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Chemical composition of Texas surface waters, 1949

This report is the fifth the a series of publications by the Texas Board of Water Engineers giving chemical analyses of the surface waters in the State of Texas. The samples for which data are given were collected between October 1, 1948 and September 30, 1949. During the water year 25 daily sampling stations were maintained by the Geological Survey. Sampled were collected less frequently during the year at many other points. Quality of water records for previous years can be found in the following reports: "Chemical Composition of Texas Surface Waters, 1938-1945," by W. W. Hastings, and J. H. Rowley; "Chemical Composition of Texas Surface Waters, 1946," by W. W. Hastings and B. Irelan; "Chemical Composition of Texas Surface Waters, 1947," by B. Irelan and J. R. Avrett; "Chemical Composition of Texas Surface Waters, 1948," by B. Irelan, D. E. Weaver, and J. R. Avrett. These reports may be obtained from the Texas Board of Water Engineers and Geological Survey at Austin, Texas. Samples for chemical analysis were collected daily at or near points on streams where gaging stations are maintained for measurement of discharge. Most of the analyses were made of 10-day composites of daily samples collected for a year at each sampling point. Three composite samples were usually prepared each month by mixing together equal quantities of daily samples collected for the 1st to the 10th, from the 11th to the 20th, and during the remainder of the month. Monthly composites were made at a few stations where variation in daily conductance was small. For some streams that are subject to sudden large changes in chemical composition, composite samples were made for shorter periods on the basis of the concentration of dissolved solids as indicated by measurement of specific conductance of the daily samples. The mean discharge for the composite period is reported in second-feet. Specific conductance values are expressed as "micromhos, K x 10 at 25° C." Silica, calcium, magnesium, sodium, potassium, bicarbonate, sulfate, chloride, and nitrate are reported in parts per million. The quantity of dissolved solids is given in tons per acre-foot, tons per day (if discharge records are available), and parts per million. The total and non-carbonate hardness are reported as parts per million calcium carbonate (CaCO 3 ). For those analyses where sodium and potassium are reported separately, "recent sodium" will include the equivalent quantity of sodium only. In analyses where sodium and potassium were calculated and reported as a combined value, the "percent sodium" will include the equivalent quantity of sodium and potassium. Weighted average analyses are given for most daily sampling stations. The weighted average analysis represent approximately the composition of water that would be found in a reservoir containing all the water passing a given station during the year after through mixing in the reservoir. Samples were analyzed according to method regularly used by the Geological Survey. These methods are essentially the same or are modifications of methods described in recognized authoritative publications for mineral analysis of water samples. These quality of water records have been collected as part of the cooperative investigations of the water resources of Texas conducted by the Geological Survey and the Texas Board of Water Engineers. Much of the work would have been impossible without the support of the following Federal State, and local agencies The United States Bureau of Reclamation, U. S. Corps of Engineers, Brazos River Conservation and Reclamation District, Lower Colorado River Authority, Red Bluff Water Power Control District, City of Amarillo, City of Abilene, and City of Forth Worth. The investigations were under the firection of Burdge Irelan, District Chemist, Austin, Texas. Analyses of water samples were made by Clara J. Carter, Lee J. Freeman, Homer D. Smith, Dorothy M. Suttle, DeForrest E. Weaver, and Clarence T. Welborn. Calculations of weighted averages were made by James R. Avrett, Burdge Irelan, Dorothy M. Suttle, and DeForrest E. Weaver.

Texas↗

Aquifer-test compilation for the San Joaquin Valley, California

This report is the first of a series the purpose of which is to make available in standard tabular form the results of aquifer tests that have been made by various private and public agencies in California. The scope of the compilation is to describe systematically, in a form agreed upon by the California Department of Water Resources and the Geological Survey, the (1) test location, (2) pumping data, (3) well data, and (4) summary of results. The results of these tests sometimes have been published but most frequently have been used only as a step in obtaining other information, consequently the results and even the location of aquifer tests have not been readily available. This report has been prepared by the Geological Survey under the immediate supervision of Fred Kunkel, district geologist for California, in cooperation with the California Department of Water Resources, and tabulates through October 1962 all tests analyzed by the Geological Survey for the San Joaquin Valley. The report is designed to be expanded when additional tests are analyzed or new tests are made.

California↗

Aquifer-test compilation for northern California

This report is the fourth of a series, the purpose of which is to flake available, in standard tabulur form, the results of aquifer tests that have been made by various private and public agencies in California. The scope of the compilation is to describe systematically, in a form agreed upon by the California Department of Water Resources end. the Geological Survey, the (1) test location, (1) pumping data, (3) well data, and (4) summary of results. The results of these tests occasionally have been published, but usually they have been used only to obtain other information. Consequently, the results of aquifer tests have not always been readily available. This report was prepared by the U.S. Geological Survey, Water Resources Division, in cooperation with the California Department of Water Resources. It tabulates, through April 1965, the tests that were available for northern California.

California↗

E-field ratio telluric survey near the Big Maria Mountains, Riverside County, California

The U.S. Geological Survey (USGS) under the Wilderness Act (Public Law 88-577) and the Federal Land Policy and Management Act (Public Law 94-579) has the responsibility, along with the U.S. Bureau of Mines, to survey certain areas in order to determine their mineral resource potential. This report presents results of three electric-field ratio telluric traverses conducted as part of the Bureau of Land Management Wilderness Program in the Big Maria Mountains, Riverside County, Calif. The telluric traverses were run on the southwest side of the Big Maria Mountains in an attempt to define the location of major buried faults near the eroded front of the range. E-field ratio tellurics is a descriptive name applied to the electrical exploration technique used in this survey. The telluric method refers to the measurement of the earth's electric field generated by induction from natural electromagnetic waves arriving at the surface. The E-field ratio telluric method uses a receiving array of three electrodes spaced equidistant and inline. This array is, in effect, two colinear dipoles sharing a common electrode. The potential difference across each dipole is then proportional to the component of the telluric field in the direction of the array. This configuration permits the measurement of the ratio of the telluric field at each dipole in the direction of the dipole line, and hence the name. The traverse data is extended by moving the three-electrode array forward one dipole length so that the forward electrode becomes the center electrode for the next ratio measurement. Electric-field data so obtained are proportional to the square root of the apparent resistivity of the earth at the location of the dipoles. However, because the apparent resistivity can be a function of the dipole direction, it is important to know the orientation of the dipoles with respect to major structures. Because the resistivity of fluid-saturated earth materials is largely dependent on the porosity of the rocks, the salinity of the pore fluid, and the presence of clays or similar material where surface conduction is high, alluvial fill, argillite and similar rocks tend to have low resistivities whereas igneous or high-grade metamorphic rocks have high resistivities. Variation in the electrical properties along a traverse may then be used to infer lithologic or structural changes.

California↗

The Connecticut Streamflow and Sustainable Water Use Estimator—A decision-support tool to estimate water availability at ungaged stream locations in Connecticut

Freshwater streams in Connecticut are subject to many competing demands, including public water supply; agricultural, commercial, and industrial water use; and ecosystem and habitat needs. In recent years, drought has further stressed Connecticut’s water resources. To sustainably allocate and manage water resources among these competing uses, Federal, State, and local water-resource managers require data and modeling tools to estimate the water availability at a variety of temporal and spatial scales for planning purposes. The Connecticut Streamflow and Sustainable Water Use Estimator (CT SSWUE), developed by the U.S. Geological Survey in cooperation with the Connecticut Department of Energy and Environmental Protection, is a decision-support tool for estimating daily unaltered streamflow and sustainable water use at ungaged sites in Connecticut. The CT SSWUE estimates unaltered daily mean streamflow and water-use-adjusted streamflow for the period from October 1, 1960, to September 30, 2015, and the monthly sustainable net withdrawal at ungaged sites in Connecticut. Unaltered streamflow is the estimated daily mean streamflow in a drainage basin in the absence of any water withdrawals or wastewater discharges and with minimal human development. Sustainable net withdrawal is the maximum net withdrawal (withdrawal minus wastewater discharges) that can be drawn from a basin without critically depleting the water available through natural streamflow patterns. Sustainable net withdrawal is defined for this study as the difference between the unaltered daily mean streamflow and a user-defined target minimum streamflow. Weighted least squares and Tobit regression techniques were used to develop equations for estimating streamflow at ungaged sites at 19 streamflow quantiles with exceedance probabilities ranging from 0.005 to 99.995 percent. Regressions were based on streamflow quantiles and basin characteristics from 36 reference streamgages in and around Connecticut. Four basin characteristics—drainage area, mean of the soil permeability, mean of the average annual precipitation, and ratio of the length of streams that overlay sand and gravel deposits to the total length of streams in the basin—are used as explanatory variables in the equations. At an ungaged site, interpolation between the streamflow quantiles estimated from the regression equations produces a continuous flow-duration curve. A time series of daily mean streamflow at an ungaged site is then estimated by assuming that for each day, the streamflow quantile occurs on the same date at both a reference streamgage and the ungaged site. In a remove-one cross validation, estimated unaltered daily mean streamflow agreed well with observed values at reference streamgages, with a few exceptions. Nash Sutcliffe efficiency ranged from −0.43 to 0.97 with a median value of 0.88. The normalized root-mean-square error ranged from 16.6 to 120.4 percent with a median value of 34.5 percent. An empirical method for estimating 95-percent prediction intervals for unaltered daily and monthly mean streamflow was developed and tested by using the cross-validation data. Prediction intervals for unaltered daily mean streamflow at the cross-validation reference streamgages performed well in most cases. Gaged streamflow values from the cross-validation data fell within the prediction intervals a median 96.6 percent of the time for daily mean time series and 93.9 percent of the time for monthly mean time series. The CT SSWUE computes water-use-adjusted streamflow using spatially referenced water-use information provided by the Connecticut Department of Energy and Environmental Protection. Available water-use information included permitted and registered water withdrawals and permitted wastewater discharges during 1998 to 2015 for the Thames River Basin and central coastal drainage basins. Water-use information was incorporated into the U.S. Geological Survey StreamStats web application for Connecticut and can be used for computing water-use-adjusted streamflow and sustainable net withdrawal at selected points of interest. Altered daily streamflow is computed by applying average daily withdrawals and wastewater discharges to the water balance equation. Average daily surface water withdrawals and wastewater discharges are applied directly to the daily water balance equation. Time-lagged alterations on streamflow from groundwater withdrawals or wastewater discharges are estimated by using a response-coefficient method developed from results of previously published, calibrated groundwater models.

Connecticut↗

Chapter A6. Section 6.4. pH

Measurement of pH is critical to the understanding of the viability and vulnerability of environmental waters and is considered a master variable in determining the aqueous geochemistry of an aqueous system. pH is a measure that represents the hydrogen-ion concentration (activity) of a solution. This section of the National Field Manual (NFM) describes U.S. Geological Survey (USGS) guidance and protocols for measurement of pH in ground and surface waters. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Chapter A6. Section 6.5. Reduction-Oxidation Potential (Electrode Method)

Reduction-oxidation (redox) potential--also referred to as Eh--is a measure of the equilibrium potential, relative to the standard hydrogen electrode, developed at the interface between a noble metal electrode and an aqueous solution containing electroactive chemical species. Measurements of Eh are used to evaluate geochemical speciation models, and Eh data can provide insights on the evolution and status of water chemistry in an aqueous system. Nevertheless, the measurement is fraught with inherent interferences and limitations that must be understood and considered to determine applicability to the aqueous system being studied. For this reason, Eh determination is not one of the field parameters routinely measured by the U.S. Geological Survey (USGS). This section of the National Field Manual (NFM) describes the equipment and procedures needed to measure Eh in water using a platinum electrode. Guidance as to the limitations and interpretation of Eh measurement also is included. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Chapter A6. Section 6.6. Alkalinity and acid neutralizing capacity

Alkalinity (determined on a filtered sample) and Acid Neutralizing Capacity (ANC) (determined on a whole-water sample) are measures of the ability of a water sample to neutralize strong acid. Alkalinity and ANC provide information on the suitability of water for uses such as irrigation, determining the efficiency of wastewater processes, determining the presence of contamination by anthropogenic wastes, and maintaining ecosystem health. In addition, alkalinity is used to gain insights on the chemical evolution of an aqueous system. This section of the National Field Manual (NFM) describes the USGS field protocols for alkalinity/ANC determination using either the inflection-point or Gran function plot methods, including calculation of carbonate species, and provides guidance on equipment selection. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Chapter A7. Section 7.0. Five-Day Biochemical Oxygen Demand

The presence of a sufficient concentration of dissolved oxygen is critical to maintaining the aquatic life and aesthetic quality of streams and lakes. Determinng how organic matter affects the concentration of dissolved oxygen (DO) in a stream or lake is integral to water-quality management. The decay of organic matter in water is measured as biochemical or chemical oxygen demand. This report describes the field protocols used by U.S. Geological Survey (USGS) personnel to determine the five-day test for biochemical oxygen demand. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Chapter A7. Section 7.1. Fecal indicator bacteria

Fecal indicator bacteria are used to assess the microbiological quality of water because, although not typically disease causing, they are correlated with the presence of several waterborne disease-causing organisms. The concentration of indicator bacteria is a measure of water safety for body-contact recreation or for consumption. This report provides information on the equipment, sampling protocols, and identification, enumeration, and calculation procedures that are in standard use by U.S. Geological Survey (USGS) personnel for the collection of data on fecal indicator bacteria. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Chapter A7. Section 7.3. Protozoan Pathogens

Protozoan pathogens are widely distributed in the aquatic environment. Cryptosporidium and Giardia are the principal protozoan pathogens that are known to affect the acceptability of water supplies for public use within the United States. A sampling program for protozoan pathogens should be conducted over an extended period of time because of cyclical and seasonal variations in their concentrations in the environment. This report provides information on the equipment, sampling protocols, and laboratory method that are in standard use by U.S. Geological Survey (USGS) personnel for the collection of data on protozoan pathogens. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Chapter A7. Section 7.4. Algal biomass indicators

Indicators of algal biomass are used to assess water quality in both moving (lotic) and stillwater (lentic) ecosystems. Algal biomass in a water body can be estimated in three ways: (1) by quantifying chlorophyll a (CHL a ), (2) by measuring carbon biomass as ash-free dry mass (AFDM), or (3) by measuring the particulate organic carbon (POC) in a sample. The CHL a procedure measures photosynthetic pigment common to all types of algae, while AFDM and POC procedures measure the carbon in a filtered water sample. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Water withdrawals in the Black Warrior-Tombigbee basin in Alabama, 1985-87

Public-supply, industrial, and power generation water withdrawals were inventoried for the Black Warrior-Tombigbee basin in Alabama for 1987. A water source capacity analysis was done for each facility to assess the risk of the future water demand exceeding the capacity of the current source. Approximately 96 percent of all water withdrawn in the study area was surface water. Surface water accounted for 88 percent of withdrawals by public suppliers and 99 percent of withdrawals by self- supplied industries.

Alabama↗

Radioactivity in the environment; a case study of the Puerco and Little Colorado River basins, Arizona and New Mexico

This report, written for the nontechnical reader, summarizes the results of a study from 1988-91 of the occurrence and transport of selected radionuclides and other chemical constituents in the Puerco and Little Colorado River basins, Arizona and New Mexico. More than two decades of uranium mining and the 1979 failure of an earthen dam containing mine tailings released high levels of radionuclides and other chemical constituents to the Puerco River, a tributary of the Little Colorado River. Releases caused public concern that ground water and streamflow downstream from mining were contaminated. Study findings show which radioactive elements are present, how these elements are distributed between water and sediment in the environment, how concentrations of radioactive elements vary naturally within basins, and how levels of radioactivity have changed since the end of mining. Although levels of radioactive elements and other trace elements measured in streamflow commonly exceed drinking-water standards, no evidence was found to indicate that the high concentrations were still related to uraniurn mining. Sediment radioactivity was higher at sample sites on streams that drain the eastern part of the Little Colorado River basin than that of samples from the western part. Radioactivity of suspended sediment measured in this study, therefore, represents natural conditions for the streams sampled rather than an effect of mining. Because ground water beneath the Puerco River channel is shallow, the aquifer is vulnerable to contamination. A narrow zone of ground water beneath the Puerco River containing elevated uranium concentrations was identified during the study. The highest concentrations were nearest the mines and in samples collected in the first few feet beneath the streambed. Natuxal radiation levels in a few areas of the underlying sedimentary aquifer not connected to the Puerco River also exceeded water quality standards. Water testing would enable those residents not using public water supplies to determine if their water is safe to use.

Water-Resources Investigations Report↗

Adjudicating groundwater: A judge’s guide to understanding groundwater and modeling

Dividing the Waters offers this groundwater science bench book that cannot be matched by any other scientific or judicial publication. Adjudicating Groundwater combines the expertise and experience of academic scientists (UC Davis/Stanford), federal scientists (U.S. Geological Survey), and judicial officers to create a resource that can fulfill the needs of judges tackling the most difficult groundwater conflicts. This bench book explains both the fundamentals of groundwater science (hydrogeology) and groundwater modeling. The bench book received peer review from scientists and judges, with oversight by the U.S. Geological Survey, making this book among the most reliable resources for judges with water cases.

Book↗

Use of a ground-water flow model with particle tracking to evaluate ground-water vulnerability, Clark County, Washington

A ground-water flow model was used in conjunction with particle tracking to evaluate ground-water vulnerability in Clark County, Washington. Using the particle-tracking program, particles were placed in every cell of the flow model (about 60,000 particles) and tracked backwards in time and space upgradient along flow paths to their recharge points. A new computer program was developed that interfaces the results from a particle-tracking program with a geographic information system (GIS). The GIS was used to display and analyze the particle-tracking results. Ground-water vulnerability was evaluated by selecting parts of the ground-water flow system and combining the results with ancillary information stored in the GIS to determine recharge areas, characteristics of recharge areas, downgradient impact of land use at recharge areas, and age of ground water. Maps of the recharge areas for each hydrogeologic unit illustrate the presence of local, intermediate, or regional ground-water flow systems and emphasize the three-dimensional nature of the ground-water flow system in Clark County. Maps of the recharge points for each hydrogeologic unit were overlaid with maps depicting aquifer sensitivity as determined by DRASTIC (a measure of the pollution potential of ground water, based on the intrinsic characteristics of the near-surface unsaturated and saturated zones) and recharge from on-site waste-disposal systems. A large number of recharge areas were identified, particularly in southern Clark County, that have a high aquifer sensitivity, coincide with areas of recharge from on-site waste-disposal systems, or both. Using the GIS, the characteristics of the recharge areas were related to the downgradient parts of the ground-water system that will eventually receive flow that has recharged through these areas. The aquifer sensitivity, as indicated by DRASTIC, of the recharge areas for downgradient parts of the flow system was mapped for each hydrogeologic unit. A number of public-supply wells in Clark County may be receiving a component of water that recharged in areas that are more conducive to contaminant entry. The aquifer sensitivity maps illustrate a critical deficiency in the DRASTIC methodology: the failure to account for the dynamics of the ground-water flow system. DRASTIC indices calculated for a particular location thus do not necessarily reflect the conditions of the ground-water resources at the recharge areas to that particular location. Each hydrogeologic unit was also mapped to highlight those areas that will eventually receive flow from recharge areas with on-site waste-disposal systems. Most public-supply wells in southern Clark County may eventually receive a component of water that was recharged from on-site waste-disposal systems.Traveltimes from particle tracking were used to estimate the minimum and maximum age of ground water within each model-grid cell. Chlorofluorocarbon (CFC)-age dating of ground water from 51 wells was used to calibrate effective porosity values used for the particle- tracking program by comparison of ground-water ages determined through the use of the CFC-age dating with those calculated by the particle- tracking program. There was a 76 percent agreement in predicting the presence of modern water in the 51 wells as determined using CFCs and calculated by the particle-tracking program. Maps showing the age of ground water were prepared for all the hydrogeologic units. Areas with the youngest ground-water ages are expected to be at greatest risk for contamination from anthropogenic sources. Comparison of these maps with maps of public- supply wells in Clark County indicates that most of these wells may withdraw ground water that is, in part, less than 100 years old, and in many instances less than 10 years old. Results of the analysis showed that a single particle-tracking analysis simulating advective transport can be used to evaluate ground-water vulnerability for any part of a ground-wate

Open-File Report↗

Water resources of Indiana County, Pennsylvania

Indiana County, west-central Pennsylvania, is a major producer of coal and natural gas. Water managers and residents are concerned about the effects of mining and natural gas exploration on the surface- and ground-water resources of the county. This study assesses the quality and quantity of water in Indiana County. Ground- and surface-water sources are used for public supplies that serve 61 percent of the total population of the county. The remaining 39 percent of the population live in rural areas and rely on cisterns and wells and springs that tap shallow aquifers. Most of the county is underlain by rocks of Middle to Upper Pennsylvanian age. From oldest to youngest, they are the Allegheny Group, the Glenshaw Formation, the Casselman Formation, and the Monongahela Group. Almost all the coals mined are in the Allegheny Group and the Monongahela Group. Ground water in Indiana County flows through fractures in the rock. The size and extent of the fractures, which are controlled by lithology, topography, and structure, determine the sustained yield of wells. Topography has a significant control over the yields of wells sited in the Allegheny Group. Properly sited wells in the Glenshaw Formation may have yields adequate for municipal, commercial, or industrial uses. The Casselman Formation yields adequate amounts of water for domestic use. Yield of the Monongahela Group is small, and the water may not be of suitable quality for most uses. Yields of hilltop wells may be marginal, but valley wells may yield sufficient amounts for large-volume users. Data on the other rock units are sparse to nonexistent. Few wells in the county yield more than 40 gallons per minute. Most of the wells that do are in valleys where alluvial deposits are extensive enough to be mapable. Short-term water-level fluctuations are variable from well to well. Seasonal water-level fluctuations are controlled by time of year and amount of precipitation. The quality of water from the Casselman Formation, Glenshaw Formation, and Allegheny Group tends to be hard and may have concentrations of iron and manganese that exceed the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels of 0.3 milligrams per liter and 0.05 milligrams per liter, respectively. Ground water from the Glenshaw Formation is less mineralized than ground water from the Allegheny Group. Concentrations of minerals in water from the Casselman Formation are between those in water from the Glenshaw Formation and the Allegheny Group. Water from wells on hilltops has lower concentrations of dissolved solids than water from wells on hillsides. Water from valley wells is the most mineralized. Nearly half the springs tested yield water that is low in pH and dissolved solids; this combination makes the water chemically aggressive. The 7-day, 10-year low-flow frequencies for 26 unregulated surface-water sites ranged from 0.0 to 0.19 cubic feet per second per square mile. The presence of coal mines and variations in precipitation were probably the principal factors affecting flow duration on Blacklick Creek (site 28) during 1953-88. Sustained base flows of regulated streams such as Blacklick Creek generally were larger than those of unregulated streams as a result of low-flow augmentation. The annual water loss in streamflow as a result of evapotranspiration, diversion, seepage to mines, and seepage to the ground-water system was determined at four sites (sites 8, 9, 17, and 28) and ranged from 35 to 53 percent. The highest concentrations of dissolved solids, iron, manganese, aluminum, zinc, and sulfate were measured mostly in streams in central and southern Indiana County, where active and abandoned coal mines are the most numerous. Streamflow was measured during low flow in two small basins; one basin almost completely deep mined (Cherry Run) and one basin unmined (South Branch Plum Creek). The measurements showed a con

Pennsylvania↗

Triennial changes in groundwater quality in aquifers used for public supply in California: Utility as indicators of temporal trends

From 2004 to 2011, the U.S. Geological Survey collected samples from 1686 wells across the State of California as part of the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment (GAMA) Priority Basin Project (PBP). From 2007 to 2013, 224 of these wells were resampled to assess temporal trends in water quality. The samples were analyzed for 216 water-quality constituents, including inorganic and organic compounds as well as isotopic tracers. The resampled wells were grouped into five hydrogeologic zones. A nonparametric hypothesis test was used to test the differences between initial sampling and resampling results to evaluate possible step trends in water-quality, statewide, and within each hydrogeologic zone. The hypothesis tests were performed on the 79 constituents that were detected in more than 5 % of the samples collected during either sampling period in at least one hydrogeologic zone. Step trends were detected for 17 constituents. Increasing trends were detected for alkalinity, aluminum, beryllium, boron, lithium, orthophosphate, perchlorate, sodium, and specific conductance. Decreasing trends were detected for atrazine, cobalt, dissolved oxygen, lead, nickel, pH, simazine, and tritium. Tritium was expected to decrease due to decreasing values in precipitation, and the detection of decreases indicates that the method is capable of resolving temporal trends.

California↗