soils during the dry period was nitrified to nitrate when the soils were rewetted, resulting in elevated concentrations of nitrate plus nitrite in streams as these constituents were progressively leached during continued wet weather. Estimated mean monthly loads of organic nitrogen and nitrate plus nitrite in stream recharge and Barton Springs discharge, which were relatively low and constant during the dry period, increased during the wet period. Loads of organic nitrogen, on average, were about six times greater in stream recharge than in Barton Springs discharge, indicating that organic nitrogen likely was being converted to nitrate within the aquifer. Loads of total nitrogen (organic nitrogen plus ammonia and nitrate plus nitrite) in stream recharge (162 kilograms per day) and in Barton Springs discharge (157 kilograms per day) for the period of the investigation were not significantly different. Dilution was not an important factor affecting concentrations of nitrate plus nitrite in the streams or in Barton Springs during the period of this investigation: Concentrations of nitrate plus nitrite did not decrease in streams with increasing stream discharge, and nitrate plus nitrite concentrations measured at Barton

Scientific Investigations Report↗

Mathematical model of San Juan Valley ground-water basin, San Benito County, California

A mathematical model study of the San Juan Valley ground-water basin in San Benito County, Calif., has quantitatively described the ground-water hydrology of the basin under past, present, and future conditions of development. An analysis of conditions in the basin prior to large-scale ground-water development indicates that net recharge equaled 9.23 cubic feet per second and occurred as subsurface flow to the eastern part of the basin and infiltration of rain, direct runoff, and minor streamflows. Net predevelopment discharge equaled 9.23 cubic feet per second and occurred as aquifer discharge to the San Benito River. The 9.23 cubic feet per second of predevelopment recharge is considered to be perennial recharge to the basin. Large-scale ground-water development occurred in the area during the period 1945-68 and caused water levels to decline throughout most of the basin. Progressive depletion of aquifer storage during this period changed the San Benito River from a gaining (perennial) stream to a losing stream along most of its reach in the basin area. Net discharge from the basin during the period 1945-68 averaged 18.10 cubic feet per second. Of this amount 17.82 cubic feet per second occurred as pumpage from wells, and 0.28 cubic foot per second occurred as basin discharge to the San Benito River. Net recharge to the basin during the same period averaged 13.57 cubic feet per second. Of this amount 4.34 cubic feet per second occurred as infiltration from the San Benito River and 9.23 cubic feet per second occurred as perennial recharge. Use of the calibrated mathematical model to simulate quantities of imported water entering the basin from the San Benito River indicates that water levels in San Juan Valley will stabilize or recover when additional recharge equals or exceeds 3,000 acre-feet per year.

California↗

Chemical, physical, and radiological quality of selected public water supplies in Florida : January-May 1979

Verde Valley--an area of complex geology where the crust of the North American plate changes from unstable to stable--is in central Arizona in the transition zone between the Basin and Range and the Colorado Plateaus tectonic provinces. Volcanism and tectonism have been progressing northeastward along the transition zone for about 20 million years. The Verde Hot Springs area is the focal point of the intersection of three major lineaments. More than 100 water samples were collected from wells and springs in the valley, and temperatures of the potential geothermal resources were calculated using two geochemical methods or geothermometers--silica and Na-K-Ca geothermometers. Because of the high concentration of dissolved magnesium in the ground water, the silica geotemperatures are considered to be more reliable than the Na-K-Ca geotemperatures. The Camp Verde and Verde Hot Springs areas contain ground water that has quartz-silica geotemperatures of between 99 and 135C and chalcedony-silica geotemperatures of between 73 and 111C. The geochemical evidence to substantiate a geothermal resource in Verde Valley is not conclusive, and further work including test drilling, should be done to verify the silica geotemperatures given in the map. (Kosco-USGS)

Water-Resources Investigations Report↗

Magmatic evolution of the Gulf of California rift

Magmatic events in the Baja peninsula-Gulf of California region are closely related to sequential tectonic regimes of: (1) late Tertiary subduction beneath the continental margin until ~16 to 12.5 Ma; and (2) continental to oceanic rifting that began about 13 Ma. Orogenic calcalkaline volcanic rocks formed subparallel belts of rhyolite ignimbrite of Oligocene age (~34 to 27 Ma) east of the Gulf in the Sierra Madre Occidental and andesite of Miocene age (~24 to 11 Ma) along the eastern Baja peninsula. Shutoff of the Miocene andesitic arc broadly corresponds to migration of the Pacific-Farallon (Guadalupe)-North America triple junction along the Baja peninsula. Orogenic andesitic volcanism ended at ~16 Ma in northern Baja, and at ~11 Ma in southern Baja, within ~1 to 2 Ma of cessation of subduction. Waning orogenic magmatism persisted along the southern Baja peninsula during the initial stages of rifting. Paleogeographic implications of the distribution of circum-Gulf volcanic rocks and their inferred easterly source areas suggest that, from about 13 to 8 Ma, the rift consisted of a narrow seaway along the eastern side of the present Gulf. By about 6 Ma, the Gulf had broadened westward to approximately its present width. The period from 13 to 10 Ma was a time of tectonic transition and magmatic diversity. During this interval, medium-K calcalkaline, high-K calcalkaline, alkalic, and tholeiitic magmas erupted from the central to southern part of the Baja peninsula-Gulf region, and from about 14 to 8 Ma, rhyolite ignimbrite erupted in the northern Gulf region. Since 10 Ma, volcanism on the western Baja peninsula has been dominated by alkalic magmas, the Gulf margins by calcalkaline magmas, and the Gulf by tholeiitic magmas. Postsubduction calcalkaline andesite to rhyolite erupted sporadically and locally along the northern Gulf margins from ~9 Ma through Holocene time. Alkalic magmas associated with rifting in the Gulf of California are unlike alkalic magmas from intraplate settings. They comprise nepheline- to quartz-normative, basaltic to andesitic rocks characterized by diverse trace element ratios. They are broadly similar to intraplate alkalic rocks in having high K, P, Ba, Sr and the light REE (rare earth elements), but have some trace element characteristics typical of orogenic magmas (low Nb and Ta relative to K, Ba, Sr, and La) that distinguish these alkalic rocks from intraplate or cratonic rift alkalic rocks. Rb abundances (mostly <25 ppm, as low as 5 ppm) are unusually low in these alkalic rocks, both in contrast to the high K (~1.7-4.1 wt% K 2 O), Ba (~800-2200 ppm), and Sr (~1000-3700 ppm), and in comparison to Rb abundances in mafic lavas in general; many samples have Rb at levels typically found in low-K tholeiites. The high K/Rb ratios, mostly ~1000 to 5000, are among the highest reported for any lavas. Samples ranging in SiO 2 from 48 to 61% have Mg’ ≥ 65, indicating that a broad range of compositions may represent primary melts. The generally high Mg’, and the low Rb, Th, Nb, and Ta in some lavas, suggest that depleted refractory mantle equivalent to a mid-ocean ridge basalt (MORB) source contributed to these melts. The distinctive trace element enrichments are attributed to the stabilization in the source of amphibole and apatite from metasomatic fluids related to prior subduction beneath the peninsula. In discrimination diagrams, these alkalic rocks typically cluster outside previously defined fields for various magma types. The common tectonic setting among these and geochemically similar alkalic suites is the occurrence in a continental margin that is undergoing extension, located along a recently or currently active convergent plate boundary. Tholeiitic basalts have erupted since the earliest stages of continental rifting through development of oceanic spreading centers. Gulf of California tholeiites exhibit an evolution distinguished particularly by differences in rare-earth-element (REE) abundances. Early-rift magmas are similar in trace element geochemistry to some intraplate tholeiites from ocean islands and continental flood basalts, and have convex-upward REE patterns. The most recent tholeiites from the East Pacific Rise in the mouth of the Gulf are equivalent to N-MORB (normal mid-ocean ridge basalt) from other mid-ocean rifts, and are depleted in the light-REE. The transition in tholeiite geochemistry from intraplate tholeiite to MORB is attributed to progressive fusion of more refractory mantle components. Incipient-rift tholeiites are derived from selective fusion of clinopyroxenite veins, and with continued melting, N-MORB are formed by fusion of peridotite. This tholeiite sequence reflects the evolution of mantle source regions in rifts that sustain an ensialic to oceanic transition.

Baja California, Baja California Sur↗

Lithic breccia and ignimbrite erupted during the collapse of Crater Lake Caldera, Oregon

The climactic eruption of Mount Mazama (6845 y.B.P.) vented a total of ∼50 km 3 of compositionally zoned rhyodacitic to basaltic magma from: (a) a single vent as a Plinian pumice fall deposit and the overlying Wineglass Welded Tuff, and (b) ring vents as ignimbrite and coignimbrite lithic breccia accompanying the collapse of Crater Lake caldera. New field and grain-size data for the ring-vent products are presented in this report. The coarse-grained, poorly bedded, clast-supported lithic breccia extends as far as 18 km from the caldera center. Like the associated ignimbrite, the breccia is compositionally zoned both radially and vertically, and silicic, mixed, and mafic types can be recognized, based on the proportion of rhyodacitic pumice. Matrix fractions in silicic breccias are depleted of fines and are lithic- and crystal-enriched relative to silicic ignimbrite due to vigorous gas sorting during emplacement. Ignimbrite occurs as a proximal veneer deposit overlying the breccia, a medial (∼ 8 to ∼ 25 km from the caldera center), compositionally zoned valley fill as much as > 110 m thick, and an unzoned distal (⪖ 20 km) facies which extends as far as 55 km from the caldera. Breccia within ∼ 9 km of the caldera center is interpreted as a coignimbrite lag breccia formed within the deflation zone of the collapsing ring-vent eruption columns. Expanded pyroclastic flows of the deflation zone were probably vertically graded in both size and concentration of blocks, as recently postulated for some turbidity currents. An inflection in the rate of falloff of lithic-clast size within the lithic breccia at ∼ 9 km may mark the outer edge of the deflation zone or may be an artifact of incomplete exposure. The onset of ring-vent activity at Mt. Mazama was accompanied by a marked increase in eruptive discharge. Pyroclastic flows were emplaced as a semicontinuous stream, as few ignimbrite flow-unit boundaries are evident. As eruption from the ring vents progressed, flow-runout distance and the extent of breccia deposition decreased due to (a) greater internal flow friction, and (b) decreasing eruption column heights. Effect (b) probably resulted from a progressive decrease in magmatic gas content and discharge rate. Waning discharge may have been promoted by the tapping of more viscous, crystal-rich magma, collapse of conduit walls, and declining caldera collapse rate.

Oregon↗

An assessment of volcanic threat and monitoring capabilities in the United States: Framework for a National Volcano Early Warning System

Executive Summary NVEWS – a National Volcano Early Warning System – is being formulated by the Consortium of U.S. Volcano Observatories (CUSVO) to establish a proactive, fully integrated, national-scale monitoring effort that ensures the most threatening volcanoes in the United States are properly monitored in advance of the onset of unrest and at levels commensurate with the threats posed. Volcanic threat is the combination of hazards (the destructive natural phenomena produced by a volcano) and exposure (people and property at risk from the hazards). The United States has abundant volcanoes, and over the past 25 years the Nation has experienced a diverse range of the destructive phenomena that volcanoes can produce. Hazardous volcanic activity will continue to occur, and – because of increasing population, increasing development, and expanding national and international air traffic over volcanic regions – the exposure of human life and enterprise to volcano hazards is increasing. Fortunately, volcanoes exhibit precursory unrest that if detected and analyzed in time allows eruptions to be anticipated and communities at risk to be forewarned with reliable information in sufficient time to implement response plans and mitigation measures. In the 25 years since the cataclysmic eruption of Mount St. Helens, scientific and technological advances in volcanology have been used to develop and test models of volcanic behavior and to make reliable forecasts of expected activity a reality. Until now, these technologies and methods have been applied on an ad hoc basis to volcanoes showing signs of activity. However, waiting to deploy a robust, modern monitoring effort until a hazardous volcano awakens and an unrest crisis begins is socially and scientifically unsatisfactory because it forces scientists, civil authorities, citizens, and businesses into “playing catch up” with the volcano, trying to get instruments and civil-defense measures in place before the unrest escalates and the situation worsens. Inevitably, this manner of response results in our missing crucial early stages of the volcanic unrest and hampers our ability to accurately forecast events. Restless volcanoes do not always progress to eruption; nevertheless, monitoring is necessary in such cases to minimize either over-reacting, which costs money, or under-reacting, which may cost lives. Volcano monitoring in the U.S. is conducted by five volcano observatories, supported primarily by the USGS Volcano Hazards Program. Under the Stafford Act, the USGS is responsible for issuing timely warnings of potential volcanic disasters to the affected populace and civil authorities. To make maximum use of the Nation’s scientific resources, the USGS operates the observatories with the help of universities and other governmental agencies, through formal partnerships. At present, about half of the most threatening U.S. volcanoes are monitored at a basic level with real-time sensors (primarily seismic arrays), and a few are well monitored with a suite of modern instrument types and methods. However, monitoring capabilities at many hazardous volcanoes are known to be sparse or antiquated, and some hazardous volcanoes have no ground-based monitoring whatsoever.

Marianas Islands↗

Break-up of Gondwana and opening of the South Atlantic: Review of existing plate tectonic models

The opening history of both the Weddell Sea and South Atlantic Ocean is critical to understanding the break- up of Gondwana and the evolution of Antarctica since Early Jurassic times. The dispersal of the Gondwanide fragments is important to understanding the development of past ocean circulation. Unfortunately the tectonics of the Weddell Sea region is difficult to resolve because of the paucity of data coverage and the region’s inherent complexity. Although considerable progress has been achieved in the past 20 years with new marine aeromagnetic data and satellite derived gravity anomaly maps, there are still several models in consideration which differ in crustal ages and schemes of opening. In this paper we present a review of four of those models. Focusing on poles of rotation, synthetic isochrons and flowlines, we proceed backward in time beginning at Chron 34 (83.5 Ma), as it is relatively well defined ocean wide, and present crustal age maps that display the estimated trace of the South America-Antarctica-Africa triple junction for each model. We also plot reconstructions at four selected epochs for all models using the same projection and scale to facilitate comparison. The diverse simplifying assumptions that need to be made in every case regarding plate fragmentation to account for the numerous syn-rift basins and periods of stretching are strong indicators that rigid plate tectonics is too simple a model for the present problem.

Open-File Report↗

Appraisal of shallow ground-water resources, Pueblo Army Depot, Colorado

The water supply for the Pueblo Army Depot, 15 miles wast of Pueblo, Colo., is obtained from wells that tap an aquifer in terrace alluvium. Withdrawals have resulted in a water-level decline of 27 feet, which adversely affects the discharge rate of individual wells. Furthermore, excessive pumpage has resulted in progressive deterioration of water quality. Over a 20-year period, hardness has increased from 70 milligrams per liter to 135 milligrams per liter and dissolved-solids content has increased from 250 milligrams per liter to 370 milligrams per liter. Two new supply wells were drilled in the southern part of the Depot and were tested to determine aquifer properties and probable production rate. The hydraulic conductivity determined from these tests ranged from about 350 to nearly 600 gallons per day per square foot. The transmissivity for the full thickness of the aquifer is in the range of 7,500 to 12,000 gallons per day per foot.<.p> The two new supply wells can be pumped at a combined rate of about 140 gallons per minute. If pumpage in the existing well field is reduced by the same amount, some recovery of water levels in the field will occur and the trend in water quality deterioration may slow or even reverse.

Colorado↗