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At least 1,297 records · Page 72Linked to original sources
USGS1966

Mines and prospects, Idaho Springs district, Clear Creek and Gilpin counties, Colorado -- Descriptions and maps

The Idaho Springs mining district forms an important segment of the Front Range mineral belt, a northeast-trending zone of coextensive intrusive rocks and hydrothermal ore deposits of early Tertiary age. This belt, which is about 50 miles long, extends from the region just west of Boulder southwestward across the Front Range. From 1859, when placer gold was discovered in Idaho Springs and lode gold in Central City, through 1959, ores valued at about $ 200 million were shipped from a 50-square-mile area that includes the Idaho Springs and adjacent districts to the north, west, and southwest. The adjacent Central City district, which produced ores valued at more than \$ 100 million, is clearly the most important district in the mineral belt. The Idaho Springs district from 1860 to 1959 produced ores valued at about $65 million, and the districts to the west and southwest produced smaller amounts. Gold has accounted for about 60 percent of the value of the ore, but in some areas silver provides the chief values, and copper, lead, and zinc add value to the ores in most areas. Mining activity in the Idaho Springs and adjacent districts was at its 'heyday' in the late 1800's, it declined sharply after 1914, it was somewhat renewed during the 1930's, and it greatly declined during World War II. In the 1950's uranium prospecting stimulated some mining activity. No uranium was produced, however, and at the close of the decade only one mine--the Bald Eagle--was being worked for its precious- and base-metal ores. In this report, 135 mines and prospects are described. The mines and prospects described are those that were accessible at the time of this study, as well as a few inaccessible properties for which some information was available. Most of the data for the inaccessible or unimportant properties were obtained from Bastin and Hill (1917) and Spurr, Garrey, and Ball (1908). The following list shows, in alphabetical order, the names of about 325 openings of mines and prospects, their coordinate location on the district map (fig. 1), the page of this report on which their description starts, and the number of the illustration, if any, referring to them.

Colorado↗
USGS1972

Radiochemical analyses of surface water from U.S. Geological Survey hydrologic bench-mark stations

The U.S. Geological Survey's program for collecting and analyzing surface-water samples for radiochemical constituents at hydrologic bench-mark stations is described. Analytical methods used during the study are described briefly and data obtained from 55 of the network stations in the United States during the period from 1967 to 1971 are given in tabular form. Concentration values are reported for dissolved uranium, radium, gross alpha and gross beta radioactivity. Values are also given for suspended gross alpha radioactivity in terms of natural uranium. Suspended gross beta radioactivity is expressed both as the equilibrium mixture of strontium-90/yttrium-90 and as cesium-137. Other physical parameters reported which describe the samples include the concentrations of dissolved and suspended solids, the water temperature and stream discharge at the time of the sample collection.

Open-File Report↗
USGS1980

Annotated bibliography of spectrophotometric studies in the system U-Fe-Se-S-O-H, 1967-78

Preparation of this bibliography was originally begun to supply background information on previous ultraviolet and visible spectrophotometric studies on various chemical species thought to be important in the formation of sedimentary uranium deposits; we also thought that preparing the bibliography would help direct experimental efforts to determine the association of iron and uranium with several metastable sulfur species. In compiling these references, however, we found that much work had been done on the chemical species of interest by using types of spectroscopy other than ultraviolet and visible spectrophotometry. The dimensions of the bibliography were therefore broadened to include a wide variety of spectral-measuring techniques to make this report useful to a larger audience.

Open-File Report↗
USGS1983

Reconnaissance geology of the Ghazzalah Quadrangle, sheet 26/41 A, Kingdom of Saudi Arabia

The Ghazzalah quadrangle is located in the northern Precambrian shield of Saudi Arabia between lat 26?30' and 27?00' N. and long 41?00' and 41?30' E. The area is underlain by two lithologically distinct, Precambrian volcanosedimentary units and a wide range of dioritoid and granitoid plutonic intrusive rocks. The only Phanerozoic rocks consist of one outcrop of Tertiary(?) basalt and widespread but thin deposits of Quaternary detritus. The Banana greenstone, the oldest rock in the quadrangle, consists of intermediate volcanic and subvolcanic rocks and minor interbedded marble, which have been metamorphosed to greenschist-facies assemblages. Volcanic rocks mainly range in composition from basalt to andesite, and subvolcanic rocks consist of diorite and diabase. The Banana greenstone is unconformably overlain by silicic volcanic rocks and minor arkosic sandstone and breccia of the Hadn formation. Preservation of delicate volcanic textures suggests that the rocks have been only incipiently metamorphosed. Unpublished rubidium/strontium isotopic data for the Hadn formation suggest an age of 620 to 610 Ma. Intrusive rocks are separable according to their ages relative to the Hadn formation. Those that are unconformably overlain by the Hadn formation consist of hornblende quartz diorite and gabbro, which may be consanguineous with the Banana greenstone, and younger tonalite, biotite-hornblende granodiorite, syenogranite, and monzogranite. Plutons of monzogranite, alkali-feldspar g,ranite, syenbgranite, peralkaline granite, and hypabyssal intrusions of granophyre were probably emplaced during a period coincident with and (or) following Hadn volcanism. Uranium-lead and rubidium/strontium isotopic data for two plutons in the adjacent Al Qasr quadrangle suggest that plutonic activity persisted in the region until about 580 to 570 Ma. Faulting appears to postdate all of the plutonic rocks. The dominant faults belong to a northeast-trending system of right-lateral shears; a subordinant system consists of mainly north- to northwest-trending faults. The peralkaline-granite plutons underlying Jibal Ba'gham and Jibal ar Rumman have the most economic potential. Wadi samples from these areas show an anomalous concentrations of tin, lead, niobium, and yttrium. Localized, intense radiometric anomalies in the Ba'gham intrusive complex are associated with high concentrations )f thorium, uranium, andrare-earth elements.

Open-File Report↗
USGS1986

Chemical quality of ground water in Salt Lake Valley, Utah, 1969-85

During 1979-84, 35 wells completed in the principal aquifer in the Salt Lake Valley, Utah, that had been sampled during 1962-67 were resampled to determine if water quality changes had occurred. The dissolved solids concentration of the water from 13 of the wells has increased by more than 10% since 1962-67. Much of the ground water between the mouth of Bingham Canyon and the Jordan River about 10 mi to the east has been contaminated by seepage from reservoirs and evaporation ponds associated with mining activities. Many domestic and irrigation wells yield water with concentrations of dissolved solids that exceed 2,000 mg/L. A reservoir in the mouth of Bingham Canyon contains acidic waters with a pH of 3 to 4 and concentrations of dissolved solids ranging from 43,000 to 68,000 mg/L. Seepage from evaporation ponds, which are about 4.5 mi east of the reservoir, also is acidic and contains similar concentrations of dissolved solids. East of the reservoir, where a steep hydraulic gradient exists along the mountain front, the velocities of contaminant movement were estimated to range from about 680-1,000 ft/yr. Groundwater underlying part of the community of South Salt Lake near the Jordan River has been contaminated by leachate from uranium-mill tailings. The major effect of the leachate from the tailings of the Vitro Chemical Co. on the shallow unconfined aquifer downgradient from the tailings was the contribution of measurable quantities of dissolved solids, chloride, sulfate, iron, and uranium. The concentration of dissolved solids in uncontaminated water was 1,650 mg/L, whereas downgradient from the tailings area, the concentrations ranged from 2,320-21,000 mg/L. The maximum volume of contaminated water was estimated to be 7,800 acre-ft. The major effect of the leachate from the Vitro tailings on the confined aquifer was the contribution of measurable quantities of dissolved solids, chloride, sulfate, and iron. The concentration of dissolved solids upgradient from the tailings was 330 mg/L, and beneath and downgradient from the tailings the concentrations were 864 and 1,240 mg/L. The minimum volume of contaminated water in the confined aquifer was estimated to be about 12,000 acre-ft. A calibrated, 3-dimensional, ground-water flow model was used to simulate potential changes in the potentiometric surface due to hypothetical ground- water withdrawals from a postulated well field in the vicinity of the Salt Lake International Center. Using a pumping rate of 30 cubic feet per second, it would require about 3,900 years for the saline ground water from beneath the lake to travel the 7 miles to the postulated well field. (Lantz-PTT)

Utah↗
USGS1986

Trace-element contents of postorogenic granites of the eastern Arabian Shield, Kingdom of Saudi Arabia

Trace-element contents for 46 postorogenic granitoids vary by as much as two orders of magnitude; most samples are strongly enriched in incompatible elements (such as the heavy rare earths, yttrium, niobium, and uranium) and depleted in the compatible elements (such as barium, strontium, scandium, europium, and cobalt). These trace-element characteristics are typical of A-type granites found in other areas of the world. In spite of the wide range in trace-element contents, no samples contained economically significant concentrations of a single element. Samples range from peralkaline to strongly peraluminous; most are weakly peraluminous or metaluminous. All three subgroups (peralkaline, metaluminous, and peraluminous) are enriched in uranium and hafnium and are depleted in compatible elements. The peralkaline granites are generally enriched in yttrium and niobium - the strongly peraluminous granites in rubidium and tantalum; both groups are also somewhat enriched in the heavy-rare-earth elements. Several of the peraluminous granites are known to be tin-bearing and, like tin-bearing granites found elsewhere in the world, their chondrite-normalized, rare-earth-element patterns are flat and have large negative europium anomalies. Samples from several plutons have very anomalous ratios for geochemically similar elements such as yttrium and holmium, niobium and tantalum, and zirconium and hafnium. These ratios may reflect differential complexing with a halogen-rich aqueous phase that may be characteristic of plutons that have been subjected to an ore-forming process. A program to test these hypotheses, through study of known mineralized areas and laboratory experiments, should be implemented. The regional trends for the chemical data and geochemical correlations over the large area sampled, suggest that the postorogenic granites were derived from a single protolith that formed by the mixing of oceanic sediments from the west, continental sediments from the east.

Open-File Report↗
USGS1987

Distribution of radionuclide and trace-elements in ground water, grasses, and surficial sediments associated with the alluvial aquifer along the Puerco River, northeastern Arizona; a reconnaissance sampling program

The concentrations of gross alpha radioactivity minus uranium equaled or exceeded 15 picoCuries/L (pCi/L) in five of 14 wells sampled. The concentration of radium-226 plus radium-228 exceeded the primary water quality standard of 5 pCi/L in one well. The concentration of uranium exceeded a recommended limit of 0.035 mg/L in two wells. Perennial grass and sediment samples had low concentrations of radionuclides. The concentration of trace elements in the sediment samples was not unusual. Water quality of surface water in the Puerco River at Chambers varied as a function of the suspended sediment concentration. Concentrations of total gross alpha radiation fluctuated from 12 to 11,200 pCi/L. Concentrations of total gross beta radiation fluctuated from 45 to 4,500 pCi/L. (Author 's abstract)

Open-File Report↗
USGS1987

Interpretation of detailed aerial gamma-ray survey, Jabal Ashirah area, southeastern Arabian Shield, Kingdom of Saudi Arabia

A detailed aerial gamma-ray spectrometric survey of the Jabal Ashirah area in the southeastern Arabian Shield has been analyzed using computer-classification algorithms. The analysis resulted in maps that show radiometric map units and gamma-ray anomalies indicating the presence of possible concentrations of potassium and uranium. The radiometric-unit map was interpreted to 'produce a simplified radiolithic map that was correlated with the mapped geology. The gamma-ray data show uranium anomalies that coincide with a tin-bearing granite, but known gold and nickel mineralization do not have any associated gamma-ray signatures.

Open-File Report↗
USGS1979

Environmental implications of element emissions from phosphate-processing operations in southeastern Idaho

In order to assess the contribution to plants and soils of certain elements emitted by phosphate processing, we sampled sagebrush, grasses, and A- and C-horizon soils along upwind and downwind transects at Pocatello and Soda Springs, Idaho. Analyses for 70 elements in plants showed that, statistically, the concentration of 7 environmentally important elements, cadmium, chromium, fluorine, selenium, uranium, vanadium, and zinc, were related to emissions from phosphate-processing operations. Two additional elements, lithium and nickel, show probable relationships. The literature on the effects of these elements on plant and animal health is briefly surveyed. Relations between element content in plants and distance from the phosphate-processing operations were stronger at Soda Springs than at Pocatello and, in general, stronger in sagebrush than in the grasses. Analyses for 58 elements in soils showed that, statistically, beryllium, fluorine, iron, lead, lithium, potassium, rubidium, thorium, and zinc were related to emissions only at Pocatello and only in the A horizon. Moreover, six additional elements, copper, mercury, nickel, titanium, uranium, and vanadium, probably are similarly related along the same transect. The approximate amounts of elements added to the soils by the emissions are estimated. In C-horizon soils, no statistically significant relations were observed between element concentrations and distance from the processing sites. At Soda Springs, the nonuniformity of soils at the sampling locations may have obscured the relationship between soil-element content and emissions from phosphate processing.

Professional Paper↗
USGS1989

Hydrogeology, ground-water movement, and subsurface storage in the Floridan aquifer system in southern Florida

The Floridan aquifer system of southern Florida is composed chiefly of carbonate rocks that range in age from early Miocene to Paleocene. The top of the aquifer system in southern Florida generally is at depths ranging from 500 to 1,000 feet, and the average thickness is about 3,000 feet. It is divided into three general hydrogeologic units: (1) the Upper Floridan aquifer, (2) the middle confining unit, and (3) the Lower Floridan aquifer. The Upper Floridan aquifer contains brackish ground water, and the Lower Floridan aquifer contains salty ground water that compares chemically to modern seawater. Zones of high permeability are present in the Upper and Lower Floridan aquifers. A thick, cavernous dolostone in the Lower Floridan aquifer, called the Boulder Zone, is one of the most permeable carbonate units in the world (transmissivity of about 2.5 x 107 feet squared per day). Ground-water movement in the Upper Floridan aquifer is generally southward from the area of highest head in central Florida, eastward to the Straits of Florida, and westward to the Gulf of Mexico. Distributions of natural isotopes of carbon and uranium generally confirm hydraulic gradients in the Lower Floridan aquifer. Groundwater movement in the Lower Floridan aquifer is inland from the Straits of Florida. The concentration gradients of the carbon and uranium isotopes indicate that the source of cold saltwater in the Lower Floridan aquifer is seawater that has entered through the karat features on the submarine Miami Terrace near Fort Lauderdale. The relative ages of the saltwater suggest that the rate of inland movement is related in part to rising sea level during the Holocene transgression. Isotope, temperature, and salinity anomalies in waters from the Upper Floridan aquifer of southern Florida suggest upwelling of saltwater from the Lower Floridan aquifer. The results of the study support the hypothesis of circulating relatively modern seawater and cast doubt on the theory that the saltwater in the Floridan aquifer system probably is connate or unflushed seawater from high stands of sea level. The principal use of the Floridan aquifer system in southern Florida is for subsurface storage of liquid waste. The Boulder Zone of the Lower Floridan aquifer is extensively used as a receptacle for injected treated municipal wastewater, oil field brine, and, to a lesser extent, industrial wastewater. Pilot studies indicate a potential for cyclic storage of freshwater in the Upper Floridan aquifer in southern Florida.

Florida↗
USGS1963

Economic geology of the Central City district, Gilpin County, Colorado

The Central City district, in Gilpin County, Colo., is on the east flank of the Front Range, about 30 miles west of Denver. The district is the most important mining camp in the Front Range mineral belt, and has yielded more than $100 million worth of gold, silver, uranium, and base-metal ores since 1859. Gold accounts for about 85 percent of the dollar value of the ore. In recent years mining activity has been slack but from 1950 to 1955 the search for uranium ores stimulated prospecting and development.

Colorado↗
USGS2005

Surface gamma-ray survey of the Barre West quadrangle, Washington and Orange Counties, Vermont

This study was designed to determine the levels of naturally occurring radioactivity in bedrock from surface measurements at outcrops during the course of 1:24,000-scale geologic mapping and to determine which rock types were potential sources of radionuclides. Elevated levels of total alpha particle radiation (gross alpha) occur in a public water system in Montpelier, Vermont. Measured gross alpha levels in the Murray Hill water system (Vermont Dept. of Environmental Conservation, unpub. data, 2005) have exceeded the maximum contaminant level of 15 picocuries per liter (pCi/l) set by the Environmental Protection Agency (EPA) (EPA, 2000). The Murray Hill system began treatment for radium in 1999. Although this treatment was successful, annual monitoring for gross alpha, radium, and uranium continues as required (Jon Kim, written communication, 2005). The water system utilizes a drilled bedrock well located in the Silurian-Devonian Waits River Formation. Kim (2002) summarized radioactivity data for Vermont, and aside from a statewide assessment of radon in public water systems (Manning and Ladue, 1986) and a single flight line from the National Uranium Resource Evaluation (NURE) (Texas Instruments, 1976) (fig. 1), no data are available to identify the potential sources of naturally occurring radioactivity in the local bedrock. Airborne gamma-ray surveys are typically used for large areas (Duval, 2001, 2002), and ground-based surveys are more commonly used for local site assessments. For example, ground-based surveys have been used for fault mapping (Iwata and others, 2001), soil mapping (Roberts and others, 2003), environmental assessments (Stromswold and Arthur, 1996), and mineral exploration (Jubeli and others, 1998). Duval (1980) summarized the methods and applications of gamma- ray spectrometry. In this study, we present the results from a ground-based gamma-ray survey of bedrock outcrops in the 7.5-minute Barre West quadrangle, Vermont. Other related and ongoing studies in the area are addressing potential mineral sources of radionuclides (Satkoski and Walsh, 2004; Satkoski and others, 2005), radionuclides in ground water (Kim and others, 2005), and bedrock geology.

Scientific Investigations Report↗
USGS2007

Occurrence of radium-224, radium-226 and radium-228 in water from the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Hornerstown and Red Bank Sands, southwestern and south-central New Jersey

This investigation is the first regionally focused study of the presence of natural radioactivity in water from the Vincentown and Wenonah-Mount Laurel aquifers, Englishtown aquifer system, and the Hornerstown and Red Bank Sands. Geologic materials composing the Vincentown and Wenonah-Mount Laurel aquifers and the Hornerstown and Red Bank Sands previously have been reported to contain radioactive (uranium-enriched) phosphatic strata, which is common in deposits from some moderate-depth coastal marine environments. The decay of uranium and thorium gives rise to natural radioactivity and numerous radioactive progeny, including isotopes of radium. Naturally occurring radioactive isotopes, especially those of radium, are of concern because radium is a known human carcinogen and ingestion (especially in water used for drinking) can present appreciable health risks. A regional network in southwestern and south-central New Jersey of 39 wells completed in the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Hornerstown and Red Bank Sands was sampled for determination of gross alpha-particle activity; concentrations of radium radionuclides, major ions, and selected trace elements; and physical properties. Concentrations of radium-224, radium-226, and radium-228 were determined for water from 28 of the 39 wells, whereas gross alpha-particle activity was determined for all 39. The alpha spectroscopic technique was used to determine concentrations of radium-224, which ranged from less than 0.5 to 2.7 pCi/L with a median concentration of less than 0.5pCi/L, and of radium-226, which ranged from less than 0.5 to 3.2 pCi/L with a median concentration of less than 0.5 pCi/L. The beta-counting technique was used to determine concentrations of radium-228. The concentration of radium-228 ranged from less than 0.5 to 4.3 pCi/L with a median of less than 0.5. Radium-228, when quantifiable, had the greatest concentration of the three radium radioisotopes in 9 of the 12 samples (75 percent). The concentration of radium-224 exceeded that of radium-226 in five of the six (83 percent) samples when both were quantifiable. The radium concentration distribution differed by aquifer, with the highest Ra-228 concentrations present in the Englishtown aquifer system and the highest Ra-226 concentrations present in the Wenonah-Mount Laurel aquifer. Radium-224 generally contributed a considerable amount of gross alpha-particle activity to water produced from all the sampled aquifers, but was not the dominant radionuclide as it is in water from the Kirkwood-Cohansey aquifer system, nor were concentrations greater than 1 pCi/L of radium-224 widespread. Gross alpha-particle activity was found to exceed the U.S Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 15 pCi/L in one sample (16 pCi/L) from the Vincentown aquifer. A greater part of the gross alpha-particle activity in water from the Wenonah-Mount Laurel aquifer resulted from the decay of Ra-226 than did the gross alpha-particle activity in the other sampled aquifers; this relation is consistent with the concentration distribution of the Ra-226 itself. Concentrations of radium-224 correlate strongly with those of both radium-226 and radium-228 (Spearman correlation coefficients, r, +0.86 and +0.66, respectively). The greatest concentrations of radium-224, radium-226, and radium-228 were present in the most acidic ground water. All radium-224, radium-226, and radium-228 concentrations greater than 2.5 pCi/L were present in ground-water samples with a pH less than 5.0. The presence of combined radium-226 and radium-228 concentrations greater than 5 pCi/L in samples from the Vincentown and Wenonah-Mount Laurel aquifers and the Englishtown aquifer system was not nearly as common as in samples from the Kirkwood-Cohansey aquifer system, likely because of the slightly higher pH of water from these aquifers relative to that of Kirkwood-Cohansey aqu

New Jersey↗
USGS2009

Occurrence and distribution of iron, manganese, and selected trace elements in ground water in the glacial aquifer system of the northern United States

Dissolved trace elements, including iron and manganese, are often an important factor in use of ground water for drinking-water supplies in the glacial aquifer system of the United States. The glacial aquifer system underlies most of New England, extends through the Midwest, and underlies portions of the Pacific Northwest and Alaska. Concentrations of dissolved trace elements in ground water can vary over several orders of magnitude across local well networks as well as across regions of the United States. Characterization of this variability is a step toward a regional screening-level assessment of potential human-health implications. Ground-water sampling, from 1991 through 2003, of the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey determined trace element concentrations in water from 847 wells in the glacial aquifer system. Dissolved iron and manganese concentrations were analyzed in those well samples and in water from an additional 743 NAWQA land-use and major-aquifer survey wells. The samples are from monitoring and water-supply wells. Concentrations of antimony, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, selenium, strontium, thallium, uranium, and zinc vary as much within NAWQA study units (local scale; ranging in size from a few thousand to tens of thousands of square miles) as over the entire glacial aquifer system. Patterns of trace element concentrations in glacial aquifer system ground water were examined by using techniques suitable for a dataset with zero to 80 percent of analytical results reported as below detection. During the period of sampling, the analytical techniques changed, which generally improved the analytical sensitivity. Multiple reporting limits complicated the comparison of detections and concentrations. Regression on Order Statistics was used to model probability distributions and estimate the medians and other quantiles of the trace element concentrations. Strontium and barium were the most frequently detected and usually were present in the highest concentrations. Iron and manganese were the next most commonly detected and next highest in concentrations. Iron concentrations were the most variable with respect to the range of variations (both within local networks and aquifer-wide) and with respect to the disparity between magnitude of concentrations (detections) and the frequency of samples below reporting limits (nondetections). Antimony, beryllium, cadmium, silver, and thallium were detected too infrequently for substantial interpretation of their occurrence or distributions or potential human-health implications. For those elements that were more frequently detected, there are some geographic patterns in their occurrence that primarily reflect climate effects. The highest concentrations of several elements were found in the West-Central glacial framework area (High Plains and northern Plains areas). There are few important patterns for any element in relation to land use, well type, or network type. Shallow land-use (monitor) wells had iron concentrations generally lower than the glacial aquifer system wells overall and much lower than major-aquifer survey wells, which comprise mostly private- and public-supply wells. Unlike those for iron, concentration patterns for manganese were similar among shallow land-use wells and major-aquifer survey wells. An apparent relation between low pH and relatively low concentrations of many elements, except lead, may be more indicative of the relatively low dissolved-solids content in wells in the Northeastern United States that comprise the majority of low pH wells, than of a pH dependent pattern. Iron and manganese have higher concentrations and larger ranges of concentrations especially under more reducing conditions. Dissolved oxygen and well depth were related to iron and manganese concentrations. Redox conditions also affect several trace elements such as arsenic and copper; however, a comparison of redox categories, based in part on iron and manganese concentrations, indicated that the concentrations of many redox-sensitive elements were not significantly different among redox categories. Some of the redox-related patterns were not what would be expected on the basis of solubility constraints. Furthermore, barium is affected by redox conditions in at least one well network even though it is not a redox-sensitive element. Concentrations of barium in portions of the glacial aquifer system are limited by sulfate, which is strongly affected by redox conditions. Few samples had concentrations of any trace element that exceeded drinking-water standards (Maximum Contaminant Levels), for compounds regulated in drinking water or Health-Based Screening Levels for unregulated trace elements. More unregulated trace elements had concentrations greater than benchmarks than regulated trace elements. More samples had manganese concentrations greater its benchmark than any other element in the glacial aquifer system wells. Of the 1,590 wells sampled for manganese, only 556 are for private or public drinking-water supplies, and of those, 9.9 percent (55) exceeded the manganese Lifetime Health Advisory. Concentrations of arsenic, selenium, and uranium less frequently exceeded Maximum Contaminant Levels. There are 29 wells that had 2 element concentrations that exceeded their respective benchmarks. Most concentrations that exceeded a health-based benchmark were from wells in the West-Central area (Iowa, Minnesota, North and South Dakota, Nebraska, and Kansas); however, there is little geographical pattern to the wells with element concentrations of concern.

Scientific Investigations Report↗
USGS2010

Arsenic-related water quality with depth and water quality of well-head samples from production wells, Oklahoma, 2008

The U.S. Geological Survey well profiler was used to describe arsenic-related water quality with well depth and identify zones yielding water with high arsenic concentrations in two production wells in central and western Oklahoma that yield water from the Permian-aged Garber-Wellington and Rush Springs aquifers, respectively. In addition, well-head samples were collected from 12 production wells yielding water with historically large concentrations of arsenic (greater than 10 micrograms per liter) from the Garber-Wellington aquifer, Rush Springs aquifer, and two minor aquifers: the Arbuckle-Timbered Hills aquifer in southern Oklahoma and a Permian-aged undefined aquifer in north-central Oklahoma. Three depth-dependent samples from a production well in the Rush Springs aquifer had similar water-quality characteristics to the well-head sample and did not show any substantial changes with depth. However, slightly larger arsenic concentrations in the two deepest depth-dependent samples indicate the zones yielding noncompliant arsenic concentrations are below the shallowest sampled depth. Five depth-dependent samples from a production well in the Garber-Wellington aquifer showed increases in arsenic concentrations with depth. Well-bore travel-time information and water-quality data from depth-dependent and well-head samples showed that most arsenic contaminated water (about 63 percent) was entering the borehole from perforations adjacent to or below the shroud that overlaid the pump. Arsenic concentrations ranged from 10.4 to 124 micrograms per liter in 11 of the 12 production wells sampled at the well head, exceeding the maximum contaminant level of 10 micrograms per liter for drinking water. pH values of the 12 well-head samples ranged from 6.9 to 9. Seven production wells in the Garber-Wellington aquifer had the largest arsenic concentrations ranging from 18.5 to 124 micrograms per liter. Large arsenic concentrations (10.4-18.5) and near neutral to slightly alkaline pH values (6.9-7.4) were detected in samples from one well in the Garber-Wellington aquifer, three production wells in the Rush Springs aquifer, and one well in an undefined Permian-aged aquifer. All well-head samples were oxic and arsenate was the only species of arsenic in water from 10 of the 12 production wells sampled. Arsenite was measured above the laboratory reporting level in water from a production well in the Garber-Wellington aquifer and was the only arsenic species measured in water from the Arbuckle-Timbered Hills aquifer. Fluoride and uranium were the only trace elements, other than arsenic, that exceeded the maximum contaminant level for drinking water in well-head samples collected for the study. Uranium concentrations in four production wells in the Garber-Wellington aquifer ranged from 30.2 to 99 micrograms per liter exceeding the maximum contaminant level of 30 micrograms per liter for drinking water. Water from these four wells also had the largest arsenic concentrations measured in the study ranging from 30 to 124 micrograms

Scientific Investigations Report↗
USGS2018

Quartz-pebble-conglomerate gold deposits

Quartz-pebble-conglomerate gold deposits represent the largest repository of gold on Earth, largely due to the deposits of the Witwatersrand Basin, which account for nearly 40 percent of the total gold produced throughout Earth’s history. This deposit type has had a controversial history in regards to genetic models. However, most researchers conclude that they are paleoplacer deposits that have been modified by metamorphism and hydrothermal fluid flow subsequent to initial sedimentation. The deposits are found exclusively within fault-bounded depositional basins. The periphery of these basins commonly consists of granite-greenstone terranes, classic hosts for lode gold that source the detrital material infilling the basin. The gold reefs are typically located along unconformities or, less commonly, at the top of sedimentary beds. Large quartz pebbles and heavy-mineral concentrates are found associated with the gold. Deposits that formed prior to the Great Oxidation Event (circa 2.4 giga-annum [Ga]) contain pyrite, whereas younger deposits contain iron oxides. Uranium minerals and hydrocarbons are also notable features of some deposits. Much of the gold in these types of deposits forms crystalline features that are the product of local remobilization. However, some gold grains preserve textures that are undoubtedly of detrital origin. Other heavy minerals, such as pyrite, contain growth banding that is truncated along broken margins, which indicates that they were transported into place as opposed to forming by in situ growth in a hydrothermal setting. The ore tailings associated with these deposits commonly contain uranium-rich minerals and sulfides. Oxidation of the sulfides releases sulfuric acid and mobilizes various metals into the environment. The neutralizing potential of the tailings is minimal, since carbonate minerals are rare. The continuity of the tabular ore bodies, such as those of the Witwatersrand Basin, has allowed these mines to be the deepest in the world. The extreme depths create engineering complications and safety issues for the miners, such as rock bursts as a result of pressure release. The richness of these deposits makes them a desirable exploration target. However, the likelihood of future discoveries is minimal. Small deposits found in the United States include those found at Nemo in the Black Hills of South Dakota and Deep Lake in the Sierra Madre of Wyoming.

Scientific Investigations Report↗
USGS2013

Effects of surface applications of biosolids on groundwater quality and trace-element concentrations in crops near Deer Trail, Colorado, 2004-2010

The U.S. Geological Survey (USGS), in cooperation with Metro Wastewater Reclamation District (Metro District), studied biosolids composition and the effects of biosolids applications on groundwater quality and trace-element concentrations in crops of the Metro District properties near Deer Trail, Colorado, during 2004 through 2010. Priority parameters for each monitoring component included the nine trace elements regulated by Colorado for biosolids (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc); other constituents also were analyzed. All concentrations for the priority parameters in monthly biosolids samples were less than Colorado regulatory limits, and the concentrations were relatively consistent. Biosolids likely were the largest source of nitrogen and phosphorus on the Metro District properties. Plutonium isotopes were not detected in the biosolids, but many organic wastewater compounds (organic wastewater compounds: wastewater indicators, pharmaceuticals, and hormones) were detected in substantial concentrations relative to minimum reporting levels and various surface-water concentrations. Bismuth, copper, mercury, nitrogen, phosphorus, silver, biogenic sterols, detergent degradates, disinfectants, fire retardants, fragrances, pharmaceuticals, and plasticizers would be the most likely biosolids signature to indicate the presence of Metro District biosolids in soil or streambed sediment from the study area. Antimony, cadmium, cobalt, copper, molybdenum, nickel, nitrogen, phosphorus, selenium, tungsten, vanadium, zinc, detergent degradates, disinfectants, fire retardants, fragrances, pharmaceuticals or their degradates, and plasticizers would be the most likely biosolids signature for groundwater and surface water in the study area. More biosolids-signature components detected and larger concentration differences from untreated materials, baseline, and blank samples indicate more evidence of biosolids presence or effects. Although the inorganic constituent concentrations were relatively large in samples from one monitoring well, the concentrations of organic wastewater compounds in groundwater samples were not correspondingly large. Concentrations of organic wastewater compounds in the groundwater samples from all five monitoring wells were less than the minimum reporting levels with only a few detections. Some of the organic wastewater compounds detected could have anthropogenic sources that are not biosolids. Concentrations of priority parameters in groundwater varied spatially and temporally but generally were less than Colorado regulatory limits. Concentrations of dissolved nitrate, arsenic, and selenium, in addition to chloride, sulfate, total dissolved solids, boron, iron, manganese, and uranium, in samples from some wells exceeded the Colorado standards. Concentrations of dissolved nitrate (three wells), molybdenum (one well), selenium (two wells), and uranium (one well) in shallow groundwater had significant (alpha = 0.05) upward trends in some parts of the study area. The biosolids-signature results indicate that the aquifers intercepted by the five routinely sampled wells likely have received some recharge through treated (biosolids-applied) fields or biosolids-affected ponds. Adverse effects from this biosolids-related recharge range from few (if any) at one well to large and significantly (alpha = 0.05) increasing nitrate concentrations at another well. A statistical evaluation of five paired wheat-grain samples from treated (biosolids-applied) fields and untreated (control) fields did not indicate any evidence that biosolids applications significantly (alpha = 0.05 or 0.10) increased concentration of any of these constituents in wheat grain. The wheat-grain concentrations from this study were similar to those from other studies for fields in North America where no biosolids were applied. The data for the limited crop samples indicate that biosolids applications are not increasing the concentrations of arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, sulfur, and zinc in mature wheat grain from the study area.

Colorado↗
USGS2014

Assessment of ethylene dibromide, dibromochloropropane, other volatile organic compounds, radium isotopes, radon, and inorganic compounds in groundwater and spring water from the Crouch Branch and McQueen Branch aquifers near McBee, South Carolina, 2010-2012

Public-supply wells near the rural town of McBee, in southwestern Chesterfield County, South Carolina, have provided potable water to more than 35,000 residents throughout Chesterfield County since the early 1990s. Groundwater samples collected between 2002 and 2008 in the McBee area by South Carolina Department of Health and Environmental Control (DHEC) officials indicated that groundwater from two public-supply wells was characterized by the anthropogenic compounds ethylene dibromide (EDB) and dibromochloropropane (DBCP) at concentrations that exceeded their respective maximum contaminant levels (MCLs) established by the U.S. Environmental Protection Agency’s (EPA) National Primary Drinking Water Regulations (NPDWR). Groundwater samples from all public-supply wells in the McBee area were characterized by the naturally occurring isotopes of radium-226 and radium-228 at concentrations that approached, and in one well exceeded, the MCL for the combined isotopes. The local water utility installed granulated activated carbon filtration units at the two EDB- and DBCP-contaminated wells and has, since 2011, shut down these two wells. Groundwater pumped by the remaining public-supply wells is currently (2014) centrally treated at a water-filtration plant. To assess the occurrence, distribution, and potential sources of the anthropogenic and naturally occurring compounds detected in groundwater in the McBee area, samples of groundwater and spring water were collected from public-supply, domestic-supply, agricultural-supply, and monitoring wells and springs, respectively, between 2010 and 2012 by the U.S. Geological Survey. The water samples were analyzed for concentrations of EDB, DBCP, other volatile organic compounds (VOCs), radium-226 and radium-228, radon, and inorganic compounds. All wells sampled were screened in the shallow Crouch Branch aquifer, the deeper McQueen Branch aquifer, or, for most public-supply wells, both aquifers. In areas where no wells existed or wells could not be installed, passive samplers that adsorb EDB, DBCP, and various VOCs, were installed in the shallow subsurface. A representative groundwater flow pathway to each public supply well and selected other wells was determined by using a calibrated three-dimensional groundwater-flow model of the Atlantic Coastal Plain in Chesterfield County and particle-tracking analysis. The aerial extent of the groundwater flow pathway to public-supply wells was mapped by using chlorofluorocarbon-concentration based, apparent-age dates of the groundwater. The water-quality data collected between 2010 and 2012, in conjunction with groundwater flow pathways and historical aerial photographs of land uses near McBee, indicate an area where EDB-, DBCP-, 1,2-dichloropropane-, 1,3-dichloropropane-, and carbon disulfide-contaminated groundwater exists in the Crouch Branch aquifer in the Cedar Creek Basin and north of McBee and is most likely related to the past use of these compounds between the early 1900s and the 1980s as soil fumigants in predominately agricultural areas north of McBee. The highest EDB concentration detected (18.6 micrograms per liter) during the 3-year study was in a groundwater sample from an agricultural-supply well located north of McBee. Other VOCs, such as dichloromethane and 1,1,2-trichloroethane, also were detected in groundwater samples from this EDB-contaminated agricultural-supply well but are from unknown source(s). The fact that the agricultural area north of McBee is located in a recharge area for the Crouch Branch aquifer most likely facilitated the groundwater contamination in this area. DBCP-contaminated groundwater detected in three public-supply wells south of McBee in the deeper McQueen Branch aquifer appears to be related to past soil fumigation practices that used DBCP in agricultural areas located south of McBee. One of the three DBCP-contaminated public-supply wells also contained EDB, most likely present in groundwater due to the release of leaded gasolines that contained EDB as a fuel additive between the 1940s and 1970s. A gasoline-source of EDB, rather than a soil-fumigation source, is supported by the co-detection in groundwater from the well of 1,2-dichloroethane, a lead scavenger compound also added to leaded gasoline. Groundwater pumped from two public-supply wells located within and to the east of the McBee town limits and one domestic-supply well east of McBee was characterized by the detection of 1,1-dichloroethane, trichloroethylene, 1,1-dichloroethylene, and perchloroethylene. Groundwater flow pathways determined for these wells indicate that the potential source(s) of these compounds detected in one public-supply well and the domestic-supply well may be located within the McBee town limits, and that the potential source(s) of these compounds detected in the public-supply well to the east of McBee may be located in an area north of McBee formerly used for agriculture, but used for industry since at least the 1970s. Radium isotopes (defined in this study as the sum of radium-226 and radium-228 concentrations) and radon were detected in all wells sampled in the McBee area between 2010 and 2012. Wells characterized by radium isotope concentrations in groundwater that exceeded the MCL of 5.0 picocuries per liter were also characterized by specific conductance values greater than 30 microsiemens per centimeter and clustered north of McBee in a predominately agricultural area, and in agricultural and urban areas located within and east of McBee. The elevated specific conductance values measured in groundwater from these wells most likely are due to recharge by water mineralized by fertilizer application in agricultural areas, or due to the recharge by water mineralized by septic-tank drain-field effluent near urban areas. Radon was detected in groundwater from all wells sampled, and radon concentrations in groundwater from three monitoring wells exceeded the proposed MCL of 300 picocuries per liter. Concentrations of uranium in groundwater in the McBee area increased with increased groundwater-sample depth, most likely due to the proximity of the sample-collection location to basement rock that contains uranium-bearing minerals.

South Carolina↗