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USGS2015

Geochemical conditions and the occurrence of selected trace elements in groundwater basins used for public drinking-water supply, Desert and Basin and Range hydrogeologic provinces, 2006-11: California GAMA Priority Basin Project

The geochemical conditions, occurrence of selected trace elements, and processes controlling the occurrence of selected trace elements in groundwater were investigated in groundwater basins of the Desert and Basin and Range (DBR) hydrogeologic provinces in southeastern California as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP is designed to provide an assessment of the quality of untreated (raw) groundwater in the aquifer systems that are used for public drinking-water supply. The GAMA PBP is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The DBR hydrogeologic provinces consist of 141 defined groundwater basins separated by mountain ranges, faults, and other features. This report presents analyses of data collected from nine study areas within the DBR hydrogeologic provinces: Antelope Valley, Borrego Valley, the Central Desert area, Coachella Valley, Colorado River, Indian Wells Valley, Low-Use Basins of the Mojave and Sonoran Deserts, the Mojave, and Owens Valley. Collectively, these nine study areas are referred to as the DBR study unit. The study unit covers approximately 7,000 square miles and includes the 63 groundwater basins in the DBR hydrogeologic provinces in which groundwater is used for public drinking-water supply. The vast majority of the 223 wells sampled for this study were long-screened production wells used primarily for public supply. Uncorrected carbon-14 ( 14 C) groundwater ages for samples collected in the DBR study unit ranged from less than (<) 100 to 33,700 years before present (BP). Sixty-six percent of sample ages were greater than (>) 100 years BP, and 40 percent were >3,800 years BP. Samples collected from wells located adjacent to mountain-front recharge areas or major surface-water features generally had younger groundwater ages than did samples collected from wells located away from mountain fronts or towards the distal ends of basin groundwater flow paths. Most groundwater sampled in the DBR study unit had alkaline pH: 89 percent of sample pH values ranged from 7.1 to 9.8, with 37 percent greater than or equal to (≥) 7.9. Groundwater age was significantly correlated (positively) with pH, likely because silicate weathering is a primary control on groundwater pH and is a slow process. The oxidation-reduction (redox) condition of the groundwater sampled in the DBR study unit was predominantly oxic (71 percent), except in the Colorado River study area where organic-rich fluvial aquifers provide the electron donors necessary to support iron-reducing (anoxic-Fe) redox processes. The cation type of 78 percent of the samples was either sodium- or mixed-type, and the anion type of 83 percent of the samples was either bicarbonate- or mixed-type. Sodium-type groundwaters generally were older and more alkaline than calcium-type groundwaters, consistent with the change in water chemistry expected from cation exchange between groundwater and aquifer sediments over long periods of time. Because of the correlation with young groundwater, calcium-type groundwater was predominantly from wells located adjacent to mountain-front recharge areas. Arsenic (As), boron (B), fluoride (F), molybdenum (Mo), strontium (Sr), uranium (U), and vanadium (V) were selected for assessment in this study because they occurred at concentrations greater than California Department of Public Health or U.S. Environmental Protection Agency regulatory or non-regulatory drinking-water-quality benchmarks in more than 2 percent of the 223 samples collected in the DBR study unit. As and F were detected most commonly (18 and 13 percent, respectively) at concentrations above associated water-quality benchmarks and Sr and V least frequently (both at 3 percent). Given that 14 C groundwater ages are predominantly >100 years BP, land use in the study unit is primarily undeveloped, and chemicals derived from anthropogenic sources, such as volatile organic compounds, were infrequently detected, high concentrations of these trace elements in groundwater were most likely the result of natural factors and not anthropogenic factors. As, F, Mo, and V concentrations showed significant positive correlations to groundwater age and to pH. This relation is partly due to the sources of trace elements likely being the weathering of primary minerals, such as silicate minerals, which is a slow process that takes place over hundreds to thousands of years. This relation also reflects the positive correlation between groundwater age and pH. Geochemical modeling predicted that the dominant species of As, Mo, and V in solution were oxyanions (HAsO 4 2– , MoO 4 2– , and H 2 VO 4– ), which are likely to be mobile in alkaline groundwater because mineral surfaces composing aquifer matrices have a predominantly negative surface charge under alkaline conditions. F also exists predominantly as a negatively charged ion (F – ). At pH values >7.5, saturation indices generated by the geochemical modeling program PHREEQC indicated that F solubility may be somewhat limited by the precipitation of the mineral fluorapatite [Ca 5 (PO 4 ) 3 F]. Speciation modeling of As in anoxic-Fe groundwater (iron-reducing conditions) showed that samples were supersaturated with orpiment (As 2 S 3 ), indicating that mineral precipitation may be responsible for low As concentrations observed in reducing groundwater. In contrast, U concentrations showed significant negative correlations to groundwater age and to pH. Higher U concentrations generally occurred in samples for which geochemical modeling indicated that the uncharged ternary complex Ca 2 UO 2 (CO 3 ) 3 was the dominant aqueous U species. This uncharged complex is not attracted to the charged surfaces of minerals and thus increases U solubility. Formation of Ca 2 UO 2 (CO 3 ) 3 was greater in younger groundwaters because calcium and uranium concentrations generally were lower in older groundwaters, likely due to cation-exchange processes and precipitation of the mineral calcite as groundwater pH increased. Co-precipitation of U with the calcite (CaCO 3 ) may remove U from the aqueous phase. Saturation indices indicated that the anoxic-Fe groundwaters from the Colorado River study area were supersaturated with the mineral uraninite (UO 2 ), suggesting that UO 2 precipitation may be responsible for the low concentrations of U observed in these samples. Concentrations of strontium, which exists primarily in a cationic form (Sr 2+ ), were not significantly correlated with either groundwater age or pH. Strontium concentrations showed a strong positive correlation with total dissolved solids (TDS). Dissolved constituents, such as Sr, that interact with mineral surfaces through outer-sphere complexation become increasingly soluble with increasing TDS concentrations of groundwater. Boron concentrations also showed a significant positive correlation with TDS, indicating the B may interact to a large degree with mineral surfaces through outer-sphere complexation.

California↗

USGS2017

Maps and grids of hydrogeologic information created from standardized water-well drillers’ records of the glaciated United States

As part of the National Water Availability and Use Program established by the U.S. Geological Survey (USGS) in 2005, this study took advantage of about 14 million records from State-managed collections of water-well drillers’ records and created a database of hydrogeologic properties for the glaciated United States. The water-well drillers’ records were standardized to be relatively complete and error-free and to provide consistent variables and naming conventions that span all State boundaries. Maps and geospatial grids were developed for (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The information included in these maps and grids is required for most assessments of groundwater availability, in addition to having applications to studies of groundwater flow and transport. The texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity were based on an assumed range of hydraulic conductivity values for coarse- and fine-grained deposits and should only be used with complete awareness of the methods used to create them. However, the maps and grids of texture-based estimated equivalent hydraulic conductivity and transmissivity may be useful for application to areas where a range of measured values is available for re-scaling. Maps of hydrogeologic information for some States are presented as examples in this report but maps and grids for all States are available electronically at the project Web site (USGS Glacial Aquifer System Groundwater Availability Study, http://mi.water.usgs.gov/projects/WaterSmart/Map-SIR2015-5105.html ) and the Science Base Web site, https://www.sciencebase.gov/catalog/item/58756c7ee4b0a829a3276352 .

Alaska, Connecticut, Idaho, Illinois, Indiana, Iow↗

USGS2015

Lead scrap use and trade patterns in the United States, 1995-2012

Since 1995, domestic production of lead has increasingly shifted from primary mining and smelting to the recovery of lead-bearing scrap by the secondary lead industry, which accounted for 91 percent of U.S. lead production in 2012. Increasingly stringent environmental regulations for lead emissions in the United States have contributed to the closure of primary lead refineries and the consolidation of the secondary lead industry. Domestic production of lead from the primary and secondary sectors in 2012 is essentially unchanged from the amount produced in 1995. The U.S. secondary industry produced an estimated 145,000 metric tons more refined lead in 2012 than it did in 1995, primarily by recovering lead from battery scrap, allowing the U.S. to maintain production at a level sufficient to supply much of the domestic demand for lead. Exports of lead contained in batteries, electronics, and scrap and waste increased more than 380 percent from 1998 through 2011. Trade patterns of lead scrap products among Canada, Mexico, and the United States have changed since initiation of the North American Free Trade Agreement in 1994, providing more flexibility of movement of materials such as lead scrap among these three trading partners. Canada was the source of an average of 98 percent of the lead contained in scrap batteries imported into the United States during the period 1998 through 2012. Canada received about 92 percent of the lead contained in scrap and waste exported from the United States in 1998; Mexico received about 89 percent of the lead contained in battery scrap exported from the United States in 2012. Domestic secondary lead facilities have been able to maintain production because of increasing domestic and foreign supply of spent lead-acid vehicle batteries, which accounted for about 95 percent of U.S. secondary lead consumption in 2012. Increased industrialization in China, India, and the Republic of Korea has led to increased demand for lead concentrates, lead scrap, and refined lead from imported sources to supplement growing domestic production. Consequently, about 94 percent of the lead in ores and concentrate produced in the United States was exported to Asia in 2012 compared to about 18 percent in 1995, and about 72 percent of lead-based scrap was exported from the United States to Asian countries in 2012 compared to about 7 percent in 1995.

Scientific Investigations Report↗

USGS2016

Hydrogeologic investigations of the Miocene Nogales Formation in the Nogales Area, Upper Santa Cruz Basin, Arizona

Hydrogeologic investigations were conducted to evaluate the groundwater resource potential for the Miocene Nogales Formation in the Nogales area, southern Arizona. Results indicate that parts of the formation may provide new, deeper sources of groundwater for the area. Geologic mapping determined the hydrogeologic framework of the formation by defining lithologic, mineralogic, and stratigraphic characteristics; identifying potential aquifers and confining units; and mapping faults and fractures which likely influence groundwater flow. Geophysical modeling was used to determine the basin geometry and thickness of the Nogales Formation and younger alluvial aquifers and to identify target areas (deep subbasins) which may prove to be productive aquifers. Volcaniclastic sandstone samples from the formation were analyzed for porosity, bulk density, saturated hydraulic conductivity, and fabric. Effective porosity ranges from 16 to 42 percent, bulk density from 1.6 to 2.47 grams per cubic centimeter, and saturated hydraulic conductivity (SHC) from 4 to 57 centimeters per day (4.9×10 -5 to 6.7×10 -4 centimeters per second). Thin sections show that sandstone framework grains consist of quartz, feldspar, biotite, hornblende, pumice, volcanic glass, and opaque minerals. The matrix in most samples consists of pumice fragments, and some contain predominantly silt and clay. Samples with a mostly silt and clay matrix have lower porosity and SHC compared to samples with mostly pumice, which have higher and wider ranges of porosity and SHC. Pore space in the Nogales Formation sediments includes moldic, intercrystalline, and fracture porosity. Some intercrystalline pore space is partially filled with calcite cement. About one third of the samples contain fractures, which correspond to fractures noted in outcrops in all members of the formation. Scanning electron microscope (SEM) and x-ray diffraction (XRD) analyses indicate that most of the samples contained the zeolite clinoptilolite and mixed-layer clay. X-ray diffraction analyses verified clinoptilolite as the only zeolite in Nogales Formation samples; they also verified the presence of smectite and illite clay and some kaolinite. Samples which contain greater amounts of clinoptilolite and lesser amounts of smectite have high porosity and SHC in narrow ranges. However, samples with abundant smectite and lesser amounts of clinoptilolite span the entire ranges of porosity and SHC for the formation. All members of the Nogales Formation are fractured and faulted as a result of Tertiary Basin and Range extensional deformation, which was broadly contemporaneous with deposition of the formation. These structures may have significant influence on groundwater flow in the upper Santa Cruz basin because, although many of the sediments in the formation have characteristics indicating they may be productive aquifers based only on porous-media flow, fracturing in these sediments may further enhance permeability and groundwater flow in these basin-fill aquifers by orders of magnitude.

Arizona↗

USGS2017

The discovery and character of Pleistocene calcrete uranium deposits in the Southern High Plains of west Texas, United States

This report describes the discovery and geology of two near-surface uranium deposits within calcareous lacustrine strata of Pleistocene age in west Texas, United States. Calcrete uranium deposits have not been previously reported in the United States. The west Texas uranium deposits share characteristics with some calcrete uranium deposits in Western Australia—uranium-vanadium minerals hosted by nonpedogenic calcretes deposited in saline lacustrine environments. In the mid-1970s, Kerr-McGee Corporation conducted a regional uranium exploration program in the Southern High Plains province of the United States, which led to the discovery of two shallow uranium deposits (that were not publicly reported). With extensive drilling, Kerr-McGee delineated one deposit of about 2.1 million metric tons of ore with an average grade of 0.037 percent U 3 O 8 and another deposit of about 0.93 million metric tons of ore averaging 0.047 percent U 3 O 8 . The west-Texas calcrete uranium-vanadium deposits occur in calcareous, fine-grained sediments interpreted to be deposited in saline lakes formed during dry interglacial periods of the Pleistocene. The lakes were associated with drainages upstream of a large Pleistocene lake. Age determinations of tephra in strata adjacent to one deposit indicate the host strata is middle Pleistocene in age. Examination of the uranium-vanadium mineralization by scanning-electron microscopy indicated at least two generations of uranium-vanadium deposition in the lacustrine strata identified as carnotite and a strontium-uranium-vanadium mineral. Preliminary uranium-series results indicate a two-component system in the host calcrete, with early lacustrine carbonate that was deposited (or recrystallized) about 190 kilo-annum, followed much later by carnotite-rich crusts and strontium-uranium-vanadium mineralization in the Holocene (about 5 kilo-annum). Differences in initial 234 U/ 238 U activity ratios indicate two separate, distinct fluid sources.

Texas↗

USGS2019

Capacity and area of Grand Lake O’ the Cherokees, northeastern Oklahoma, 2009

In February 2017, the Grand River Dam Authority filed to relicense the Pensacola Hydroelectric Project with the Federal Energy Regulatory Commission. The predominant feature of the Pensacola Hydroelectric Project is Pensacola Dam, which impounds Grand Lake O’ the Cherokees (locally called Grand Lake) in northeastern Oklahoma. Identification of information gaps and assessment of project effects on stakeholders are central aspects of the Federal Energy Regulatory Commission relicensing process. Due to the natural changes to the reservoir over time, new capacity and area tables are needed periodically. The most recent complete capacity and area table was produced in 1940. Capacity and area tables identify the relations between the elevation of the water surface and the volume of water that can be impounded at each water surface elevation. This report (1) presents an updated capacity and area table for Grand Lake O’ the Cherokees for 2009, (2) describes the methods used to calculate the updated capacity and area values presented in the table, and (3) compares the updated capacity table to historical capacity tables produced from a survey in 1940 and from a hydrographic survey of the lake by the Oklahoma Water Resources Board in 2009. The new capacity values computed for Grand Lake O’ the Cherokees indicate that capacity at conservation pool elevation has decreased about 157,000 acre-feet or 10 percent since 1940 and capacity at top of dam elevation has decreased about 200,000 acre-feet or 8 percent since 1940. This difference in the capacities could be attributed to the advancements of technologies; the techniques used for surveying lakes have changed from the 1940 survey to the 2009 survey. Another possible reason for loss in capacity could be as time progresses, lakes like Grand Lake O’ the Cherokees slowly impound sediment carried by the rivers that feed into the lakes, thus diminishing the amount of water that the lake holds. The most recent survey used measured water depths and Global Position System collected electronically, but the methods used to collect data in 1940 are unknown. Due to the advancement of technology, the 2009 survey is likely more precise than the 1940 survey.

Oklahoma↗

USGS2021

A comparison of Landsat 8 Operational Land Imager and Provisional Aquatic Reflectance science product, Sentinel–2B, and WorldView–3 imagery for empirical satellite-derived bathymetry, Unalakleet, Alaska

Satellite-derived bathymetry (SDB) based upon an empirical band ratio method is a cost-effective means for mapping nearshore bathymetry in coastal areas vulnerable to natural hazards. This is particularly important for the low-lying coastal community of Unalakleet, Alaska, that has been negatively affected not only by flooding, storm surge, and historically strong storms but also by high erosion rates stemming from the Unalakleet River and Norton Sound. The purpose of this study was to assess the viability of different satellite imagery, including Landsat 8 (L8) Operational Land Imager, Sentinel–2B, WorldView–3, and L8 Provisional Aquatic Reflectance science product, for deriving SDB for Unalakleet, Alaska. Correlations were performed between satellite imagery band ratios and topobathymetric (topobathy) light detection and ranging (lidar) and in situ single-beam sound navigation and ranging (sonar). The satellite imagery correlations with topobathy lidar did not yield as high of a linear relation with water depths as the satellite imagery correlations with the single-beam sonar. An extinction depth, where light no longer attenuates through the water column, was not identified because of the shallow depths within the topobathy lidar and single-beam sonar datasets. Although some single-beam soundings measured at 7 meters deep, the correlations with the SDB band ratios did not yield a strong linear relation. Satellite imagery band ratio correlations with Electronic Navigational Chart soundings did not yield a strong linear relation because of older source data. Less than optimal linear regressions were most likely due to the geography of Unalakleet, Alaska, a low-lying coastal community subject to high erosion rates from surrounding waters. This study is one of the first attempts to compare different satellite imagery band ratio correlations with topobathy lidar and in situ sonar to assess the viability for nearshore SDB for coastal Unalakleet, Alaska.

Alaska↗

USGS2022

2021 assessment of the Joint Fire Science Program’s Fire Science Exchange Network

The U.S. Geological Survey (USGS), on behalf of the Joint Fire Science Program (JFSP), conducted an evaluation of the Fire Science Exchange Network (FSEN), which connects wildland fire scientists and practitioners through 15 individual exchanges across the United States to help address complex wildfire needs and challenges. The study was divided into two phases: The first phase was a literature review and synthesis from materials provided by the JFSP Board. Phase two, informed by the JFSP review, was an online survey sent to more than 16,000 exchange network users compiled from the electronic mailing lists for each exchange. Respondents were asked their opinions on the importance, quality, and delivery of information for 16 key fire science topics, the prioritization of FSEN objectives, and from where and to what extent respondents are gathering information on key topics. Overall, respondents believed that sharing information and building relationships are the most important objectives of the FSEN. Respondents believed the exchange network is successful in delivering information for many of the key science topics (for example, fire behavior, prescribed fire, firefighter safety, and incident management); gaps were identified in scientific resources available for some topics (for example, economic impacts, social science and human dimensions, Indigenous knowledge). Most respondents participated in one to two exchanges and relied heavily on their respondent location (the exchange in which they primarily live and [or] work) for information. Respondents also often relied on external sources outside of the exchange network. Regional patterns emerged in information gathering whereby respondents from exchanges in the western United States (for example, Northern Rockies, Southern Rockies, and Northwest) and respondents from exchanges in the eastern United States (for example, Southern, Oak Woodlands, and Tallgrass) frequently gathered information from each other.

Scientific Investigations Report↗

USGS2023

Analysis of high-resolution single channel seismic data for use in sediment resource evaluation, eastern Texas and western Louisiana Continental Shelf, Gulf of Mexico

Shallow subsurface geologic data recorded as high-resolution seismic profiles are used to interpret the geology of coastal and marine systems. These data were originally recorded on paper rolls that are stored in geophysical archives. Data collection has since converted to entirely digital formats, yet the analog data are still useful for geologic interpretation. This report describes the process of recovering analog copies of seismic profiles from physical archives, electronically scanning, and converting them to industry-standard digital format. The recovered data are also reviewed and assessed for potential sediment resources. The data recovered in this study were collected from the Gulf of Mexico continental shelf offshore of East Texas and West Louisiana. The project is a collaborative study between the U.S. Geological Survey and the Bureau of Ocean Energy Management.

Louisiana, Texas↗

USGS2024

Monitoring lahars

Introduction Lahars, or debris flows that originate from a volcano (Pierson and Scott, 1985; Pierson, 1995), are among the most destructive, far-reaching, and persistent hazards on stratovolcanoes. Lahars may be triggered by syneruptive rapid melting of snow and ice, lake breakouts, or heavy rains in conjunction with large eruptive columns. Alternatively, lahars can follow eruptions, when clastic deposits are mobilized by heavy rainfall or lake breakouts, occurring sporadically for years to decades after large eruptions. Some lahars can travel many tens of kilometers in river drainages stemming from volcanoes, as during the 1980 eruption of Mount St. Helens (Washington) (for example, Janda and others, 1981), recent eruptions of Redoubt Volcano (Alaska) (fig. H1; Dorava and Meyer, 1994; Waythomas and others, 2013), and the 1991 eruption of Mount Pinatubo (Philippines) (Major and others, 1996; Pierson and others, 1996). Large lahars are less likely in the absence of eruptive activity, but still possible. The Electron Mudflow at Mount Rainier (approximately A.D. 1500), Wash., is an example of a potential noneruptive lahar, likely initiated by a spontaneous collapse of weak rock, that reached the Puget Lowland after it flowed dozens of kilometers without a recognized eruptive trigger (Sisson and Vallance, 2009). The extreme hazard posed by lahars was demonstrated tragically by the 1985 Nevado del Ruiz (Colombia) catastrophe that claimed the lives of more than 20,000 people (Naranjo and others, 1986). The potential to provide warnings of minutes to hours in advance of lahar arrival in a populated area (for example, Voight, 1990) is a strong reason to provide special monitoring attention to the hazard. Populated river valleys are located downstream from many very high threat and high threat volcanoes, and these areas could be affected by lahars (for example, Hoblitt and others, 1998). The volume and mobility of lahars are two characteristics that can influence the extent of downstream effects (for example, George and others, 2022). The flows that reach the farthest downstream are mobile and voluminous. Additionally, entrainment of material as a lahar travels downstream may increase the volume, and a lahar that starts small may grow to a destructive size under certain conditions. Increasingly, stratovolcanoes host recreational enthusiasts who could be affected by relatively localized geologic hazards, such as rainfall-induced debris flows, glacial outburst floods, rockfalls, and avalanches. These types of events can be common on many volcanoes, occurring seasonally in the case of debris flows and several times per year in the case of avalanches and rockfalls (for example, Allstadt and others, 2018). Many very high threat stratovolcanoes, especially within the contiguous United States, have low eruption frequencies (less than once per century), such that monitoring networks could be used more often for detection and characterization of small surface flows than for identification of volcanic unrest. Such information can be used to validate avalanche forecasts, inform rescue efforts, or notify other agencies of potentially damaged infrastructure (for example, roads, powerlines, or trails). Note that although many of these smaller surface flows create seismic and infrasound waves, the signals are typically highly distorted by the complex volcanic topography and geology. In general, the smaller the flow, the weaker the geophysical signals that it generates, and thus a denser geophysical network is required to study smaller flows (for example, Allstadt and others, 2018). Lahar detection may not be an appropriate or necessary monitoring capability for all volcanoes. Some very high threat volcanoes, like Kīlauea and Mauna Loa, have no lahar hazards currently, and thus no detection, tracking, and characterization capabilities for lahars are needed. At other very high threat volcanoes, such as Pavlof Volcano, Alaska, lahars might be common but pose minimal threat because the volcano is so remote. Ideally, the local observatory would understand the combination of hazard and risk associated with surface flows and assign monitoring and detection capabilities appropriately. Several volcano monitoring techniques (for example, Real-Time Seismic Amplitude Measurement [RSAM], amplitude-based locations, and infrasound array processing) can be adapted to also detect, characterize, and track debris flows, lahars, and other surface flows, so instrumentation installed for detecting volcanic unrest and eruptions can have multiple purposes. The utility of instrumentation for the purpose of monitoring unrest and lahars further justifies the importance and utility of a dense network of monitoring stations, even if the volcano remains quiescent.

Scientific Investigations Report↗

USGS2024

Case definitions for wildlife diseases

Welcome to the first manual of “Case Definitions for Wildlife Diseases,” a “living” electronic publication. The plan is to add and update this manual’s case definitions periodically as warranted; thus, this manual will never be completed, and readers should download the latest versions of specific chapters (that is, definitions) when available. Constructive suggestions from readers are welcome and will help guide adjustments as this project progresses. The purpose of this manual is to provide case definitions for selected diseases of importance to wildlife in Canada and the United States. Case definitions provide standard sets of criteria for classifying the degree of certainty of a particular diagnosis and help improve surveillance data quality and comparability. Better data and standardization allow for improved data sharing, which increases geographic and species surveillance coverage and permits more robust analyses. The definitions included in this manual have been developed by veterinary pathologists, epidemiologists, and wildlife biologists primarily from the U.S. Geological Survey National Wildlife Health Center (NWHC) and Canadian Wildlife Health Cooperative (CWHC). Pathologists from each organization reviewed and finalized the definitions. Each case definition has been peer reviewed by two scientific experts before publication. This manual begins with the case definition template. This generic template includes four sections: “Individual, Place, and Time Criteria for Diagnosis and Testing,” “Field Criteria for Diagnosis,” “Laboratory Criteria for Diagnosis,” and “Epidemiological Linkage Criteria for Diagnosis” and can be used to guide development of new case definitions. Information in each section is then combined to provide an overall case classification. Disease diagnoses are classified as “Confirmed,” “Presumptive,” or “Suspected;” and evidence of a pathogen or toxin is classified as “Exposed” or “Present/Detected.” Each subsequent chapter is then a case definition for a specific disease of wildlife, and infectious and non-infectious diseases are included.

Techniques and Methods↗

USGS2010

Levels at gaging stations

Operational procedures at U.S. Geological Survey gaging stations include periodic leveling checks to ensure that gages are accurately set to the established gage datum. Differential leveling techniques are used to determine elevations for reference marks, reference points, all gages, and the water surface. The techniques presented in this manual provide guidance on instruments and methods that ensure gaging-station levels are run to both a high precision and accuracy. Levels are run at gaging stations whenever differences in gage readings are unresolved, stations may have been damaged, or according to a pre-determined frequency. Engineer’s levels, both optical levels and electronic digital levels, are commonly used for gaging-station levels. Collimation tests should be run at least once a week for any week that levels are run, and the absolute value of the collimation error cannot exceed 0.003 foot/100 feet (ft). An acceptable set of gaging-station levels consists of a minimum of two foresights, each from a different instrument height, taken on at least two independent reference marks, all reference points, all gages, and the water surface. The initial instrument height is determined from another independent reference mark, known as the origin, or base reference mark. The absolute value of the closure error of a leveling circuit must be less than or equal to 0.003√n ft, where n is the total number of instrument setups, and may not exceed |0.015| ft regardless of the number of instrument setups. Closure error for a leveling circuit is distributed by instrument setup and adjusted elevations are determined. Side shots in a level circuit are assessed by examining the differences between the adjusted first and second elevations for each objective point in the circuit. The absolute value of these differences must be less than or equal to 0.005 ft. Final elevations for objective points are determined by averaging the valid adjusted first and second elevations. If final elevations indicate that the reference gage is off by |0.015| ft or more, it must be reset.

Techniques and Methods↗

USGS2010

Stage measurement at gaging stations

Stream and reservoir stage are critical parameters in the computation of stream discharge and reservoir volume, respectively. In addition, a record of stream stage is useful in the design of structures that may be affected by stream elevation, as well as for the planning for various uses of flood plains. This report describes equipment and methodology for the observation, sensing, and recording of stage in streams and reservoirs. Although the U.S. Geological Survey (USGS) still uses the traditional, basic stilling-well float system as a predominant gaging station, modern electronic stage sensors and water-level recorders are now commonly used. Bubble gages coupled with nonsubmersible pressure transducers eliminate the need for stilling wells. Submersible pressure transducers have become common in use for the measurement of stage in both rivers and lakes. Furthermore, noncontact methods, such as radar, acoustic, and laser methods of sensing water levels, are being developed and tested, and in the case of radar, are commonly used for the measurement of stage. This report describes commonly used gaging-station structures, as well as the design and operation of gaging stations. Almost all of the equipment and instruments described in this report will meet the accuracy standard set by the USGS Office of Surface Water (OSW) for the measurement of stage for most applications, which is ±0.01 foot (ft) or 0.2 percent of the effective stage. Several telemetry systems are used to transmit stage data from the gaging station to the office, although satellite telemetry has become the standard. These telemetry systems provide near real-time stage data, as well as other information that alerts the hydrographer to extreme or abnormal events, and instrument malfunctions.

Techniques and Methods↗

USGS2010

Discharge measurements at gaging stations

The techniques and standards for making discharge measurements at streamflow gaging stations are described in this publication. The vertical axis rotating-element current meter, principally the Price current meter, has been traditionally used for most measurements of discharge; however, advancements in acoustic technology have led to important developments in the use of acoustic Doppler current profilers, acoustic Doppler velocimeters, and other emerging technologies for the measurement of discharge. These new instruments, based on acoustic Doppler theory, have the advantage of no moving parts, and in the case of the acoustic Doppler current profiler, quickly and easily provide three-dimensional stream-velocity profile data through much of the vertical water column. For much of the discussion of acoustic Doppler current profiler moving-boat methodology, the reader is referred to U.S. Geological Survey Techniques and Methods 3–A22 (Mueller and Wagner, 2009). Personal digital assistants (PDAs), electronic field notebooks, and other personal computers provide fast and efficient data-collection methods that are more error-free than traditional hand methods. The use of portable weirs and flumes, floats, volumetric tanks, indirect methods, and tracers in measuring discharge are briefly described.

Techniques and Methods↗

USGS2024

Methods of analysis—Determination of pesticides in filtered water and suspended sediment using liquid chromatography- and gas chromatography-tandem mass spectrometry

The widespread application of pesticides in agricultural and urban areas leads to their presence in surface waters. Presence of these biologically active chemicals in environmental waters potentially has adverse effects on nontarget organisms. To better understand the environmental fate of these contaminants, a robust method to capture chemicals with wide-ranging physicochemical properties has been developed. The method was developed by the U.S. Geological Survey’s Organic Chemistry Research Laboratory to monitor pesticides, pesticide degradates, and other agrochemicals in environmental surface waters throughout the country. The analysis involves a multiresidue method to determine 183 pesticides and pesticide degradates in filtered water samples and 178 pesticides and pesticide degradates in paired suspended sediment samples. After the filtration of whole water, contaminants are individually measured in the filtered water and the collected suspended sediment. Filtered water is extracted via solid-phase extraction, whereas suspended sediment is extracted using an ultrasonication, solid-liquid extraction. Samples are analyzed by liquid chromatography-tandem mass spectrometry using an electrospray ionization source in positive and negative modes and analyzed by gas chromatography-tandem mass spectrometry using an advanced electron ionization source in positive mode. Instrument parameters were optimized for the highest sensitivity, and at least two transitions (quantifier and qualifier) were monitored for each analyte. Recoveries in test filtered water ( n =9; 183 analytes) from the American River, California, and suspended sediment ( n =9; 178 analytes) samples fortified at 15 nanograms per liter (ng/L) ranged from 70.1 to 121.0 and 71.1 to 117.0 percent in water and suspended sediment filter samples, respectively. Method detection limits of pesticides and pesticide degradates ranged from 0.5 to 10.6 ng/L in water and 0.7 to 11.8 ng/L in suspended sediment filters. Reporting limits were 1.1–21.1 ng/L and 1.5–23.7 ng/L in water and filter samples, respectively. The developed method is applied to surface-water samples for the analysis of pesticides, pesticide degradates, and other agrochemicals.

Techniques and Methods↗

USGS1990

Borehole geophysics applied to ground-water investigations

The purpose of this manual is to provide hydrologists, geologists, and others who have the necessary background in hydrogeology with the basic information needed to apply the most useful borehole-geophysical-logging techniques to the solution of problems in ground-water hydrology. Geophysical logs can provide information on the construction of wells and on the character of the rocks and fluids penetrated by those wells, as well as on changes in the character of these factors over time. The response of well logs is caused by petrophysical factors, by the quality, temperature, and pressure of interstitial fluids, and by ground-water flow. Qualitative and quantitative analysis of analog records and computer analysis of digitized logs are used to derive geohydrologic information. This information can then be extrapolated vertically within a well and laterally to other wells using logs. The physical principles by which the mechanical and electronic components of a logging system measure properties of rocks, fluids, and wells, as well as the principles of measurement, must be understood if geophysical logs are to be interpreted correctly. Plating a logging operation involves selecting the equipment and the logs most likely to provide the needed information. Information on well construction and geohydrology is needed to guide this selection. Quality control of logs is an important responsibility of both the equipment operator and the log analyst and requires both calibration and well-site standardization of equipment. Logging techniques that are widely used in ground-water hydrology or that have significant potential for application to this field include spontaneous potential, resistance, resistivity, gamma, gamma spectrometry, gamma-gamma, neutron, acoustic velocity, acoustic televiewer, caliper, and fluid temperature, conductivity, and flow. The following topics are discussed for each of these techniques: principles and instrumentation, calibration and standardization, volume of investigation, extraneous effects, and interpretation and applications.

Techniques of Water-Resources Investigations↗

USGS1985

Acoustic velocity meter systems

Acoustic velocity meter (AVM) systems operate on the principles that the point-to-point upstream traveltime of an acoustic pulse is longer than the downstream traveltime and that this difference in traveltime can be accurately measured by electronic devices. An AVM system is capable of recording water velocity (and discharge) under a wide range of conditions, but some constraints apply: 1. Accuracy is reduced and performance is degraded if the acoustic path is not a continuous straight line. The path can be bent by reflection if it is too close to a stream boundary or by refraction if it passes through density gradients resulting from variations in either water temperature or salinity. For paths of less than 100 m, a temperature gradient of 0.1' per meter causes signal bending less than 0.6 meter at midchannel, and satisfactory velocity results can be obtained. Reflection from stream boundaries can cause signal cancellation if boundaries are too close to signal path. 2. Signal strength is attenuated by particles or bubbles that absorb, spread, or scatter sound. The concentration of particles or bubbles that can be tolerated is a function of the path length and frequency of the acoustic signal. 3. Changes in streamline orientation can affect system accuracy if the variability is random. 4. Errors relating to signal resolution are much larger for a single threshold detection scheme than for multiple threshold schemes. This report provides methods for computing the effect of various conditions on the accuracy of a record obtained from an AVM. The equipment must be adapted to the site. Field reconnaissance and preinstallation analysis to detect possible problems are critical for proper installation and operation of an AVM system.

Techniques of Water-Resources Investigations↗

USGS2004

Use of submersible pressure transducers in water-resources investigations

Submersible pressure transducers, developed in the early 1960s, have made the collection of water-level and pressure data much more convenient than former methods. Submersible pressure transducers, when combined with electronic data recorders have made it possible to collect continuous or nearly continuous water-level or pressure data from wells, piezometers, soil-moisture tensiometers, and surface water gages. These more frequent measurements have led to an improved understanding of the hydraulic processes in streams, soils, and aquifers. This manual describes the operational theory behind submersible pressure transducers and provides information about their use in hydrologic investigations conducted by the U.S. Geological Survey.

Techniques of Water-Resources Investigations↗