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At least 1,297 records · Page 72Linked to original sources

Crustal controls on magmatic-hydrothermal systems: A geophysical comparison of White River, Washington, with Goldfield, Nevada

The White River altered area, Washington, and the Goldfield mining district, Nevada, are nearly contemporaneous Tertiary (ca. 20 Ma) calc-alkaline igneous centers with large exposures of shallow (<1 km depth) magmatic-hydrothermal, acid-sulfate alteration. Goldfield is the largest known high-sulfidation gold deposit in North America. At White River, silica is the only commodity exploited to date, but, based on its similarities with Goldfield, White River may have potential for concealed precious and/or base metal deposits at shallow depth. Both areas are products of the ancestral Cascade arc. Goldfield lies within the Great Basin physiographic province in an area of middle Miocene and younger Basin and Range and Walker Lane faulting, whereas White River is largely unaffected by young faults. However, west-northwest–striking magnetic anomalies at White River do correspond with mapped faults synchronous with magmatism, and other linear anomalies may reflect contemporaneous concealed faults. The White River altered area lies immediately south of the west-northwest–striking White River fault zone and north of a postulated fault with similar orientation. Structural data from the White River altered area indicate that alteration developed synchronously with an anomalous stress field conducive to left-lateral, strike-slip displacement on west-northwest–striking faults. Thus, the White River alteration may have developed in a transient transtensional region between the two strike-slip faults, analogous to models proposed for Goldfield and other mineral deposits in transverse deformational zones. Gravity and magnetic anomalies provide evidence for a pluton beneath the White River altered area that may have provided heat and fluids to overlying volcanic rocks. East– to east-northeast–striking extensional faults and/or fracture zones in the step-over region, also expressed in magnetic anomalies, may have tapped this intrusion and provided vertical and lateral transport of fluids to now silicified areas. By analogy to Goldfield, geophysical anomalies at the White River altered area may serve as proxies for geologic mapping in identifying faults, fractures, and intrusions relevant to hydrothermal alteration and ore formation in areas of poor exposure.

Nevada, Washington↗

Geologic and hydrogeologic characteristics of the White River Formation, Lance Formation, and Fox Hills Sandstone, northern greater Denver Basin, southeastern Laramie County, Wyoming

In cooperation with the Wyoming State Engineer’s Office, the U.S. Geological Survey studied the geologic and hydrogeologic characteristics of Cenozoic and Upper Cretaceous strata at a location in southeastern Laramie County within the Wyoming part of the Cheyenne Basin, the northern subbasin of the greater Denver Basin. The study aimed to improve understanding of the aquifers/aquifer systems in these strata, motivated in part by declining groundwater levels and interest in exploring future groundwater supplies. Based on detailed geologic characterization using information obtained by drilling and coring a 960-foot-(ft) deep exploratory borehole, and comparisons with previously published descriptions, identified Cenozoic lithostratigraphic units included 40 ft of Quaternary older alluvial fan deposits consisting of an unconsolidated mixture of sand and gravel with lesser quantities of silt and clay in varying proportions and the underlying 407.3-ft-thick White River Formation of late Eocene-Oligocene age consisting largely of mudrocks with sparse thin beds of sandstone, muddy gravel, and conglomeratic mudrocks. Identified Upper Cretaceous lithostratigraphic units included the 351.6-ft-thick Lance Formation, consisting of terrestrial sedimentary rocks including mudrocks (muddy shale and silty and sandy shale, siltstone, claystone, and mudstone) interbedded with much smaller quantities of very fine- to medium-grained muddy and silty sandstone and coal; the 79.6-ft-thick Fox Hills Sandstone, consisting of a transitional marine sequence of muddy or silty sandstone present in five individual beds; and 86.7 ft of the upper transition member of the Pierre Shale, consisting largely of marine sedimentary rocks such as muddy shale. Beds of the upper and lower Fox Hills Sandstone were separated by tongues of the Lance Formation and upper transition member of the Pierre Shale, respectively. The White River hydrogeologic unit, consisting of the entire White River Formation or Group at the study site, did not contain any substantial secondary permeability features in the mudrocks that composed almost all the unit. A monitoring well (BR–1) was completed in the White River aquifer with the well screen open to the only coarse-grained unit (muddy sandstone) that had sufficient thickness and permeability to be considered as an aquifer. Sampling of the well for a broad suite of constituents indicated groundwater generally was of excellent quality except dissolved arsenic was detected at a concentration greater than the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level, and dissolved sodium was measured at a concentration greater than several EPA Drinking Water Advisory Levels (DWAs) for the constituent. Well development, well purging for groundwater sampling, and calculated aquifer properties indicated the sandstone aquifer screened by monitoring well BR–1 was not very productive. Analysis of the well water-level responses in BR–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response with wellbore-storage effects. Hydraulic properties estimated based on these responses yielded values of hydraulic conductivity ( K , 0.057 foot per day [ft/d]), specific storage ( Ss , 1.6×10 −6 per foot [ft −1 ]) and porosity ( n , 0.43). Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated an upward trend (+1.13 foot per year [ft/yr]) during the period analyzed, September 5, 2014, to September 30, 2017. Lithologic characteristics of the Lance hydrogeologic unit, consisting of the entire Lance Formation at the study site, indicated a potential aquifer in a “sandy” interval in the upper part of the unit. Most of the Lance hydrogeologic unit below the “sandy” interval consisted of various low-permeability lithologies unlikely to yield substantial quantities of water. This lower part of the hydrogeologic unit likely functions as a confining unit separating the underlying Lance-Fox Hills aquifer. A geologic cross section constructed for this study indicated fine-grained sediments composed most of the Lance Formation/hydrogeologic unit not only at the study location, but also throughout southern Laramie County along the line of section and throughout the Wyoming and Colorado parts of the Cheyenne Basin. A monitoring well (LN–1) completed in a sandstone bed in the “sandy” interval of the Lance hydrogeologic unit produced a mean of about 23 gallons per minute (gal/min) during well development, indicating sandstone beds can form moderately productive confined subaquifers in this part of the hydrogeologic unit. Analysis of the well water-level responses in well LN–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties estimated based on these responses yielded values for a lower bounding K of 0.60 ft/d, Ss of 1.6×10 −6 ft −1 , and n of 0.38. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−0.86 ft/yr) during the period analyzed (November 8, 2014, to September 30, 2017). Analyses for a broad suite of constituents in samples from well LN–1 indicated groundwater quality generally was excellent, although dissolved sodium was measured at a concentration greater than two EPA DWA levels for the constituent. Because of the absence of any overlying or intertonguing sandstone beds belonging to the lower/basal part of the Lance Formation, the Lance-Fox Hills aquifer at the study site consisted only of the five sandstone beds of the Fox Hills Sandstone. The cross section constructed for this study illustrated how the Fox Hills Sandstone, and thus, most of the Lance-Fox Hills aquifer, consists of a series of sandstone bodies that overlap (shingle) upward to the east across southern Laramie County. These bodies collectively form a fairly continuous body of sandstone, thus potentially forming an areally extensive aquifer across southern Laramie County, and by extension, throughout most of the formation’s extent in the Wyoming part of the Cheyenne Basin, as is the case in the Colorado part of the basin. A monitoring well (FH–1) completed in part of the thickest sandstone bed of the Lance-Fox Hills aquifer was moderately to highly productive and easily produced 25 to 30 gal/min after development. Substantially larger water production rates likely could be obtained by penetrating the full thickness of this bed and by completing a well open to the other overlying and underlying sandstone beds of the aquifer. Analysis of the water-level responses in well FH–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties computed based on these responses yielded values for a lower bounding estimate for K of 0.26 ft/d, for Ss of 1.0×10 −6 ft −1 , and for n of 0.41. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−1.74 ft/yr) during the period analyzed, December 19, 2014, to September 30, 2017. Sampling of monitoring well FH–1 and two production wells completed in the Fox Hills Sandstone in other parts of Laramie County indicated groundwater quality generally is excellent, although pH exceeded a recommended EPA aesthetic drinking-water standard (Secondary Maximum Contaminant Level) in two of three sampled wells, total dissolved solids concentrations exceeded the Secondary Maximum Contaminant Level in one of the two sampled production wells, and dissolved sodium was measured in all three sampled wells at a concentration greater than two EPA DWA levels for the constituent. The Wyoming Class II agricultural (irrigation) sodium adsorption ratio standard of 8 was exceeded in all three sampled wells, indicating these waters are not suitable for irrigation use. Computed vertical hydraulic gradients indicated a strong potential for downward flow throughout the groundwater system at the study site, including from the low-yielding aquifer in the upper White River Formation/hydrogeologic unit (monitoring well BR–1) to the sandstone subaquifer in the Lance Formation/hydrogeologic unit (monitoring well LN–1), and from the Lance subaquifer (monitoring well LN–1) to the sandstone bed/aquifer that composes much of the Lance-Fox Hills aquifer thickness at the study site (monitoring well FH–1). However, large hydraulic-head differences between wells indicated high resistance to vertical flow attributable to the low vertical hydraulic conductivity of intervening strata, which consisted almost entirely of low-permeability mudrocks. The confined nature of the sandstone aquifers monitored by the various wells coupled with dissimilarities between groundwater-level fluctuations and trends in groundwater levels indicated downward flow through the intervening strata (primarily mudrocks in the various lithostratigraphic/hydrogeologic units) between the examined sets of wells likely was small.

Wyoming↗

Allostratigraphy of the U.S. middle Atlantic continental margin; characteristics, distribution, and depositional history of principal unconformity-bounded upper Cretaceous and Cenozoic sedimentary units

Publication of Volumes 93 and 95 ('The New Jersey Transect') of the Deep Sea Drilling Project's Initial Reports completed a major phase of geological and geophysical research along the middle segment of the U. S. Atlantic continental margin. Relying heavily on data from these and related published records, we have integrated outcrop, borehole, and seismic-reflection data from this large area (500,000 km^2 ) to define the regional allostratigraphic framework for Upper Cretaceous and Cenozoic sedimentary rocks. The framework consists of 12 alloformations, which record the Late Cretaceous and Cenozoic depositional history of the contiguous Baltimore Canyon trough (including its onshore margin) and Hatteras basin (northern part). We propose stratotype sections for each alloformation and present a regional allostratigraphic reference section, which crosses these basins from the inner edge of the coastal plain to the inner edge of the abyssal plain. Selected supplementary reference sections on the coastal plain allow observation of the alloformations and their bounding unconformities in outcrop. Our analyses show that sediment supply and its initial dispersal on the middle segment of the U. S. Atlantic margin have been governed, in large part, by hinterland tectonism and subsequently have been modified by paleoclimate, sea-level changes, and oceanic current systems. Notable events in the Late Cretaceous to Holocene sedimentary evolution of this margin include (1) development of continental-rise depocenters in the northern part of the Hatteras basin during the Late Cretaceous; (2) the appear ance of a dual shelf-edge system, a marked decline in siliciclastic sediment accumulation rates, and widespread acceleration of carbonate production during high sea levels of the Paleogene; (3) rapid deposition and progradation of thick terrigenous delta complexes and development of abyssal depocenters during the middle Miocene to Quaternary interval; and (4) deep incision of the shelf edge by submarine canyons, especially during the Pleistocene. Massive downslope gravity flows have dominated both the depositional and erosional history of the middle segment of the U. S. Atlantic Continental Slope and Rise during most of the last 84 million years. The importance of periodic widespread erosion is recorded by well-documented unconformities, many of which can be traced from coastal-plain outcrops to coreholes on the continental slope and lower continental rise. These unconformities form the boundaries of the 12 allostratigraphic units we formally propose herein. Seven of the unconformities correlate with supercycle boundaries (sequence boundaries) that characterize the Exxon sequence-stratigraphy model.

Professional Paper↗

Detecting avalanche path ground cover and vegetation change across multiple scales through time using remote sensing tools

Large-magnitude avalanches often alter vegetation composition, avalanche path dimensions, and subsequent avalanche return periods. Understanding temporal changes in individual avalanche path trimlines, runout zones, and geomorphic characteristics helps forecasters, planners, and engineers estimate potential avalanche destructive size and impact on infrastructure or settlements in the runout zone. Understanding these changes on a large scale also provides information on post-cycle avalanche distribution. Here, we use remote sensing platforms and change detection techniques to examine vegetation change in avalanche paths in Montana and Colorado. In northwest Montana, we implemented a novel approach using lidar, aerial imagery, and a random forest model to classify imagery-observed vegetation within avalanche paths. We calculated spatially explicit avalanche return periods using a physically based spatial interpolation method and characterized the vegetation within those return period zones. In Colorado, we investigated changes in avalanche path vegetation characteristics prior to and after a widespread large-magnitude avalanche cycle. The highest frequency of avalanche return periods was broadly characterized by grassland and shrubland, but topography greatly influences vegetation classes and return periods. Furthermore, statistically significant differences in lidar-derived vegetation canopy height exist between categorical return periods. We used optical sensors from satellite imagery to analyze changes in Normalized Difference Vegetation Index (NDVI) to calculate ground cover change over time. NDVI, a measure of near-infrared and red bands within the imagery, allowed us to distinguish between green vegetation (e.g., trees and shrubs) and non-vegetated ground cover (e.g., dead and downed trees, rocks, and dirt) within avalanche paths. For this study, we calculated changes in NDVI values by comparing imagery from 2018 to imagery from 2019 after a widespread large magnitude avalanche cycle occurred in March 2019 in Colorado, United States. We applied a filtering process to reduce error, classified NDVI change based on the value distribution, and then calculated area change of all areas within each avalanche path. We completed this process for 1633 avalanche paths throughout Colorado. We found that using NDVI difference values pre- and post-avalanche cycle allowed us to identify ground cover change in avalanche paths throughout Colorado. These changes span from a slight expansion of existing avalanche paths to substantial landscape disturbance. For example, a size D5 avalanche caused severe ground cover change in 18% of one single path near Aspen, Colorado. This suggests that large magnitude avalanches can redefine avalanche path dimensions and could impact subsequent avalanche size and frequency. Using NDVI from satellite imagery is a simple way to detect ground cover changes in avalanche paths on a large scale or in remote areas. In general, remote sensing products to detect and examine vegetation and ground cover change in avalanche paths can help inform avalanche distribution and benefit planning efforts.

Montana↗

Thermophysical and compositional properties of paleobedforms on Mars

Bedforms on Earth and Mars are often preserved in the rock record in the form of sedimentary rock with distinct cross-bedding. On rare occasions, the full-surface geometry of a bedform can be preserved through burial and lithification. These features, known as paleobedforms, are found in a variety of geographic locations on Mars. Evidence in the morphology of paleobedforms, such as the retention of impact craters and steep erosional scarps, suggests that these features are well-lithified and capable of withstanding prolonged weathering and erosion. Here, we present results from thermophysical and compositional analyses on a subset of the best preserved paleobedform candidate fields on Mars. Thermophysical modeling elucidates the changes these bedforms underwent from their unconsolidated, particulate nature to their currently observed properties. Certain paleobedforms have elevated thermal inertias (e.g., ∼300–500 J·m −2 ·s −1/2 ·K −1 ) when compared with modern bedforms (∼250 J·m −2 ·s −1/2 ·K −1 ), and modeling indicates that they have cement volumes of 0.8%–1.5% even as high as 30%. However, most paleobedform candidates have unexpectedly low thermal inertia when compared with modern dunes. Additionally, compositional analyses reveal a range of spectral characteristics within paleobedforms (e.g., primary and secondary alteration products). These features add to the already existing class of Martian surfaces in which thermal inertia does not seem to correspond to erodibility, cohesion, or mechanical strength. Studying paleobedforms with both raised and nonraised thermal inertia has provided new insights into lithification on Mars and constrained the environmental conditions leading to the formation of these enigmatic features.

Journal of Geophysical Research - Planets↗

Assessment of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

Operation of a coal-tar distillation and wood-preserving facility in St. Louis Park, Minnesota, during 1918-72 contaminated ground water with coal-tar derivatives and inorganic chemicals. Coal-tar derivatives entered the groundwater system through three major paths: (1) Spills and drippings that percolated to the water table, (2) surface runoff and plant process water that was discharged to wetlands south of the former plant site, and (3) movement of coal tar directly into bedrock aquifers through a multiaquifer well on the site. In the drift, Platteville, and St. Peter aquifers, ground water flows laterally from west to east and vertically downward. Near the former plant site, creosote-like organic fluids have migrated vertically downward through the drift and are being partially dissolved by ground water. Ground water has preferentially mobilized low-molecular-weight compounds such as phenolic compounds, alkyl-benzenes, and naphthalene, although polynuclear aromatic hydrocarbons as heavy as benzo(a)pyrene have been mobilized at low concentrations. Sorption of high-molecular-weight compounds has retarded their migration down the hydraulic gradient compared to low-molecular-weight compounds in the plume. Some simple phenolic compounds are being degraded to methane and carbon dioxide by bacteria under anaerobic conditions in the drift-PlattevilleSt. Peter aquifer system. Other low-molecular-weight aromatic compounds are apparently being degraded by aerobic bacteria at the periphery of the plume where oxygen is available. Intermediate degradation products such as volatile fatty acids are likely present, but complete conversion of the organic contaminants to innocuous inorganic substances has not been demonstrated. Near and south of 36th and Wooddale Avenues, contaminants enter the St. Peter aquifer where the Glenwood confining unit has been eroded in a buried bedrock valley. Contaminants previously entered the Prairie du Chien-Jordan aquifer through at least one multiaquif er well (W38). Other sources of contaminants and the low concentrations of contaminants hamper delineation of the maximum areal extent of contaminants that are resistant to biologic degradation. These biorefractory compounds will probably continue to migrate down the hydraulic gradients in the drift and Platteville and St. Peter aquifers. Of particular concern with respect to the health risk to humans are the polynuclear aromatic hydrocarbons, which are a major constituent of coal tar and are found in municipal wells near the site that are completed in the Prairie du Chien-Jordan aquifer. The Prairie du Chien-Jordan aquifer lies 250 to 500 feet below land surface and is relatively well protected from nearsurface sources of contamination by overlying rocks. However, the aquifer has been contaminated since at least 1932 because coal-tar derivatives have entered the aquifer through multiaquifer wells. The most significant single source of contamination in the aquifer is a well drilled on the site in 1917 (well W23) that has contained liquid coal-tar since at least 1958. The introduction, dissolution, and movement of this coal-tar in ground water has contaminated nearby municipal wells. The composition of the tar in well W23, and the ratio of concentrations of individual compounds in water from well W23 to those in municipal well SLP15, are consistent with known hydrologic, chemical, and biologic processes, and the conclusion that contaminants in well SLP15 are due primarily to contaminants introduced at well W23. Most of the major polynuclear aromatic hydrocarbons in the tar, although slightly soluble in water and strongly sorbed by aquifer materials, have moved greater distances at higher concentrations than have the lower-molecular-weight, more soluble compounds such as phenolic compounds and naphthalene. The latter are apparently being degraded by bacteria. The direction and rate of contaminant movement within the Prairie du Chien-Jordan aquifer changes with time because the ground-water-flow system continually adjusts to hydraulic stresses caused by ground-water withdrawals and flow through multiaquifer wells. Contaminants can move rapidly through the Prairie du Chien-Jordan because the upper part of the aquifer is a carbonate rock having fracture and solution-channel permeability, low effective porosity, and relatively small surface area for sorption. Consequently, the concentration and composition of contaminants in water pumped from individual industrial and municipal wells completed in the aquifer fluctuate with time. Although contaminants have been in the aquifer for at least 50 years and their spatial distribution is complex, concentrations remain highest near their points of introduction through multiaquifer wells near and on the site of the former plant. Contaminants reached the Ironton-Galesville aquifer through at least two deep multiaquifer wells (W23 and W38), but the extent of contamination in this aquifer, and in the underlying Mount Simon-Hinckley aquifer, is not known.

Minnesota↗

Characterization and origin of natural gases of the Anadarko Basin

Natural-gas production in the Anadarko basin is from three geographically separated areas that can be differentiated by age of reservoir and by inferred nature of thermal origin of the gases. In the central basin, nonassociated gases are produced mainly from Upper Mississippian and Pennsylvanian sandstones. Gases become isotopically heavier (&delta; 13 C 1 values range from -49.8 to -33.2 ppt) and chemically drier (C 1 /C 1&ndash;5 values range from 0.74 to 0.99) with increasing level of thermal maturity. Gas samples are from depths as much as 21,600 ft. Gases were generated mainly from interbedded shales with type-III kerogen during the mature and postmature stages of hydrocarbon generation. Deviations from the trend are due to mixing and migration of gases generated at different levels of thermal maturity over the past 250 m.y. In the giant Panhandle-Hugoton field, nonassociated gases are generally produced from Permian carbonates at depths <3,000 ft. Gases display little compositional variation &delta; 13 C 1 values range from -46.4 to -39.9 ppt, C 1 /C 1&ndash;5 values range from 0.69 to 0.96). Because organic-rich, mature source rocks are not present in the area, gases probably were generated in the central basin from Pennsylvanian or older source rocks during the mature stage of hydrocarbon generation. This implies migration over distances as much as several hundred miles. In the Sooner trend, associated gases are produced from Silurian, Devonian, and Mississippian carbonates at depths as great as 9,600 ft and were generated from type-II kerogen during the mature stage of hydrocarbon generation. Associated oil correlates with extracts of the Upper Devonian and Lower Mississippian Woodford Shale. Gases are isotopically lighter (&delta; 13 C 1 values of -47.3 to -40.6 ppt) and chemically wetter (C 1 /C 1&ndash;5 values of 0.67 to 0.99) than those derived from type-III kerogen at an equivalent level of thermal maturity.

Oklahoma↗

Characteristics of marine uranium-bearing sedimentary rocks

Many marine sedimentary black shale and phosphorite formations contain 0.01 to 0.02 percent uranium, and one, the alum shale of Sweden, contains as much as 0.5 percent. The published fact that uranium is already being recovered on a laboratory scale from Swedish deposits forcefully suggests that similar deposits in the United States and possibly many other countries may prove to be an important future source of uranium.The marine uranium-bearing black shales are rich in organic matter and sulfides and contain little or no carbonate. The best are found in relatively thin formations of pre-Mesozoic age. The nature of the uranium-bearing mineral or compound is not known. In contrast, nonmarine black shales, as a group, are not uraniferous.All marine phosphorites tested thus far are uraniferous and so too are the phosphatic nodules found in many marine black shales. With some exceptions, the uranium increases in a general way with increase in phosphate content and is believed to be in the phosphate mineral. Like the black shales, the phosphorite formations are characteristically thin; many are associated with unconformities or, in other words, periods during which little else in the way of sediment accumulated.Significant concentrations of uranium in marine sediments other than black shales and phosphorites are thus far known only in beach placer deposits and the gold-bearing conglomerates of the Witwatersrand district, South Africa.Uranium may be found in other types of marine sediments on further prospecting, but especially promising are the sediments rich in organic matter, phosphate, or both, found in relatively thin formations believed to be the entire depositional products of long periods of geologic time. Such formations are most characteristic of those areas where, at the time of deposition, the adjacent land masses were so stable and low that the influx of clastic materials was small; the basin of deposition was large or of such configuration that fine-grained sediments could accumulate; and chemical conditions in the seawater prevented deposition of large amounts of carbonate.

Economic Geology↗

Evidence for primitive magma storage and eruption following prolonged equilibration in thickened crust

In continental arcs, the exposure of primitive eruptive products at the surface is typically a result of rapid magmatic transfer through the crust. As a result, the initially primitive magma experiences minimal crustal residence and thus insignificant differentiation towards more evolved products. This rapid transfer of primitive magma through thickened crust is commonly recorded from smaller, monogenetic cinder cones. Manantial Pelado (35.5° S) is a long-lived stratocone in the Southern Andean Volcanic Zone (SVZ) overlying thick continental crust (45–50 km) that produces almost exclusively mafic material. As Manantial Pelado is surrounded by extensive silicic volcanism, the study of its mafic exposure as a stratocone can be used to further understand magmatic origins of long-lived volcanic systems. Our study uses textural, geochemical, and geochronological data from lavas collected from Manantial Pelado to characterize its magmatic petrogenesis, assess the primitive nature, and explain processes in the crust within the SVZ. A geologic description of the volcano reveals a mostly monotonous eruptive history of basaltic andesites that are now accessible through glacially carved valleys. New 40 Ar/ 39 Ar dating constrains most of the volcano’s cone constructing phase to last from ~ 220 to 190 ka. At ~ 30 ka, small-volume activity and different petrography of more intermediate magmas were present reflecting a change in the volcano’s character. A combination of the whole-rock and mineral-scale data reveals that basaltic andesites at Manantial Pelado are among the most primitive magmas in the thickened crust of the SVZ. Evidence for this primitive signature consists of textural and zonation patterns in olivine, the presence of Cr-spinel in olivine cores, and elevated Fo and Ni content within olivine cores. This data combined with elemental diffusion modeling provides evidence for a primitive signature for these lavas. Intermediate Fo olivines with uniform core compositions (Fo 80–84 ) suggest that basaltic andesites reside in the crust in quasi-closed system environments for extended storage prior to eruption (~ 25–6000 years). Diffusive equilibration in those intermediate Fo olivines masks the primitive nature of the magmas. These results suggest that mafic magmas can have a protracted storage history in the crust that does not significantly alter their primitive bulk composition before reaching the surface. We argue that these are important processes in understanding the magmatic origin of long-lived systems and the presence of compositionally homogenous olivines at intermediate Fo content may represent cryptic evidence for recharge with primitive magmas that experienced prolonged crustal storage.

Manantial Pelado↗

Attributes for NHDPlus Catchments (Version 1.1) for the Conterminous United States: Physiographic Provinces

This dataset represents the area of each physiographic province (Fenneman and Johnson, 1946) in square meters, compiled for every catchment of NHDPlus for the conterminous United States. The source data are from Fenneman and Johnson's Physiographic Provinces of the United States, which is based on 8 major divisions, 25 provinces, and 86 sections representing distinctive areas having common topography, rock type and structure, and geologic and geomorphic history (Fenneman and Johnson, 1946). The NHDPlus Version 1.1 is an integrated suite of application-ready geospatial datasets that incorporates many of the best features of the National Hydrography Dataset (NHD) and the National Elevation Dataset (NED). The NHDPlus includes a stream network (based on the 1:100,00-scale NHD), improved networking, naming, and value-added attributes (VAAs). NHDPlus also includes elevation-derived catchments (drainage areas) produced using a drainage enforcement technique first widely used in New England, and thus referred to as "the New England Method." This technique involves "burning in" the 1:100,000-scale NHD and when available building "walls" using the National Watershed Boundary Dataset (WBD). The resulting modified digital elevation model (HydroDEM) is used to produce hydrologic derivatives that agree with the NHD and WBD. Over the past two years, an interdisciplinary team from the U.S. Geological Survey (USGS), and the U.S. Environmental Protection Agency (USEPA), and contractors, found that this method produces the best quality NHD catchments using an automated process (USEPA, 2007). The NHDPlus dataset is organized by 18 Production Units that cover the conterminous United States. The NHDPlus version 1.1 data are grouped by the U.S. Geologic Survey's Major River Basins (MRBs, Crawford and others, 2006). MRB1, covering the New England and Mid-Atlantic River basins, contains NHDPlus Production Units 1 and 2. MRB2, covering the South Atlantic-Gulf and Tennessee River basins, contains NHDPlus Production Units 3 and 6. MRB3, covering the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy River basins, contains NHDPlus Production Units 4, 5, 7 and 9. MRB4, covering the Missouri River basins, contains NHDPlus Production Units 10-lower and 10-upper. MRB5, covering the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf River basins, contains NHDPlus Production Units 8, 11 and 12. MRB6, covering the Rio Grande, Colorado and Great Basin River basins, contains NHDPlus Production Units 13, 14, 15 and 16. MRB7, covering the Pacific Northwest River basins, contains NHDPlus Production Unit 17. MRB8, covering California River basins, contains NHDPlus Production Unit 18.

Data Series↗

Geology and ground-water hydrology of the Mokelumne area, California

The Mokelumne River basin of central California comprises portions of the California Trough and the Sierra Nevada section of the Pacific Mountain system. The California Trough is divisible into four subsections-the Delta tidal plain, the Victor alluvial plain, tlie river flood plains and channels, and the Arroyo Seco dissected pediment. These four subsections comprise the land forms produced by the Mokelumne River and other streams since the Sierra Nevada attained its present height in the Pleistocene epoch. The Victor alluvial plain rises eastward from the Delta plain and abuts on the dissected Arroyo Seco pediment; in the Mokelumne area it is 12 to 16 miles wide and slopes between 5 and 8 feet in a mile. It includes relatively extensive tracts that are intensively cultivated and irrigated with water pumped from wells. The Victor plain has been compounded of overlapping alluvial fans along the western base of the Sierra Nevada. It is prolonged eastward into the pediment by tongues of alluvium along several of the present streams; thus it seems likely that the present stream pattern in the eastern part of the area has been fixed since dissection of the pediment began. Three of the four major streams-the Mokelumne and Cosumnes Rivers and Dry Creek-traverse the Victor plain in trenches which are 15 to 40 feet deep at the heads of their respective alluvial fans but which die out toward the west. The floors of these trenches, the historic flood plains, are from 100 yards to a mile wide. The exceptional major stream, which has not entrenched itself, is the Calaveras River. The Arroyo Seco pediment, which lies east of the Victor plain, was initially at least 8 to 15 miles wide and lay along the western foot of the Sierra Nevada entirely .across the Mokelumne area. Its numerous remnants decline 15 to 35 feet in a mile toward the west. The Sierra Nevada section adjoins and lies east of the California Trough. Its major ridge crests define a volcanic plain whose westward slope is' inferred to have been initially about 90 feet in a mile but is now about 180 feet in a mile, owing to tilting of the Sierra Nevada block in Pleistocene time. In and near the Mokelumne area the Sierra Nevada and California Trough together are roughly coextensive with a single structural unit. The Sierra Nevada constitutes a block that has risen with respect to adjoini;ng valley areas 'by simple rotation or tilting toward the west; it has not been warped or faulted -extensively. It is inferred that this block extends westward beneath the thick alluvial deposits of the trough without material warping or faulting. The oldest rocks of the Mokelumne region are the Carboniferous and Jurassic -rocks that compose the crystalline core of the Sierra Nevada. These are overlain unconformably by sediments of Tertiary age--in upward succession the lone, Valley Springs, Mehrten, and J.Jaguna formations. Of these formations all except the lone are newly discriminated, and type sections are described in the full text. These Tertiary sediments form a great wedge, thinnest along the mountain front to the east, where they have been truncated by erosion. They dip about 2° W. The lone formation (Eocene) consists chiefly of sandstone, clay, and shale; its maximum thickness is 450 feet. The Valley Springs formation (middle? Miocene) overlies the lone formation unconformably. It is composed largely of greenish-gray clay, shale, and sandstone derived from rhyolitic ejectamenta. These rhyolitic deposits are confined to narrow channels in the higher part of the Sierra Nevada, but they spread fanlike over the lower western edge of the mountain block, where they attain a maximum thickness of 525 feet. The Mehrten formation (upper? Miocene and lower Pliocene?) comprises the andesitic rocks that constructed the Sierran volcanic plain. In the Mokelumne area it consists chiefly of sandstone and siltstone but includes, as a minor though conspicuous part of the formation, layers and tongues of resistant breccia or agglomerate, which are presumed to have originated as mud flows. Nonfragmental andesite is not known to occur in the Mokelumne area, although several possible vents occur farther east. In the eastern part of the area the Mehrten formation truncates in turn the Valley Springs and lone formations and the pre-Cretaceous rocks; in the western part the Mehrten formation (andesitic) interfingers with the underlying Valley Springs formation (rhyolitic). Its maximum measured thickness is 400 feet. Few of the irrigation wells are so deep that they can be said with assurance to reach the Mehrten formation. The Laguna formation (Pliocene? and possibly lower Pleistocene) comprises poorly sorted, nonandesitic fluviatile sedimentary that overlie the Mehrten formation. It is inferred to be essentially parallel to and tilted equally with the Mehrten formation and to be about 400 feet thick. The Arroyo Seco gravel (presumably middle Pleistocene) veneers the Arroyo Seco pediment. At its easternmost outcrops the formation is composed of pebbles, cobbles, and boulders in a matrix of brick-red sand and silt; farther west, down the slope of the pediment, it becomes pr9gressively finer. It is inferred that the Arroyo Seco gravel is a coarse fraction of the rock waste that was transported from the Sierra Nevada after the Sierran.block was tilted in Pleistocene time. It is inferred further that the correlative of the Arroyo Seco gravel in the California Trough is a wedge-shaped mass of sediments whose base is the tilted Laguna formation and whose top can be interpolated by projecting a hypothetical surface through the remnants of the pediment. The Victor formation comprises the fluviatile sand, silt, and gravel that built the Victor alluvial plain over the hypothetical equivalent of the Arroyo' Seco gravel along the axis of the California Trough and against the western front of the dissected pediment to the east. The formation is thought to be about 100 feet thick along the western margin of the Mokelumne area, according to an estimate based upon projecting the slope of the Arroyo Seco pediment westward beneath the Victor plain. The Mokelumne area lies on the fertile central plain along the Mokelumne River about the city of Lodi, in northern San Joaquin County, and has been intensively developed for the cultivation of grapes, deciduous fruits, and other crops. Of necessity its great productiveness is maintained by irrigation. Extensive irrigation from wells began about 1907 and has increased steadily until in 1932 about 50,000 acres (80 percent of the area) was watered in that manner. The specific question at issue is the extent to which the supply of ground water and hence the productiveness of the area are dependent upon the water flowing in the Mokelumne River and the extent to which that productiveness may be influenced by regulation of the stream--:in particular, by the substantial regulation of the river that is accomplished by the Pardee Dam of the East Bay Municipal Utility District, which began to function in March 1929. The depth of 1,447 irrigation wells in five townships in the central part of the area (T. 3 N., Rs. 6 and 7 E., and T. 4 N., Rs. 6 to 8 E.) ranges from 20 to 910 feet. About half the wells bottom within a 100-foot zone whose base is 75 feet below the projected Arroyo Seco pediment; essentially that zone constitutes the Victor formation. Only 6 percent of the wells bottom within the next lower 25- foot zone, but the percentage increases sharply for depths still greater; it is inferred that impervious strata are relatively persistent between 75 and 100 feet below the projected pediment and that these are the uppermost part of the Arroyo Seco gravel. Of 580 observation wells known to bottom in the Victor formation, essentially all appear to indicate a regional water-table stage; thus the water is essentially unconfined. On the other hand, nearly all wells so deep that they reach the Arroyo Seco gravel or some underlying formation tap confined water. Near the Mokelumne River the water levels in these deep wells stand below the water table, which is semiperched. In most deep wells remote from the river the water level stands above the water table except during the pumping season. Fluctuations of ground-water levels are ascribed to moving or changing load on the land surface, earthquakes, variation of barometic pressure, ground-water draft by vegetation, infiltration of rain and certain indirect effects of rainfall, infiltration of water applied to the land for irrigation, variation in the discharge of streams, and pumping from wells. In the eastern part of the central district, between Clements and the vicinity of Lockeford, it is inferred that (1) the river and the water in the alluvium of the flood plain are not insulated from the water in the sediments that form the adjacent Victor plain; (2) locally if not generally, however, there are discontinuities in pervious strata along the outer margin of the flood plain, where the water table passes from the alluvium into the enclosing sediments, so that percolation of ground water is impeded materially at that margin; (3) rising river stages set up ground-water waves that store relatively large volumes of water in the alluvium close to the river, whereas falling stages cause much of that stored water to percolate back into the river, weeks and even months lapsing before the ground-water stage becomes steady within the flood plain; and (4) seepage loss from the river into the alluvium tends to be intermittent and to alternate with seepage gain, the rate of loss or gain lagging weeks or months behind the fluctuations of river stage and lagging more for moderate changes at low stage. However, in the succeeding reach downstream as far as Woodbridge, it is inferred that percolation of ground water is not impeded generally along the outer margin of the flood plain and that the river tends to lose almost continuously by seepage rather than intermittently, although the rate of loss fluctuates somewhat in response to changing river stage. The yearly pumpage for irrigation has been as much as 114,600 acre-feet (1928- 29), and there have been as many as 2,500 wells equipped with irrigation pumping plants (1931). Commonly the wells are pumped only in daylight and are idle over week-ends and holidays, also during and after protracted rainstorms in the early part of the season. In a small district near Victor pumping in recent years has begun in January or February, has reached its height in March, and largely has passed by April. In outlying districts general pumping has begun as late as May, reached its height in June or July, and waned by September. Since 1907 the water table appears to have declined steadily in most of the Mokelumne area except along the river. The decline was least in the Woodbridge Irrigation District, where in four typical wells. the average decline from 1907 to 1937 was 3 feet, or 0.15 foot a year. Among 18 shallow wells in the district of most intensive pumping the average recession of the water table from 1907 to 1927 was 11 feet, or 0.55 foot a year; the greatest measured recession was 15 feet, or 0.75 foot a year. From 1927 to 1933 the water table declined 5 feet or more over most of the central pumping district except within 2 miles of the Mokelumne River, and the greatest measured decline was 9 feet. The area of material recession ,extends 4 to 7 miles eastward beyond the central pumping district, whence it is inferred that pumping has drawn gradually on remote ground-water storage. It is inferred that the Mokelumne River ordinarily has been a losing stream between the Mehrten dam site, near Clements, and the Woodbridge Dam, the area that received the percolate having been triangular with its upstream and having included about 5,200 acres of the flood plain and 36,500 acres in outlying districts to the north and to the south. Mean fluctuations of the water table within the area receiving percolate from ihe river are believed to indicate that relatively little water is drawn from outside the area. Accordingly, simple storage methods are competent for a ground-water inventory. It is inferred that the rate of seepage loss from the river depends jointly upon river discharge, stage in the Woodbridge Reservoir, and groundwater pumpage. The foregoing inferences lead to the following conclusions with respect to ground-water replenishment by seepage loss from the river in the intensively cultivated district about Lodi: (1) The annual replenishment has tended to increase for at least two decades, owing to the gradual increase in head between surface water and ground water as ground-water levels have been lowered progressively by pumping; (2) annual replenishment has tended to increase, especially in recent years, owing to gradually prolonged use of the Woodbridge Reservoir, for thereby a relatively large wetted area and great differential head have been maintained for an increasing term; (3) the rate of replenishment tends to be greater under regulation than under the so-called natural regimen, to the extent that regulation has maintained a moderately large wetted area and stage in the river through the later part ·of each pumping season, whi1e the ground-water levels have been lowest. Moreover, for any particular yearly run-off below the Mehrten dam site, the replenishment by seepage would tend to be greater under the regulated regimen to the extent that fluctuations in discharge were suppressed, for the greatest yearly mean stage and mean wetted area would be afforded by constant discharge. -Thus, diverting water out of the Mokelumne River Basin at the Pardee Dam does not necessari1y-entail a diminution in ground-water replenishment by seepage loss along the lower reach of the stream, at least in the replenishment beneath the Victor plain above the gaging station at Woodbridge. Rather. the Pardee Dam affords a means for so regulating the discharge as to effect a maximum ground-water replenishment with-a given run-off in the natural channel. Bodies of ground water perched above the regional water table are common in the Laguna formation, especially in its lower part. Conspicuous bodies occur about 3 miles south of Clay, in a district between 1 mile and 5 miles south of Clements, and along Dry Creek in T. 5 N., Rs. 7 and 8 E. From the relation between the water table and the piezometric surface for water confined in deep aquifers, the area receiving percolate from the Mokelumne River may be divided roughly into (1) a central area, extending not :p1ore than half a mi1e beyond the flood plain, in which the piezometric surface is inferred to have stood below the water table throughout the term of the investigation and hence in which the difference in head has favored the percolation of water from shallow beds into deep beds in all seasons, and (2) an outlying area in which the difference in head likewise favors downward percolation into deep beds during the pumping season but favors upward percolation during the nonpumping season. This outlying area includes about 75 percent of the segment of the Victor plain that receives percolate from the river. From 1927 to 1933 the subartesian head that existed during the nonpumping season in the area remote from the river tended to increase; it is therefore inferred that the relative opportunity for seasonal recharge of the shallow water-bearing beds by underfeeding has likewise tended to increase. On the other hand, the negative differential head in wells near the river also has tended to increase; thus in this central area the opportunity for discharge of water from shallow beds by downward percolation has probably tended to increase. It is believed that ground-water storage within the area near the river is not decreased materially by" discharge westward through deep pervious beds, also that the yearly addition to ground-water storage in the outlying area by deep percolation from a remote easterly source is scant and for all practical purposes is offset by downward percolation along the river.

California↗

Central Colorado Assessment Project - Application of integrated geologic, geochemical, biologic, and mineral resource studies

Central Colorado is one of the fastest-growing regions in the Western United States. Population along the Front Range increased more than 30 percent between 1990 and 2000 (http://www.demographia.com/db-metro3newworld.htm) with some counties within the study area, such as Park County, experiencing greater than 100-percent growth (http://www.censusscope.org/us/s8/rank_popl_growth.html). This growth has caused tremendous demand for natural resources and has created challenging land-management issues related to the interface between wilderness and urban expansion. Management of this wilderness/urban interface will benefit from current digital geoscience information collected by the U.S. Geological Survey (USGS) Central Colorado Assessment Project that began in 2003. Approximately 20,800 square miles (53,800 km2) of land divided almost equally between the public and private sectors were part of the assessment. The study area includes much of the Colorado Mineral Belt, a northeast-trending zone that contains 30 economically significant metal deposits. Historically, the area provided much of Colorado's metal production. The only active gold and molybdenum mines in Colorado lie within the study area. Recently, metal and uranium exploration activity has increased sharply in response to record prices for metals and uranium. This further underscores the need for up-to-date geoscience information presented in compatible GIS databases to facilitate rapid land-management decisions. Cooperative studies by USDA Forest Service, National Park Service supported by the USGS Mineral Resources Program (MRP), and National Cooperative Geologic Mapping Programs (NCGMP) contributed to the mineral-resource assessment and included regional geologic mapping at the scale 1:100,000, collection and geochemical studies of stream sediments, surface water, and bedrock samples, macroinvertebrate and biofilm studies in the riparian environment, remote-sensing studies, and geochronology. Geoscience information available as GIS layers has improved understanding of the distribution of metallic, industrial, and aggregate resources, location of areas that have potential for their discovery or development, helped to understand the relation of tectonics, magmatism, and paleohydrology to the genesis of the metal deposits in the region, and provided insight on the geochemical and environmental effects that historical mining and natural, mineralized rock exposures have on surface water, ground water, and aquatic life.

Fact Sheet↗

Growth of the 2004-2006 lava-dome complex at Mount St. Helens, Washington

The eruption of Mount St. Helens from 2004 to 2006 has comprised extrusion of solid lava spines whose growth patterns were shaped by a large space south of the 1980-86 dome that was occupied by the unique combination of glacial ice, concealed subglacial slopes, the crater walls, and relics of previous spines. The eruption beginning September 2004 can be divided (as of April 2006) into five phases: (1) predome deformation and phreatic activity, (2) initial extrusion of spines, (3) recumbent spine growth and repeated breakup, (4) southward extrusion across previous dome debris, and (5) normal faulting of the phase 4 dome to form a depression, a shift to westward extrusion and overthrusting of earlier phase 5 products. Overall, steady spine extrusion gradually slowed from 6 m 3 /s in November 2004 to 0.6 m 3 /s in February 2006. Thermal camera data show that phase 1 activity included low-temperature thermal features, such as fumaroles, fractures, and ground warming related to rapid uplift, as well as deformation in the south moat of the crater. The relatively cold (<160&deg;C) phreatic eruptions of early October heralded activity at a subglacial vent situated along the south-sloping margin of the 1980–86 dome. Thermal infrared imagery, documenting increased heat flow, presaged phase 2 extrusion of the October 11–15, 2004, lava spine. The thermal images of the extruding spine revealed a hot basal margin and highest temperatures of 600–730&deg;C. During phase 3, a recumbent whaleback-shaped spine with a low-temperature shroud of fault gouge and a hot, U-shaped basal margin extruded. This spine pushed southward along the bed of the glacier until it encountered the south wall of the 1980 crater, whereupon it broke up, decoupled, and regrew. Continued southward growth of the recumbent spine pushed cold deformed rock, hot dome rubble, and glacier ice eastward at a rate of 2 m/d. In April 2005, breakup of the whaleback and growth of a lava spine across previous dome rubble heralded phase 4 spine thrusting over previous spine remnants. During phase 4, the active spine pushed southward with an increasingly vertical component and increasing incidence of large rockfalls. In late July, the spine decoupled from its source, the vent reorganized, and a new spine began to grow westward at right angles to the previous growth direction, defining phase 5. Dome migration again plowed glacier ice out of the way at a rate of about 2 m/d, this time westward. In early October, the spine buckled near the vent and thrust over the previous one. A massive spine monolith had been constructed by December 2005, and growth of spines with increasingly steep slopes characterized activity through April 2006. The chief near-surface controls on spine extrusion during 2004-6 have been vent location, relict topographic surfaces from the 1980s, and spine remnants emplaced previously during the present eruption. In contrast, glacier ice has had minimal influence on spine growth. Ice as thick as 150 m has prevented formation of marginal angle-of-repose talus fans but has not provided sufficient resistance to stop spine growth or slow it appreciably. Spines initially emerged along a relict south-facing slope as steep as 40&deg; on the 1980s dome. The open space of the moat between that dome and the crater walls permitted initial southward migration of recumbent spines. An initial spine impinged on the opposing slopes of the crater and stopped; in contrast, recumbent whaleback spines of phase 3 impinged on opposing walls of the crater at oblique angles and rotated eastward before breaking up. Once spine remnants occupied all available open space to the south, spines thrust over previous remnants. Finally, with south and east portions of the moat filled, spine growth proceeded westward. Although Crater Glacier had only a small influence on the growing spines, spine growth affected the glacier dramatically, initially dividing it into two arms and then bulldozing it hundreds of meters, first east and then west, and heaping it more than 100 m higher than its original altitude.

Washington↗

Maturation study of vitrinite in carbonaceous shales and coals: Insights from hydrous pyrolysis

The presence of vitrinite in sedimentary rocks of post-Silurian age allows its reflectance to be used to estimate the thermal maturation of organic matter in petroleum systems. Increasing reflectance of vitrinite, which is primarily driven by aromaticity, depends primarily on the time and temperature attributes of its evolutionary pathway. This study evaluated carbonaceous shales proximal to coal measures and coal samples via isothermal hydrous pyrolysis (HP) to compare differences in the maturation pathways of vitrinite. Sample residues were analysed via vitrinite reflectance (VRo), geochemical screening tests (organic carbon and programmed temperature pyrolysis), and infrared spectroscopy. The study included samples from Indian and North American basins, to observe differences in vitrinite evolution with respect to enclosing mineral matrix, starting degree of aromaticity, organic matter types, stratigraphic age, and depositional environment. The organic content of HP residues shows an intuitive response to the thermal stress of HP, e.g., a general depletion of total organic carbon (TOC) content, pyrolyzate (S2), and hydrogen index with increasing HP temperature. Infrared proxies including C-factor and CH2/CH3 generally decrease with increasing thermal maturity indicating loss of O via CO2 generation and the thermal cracking of aliphatic organic matter. Tmax, production index (PI), and VRo show intuitive increasing values with respect to HP temperature. The least mature sample (0.48 ± 0.05% VRo) generally experienced the maximum change in these parameters during maturation, whereas the most mature sample (0.99 ± 0.06% VRo) generally showed the least change. This observation is consistent with higher kinetic barriers to reaction in more aromatic vitrinite which contains higher bond dissociation energies. Devolatilization of vitrinite during HP causes formation of gas evacuation vacuoles and contraction cracks in the vitrinite grains of both coal and carbonaceous shale. Similarities in vitrinite response to HP between coal and carbonaceous shale suggest that thermal evolution of the vitrinite maceral is principally controlled by inherent rate-limiting kinetic parameters related to its molecular structure. Whereas, the stratigraphic age, sedimentary environment, surrounding organic matter, lithology, and catalysis by mineral composition have less effect. To further improve our understanding of vitrinite aromatization and kinetic parameters, future studies of vitrinite reflectance thermal evolution with temperature should include coal and carbonaceous shale from the same stratigraphic section and extant woody tissue from modern vascular plants.

International Journal of Coal Geology↗

A geochemical investigation of selected areas in Greenville and Laurens Counties, South Carolina: Implications for mineral resources

The purpose of this study is to geochemically evaluate three areas within the Greenville 1&deg; x 2&deg; quadrangle (see index map) that have been shown by previous studies to contain anomalously high amounts of tin. Jackson and Moore (1992) reported the presence of cassiterite (SnO 2 )-bearing heavy-mineral concentrates from stream sediment samples that were collected during a regional geochemical reconnaissance of the Greenville 1&deg; x 2&deg; quadrangle. The data reported here confirm identified in selected heavy-mineral concentrate samples. In addition, anomalously high concentrations of barium, beryllium, lanthanum, and thorium are also reported for parts of the same areas. No significant mineral deposits are known to occur in the study areas. There was, however, minor production of monazite from several nearby localities (Sloan, 1908), and gold was produced from deposits in the northeastern part of Greenville County and nearby Spartanburg County (McCauley and Butler, 1966). The three areas selected for resampling are located in the Inner Piedmont physiographic province of South Carolina (see index map). The generalized tectonic setting of the region and the locations of the study is just north of Greenville, S.C. Much of it is within the moderately to steeply sloped terrane of Paris Mountain State Park where elevations reach approximately 600 m. Simpsonville, S.C., is neat the center of the second study area, and the southernmost study area is near Hickory Tavern, S.C. Both the Simpsonville and Hickory Tavern study areas are in more gently rolling Piedmont terrane. Each of the sampled areas is drained by tributaries of the Enoree and Reedy Rivers. Parts of three different thrust sheets underlie the region covered by this study (fig. 1); in ascending structural position, they are the Six Mile, Paris Mountain, and Laurens thrust sheets (Nelson and others, 1987). Nelson (1988, p. 7) described the contacts between these sheets as being along unnamed faults. The rocks in and around the study areas have undergone sillimanite-muscovite-grade metamorphism (Nelson, 1988, p. 9). Nelson (1988, p. 13) reports that the Six Mile thrust sheet was metamorphosed about 344 Ma. The geology of these sheets as described in this study, including geologic contacts, rock descriptions, and unit names, generally follows that of Nelson and others (1987, 1989). Within the Paris Mountain study area, rocks of the Paris Mountain thrust sheet predominate (fig. 2) and consist of a biotite-muscovite-sillimanite schist (EZsp) that has extensive lenses of fine- to medium- grained biotite granite gneiss (Pzgp). Areas of biotite granite gneiss that occur in the southern part of the Paris Mountain study area contain extensive pegmatitic and leucogranitic phases. These pegmatitic zones consist mostly of coarse-grained microcline feldspar and quartz with minor amounts of muscovite, biotite, and garnet. Smaller pegmatite lenses (<0.5 m thick) that occur within the biotite-muscovite-sillimanite schist of the Paris Mountain study area are generally of similar mineralogy, although some contain tourmaline crystals up to 5 cm in length. The Six Mile thrust sheet underlies the northern edge of the Paris Mountain study area, where it is composed of gneissic biotitic granites of the Caesars Head Granite (figs. 1 and 2). The northwestern part of the Simpsonville study area (figs. 1 and 3), within the Paris Mountain thrust sheet, is underlain by a biotite-muscovite-sillimanite schist (EZsp) that contains lenses of biotite granite gneiss (Pzgp). In the southeastern part of the Simpsonville study area, within the Laurens thrust sheet, biotite gneiss (EZgl), biotite granite gneiss (Pzgf), and minor amphibolite (EZal) are interlayered biotite (EZgl), granite gneiss (Dgg), and amphibolite (EZal) of the Laurens thrust sheet (fig. 4).

South Carolina↗

Altitude of the top of the Madison Limestone in the Black Hills area, South Dakota

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and groundwater in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers). The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study arca arc Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills. The purpose of this map is to show the altitude of the top (structure contours) of the Madison Limestone within the area of the Black Hills Hydrology Study. The depth to the top of the Madison Limestone can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation. However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

South Dakota↗

Variation in the terrestrial isotopic composition and atomic weight of argon

The isotopic composition and atomic weight of argon (Ar) are variable in terrestrial materials. Those variations are a source of uncertainty in the assignment of standard properties for Ar, but they provide useful information in many areas of science. Variations in the stable isotopic composition and atomic weight of Ar are caused by several different processes, including (1) isotope production from other elements by radioactive decay (radiogenic isotopes) or other nuclear transformations (e.g., nucleogenic isotopes), and (2) isotopic fractionation by physical-chemical processes such as diffusion or phase equilibria. Physical-chemical processes cause correlated mass-dependent variations in the Ar isotope-amount ratios ( 40 Ar/ 36 Ar, 38 Ar/ 36 Ar), whereas nuclear transformation processes cause non-mass-dependent variations. While atmospheric Ar can serve as an abundant and homogeneous isotopic reference, deviations from the atmospheric isotopic ratios in other Ar occurrences limit the precision with which a standard atomic weight can be given for Ar. Published data indicate variation of Ar atomic weights in normal terrestrial materials between about 39.7931 and 39.9624. The upper bound of this interval is given by the atomic mass of 40 Ar, as some samples contain almost pure radiogenic 40 Ar. The lower bound is derived from analyses of pitchblende (uranium mineral) containing large amounts of nucleogenic 36 Ar and 38 Ar. Within this interval, measurements of different isotope ratios ( 40 Ar/ 36 Ar or 38 Ar/ 36 Ar) at various levels of precision are widely used for studies in geochronology, water&ndash;rock interaction, atmospheric evolution, and other fields.

Pure and Applied Chemistry↗

Altitude of the top of the Inyan Kara Group in the Black Hills area, South Dakota

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers). The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills. The purpose of this map is to show the altitude of the top (structure contours) of the Inyan Kara Group within the area of the Black Hills Hydrology Study. The depth to the top of the Inyan Kara Group can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation. However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

Hydrologic Atlas↗