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USGS2008

Tracing ground water input to base flow using sulfate (S, O) isotopes

Sulfate (S and O) isotopes used in conjunction with sulfate concentration provide a tracer for ground water contributions to base flow. They are particularly useful in areas where rock sources of contrasting S isotope character are juxtaposed, where water chemistry or H and O isotopes fail to distinguish water sources, and in arid areas where rain water contributions to base flow are minimal. Sonoita Creek basin in southern Arizona, where evaporite and igneous sources of sulfur are commonly juxtaposed, serves as an example. Base flow in Sonoita Creek is a mixture of three ground water sources: A, basin ground water with sulfate resembling that from Permian evaporite; B, ground water from the Patagonia Mountains; and C, ground water associated with Temporal Gulch. B and C contain sulfate like that of acid rock drainage in the region but differ in sulfate content. Source A contributes 50% to 70%, with the remainder equally divided between B and C during the base flow seasons. The proportion of B generally increases downstream. The proportion of A is greatest under drought conditions.

Ground Water↗
USGS2005

Assessing background ground water chemistry beneath a new unsewered subdivision

Previous site-specific studies designed to assess the impacts of unsewered subdivisions on ground water quality have relied on upgradient monitoring wells or very limited background data to characterize conditions prior to development. In this study, an extensive monitoring program was designed to document ground water conditions prior to construction of a rural subdivision in south-central Wisconsin. Previous agricultural land use has impacted ground water quality; concentrations of chloride, nitrate-nitrogen, and atrazine ranged from below the level of detection to 296 mg/L, 36 mg/L, and 0.8 ??g/L, respectively, and were highly variable from well to well and through time. Seasonal variations in recharge, surface topography, aquifer heterogeneities, surficial loading patterns, and well casing depth explain observed variations in ground water chemistry. This variability would not have been detected if background conditions were determined from only a few monitoring wells or inferred from wells located upgradient of the subdivision site. This project demonstrates the importance of characterizing both ground water quality and chemical variability prior to land-use change to detect any changes once homes are constructed. Copyright ?? 2005 National Ground Water Association.

Ground Water↗
USGS1999

Nitrate, volatile organic compounds, and pesticides in ground water — A summary of selected studies from New Jersey and Long Island, New York

This report describes the ground-water systems in the unconsolidated sand and gravel aquifers of the Coastal Plain of New Jersey and Long Island and in the fractured bedrock and valley-fill aquifers of northern New Jersey; summarizes current knowledge about the occurrence and distribution of nitrate, volatile organic compounds (VOCs), and pesticides in these systems; and explains why some ground-water systems are more vulnerable to comtamination than others. Although the vulnerability of ground water to contamination from the land surface is influenced by many factors, the degree of aquifer confinement, the depth of the well, and the surrounding land use are key factors. Unconfined aquifers generally are much more vulnerable to contamination than confined aquifers. For a well in a confined aquifer, the farther the well is from the unconfined area, the less vulnerable it is to contamination. Generally, the deeper the well, the less vulnerable it is to contamination. Finally, because human activities greatly affect the quality of water that recharges an aquifer, the amount and type of land use in the area that contributes water to the well is a key factor in determining vulnerability. Nitrate contamination of ground water typically occurs in agricultural and residential areas, especially where the aquifer is very permeable and unconfined and nitrogen-fertilizer use is high. In New Jersey and on Long Island, concentrations of nitrate exceed the U.S. Environmental Protection Agency Maximum Contaminant Level (MCL) more often than those of VOCs or pesticides. Nitrate contamination generally is associated with nonpoint sources. VOC contamination of ground water occurs primarily in urban areas, especially in mixed urban and industrial areas where chemicals are used. In general, VOC concentrations are low and do not exceed MCLs. High concentrations of VOCs generally are associated with point sources. Pesticide contamination of ground water occurs in some agricultural and residential areas, where the aquifer is very permeable and unconfined, and where the chemicals are used. Concentrations of pesticides in New Jersey and on Long Island generally are low; in agricultural areas of Long Island, however, some have been found to exceed MCLs. Pesticide contamination generally is associated with nonpoint sources.

New Jersey, New York↗
USGS2005

Pre- and post-reservoir ground-water conditions and assessment of artificial recharge at Sand Hollow, Washington County, Utah, 1995-2005

Sand Hollow, Utah, is the site of a surface-water reservoir completed in March 2002, which is being operated by the Washington County Water Conservancy District primarily as an aquifer storage and recovery project. The reservoir is an off-channel facility receiving water from the Virgin River, diverted near the town of Virgin, Utah. It is being operated conjunctively, providing both surface-water storage and artificial recharge to the underlying Navajo aquifer. The U.S. Geological Survey and the Bureau of Reclamation conducted a study to document baseline ground-water conditions at Sand Hollow prior to the operation of the reservoir and to evaluate changes in ground-water conditions caused by the reservoir. Pre-reservoir age dating using tritium/helium, chlorofluorocarbons, and carbon-14 shows that shallow ground water in the Navajo Sandstone in some areas of Sand Hollow entered the aquifer from 2 to 25 years before sample collection. Ground water in low-recharge areas and deeper within the aquifer may have entered the aquifer more than 8,000 years ago. Ground-water levels in the immediate vicinity of Sand Hollow Reservoir have risen by as much as 80 feet since initial filling began in March 2002. In 2005, ground water was moving laterally away from the reservoir in all directions, whereas the pre-reservoir direction of ground-water flow was predominantly toward the north. Tracers, or attributes, of artificial recharge include higher specific conductance, higher dissolved-solids concentrations, higher chloride-to-bromide ratios, more-depleted stable isotopes ( 2 H and 18 O), and higher total-dissolved gas pressures. These tracers have been detected at observation and production wells close to the reservoir. About 15,000 tons of naturally occurring salts that previously accumulated in the vadose zone beneath the reservoir are being flushed into the aquifer. Except for the shallowest parts of the aquifer, this is generally not affecting water quality, largely because of the large saturated thickness of the Navajo aquifer. Since the initial filling of Sand Hollow Reservoir, arsenic concentrations have risen to exceed U.S. Environmental Protection Agency standards only in some shallow observation wells. These increases in arsenic concentration are likely caused by increasing pH associated with artificial recharge beneath the reservoir, rather than flushing of previously accumulated salts in the vadose zone. There has been no trend of increasing arsenic concentration in deeper production wells. Estimated evaporation rates for Sand Hollow Reservoir, calculated by the Jensen-Haise method with data from the Sand Hollow weather station, range from about 55 to 61 inches per year and result in a total evaporative loss of about 6,000 acre-feet of water from March 2002 to September 2004. Rates of artificial recharge of ground water beneath Sand Hollow Reservoir have ranged from about 0.02 to 0.44 feet per day, with an average rate excluding the initial 3-month wetting period of about 0.06 feet per day. A total of about 28,000 acre-feet of recharge to the underlying Navajo aquifer occurred from March 2002 to September 2004.

Utah↗
USGS2001

User interface for ground-water modeling: Arcview extension

Numerical simulation for ground-water modeling often involves handling large input and output data sets. A geographic information system (GIS) provides an integrated platform to manage, analyze, and display disparate data and can greatly facilitate modeling efforts in data compilation, model calibration, and display of model parameters and results. Furthermore, GIS can be used to generate information for decision making through spatial overlay and processing of model results. Arc View is the most widely used Windows-based GIS software that provides a robust user-friendly interface to facilitate data handling and display. An extension is an add-on program to Arc View that provides additional specialized functions. An Arc View interface for the ground-water flow and transport models MODFLOW and MT3D was built as an extension for facilitating modeling. The extension includes preprocessing of spatially distributed (point, line, and polygon) data for model input and postprocessing of model output. An object database is used for linking user dialogs and model input files. The Arc View interface utilizes the capabilities of the 3D Analyst extension. Models can be automatically calibrated through the Arc View interface by external linking to such programs as PEST. The efficient pre- and postprocessing capabilities and calibration link were demonstrated for ground-water modeling in southwest Kansas.

Journal of Hydrologic Engineering↗
USGS1963

Geology and ground-water conditions in southern Nassau and southeastern Queens Counties, Long Island, N.Y.

Test drilling, electrical logging, and water sampling of 'outpost' and other wells have revealed the existence of a deep confined body of salt water in the Magothy(?) formation beneath southwestern Nassau and southeastern Queens Counties, Long Island, N.Y. In connection with a test-drilling program, cooperatively sponsored by the U.S. Geological Survey, the Nassau County Department of Public Works, and the New York State Water Resources Commission (formerly Water Power and Control Commission), 13 wells ranging in depth from about 130 to 800 feet were drilled during 1952 and 1953 and screened at various depths in the Magothy(?) formation and Jameco gravel. On the basis of the preliminary geologic, hydrologic, and chemical data from these wells, a detailed investigation of ground-water conditions from the water table to the bedrock was begun in a 200-square-mile area in southern Nassau and southeastern Queens Counties. The Inain purposes of the investigation were to delineate the bodies of fresh and salty ground water in the project area, to relate their occurrence and movement to geologic and hydrologic conditions, to estimate the rate of encroachment, if any, of the salty water, and to evaluate the effectiveness of the existing network of outpost wells as detectors of salt-water encroachment. About a million people in the report area, residing mainly in southern Nassau County, are completely dependent on ground water as a source of supply. Fortunately, precipitation averages about 44 inches per year, of which approximately half is estimated to percolate into the ground-water reservoir. The ground water is contained in and moves through eight differentiated geologic units composed of unconsolidated gravel, sand, and clay, of Late Cretaceous, Pleistocene, and Recent age, having a maximum total thickness of about 1,700 feet. The underlying metamorphic and igneous crystalline basement rocks are of Precambrian age and are not water bearing. The water-yielding units from the surface down are (1) the upper Pleistocene deposits, (2) the principal artesian aquifer, composed of the Jameco gravel and Magothy(?) formation, and (3) the Lloyd sand member of the Raritar formation. The confining units are the '20-foot' clay, the Gardiners clay, and the clay member of the Raritan formation. The upper Pleistocene deposits contain an extensive unconfined body of fresh water. Fresh water under artesian conditions is contained in the principal artesian aquifer and the Lloyd sand member. The piezometric surface of the principal artesian aquifer is similar in shape to the south-ward-sloping water table; it ranges in altitude from about sea level to 55 feet above. The chemical quality of the fresh ground water in most of the area in all aquifers is good to excellent, and concentrations of dissolved solids and of chloride generally are below 100 ppm (parts per million) and 10 ppm, respectively. Analyses of water samples from selected wells show no progressive increase in concentration of chloride in most of the area. The data on quality of water have been used to delineate one major and several minor bodies of salty ground water. The wedgeshaped main confined salt-water body, in which the concentration of chloride reaches about 17,000 ppm, is in the Magothy(?) formation and Jameco gravel in extreme southwestern Nassau County and southeastern Queens County. The base of the salt-water wedge is about at the top of the clay member of the Raritan formation. Beneath the barrier beach in south-central and southeastern Nassau County a shallow extension of the main confined salt-water body contains as much as 4,000 ppm of chloride and is separated from the lower main salt-water body by fresh ground water. Shallow, thin bodies of unconfined salty ground water are common in the upper Pleistocene and Recent deposits adjacent to salty surface water in tidal creeks, bays, and the Atlantic

New York↗
USGS1972

Ground-water quality in Wisconsin through 1972

Ground water, a plentiful and largely underdeveloped resource of Wisconsin, has good to excellent chemical quality in most places. This resource is readily available in most parts of the State for municipal, industrial, and rural uses. In 1970, about 0.5 billion gallons of ground water a day was pumped in Wisconsin for all uses (Murray and Reeves, 1972). In addition, underground reservoirs discharge an average of 16 billion gallons per day of water of relatively constant temperature and uniform quality, which maintains the base flow of streams and the level of lakes (Holt, 1964).

Wisconsin↗
USGS2007

Atrazine and metolachlor occurrence in shallow ground water of the United States, 1993 to 1995: Relations to explanatory factors

Since 1991, the U.S. Geological Survey has been conducting the National Water Quality Assessment (NAWQA) Program to determine the quality of the Nation's water resources. In an effort to obtain a better understanding of why pesticides are found in shallow ground water on a national scale, a set of factors likely to affect the fate and transport of two herbicides in the subsurface were examined. Atrazine and metolachlor were selected for this discussion because they were among the most frequently detected pesticides in ground water during the first phase of the NAWQA Program (1993 to 1995), and each was the most frequently detected compound in its chemical class (triazines and acetanilides, respectively). The factors that most strongly correlated with the frequencies of atrazine detection in shallow ground-water networks were those that provided either: (1) an indication of the potential susceptibility of ground water to atrazine contamination, or (2) an indication of relative ground-water age. The factors most closely related to the frequencies of metolachlor detection in ground water, however, were those that estimated or indicated the intensity of the agricultural use of metolachlor. This difference is probably the result of detailed use estimates for these compounds being available only for agricultural settings. While atrazine use is relatively extensive in nonagricultural settings, in addition to its widespread agricultural use, metolachlor is used almost exclusively for agricultural purposes. As a result, estimates of agricultural applications provide a less reliable indication of total chemical use for atrazine than for metolachlor. A multivariate analysis demonstrated that the factors of interest explained about 50 percent of the variance in atrazine and metolachlor detection frequencies among the NAWQA land-use studies examined. The inclusion of other factors related to pesticide fate and transport in ground water, or improvements in the quality and accuracy of the data employed for the factors examined, may help explain more of the remaining variance in the frequencies of atrazine and metolachlor detection.

Journal of the American Water Resources Associatio↗
USGS2005

Effects of urban storm-runoff control on ground-water recharge in Nassau County, New York

Before urban development, most ground-water recharge on Long Island, New York, occurred during the dormant season, when evapotranspiration is low. The use of recharge basins for collection and disposal of urban storm runoff in Nassau County has enabled ground-water recharge to occur also during the growing season. In contrast, the use of storm sewers to route storm runoff to streams and coastal waters has resulted in a decrease in ground-water recharge during the dormant season. The net result of these two forms of urban storm-runoff control has been an increase in annual recharge of about 12 percent in areas served by recharge basins and a decrease of about 10 percent in areas where storm runoff is routed to streams and tidewater. On a countywide basis, annual ground-water recharge has remained nearly the same as under predevelopment conditions, but its distribution pattern has changed. Redistribution resulted in increased recharge in the eastern and central parts of the county, and decreased recharge in the western and nearshore areas. Model simulation of recharge indicates that the water-table altitude has increased by as much as 5 ft above predevelopment levels in areas served by recharge basins and declined by as much as 3 feet in areas where stormwater is discharged to streams and tidewater.

Groundwater↗
USGS1996

Assessment of severity and distribution of corrosive ground water in Pennsylvania

Relations between corrosive ground water, water chemistry, and geology in Pennsylvania were evaluated by use of a modified version of the Langelier Saturation Index (LSIsn) and a geologic contact dataset in a Geographic Information System. Water-chemistry information for water samples collected from 4,839 combined private and public-supply wells from 1900 to 1993 was used to calculate the LSIsn. Thirty-eight lithologic subgroups within four major rock types-carbonate, siliciclastic, crystalline, and unconsolidated-in Pennsylvania were grouped together if the mean of ranked LSIsn values were not significantly different. A water is considered corrosive if the LSIsn value is negative, preventing the precipitation of calcium carbonate, therefore, allowing corrosive reactions with the interior of piping systems. Statistical tests of the LSIsn values show the least corrosive waters are in the carbonate lithologic subgroup, and the most corrosive waters are in the quartzite lithologic subgroup. Approximately 58 percent of the 4,839 LSIsn values were considered moderately to extremely corrosive. A map showing the location of 4,839 wells and associated corrosivity range within 11 lithologic subgroups will aid in identifying potential areas of corrosive ground water in Pennsylvania.

Open-File Report↗
USGS1996

Hydrogeology and simulation of ground-water flow at the South Well Field, Columbus, Ohio

The City of Columbus, Ohio, operates four radial collector wells in southern Franklin County. The 'South Well Field' is completed in permeable outwash and ice-contact deposits, upon which flow the Scioto River and Big Walnut Creek. The wells are designed to yield approximately 42 million gallons per day; part of that yield results from induced infiltration of surface water from the Scioto River and Big Walnut Creek. The well field supplied up to 30 percent of the water supply of southern Columbus and its suburbs in 1991. This report describes the hydrogeology of southern Franklin County and a tran sient three-dimensional, numerical ground-water- flow model of the South Well Field. The primary source of ground water in the study area is the glacial drift aquifer. The glacial drift is composed of sand, gravel, and clay depos ited during the Illinoian and Wisconsinan glaciations. In general, thick deposits of till containing lenses of sand and gravel dominate the drift in the area west of the Scioto River. The thickest and most productive parts of the glacial drift aquifer are in the buried valleys in the central and eastern parts of the study area underlying the Scioto River and Big Walnut Creek. Horizontal hydraulic conductivity of the glacial drift aquifer differs spa tially and ranges from 30 to 375 feet per day. The specific yield ranges from 0.12 to 0.30. The secondary source of ground water within the study area is the underlying carbonate bedrock aquifer, which consists of Silurian and Devonian limestones, dolomites, and shales. The horizontal hydraulic conductivity of the carbonate bedrock aquifer ranges from 10 to 15 feet per day. The storage coefficient is about 0.0002. The ground-water-flow system in the South Well Field area is recharged by precipitation, regional ground-water flow, and induced stream infiltration. Yearly recharge rates varied spatially and ranged from 4.0 to 12.0 inches. The three-dimensional, ground-water-flow model was constructed by use of the U.S. Geological Survey three-dimensional finite-difference ground-water-flow code. Recharge, boundary flux, and river leakage are the principal sources of water to the flow system. The study area is bounded on the north and south by streamlines, with flow entering the area from the east and west. Areal recharge is contributed throughout the study area, although a comparatively high percentage of precipitation reaches the water table in the area east of the Scioto River where little surface drain age exists. Ground-water flow is downward in the uplands of the Scioto River, and upward near the river in the glacial drift and carbonate bedrock aquifers. The numerical model contains 53 rows, 45 columns, and 3 layers. The uppermost two layers represent the glacial drift. The bottom layer represents the carbonate bedrock. The horizontal model grid is variably spaced to account for differences in available data and to simulate heads accurately in specific areas of interest. The length and width of grid cells range from 200 to 2,000 feet; the finer spacings are designed to increase detail in the areas near the collector wells. The model uses 7,155 active nodes. Measurements of water levels from October 1979 were used to represent steady-state conditions before municipal pumping at the well field began. Measurements made during March 1986 were used to represent steady-state conditions after commencement of pumping at the well field. Water levels measured during March 1986 - June 1991 were used for calibration targets in the transient simulations. The transient model was discretized into eight stress periods of 93 to 487 days on the basis of recharge, well-field pumpage, and available water-level data. Transient model calibration was based on seven sets of hydraulic-head measure ments made during March 1986 - June 1991. This time period includes large-scale increases in well- field production associated with a drought in the summer of 1988, an

Water-Resources Investigations Report↗
USGS2005

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [ 18 O/ 16 O (δ 18 O), 2 H/ 1 H (δD), 13 C/ 12 C (δ 13 C), tritium ( 3 H), and strontium‐87/strontium‐86 ( 87 Sr/ 86 Sr)] along with geochemical mass‐balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (δ 18 O and <δD) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass‐balance calculations, based on differences in δ 18 O and δD, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18 O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, δ 13 C and 87 Sr/ 86 Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post‐ 1950s concentrations of 3 H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.

Ground Water↗
USGS1983

Ground-water quality data for Oklahoma, 1981

The U.S. Geological Survey has collected data on Oklahoma's ground-water resources since 1934. Most of these data were collected as part of specific ground-water studies conducted in cooperation with various Federal, State, and local agencies. Ground-water quality data, as well as data on construction, yield, water levels, and other physical well parameters collected prior to 1981 are available from the U.S. Geological Survey, Oklahoma District Office. Although water-quality data for wells, test holes, and springs have been published, they are scattered though a variety of reports and are not readily available on a statewide basis. The purpose of this report is to make available, annually, all of the ground-water quality data collected by the U.S. Geological Survey in the Sate of Oklahoma. This report contains ground-water quality data collected in 1981 from 524 sites in 15 counties, predominately in eastern Oklahoma.

Open-File Report↗
USGS2004

Simulated effects of impoundment of lake seminole on ground-water flow in the upper Floridan Aquifer in southwestern Georgia and adjacent parts of Alabama and Florida

Hydrologic implications of the impoundment of Lake Seminole in southwest Georgia and its effect on components of the surface- and ground-water flow systems of the lower Apalachicola?Chattahoochee?Flint (ACF) River Basin were investigated using a ground-water model. Comparison of simulation results of postimpoundment drought conditions (October 1986) with results of hypothetical preimpoundment conditions (a similar drought prior to 1955) provides a qualitative measure of the changes in hydraulic head and ground-water flow to and from streams and Lake Seminole, and across State lines caused by the impoundment. Based on the simulation results, the impoundment of Lake Seminole changed ground-water flow directions within about 20?30 miles of the lake, reducing the amount of ground water flowing from Florida to Georgia southeast of the lake. Ground-water storage was increased by the impoundment, as indicated by a simulated increase of as much as 26 feet in the water level in the Upper Floridan aquifer. The impoundment of Lake Seminole caused changes to simulated components of the ground-water budget, including reduced discharge from the Upper Floridan aquifer to streams (315 million gallons per day); reduced recharge from or increased discharge to regional ground-water flow at external model boundaries (totaling 183 million gallons per day); and reduced recharge from or increased discharge to the undifferentiated overburden (totaling 129 million gallons per day).

Alabama, Florida, Georgia↗
USGS1992

Ground-water levels and directions of flow in the vicinity of a well field, Elkhart, Indiana, December 1989

Water levels were measured in 51 observation wells in the vicinity of the Elkhart Water Works Main Street well field during 5 days of normal pumping at the well field and little or no recharge to the ground water from precipitation. Water levels were measured once each day during December 18-22, 1989. Water-level altitudes were plotted and contoured on maps to determine the distribution of ground-water levels and directions of flow in the unconfined sand and gravel aquifer tapped by the well field. Measured ground-water levels ranged from about 7.5 to 30 feet below land surface. Ground-water levels were highest north and northwest of the Main Street well field and lowest at the Main Street well field and near the St. Joseph River. Regional ground-water flow is toward the south or southeast. Ground-water levels near the river are higher than the river stage, indicating that ground water discharges to the river. As a result of pumping, three cones of depression have formed in the water table in the mapped area. A small cone of depression northwest of the Main Street well field is caused by industrial pumping. Two cones of depression have formed at the Main Street well field-one in the eastern part of the well field and one in the western part of the well field. Horizontal hydraulic gradients are variable in the study area but are largest in the eastern part of the Main Street well field and near the St. Joseph River. In general, water levels measured in seven sets of paired wells do not indicate a vertical hydraulic gradient; however, a downward gradient was measured in one set of paired wells near a pumped area at the Main Street well field.

Indiana↗
USGS1997

Pesticides in surface and ground water of the San Joaquin-Tulare basins, California: Analysis of available data, 1966 Through 1992

Available pesticide data (1966-92) for surface and ground water were analyzed for the San Joaquin-Tulare Basins, California, one of 60 large hydrologic systems being studied as part of the National Water-Quality Assessment Program of the U.S. Geological Survey. Most of the pesticide data were for the San Joaquin Valley, one of the most intensively farmed and irrigated areas of the United States. Data were obtained from the Storage and Retrieval data base of the U.S. Environmental Protection Agency, the water-quality data base of the U.S. Geological Survey, and from data files of State agencies. Pesticides detected in surface water include organochlorine pesticides, organophosphate pesticides, carbamate pesticides, and triazine herbicides. Pesticides detected in ground water include triazine and other organonitrogen herbicides and soil fumi gants. Surface-water data indicate seasonal patterns for the detection of organophosphate and carbamate pesticides, which are attributed to their use on almond orchards and alfafa fields. Organochlorine pesticides were detected primarily in river-bed sediments. Concentrations detected in bed sediments of the San Joaquin River near Vernalis are among the highest of any major river system in the United States. Patterns and timing of pesticide use indicate that pesticides might be present in surface-water systems during most months of a year. The most commonly detected pesticide in ground water is the soil fumigant, dibromochloropropane. Dibromochloropropane, used primarily on vineyards and orchards, was detected in ground water near the city of Fresno. Triazine and other organonitrogen herbicides were detected near vineyards and orchards in the same general locations as the detections of dibromochloropropane. Pesticides were detected in ground water of the east side of the valley floor, where the soils are sandy or coarsegrained, and water-soluble pesticides with long environmental half-lives were used. In contrast, fewer pesticides were detected in ground water of the west side of the valley, where soils generally are finer grained.

California↗
USGS1998

Technology Transfer Opportunities: Automated Ground-Water Monitoring, A Proven Technology

Introduction The U.S. Geological Survey (USGS) has developed and tested an automated ground-water monitoring system that measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automated ground-water monitoring systems can be used to monitor known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, to serve as early warning systems monitoring ground-water quality near public water-supply wells, and for ground-water quality research.

Fact Sheet↗
USGS2006

Geochemical patterns of arsenic-enriched ground water in fractured, crystalline bedrock, Northport, Maine, USA

High mean As concentrations of up to 26.6 ??mol/L (1990 ??g/L) occur in ground water collected from a fractured-bedrock system composed of sulfidic schist with granitic to dioritic intrusions. Sulfides in the bedrock are the primary source of the As in the ground water, but the presence of arsenopyrite in rock core retrieved from a borehole with As concentrations in the ground water barely above the detection limit of 2.0 ??mol/L, shows that there are complicating factors. Chemical analyses of water from 35 bedrock wells throughout a small watershed reveal spatial clustering of wells with high As concentrations. Stiff diagrams and box plots distinguish three distinct types; calcium-bicarbonate-dominated water with low As concentrations (CaHCO 3 type), sodium-bicarbonate-dominated water with moderately high As concentrations (NaHCO3 type), and calcium-bicarbonate-dominated water with very high As concentrations (High-As type). It is proposed that differences in recharge area and ground-water evolution, and possible bedrock composition difference are responsible for the chemical distinctions within the watershed. Lack of correlation of As concentrations with pH indicates that desorption of As is an insignificant control on As concentration. Correlations of As concentrations with Fe and redox parameters indicates that reductive dissolution of Fe(III) oxyhydroxides may play a role in the occurrence of high As concentrations in the NaHCO3 and High-As type water. The oxidation of sulfide minerals occurs within the ground-water system and is ultimately responsible for the existence of As in the ground water, but there is no correlation between As and SO4 concentrations, probably due to precipitation of Fe(III) oxyhydroxides and adsorption of As under oxidizing conditions. Crown Copyright ?? 2006 Published by Elsevier Ltd. All rights reserved.

Applied Geochemistry↗