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USGS2014

Groundwater-quality characteristics for the Wyoming Groundwater-Quality Monitoring Network, November 2009 through September 2012

Groundwater samples were collected from 146 shallow (less than or equal to 500 feet deep) wells for the Wyoming Groundwater-Quality Monitoring Network, from November 2009 through September 2012. Groundwater samples were analyzed for physical characteristics, major ions and dissolved solids, trace elements, nutrients and dissolved organic carbon, uranium, stable isotopes of hydrogen and oxygen, volatile organic compounds, and coliform bacteria. Selected samples also were analyzed for gross alpha radioactivity, gross beta radioactivity, radon, tritium, gasoline range organics, diesel range organics, dissolved hydrocarbon gases (methane, ethene, and ethane), and wastewater compounds. Water-quality measurements and concentrations in some samples exceeded numerous U.S. Environmental Protection Agency (EPA) drinking water standards. Physical characteristics and constituents that exceeded EPA Maximum Contaminant Levels (MCLs) in some samples were arsenic, selenium, nitrite, nitrate, gross alpha activity, and uranium. Total coliforms and Escherichia coli in some samples exceeded EPA Maximum Contaminant Level Goals. Measurements of pH and turbidity and concentrations of chloride, sulfate, fluoride, dissolved solids, aluminum, iron, and manganese exceeded EPA Secondary Maximum Contaminant Levels in some samples. Radon concentrations in some samples exceeded the alternative MCL proposed by the EPA. Molybdenum and boron concentrations in some samples exceeded EPA Health Advisory Levels. Water-quality measurements and concentrations also exceeded numerous Wyoming Department of Environmental Quality (WDEQ) groundwater standards. Physical characteristics and constituents that exceeded WDEQ Class I domestic groundwater standards in some samples were measurements of pH and concentrations of chloride, sulfate, dissolved solids, iron, manganese, boron, selenium, nitrite, and nitrate. Measurements of pH and concentrations of chloride, sulfate, dissolved solids, aluminum, iron, manganese, boron, and selenium exceeded WDEQ Class II agriculture groundwater standards in some samples. Measurements of pH and concentrations of sulfate, dissolved solids, aluminum, boron, and selenium exceeded WDEQ Class III livestock groundwater standards in some samples. The concentrations of dissolved solids in two samples exceeded the WDEQ Class IV industry groundwater standard. Measurements of pH and concentrations of dissolved solids, aluminum, iron, manganese, and selenium exceeded WDEQ Class special (A) fish and aquatic life groundwater standards in some samples. Stable isotopes of hydrogen and oxygen measured in water samples were compared to the Global Meteoric Water Line and Local Meteoric Water Lines. Results indicated that recharge to all of the wells was derived from precipitation and that the water has undergone some fractionation, possibly because of evaporation. Concentrations of organic compounds did not exceed any State or Federal water-quality standards. Few volatile organic compounds were detected in samples, whereas gasoline range organics, diesel range organics, and methane were detected most frequently. Concentrations of wastewater compounds did not exceed any State or Federal water-quality standards. The compounds N,N-diethyl-meta-toluamide (DEET), benzophenone, and phenanthrene were detected most frequently. Bacteria samples were collected, processed, incubated, and enumerated in the field or at the U.S. Geological Survey Wyoming-Montana Water Science Center. Total coliforms and Escherichia coli were detected in some samples.

Wyoming↗
USGS2015

Geochemical conditions and the occurrence of selected trace elements in groundwater basins used for public drinking-water supply, Desert and Basin and Range hydrogeologic provinces, 2006-11: California GAMA Priority Basin Project

The geochemical conditions, occurrence of selected trace elements, and processes controlling the occurrence of selected trace elements in groundwater were investigated in groundwater basins of the Desert and Basin and Range (DBR) hydrogeologic provinces in southeastern California as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP is designed to provide an assessment of the quality of untreated (raw) groundwater in the aquifer systems that are used for public drinking-water supply. The GAMA PBP is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The DBR hydrogeologic provinces consist of 141 defined groundwater basins separated by mountain ranges, faults, and other features. This report presents analyses of data collected from nine study areas within the DBR hydrogeologic provinces: Antelope Valley, Borrego Valley, the Central Desert area, Coachella Valley, Colorado River, Indian Wells Valley, Low-Use Basins of the Mojave and Sonoran Deserts, the Mojave, and Owens Valley. Collectively, these nine study areas are referred to as the DBR study unit. The study unit covers approximately 7,000 square miles and includes the 63 groundwater basins in the DBR hydrogeologic provinces in which groundwater is used for public drinking-water supply. The vast majority of the 223 wells sampled for this study were long-screened production wells used primarily for public supply. Uncorrected carbon-14 ( 14 C) groundwater ages for samples collected in the DBR study unit ranged from less than (<) 100 to 33,700 years before present (BP). Sixty-six percent of sample ages were greater than (>) 100 years BP, and 40 percent were >3,800 years BP. Samples collected from wells located adjacent to mountain-front recharge areas or major surface-water features generally had younger groundwater ages than did samples collected from wells located away from mountain fronts or towards the distal ends of basin groundwater flow paths. Most groundwater sampled in the DBR study unit had alkaline pH: 89 percent of sample pH values ranged from 7.1 to 9.8, with 37 percent greater than or equal to (&ge;) 7.9. Groundwater age was significantly correlated (positively) with pH, likely because silicate weathering is a primary control on groundwater pH and is a slow process. The oxidation-reduction (redox) condition of the groundwater sampled in the DBR study unit was predominantly oxic (71 percent), except in the Colorado River study area where organic-rich fluvial aquifers provide the electron donors necessary to support iron-reducing (anoxic-Fe) redox processes. The cation type of 78 percent of the samples was either sodium- or mixed-type, and the anion type of 83 percent of the samples was either bicarbonate- or mixed-type. Sodium-type groundwaters generally were older and more alkaline than calcium-type groundwaters, consistent with the change in water chemistry expected from cation exchange between groundwater and aquifer sediments over long periods of time. Because of the correlation with young groundwater, calcium-type groundwater was predominantly from wells located adjacent to mountain-front recharge areas. Arsenic (As), boron (B), fluoride (F), molybdenum (Mo), strontium (Sr), uranium (U), and vanadium (V) were selected for assessment in this study because they occurred at concentrations greater than California Department of Public Health or U.S. Environmental Protection Agency regulatory or non-regulatory drinking-water-quality benchmarks in more than 2 percent of the 223 samples collected in the DBR study unit. As and F were detected most commonly (18 and 13 percent, respectively) at concentrations above associated water-quality benchmarks and Sr and V least frequently (both at 3 percent). Given that 14 C groundwater ages are predominantly >100 years BP, land use in the study unit is primarily undeveloped, and chemicals derived from anthropogenic sources, such as volatile organic compounds, were infrequently detected, high concentrations of these trace elements in groundwater were most likely the result of natural factors and not anthropogenic factors. As, F, Mo, and V concentrations showed significant positive correlations to groundwater age and to pH. This relation is partly due to the sources of trace elements likely being the weathering of primary minerals, such as silicate minerals, which is a slow process that takes place over hundreds to thousands of years. This relation also reflects the positive correlation between groundwater age and pH. Geochemical modeling predicted that the dominant species of As, Mo, and V in solution were oxyanions (HAsO 4 2&ndash; , MoO 4 2&ndash; , and H 2 VO 4&ndash; ), which are likely to be mobile in alkaline groundwater because mineral surfaces composing aquifer matrices have a predominantly negative surface charge under alkaline conditions. F also exists predominantly as a negatively charged ion (F &ndash; ). At pH values >7.5, saturation indices generated by the geochemical modeling program PHREEQC indicated that F solubility may be somewhat limited by the precipitation of the mineral fluorapatite [Ca 5 (PO 4 ) 3 F]. Speciation modeling of As in anoxic-Fe groundwater (iron-reducing conditions) showed that samples were supersaturated with orpiment (As 2 S 3 ), indicating that mineral precipitation may be responsible for low As concentrations observed in reducing groundwater. In contrast, U concentrations showed significant negative correlations to groundwater age and to pH. Higher U concentrations generally occurred in samples for which geochemical modeling indicated that the uncharged ternary complex Ca 2 UO 2 (CO 3 ) 3 was the dominant aqueous U species. This uncharged complex is not attracted to the charged surfaces of minerals and thus increases U solubility. Formation of Ca 2 UO 2 (CO 3 ) 3 was greater in younger groundwaters because calcium and uranium concentrations generally were lower in older groundwaters, likely due to cation-exchange processes and precipitation of the mineral calcite as groundwater pH increased. Co-precipitation of U with the calcite (CaCO 3 ) may remove U from the aqueous phase. Saturation indices indicated that the anoxic-Fe groundwaters from the Colorado River study area were supersaturated with the mineral uraninite (UO 2 ), suggesting that UO 2 precipitation may be responsible for the low concentrations of U observed in these samples. Concentrations of strontium, which exists primarily in a cationic form (Sr 2+ ), were not significantly correlated with either groundwater age or pH. Strontium concentrations showed a strong positive correlation with total dissolved solids (TDS). Dissolved constituents, such as Sr, that interact with mineral surfaces through outer-sphere complexation become increasingly soluble with increasing TDS concentrations of groundwater. Boron concentrations also showed a significant positive correlation with TDS, indicating the B may interact to a large degree with mineral surfaces through outer-sphere complexation.

California↗
USGS2017

Status and understanding of groundwater quality in the Bear Valley and Lake Arrowhead Watershed Study Unit, 2010: California GAMA Priority Basin Project

Groundwater quality in the 112-square-mile Bear Valley and Lake Arrowhead Watershed (BEAR) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit comprises two study areas (Bear Valley and Lake Arrowhead Watershed) in southern California in San Bernardino County. The GAMA-PBP is conducted by the California State Water Resources Control Board (SWRCB) in cooperation with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA BEAR study was designed to provide a spatially balanced, robust assessment of the quality of untreated (raw) groundwater from the primary aquifer systems in the two study areas of the BEAR study unit. The assessment is based on water-quality collected by the USGS from 38 sites (27 grid and 11 understanding) during 2010 and on water-quality data from the SWRCB-Division of Drinking Water (DDW) database. The primary aquifer system is defined by springs and the perforation intervals of wells listed in the SWRCB-DDW water-quality database for the BEAR study unit. This study included two types of assessments: (1) a status assessment , which characterized the status of the quality of the groundwater resource as of 2010 by using data from samples analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements, and (2) an understanding assessment , which evaluated the natural and human factors potentially affecting the groundwater quality. The assessments were intended to characterize the quality of groundwater resources in the primary aquifer system of the BEAR study unit, not the treated drinking water delivered to consumers. Bear Valley study area and the Lake Arrowhead Watershed study area were also compared statistically on the basis of water-quality results and factors potentially affecting the groundwater quality. Relative concentrations (RCs), which are sample concentration of a particular constituent divided by its associated health- or aesthetic-based benchmark concentrations, were used for evaluating the groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. An RC greater than 1.0 indicates a concentration greater than a benchmark. Organic (volatile organic compounds and pesticides) and special-interest (perchlorate) constituent RCs were classified as “high” (RC greater than 1.0), “moderate” (RC less than or equal to 1.0 and greater than 0.1), or “low” (RC less than or equal to 0.1). For inorganic (radioactive, trace element, major ion, and nutrient) constituents, the boundary between low and moderate RCs was set at 0.5. Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating groundwater quality at the study-unit scale or for its component areas. High aquifer-scale proportion was defined as the percentage of the area of the primary aquifer system with a RC greater than 1.0 for a particular constituent or class of constituents; the percentage is based on area rather than volume. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifer system with moderate and low RCs, respectively. A spatially weighted statistical approach was used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. The status assessment for the Bear Valley study area found that inorganic constituents with health-based benchmarks were detected at high RCs in 9.0 percent of the primary aquifer system and at moderate RCs in 13 percent. The high RCs of inorganic constituents primarily reflected high aquifer-scale proportions of fluoride (in 5.4 percent of the primary aquifer system) and arsenic (3.6 percent). The RCs of organic constituents with health-based benchmarks were high in 1.0 percent of the primary aquifer system, moderate in 8.1 percent, and low in 70 percent. Organic constituents were detected in 79 percent of the primary aquifer system. Two groups of organic constituents and two individual organic constituents were detected at frequencies greater than 10 percent of samples from the USGS grid sites: trihalomethanes (THMs), solvents, methyl tert -butyl ether (MTBE), and simazine. The special-interest constituent perchlorate was detected in 93 percent of the primary aquifer system; it was detected at moderate RCs in 7.1 percent and at low RCs in 86 percent. The status assessment in the Lake Arrowhead Watershed study area showed that inorganic constituents with human-health benchmarks were detected at high RCs in 25 percent of the primary aquifer system and at moderate RCs in 41 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of radon‑222 (in 62 percent of the primary aquifer system) and uranium (26 percent). RCs of organic constituents with health-based benchmarks were moderate in 7.7 percent of the primary aquifer system and low in 46 percent. Organic constituents were detected in 54 percent of the primary aquifer system. The only organic constituents that were detected at frequencies greater than 10 percent of samples from the USGS grid sites were THMs. Perchlorate was detected in 62 percent of the primary aquifer system at uniformly low RCs. The second component of this study, the understanding assessment , identified the natural and human factors that could have affected the groundwater quality in the BEAR study unit by evaluating statistical correlations between water-quality constituents and potential explanatory factors. The potential explanatory factors evaluated were land use (including density of septic tanks and leaking or formerly leaking underground fuel tanks), site type, aquifer lithology, well construction (well depth and depth to the top-of-perforated interval), elevation, aridity index, groundwater-age distribution, and oxidation-reduction condition (including pH and dissolved oxygen concentration). Results of the statistical evaluations were used to explain the distribution of constituents in groundwater of the BEAR study unit. In the Bear Valley study area, high and moderate RCs of fluoride were found in sites known to be influenced by hydrothermic conditions or that had high concentrations of fluoride historically. The high RC of arsenic can likely be attributed to desorption of arsenic from aquifer sediments saturated in old groundwater with high pH under reducing conditions. The THMs were detected more frequently at USGS grid sites that were wells, part of a large urban water system, and surrounded by urban land use. Solvents, MTBE, and simazine were all detected more frequently at USGS grid sites that were wells with a greater urban percentage of surrounding land use and that accessed older groundwater than other USGS grid sites. Comparison between the observed and predicted detection frequencies of perchlorate at USGS grid sites indicated that anthropogenic sources could have contributed to low levels of perchlorate in the groundwater of the Bear Valley study area. In the Lake Arrowhead Watershed study area, high and moderate RCs of radon-222 and uranium can be attributed to older groundwater from the granitic fractured-rock primary aquifer system. Low RCs of THMs were detected at USGS grid sites that were wells and part of small water systems. The similarities between the observed and predicted detection frequencies of perchlorate in samples from USGS grid sites indicated that the source and distribution of perchlorate were most likely attributable to precipitation (rain and snow), with minimal, if any, contribution from anthropogenic sources.

California↗
USGS2020

Groundwater quality and geochemistry of West Virginia’s southern coal fields

Coal mining has been the dominant industry and land use in West Virginia’s southern coal fields since the mid-1800s. Mortality rates for a variety of serious chronic conditions, such as diabetes, heart disease, and some forms of cancer in Appalachian coal mining regions, are higher than in areas lacking substantial coal mining activity within the Appalachian Region or elsewhere in the United States. Causes of the increased mortality and morbidity are not clear, but poor diet, high rates of smoking, socioeconomic factors, and the quality of groundwater used by area residents are all possible contributing factors. This study was conducted by the U.S. Geological Survey in cooperation with the West Virginia Department of Health and Human Resources and the West Virginia Department of Environmental Protection, with grant support from the Centers for Disease Control and Prevention (CDC) to assess the quality of groundwater in southern West Virginia. The data from this assessment of groundwater quality may be used by the CDC and other agencies to potentially investigate the role or lack thereof of groundwater quality with respect to mortality and morbidity rates in the region. The study was conducted in a region where a high density of current or past coal mining combined with a lack of advanced sewage treatment could affect concentrations of commonly occurring constituents plus contaminants, including nitrate, trace metals, major ions, indicator bacteria, radon, hydrogen sulfide, and dissolved hydrocarbons. Because rural residential wells and mine outfalls are considered private sources of water in the region, and are therefore unregulated and unmonitored, water-quality data are sparse. To fill the data gap and assess the groundwater quality in the region, water-quality samples were collected from 60 sites in a 10-county area. The 60 sites sampled included 46 rural residential homeowner wells and 14 mine outfall discharges used for residential supply. For this study, all samples were collected prior to any filtration or other treatments, typically at the pressure tank, and are indicative of total and dissolved constituents in the untreated water. Generally, data for the 60 sites indicate that most waters sampled do not exceed thresholds for most U.S. Environmental Protection Agency (EPA) drinking-water standards and U.S. Geological Survey (USGS) drinking-water screening criteria. However, there were several notable exceptions. Turbidity exceeded the 5-Nephelometric Turbidity Unit (NTU) EPA treatment technique (TT) drinking-water standard in 14 of 60 (23 percent) sites sampled and exceeded the 1-NTU TT standard in 51 of 60 (85 percent) sites sampled. Turbidity is common in many wells in southern West Virginia and may be attributed to iron oxyhydroxide precipitates, sediment carried into the aquifers from the shallow soil zone due to improperly constructed or cased wells or transported to the aquifer in shallow stress-relief fracture zones or through permeable bedding-plane partings. For the sites sampled, 31 of 60 (52 percent) had pH values at, above, or below the upper and lower range of the EPA Secondary Maximum Contaminant Level (SMCL, 6.5–8.5 standard units). Of those 31 sites, 28 (90 percent) were indicative of acidic corrosive water and 3 (10 percent) were indicative of alkaline water. The Langelier Saturation Index (LSI), which is a measure of the corrosivity of the water, was computed for all sites sampled for the study. Eighty-two percent of the sites sampled had waters that were classified as corrosive, based on a LSI less than −0.5. Corrosive water has the potential to leach lead, copper, and other metals from lead, copper, galvanized, or lead-tin soldered connections in water lines. The chloride to sulfate mass ratio also was assessed with the alkalinity to indicate the potential to promote galvanic corrosion (PPGC) of water lines and plumbing fixtures. Only one of the sites (1.7 percent) classified as a corrosive water site, had a PPGC considered high; the remaining sites were classified as having either a moderate (53.3 percent) or low (45 percent) PPGC. Therefore, the type of plumbing systems sampled for this study may be affected by corrosive water, but the potential for leaching trace metals and other constituents from residential plumbing systems containing older galvanized pipes or lead-tin soldered copper pipes is moderate to low. The indicator bacteria total coliform and Escherichia coli ( E. coli ) also were detected in groundwater samples to varying degrees. Total coliforms, which are a broad class of indicator bacteria, are common in groundwater in southern West Virginia and were detected in 39 of the 60 sites (65 percent) sampled. The presence of total coliform bacteria is a potential indicator of surface contamination, due to improperly constructed or cased wells, or infiltration of soil or other surface contaminants into the aquifer or well bore. E. coli bacteria, however, are much more indicative of fecal contamination of groundwater from either human or animal sources, and 14 of the 60 (23 percent) sites sampled had detections of E. coli . Although only a few strains of E. coli are known pathogens, their presence in groundwater may be an indicator of other related pathogens such as viruses and should be regarded as a serious potential issue. Water treatment such as chlorination, ozonation, or ultraviolet light may be appropriate to kill potential pathogenic bacteria or viruses in the source water. Manganese and iron were prevalent contaminants in the groundwater samples collected for this study, with 30 of 60 (50 percent) sites analyzed for manganese and 25 of 60 (42 percent) sites analyzed for iron exceeding the proposed 50- and 300-micrograms per liter (µg/L) SMCL drinking-water standards, respectively, for aesthetic criteria such as taste, odor, or staining of plumbing fixtures. Fourteen of the 60 sites sampled (23 percent) had concentrations of manganese that exceeded the 300-µg/L USGS health-based screening level, and 1 site exceeded the 1,600-µg/L EPA drinking-water equivalent level, which is based on a lifetime exposure level. Sodium is another common constituent in groundwater within the study area. Sodium has an EPA health-based value (HBV) of 20 milligrams per liter (mg/L) for individuals who are on a sodium-restricted diet for blood pressure or other health reasons. Sodium concentrations exceeded the 20-mg/L EPA HBV in 27 of 60 (45 percent) samples. Radon, a naturally occurring carcinogenic radioactive gas known to cause lung cancer, was detected at concentrations at or exceeding the proposed 300-picocuries per liter (pCi/L) EPA Maximum Contaminant Level (MCL) in 12 of the 60 (20 percent) sites sampled. Sites with radon gas concentrations exceeding the 300-pCi/L proposed MCL have the potential for airborne concentrations of radon to exceed the 4-pCi/L indoor air standard. Inhalation of radon can cause lung cancer, and the 4-pCi/L indoor air standard is based on an inhalation standard. Therefore, homeowners whose wells have radon gas concentrations exceeding 300 pCi/L may be advised to have their indoor air tested to determine if indoor air concentrations exceed the 4-pCi/L indoor air standard established by the EPA. Various factors were analyzed statistically and graphically to determine whether they have an influence on groundwater quality within the study area, including topographic setting, well depth, type of mining (surface or underground), type of site (well or mine outfall), and geologic formation. Only geologic formation and the type of site sampled had strong statistical correlations with one or more of the constituents of concern for this study. The overall chemistry of outfalls (mine outfalls) and wells was significantly different, with a much higher dissolved oxygen content in outfalls than in wells. The dissolved oxygen content is the primary component driving the oxidation and reduction of minerals, and the precipitation of minerals that are saturated or super saturated with respect to various cations and anions. Median dissolved oxygen concentrations for the outfalls sampled was 8.75 mg/L, and only 0.4 mg/L for the wells sampled. Median concentrations of sulfate and selenium were much higher in waters from the outfalls sampled, with median concentrations of 73.75 mg/L and 2.35 µg/L, respectively, compared to the wells sampled, which had median concentrations of 18.3 mg/L and less than (<) the 0.05-µg/L method detection limit, respectively. The maximum selenium concentration was for a well, with a concentration of 16.6 µg/L. The geochemical processes that control sulfate and selenium concentrations in groundwater are similar and are the result of the oxidation of sulfide minerals such as pyrite and ferroselite. Iron and manganese concentrations were elevated in most of the wells sampled, with median concentrations of 269.5 and 124.5 µg/L, respectively, but were rarely detected in the outfalls sampled, with median concentrations of < 4.0 and < 0.4 µg/L, respectively. The difference in iron and manganese between wells and outfalls is indicative of the role of dissolved oxygen on processes controlling groundwater chemistry in the region. Three principal geologic formations were assessed for the study, and the overall chemistry for the Pocahontas, New River, and Kanawha Formations varied substantially with respect to several constituents. Concentrations of calcium, magnesium, and total dissolved solids were highest for sites sampled in the Pocahontas Formation, with median concentrations of 41.9, 18.6, and 312 mg/L, respectively. For constituents that are commonly associated with mining activity, the highest concentrations were for sites sampled in the New River Formation, with median concentrations of iron and manganese of 2,450 µg/L and 482 µg/L, respectively, and a median pH of 6.35 standard units. Concentrations of barium also were elevated in samples collected from sites in the New River Formation, with a median barium concentration of 184 µg/L. The source of the barium is not fully known but may be associated with commingling of shallow groundwater with deeper brines or dissolution of the mineral barite. The highest median sulfate concentrations were from sites sampled in the Pocahontas Formation, with a median concentration of 64.0 mg/L. Of the 12 sites at or exceeding the 300-pCi/L proposed drinking-water standard for radon, 8 (67 percent of MCL exceedances) were for sites deriving water from the Kanawha Formation, 3 (25 percent of MCL exceedances) were for sites deriving water from the New River Formation, and only 1 site was for water from the Pocahontas Formation (8 percent of proposed MCL exceedances). Dissolved hydrocarbons, including methane, ethane, propane, propene, n - and i -butane, 1-butene, n - and i -pentane, pentane, 2- and 3-ethyl pentane, hexane, and benzene were analyzed in samples collected from 59 of the 60 sites to assess the potential occurrence and sources of these trace gases in groundwater within the study area. Results of the analysis indicate that most of the gas is of shallow biogenic origin, possibly associated with coal-bed methane, but a subset of samples has a gas signature and a chloride to bromide ratio indicative of potential mixing with deeper thermogenic gases. Only 2 of the 59 (3.3 percent) sites sampled had concentrations of methane gas, which is a highly combustible and explosive gas, exceeding the 10 milligrams per kilogram level of concern established by the U.S. Office of Surface Mining Reclamation and Enforcement. Principal components analysis was used to assess the primary geochemical processes occurring in the aquifers sampled. The first principal component had significant positive loadings for bromide, chloride, silica, ammonia, barium, iron, manganese, and arsenic, and significant negative loadings for dissolved oxygen, potassium, nitrate, and uranium, and reflects reduction and oxidation (redox) processes occurring in deeper anoxic groundwater or shallow oxic groundwater. The strong positive loadings for iron, manganese, barium, and arsenic are correlated with reducing conditions often found deeper in the aquifer. More oxic water is correlated with oxidation of nitrogen species to nitrate and environmental mobilization of uranium and sulfate in shallow wells and mine outfalls.

West Virginia↗
USGS2020

Geochemical and mineralogical study of the Red Mountain porphyry copper-molybdenum deposit and vicinity, Santa Cruz County, Arizona

The Red Mountain porphyry copper-molybdenum deposit (Cu-Mo deposit or PCD) is located in the northern part of the Patagonia Mountains, Santa Cruz County, Arizona. Extensive core drilling has delineated a large, deep-seated, structurally intact mineral system that extends from the present surface to depths of more than 1,765 meters. This system is hosted in a thick complex of predominantly felsic to andesitic volcanic rocks of the Cretaceous Period. This complex was intruded by scattered bodies of the Tertiary Period that are predominantly quartz monzonite porphyry; no major associated source intrusion has yet been found at depth. A total of 818 samples of core were analyzed for as many as 44 elements. The abundances and distributions at depth of at least 17 of these elements (silver [Ag], arsenic [As], gold [Au], boron [B], bismuth [Bi], copper [Cu], mercury [Hg], potassium [K], molybdenum [Mo], lead [Pb], sulfur [S], antimony [Sb], tin [Sn], tellurium [Te], thallium [Tl], tungsten [W], and zinc [Zn]) are related mostly to events that generated the Red Mountain system. Many of these same samples were also analyzed by X-ray diffraction for a suite of minerals. The multielement and mineralogical analyses of the core samples provide important information about the concentrations, associations, and distributions of select elements and minerals, including zoning patterns that may not be apparent from visual examination of core samples. The distributions of selected elements and minerals in these samples reveal an unusually complete mineral system that extends from a typical PCD with potassic alteration at depth to peripheral zones of phyllic and advanced argillic alteration as well as a copper-rich supergene enriched zone and the remnants of a leached cap. R-mode factor analysis was run with 34 elements for a set of samples from the deep part of the hypogene Cu-Mo deposit and another set from the part of the supergene zone with the highest copper enrichment. For the hypogene zone dataset, five factors are related to the PCD: (1) Ag, Cu, Mo, S, and Te; (2) As, B, Hg, and Sb; (3) Au and sodium (Na); (4) manganese (Mn), Pb, and Zn; and (5) K and Tl. For the supergene dataset, the deposit-related factors include (1) Cu, Mo, S, and Te; (2) Ag, As, Hg, Pb, Sb, and Tl; (3) Au and Na; and (4) K and rubidium (Rb). The changes in element associations between the two datasets indicate that some of these new associations are a result of formation of several suites of hypogene minerals in the deep part of the deposit and different hypogene mineral suites in the peripheral part of the deposit. Some changes may be because of the effects of supergene processes. Zones containing deposit-related elements and minerals common to many PCDs are present at Red Mountain. These zones include a crude, inverted cup-shaped shell containing anomalous copper accompanied by high concentrations of Ag, Au, K, Mo, total S, sulfate S, Sb, Te, and Tl, as well as local concentrations of As, B, Hg, Pb, and Zn. Hydrothermal minerals spatially associated with the deep hypogene Cu-Mo deposit include chalcopyrite, molybdenite, pyrite, plagioclase, orthoclase, biotite, magnetite, calcite, quartz, and anhydrite. Many of the hydrothermally deposited elements that are spatially related to the deposit are also concentrated in zones above the deep part of the deposit, including Ag, As, K, Pb, Sb, Te, Tl, and Zn. These elements are concentrated either (1) in generally wide, flat zones present in the upper part of the system or (2) in crudely arcuate peripheral zones found mainly in the middle part of the system and surrounding the deep part of the deposit. Near-surface, restricted hypogene anomalies are present for bismuth, mercury, tin, and tungsten. The upper part of the deposit has been subjected to supergene enrichment and weathering. Deposit-related elements that remain anomalous in this area include Ag, As, Au, B, Bi, cobalt (Co), Cu, Hg, Mo, Pb, S, Sb, Sn, Te, Tl, uranium (U), and W. These positive concentrations indicate that, with the exception of copper and possibly mercury and uranium, these elements had relatively low chemical mobilities in the supergene enrichment and later weathering environments at Red Mountain. Most may have been deposited during one or more hypogene events and then redistributed locally during later events. Zinc is the only deposit-related element that has clearly been depleted as a result of supergene and (or) weathering events. Minerals that are common in the unweathered upper part of the system include chalcocite, pyrite, quartz, sericite, alunite, and pyrophyllite, as well as less common covellite, enargite, tennantite, tourmaline, barite, anglesite, and other sulfide or sulfate minerals. Subsequent to formation of the Red Mountain Cu-Mo deposit and supergene enrichment, chemical weathering produced an area of pervasive hematite and other iron oxides in the near-surface part of the deposit to form a leached cap. These iron-rich minerals formed primarily as a result of the oxidation of pyrite. This event was accompanied by losses of cobalt, mercury, magnesium, and zinc, as well as destruction of sericite, plagioclase, pyrite, clay minerals, and pyrophyllite. A total of 122 rock samples, 119 soil samples, and samples of three plant species (57 mesquite, 108 oak, and 68 juniper) were collected over and around Red Mountain. For the rock and soil samples, the distributions of anomalous Ag, As, Bi, Cu, Fe, Mo, Pb, Sb, Te, and Tl best delineated the exposed part of the deposit. The highest concentrations of many of these elements are centered on one or both of two main areas with exposures of quartz monzonite porphyry. The high concentrations of arsenic in the deposit area (as much as 390 parts per million (ppm) in rock and 1,500 ppm in soil) and of lead (as much as 2,370 ppm in rock and 1,490 ppm in soil) are particularly noteworthy. The concentrations of various elements in the plant ash vary widely among the three species and are species dependent. Many of the deposit-related elements are either nonessential for plant growth or are considered toxic at certain concentration ranges. In spite of this, the distributions of potentially toxic Ag, As, Bi, Cd, Cu, Mo, Pb, Sb, selenium (Se), and Zn produce deposit-related anomalies for one or more of the three species. Vegetation sampling offered no advantage over rock or soil sampling as an exploration tool. From an environmental standpoint, however, the plant analyses provide baseline data for both essential and nonessential elements that might be useful, for example, for selecting native plant species for revegetating mine waste areas. The exposed part of the Red Mountain deposit has not been greatly disturbed as a result of mining and other activities. However, some of the rock, soil, and plant samples that were collected near the Harshaw Creek and Alum Gulch drainages, which are peripheral to Red Mountain, are also anomalous for various deposit-related elements. These anomalies are probably the result of dispersion of stream sediments contaminated with material from past mining.

Arizona↗
USGS2020

Groundwater quality in relation to drinking water health standards and hydrogeologic and geochemical characteristics for 47 domestic wells in Potter County, Pennsylvania, 2017

As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, water samples from 47 domestic wells in Potter County were collected from May through September 2017. The sampled wells had depths ranging from 33 to 600 feet in sandstone, shale, or siltstone aquifers. Groundwater samples were analyzed for physicochemical properties that could be evaluated in relation to drinking-water health standards, geology, land use, and other environmental factors. Laboratory analyses included concentrations of major ions, nutrients, bacteria, trace elements, volatile organic compounds (VOCs), ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. Results of this 2017 study show that groundwater quality generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded maximum contaminant levels (MCLs) for total coliform bacteria (69.6 percent), Escherichia coli (30.4 percent), arsenic, and barium; and secondary maximum contaminant levels (SMCLs) for field pH, manganese, sodium, iron, total dissolved solids, aluminum, and chloride. All of the analyzed VOCs were below limits of detection and associated drinking water criteria. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter in 80.9 percent of the samples. The field pH of the groundwater ranged from 4.6 to 9.0. Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH values outside this range. Calcium/bicarbonate waters were the predominant hydrochemical type for the sampled aquifers, with mixed water types for many samples, including variable contributions from calcium, magnesium, and sodium combined with bicarbonate, sulfate, chloride, and nitrate. Water from 45 wells had concentrations of methane greater than the 0.0002 milligrams per liter (mg/L) detection limit. One sample had the maximum value of 11 mg/L, which exceeds the Pennsylvania action level of 7 mg/L. Additionally, three other samples had concentrations of methane greater than 4 mg/L. Outgassing of such levels of methane from the water to air within a confined space can result in a potential hazard. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH with relatively elevated concentrations of iron, manganese, ammonia, lithium, fluoride, and boron. Other constituents, including barium, sodium, chloride, and bromide, commonly were elevated, but not limited to, those well-water samples with elevated methane. Low levels of ethane (as much as 1.2 mg/L) were present in eight samples with the highest methane concentrations. Five samples were analyzed for methane isotopes. The isotopic and hydrocarbon compositions in these five samples suggest the methane may be of microbial origin or a mixture of thermogenic and microbial gas, but differed from the compositions reported for mud-gas logging samples collected during drilling of gas wells. The concentrations of sodium (median 8.2 mg/L), chloride (median 7.64 mg/L), and bromide (median 0.02 mg/L) for the 47 groundwater samples collected for this study ranged widely and were positively correlated with one another and with specific conductance and associated measures of ionic strength. Sixty percent of the Potter County well-water samples had chloride concentrations less than 10 mg/L. Samples with higher chloride concentrations had variable bromide concentrations and corresponding chloride/bromide ratios that are consistent with sources such as road-deicing salt and septic effluent (low bromide) or brine (high bromide). Brines are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. It is also possible that valley wells were drilled close to or into the brine-freshwater interface, so brine signatures do not necessarily indicate contamination due to drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. Although 1 of 8 groundwater samples with the highest methane concentrations (greater than 0.2 mg/L) had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with road-deicing salt, the other 7 of 8 samples with elevated methane had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported. Approximately 50 percent of Potter County well-water samples, including two samples with the fourth (72.9 mg/L) and fifth (47.0 mg/L) highest chloride concentrations, have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt or septic effluent.

Pennsylvania↗
USGS2020

Geochemical assessment of the Hueco Bolson, New Mexico and Texas, 2016–17

Understanding groundwater quality in transboundary aquifers like the Hueco Bolson is important for the 2.7 million people along the United States and Mexico border living in and near the combined metropolitan areas of Ciudad Juárez, Mexico, and El Paso, Texas, who rely on groundwater for water supply. To better understand water-quality conditions in the Mexico–New Mexico–Texas transboundary area, 23 water-supply wells were sampled in the Hueco Bolson within the United States near El Paso, Tex., during August–September 2016 and May–June 2017. Groundwater samples were analyzed for physical properties, major ions, dissolved solids, nutrients, trace elements, organic compounds, and selected isotopes such as strontium, hydrogen, oxygen, tritium, and carbon-14. Most of the water samples from the Hueco Bolson water-supply wells were classified as a sodium-chloride type water. Only four wells sampled in the study area had dissolved-solids concentrations greater than 1,000 milligrams per liter (mg/L), with three of those wells closest to the Rio Grande/Río Bravo del Norte (hereinafter referred to as the Rio Grande). Nitrate concentrations in the groundwater samples collected in the study area ranged from below the long-term method detection level of 0.04 to 6.2 mg/L. Arsenic was the only trace element detected in the wells sampled that had concentrations exceeding the designated drinking-water standard of 10 micrograms per liter (μg/L). Four of the 23 wells had arsenic concentrations greater than 10 μg/L, and these wells were all located near the Rio Grande. Three of the wells with the highest uranium concentrations (greater than 10 μg/L) were also located near the Rio Grande, and two of those wells were the same wells that had arsenic concentrations greater than 10 μg/L. Groundwater samples were analyzed for 83 organic compounds, but only 6 were detected—simazine, prometryn, prometon, atrazine, deethylatrazine, and dichloroaniline. All concentrations for the organic compounds detected were less than 0.03 μg/L, and the detections were only in five groundwater wells, three of which were located near the Rio Grande. Strontium, hydrogen, and oxygen isotopic values indicate that recharge water to the central and northern sections of the study area originates from near the Franklin Mountains, whereas groundwater in the southern section of the study area is likely from the Rio Grande valley. Tritium and carbon-14 values indicate that most of the wells that were sampled contained water that is considered premodern, which means that it is more than several hundred years old. Three wells with modern groundwater (approximately less than 70 years old) are located near the Rio Grande and are the same wells that had elevated arsenic or uranium concentrations and organic compound detections. Most of the results of the geochemical analyses indicate that groundwater near the Rio Grande has higher dissolved-solids concentrations, higher concentrations of several trace elements, and slightly more organic compound detections than the groundwater farther away from the Rio Grande; therefore, the groundwater may be affected by the Rio Grande and surrounding land-use activities.

New Mexico, Texas↗
USGS2024

Status and understanding of groundwater quality in the Mojave Basin Domestic-Supply Aquifer study unit, 2018—California GAMA Priority Basin Project

Groundwater quality in the western part of the Mojave Desert in San Bernardino County, California, was investigated in 2018 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The Mojave Basin Domestic-Supply Aquifer study unit (MOBS) region was divided into two study areas—floodplain and regional—to assess differences between the two major aquifers used for drinking water supply in the area. This assessment characterized the quality of ambient groundwater and not the quality of treated drinking water. The study included three components: (1) a status assessment, which characterized the quality of groundwater resources used for domestic drinking-water supply in the floodplain and regional study areas; (2) a brief understanding assessment, which evaluated factors that could potentially affect the quality of groundwater used by domestic wells in the region; and (3) a comparative assessment between the groundwater resources used by domestic wells and public-supply wells in the two study areas. The domestic-well assessment was based on data collected by the U.S. Geological Survey from 48 domestic wells in January–May 2018. The public-supply assessment was based on data for samples from 322 public-supply wells in 2008–18, either collected by the U.S. Geological Survey or compiled from the California State Water Resources Control Boards Division of Drinking Water publicly available database. Concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. Relative concentrations, defined as the measured concentration divided by the benchmark concentration, were classified as high (greater than 1.0), moderate (greater than 0.5 for inorganic constituents or 0.1 for organic and special-interest constituents, and not high), or low (concentrations lower than moderate). The floodplain and regional study areas were divided into 15 and 35 grid cells, respectively, and grid-based methods were used to compute the areal proportions of the two study areas with high, moderate, or low relative concentrations of individual constituents and classes of constituents. For the domestic-supply assessment, one or more inorganic constituents with health-based benchmarks were detected at high relative concentrations in 58 percent of the regional study area and 13 percent of the floodplain study area. The inorganic constituents with health-based benchmarks detected at high relative concentrations in the regional study area were arsenic, chromium and hexavalent chromium, fluoride, adjusted gross alpha particle activity, uranium, molybdenum, strontium, and nitrate; only arsenic was detected at high relative concentrations in the floodplain study area. One or more inorganic constituents with secondary maximum contaminant level benchmarks were detected at high concentrations in 15 and 6.7 percent of the regional and floodplain study areas, respectively. The constituents detected at high relative concentrations in the regional study area were total dissolved solids, chloride, sulfate, and iron; only total dissolved solids and sulfate were detected at high relative concentrations in the floodplain study area. Organic constituents were not detected at moderate or high relative concentrations in either the regional or floodplain study areas. Volatile organic compounds were detected at low relative concentrations in 21 and 27 percent of the regional and floodplain study areas, respectively, and pesticides were detected at low relative concentrations in 9.1 and 20 percent of the regional and floodplain study areas, respectively. The only individual organic constituent detected in more than 10 percent of either study area was the trihalomethane trichloromethane. Total coliform bacteria were detected in 15 and 27 percent of the grid wells in the regional and floodplain study areas, respectively. The greater prevalence of high relative concentrations of many inorganic constituents in the regional study area compared to the floodplain area likely indicates the greater diversity of geologic material at depth in aquifer material and generally finer-grained alluvium compared to the floodplain study area combined with generally older groundwater that has had more contact time with aquifer materials. In general, trace element concentrations (1) increased with increasing groundwater age, (2) increased with distance from recharge sources in the mountains, and (3) increased with closer proximity to some types of geological units. In general, groundwater from domestic wells in the floodplain study area is young, with most samples containing a component of modern groundwater based on tritium and unadjusted carbon-14 activities, whereas groundwater from domestic wells in the regional study area generally is old, with most samples having unadjusted carbon-14 ages of 5,000–40,000 years. Public-supply wells in MOBS generally were deeper than domestic wells and presumably are in contact with older, more weathered alluvium that may have more mobile trace elements, such as arsenic or uranium. However, only 26 percent of the public-supply regional study area had high relative concentrations of inorganic constituents, compared to 58 percent for the domestic regional study area. The percentages of the public-supply and domestic floodplain study areas with high relative concentrations of inorganic constituents were 11 and 13 percent, respectively. The ages of groundwater used by public-supply and domestic wells in each study area were similar, which was not expected given the greater depth of the public-supply wells. Three potential factors may contribute to these results: (1) greater spatial footprint of domestic well network, which may result in domestic wells pumping groundwater from fractured bedrock or mineralized areas not used by public-supply wells; (2) greater pumping rates in public-supply wells, resulting in more water being withdrawn from coarse-grained, heterogeneous alluvium than finer-grained layers, which may have higher concentrations of (or more mobile) inorganic constituents; and (3) a greater degree of well management with public-supply wells, which may include pausing use of or decommissioning wells if treating or blending water is not feasible to lower constituent concentrations.

California↗
USGS2026

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California↗
USGS1949

Preliminary results of prospecting of the "leached" zone over phosphate deposits in NW 1/4 of sec. 9, T. 31 S., R. 25 E., Polk County, Florida

The NW 1/4 Sec. 9 T. 31 S., R. 25 E. is underlain by a 4-to-15-foot thick layer of leached zone material in which the uranium content ranges from 0.001-0.018 percent. Several well defined areas of relatively high uranium content are outlined on figure 2. The International Minerals & Chemical Corporation wishes information as to the advisability of making plans for the stockpiling of this material.

Florida↗
USGS1949

Study of radioactive equilibrium in Carnotite ores of the Colorado Plateau

The purpose of this study was to determine the age of Colorado Plateau carnotite. In addition to quantitative analyses of uranium and lead, the radium-uranium equilibrium of each sample was studied. Of the 12 samples studied, 10 are deficient in radium. If a minimum age of 130 million years is chosen for the enclosing sediments, 11 samples are deficient in lead. This deficiency may be explained by (1) leaching of lead or (2) assuming too great an age. Three samples, chosen for lead-isotope analysis, have Pb 207 /Pb 206

Colorado↗
USGS1951

Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period April 1, 1948-December 31, 1950

This report summarizes the research work of the Trace Elements Section, Geochemistry and Petrology Branch, from the organization of the Section in April 1948 to December 31, 1950. The research undertaken thus far consists of laboratory and related field studies in the following fields: 1. Mineralogic and petrologic investigations of radioactive rocks, minerals, and ores. 2. Investigations of chemical methods of analysis for uranium, thorium, and other elements and compounds in radioactive materials, and related chemical problems. 3. Investigations of spectrographic methods of analysis for a wide variety of elements in radioactive materials. 4. Investigations of radiometric methods of analysis as applied to radioactive materials. It should be emphasized that the work undertaken thus far, described under the headings "Future work", is almost entirely in the nature of investigations supporting the field appraisal of known important uraniferous deposits. A comprehensive program of more fundamental research was submitted in April 1949 in a report entitled "Proposed program of desirable research in the geochemistry of uranium," but funds for this work have not been authorized. It is hoped, however, that funds to support basic research of the type indicated in that report may be available in the future. This report does not cover the analytical work of the Section nor the public-sample program. The analytical work has been summarized for the fiscal year 1950 in the report, "Numerical summary of the analytical work of the Trace Elements Section, Geochemistry and Petrology Branch, for the fiscal year 1950," by John C. Rabbit, U.S. Geol. Survey Trace Elements Memorandum Rept. 174, October 1950. A report on the public-sample program is in preparation. Much of the material in this report has been paraphrased from reports prepared by members of the Section. My special thanks are due them; to Earl Ingerson, chief of the Geochemistry and Petrology Branch of the Survey, for his critical review; to my secretary, Marie Woolihan, for her aid in collecting material; and to Virginia Layne of the editorial staff of the Section for typing the manuscript and the multilith mats.

Trace Elements Investigations↗
USGS1951

Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period January 1-March 31, 1951

This report summarized the research work of the Trace Elements Section, Geochemistry and Petrology Branch for the period January 1 - March 31, 1951. Work before that is summarized in an earlier report, "Summary of the research work of the Trace Elements Section, Geochemistry and Petrology Branch, for the period April 1, 1948 - December 31, 1950," by John C. Rabbitt (U.S. Geol. Survey Trace Elements Investigations Rept. 148, January 1951). This report will be referred to as TEIR 148. In TEIR 148 the purpose of each project was described and it is not thought necessary to repeat that material. The research work of the section consists of laboratory and related field studies in the following fields: 1. Mineralogic and petrologic investigations of radioactive rocks, minerals, and ores. 2. Investigations of chemical methods of analysis for uranium, thorium, and other elements and compounds in radioactive materials, and related chemical problems. 3. Investigations of spectographic method of analysis for a wide variety of elements in radioactive materials. 4. Investigation of radiometric methods of analysis is applied to radioactive materials. It should be emphasized that the work undertaken so far is almost entirely in the nature of investigations supporting the field appraisal of known uraniferous deposits. A program of more fundamental research, particularly in the mineralogy and geochemistry of uranium, is now being drawn up and will be submitted for approval soon. This report does not deal with the routine analytical work of the Section nor the public-sample program. The analytical work will be summarized in a report to be issued after the end of fiscal year 1951, and a report on the public-sample program is in process. Special thanks are due members of the Section who are engaged in the research work and who have supplied material for this report, the Early Ingerson, Chief of the Geochemistry and Petrology Branch for his critical review, to Jane Titcomb of the editorial staff of the Section for editing the report, and to Virginia Layne of the same staff, for typing the manuscript and the multilith mats.

Trace Elements Investigations↗
USGS1955

Geology of the Wood and East Calhoun mines, Central City District, Gilpin County, Colorado

The Wood-East Calhoun mine area is underlain by complexly folded Precambrian gneiss and pegmatite. The major fold in the area is an anticline that trends about N. 60° E. The Precambrian rocks are intruded by bostonite porphyry dikes of Tertiary age. All the rocks are cut by east- to northeast - trending faults that have been filled by precious metal-sulfide veins which have been worked chiefly for gold. The Wood vein occurs in an east-trending fault; the Calhoun vein occurs in a northeast-trending fault. Much of the uranium production of the Central City district has come from the Wood vein on Quartz Hill. The veins consist chiefly of quartz; pyrite is the chief metallic mineral and chalcopyrite is next in abundance. Sphalerite, galena, tetrahedrite-tennantite, and pitchblende are locally present. Deposition began with alteration-stage quartz and pyrite followed in order by pitchblend, light-yellow pyrite, massive quartz, yellow pyrite, shalerite, comb quartz, chalcopyrite, tetrahedrite-tennantite, galena, chalcopyrite, pyrite, and gray to light-brown fine-grained quartz. The veins of the Central City district are zoned, with quartz-pyrite veins near the center and galena-sphalerite veins on the periphery. The known pitchblende bodies are in the transition between these, but paragenetically, the pitchblende is earlier than all other metallic minerals. A trace element study of the ore indicates an association of zirconium and molybdenum with uranium, of bismuth, antimony, and arsenic with copper, and of cadmium with zinc. The pitchblende and other ore minerals are concentrated in ore shoots. The shoots are in open spaces controlled by the competency of the wall rocks, the presence of a prevailing direction of weakness in the rocks, and changes in strike and dip of the vein. The pitchblende is thought to be a local constituent of the quartz-pyrite ores and to owe its origin to residual solutions from the quartz bostonite magma.

Colorado↗
USGS1953

Radiometric reconnaissance in the Garfield and Taylor park quadrangles, Chaffee and Gunnison counties, Colorado

During the summer of 1952 most of the mines and prospects in the Garfield and Taylor Park quadrangles of west-central Colorado were examined radiometrically by the U. S. Geological Survey to determine the extent, grade, and mode of occurrence of radioactive substances. The region contains a relatively large number of rock types, chiefly pre-Cambrian schists, gneisses, and granites; large and small isolated areas of sedimentary rocks of Paleozoic and Mesozoic ages; and a great succession of intrusive rocks of Tertiary age that range from andesite to granite and occur as stocks, chonoliths, sills, dikes, and one batholith. The prevailing structures are northwest-trending folds and faults. Ores valued at about $30,000,000 have been produced from this region. Silver, lead, zinc, and gold have accounted for most of this value, but small tonnages of copper, tungsten, and molybdenum have also been produced. The principal ore minerals are sphalerite, silver-bearing galena, cerussite, smithsonite, and gold-bearing pyrite and limonite; they occur chiefly as replacement bodies in limestone and as shoots in pyritic quartz veins. Anomalous radioactivity is uncommon and the four localities at which it is known are widely separated in space. The uranium content of samples from these localities is low. Brannerite, the only uranium-bearing mineral positively identified in the region, occurs sparingly in a few pegmatites and in one quartz-beryl-pyrite vein. Elsewhere radioactivity is associated with (l) black shale seams in the Manitou dolomite, (2) a quartz-pyrite-molybdenite vein, (3) a narrow border zone of oxidized material surrounding a small lead zinc ore body in the Manitou dolomite along a strong fault zone.

Colorado↗
USGS1953

The geology and mineralogy of the W. Wilson mine near Clancey, Jefferson County, Montana

The W. Wilson mine, near Clancey, Mont., explores a siliceous vein in quartz monzonite of the Boulder batholith. The vein is a composite structure that consists of several closely spaced veinlets of quartz and chalcedony separated by silicified quartz monzonite. The vein has been recurrently brecciated and silicified. Typically, the quartz monzonite has been hydrothermally altered in zones of decreasing intensity outward from the vein. Pitchblende was deposited in and along the vein during one stage of the silicification that is characterized by fine-grained disseminated pyrite in black chalcedony. Subsequently most of the pitchblende was oxidized and hydrated to form a series of brightly colored secondary uranium minerals that exhibit a zonal relationship. Most of the known uranium minerals are localized in two small elongate ore bodies.

Montana↗
USGS1955

Geology of the Huron River pitchblende occurrence, Baraga County, Michigan

Small quantities of uranium-bearing minerals were discovered by a geologist of the Jones and Laughlin Ore Company during the summer of 1949 along the East Branch of the Huron River, sec. 1, T. 51 N., R. 30 W., Baraga County, Mich. Subsequent diamond drilling of the prospect by the Jones and Laughlin Ore Company and the Ford Motor Company disclosed only minor amounts of radioactive materials at shallow depths in the immediate vicinity of the surface showings. Pitchblende and secondary uranium minerals occur as very small, discontinuous stringers and pods in calcite and quartz cementing the breccia within a low-angle shear zone that dips about 10 degrees to the southwest. The shear zone has a thickness of 10 to 30 feet and cuts black, locally carbonaceous slates of the upper Huronian Precambrian Michigamme slate. Mineral deposition during two hypogene stages and one supergene stage was identified in polished sections. The first phase consisted of the introduction of quartz and minor hematite into the sheared slate. After fracturing of the quartz the second stage was initiated by deposition of calcite, pyrite, rutile, pitchblende, bornite, sphalerite, chalcopyrite, galena, and greenockite. The supergene stage consisted of the development of metatyuyamunite, chalcopyrite, chalcocite, covellite, cuprite, volborthite, malachite, and goethite.

Michigan↗