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Biomonitoring of Environmental Status and Trends (BEST) Program: Environmental contaminants and their effects on fish in the Yukon River Basin

This project collected, examined, and analyzed 217 fish representing three species at 10 stations in the U.S. portion of the Yukon River Basin (YRB) from May to October 2002. Four sampling sites were located on the Yukon River; two were located on the Porcupine River, and one site was on each of the Ray, Tanana, Tolavana, and Innoko Rivers. Norther pike ( Esox lucius ), longnose sucker ( Catostomus catostomus ), and burbot ( Lota lota ) were weighed and measured, and examined in the field for external and internal lesions, and liver, spleen, and gonads were weighed to compute somatic indices. Selected tissues and fluids were collected and preserved for analysis of fish health and reproductive biomarkers. Composite samples of whole fish from each station were grouped by species and gender and analyzed for organochlorines and elemental contaminants and for dioxin-like activity using H4IIE rat hepatoma cell bioassay.

Alaska↗

Sedimentation and Occurrence and Trends of Selected Chemical Constituents in Bottom Sediment, Empire Lake, Cherokee County, Kansas, 1905-2005

For about 100 years (1850-1950), the Tri-State Mining District in parts of southeast Kansas, southwest Missouri, and northeast Oklahoma was one of the primary sources of lead and zinc ore in the world. The mining activity in the Tri-State District has resulted in substantial historical and ongoing input of cadmium, lead, and zinc to the environment including Empire Lake in Cherokee County, southeast Kansas. The environmental contamination caused by the decades of mining activity resulted in southeast Cherokee County being listed on the U.S. Environmental Protection Agency's National Priority List as a superfund hazardous waste site in 1983. To provide some of the information needed to support efforts to restore the ecological health of Empire Lake, a 2-year study was begun by the U.S. Geological Survey in cooperation with the U.S. Fish and Wildlife Service and the Kansas Department of Health and Environment. A combination of sediment-thickness mapping and bottom-sediment coring was used to investigate sediment deposition and the occurrence of cadmium, lead, zinc, and other selected constituents in the bottom sediment of Empire Lake. The total estimated volume and mass of bottom sediment in Empire Lake were 44 million cubic feet and 2,400 million pounds, respectively. Most of the bottom sediment was located in the main body and the Shoal Creek arm of the reservoir. Minimal sedimentation was evident in the Spring River arm of the reservoir. The total mass of cadmium, lead, and zinc in the bottom sediment of Empire Lake was estimated to be 78,000 pounds, 650,000 pounds, and 12 million pounds, respectively. In the bottom sediment of Empire Lake, cadmium concentrations ranged from 7.3 to 76 mg/kg (milligrams per kilogram) with an overall median concentration of 29 mg/kg. Compared to an estimated background concentration of 0.4 mg/kg, the historical mining activity increased the median cadmium concentration by about 7,200 percent. Lead concentrations ranged from 100 to 950 mg/kg with an overall median concentration of 270 mg/kg. Compared to an estimated background concentration of 33 mg/kg, the median lead concentration was increased by about 720 percent as a result of mining activities. The range in zinc concentrations was 1,300 to 13,000 mg/kg with an overall median concentration of 4,900 mg/kg. Compared to an estimated background concentration of 92 mg/kg, the median zinc concentration was increased by about 5,200 percent. Within Empire Lake, the largest sediment concentrations of cadmium, lead, and zinc were measured in the main body of the reservoir. Within the Spring River arm of the reservoir, increased concentrations in the downstream direction likely were the result of tributary inflow from Short Creek, which drains an area that has been substantially affected by historical lead and zinc mining. Compared to nonenforceable sediment-quality guidelines, all Empire Lake sediment samples (representing 21 coring sites) had cadmium concentrations that exceeded the probable-effects guideline (4.98 mg/kg), which represents the concentration above which toxic biological effects usually or frequently occur. With one exception, cadmium concentrations exceeded the probable-effects guideline by about 180 to about 1,400 percent. With one exception, all sediment samples had lead concentrations that exceeded the probable-effects guideline (128 mg/kg) by about 10 to about 640 percent. All sediment samples had zinc concentrations that exceeded the probable-effects guideline (459 mg/kg) by about 180 to about 2,700 percent. Overall, cadmium, lead, and zinc concentrations in the bottom sediment of Empire Lake have decreased over time following the end of lead and zinc mining in the area. However, the concentrations in the most recently deposited bottom sediment (determined for 4 of 21 coring sites) still exceeded the probable-effects guideline by about 440 to 640 percent for cadmium, about 40 to 80 percent for lead, and about 580

Scientific Investigations Report↗

Potentiometric Surfaces and Water-Level Trends in the Cockfield and Wilcox Aquifers of Southern and Northeastern Arkansas, 2006

The Cockfield Formation of Claiborne Group and the Wilcox Group contain aquifers that provide sources of ground water in southern and northeastern Arkansas. In 2000, about 9.9 million gallons per day was withdrawn from the Cockfield Formation of Claiborne Group and about 22.2 million gallons per day was withdrawn from the Wilcox Group. Major withdrawals from the aquifers were for industrial and public water supplies. A study was conducted by the U.S. Geological Survey in cooperation with the Arkansas Natural Resources Commission and the Arkansas Geological Survey to determine the water level associated with the aquifers in the Cockfield Formation of Claiborne Group and the Wilcox Group in southern and northeastern Arkansas. During February and March 2006, 56 water-level measurements were made in wells completed in the Cockfield aquifer and 59 water-level measurements were made in wells completed in the Wilcox aquifer, 16 in southwestern and 43 in northeastern Arkansas. This report presents the results as potentiometric-surface maps and as long-term water-level hydrographs. The regional direction of ground-water flow in the Cockfield Formation of Claiborne Group generally is towards the east and southeast, away from the outcrop, except in areas of intense ground-water withdrawals, such as western Drew County, southeastern Lincoln County, southwestern Calhoun County, and near Crossett in Ashley County. There are three cones of depression indicated by relatively low water-level altitudes in southeastern Lincoln County, southwestern Calhoun County, and near Crossett in Ashley County. The lowest water-level altitude measured was 44 feet above the National Geodetic Vertical Datum of 1929 in Lincoln County; the highest water-level altitude measured was 346 feet above the National Geodetic Vertical Datum of 1929 in Columbia County at the outcrop area. Hydrographs from 40 wells with historical water levels from 1986 to 2006 were evaluated using linear regression to calculate the annual rise or decline. Calhoun and Cleveland Counties have mean annual rises from 0.01 to 0.07 feet per year. Arkansas, Ashley, Bradley, Chicot, Columbia, Drew, Lincoln, and Union Counties have mean annual declines from 0.4 to 0.55 feet per year. Desha County has a mean annual decline of about 1.35 feet per year. The direction of ground-water flow in the southwestern study area of the Wilcox Group generally is south and east. The lowest water-level altitude measured in southwestern Arkansas was 147 feet above the National Geodetic Vertical Datum of 1929 near the Ouachita River in Clark County; the highest water-level altitude measured was 397 feet above the National Geodetic Vertical Datum of 1929 in the outcrop area of Hempstead County. The direction of ground-water flow in the northeastern study area of the Wilcox Group generally is south and east. The lowest water-level altitude measured in northeastern Arkansas was 120 feet above the National Geodetic Vertical Datum of 1929 near West Memphis in Crittenden County; the highest water-level altitude measured was 368 feet above the National Geodetic Vertical Datum of 1929 on Crowleys Ridge in Clay County. Hydrographs from 28 wells with historical water levels from 1986 to 2006 were evaluated using linear regression to calculate the annual rise or decline. All 28 wells showed an annual decline from 1986 to 2006. Craighead, Greene, Mississippi, and Poinsett Counties have mean annual declines from 0.27 to 1.00 feet per year. Crittenden, Lee, and St. Francis Counties have mean annual declines from 1.39 to 1.64 feet per year.

Scientific Investigations Report↗

Matching magnetic trends and patterns across the Tintina fault, Alaska and Canada--evidence for offset of about 490 kilometers: Chapter C in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

Magnetic anomaly patterns on opposite sides of the mapped Tintina fault in eastern Alaska and western Canada show an apparent offset of about 490 kilometers (km), probably of Eocene age. This estimate is compared with previous geologically based estimates of 400 to 430 km and paleomagnetically based estimates of more than 1,100 km. The apparent geophysical alignments have geologic implications that deserve further study.

Alaska;Yukon↗

Sedimentation and occurrence and trends of selected nutrients, other chemical constituents, and diatoms in bottom sediment, Fall River Lake, southeast Kansas, 1948-2006

A combination of available bathymetric-survey information and bottom-sediment coring was used to investigate sedimentation and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, diatoms, and the radionuclide cesium-137 in the bottom sediment of Fall River Lake, southeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1948 through 2006 in the original conservation pool of the reservoir was 470 million cubic feet and 18.8 billion pounds, respectively. The estimated sediment volume occupied about 36 percent of the original conservation-pool, water-storage capacity of the reservoir. Mean annual net sediment deposition since 1948 in the original conservation pool of the reservoir was estimated to be 324 million pounds per year. Mean annual net sediment yield from the Fall River Lake Basin was estimated to be 585,000 pounds per square mile per year. The mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Fall River Lake were estimated to be 648,000 pounds per year and 267,000 pounds per year, respectively. The estimated mean annual net yields of total nitrogen and total phosphorus from the Fall River Lake Basin were 1,170 pounds per square mile per year and 480 pounds per square mile per year, respectively. Throughout the history of Fall River Lake, total nitrogen and total phosphorus concentrations in the deposited sediment were relatively uniform. Trace element concentrations in the bottom sediment of Fall River Lake generally were uniform over time. Arsenic, chromium, nickel, and zinc concentrations typically exceeded the threshold-effects guidelines, which represent the concentrations above which toxic biological effects occasionally occur. Trace element concentrations did not exceed the probable-effects guidelines (available for eight trace elements), which represent the concentrations above which toxic biological effects usually or frequently occur. Diatom occurrence in the bottom sediment of Fall River Lake was dominated by the species Aulacoseira granulata , which is an indicator of eutrophic (nutrient-rich) conditions. The abundance of the diatom Aulacoseira granulata , combined with cyanobacteria evidence and historical water-quality data, indicated that Fall River Lake likely has been eutrophic throughout much of its history.

Kansas↗

Temporal and spatial variations in precipitation, streamflow, suspended-sediment loads and yields, and land-condition trend analysis at the U.S. Army Piñon Canyon Maneuver Site, Las Animas County, Colorado, 1983 through 2007

In 2007, the U.S. Geological Survey, in cooperation with the U.S. Department of the Army, began an assessment of the spatial and temporal variations in precipitation, streamflow, suspended-sediment loads and yields, changes in land condition, effects of the tributaries on the Purgatoire River and the possible relation of effects from military training to hydrology and land conditions that have occurred at Pinon Canyon Maneuver Site (PCMS) from 1983 through 2007. Data were collected for precipitation (19 stations) and streamflow and sediment load (5 tributary and 2 main-stem Purgatoire River stations) during 1983 through 2007 for various time periods. The five tributary stations were Van Bremer Arroyo near Model, Taylor Arroyo below Rock Crossing, Lockwood Canyon Creek near Thatcher, Red Rock Canyon Creek at the mouth, and Bent Canyon Creek at the mouth. In addition, data were collected at two Purgatoire River stations: Purgatoire River near Thatcher and Purgatoire River at Rock Crossing.

Colorado↗

Geochemical trends and natural attenuation of RDX, nitrate, and perchlorate in the hazardous test area Fractured-Granite aquifer, White Sands Missile Range, New Mexico, 1996-2006

A fractured-granite aquifer at White Sands Missile Range is contaminated with the explosive compound RDX, nitrate, and perchlorate (oxidizer associated with rocket propellant) from the previous use of the Open Burn/Open Detonation site at the Hazardous Test Area. RDX, nitrate, and perchlorate ground-water concentrations were analyzed to examine source characteristics, spatial and temporal variability, and the influence of the natural attenuation processes of dilution and degradation in the Hazardous Test Area fractured-granite aquifer. Two transects of ground-water wells from the existing monitoring-site network - one perpendicular to ground-water flow (transect A-A') and another parallel to ground-water flow (transect B-B') - were selected to examine source characteristics and the spatial and temporal variability of the contaminant concentrations. Ground-water samples collected in 2005 from a larger sampling of monitoring sites than the two transects were analyzed for various tracers including major ions, trace elements, RDX degradates, dissolved gases, water isotopes, nitrate isotopes, and sulfate isotopes to examine the natural attenuation processes of dilution and degradation. Recharge entrains contaminants at the site and transports them downgradient towards the Tularosa Basin floor through a poorly connected fracture system(s). From 1996 to 2006, RDX, nitrate, and perchlorate concentrations in ground water downgradient from the Open Burn/Open Detonation site have been relatively stable. RDX, nitrate, and perchlorate in ground water from wells near the site indicate dispersed contaminant sources in and near the Open Burn/Open Detonation pits. The sources of RDX and nitrate in the pit area have shifted with time, and the shift correlates with the regrading of the south and east berms of each pit in 2002 and 2003 following closure of the site. The largest RDX concentrations were in ground water about 0.1 mile downgradient from the pits, the largest perchlorate concentrations were in ground water about 0.15 mile downgradient from the pits, and the largest nitrate concentrations were in ground water about 0.25 mile down-gradient from the pits. Strong and moderate correlation of water level and the contaminant concentrations near the source areas and low correlation outside and downgradient from the source areas indicates a diminishing of the water level/contaminant relation with downgradient flow. Ground water was not progressively older at all locations downgradient from the Open Burn/Open Detonation site indicating multiple recharge areas. Major ion and strontium concentrations and d2H and d18O values identified similar sources of recharge waters comprising the aquifer except along the basin periphery where recharge water may be influenced by dissolution of mineral assemblages associated with ore deposits that are present along the basin margins. Ground-water ages, dissolved-solids concentrations, and calcium-strontium concentrations indicate limited or partial connectivity between fractures and contributions of uncontaminated recharge water downgradient from the site that dilutes contaminant concentrations. Changes in RDX and nitrate concentration patterns, the presence of methane, changes in carbon dioxide concentrations and d15N and d34S values, and variable reduction-oxidation conditions suggest degradation of contaminants in the downgradient direction. Estimated values of electron potential were assigned to ground water collected in October 2005 from all monitoring sites at the Hazardous Test Area. Moderate to strong reducing conditions were present upgradient from the Open Burn/Open Detonation site, at the site, and at various locations downgradient from the site, but the aquifer contained well-oxygenated water between many of the reducing areas. The spatial variability of reduction-oxidation conditions in the aquifer exemplifies the partial connectivity of the fracture system(s). Dilution of the contaminants i

New Mexico↗

Analysis of Streamflow Trends, Ground-Water and Surface-Water Interactions, and Water Quality in the Upper Carson River Basin, Nevada and California

Changes in land and water use and increasing development of water resources in the Carson River basin may affect flow of the river and, in turn, affect downstream water users dependent on sustained river flows to Lahontan Reservoir. To address these concerns, the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, Churchill County, and the Truckee-Carson Irrigation District, began a study in April 2006 to compile data on changes in land and water use, ground-water levels and pumping, streamflow, and water quality, and to make preliminary analyses of ground-water and surface-water interactions in the Carson River basin upstream of Lahontan Reservoir. The part of the basin upstream of Lahontan Reservoir is called the upper Carson River basin in this report. In 2005, irrigated agricultural land covered about 39,000 acres in Carson Valley, 3,100 acres in Dayton Valley, and 1,200 acres in Churchill Valley. Changes in land use in Carson Valley from the 1970s to 2005 included the development of about 2,700 acres of native phreatophytes, the development of 2,200 acres of irrigated land, 900 acres of land irrigated in the 1970s that appeared fallow in 2005, and the irrigation of about 2,100 acres of new agricultural land. In Dayton and Churchill Valleys, about 1,000 acres of phreatophytes and 900 acres of irrigated land were developed, about 140 acres of phreatophytes were replaced by irrigation, and about 600 acres of land irrigated in the 1970s were not irrigated in 2006. Ground-water pumping in the upper Carson River basin increases during dry years to supplement surface-water irrigation. Total annual pumping exceeded 20,000 acre-ft in the dry year of 1976, exceeded 30,000 acre-ft in the dry years from 1987 to 1992, and increased rapidly during the dry years from 1999 to 2004, and exceeded 50,000 acre-ft in 2004. As many as 67 public supply wells and 46 irrigation wells have been drilled within 0.5 mile of the Carson River. Pumping from these wells has the potential to affect streamflow of the Carson River. It is not certain, however, if all these wells are used currently. Annual streamflow of the Carson River is extremely variable, ranging from a low of about 26,000 acre-ft in 1977 to slightly more than 800,000 acre-ft in 1983 near Fort Churchill. Graphs of the cumulative annual streamflow and differences in the cumulative annual streamflow at Carson River gaging stations upstream and downstream of Carson and Dayton Valleys show an annual decrease in streamflow. The annual decrease in Carson River streamflow averaged about 47,000 acre-ft through Carson Valley, and about 11,000 acre-ft through Dayton Valley for water years 1940-2006. The decrease in streamflow through Carson and Dayton Valleys is a result of evapotranspiration on irrigated lands and losses to ground-water storage, with greater losses in Carson Valley than in Dayton Valley because of the greater area of irrigated land in Carson Valley.

Scientific Investigations Report↗

Water use in Georgia by county for 2005; and water-use trends, 1980-2005

Water use for 2005 for each county in Georgia was estimated using data obtained from various Federal and State agencies and local sources. Total consumptive water use also was estimated for each county in Georgia for 2005. Estimates of offstream water use include the categories of public supply, domestic, commercial, industrial, mining, irrigation, livestock, and thermoelectric power. The only category of instream use estimated was hydroelectric-power generation. Total offstream water use from ground- and surface-water sources was about 5,471 million gallons per day (Mgal/d) in 2005. Surface water used in the process of thermoelectric-power generation was the largest volume of water withdrawn with withdrawals of 2,717 Mgal/d in 2005. Estimated instream water use for hydroelectric-power generation was 54,096 Mgal/d. Withdrawals for irrigation totaled 752 Mgal/d with 65 percent supplied by ground-water sources. Surface water provided 78 percent of the 1,180 Mgal/d withdrawn for public supply. Many counties in the northern Piedmont physiographic province of Georgia, an area of dense population, had a large percentage of withdrawals from surface-water sources. In contrast, in the southern Coastal Plain physiographic province part of the State, many counties had more withdrawals from ground-water sources. As part of the Georgia Water-Use Program, statewide water-use estimates have been compiled every 5 years since 1980. During this period, water use was greatest in 1980 at 6,725 Mgal/d. Water use decreased by 31 percent to 5,353 Mgal/d in 1990 then increased to 6,487 Mgal/d in 2000. By 2005, water withdrawals had decreased to an estimated 5,471 Mgal/d primarily because of a decline in withdrawals for thermoelectric-power generation and a decline in demands as 2005 was a normal year for precipitation compared to 2000, which was in drought. Throughout the period 1980–2005, water withdrawn for thermoelectric-power generation made up the largest volume of offstream water use in Georgia. Total withdrawals for thermoelectric-power generation decreased about 24 percent in 2005 compared to 2000, due to the decommissioning of three power plants in the State. In addition, several plants operated by Georgia Power Company were retooled during this period to increase water conservation. Public-supply use steadily increased from 1980 to 2000, concurrent with increasing population in the State; however, in 2005, there was a slight decrease in public-supply use. Conversely, industrial water use decreased during the period 1980–2005. Water withdrawals for irrigation during 1980–2005 followed changing hydrologic conditions, increasing during drier years (1980 and 2000) and decreasing during normal or wetter years. Withdrawals for the categories of domestic and commercial use remained about the same during 1980–2005. Livestock and mining use increased in 2005 compared to the 2000 estimates because of changes in estimation techniques. Consumptive water use was determined for each category of use and compiled for each county. Estimation techniques vary for each water-use category. While consumptive use varied for each county in 2005, from about 1 percent to nearly 100 percent of total withdrawals, consumptive-use estimates for the entire State totaled 1,310 Mgal/d, about 24 percent of total withdrawals.

Georgia↗

Status and Trends of Sea Otter Populations in Southeast Alaska, 1969-2003

Aerial surveys of all known sea otter (Enhydra lutris) habitat in Southeast Alaska (SE AK) in 2002-2003 indicated a population size of 8,949 otters [Standard Error (SE) = 899] at an average density of 0.92 otters per square kilometer. These findings on sea otter distribution and abundance were compared to results from several previous surveys. Sea otters have expanded their range beyond the outer coast of SE AK and currently occupy inside waters such as Glacier Bay and Sumner Strait. This range expansion, along with archeological evidence, supports the hypothesis that sea otters are capable of colonizing inside waters in SE AK. Inside Glacier Bay National Park and Preserve, in northern SE AK, sea otter abundance has increased from 5 in 1995 to 1,266 (SE = 196) in 2002, more than doubling on an average annual basis, indicating immigration and reproduction as factors contributing to population growth. In the remainder of northern SE AK, the estimated abundance has declined from 2,295 in 1987 to 1,838 (SE = 307) in 2002. In southern SE AK, the abundance of sea otters increased from 2,167 in 1988 to 5,845 (SE = 821) in 2003. Overall, population growth rates for sea otters in SE AK between 1987 and 2003 are much lower than rates from previous studies and were unexpected given the amount of unoccupied habitat available in SE AK. Divergent population trajectories were evident between the southern (6.6 percent per year) and northern areas of SE AK (2.0 percent per year). These differences suggest variation in reproductive or survival rates between the areas. Harvest levels between 1989 and 2003 may have had a measurable effect on sea otter populations in SE AK. Available data on age and sex specific fecundity and survival rates could be used to develop age- and sex-structured population matrix models to help guide management and conservation of sea otter populations.

Scientific Investigations Report↗

Land Cover Trends in the Southern Florida Coastal Plain

This report presents an assessment of land use and land cover change in the Southern Florida Coastal Plain ecoregion for the period from 1973 to 2000. The ecoregion is one of 84 level III ecoregions defined by the Environmental Protection Agency; ecoregions have been designed to serve as a spatial framework for environmental resource management and denote areas that contain a geographically distinct assemblage of biotic and abiotic phenomena, including geology, physiography, vegetation, climate, soils, land use, wildlife, and hydrology. The Southern Florida Coastal Plain ecoregion covers an area of approximately 22,407 square kilometers [8,651 square miles] across the lower portion of the Florida peninsula, from Lake Okeechobee southward through the Florida Keys. It comprises flat plains with wet soils, marshland and swamp land cover with Everglades and palmetto prairie vegetation types.

Scientific Investigations Report↗

Water Withdrawals, Use, and Trends in Florida, 2005

In 2005, the total amount of water withdrawals in Florida was estimated at 18,359 million gallons per day (Mgal/d). Saline water accounted for 11,486 Mgal/d (63 percent), and freshwater accounted for 6,873 Mgal/d (37 percent). Groundwater accounted for 4,247 Mgal/d (62 percent) of freshwater withdrawals, and surface water accounted for the remaining 2,626 Mgal/d (38 percent). Surface water accounted for nearly all (99.9 percent) saline-water withdrawals. An additional 660 Mgal/d of reclaimed wastewater was used in Florida during 2005. The largest amount of freshwater was withdrawn from Palm Beach County, and the largest amount of saline water was withdrawn from Pasco County. Fresh groundwater provided drinking water (public supplied and self-supplied) for 16.19 million people (90 percent of Florida's population), and fresh surface water provided drinking water for 1.73 million people (10 percent). The majority of groundwater withdrawals (nearly 60 percent) in 2005 was obtained from the Floridan aquifer system which is present throughout the entire State. The majority of fresh surface-water withdrawals (59 percent) came from the southern Florida hydrologic unit subregion and is associated with Lake Okeechobee and the canals in the Everglades Agricultural Area of Glades, Hendry, and Palm Beach Counties, as well as the Caloosahatchee River and its tributaries in the agricultural areas of Collier, Glades, Hendry, and Lee Counties. Overall, agricultural irrigation accounted for 40 percent of the total freshwater withdrawals (ground and surface), followed by public supply with 37 percent. Public supply accounted for 52 percent of groundwater withdrawals, followed by agricultural self-supplied (31 percent), ommercial-industrial-mining self-supplied (8.5 percent), recreational irrigation and domestic self-supplied (4 percent each), and power generation (0.5 percent). Agricultural self-supplied accounted for 56 percent of fresh surface-water withdrawals, followed by power generation (20.5 percent), public supply (13 percent), recreational irrigation (6 percent), and commercial-industrial self-supplied (4.5 percent). Power generation accounted for nearly all (99.9 percent) saline-water withdrawals. Of the 17.92 million people who resided in Florida during 2005, 41 percent (7.36 million people) resided in the South Florida Water Management District (SFWMD), followed by the St. Johns River Water Management District (SJRWMD) and the Southwest Florida Water Management District (SWFWMD) with 25 percent each (4.46 and 4.44 million people, respectively), the Northwest Florida Water Management District (NWFWMD) with 7.5 percent (1.34 million people), and the Suwannee River Water Management District (SRWMD) with 1.5 percent (0.32 million people). The largest amount of freshwater withdrawals was from the SFWMD, which was one-half (50 percent) of the State's total freshwater withdrawals, followed by the SJRWMD (19 percent), SWFWMD (16 percent), NWFWMD (10 percent), and SRWMD (5 percent). Between 1950 and 2005, the population of Florida increased by 15.15 million (550 percent), and the total water withdrawals (fresh and saline) increased 15,700 Mgal/d (600 percent). More recently, total withdrawals decreased 1,790 Mgal/d (9 percent) between 2000 and 2005, but the total population increased by 1.94 million (12 percent). Between 1990 and 2005, saline-water withdrawals increased 1,120 Mgal/d (11 percent), whereas between 2000 and 2005, saline-water withdrawals decreased 470 Mgal/d (4 percent). Between 1990 and 2005, freshwater withdrawals decreased 710 Mgal/d (9 percent), whereas between 2000 and 2005, freshwater withdrawals decreased 1,320 Mgal/d (16 percent). The use of highly mineralized groundwater as a source of supply, primarily for public supply, also has increased in Florida. This water, referred as nonpotable water, increased from just less than 2 Mgal/d in 1970, to 142 Mgal/d in 2005. Nonpotable water is treated to meet drin

Scientific Investigations Report↗

Occurrence and Trends of Selected Chemical Constituents in Bottom Sediment, Grand Lake O' the Cherokees, Northeast Oklahoma, 1940-2008

After over 100 years of continuous activity, lead and zinc mining in the Tri-State Mining District (hereafter referred to as the TSMD) in parts of southeast Kansas, southwest Missouri, and northeast Oklahoma ended in the 1970s. The mining activity resulted in substantial historical and ongoing input of cadmium, lead, and zinc to the environment including Grand Lake O' the Cherokees (hereafter referred to as Grand Lake), a large reservoir in northeast Oklahoma. To help determine the extent and magnitude of contamination in Grand Lake, a one-year study was conducted by the U.S. Geological Survey in cooperation with the U.S. Fish and Wildlife Service. Bottom-sediment coring at five sites was used to investigate the occurrence of cadmium, lead, zinc, and other selected constituents in the bottom sediment of Grand Lake. Cadmium concentrations in the bottom sediment of Grand Lake ranged from 2.3 to 3.6 mg/kg (milligrams per kilogram) with a median of 3.5 mg/kg (5 samples). Compared to an estimated local background concentration of 0.6 mg/kg, the historical mining activity increased cadmium concentrations by about 280 to 500 percent. Lead concentrations ranged from 35 to 102 mg/kg with a median of 59 mg/kg (50 samples). Compared to an estimated local background concentration of 20 mg/kg, the historical mining activity increased lead concentrations by about 75 to 410 percent. The range in zinc concentrations was 380 to 986 mg/kg with a median of 765 mg/kg (50 samples). Compared to an estimated local background concentration of 100 mg/kg, the historical mining activity increased zinc concentrations by about 280 to 890 percent. With the exception of the most upstream coring site, the lead and zinc depositional profiles generally were similar in terms of the range in concentrations measured and the temporal pattern observed. Depositional profiles for lead and zinc indicated mid-core peaks followed by concentrations that decreased since about the 1980s. The depositional profiles reflect the complex interaction of several factors including historical mining and related activities, mine drainage, remediation, landscape stabilization, precipitation and associated runoff, and the erosion and transport of contaminated and clean sediments within the basin. Compared to sediment-quality guidelines, the Grand Lake samples had cadmium concentrations that were substantially less than the general probable-effects concentration (PEC) (4.98 mg/kg) and a TSMD-specific PEC (11.1 mg/kg). The PECs represent the concentration above which toxic biological effects are likely to occur. Likewise, all sediment samples had lead concentrations that were substantially less than the general PEC (128 mg/kg) and a TSMD-specific PEC (150 mg/kg). Zinc concentrations typically exceeded the general PEC (459 mg/kg), but were substantially less than a TSMD-specific PEC (2,083 mg/kg). Throughout the history of Grand Lake, lead and zinc concentrations in the deposited sediment did not approach or exceed the TSMD-specific PECs. As of 2008, legacy effects of mining still included the delivery of contaminated sediment to Grand Lake by the Spring and Neosho Rivers. The Neosho River, with its larger flows and less-contaminated sediment, likely dilutes the load of contaminated sediment delivered to Grand Lake by the Spring River. The information contained in this report provides a baseline of Grand Lake conditions with which to compare future conditions that may represent a response to changes in mining-related activity in the Grand Lake Basin.

Scientific Investigations Report↗

Status and trends of the rainbow trout population in the Lees Ferry reach of the Colorado River downstream from Glen Canyon Dam, Arizona, 1991–2009

The Lees Ferry reach of the Colorado River, a 25-kilometer segment of river located immediately downstream from Glen Canyon Dam, has contained a nonnative rainbow trout (Oncorhynchus mykiss) sport fishery since it was first stocked in 1964. The fishery has evolved over time in response to changes in dam operations and fish management. Long-term monitoring of the rainbow trout population downstream of Glen Canyon Dam is an essential component of the Glen Canyon Dam Adaptive Management Program. A standardized sampling design was implemented in 1991 and has changed several times in response to independent, external scientific-review recommendations and budget constraints. Population metrics (catch per unit effort, proportional stock density, and relative condition) were estimated from 1991 to 2009 by combining data collected at fixed sampling sites during this time period and at random sampling sites from 2002 to 2009. The validity of combining population metrics for data collected at fixed and random sites was confirmed by a one-way analysis of variance by fish-length class size. Analysis of the rainbow trout population metrics from 1991 to 2009 showed that the abundance of rainbow trout increased from 1991 to 1997, following implementation of a more steady flow regime, but declined from about 2000 to 2007. Abundance in 2008 and 2009 was high compared to previous years, which was likely the result of increased early survival caused by improved habitat conditions following the 2008 high-flow experiment at Glen Canyon Dam. Proportional stock density declined between 1991 and 2006, reflecting increased natural reproduction and large numbers of small fish in samples. Since 2001, the proportional stock density has been relatively stable. Relative condition varied with size class of rainbow trout but has been relatively stable since 1991 for fish smaller than 152 millimeters (mm), except for a substantial decrease in 2009. Relative condition was more variable for larger size classes, and substantial decreases were observed for the 152-304-mm size class in 2009 and 305-405-mm size class in 2008 that persisted into 2009.

Arizona↗

Water withdrawals, wastewater discharge, and water consumption in the Apalachicola-Chattahoochee-Flint River Basin, 2005, and water-use trends, 1970-2005

The Apalachicola-Chattahoochee-Flint (ACF) River Basin covers about 20,500 square miles that drains parts of Alabama, Florida, and Georgia. The basin extends from its headwaters northern Georgia to the Gulf of Mexico. Population in the basin was estimated to be 3.7 million in 2005, an increase of about 41 percent from the 1990 population of 2.6 million. In 2005, slightly more than 721,000 acres of crops were irrigated within the basin. In 2005, the total amount of water withdrawn in the ACF River Basin was about 1,990 million gallons per day (Mgal/d). Of this, surface water accounted for 1,591 Mgal/d (80 percent) and groundwater accounted for 399 Mgal/d (20 percent). Surface water was the primary water source of withdrawals in the northern and central parts of the basin, and groundwater was the primary source in the southern part. The largest surface-water withdrawals was from Cobb County, Georgia (410 Mgal/d, mostly from the Chattahoochee River and Lake Alatoona), and the largest groundwater withdrawals was from Dougherty County, Georgia (38 Mgal/d, mostly from the Upper Floridan aquifer system). Thermoelectric power generation accounted for the largest water withdrawals in 2005 at 788 Mgal/d (40 percent). Most of these withdrawals were used for once-through cooling, and nearly all water used for this purpose was returned to its source. Public supply accounted for 609 Mgal/d (30 percent) of total withdrawals in 2005, followed by agricultural self-supplied (including crop, golf course irrigation, and livestock) at 365 Mgal/d (18 percent), commercial-industrial self-supplied (including mining) at 191 Mgal/d (10 percent), and domestic self-supplied at 37 Mgal/d (2 percent). Public-supply withdrawals were lowest during January, February, and March (about 500 Mgal/d), and highest during September (about 700 Mgal/d). As the population of the ACF River Basin increased by 1.7 million (83 percent) in the 35 years between 1970 and 2005, total withdrawals in the basin increased by more than 515 Mgal/d (35 percent). Of this increase, surface-water accounted for 206 Mgal/d (15 percent) and groundwater accounted for 309 Mgal/d (350 percent). Since 1980, total water withdrawals have generally declined, except in 2000 when they peaked because of below-average rainfall. In 2000, an estimated 49 percent of the water withdrawn for public supply in the basin was consumed, and the remaining 51 percent was returned to the hydrologic system through wastewater treatment systems. In 2005, an estimated 38 percent was consumed and 62 percent was returned to the hydrologic system. This contrast between water withdrawals and wastewater discharges for these years was caused primarily by below-average rainfall during 2000 (a dry year) and above-average rainfall during 2005 (a wet year).

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