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Proposed program for and present status of the Geological Survey's investigation of domestic resources of radioactive raw materials

This interim report is designed to show the present status of the Geological Survey's information and the parts of a comprehensive program necessary to improve our information about the raw material resources of uranium and thorium. Rarely in geologic work has it been necessary. to determine so completely a nation's resources of useful minerals in so brief a span of time. Ordinarily, information on mineral resources Is accumulated during a long period of years. However, uranium and thorium were suddenly thrust from a position of subsidiary economic interest into one of great strategic importance. Information concerning their occurrence must, therefore, be obtained as rapidly as reliable methods of investigation will permit. Accordingly the program must be at once comprehensive and carried out over an area more extensive than is usual in the search for and appraisal of most other mineral resources.

Trace Elements Investigations↗

Airborne radioactivity surveys for phosphate in Florida

Airborne radioactivity surveys totalling 5,600 traverse miles were made in ten areas in Florida, which were thought to be geologically favorable for the occurrence of uraniferous phosphate deposits. Abnormal radioactivity was recorded in eight of the ten areas surveyed. The anomalies are located in Bradford, Clay, Columbia, DeSoto, Dixie, Lake, Marion, Orange, Sumter, Taylor, and Union Counties. Two of the anomalies were investigated briefly on the ground. One resulted from a deposit of river-pebble phosphate in the Peace River valley; samples of the river pebble contain an average of 0.013 percent equivalent uranium. The other anomaly resulted from outcrops of leached phosphate rock containing as much as 0.016 percent equivalent uranium. Several anomalies in other areas were recorded at or near localities where phosphate deposits have been reported to occur.

Florida↗

Stratigraphy of parts of De Soto and Hardee Counties, Florida

The late Cenozoic stratigraphy of part of central Florida immediately south of the land-pebble phosphate district was studies in detail to determine the southern limit of the economically important Bone Valley formation and its relations with marine rocks of late Miocene and Pliocene age in south-central Florida. In addition a reconnaissance type appraisal of the phosphate and uranium resources of this area was desired. The upper Tertiary and Quaternary rocks were mapped, and the economic geology was studied in a general manner. The Hawthorn formation of middle Miocene age, is the oldest rock Exposed. Undifferentiated phosphatic sand and clay may be composed of the Bone Valley formation, of late Miocene to Pliocene age; a combination of Bone Valley formation and residuum of weathered Hawthorn formation; or Hawthorn residuum alone. The Bone Valley formation and residuum of Hawthorn formation appear almost identical in cuttings from auger drilling in this area. It was not feasible nor practical to map these two units separately. The undifferentiated phosphatic sand and clay interfingers with a marine sand of late Miocene age, The Caloosahatchee marl of Pliocene age, is present in the southeast corner of the area investigated. It is apparent that the undifferentiated phosphatic sand and clay was undergoing subaerial erosion and reworking during deposition or the Caloosahatchee marl. Stratified sand and clayey sand containing scattered thin lenses of fresh-water limestone and marl of Pleistocene age are either floodplain deposits or subaerial topset beds of a delta made by the Pleistocene Peace River. Sediments of Recent age are local stream deposits. Bars and shoals in the Peace River south of Brownville, De Soto County, contain appreciable tonnages of low grade "river-pebble" phosphate. The phosphate and uranium content of the undifferentiated phosphatic sand and clay in Hardee County is too low to be of economic significance.

Florida↗

Selected annotated bibliography of the geology of uraniferous and radioactive native bituminous substances, exclusive of coals, in the United States

Native bituminous substances are divided into two groups, 1) bitumens and, 2) pyrobitumens. Bitumens are composed principally of hydrocarbons substantially free from oxygenated bodies, are fusible, and are soluble in carbon disulfide. Native bitumens occur in liquid and solid forms. The native liquid bitumens include all petroleums or crude oils. Native solid bitumens include native waxes such as ozocerite, asphalts or petroleum tars, and asphaltites such as gilsonite and grahamite. Pyrobitumens are composed principally of hydrocarbons which may contain oxygenated bodies. They are infusible and are insoluble, or nearly insoluble, in carbon disulfide. Native pyrobitumens are divided into an oxygen-containing group including peats, lignites, and coals, and an essentially oxygen-free, asphaltic group including such substances as wurtzilite, albertite, impsonite, and ingramite. Thucholites, which are carbonaceous substances that may contain uranium, thorium, and rare earths, commonly are considered to be pyrobitumens. Their compositions are variable and may fall into either the oxygen-containing or oxygen-free group. All varieties of native bituminous substances may be associated with mineral matter. The nomenclature of bitumens and pyrobitumens is used very loosely in the literature. This circumstance arises from the difficulty in recognizing many of these substances by visual examination, and because many of them can be identified accurately only by chemical methods. Inasmuch as some of the chemical procedures are time-consuming and satisfactory analytical methods have not been devised for all these substances, geologists generally have not obtained precise identifications but rather have used names that appeared most appropriate to the circumstances. It is expected that future research will show many substances called "asphaltite," "thucholite," etc., to be incorrectly identified. The nomenclature used by the authors of the various references of this bibliography is followed without deviation or further discussion. The stratigraphic nomenclature also is that used by the authors. In this bibliography emphasis is placed on reports dealing with the uranium contents and radioactivity of native bituminous substances rather than on mineralogical and chemical studies of these substances. The distribution of the substances described in the references is shown on the accompanying map. The indicated presence of these substances does not infer that they contain sufficient radioactive elements to constitute ores.

Trace Elements Investigations↗

Reconnaissance of radioactive rocks of Maine

The state of Maine was traversed with car-mounted Geiger-Mueller equipment in the late summer of 1948 and the radioactivity of approximately 4,600 miles of road was logged. All samples were analyzed, both in the field by comparing the radioactivity of each sample to the radioactivity of a stranded measured with a simple scaling modification of a portable counter, and in the Geological Survey’s Trace Elements Section Washington Laboratory. Differences between both types of analyses were negligible. The maximum equivalent uranium content of the most radioactive rocks thus analyzed was 0.008 percent. A 1,400-square-mile abnormally radioactive province in southwestern Maine was outlined. The outcrop data obtained from car traversing are evaluated statistically. Cumulative frequency distribution curves are drawn to show the distribution of outcrops at various levels of radioactivity, and straight-line extensions are made to show to maximum probable grade for various rock types and areas in Maine. A maximum grade of 0.055 percent equivalent uranium is thus predicted for the entire state. This prediction necessarily is a broad generalization because large areas of Main are inaccessible for car traversing. A concept of evaluation of an area for possible mineral deposits is proposed on the basis of lithology, and observed and indicated ranges in grade.

Maine↗

Preliminary statement of the analyses of ground water from the Morrison Formation, southwestern Colorado and southeastern Utah

As part of a study of the carnotite deposits of the Colorado Plateau,, samples of ground water from the Salt Wash sandstone and Brushy Basin shale members of the Morrison formation have been analyzed to determine their chemical character and metal content. The Salt Wash ground water is largely a bicarbonate solution with variable amounts of calcium and magnesium ions; that from the Brushy Basin is either a sulfate or bicarbonate solution with sodium, The ground water from the Salt Wash and Brushy Basin members is generally weakly alkaline In most samples, the metal ions of uranium, vanadium, copper, lead, and selenium are present in amounts of less than 1 part per million. It is concluded that if the ground water responsible for introduction of the uranium and vanadium metals into the Salt Wash was comparable to the recent ground water, it contained very small amounts of the metal ions.

Colorado;Utah↗

Radioactive minerals in the Yakataga beach placers, southern Alaska

Radioactivity of nine samples of beach placer deposits in the Yakataga area, southern Alaska, was studied in 1948. The samples were given to the Geological Survey by prospectors operating in the area operating in the area. The heavy-mineral fractions from the concentrates average 0.044 percent equivalent uranium. Three minerals, all members of the zircon group, contain the radioactive material in the sample; one mineral is uranium-bearing, the other two are thorium-bearing. Unless the concentration of radioactive minerals in the beach deposits is considerably higher than the present qualitative data indicate, the placers at Yakataga beach do not constitute a feasible source of supply of radioactive materials.

Alaska↗

Preliminary summary review of thorium-bearing mineral occurrences in Alaska

Thorium-bearing minerals are known at 47 localities in Alaska. At these localities the thorium occurs as a major constituent or in minor amounts as an impurity in one or more of the following 12 minerals: allanite, columbite, ellsworthite, eschynite, gummite, monazite, orangite, parisite, thorianite, thorite, xenotime, and zircon. In addition other minerals, such as biotite and sphene, are radioactive and may contain thorium. Several unidentified columbate minerals with uranium or thorium and uranium as major constituents have been recognized at some localities. The distribution, by type of deposit, of the 57 thorium occurrences is as follows: lode - 3, lode and placer - 1, granitic rock - 3, granitic rock and related placer - 14, and placer - 26. Of the four lode occurrences only the radioactive veins at Salmon Bay in southeastern Alaska and the contact metamorphic deposit in the Nixon Fork area of central Alaska warrant further consideration, although insufficient data are available to determine whether these two deposits have commercial possibilities. The remaining occurrences of thorium-bearing minerals in Alaska are limited to placer deposits and disseminations of accessory minerals in granitic rocks. In most of these occurrences the thorium-bearing minerals occur in only trace amounts and consequently warrent little further consideration. More data are needed to determine the possibilities of byproduct recovery of thorium-bearing minerals from several of the gold and tin placers.

Alaska↗

Airborne radioactivity survey of parts of Atlantic Ocean beach, Virginia to Florida

The accompanying maps show the results of an airborne radioactivity survey along the Atlantic Ocean beach from Cape Henry, Virginia to Cape Fear, North Carolina and from Savannah Bach Georgia to Miami Beach, Florida. The survey was made March 23-24, 1953, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation detection equipment mounted in a Douglas DC-3 aircraft and consisted of one flight line, at a 500-foot altitude, parallel to the beach. The vertical projection of the flight line coincided approximately with the landward limit of the modern beach. The width of the zone on the ground from which anomalous radiation is measured at the normal 500 foot flight altitude varies with the areal extent radioactivity of the source. For strong sources of radioactivity the width of the zone would be as much as 1,400 feet. The location of the flight lines is shown on the index map below. No abnormal radioactivity was detected along the northern flight line between Cape Henry, Virginia and Cape Fear, North Carolina. Along the southern flight line fourteen areas of abnormal radioactivity were detected between Savannah Beach, Georgia and Anastasia Island, Florida as shown on the map on the left. The abnormal radioactivity is apparently due to radioactive minerals associated with "black sand" deposits with occur locally along the beach in this region. The present technique of airborne radioactivity measurement does not permit distinguishing between activity sue to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to one or to a combination of these elements. It is not possible to determine the extent or radioactive content of the materials responsible for the abnormal radioactivity. The information given on the accompanying map indicates only those localities of greater-than-average radioactivity and, therefore suggest areas in which uranium and thorium deposits are more likely to occur.

Florida;Georgia;North Carolina;South Carolina;Virg↗

Airborne radioactivity survey of parts of the Atlantic Ocean beach, North and South Carolina

The accompanying map shows the results of an airborne radioactivity survey along the Atlantic Ocean beach between Edisto Island, South Carolina and Cape Fear, North Carolina. The survey was made May 20, 1953, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation detection equipment mounted in a Douglas DC-3 aircraft and consisted of one flight line, at a 500-foot altitude, parallel to the beach. The vertical projection of the flight line coincided approximately with the landward limit of the modern beach. The width of the zone on the ground from which anomalous radiation is measured at the nominal 500 foot flight altitude varies with areal extent and intensity of radioactivity of the source. For strong sources of radioactivity the width of the zone may be as much as 1400 feet. The accompanying maps show the approximate locations of the areas of greater-than-average radioactivity (at left) and the location of the traverse flown (at right). The abnormal radioactivity is apparently caused by radioactive minerals associated with "black sand" deposits which occur locally along the beach in this region. The present technique of airborne radioactivity measurement does not permit distinguishing between activity due to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to one or a combination of these elements. It is not possible to determine the extent or radioactive content of the materials responsible for the abnormal radioactivity. The information given in the accompanying map showing the localities of greater-than-average radioactivity therefore, suggests areas in which uranium and thorium deposits are more likely to occur.

North Carolina;South Carolina↗

Airborne radioactivity survey of the Gulf of Mexico beach between Sanibel Island and Caladesi Island, Florida

The accompanying map shows the results of an airborne radioactivity survey along the Gulf of Mexico beach between Sanibel Island and Caladesi Island in Florida. This survey was made May 4, 1953, as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation detection equipment mounted in a Douglas DC-3 aircraft and consisted of one flight line, at a 500-foot altitude , parallel to the beach. The vertical projection of the flight line coincided approximately with the landward limit of the modern beach. The width of the zone on the ground from which anomalous radiation is measured at the nominal 500 foot flight altitude varies with the areal extent and intensity of the radioactivity the width of the zone may be as much as 1400 feet. The accompanying map and index map show the approximate locations of the areas of greater-than-average radioactivity and the location of the traverse flown. The abnormal radioactivity is apparently caused by radioactive minerals associated with "black sand" deposits which occur locally along the beach in the region. The present technique of airborne radioactivity measurement does not permit distinguishing between activity due to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to one or to a combination of these elements. It is not possible to determine the extent or radioactive content of the materials responsible for the abnormal radioactivity. The information given in the accompanying map showing the localities of greater-than-average radioactivity therefore, suggests area in which uranium or thorium deposits are more likely to occur.

Florida↗

Airborne radioactivity survey of parts of Baggs SW and Baggs SE quadrangles, Carbon and Sweetwater counties, Wyoming

The accompanying map shows the results of an airborne radioactivity survey in 151 square miles of Baggs SW and Baggs SE quadrangles, Wyoming. This area is part of a larger survey made in southern Carbon and Sweetwater counties by the U.S. Geological Survey, November 9-24, 1953. The work was undertaken as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation detection equipment mounted in a C-47 aircraft and consisted of parallel east-west flight lines spaced at quarter mile intervals, flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyrostabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. The width of the zone on the ground form which the anomalous radiation is measured at the nominal 500 foot flight altitude varied with the areal extent and the intensity of radioactivity of the source. For strong sources of radioactivity the width of the zone may be as much as 1,400 feet. Thus, quarter mile spacing of the flight lines would be adequate to detect anomalies from strong sources of radioactivity; however, small areas of considerable radioactivity midway between flight lines may not be noted. The approximate locations of twelve radioactivity anomalies are shown on the accompanying map. The plotted position of the anomalies may be in error by as much as a quarter mile owing to the errors in available base maps or to the existence of areas on the base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The present technique of airborne radioactivity measurement does not permit distinguishing between activity due to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to one or to a combination of these elements. The radioactivity anomalies shown on the accompanying map cannot be interpreted in terms of either radioactive content or the extent of the source materials. Any particular anomaly may represent slightly greater-than-average radioactivity over an area of a few thousand square feet or high radioactivity over an area of a few hundred square feet. Thus radioactivity anomalies indicate localities of more-than-average radioactivity and, therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

Airborne radioactivity survey of parts of Sand Creek SW and Sand Creek SE quadrangles, Sweetwater county, Wyoming

The accompanying map shows the results of an airborne radioactivity survey in 125 square miles of Sand Creek SW and Sand Creek SE quadrangles, Wyoming. This area is part of a larger survey made in southern Carbon and Sweetwater counties by the U.S. Geological Survey, November 9-24, 1953. The work was undertaken as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation detection equipment mounted in a C-47 aircraft and consisted of parallel east-west flight lines spaced at quarter mile intervals, flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyrostabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. The width of the zone on the ground form which the anomalous radiation is measured at the nominal 500 foot flight altitude varied with the areal extent and the intensity of radioactivity of the source. For strong sources of radioactivity the width of the zone may be as much as 1,400 feet. Thus, quarter mile spacing of the flight lines would be adequate to detect anomalies from strong sources of radioactivity; however, small areas of considerable radioactivity midway between flight lines may not be noted. The approximate locations of nine radioactivity anomalies are shown on the accompanying map. The plotted position of the anomalies may be in error by as much as a quarter mile owing to the errors in available base maps or to the existence of areas on the base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The present technique of airborne radioactivity measurement does not permit distinguishing between activity due to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to one or to a combination of these elements. The radioactivity anomalies shown on the accompanying map cannot be interpreted in terms of either radioactive content or the extent of the source materials. Any particular anomaly may represent slightly greater-than-average radioactivity over an area of a few thousand square feet or high radioactivity over an area of a few hundred square feet. Thus radioactivity anomalies indicate localities of more-than-average radioactivity and, therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

Water-quality characteristics in the Black Hills area, South Dakota

This report summarizes the water-quality characteristics of ground-water and surface-water in the Black Hills area. Differences in groundwater quality by aquifer and differences in surfacewater quality by water source are presented. Ground-water characteristics are discussed individually for each of the major aquifers in the Black Hills area, referred to herein as the Precambrian, Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Characteristics for minor aquifers also are discussed briefly. Surface-water characteristics are discussed for hydrogeologic settings including headwater springs, crystalline core sites, artesian springs, and exterior sites. To characterize the water quality of aquifers and streams in the Black Hills area, data from the U.S. Geological Survey National Water Information System water-quality database were examined. This included samples collected as part of the Black Hills Hydrology Study as well as for other studies within the time frame of October 1, 1930, to September 30, 1998. Tables of individual results are not presented in this report, only summaries. Constituents summarized and discussed include physical properties, common ions, nutrients, trace elements, and radionuclides. Comparisons of concentration levels are made to drinking-water standards as well as beneficial-use and aquatic-life criteria. Ground water within the Black Hills and surrounding area generally is fresh and hard to very hard. Concentrations exceeding various Secondary and Maximum Contaminant Levels may affect the use of the water in some areas for many aquifers within the study area. Concentrations that exceed Secondary Maximum Contaminant Levels (SMCL's) generally affect the water only aesthetically. Radionuclide concentrations may be especially high in some of the major aquifers used within the study area and preclude the use of water in some areas. The sodiumadsorption ratio and specific conductance may affect irrigation use for some wells. High concentrations of iron and manganese are the only concentrations that may hamper the use of water from Precambrian aquifers. The principal deterrents to use of water from the Deadwood aquifer are the high concentrations of radionuclides as well as iron and manganese. Iron, manganese, and hardness may deter use of water from the Madison aquifer as well as dissolved solids and sulfate in downgradient wells (generally deeper than 2,000 feet). Iron, manganese, and hardness may also deter use of the Minnelusa aquifer. Water from the Minnekahta aquifer generally is suitable for all water uses although it is hard to very hard. High concentrations of dissolved solids, iron, sulfate, and manganese may hamper the use of water from the Inyan Kara aquifer. In the southern Black Hills, radium-226 and uranium concentrations also may preclude use of water from the Inyan Kara aquifer. Suitability for irrigation may be affected by high specific conductance and sodium-adsorption ratio for the Inyan Kara. Surface-water quality within the Black Hills and surrounding area generally is very good but the water is hard to very hard. Concentrations of some constituents in the study area tend to be higher exterior to the Black Hills, primarily due to influences from the Cretaceous-age marine shales, including dissolved solids, sodium, sulfate, selenium, and uranium. Headwater springs have relatively constant discharge, specific conductance, dissolved solids, and concentrations of most other constituents. Concentrations at crystalline core sites are very similar to those found in samples from Precambrian aquifers. Some high nitrate concentrations greater than the Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) have occurred at Annie Creek near Lead, which have been attributed to mining impacts. Trace elements generally are low with the exception of arsenic, for which 60 percent of samples exceed the proposed MCL of 10 ug/L (micrograms per liter) and one sample

Water-Resources Investigations Report↗

Ground-water flow and quality near Canon City, Colorado

Water in aquifers that underlie the Lincoln Park area near Canon City, Colorado, contains measurable concentrations of chemical constituents that are similar to those in raffinate (liquid waste) produced by a nearby uranium ore processing mill. The objective of this study was to expand the existing geohydrologic data base by collecting additional geohydrologic and water quality, in order to refine the description of the geohydrologic and geochemical systems in the study area. Geohydrologic data were collected from nine tests wells drilled in the area between the U.S. Soil Conservation Service dam and Lincoln Park. Lithologic and geophysical logs of these wells indicated that the section of Vermejo Formation penetrated consisted of interbedded sandstone and shale. The sandstone beds had a small porosity and small hydraulic conductivity. Groundwater flow from the U.S. Soil Conservation Service dam to Lincoln Park seemed to be along an alluvium-filled channel in the irregular and relatively undescribed topography of the Vermejo Formation subcrop. North of the De Weese Dye Ditch, the alluvium becomes saturated and groundwater generally flows to the northeast. Water samples from 28 sites were collected and analyzed for major ions and trace elements; selected water samples also were analyzed for stable isotopes; samples were collected from wells near the uranium ore processing mill, from privately owned wells in Lincoln Park, and from the test wells drilled in the intervening area. Results from the quality assurance samples indicate that cross-contamination between samples from different wells was avoided and that the data are reliable. Water in the alluvial aquifer underlying Lincoln Park is mainly a calcium bicarbonate type. Small variations in the composition of water in the alluvial aquifer appears to result from a reaction of water leaking from the De Weese Dye Ditch with alluvial material. Upward leakage from underlying aquifers does not seem to be significant in determining the chemical composition of water in the alluvial aquifer. (Author 's abstract)

Water-Resources Investigations Report↗

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in Bowdoin National Wildlife Refuge and adjacent areas of the Milk River basin, northeastern Montana, 1986-87

Concentrations of trace elements, radiochemicals, and pesticides in the Bowdoin National Wildlife Refuge lakes generally were not substantially larger than those in the water supplied from Dodson South Canal or in irrigation drainage. Concentrations of arsenic (47 micrograms/L), uranium (43 microg/L), and vanadium (51 microg/L) in Dry Lake Unit, and boron (1,000 microg/L) in Lake Bowdoin were notably larger than at other sites. Zinc concentrations in an irrigation drain (56 microg/L) and two shallow domestic wells (40 and 47 microg/L) were elevated relative to other sites. Concentrations of gross alpha radiation (64 picocuries/L) and gross beta radiation (71 picocuries/L) were elevated in Dry Lake Unit. Pesticides concentrations at all sites were 0.08 microg/L or less. Water use guidelines concentrations for boron, cadmium, uranium, zinc, and gross alpha radiation were slightly exceeded at several sites. In general, trace-constituent concentrations measured in the water do not indicate any potential toxicity problems in Bowdoin National Wildlife Refuge; however, highwater conditions in 1986 probably caused dilution of dissolved constituents compared to recent dry years. Trace element concentrations in bottom sediments of the refuge lakes were generally similar to background concentrations in the soils. The only exception was Dry Lake Unit, which had concentrations of chromium (99 micrograms/g), copper (37 microg/g), nickel (37 microg/g), vanadium (160 microg/g), and zinc (120 microg/g) that were about double the mean background concentrations. The maximum selenium concentration in bottom sediment was 0.6 microg/g. Pesticide concentrations in bottom sediments were less than analytical detection limits at all sites. With few exceptions, concentrations of trace elements and pesticides in biota generally were less than values known to produce harmful effects on growth or reproduction.

Montana↗

Radium and radon in ground water in the Chickies Quartzite, southeastern Pennsylvania

The Chickies Quartzite, a Lower Cambrian-age formation compromised of quartzite and slate overlying a basal conglomerate, forms a narrow ridges and crops out discontinuously over 112 square miles in the Piedmont physiographic province of southeastern Pennsylvania. The formation is a low-yielding, fractured- rock, water-table aquifer recharged primarily by local precipitation. It is the sole source of water supply for thousands of domestic users. Ground water in the Chickies Quartzite generally is soft and acidic. During 1986-88, the U.S. Geological Survey sampled water from 160 wells that penetrate the Chickies Quartzite to determine the magnitude and distribution of radium-226 (Ra-226), radium-228 (Ra-228), and radon-222 (Rn-222) activities in ground water in the formation and to characterize the geochemical environmental associated with elevated activities of radium (Ra). In addition, 28 wells penetrating adjacent geologic units and 1 well in the Hardyston Quartzite were sampled to determine relative background Ra and RN-222 activities in ground water. Analyses included determination of activities of dissolved Ra-226, Ra-228, and RN-222, and concentrations of dissolved uranium (U), dissolved organic carbon (DOC), and major and minor dissolved inorganic ions. Rock samples were analyzed for U and thorium (Th) and geophysical logs were run to determine sources of Ra and RN-222 in the Chickies Quartzite. Activities of up to 41 pCi/L (picocuries per liter) for Ra-226, 160 pCi/L for Ra-228, and 32,300 pCi/L for RN-222 were measured in ground water in the Chickies Quartzite. Forty-seven percent of the samples contained Ra-226 and Ra-228 activities greater than 5 pCi/L. Median activities measured were 1.2 pCi/L for Ra-226, 2.6 pCi/L for Ra-228, 4.2 pCi/L for combined Ra-226 and Ra-228, and 2,400 pCi/L for RN-222 Ra-228 activity exceeded Ra-226 activity in about 92 percent of 100 water samples; the median Ra-228/Ra226 activity ratio was 2.4. Ra-228/Ra-226 activity ratios commonly were greater in ground water than calculated Th/U ratios in rock samples, suggesting perferential leaching of Ra-228 from aquifer solids. Of ground water in the adjacent geologic units, the highest activities (up to 2.9 pCi/L for Ra-226, 12 pCi/L for Ra-228, and 25,300 pCi/L for RN-222) were measured in ground water in the Harpers Phyllite and Antietam Quartzite. Nonparametric (Spearman rho test) statistical correlations show that the activity of dissolved Ra is inversely related to pH and directly related to concentrations of total dissolved solids, DOC, barium, and sulfate. Low pH decreases absorption of Ra onto the aquifer matrix. The other factors may favor Ra mobility by enhancing complexation or increasing solubility. RN-222 activity does not correlate with and is not supported by the activity of its parent, Ra-226, in solution. Ra-226 activity correlates positively, but weakly, with U concentrations. Ra-226 does not appear to be supported by its parent, U-238, in solution. Observed distributions of Ra-228, Ra-226, and RN-222 activities in ground water in different lithologies of the Chickies Quartzite reflect different geochemical controls on absorption and distribution of parent thorium-232 (Th-232) and uranium-238 (U-238) in the formation. Radium activities were greatest in acidic ground water in the conglomerate and quartzite (median pH of 5.0 and 5.2, respectively) and least in the more neutral water in the slate (median pH of 6.4). For ground water in the conglomerate, quartzite, and slate, respectively, median activities measured were 1.3, 1.5, and .02 pCi/L for Ra-226; and 3.7, 2.5, and 1.0 pCi/L for Ra-228. Natural-gamma-ray geophysical logs and results of rock analyses indicate that the conglomerate may contain more Th and U than the quartzite and that the conglomerate may be more enriched in Th with respect to U than the quartzite; Th and U distribution in both lithogies is variable. Median RN-222 activities in gro

Water-Resources Investigations Report↗

Radioactivity in the environment; a case study of the Puerco and Little Colorado River basins, Arizona and New Mexico

This report, written for the nontechnical reader, summarizes the results of a study from 1988-91 of the occurrence and transport of selected radionuclides and other chemical constituents in the Puerco and Little Colorado River basins, Arizona and New Mexico. More than two decades of uranium mining and the 1979 failure of an earthen dam containing mine tailings released high levels of radionuclides and other chemical constituents to the Puerco River, a tributary of the Little Colorado River. Releases caused public concern that ground water and streamflow downstream from mining were contaminated. Study findings show which radioactive elements are present, how these elements are distributed between water and sediment in the environment, how concentrations of radioactive elements vary naturally within basins, and how levels of radioactivity have changed since the end of mining. Although levels of radioactive elements and other trace elements measured in streamflow commonly exceed drinking-water standards, no evidence was found to indicate that the high concentrations were still related to uraniurn mining. Sediment radioactivity was higher at sample sites on streams that drain the eastern part of the Little Colorado River basin than that of samples from the western part. Radioactivity of suspended sediment measured in this study, therefore, represents natural conditions for the streams sampled rather than an effect of mining. Because ground water beneath the Puerco River channel is shallow, the aquifer is vulnerable to contamination. A narrow zone of ground water beneath the Puerco River containing elevated uranium concentrations was identified during the study. The highest concentrations were nearest the mines and in samples collected in the first few feet beneath the streambed. Natuxal radiation levels in a few areas of the underlying sedimentary aquifer not connected to the Puerco River also exceeded water quality standards. Water testing would enable those residents not using public water supplies to determine if their water is safe to use.

Water-Resources Investigations Report↗