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Environmental controls on water quality: Case studies from Battle Mountain mining district, north-central Nevada

The environmental controls on water quality were the focus of our study in a portion of the Battle Mountain mining district, north-central Nevada. Samples representing areas outside known mineralized areas, in undisturbed mineralized areas, and in mined areas were chemically and isotopically analyzed. The results are related to geologic, hydrologic, and climatic data. Streams in background areas outside the mineralized zones reflect normal weathering of volcanically derived rocks. The waters are generally dilute, slightly alkaline in pH, and very low in metals. As these streams flow into mineralized zones, their character changes. In undisturbed mineralized areas, discharge into streams of ground water through hydrologically conductive fractures can be traced with chemistry and, even more effectively, with sulfur isotopic composition of dissolved sulfate. Generally, these tracers are much more subtle than in those areas where mining has produced adits and mine-waste piles. The influence of drainage from these mining relicts on water quality is often dramatic, especially in unusually wet conditions. In one heavily mined area, we were able to show that the unusually wet weather in the winter and spring greatly degraded water quality. Addition of calcite to the acid, metalrich mine drainage raised the stream pH and nearly quantitatively removed the metals through coprecipitation and (or) adsorption onto oxyhydroxides. This paper is divided into four case studies used to demonstrate our results. Each addresses the role of geology, hydrology, mining activity and (or) local climate on water quality. Collectively, they provide a comprehensive look at the important factors affecting water quality in this portion of the Battle Mountain mining district.

Nevada↗

Development of a precipitation-runoff model to simulate unregulated streamflow in the South Fork Flathead River Basin, Montana

This report documents the development of a precipitation-runoff model for the South Fork Flathead River Basin, Mont. The Precipitation-Runoff Modeling System model, developed in cooperation with the Bureau of Reclamation, can be used to simulate daily mean unregulated streamflow upstream and downstream from Hungry Horse Reservoir for water-resources planning. Two input files are required to run the model. The time-series data file contains daily precipitation data and daily minimum and maximum air-temperature data from climate stations in and near the South Fork Flathead River Basin. The parameter file contains values of parameters that describe the basin topography, the flow network, the distribution of the precipitation and temperature data, and the hydrologic characteristics of the basin soils and vegetation. A primary-parameter file was created for simulating streamflow during the study period (water years 1967-2005). The model was calibrated for water years 1991-2005 using the primary-parameter file. This calibration was further refined using snow-covered area data for water years 2001-05. The model then was tested for water years 1967-90. Calibration targets included mean monthly and daily mean unregulated streamflow upstream from Hungry Horse Reservoir, mean monthly unregulated streamflow downstream from Hungry Horse Reservoir, basin mean monthly solar radiation and potential evapotranspiration, and daily snapshots of basin snow-covered area. Simulated streamflow generally was in better agreement with observed streamflow at the upstream gage than at the downstream gage. Upstream from the reservoir, simulated mean annual streamflow was within 0.0 percent of observed mean annual streamflow for the calibration period and was about 2 percent higher than observed mean annual streamflow for the test period. Simulated mean April-July streamflow upstream from the reservoir was about 1 percent lower than observed streamflow for the calibration period and about 4 percent higher than observed for the test period. Downstream from the reservoir, simulated mean annual streamflow was 17 percent lower than observed streamflow for the calibration period and 12 percent lower than observed streamflow for the test period. Simulated mean April-July streamflow downstream from the reservoir was 13 percent lower than observed streamflow for the calibration period and 6 percent lower than observed streamflow for the test period. Calibrating to solar radiation, potential evapotranspiration, and snow-covered area improved the model representation of evapotranspiration, snow accumulation, and snowmelt processes. Simulated basin mean monthly solar radiation values for both the calibration and test periods were within 9 percent of observed values except during the month of December (28 percent different). Simulated basin potential evapotranspiration values for both the calibration and test periods were within 10 percent of observed values except during the months of January (100 percent different) and February (13 percent different). The larger percent errors in simulated potential evaporation occurred in the winter months when observed potential evapotranspiration values were very small; in January the observed value was 0.000 inches and in February the observed value was 0.009 inches. Simulated start of melting of the snowpack occurred at about the same time as observed start of melting. The simulated snowpack accumulated to 90-100 percent snow-covered area 1 to 3 months earlier than observed snowpack. This overestimated snowpack during the winter corresponded to underestimated streamflow during the same period. In addition to the primary-parameter file, four other parameter files were created: for a "recent" period (1991-2005), a historical period (1967-90), a "wet" period (1989-97), and a "dry" period (1998-2005). For each data file of projected precipitation and air temperature, a single parameter file can be used to simulate a s

Montana;Idaho↗

A comprehensive evaluation of two MODIS evapotranspiration products over the conterminous United States: using point and gridded FLUXNET and water balance ET

Remote sensing datasets are increasingly being used to provide spatially explicit large scale evapotranspiration (ET) estimates. Extensive evaluation of such large scale estimates is necessary before they can be used in various applications. In this study, two monthly MODIS 1 km ET products, MODIS global ET (MOD16) and Operational Simplified Surface Energy Balance (SSEBop) ET, are validated over the conterminous United States at both point and basin scales. Point scale validation was performed using eddy covariance FLUXNET ET (FLET) data (2001–2007) aggregated by year, land cover, elevation and climate zone. Basin scale validation was performed using annual gridded FLUXNET ET (GFET) and annual basin water balance ET (WBET) data aggregated by various hydrologic unit code (HUC) levels. Point scale validation using monthly data aggregated by years revealed that the MOD16 ET and SSEBop ET products showed overall comparable annual accuracies. For most land cover types, both ET products showed comparable results. However, SSEBop showed higher performance for Grassland and Forest classes; MOD16 showed improved performance in the Woody Savanna class. Accuracy of both the ET products was also found to be comparable over different climate zones. However, SSEBop data showed higher skill score across the climate zones covering the western United States. Validation results at different HUC levels over 2000–2011 using GFET as a reference indicate higher accuracies for MOD16 ET data. MOD16, SSEBop and GFET data were validated against WBET (2000–2009), and results indicate that both MOD16 and SSEBop ET matched the accuracies of the global GFET dataset at different HUC levels. Our results indicate that both MODIS ET products effectively reproduced basin scale ET response (up to 25% uncertainty) compared to CONUS-wide point-based ET response (up to 50–60% uncertainty) illustrating the reliability of MODIS ET products for basin-scale ET estimation. Results from this research would guide the additional parameter refinement required for the MOD16 and SSEBop algorithms in order to further improve their accuracy and performance for agro-hydrologic applications.

Remote Sensing of Environment↗

Availability, sustainability, and suitability of ground water, Rogers Mesa, Delta County, Colorado: Types of analyses and data for use in subdivision water-supply reports

The population of Delta County, Colorado, like that in much of the Western United States, is forecast to increase substantially in the next few decades. A substantial portion of the increased population likely will reside in rural subdivisions and use residential wells for domestic water supplies. In Colorado, a subdivision developer is required to submit a water-supply plan through the county for approval by the Colorado Division of Water Resources. If the water supply is to be provided by wells, the water-supply plan must include a water-supply report. The water-supply report demonstrates the availability, sustainability, and suitability of the water supply for the proposed subdivision. During 2006, the U.S. Geological Survey, in cooperation with Delta County, Colorado, began a study to develop criteria that the Delta County Land Use Department can use to evaluate water-supply reports for proposed subdivisions. A table was prepared that lists the types of analyses and data that may be needed in a water-supply report for a water-supply plan that proposes the use of ground water. A preliminary analysis of the availability, sustainability, and suitability of the ground-water resources of Rogers Mesa, Delta County, Colorado, was prepared for a hypothetical subdivision to demonstrate hydrologic analyses and data that may be needed for water-supply reports for proposed subdivisions. Rogers Mesa is a 12-square-mile upland mesa located along the north side of the North Fork Gunnison River about 15 miles east of Delta, Colorado. The principal land use on Rogers Mesa is irrigated agriculture, with about 5,651 acres of irrigated cropland, grass pasture, and orchards. The principal source of irrigation water is surface water diverted from the North Fork Gunnison River and Leroux Creek. The estimated area of platted subdivisions on or partially on Rogers Mesa in 2007 was about 4,792 acres of which about 2,756 acres was irrigated land in 2000. The principal aquifer on Rogers Mesa consists of alluvial-fan deposits that overlie shale and, locally, sandstone. Maps of the base of the aquifer, the water table, and the saturated thickness of the aquifer were prepared from data from the well files of the Colorado Division of Water Resources. The base of the aquifer generally is topographically higher than the valleys of the North Fork Gunnison River and Leroux Creek, and direct hydraulic connection of the aquifer to North Fork Gunnison River and Leroux Creek is limited. The aquifer is recharged primarily by infiltration of surface water diverted for irrigation. Ground water discharges to seeps and springs and through slope deposits at the boundaries of the aquifer. Data from the well files also were used to estimate the specific capacity of wells and to estimate the transmissivity and hydraulic conductivity of the aquifer. A water budget was used to estimate recharge to and discharge from the aquifer. Although storage within the aquifer likely varies seasonally and from year to year, it was assumed that there were no long-term changes in ground-water storage. Estimated average annual recharge to and discharge from the aquifer during November 1998 through October 2006 were about 30,767 acre-feet per year. Although sufficient ground water is available on Rogers Mesa for additional domestic water supplies, conversion of irrigated land to residential land use likely would reduce recharge to the aquifer, affecting the sustainability of ground-water supplies on Rogers Mesa. Stream-depletion analyses indicate that the ground water in the aquifer likely would be considered tributary ground water and additional uses of ground water to supply new subdivisions likely would require implementation of augmentation plans. Although sufficient ground water is available on Rogers Mesa for additional domestic water supplies, conversion of irrigated land to residential land use likely would reduce recharge to the aquifer, affecting the sustainability of ground-water supplies on Rogers Mesa. Stream-depletion analyses indicate that the ground water in the aquifer likely would be considered tributary ground water and additional uses of ground water to supply new subdivisions likely would require implementation of augmentation plans. Although the dissolved solids and dissolved sulfate concentrations in ground water from Rogers Mesa aquifer commonly exceeded the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels for drinking-water supplies, the quality of ground water from the aquifer generally is suitable for residential use. Concentrations of total nitrogen (nitrite plus nitrate, as nitrogen) in ground water ranged from 0.38 to 3.2 milligrams per liter and were less than the State of Colorado maximum contaminant level of 10 milligrams per liter. Concentrations of selenium from seeps and springs at the boundaries of the aquifer commonly exceeded 50 micrograms per liter, the State of Colorado maximum contaminant level for drinking-water supplies. This preliminary evaluation of ground-water supplies on Rogers Mesa could be improved with the collection of additional data including: additional mapping of hydrogeologic features; more accurate locations and altitudes of wells; accurate estimates of water-budget components; measurements of ground-water levels; and collection and analyses of ground-water samples. The use of numerical models of ground-water flow could improve evaluations of the potential effects of changes in land and water use on the water budget, aquifer storage, stream depletion, and well interference.

Colorado↗

Preliminary geochemical assessment of water in selected streams, springs, and caves in the Upper Baker and Snake Creek drainages in Great Basin National Park, Nevada, 2009

Water in caves, discharging from springs, and flowing in streams in the upper Baker and Snake Creek drainages are important natural resources in Great Basin National Park, Nevada. Water and rock samples were collected from 15 sites during February 2009 as part of a series of investigations evaluating the potential for water resource depletion in the park resulting from the current and proposed groundwater withdrawals. This report summarizes general geochemical characteristics of water samples collected from the upper Baker and Snake Creek drainages for eventual use in evaluating possible hydrologic connections between the streams and selected caves and springs discharging in limestone terrain within each watershed. Generally, water discharging from selected springs in the upper Baker and Snake Creek watersheds is relatively young and, in some cases, has similar chemical characteristics to water collected from associated streams. In the upper Baker Creek drainage, geochemical data suggest possible hydrologic connections between Baker Creek and selected springs and caves along it. The analytical results for water samples collected from Wheelers Deep and Model Caves show characteristics similar to those from Baker Creek, suggesting a hydrologic connection between the creek and caves, a finding previously documented by other researchers. Generally, geochemical evidence does not support a connection between water flowing in Pole Canyon Creek to that in Model Cave, at least not to any appreciable extent. The water sample collected from Rosethorn Spring had relatively high concentrations of many of the constituents sampled as part of this study. This finding was expected as the water from the spring travelled through alluvium prior to being discharged at the surface and, as a result, was provided the opportunity to interact with soil minerals with which it came into contact. Isotopic evidence does not preclude a connection between Baker Creek and the water discharging from Rosethorn Spring. The residence time of water discharging into the caves and from selected springs sampled as part of this study ranged from 10 to 25 years. Within the upper Snake Creek drainage, the results of this study show geochemical similarities between Snake Creek and Outhouse Spring, Spring Creek Spring, and Squirrel Spring Cave. The strontium isotope ratio ( 87 Sr/ 86 Sr) for intrusive rock samples representative of the Snake Creek drainage were similar to carbonate rock samples. The water sample collected from Snake Creek at the pipeline discharge point had lower strontium concentrations than the sample downstream and a similar 87 Sr/ 86 Sr value as the carbonate and intrusive rocks. The chemistry of the water sample was considered representative of upstream conditions in Snake Creek and indicates minimal influence of rock dissolution. The results of this study suggest that water discharging from Outlet Spring is not hydrologically connected to Snake Creek but rather is recharged at high altitude(s) within the Snake Creek drainage. These findings for Outlet Spring largely stem from the relatively high specific conductance and chloride concentration, the lightest deuterium (δD) and oxygen-18 (δ 18 O) values, and the longest calculated residence time (60 to 90 years) relative to any other sample collected as part of this study. With the exception of water sampled from Outlet Spring, the residence time of water discharging into Squirrel Spring Cave and selected springs in the upper Snake Creek drainage was less than 30 years.

Nevada↗

Hydrogeology and Ground-Water Quality of Brunswick County, North Carolina

Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydrogeologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers. All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County. In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system. The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply for the county. The upper part of the Peedee aquifer is an important source of ground-water supply for domestic and commercial use. Ground water in the lower part of the Peedee aquifer and the underlying aquifers is brackish and is not known to be used as a source of supply in Brunswick County. Most of the precipitation that recharges the surficial aquifer is discharged to local streams that drain into the Waccamaw River, Cape Fear River, and Atlantic Ocean. Recharge to the Castle Hayne aquifer occurs primarily from the surficial aquifer. Recharge to the Peedee aquifer occurs primarily from the surficial and Castle Hayne aquifers, with some upward leakage of water also occurring from the underlying Black Creek aquifer. Discharge from the Castle Hayne and Peedee aquifers occurs to local streams, the Cape Fear River, and the Atlantic Ocean. Evaluation of water-level data for the period January 1970 through May 2002 indicated no apparent long-term temporal trends in water levels in the surficial and Castle Hayne aquifers and in the upper part of the Peedee aquifer. The most significant water-level trends were noted for wells tapping the lower part of the Peedee aquifer and tapping the Black Creek aquifer where water levels have declined as much as 41 and 37 feet, respectively. These ground-water-level declines are attributed to regional ground-water pumping in areas outside of Brunswick County. Water-level data for Brunswick County wells tapping the upper Cape Fear and lower Cape Fear aquifers tend to fluctuate within a fairly uniform range with no apparent temporal trend noted. Analysis of vertical hydraulic gradients during this same period primarily indicate downward flow of ground water within and among the surficial, Castle Hayne, and Peedee aquifers. The vertical flow of ground water in the Black Creek aquifer is upward into the overlying Peedee aquifer. Upward flow also is noted for the upper and lower Cape Fear aquifers. Historic and recent analytic data were evaluated to better understand the sources of water contained in Brunswick County aquifers and the suitability of the water for consumption. Based on analytical results obtained for recent samples collected during this study, ground water from the surficial aquifer, Castle Hayne aquifer, and upper part of the Peedee aquifer appears to be generally suitable for drinking water. Although concentrations of iron and manganese commonly exceeded the drinking-water standards, the concern generally associated with the occurrence of these analytes in a water supply is one of aesthetics. In all samples, nitrate, nitrite, and sulfate were detected at concentrations less than drinkingwater standards. Based on historic analytical data, the brackish water in the lower part of the Peedee aquifer and in the Black Creek, upper Cape Fear, and lower Cape Fear aquifers is classified as a sodium-chloride type water. The presence of brackish water in these deeper systems combined with upward vertical gradients presents the potential for upward migration of brackish water into overlying aquifers, or upconing beneath areas of pumping. The current (2001) location of the boundary between freshwater and brackish water in Brunswick County aquifers is unknown.

North Carolina↗

Evaluation of mean-monthly streamflow-regression equations for Colorado, 2014

The U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board, evaluated the predictive uncertainty of mean-monthly streamflow-regression equations representative of natural streamflow conditions in Colorado. This study evaluates the predictive uncertainty of mean-monthly streamflow-regression equations developed in a 2009 U.S. Geological Survey study using streamflow data collected over the entire period of record at each streamgage through calendar year 2013. The study area for this report is limited to the Mountain, Northwest, Rio Grande, and Southwest hydrologic regions of Colorado. Data collected from the beginning of the period of record through calendar year 2013 were used to evaluate the mean-monthly streamflow equations using the same basin characteristics as in the 2009 study. U.S. Geological Survey and Colorado Division of Water Resources streamgages with at least 10 years of streamflow record and identified as representative of natural streamflow conditions were selected for this study. During the streamgage selection process, a total of 432 streamgages, composed of 278 from the 2009 study and 154 new streamgages, were identified. The updated standard error of prediction and adjusted coefficient of determination values that correspond to the mean-monthly streamflow equations developed in the 2009 study are in close agreement with the results of this study. The old streamgages performed slightly better than the new streamgages, with approximately 88 and 85 percent of the data within the prediction intervals, respectively. This result was expected because the streamgages used to develop the regression equations should yield a better performance than the new streamgages. For all hydrologic regions, approximately 87 percent of the data are within the 95-percent prediction intervals. The explanation for why fewer than 95 percent of the data are within the prediction intervals is that the data do not conform perfectly to the regression assumptions required to accurately estimate performance metrics. The equations for the Rio Grande hydrologic region had the best fit with the parametric prediction-interval assumptions, with approximately 91.8 percent of the data within the prediction interval (average 12 months). The Mountain, Northwest, and Southwest hydrologic regions had 87.8, 84.9, and 83.5 percent of the data contained within the prediction interval, respectively. Monthly adjusted coefficient of determination values were computed and have the same general pattern for all four hydrologic regions. The largest values usually occur in March or April, and the lowest values usually occur in August or September. Only the Rio Grande hydrologic region deviates from this seasonal pattern, exhibiting a decrease in adjusted coefficient of determination values in August and September, with the lowest values occurring in the winter months (December, January, and February). Generally, the adjusted coefficient of determination values for this report are just slightly less (0.76 compared to 0.79) than the values computed in the 2009 study. The similarity of values, even when tested with data not used to originally develop the mean-monthly streamflow-regression equations, provides confidence that the predictive uncertainty of mean-monthly regression equations in the 2009 study are accurate. The fact that the results for the two datasets are very similar provides assurance that when these equations are applied to locations not used to develop the equations, the standard error of prediction and adjusted-coefficient of determination error metrics should be similar to those established in the 2009 study for locations with natural streamflow. The median absolute differences between the observed and computed mean-monthly streamflow for Mountain, Northwest, and Southwest hydrologic regions are fairly uniform throughout the year, with the exception of late summer and early fall (July, August, and September), when each hydrologic region exhibits a substantial increase in median absolute percent difference. The greatest difference occurs in the Northwest hydrologic region, and the smallest difference occurs in the Mountain hydrologic region. The Rio Grande hydrologic region shows seasonal variation in median absolute percent difference with March, April, August, and September having a median absolute difference near or below 40 percent, and the remaining months of the year having a median absolute difference near or above 50 percent. In the Mountain, Northwest, and Southwest hydrologic regions, the mean-monthly streamflow equations perform the best during spring (March, April, and May). However, in the Rio Grande hydrologic region, the mean-monthly streamflow equations perform the best during late summer and early fall (August and September).

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Distribution of oxygen-18 and deuteriun in river waters across the United States

Reconstruction of continental palaeoclimate and palaeohydrology is currently hampered by limited information about isotopic patterns in the modern hydrologic cycle. To remedy this situation and to provide baseline data for other isotope hydrology studies, more than 4800, depth- and width-integrated, stream samples from 391 selected sites within the USGS National Stream Quality Accounting Network (NASQAN) and Hydrologic Benchmark Network (HBN) were analysed for δ 18 O and δ 2 H ( http://water.usgs.gov/pubs/ofr/ofr00-160/pdf/ofr00-160.pdf ). Each site was sampled bimonthly or quarterly for 2·5 to 3 years between 1984 and 1987. The ability of this dataset to serve as a proxy for the isotopic composition of modern precipitation in the USA is supported by the excellent agreement between the river dataset and the isotopic compositions of adjacent precipitation monitoring sites, the strong spatial coherence of the distributions of δ 18 O and δ 2 H, the good correlations of the isotopic compositions with climatic parameters, and the good agreement between the ‘national’ meteoric water line (MWL) generated from unweighted analyses of samples from the 48 contiguous states of δ 2 H=8·11δ 18 O+8·99 ( r 2 =0·98) and the unweighted global MWL of sites from the Global Network for Isotopes in Precipitation (GNIP) of the International Atomic Energy Agency and the World Meteorological Organization (WMO) of δ 2 H=8·17δ 18 O+10·35. The national MWL is composed of water samples that arise in diverse local conditions where the local meteoric water lines (LMWLs) usually have much lower slopes. Adjacent sites often have similar LMWLs, allowing the datasets to be combined into regional MWLs. The slopes of regional MWLs probably reflect the humidity of the local air mass, which imparts a distinctive evaporative isotopic signature to rainfall and hence to stream samples. Deuterium excess values range from 6 to 15‰ in the eastern half of the USA, along the northwest coast and on the Colorado Plateau. In the rest of the USA, these values range from −2 to 6‰, with strong spatial correlations with regional aridity. The river samples have successfully integrated the spatial variability in the meteorological cycle and provide the best available dataset on the spatial distributions of δ 18 O and δ 2 H values of meteoric waters in the USA.

Hydrological Processes↗

Observed and simulated ground motions in the San Bernardino basin region for the Hector Mine, California, earthquake

During the MW 7.1 Hector Mine earthquake, peak ground velocities recorded at sites in the central San Bernardino basin region were up to 2 times larger and had significantly longer durations of strong shaking than sites just outside the basin. To better understand the effects of 3D structure on the long-period ground-motion response in this region, we have performed finite-difference simulations for this earthquake. The simulations are numerically accurate for periods of 2 sec and longer and incorporate the detailed spatial and temporal heterogeneity of source rupture, as well as complex 3D basin structure. Here, we analyze three models of the San Bernardino basin: model A (with structural constraints from gravity and seismic reflection data), model F (water well and seismic refraction data), and the Southern California Earthquake Center version 3 model (hydrologic and seismic refraction data). Models A and F are characterized by a gradual increase in sediment thickness toward the south with an abrupt step-up in the basement surface across the San Jacinto fault. The basin structure in the SCEC version 3 model has a nearly uniform sediment thickness of 1 km with little basement topography along the San Jacinto fault. In models A and F, we impose a layered velocity structure within the sediments based on the seismic refraction data and an assumed depth-dependent Vp/Vs ratio. Sediment velocities within the SCEC version 3 model are given by a smoothly varying rule-based function that is calibrated to the seismic refraction measurements. Due to computational limitations, the minimum shear-wave velocity is fixed at 600 m/sec in all of the models. Ground-motion simulations for both models A and F provide a reasonably good match to the amplitude and waveform characteristics of the recorded motions. In these models, surface waves are generated as energy enters the basin through the gradually sloping northern margin. Due to the basement step along the San Jacinto fault, the surface wave energy is confined to the region north of this structure, consistent with the observations. The SCEC version 3 model, lacking the basin geometry complexity present in the other two models, fails to provide a satisfactory match to the characteristics of the observed motions. Our study demonstrates the importance of using detailed and accurate basin geometry for predicting ground motions and also highlights the utility of integrating geological, geophysical, and seismological observations in the development and validation of 3D velocity models.

California↗

Geology and ground-water conditions in southern Nassau and southeastern Queens Counties, Long Island, N.Y.

Test drilling, electrical logging, and water sampling of 'outpost' and other wells have revealed the existence of a deep confined body of salt water in the Magothy(?) formation beneath southwestern Nassau and southeastern Queens Counties, Long Island, N.Y. In connection with a test-drilling program, cooperatively sponsored by the U.S. Geological Survey, the Nassau County Department of Public Works, and the New York State Water Resources Commission (formerly Water Power and Control Commission), 13 wells ranging in depth from about 130 to 800 feet were drilled during 1952 and 1953 and screened at various depths in the Magothy(?) formation and Jameco gravel. On the basis of the preliminary geologic, hydrologic, and chemical data from these wells, a detailed investigation of ground-water conditions from the water table to the bedrock was begun in a 200-square-mile area in southern Nassau and southeastern Queens Counties. The Inain purposes of the investigation were to delineate the bodies of fresh and salty ground water in the project area, to relate their occurrence and movement to geologic and hydrologic conditions, to estimate the rate of encroachment, if any, of the salty water, and to evaluate the effectiveness of the existing network of outpost wells as detectors of salt-water encroachment. About a million people in the report area, residing mainly in southern Nassau County, are completely dependent on ground water as a source of supply. Fortunately, precipitation averages about 44 inches per year, of which approximately half is estimated to percolate into the ground-water reservoir. The ground water is contained in and moves through eight differentiated geologic units composed of unconsolidated gravel, sand, and clay, of Late Cretaceous, Pleistocene, and Recent age, having a maximum total thickness of about 1,700 feet. The underlying metamorphic and igneous crystalline basement rocks are of Precambrian age and are not water bearing. The water-yielding units from the surface down are (1) the upper Pleistocene deposits, (2) the principal artesian aquifer, composed of the Jameco gravel and Magothy(?) formation, and (3) the Lloyd sand member of the Raritar formation. The confining units are the '20-foot' clay, the Gardiners clay, and the clay member of the Raritan formation. The upper Pleistocene deposits contain an extensive unconfined body of fresh water. Fresh water under artesian conditions is contained in the principal artesian aquifer and the Lloyd sand member. The piezometric surface of the principal artesian aquifer is similar in shape to the south-ward-sloping water table; it ranges in altitude from about sea level to 55 feet above. The chemical quality of the fresh ground water in most of the area in all aquifers is good to excellent, and concentrations of dissolved solids and of chloride generally are below 100 ppm (parts per million) and 10 ppm, respectively. Analyses of water samples from selected wells show no progressive increase in concentration of chloride in most of the area. The data on quality of water have been used to delineate one major and several minor bodies of salty ground water. The wedgeshaped main confined salt-water body, in which the concentration of chloride reaches about 17,000 ppm, is in the Magothy(?) formation and Jameco gravel in extreme southwestern Nassau County and southeastern Queens County. The base of the salt-water wedge is about at the top of the clay member of the Raritan formation. Beneath the barrier beach in south-central and southeastern Nassau County a shallow extension of the main confined salt-water body contains as much as 4,000 ppm of chloride and is separated from the lower main salt-water body by fresh ground water. Shallow, thin bodies of unconfined salty ground water are common in the upper Pleistocene and Recent deposits adjacent to salty surface water in tidal creeks, bays, and the Atlantic

New York↗

Hydrologic conditions in Kansas, water year 2020

The U.S. Geological Survey, in cooperation with Federal, State, and local agencies, maintains a long-term network of hydrologic monitoring stations in Kansas. This network included 219 real-time streamgages, 12 real-time reservoir-level monitoring stations, and 20 groundwater monitoring stations in water year (WY) 2020. A WY is a 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. Real-time data are verified by U.S. Geological Survey personnel throughout the year with regular measurements of streamflow, lake levels, and groundwater levels. Hydrologic data collected in real time aid in the understanding of, and decisions made involving, water resources of Kansas. Hydrologic conditions are assessed annually by comparing statistical analyses of current and past WY data for the period of record. The monitoring of hydrologic conditions in Kansas can provide critical information to meet several needs including water-resources management, protection of life and property, reservoir operations, agricultural practices, public supply, ecological assessments, and industrial and recreational purposes.

Kansas↗

Data on uranium and radium in ground water in the United States, 1954 to 1957

This report is one of a series resulting from a study by the U.S. Geological Survey to determine the occurrence and distribution of naturally radioactive substances in water. From 1954-57 uranium and radium concentrations were determined in 561 samples, mainly of ground water, having wide geologic and geographic distribution. These concentrations, together with data on the hydrologic and geologic environment, the beta-gamma activity, and the chemical characteristics of each sample, are tabulated by States. The conterminous United States was subdivided into 10 geotectonic regions to facilitate statistical interpretation of the occurrence of uranium and radium in fresh water in approximately homogeneous geologic provinces. For each geotectonic region, the range and median were determined for the concentrations of radium and uranium; for regions from which sufficient data were available, log-normal frequency distribution curves were calculated and superimposed on histograms of radium and uranium concentrations in the samples. An "anomaly threshold" is suggested for both radioelements for each region analyzed statistically. The western stable region had the greatest median and highest "anomaly threshold" for uranium. This region also had the highest "anomaly threshold" for radium, but the largest median for radium was found for samples collected in the Ozark-Ouachita system. The median concentration for uranium was lowest for the Atlantic and Gulf Coastal Plain and the Pacific orogenic belt. This latter region also had the lowest median-radium content.

Professional Paper↗

Application of artificial neural networks to complex groundwater management problems

As water quantity and quality problems become increasingly severe, accurate prediction and effective management of scarcer water resources will become critical. In this paper, the successful application of artificial neural network (ANN) technology is described for three types of groundwater prediction and management problems. In the first example, an ANN was trained with simulation data from a physically based numerical model to predict head (groundwater elevation) at locations of interest under variable pumping and climate conditions. The ANN achieved a high degree of predictive accuracy, and its derived state-transition equations were embedded into a multiobjective optimization formulation and solved to generate a trade-off curve depicting water supply in relation to contamination risk. In the second and third examples, ANNs were developed with real-world hydrologic and climate data for different hydrogeologic environments. For the second problem, an ANN was developed using data collected for a 5-year, 8-month period to predict heads in a multilayered surficial and limestone aquifer system under variable pumping, state, and climate conditions. Using weekly stress periods, the ANN substantially outperformed a well-calibrated numerical flow model for the 71-day validation period, and provided insights into the effects of climate and pumping on water levels. For the third problem, an ANN was developed with data collected automatically over a 6-week period to predict hourly heads in 11 high-capacity public supply wells tapping a semiconfined bedrock aquifer and subject to large well-interference effects. Using hourly stress periods, the ANN accurately predicted heads for 24-hour periods in all public supply wells. These test cases demonstrate that the ANN technology can solve a variety of complex groundwater management problems and overcome many of the problems and limitations associated with traditional physically based flow models.

Natural Resources Research↗

Using OTIS to model solute transport in streams and rivers

Solute transport in streams and rivers is governed by a suite of hydrologic and geochemical processes. Knowledge of these processes is needed when assessing the fate of contaminants that are released into surface waters. The study of solute fate and transport often is aided by solute transport models that mathematically describe the underlying processes. This fact sheet describes a model that considers One-Dimensional Transport with Inflow and Storage (OTIS). As shown by several example applications, OTIS may be used in conjunction with field-scale data to quantify hydrologic processes (advection, dispersion, and transient storage) and certain chemical reactions (sorption and first-order decay).

Fact Sheet↗

Methodology for applying monitored natural attenuation to petroleum hydrocarbon-contaminated ground-water systems with examples from South Carolina

Natural attenuation processes such as dispersion, advection, and biogradation serve to decrease concentrations of disssolved contaminants as they are transported in all ground-water systems. However, the efficiency of these natural attenuation processes and the degree to which they help attain remediation goals, varies considerably from site to site. This report provides a methodology for quantifying various natural attenuation mechanisms. This methodology incorporates information on (1) concentrations of contaminants in space and/or time; (2) ambient reduction/oxidation (redox) conditions; (3) rates and directions of ground-water flow; (4) rates of contaminant biodegradation; and (5) demographic considerations, such as the presence of nearby receptor exposure points or property boundaries. This document outlines the hydrologic, geochemical, and biologic data needed to assess the efficiency of natural attenuation, provides a screening tool for making preliminary assessments, and provides examples of how to determine when natural attenuation can be a useful component of site remediation at leaking underground storage tank sites. At a site in the Piedmont Physiographic Province (Laurens, South Carolina), hydrologic and water-chemistry data indicate that the natural attenuation capacity for benzene is approximately 5 percent per foot of flowpath. As a result, benzene concentrations would decrease from about 28,000 micrograms per liter in ground water at the source area to less than 5 micrograms per liter 200 feet downgradient and prior to discharging to a stream. Because of this rapid attenuation, contaminants do not presently impact the stream downgradient of the site. In contrast, at a site in the coastal Plain Physiographic Province (Charleston, South Carolina), hydrologic and water-chemistry data indicate that, even thought the site has a substantial natural attenuation capacity, it may not be sufficient to fully protect a nearby point of ground-water discharge. These two sites illustrate how the efficiency of natural attenuation processes acting on petroleum hydrocarbons can be systematically evaluated using hydrologic, geochemical, and microbiologic methods. These methods, in turn, can be used to assess the role that the natural attenuation of petroleum hydrocarbons can play in achieving overall site remediation.

South Carolina↗

Hydrogeology and simulation of ground-water flow, Picatinny Arsenal and vicinity, Morris County, New Jersey

Ground-water flow in glacial sediments and bedrock at Picatinny Arsenal, N.J., was simulated by use of a three-dimensional finite-difference ground- water-flow model. The modeled area includes a 4.3-square-mile area that extends from Picatinny Lake to the Rockaway River. Most of the study area is bounded by the natural hydrologic boundaries of the ground-water system. eophysical logs, lithologic logs, particle-size data, and core data from selected wells and surface geophysical data were analyzed to define the hydrogeologic framework. Hydrogeologic sections and thickness maps define six permeable and three low-permeability layers that are represented in the model as aquifers and confining units, respectively. Hydrologic data incorporated in the model include a rate of recharge from precipitation of 22 inches per year, estimated from long-term precipitation records and estimates of evapotranspiration. Additional recharge from infiltration along valleys was estimated from measured discharge of springs along the adjacent valley walls and from estimates of runoff from upland drainage that flows to the valley floor. Horizontal and vertical hydraulic conductivities of permeable and low-permeability layers were estimated from examination of aquifer-test data, gamma-ray logs, borehole cuttings, and previously published data. Horizontal hydraulic conductivities in glacial sediments range from 10 to 380 feet per day. Vertical hydraulic conductivities of the low-permeability layers range from 0.01 to 0.7 feet per day. The model was calibrated by simulating steady-state conditions during 1989-93 and by closely matching simulated and measured ground-water levels, vertical ground-water-head differences, and streamflow gain and loss. Simulated steady-state potentiometric- surface maps produced for the six permeable layers indicate that ground water in the unconfined material within Picatinny Arsenal flows predominantly toward the center of the valley, where it discharges to Green Pond Brook. Beneath the upper confining unit, ground water flows southwestward, down the valley. Between First Street and Farley Avenue, the upper confining unit pinches out near the valley walls, resulting in a major input of water to, and causing a local potentiometric high in, the underlying aquifer layers. Ground-water-flow directions southwest of the southern arsenal boundary are predominantly to the Rockaway River.

New Jersey↗

Performance mapping and weighting for the evapotranspiration models of the OpenET ensemble

Evapotranspiration (ET) accounts for the majority of water available from precipitation in the terrestrial water cycle, and improvements to the accuracy, resolution, and coverage of ET data can enhance hydrologic models and assessments. The OpenET collaboration of six remotely sensed ET modeling teams has demonstrated that an ensemble approach to ET estimation generally provides improved accuracy relative to individual ensemble members. The performance of individual models has been shown to vary by land cover type and climate zone, but a thorough study of the variables that influence model performance differences has not yet been conducted. In this paper, we model the performance of OpenET models relative to flux tower data as a function of variables such as land cover type and precipitation. These performance models are used to map estimated OpenET model performance across the conterminous United States. We develop relative weights based on these modeled performance metrics and show that a performance-weighted ensemble improves accuracy relative to the current OpenET ensemble method to varying degrees. The monthly mean absolute error of the weighted ensemble is reduced relative to the current method by 8% in agricultural settings, by 23% in shrublands and mixed forests, and by 5% in grasslands and evergreen forests. We produce weight maps that can be used to generate performance-weighted ensemble values for OpenET data. The results can be used to inform model selection and provide insight about the controls on model performance that could lead to model refinement.

Water Resources Research↗

Brackish groundwater and its potential to augment freshwater supplies

Secure, reliable, and sustainable water resources are fundamental to the Nation’s food production, energy independence, and ecological and human health and well-being. Indications are that at any given time, water resources are under stress in selected parts of the country. The large-scale development of groundwater resources has caused declines in the amount of groundwater in storage and declines in discharges to surface water bodies (Reilly and others, 2008). Water supply in some regions, particularly in arid and semiarid regions, is not adequate to meet demand, and severe drought intensifies the stresses affecting water resources (National Drought Mitigation Center, the U.S. Department of Agriculture, and the National Oceanic and Atmospheric Association, 2015). If these drought conditions continue, water shortages could adversely affect the human condition and threaten environmental flows necessary to maintain ecosystem health. In support of the national census of water resources, the U.S. Geological Survey (USGS) completed the national brackish groundwater assessment to provide updated information about brackish groundwater as a potential resource to augment or replace freshwater supplies (Stanton and others, 2017). Study objectives were to consolidate available data into a comprehensive database of brackish groundwater resources in the United States and to produce a summary report highlighting the distribution, physical and chemical characteristics, and use of brackish groundwater resources. This assessment was authorized by section 9507 of the Omnibus Public Land Management Act of 2009 (42 U.S.C. 10367), passed by Congress in March 2009. Before this assessment, the last national brackish groundwater compilation was completed in the mid-1960s (Feth, 1965). Since that time, substantially more hydrologic and geochemical data have been collected and now can be used to improve the understanding of the Nation’s brackish groundwater resources.

Fact Sheet↗