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Airborne geophysics for geologic mapping of critical mineral systems in the United States southern midcontinent

The increased demand for clean energy technology and a significant reliance on foreign supply chains have given impetus to understanding critical mineral systems and locating potential resources within the United States. At least thirteen critical mineral-bearing systems have been identified throughout the U.S. southern Midcontinent (Hofstra and Kreiner, 2020) but much of the region’s geologic framework is concealed by vegetation and sedimentary cover that hinder traditional geologic mapping efforts. Airborne geophysical data provide an effective way to overcome these obstacles and to provide additional insight into the deeper structures that underlie shallow mineralization. However, legacy airborne magnetic and radiometric data were collected using now-outdated instruments and methods, inconsistent survey parameters, and large flight-line spacings resulting in low-resolution data that present challenges to regional-scale study and interpretation. Over the last decade, the U.S. Geological Survey Earth Mapping Resources Initiative (EMRI) and National Cooperative Geologic Mapping Program have conducted a series of high-resolution airborne magnetic and radiometric surveys across the southern Midcontinent (Fig. 1) as part of an effort to improve understanding of the geophysical framework and natural resource potential in the region. These surveys are designed using modern survey methods and instruments with consistent parameters for flight-line spacing and flight height relative to magnetic sources. The EMRI airborne surveys are planned in collaboration with State geological surveys based on focus areas (Dicken et al., 2022) according to the presence of or potential for critical mineral deposits. High-resolution airborne magnetic and radiometric data cover focus areas such as the southeast Missouri iron metallogenic province and South-Central iron-oxide-apatite (IOA) – iron-oxide-copper-gold (IOCG) province, the Magnet Cove alkaline-carbonatite complex, the Midwest Permian ultramafic dike district, the Illinois-Kentucky fluorspar district, and several Mississippi Valley-type lead-zinc deposits and districts (Fig. 1). These focus areas represent known deposits or prospective host systems of critical minerals including rare earth elements (REEs), platinum-group elements (PGEs), cobalt, lithium, fluorspar, niobium, titanium, vanadium, lead, zinc, gallium, germanium, and many more. Other significant geologic and geophysical features covered include the Reelfoot rift, the New Madrid seismic zone, the Illinois basin, the Arkoma basin, the South-Central magnetic lineament, and the Kentucky-Tennessee magnetic anomaly (Fig. 1). This presentation focuses on new airborne magnetic and radiometric data with continuous coverage across parts of six states, preliminary interpretations, examples of geologic mapping applications, and discussion of newly discovered magnetic anomalies and follow-up investigations.

Conference Paper

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods

An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets

Mineral commodity summaries 2025

Introduction Each mineral commodity chapter of the 2025 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2024 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the MCS 2025 are welcomed.

Mineral Commodity Summaries

Mineral commodity summaries 2026

Introduction Each mineral commodity chapter of the 2026 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2025 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the 2026 MCS are welcomed.

Mineral Commodity Summaries

Relationship between peak and cumulative ground motions from 49 Mw 3-6 earthquakes in the San Francisco Bay Area

We examine the relationship between peak ground velocity (PGV) and cumulative absolute displacement (CAD) for 49 M w 3 – 6 earthquakes in the San Francisco Bay Area (SFBA) and gain insight into the spatiotemporal partitioning of seismic energy in ground motion records with respect to source, path, and site effects. PGV and CAD are positively correlated, but there can be large deviations from the average trend. For example, ground motion records with either very long duration resonance or short pulse-like motions will have higher or lower CAD, respectively, but could have very similar PGV. We perform principal component analysis (PCA) on PGV-CAD for >7000 records in the SFBA with the goal of investigating what influences positive or negative anomalies in cumulative motions. PCA rotates the PGV-CAD datapoints into two principal components, where the one with the larger variance, which we call the “primary intensity” represents mostly the distance-dependence of ground motion amplitudes. The other principal component, which we call the “excess motion”, represents the deviation from cumulative motions that would be typical for a ground motion record with a given PGV. The excess motion will be positive in the case of records with long duration ringing and will be negative for short duration pulse-like ground motions. We find that excess motion is generally positive at sites in sedimentary basins and in soft sediments around the SF Bay. Excess motion is generally negative in the very near field, as well as at sites on hard bedrock. We discuss the findings here in terms of implications for seismic hazard applications and other wave propagation phenomena.

California

Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2021–22

Between the 1950s and 1980s, wastewater generated at the Idaho National Laboratory contained Iodine-129 ( 129 I); this wastewater was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well, unlined infiltration ponds, or leaked from distribution systems below industrial facilities. During 2021–22, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy and the Idaho Department of Environmental Quality Idaho National Laboratory Oversight Program, collected groundwater samples from 64 monitoring wells in the ESRP aquifer, 6 of which are part of a multilevel monitoring system, to determine the concentration of 129 I in the groundwater. These samples were analyzed by accelerator mass spectrometry as part of a long-term ongoing study to track trends and occurrences of this carcinogenic, long-lived radionuclide in the environment. Concentrations ranged from slightly above the locally determined background concentration of 5.4×10 −6 picocuries per liter, to just below the U.S. Environmental Protection Agency’s maximum contaminant level of 1 picocurie per liter. Discharge of wastewater containing 129 I has been discontinued to the aquifer, and long-term trends from a subset (n=15) of sampled wells show decreasing 129 I concentrations over the last three decades. Concentrations of 129 I in groundwater from monitoring wells near facilities at the Idaho National Laboratory are affected by episodic recharge from an ephemeral surface-water source and by the fracture-flow dominated hydrologic regime in the ESRP aquifer. The spatially focused sampling effort has also identified a low-level 129 I plume that affects long-term water quality near and downgradient from the Advanced Test Reactor Complex in the southwestern part of the facility that had not been clearly defined in previous sampling efforts, although the definition of the plume is somewhat limited by available data.

Idaho

Lithium from magma to mine in an early Yellowstone hotspot caldera

Renewable energy technologies rely on the extraction of metals not historically in high demand, such as lithium (Li), for which ore deposit models are incompletely understood. One of the world’s largest Li deposits is hosted in lake sediments of the 16.4 Ma McDermitt caldera, which formed during the early stages of Yellowstone hotspot volcanism in the western United States. Eruptive and posteruptive mobility of Li are major challenges in elucidating deposit formation. Melt inclusions preserved in quartz crystals provide a means to assess pre-eruptive magmatic Li contents. Concentrations of Li determined by ion microprobe for melt inclusions in a McDermitt rhyolite lava are 400−1350 ppm, compared to 20−70 ppm Li in matrix rhyolite glasses. Synthesis with melt inclusion data for eight additional calderas demonstrates a recurrence of Li-rich rhyolitic magmas (200−2000 ppm Li) in the western part of the Yellowstone hotspot track. However, unlike the multicyclic caldera complexes with overlapping fault networks that may have compromised Li retention, the McDermitt caldera remained a closed hydrologic system throughout its evolution. Modeling indicates 100 km 3 of resurgent magma could yield 25−150 Mt Li in a magmatic fluid and supports accumulation of Li-rich magmatic fluid in a closed intracaldera lake, followed by evaporative concentration and sequestration of Li within clay minerals to generate the McDermitt deposit.

Idaho, Nevada, Oregon, Wyoming

Projecting stream water quality using Weighted Regression on Time, Discharge, and Season (WRTDS): An example with drought conditions in the Delaware River Basin

Future water availability depends on understanding the responses of constituent concentrations to hydrologic change. Projecting future water quality remains a methodological challenge, particularly when using discrete observations with limited temporal resolution. This study introduces Weighted Regression on Time, Discharge, and Season for Projection (WRTDS-P), a novel, computationally efficient method that enables the projection of daily stream water quality under varying hydrologic conditions using commonly available discrete monitoring data. WRTDS-P model performance was validated using 39 sites in the Delaware River Basin (DRB) and four key constituents: specific conductance (SC), nitrate (NO 3 − ), magnesium (Mg 2+ ) and calcium (Ca 2+ ). Projections were tested against holdout data from the final 1 to 5 years of each time series, demonstrating robust predictive capability, with median Nash-Sutcliffe efficiencies of 0.67 for SC, 0.56 for NO 3 − , 0.65 for Ca 2+ , and 0.79 for Mg 2+ . Model uncertainty was correlated with indicators of hydrologic or geochemical mass-sinks, such as groundwater storage and adsorption in wetland soils. Drought scenario analyses for SC used ranges of reduced discharge including flows from the 1965 drought of record. Scenarios predicted widespread increases of SC, especially in southern DRB streams where baseline SC levels are already elevated. Fractional increases of SC were more uniformly distributed, indicating potential risk to sensitive ecosystems. Notably, drought-induced SC increases were positively correlated with interannual SC trends, indicating that hydrologic extremes could exacerbate ongoing salinization. This work provides a transferable and interpretable framework for projecting future water quality and assessing hydrologic risk to water resources and aquatic ecosystems.

Delaware, New Jersey, New York, Pennsylvania

Estimating groundwater level records using MOVE.1 and computing monthly percentiles from estimated groundwater records in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed record extensions on groundwater levels at select wells using the Maintenance of Variance Extension type 1 (MOVE.1) method. The groundwater levels estimated from these record extensions were used to compute monthly percentiles to improve future determinations of a groundwater index. In Massachusetts, 27 of 29 short-record study wells with continuous groundwater levels between 0.8 and 8.1 years were suitable for record extensions; 37 long-record index wells were used to extend the groundwater level records at the study wells. The index well selected to pair with a study well was chosen based on Pearson correlation coefficient values; cross-correlation between the two wells; geologic and topographic similarity; and smallest distance spanning the wells. Each study well and its corresponding index well have 1 or more years of concurrent, overlapping data; a Pearson correlation coefficient that exceeded a threshold value of 0.8; and a similar aquifer type and hydrologic characteristics. Of the 29 study wells, 2 showed poor correlations with all index wells and were not considered for record extensions. Performance metrics used to assess the accuracy of the MOVE.1 models indicated that most models provided reasonable estimates of groundwater levels. Root mean square error values ranged from 0.097 to 2.292 feet, with a median of 0.536 foot. Nash-Sutcliffe efficiency coefficient values ranged from 0.623 to 0.996, with a median value of 0.759. Generally, study wells in close geographical proximity to their index well resulted in stronger model performance. The average length of groundwater level records was extended by 14.1 years to a new average of 18.1 years. The estimated groundwater level records from the MOVE.1 models resulted in an increase in the range of highest and lowest groundwater levels at 23 of 27 wells. The increase in range of groundwater levels was between 0.08 to 7.95 feet. Monthly percentiles for State drought indices were computed from the estimated MOVE.1 records and observed records through December 31, 2021. Percentiles computed from estimated records show an average groundwater level about 1.0 foot lower than observed data at the 2d percentile and 0.1 foot lower at the 30th percentile.

Massachusetts

Seismic techniques and suggested instrumentation to monitor volcanoes

Introduction Changes in the pressure or location of magma can stress or break surrounding rocks and trigger flow of nearby waters and gases, causing seismic signals, such as discrete earthquakes and tremor. These phenomena are types of seismic unrest that commonly precede eruption and can be used to forecast volcanic activity. Mass movements at the surface, including avalanches, debris flows, and lahars, may also generate seismic signals that are specifically addressed in chapter H , this volume (Thelen and others, 2024). Our focus in this chapter is to determine the levels of instrumentation recommended to produce high-quality, well-constrained seismic observations important for early warning of impending eruptions, detecting changes in ongoing eruptions, and characterizing other hazardous volcanic events. There are emerging techniques and new types of instrumentation, such as distributed acoustic sensing or rotational seismometers, that we do not consider here. These types of instrumentation show promise for monitoring but still require maturation before being considered more generally in volcano monitoring. Most of the capabilities mentioned below are universal for all types of volcanic systems, although some are best applied to stratovolcanoes with an apical single vent. In some settings, such as calderas or shield volcanoes, we must broaden coverage to include multiple possible storage regions or vent locations. As an example, Thelen (2014) discretized the long rift zones of shield volcanoes in Hawaiʻi as a set of evenly spaced “vents.” In this construct, each vent comes with recommendations, and several thousand network configurations were simulated to assess the effect on network quality levels and to determine the most efficient network design. The same process could be applied in a caldera setting or a volcanic field, where an evenly spaced grid of potential vents is considered. Localized recommendations for each unique system are beyond the scope of this report and left up to local experts to assess based on the conditions, restrictions, and requirements of each volcano.

Scientific Investigations Report

Phase 1 technical implementation plan for the expansion of the ShakeAlert earthquake early warning system to Alaska

Executive Summary The conference report accompanying the fiscal year (FY) 2022 Consolidated Appropriations Act (Public Law 117–103) for the U.S. Department of the Interior and related agencies directed the U.S. Geological Survey (USGS) to “work with the State of Alaska to develop an implementation plan to be completed within two years in order to put ShakeAlert/Earthquake Early Warning in Alaska” (p. 29). Congress included $1 million in the FY 2022 appropriation to conduct this effort. The USGS Earthquake Hazards Program, along with partner organizations, has developed the ShakeAlert earthquake early warning (EEW) system for the West Coast, which currently operates in California, Oregon, and Washington. The purpose of the system and its alert delivery partners is to reduce the impact of earthquakes and save lives and property by delivering ShakeAlert-powered alerts that are transmitted to the public via mass notification technologies, and by providing more detailed data streams to institutional users and commercial service providers to trigger automated, user-specific, protective actions. ShakeAlert was designed in such a way that it could be expanded to other U.S. regions with high earthquake risk, after the build-out of seismic and geodetic networks to support ShakeAlert in a specified region is completed and the necessary funding is secured for long-term operation and maintenance. When an earthquake occurs, seismic waves radiate from the rupturing fault like waves on a pond. It is these waves that people feel as earthquake shaking and that can cause damage to structures. Using networks of ground-motion sensors and sophisticated computer algorithms, ShakeAlert can detect an earthquake seconds after it begins, calculate its location and magnitude, and estimate the resulting intensity of shaking. Early warnings of impending shaking are then sent to people and systems that may experience damaging shaking, allowing them to take appropriate protective actions. Depending on the user’s distance from the earthquake, alerts may be delivered before, during, or after the arrival of strong shaking. There will almost always be a region near the earthquake epicenter where alerts arrive after damaging shaking has begun. The ShakeAlert system updates its ground-motion estimates as an earthquake grows larger. In response to the FY 2022 congressional direction, the USGS worked with the State of Alaska to devise this implementation plan for ShakeAlert expansion to Alaska. The USGS engaged with the Alaska Division of Homeland Security and Emergency Management (DHS&EM) and the Alaska Division of Geological and Geophysical Surveys (DGGS). A cooperative agreement was awarded to the Alaska Earthquake Center (AEC) at the University of Alaska Fairbanks (UAF) for their contributions to the plan and their work coordinating with other networks in Alaska. The USGS engaged with the Alaska Seismic Hazards Safety Commission (ASHSC) throughout the process. The USGS also held a series of Alaska stakeholder engagements. The process of developing the implementation plan was facilitated by contracted staff from Corner Alliance, which is a government consulting firm. This implementation plan describes the details and estimates the costs for a Phase 1 expansion of the ShakeAlert system to Alaska. A geographically limited Phase 1 goal was chosen that covers the highest risk and most populated areas of Alaska. The areas proposed encompass the State’s main population centers and 90 percent of the State’s population. This Phase 1 design is considered very challenging and ambitious from the viewpoint of network operators. The lessons learned if this plan is implemented could be used to consider subsequent phases to expand EEW beyond Phase 1 in Alaska in the future. ShakeAlert is built on the foundation of the sensor networks and data processing infrastructure of the USGS-led Advanced National Seismic System (ANSS). This implementation plan calls for a total of 450 high-quality, real-time EEW-capable ANSS seismic stations in Alaska: 270 new stations, 160 upgraded stations, and 20 existing stations. These seismic station numbers are based on a station spacing of 10 kilometers (km) in urban areas, 20 km in seismic source areas that endanger population centers, and 40 km in other areas. The associated costs also include support for some EEW-capable global navigation satellite system (GNSS) stations, with a focus on improving warnings for large subduction zone earthquakes. For effective EEW, ShakeAlert requires low-latency, high-availability, robust telemetry links to deliver continuous, real-time data from field stations to the data centers. The Alaska data processing hardware infrastructure would follow the general design for fail-safe operation that is used for the ShakeAlert system on the West Coast. The ShakeAlert architecture uses two independent layers: the production layer for earthquake processing and the alert layer to make alerting decisions and serve alerts to users. This implementation plan includes two geographically separated data centers in Alaska, each with two fully independent production and alert layers using the same system design developed for the West Coast. As of March 2024, the ShakeAlert system is at version 3.0.1, with more advanced versions in the development and testing pipeline. ShakeAlert originally used two algorithms to determine the location and magnitude of earthquakes using seismic data. A third algorithm that can calculate very large magnitudes of very large earthquakes with geodetic data was added in March 2024. ShakeAlert publishes several data and alert products to meet the needs of different users. All messages include the location of the earthquake, either as a point or a line, and its magnitude. Ground-shaking estimates are published in two forms, as ground-motion contours and a map grid. Providing adequate warning time for strong shaking (the “target threshold”) requires sending alerts at a threshold lower than that strong shaking level (the “alert threshold”). The thresholds for public alerting in Alaska would be a joint USGS and State decision. To have the greatest benefit, ShakeAlert-powered alerts would be delivered to institutional users and individuals by all practical pathways. The USGS alert layer can support thousands of institutional users and alert redistributors, but the USGS does not have the mission nor the infrastructure and expertise to perform mass notifications to the public or implement automatic actions for end users of the alerts. To meet this need, ShakeAlert recruits private sector “technology enablers” that have the necessary expertise to develop end-user implementations using EEW alerts with the goal of stimulating an EEW industry. Earthquake early warning alerts are useless if people do not know how to respond to them. Although the alert messages include instructions about what to do (drop, cover, and hold on), alerts are more effective if people have been trained in advance. Messages about ShakeAlert’s capabilities, limitations, and benefits could be integrated with existing earthquake education programs, including State-run programs. Therefore, ShakeAlert would coordinate with both public and private partners and stakeholders through various partnerships and agreements to accomplish consistent and ongoing public earthquake hazard education. The estimated capital cost of completing the computing infrastructure and sensor networks for the Phase 1 ShakeAlert expansion to Alaska is approximately $66 million in 2024 dollars. The annual operation and maintenance cost of the completed system is estimated to be $12 million per year in 2024 dollars when fully built out.

Alaska

Tracing fluid evolution during batholith and deposit formation: In-situ and bulk rock Mo isotopes from the Questa porphyry Mo deposit, New Mexico, USA

The Oligocene Questa porphyry Mo deposit, located in New Mexico, USA, is a well-characterized system that formed over 400 kyr, punctuating the 8 Myr formation of the Questa-Latir batholith. Detailed sampling of the intrusions and minerals associated with magmatichydrothermal mineralization, as well as bookending barren intrusions, allows for examination of the Mo isotope record of the deposit and its host batholith. Through this established chronologic framework, such data can yield insights into the metallogenesis of deposit formation and long-term magma genesis evolution for upper crustal magmatism. The Mo isotopic compositions of barren intrusions yield a younging trend towards lighter δ 98 Mo. However, intrusions associated with Mo deposit formation yield heavier δ 98 Mo relative to barren magmatism, by up to 2.0‰. This indicates that they were affected by an isotopically heavy and Mo-rich fluid. The in-situ data from molybdenite covers the range observed in mineralized bulk rocks. However, individual samples consistently yield Mo isotopic variations of 0.4‰ to 0.5‰. The consistency of the δ 98 Mo variation in in-situ analyses of molybdenite within hand samples and individual mineral grains is likely the result of MoS 2 crystallization in a closed system and reflects an almost complete precipitation of Mo.

New Mexico

Global pegmatite-hosted lithium, cesium, and rubidium resources: A dataset for grade and tonnage modeling

Quantitative mineral resource assessments of potential undiscovered deposits can inform future mineral supply scenarios, but their accuracy is conditional on building robust grade and tonnage models of known deposits. This study presents an up-to-date global compilation and analysis of recently discovered and original, in-situ pegmatite-hosted Li, Cs, and Rb resources prior to historic production. Our analysis yields a median tonnage of 21.2 million tons (Mt) and grade of 1.12% Li 2 O, respectively, for global Li pegmatite deposits ( n = 73). The grades and tonnages of Li pegmatite resources vary depending on the age of the bedrock host domain, pegmatite crystallization age, and primary ore mineralogy. Lithium pegmatite resources hosted in Archean to transitional Archean-Paleoproterozoic domains have the largest median tonnage (29.8 Mt; n = 38), and those hosted in Paleoproterozoic to Mesoproterozoic domains have smaller median tonnages (6.5 Mt; n = 16). Cesium deposits where pollucite is the primary ore mineral have a bimodal grade distribution, with modes of 2.40 and 0.035 wt% Cs 2 O for high- and low-grade deposits, respectively, while Rb deposits are more unimodal with a median grade of 0.247 wt% Rb 2 O. Pegmatite-hosted Cs and Rb resources have median tonnages of 7.6 and 6.3 Mt, respectively. Covariation between ore mineralogy and the degree of crustal enrichment in pegmatite-hosted deposits is diagnostic of petrogenetic differences, including melt source characteristics, magma evolution, or variable degrees of volatile solubility. The Li pegmatite compilation is suitable for fitting robust numerical models to support quantitative assessments. More well-defined Rb and Cs pegmatite resources are required for quantitative assessments, but these data provide useful information about original in-place resources for framing supply discussions.

Ore Geology Reviews

Streamflow, ground-water recharge and discharge, and characteristics of surficial deposits in Buzzards Bay Basin, southeastern Massachusetts

Streamflow measurements at 14 low-flow partial-record stations and two discontinued streamflow-gaging stations were related to concurrent streamflows at six long-term streamflow-gaging stations to estimate streamflows at selected flow durations from 50 to 99 percent for water years 1967-91. At low flows, stream discharge per square mile generally increased with increasing percentage of subbasin underlain by stratified-drift deposits. At the 70-, 90-, and 99-percent flow durations, subbasins underlain primarily by stratified-drift deposits had stream discharges per square mile at least 2, 4, and 8 times greater, respectively, than subbasins underlain primarily by till and bedrock deposits. Streamflow measured three times at the Paskamanset River showed that streamflows downstream of municipal pumped wells increased at a lower rate per unit drainage area than streamflows upstream of the pumped wells. When pumpage from wells near the river was added to measured streamflow at the most downstream station, the sum was similar to the potential streamflow at the station if its streamflow per unit area was the same as that upstream from the pumped wells. Mean ground-water recharge and discharge rates were computed from continuous records of daily mean discharge during water years 1967-91 for six streamflow-gaging stations in southeastern Massachusetts and Rhode Island. Estimates of mean ground-water recharge were 19.7 to 22.6 inches per year for stations with drainage areas primarily underlain by till and bedrock deposits, and 23.8 to 25.2 inches per year for stations with drainage areas primarily underlain by stratified-drift deposits. During drought years, annual ground-water recharge can be less than 50 percent of the mean ground-water recharge rate for water years 1967-91. Estimates of ground-water discharge rates generally were 1 to 4 inches per year less than estimates of ground-water recharge rates. Ground-water discharge-duration curves were calculated from hydrograph separation of streamflow records at the six continuous streamflow-gaging stations for water years 1967-91. When streamflows were less than the median streamflow (50-percent duration), ground-water discharges averaged 85.7 percent of the total streamflow at the six streamflow-gaging stations. Ground-water discharges were estimated at the 14 low-flow partial-record stations and two discontinued streamflow-gaging stations by multiplying streamflows at the selected flow durations from 50 to 99 percent for water years 1967-91 by 85.7 percent. Data on surficial deposits in the basin were obtained by drilling 10 wells, by conducting 12 seismic-refraction surveys, and by collecting well log data for 313 wells from consulting firms and the Massachusetts Department of Environmental Management. These data indicated that a few minor corrections could be made to existing saturated thickness maps for stratified-drift deposits in Buzzards Bay Basin. Few well logs were detailed enough to estimate transmissivities; thus existing transmissivity maps were not updated for stratified-drift deposits in the basin.

Massachusetts

Stormflow chemistry in the Santa Ana River below Prado Dam and at the diversion downstream from Imperial Highway, southern California, 1995-98

The Santa Ana River drains about 2,670 square miles of the densely populated coastal area of southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted into ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. Stormflow in the Santa Ana River is considered a source of "high-quality" water suitable for use as a source of ground-water recharge. To test this assumption, stormflow samples were collected at two locations--below Prado Dam and at the diversion point downstream from Imperial Highway--for 12 winter storms between 1995 and 1998. Nitrate concentrations decreased during stormflow from a median concentration of 7.8 milligrams per liter in base flow to concentrations less than 1 milligram per liter in some large storms. Concentrations of chemically reduced forms of nitrogen (nitrite, ammonia, and organic nitrogen) increased during stormflow and are the predominant forms of nitrogen in large stormflows. Dissolved organic carbon (DOC) concentrations increased from a median concentration of 4.6 milligrams per liter in base flow to more than 20 milligrams per liter in some stormflows. Concentrations of DOC were especially high during the first storm of the rainy season, and large increases in DOC concentrations were measured even as a result of small early season storms that did not cause large increases in streamflow. DOC present during early season stormflow had less ultraviolet absorbance at 254 nanometers (UV 254 ) per unit of carbon than did DOC from late season stormflows. DOC in water held in storage behind Prado Dam had the highest UV 254 absorbance per unit of carbon. Maximum pesticide concentrations in stormflow did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels. Most pesticide concentrations were less than 1 microgram per liter and less than the detection limits obtained using standard drinking water analyses. Increases in concentrations of pesticides such as diazinon, malathion, and chlorpyrifos in stormflow result from runoff from urban areas downstream from Prado Dam. In general, large late season stormflows have the most pesticide detections of all stormflows sampled. Concentrations of methyl tert-butyl ether (MTBE), a gasoline additive, during base flow were as high as 0.9 microgram per liter and concentrations decreased during stormflow. Like pesticides, the concentrations did not exceed the U.S. Environmental Protection Agency Maximum Contaminant Levels for MTBE.

California

Leachate plumes in ground water from Babylon and Islip landfills, Long Island, New York

Landfills operated by the Towns of Babylon and Islip in southwest and central Suffolk County contain urban refuse, incinerated garbage, and scavenger (cesspool) waste; some industrial refuse is deposited at the Babylon site. The Islip landfill was started in 1933, the Babylon landfill in 1947. The landfills are in contact with and discharge leachate into the highly permeable upper glacial aquifer (hydraulic conducitvity 190 to 500 ft/d [feet per day]). The aquifer is 74 feet thick at the Babylon landfill and 170 feet thick at the Islip landfill. The leachate-enriched water occupies the entire thickness of the aquifer beneath both landfills, but hydrologic boundaries retard downward migration of the plumes to deeper aquifers. The Babylon plume is 1,900 feet wide at the landfill and narrows to about 700 feet near its terminus 10,000 feet from the landfill. The Islip plume is 1,400 feet wide at the landfill and narrows to 500 feet near its terminus 5,000 feet from the landfill. Hydrochemical maps and sections show the distribution of the major chemical constituents of the plumes. The most highly leachate-enriched ground water obtained was from the Babylon site; it contained 860 mg/L (milligrams per liter) sodium, 110 mg/L potassium, 565 mg/L calcium, 100 mg/L magnesium, 2,700 mg/L bicarbonate, and 1,300 mg/L chloride. Sulfate was notably absent or in low concentration in most parts of both plumes. Nitrogen in plume water was mostly in the form NH4+, and concentrations as high as 90 mg/L were found; concentrations of nitrogen as N in the plume were less than 10 mg/L. As much as 440 mg/L iron and 190 mg/L manganese were found in the leachate-enriched water. Samples were also tested for arsenic, boron, cadmium, cobalt, chromium, copper, mercury, nickel, lead, selenium, strontium, and zinc. Boron was more or less ubiquitous and was found in concentrations as high as 2 mg/L. Organic carbon was found in concentrations as high as 2,250 mg/L in the most highly leachate-enriched water but attenuated rapidly to less than 20 mg/L. Dissolved-solids concentrations near the landfills were between 400 and 3,000 mg/L at Babylon and between 500 and 1,500 mg/L at Islip. Ground-water temperatures near the landfills exceed those in ambient water by as much as 7°C at Babylon and 16°C at Islip. Heat contributed by the landfills was mostly dissipated within 0.4 mi of the landfill, butat Islip, the warm leachate-enriched water extended 0.5 mi downgradient. The entrance of leachate into the less dense ground water as pulsations after rainfall may explain the presence of high leachate enrichment near the bottom of the aquifer. A comparison of the physical characteristics of leachate-enriched ground water with those of ambient water suggests that the downward movement of leachate results from its greater density. Simulation of the movement and dispersion of the Babylon plume with a mathematical dispersion model indicated the coefficient of longitudinal dispersion to be about 60 ft 2 /d (feet squared per day) and the ground-water velocity to be 1 ft/d. However, the velocity determined from the hydraulic gradient and public-supply wells in the area was 4 ft/d, which would cause a plume four times as long as that predicted by the mathmatical dispersion model. At the Islip site, the plume was one-third the length calculated on the basis of the age of the landfill. The shortness of the plumes has not been explained; it may be a result of the leachate's having been too dilute to form a plume during the early years of the landfills.

New York