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Symposium on land erosion: Introduction

One of the very obvious geologic phenomena that is continuously in operation throughout the Earth's land surface is erosion , the process of wearing away the soil or the surface mantle. The falling of rain drops on an unprotected slope, the flow of water across land or in a channel, the borings of a rodent, the expansion of a root, the pull of gravity, the gouging of a glacier, or the impinging of wind on an open surface are some of the forces continually at work in this erosion process. The tendency of these forces is to bring everything to a common level and the moment a point of land or a continent rises above its surroundings, gravity, rain, wind, and all the other forces set to work, bringing it back to the level of its nieghbor. The poetic expression “the everlasting hills” is an illusion, for these erosion forces have been operative since the dawn of geologic history and the evidence is conclusive that in this sequence of time numerous generations of hills and mountain ranges have been uplifted and then razed by erosion , the waste and rock debris of one range forming the source material for its successor. We could not have the great deposits of alluvium and the thick beds of conglomerate, sandstones, and shales that occur at present throughout the Earth without erosion to furnish the source material.

Eos, Transactions, American Geophysical Union↗

How the geomagnetic field vector reverses polarity

A highly detailed record of both the direction and intensity of the Earth's magnetic field as it reverses has been obtained from a Miocene volcanic sequence. The transitional field is low in intensity and is typically non-axisymmetric. Geomagnetic impulses corresponding to astonishingly high rates of change of the field sometimes occur, suggesting that liquid velocity within the Earth's core increases during geomagnetic reversals. ?? 1985 Nature Publishing Group.

Nature↗

Liquid carbon dioxide of magmatic origin and its role in volcanic eruptions

Natural liquid carbon dioxide is produced commercially from a 2.5-km-deep well near the 4,500-yr-old maar volcano, Mount Gambier, South Australia. The carbon dioxide has accumulated in a dome that is located on the extension of a linear chain of volcanic activity. A magmatic origin for the fluid is suggested by the geological setting, δ 13 C PDB of –4.0‰, for the CO 2 (where PDB represents the carbon-isotope standard), and a relatively high 3 He component of the contained helium and high 3 He/C ratio (6.4 x 10 −10 ). The 3 He/ 4 He and He/Ne ratios are 3.0 and > 1,370 times those of air, respectively. The CO 2 , as collected at the Earth's surface at 29.5 °C and 75 bar, expands more than 300-fold to form a gas at 1 atm and 22 °C. We suggest that liquid CO 2 or high-density CO 2 fluid (the critical point is 31.1 °C, 73.9 bar) of volcanic origin that expands explosively from shallow levels in the Earth's crust may be a major contributor to 'phreatic' volcanic eruptions and maar formation. Less violent release of magmatic CO 2 into crater lakes may cause gas bursts with equally disastrous consequences such as occurred at Lake Nyos, Cameroon, in August 1986.

Nature↗

Degradation of trifluoroacetate in oxic and anoxic sediments

THE deleterious effect of chlorofluorocarbons on stratospheric ozone has led to international cooperation to end their use. The search for acceptable alternatives has focused on hydrofluorocarbons (HFCs) or hydrochlorofluorocarbons (HCFCs) which are attractive because they have relatively short atmospheric residence times. HFCs and HCFCs are attacked by tropospheric hydroxyl radicals, leading to the formation of trifluoroacetate (TFA). Most of the atmospheric TFA is deposited at the Earth's surface, where it is thought to be highly resistant to bacterial attack. Therefore, use of HCFCs and HFCs may lead to accumulation of TFA in soils, where it could prove toxic or inhibitory to plants and soil microbial communities. Although little is known about the toxicity of TFA, monofluoroacetate, which occurs at low levels in some plants and which is susceptible to slow attack by aerobic soil microbes, is known to be acutely toxic. Here we report that TFA can be rapidly degraded microbially under anoxic and oxic conditions. These results imply that significant microbial sinks exist in nature for the elimination of TFA from the environment. We also show that oxic degradation of TFA leads to the formation of fluoroform, a potential ozone-depleting compound with a much longer atmospheric lifetime than the parent compounds.The deleterious effect of chlorofluorcarbons on stratospheric ozone has led to international cooperation to end their use. The search for acceptable alternatives has focused on hydroflnorocarbons (HFCs) or hydrochloroflnorcarbons (HCFs) which are attractive because they have relatively short atmospheric residence times. HFCs and HCFs are attacked by tropospheric hydroxyl radicals, leading to the formation of trifluoroacetate (TFA). Most of the atmospheric TFA is deposited at the Earth's surface, where it is thought to be highly resistant to bacterial attack. Therefore, use of HCFs and HCFs may lead to accummulation of TFA in soils, where it could prove toxic or inhibitory to plants and soil microbial communities. Although little is known about the toxicity of TFA, monofluoracetate, which occurs at low levels in some plants and which is susceptible to slow attack by aerobic soil microbes, is known to be acutely toxic. Here we report that TFA can be rapidly degraded microbially under anoxic and oxic conditions. These results imply that significant microbial sinks exist in nature for the elimination of TFA from the environment. We also show that oxic degradation of TFA leads to the formation of fluoroform, a potential ozone-depleting compound with a much longer atmospheric lifetime than the parent compounds.

Nature↗

Seismic evidence for widespread western-US deep-crustal deformation caused by extension

Laboratory experiments have established that many of the materials comprising the Earth are strongly anisotropic in terms of seismic-wave speeds. Observations of azimuthal and radial anisotropy in the upper mantle are attributed to the lattice-preferred orientation of olivine caused by the shear strains associated with deformation, and provide some of the most direct evidence for deformation and flow within the Earths interior. Although observations of crustal radial anisotropy would improve our understanding of crustal deformation and flow patterns resulting from tectonic processes, large-scale observations have been limited to regions of particularly thick crust. Here we show that observations from ambient noise tomography in the western United States reveal strong deep (middle to lower)-crustal radial anisotropy that is confined mainly to the geological provinces that have undergone significant extension during the Cenozoic Era (since 65 Myr ago). The coincidence of crustal radial anisotropy with the extensional provinces of the western United States suggests that the radial anisotropy results from the lattice-preferred orientation of anisotropic crustal minerals caused by extensional deformation. These observations also provide support for the hypothesis that the deep crust within these regions has undergone widespread and relatively uniform strain in response to crustal thinning and extension. ?? 2010 Macmillan Publishers Limited. All rights reserved.

Nature↗

Prolonged magmatic activity on Mars inferred from the detection of felsic rocks

Rocks dominated by the silicate minerals quartz and feldspar are abundant in Earth’s upper continental crust. Yet felsic rocks have not been widely identified on Mars, a planet that seems to lack plate tectonics and the associated magmatic processes that can produce evolved siliceous melts on Earth. If Mars once had a feldspar-rich crust that crystallized from an early magma ocean such as that on the Moon, erosion, sedimentation and volcanism have erased any clear surface evidence for widespread felsic materials. Here we report near-infrared spectral evidence from the Compact Reconnaissance Imaging Spectrometer for Mars onboard the Mars Reconnaissance Orbiter for felsic rocks in three geographically disparate locations on Mars. Spectral characteristics resemble those of feldspar-rich lunar anorthosites, but are accompanied by secondary alteration products (clay minerals). Thermodynamic phase equilibrium calculations demonstrate that fractional crystallization of magma compositionally similar to volcanic flows near one of the detection sites can yield residual melts with compositions consistent with our observations. In addition to an origin by significant magma evolution, the presence of felsic materials could also be explained by feldspar enrichment by fluvial weathering processes. Our finding of felsic materials in several locations on Mars suggests that similar observations by the Curiosity rover in Gale crater may be more widely applicable across the planet.

Nature Geoscience↗

2019 M7.1 Ridgecrest earthquake slip distribution controlled by fault geometry inherited from Independence dike swarm

Faults often form through reactivation of pre-existing structures, developing geometries and mechanical properties specific to the system’s geologic inheritance. Competition between fault geometry and other factors (e.g., lithology) to control slip at Earth’s surface is an open question that is central to our knowledge of fault processes and seismic hazards. Here we use remote sensing data and field observations to investigate the origin of the 2019 M 7.1 Ridgecrest, California, earthquake rupture geometry and test its impact on the slip distribution observed at Earth’s surface. Common geometries suggest the fault system evolved through reactivation of structures within the surrounding Independence dike swarm (IDS). Mechanical models testing a range of fault geometries and stress fields indicate that the inherited rupture geometry strongly controlled the M 7.1 earthquake slip distribution. These results motivate revisiting the development of other large-magnitude earthquake ruptures (1992 M 7.3 Landers, 1999 M 7.1 Hector Mine) and tectonic provinces within the IDS.

California↗

Mechanics of near-field deformation during co- and post-seismic shallow fault slip

Poor knowledge of how faults slip and distribute deformation in the shallow crust hinders efforts to mitigate hazards where faults increasingly intersect with the expanding global population at Earth’s surface. Here we analyze two study sites along the 2014 M 6.0 South Napa, California, earthquake rupture, each dominated by either co- or post-seismic shallow fault slip. We combine mobile laser scanning (MLS), active-source seismic tomography, and finite element modeling to investigate how deformation rate and mechanical properties of the shallow crust affect fault behavior. Despite four orders-of-magnitude difference in the rupture velocities, MLS-derived shear strain fields are remarkably similar at the two sites and suggest deceleration of the co-seismic rupture near Earth’s surface. Constrained by the MLS and seismic data, finite element models indicate shallow faulting is more sensitive to lithologic layering and plastic yielding than to the presence of fault compliant zones (i.e., regions surrounding faults with reduced stiffness). Although both elastic and elastoplastic models can reproduce the observed surface displacement fields within the uncertainty of MLS data, elastoplastic models likely provide the most reliable representations of subsurface fault behavior, as they produce geologically reasonable stress states and are consistent with field, geodetic, and seismological observations.

California↗

Gas hydrates in sustainable chemistry

Gas hydrates have received considerable attention due to their important role in flow assurance for the oil and gas industry, their extensive natural occurrence on Earth and extraterrestrial planets, and their significant applications in sustainable technologies including but not limited to gas and energy storage, gas separation, and water desalination. Given not only their inherent structural flexibility depending on the type of guest gas molecules and formation conditions, but also the synthetic effects of a wide range of chemical additives on their properties, these variabilities could be exploited to optimise the role of gas hydrates. This includes increasing their industrial applications, understanding and utilising their role in Nature, identifying potential methods for safely extracting natural gases stored in naturally occurring hydrates within the Earth, and for developing green technologies. This review summarizes the different properties of gas hydrates as well as their formation and dissociation kinetics and then reviews the fast-growing literature reporting their role and applications in the aforementioned fields, mainly concentrating on advances during the last decade. Challenges, limitations, and future perspectives of each field are briefly discussed. The overall objective of this review is to provide readers with an extensive overview of gas hydrates that we hope will stimulate further work on this riveting field.

Chemical Society Reviews↗

Plumes, or plate tectonic processes?

Hotspots – large volcanic provinces – such as Iceland, Hawaii and Yellowstone, are almost universally assumed to come from plumes of hot mantle rising from deep within the Earth. At Iceland, perhaps the best-studied hotspot on Earth, this hypothesis is inconsistent with many first-order observations, such as the lack of high temperatures, a volcanic track or a seismic anomaly in the lower mantle. The great melt production there is explained better by enhanced fertility in the mantle where the mid-Atlantic spreading ridge crosses the Caledonian suture zone. The thick crust built by the excessive melt production encourages complex, unstable, leaky microplate tectonics, which provides positive feedback by enhancing volcanism further. Such a model explains Iceland as a natural consequence of relatively shallow processes related to plate tectonics, and accounts for all the first- and second-order geophysical, geological and geochemical observations at Iceland without special pleading or invoking coincidences.

Astronomy and Geophysics↗

Inversion of data from electrical resistivity imaging surveys in water-covered areas

Electrical resistivity imaging surveys widely used in many environmental and engineering studies have also been conducted in water-covered areas. Surveys in water-covered areas include conventional surveys using multi-electrode resistivity systems where part of the survey line crosses a river or stream, and surveys conducted entirely within a water-covered environment. Surveys that are located entirely within a water-covered environment utilise electrodes mounted on a streamer, towed behind a boat. The streamer can be dragged along the water bottom, or float on the water surface. In this paper, the smoothness-constrained least-squares inversion method commonly used to interpret electrical resistivity imaging data from land surveys is adapted for underwater surveys. To accommodate the water bottom topography, a distorted finite-element grid is used to calculate the apparent resistivity values for the inversion model. The first few rows of elements are used to model the water layer, while the lower part of the grid is used for the sub-bottom resistivity distribution. For robust inversion, the water column resistivity and geometry must be known accurately as a large proportion of the current flows through the water layer. The section of the Earth below the bottom surface is subdivided into a large number of rectangular cells. The water column resistivity and geometry in the earth model is fixed, and the inversion program attempts to determine the resistivity of the cells that would most accurately reproduce the observed resistivity measurements. Implementation of water column resistivity and geometric constraints is demonstrated using numerical simulations and field data. Examples of electrical resistivity imaging surveys conducted on and across water bodies including rivers and near-shore marine environments are shown.

Exploration Geophysics↗

Uranium redox transition pathways in acetate-amended sediments

Redox transitions of uranium [from U(VI) to U(IV)] in low-temperature sediments govern the mobility of uranium in the environment and the accumulation of uranium in ore bodies, and inform our understanding of Earth’s geochemical history. The molecular-scale mechanistic pathways of these transitions determine the U(IV) products formed, thus influencing uranium isotope fractionation, reoxidation, and transport in sediments. Studies that improve our understanding of these pathways have the potential to substantially advance process understanding across a number of earth sciences disciplines. Detailed mechanistic information regarding uranium redox transitions in field sediments is largely nonexistent, owing to the difficulty of directly observing molecular-scale processes in the subsurface and the compositional/physical complexity of subsurface systems. Here, we present results from an in situ study of uranium redox transitions occurring in aquifer sediments under sulfate-reducing conditions. Based on molecular-scale spectroscopic, pore-scale geochemical, and macroscale aqueous evidence, we propose a biotic–abiotic transition pathway in which biomass-hosted mackinawite (FeS) is an electron source to reduce U(VI) to U(IV), which subsequently reacts with biomass to produce monomeric U(IV) species. A species resembling nanoscale uraninite is also present, implying the operation of at least two redox transition pathways. The presence of multiple pathways in low-temperature sediments unifies apparently contrasting prior observations and helps to explain sustained uranium reduction under disparate biogeochemical conditions. These findings have direct implications for our understanding of uranium bioremediation, ore formation, and global geochemical processes.

PNAS↗

Spatially robust estimates of biological nitrogen (N) fixation imply substantial human alteration of the tropical N cycle

Biological nitrogen fixation (BNF) is the largest natural source of exogenous nitrogen (N) to unmanaged ecosystems and also the primary baseline against which anthropogenic changes to the N cycle are measured. Rates of BNF in tropical rainforest are thought to be among the highest on Earth, but they are notoriously difficult to quantify and are based on little empirical data. We adapted a sampling strategy from community ecology to generate spatial estimates of symbiotic and free-living BNF in secondary and primary forest sites that span a typical range of tropical forest legume abundance. Although total BNF was higher in secondary than primary forest, overall rates were roughly five times lower than previous estimates for the tropical forest biome. We found strong correlations between symbiotic BNF and legume abundance, but we also show that spatially free-living BNF often exceeds symbiotic inputs. Our results suggest that BNF in tropical forest has been overestimated, and our data are consistent with a recent top-down estimate of global BNF that implied but did not measure low tropical BNF rates. Finally, comparing tropical BNF within the historical area of tropical rainforest with current anthropogenic N inputs indicates that humans have already at least doubled reactive N inputs to the tropical forest biome, a far greater change than previously thought. Because N inputs are increasing faster in the tropics than anywhere on Earth, both the proportion and the effects of human N enrichment are likely to grow in the future.

Proceedings of the National Academy of Sciences of↗

Diffuse fluid flux through orogenic belts: Implications for the world ocean

Fifty years ago a classic paper by W. W. Rubey [(1951) Geol. Soc. Am. Bull. 62, 1111-1148] examined various hypotheses regarding the origin of sea water and concluded that the most likely hypothesis was volcanic outgassing, a view that was generally accepted by earth scientists for the next several decades. More recent work suggests that the rate of subduction of water is much larger than the volcanic outgassing rate, lending support to hypotheses that either ocean volume has decreased with time, or that the imbalance is offset by continuous replenishment of water by cometary impacts. These alternatives are required in the absence of additional mechanisms for the return of water from subducting lithosphere to the Earth's surface. Our recent work on crustal permebility suggests a large capacity for water upflow through tectonically active continental crust, resulting in a heretofore unrecognized degassing pathway that can accommodate the waer subduction rate. Escape of recycled water via delivery from the mantle through zones of active metamorphism eliminates the mass-balance argument for the loss of ocean volume or extraterestrial sources.

Proceedings of the National Academy of Sciences of↗

State shifts in the deep Critical Zone drive landscape evolution in volcanic terrains

Understanding the near-surface environment where atmospheric and solid earth processes interact, often termed the “Critical Zone,” is important for assessing resources and building resilient societies. Here, we examine a volcanic landscape in the Oregon Cascade Range, an understudied Critical Zone setting that is host to major regional water resources, pervasive silicate weathering, and significant geohazards. We leverage a bedrock age chronosequence to show that the volcanic Critical Zone undergoes a structural shift, from depth extents of >1 km to meters, over timescales of ~1 My. We map an active groundwater volume comparable to major continental lakes, stored at the Cascade Range crest. This state shift makes volcanic landscape evolution a unique probe of deep coupling between Earth systems.

PNAS↗

Pb-isotopic systematics of lunar highland rocks (>3.9 Ga): Constraints on early lunar evolution

The present lead (Pb)-isotopic database of over 200 analyses from nearly 90 samples of non-mare basalt, lunar highland rocks (>3.9 Ga) delineate at least three isotopically distinct signatures that in some combination can be interpreted to characterize the systematics of the entire database. Two are fairly new sets of lunar data and are typical of Pb data from other solar-system objects, describing nearly linear arrays slightly above the “geochron” values, with 207 Pb/ 206 Pb values <0.9. In aggregate, those data allow a relatively new interpretation of the Pb-isotopic evolution of the Moon, helping to identify and characterize a planetary evolutionary stage not preserved by Earth rocks. From the Pb-isotopic compositions, a source 238 U/ 204 Pb (μ) value can be calculated; differences in μ values from one Pb signature to another can have important implications on the age and evolution of Moon-forming events. In particular, the U/Pb ratio is one method of measuring the fractionation between refractory and volatile elements, an important indicator when considering large-scale planetary differentiation stages. The oldest Pb signature is represented solely by ferroan anorthosite 60025, presumably a piece of the early plagioclase-rich lunar crust produced from a magma ocean, and is characterized by source μ values between 35 and 100 at ~4.43 Ga. Another prominent and uniquely lunar Pb signature, identified more than 20 years ago, is representative of many ferroan anorthosites and most high-Mg suite rocks (particularly 15415, 62237, 76535, and 78235), and is characterized by extremely high 207 Pb/ 206 Pb values (∼1.45) that require extremely high source μ values (>500). Although the age and origin of this exotic Pb is not well constrained, it is interpreted to be related to the entrapment of incompatible-element-rich (U, Th) melts within the lunar upper mantle and crust between 4.36 and 4.46 Ga (urKREEP residuum?). The latest discovered Pb signature is found only in lunar meteorites and is characterized by relatively low source μ values between 10 and 50 at 3.9 Ga. The fact that most lunar crustal rocks (>3.9 Ga) exhibit high 207 Pb/ 206 Pb values requires that they were derived from, mixed with, or contaminated by Pb produced from early-formed, high-μ sources. The ubiquity of these U-Pb characteristics in the sample collection is probably an artifact of Apollo and Luna sampling sites, all located on the near side of the Moon, which was deeply excavated during the basin-forming event(s). However, the newest Pb-isotopic data support the idea that the Moon originally had a μ value of ~8 to 35, slightly elevated from Earth values, and that progressive U-Pb fractionations occurred within the Moon during later stages of differentiation between 4.36 and 4.46 Ga.

International Geology Review↗

Auroral omens of the American Civil War

Aurorae are a splendid night-time sight: coruscations of green, purple, and red fluorescent light in the form of gently wafting ribbons, billowing curtains, and flashing rays. Mostly seen at high latitudes, in the north aurorae are often called the northern lights or aurora borealis, and, in the south, the southern lights or aurora australis. The mystery of their cause has historically been the subject of wonder. The folklore and mythology of some far-northern civilizations attributed auroral light to celestial deities. And, in ironic contrast with their heavenly beauty, unusual auroral displays, such as those seen on rare occasions at lower southern latitudes, have sometimes been interpreted as portending unfavorable future events. Today we understand aurorae to be a visual manifestation of the dynamic conditions in the space environment surrounding the earth. Important direct evidence in support of this theory came on September 1, 1859. On that day, an English astronomer named Richard Carrington was situated at his telescope, which was pointed at the sun. While observing and sketching a large group of sunspots, he saw a solar flare—intense patches of white light that were superimposed upon the darker sunspot group and which were illuminated for about a minute. One day later, a magnetic storm was recorded at specially designed observatories in Europe, across Russia, and in India. By many measures, the amplitude of magnetic disturbance was the greatest ever recorded. In the United States, the effects of the Carrington storm could be seen as irregular backand-forth deflections of a few degrees in the magnetized needle of a compass. Rapid magnetic variation also induced electric fields in the earth’s conducting lithosphere, and interfered with the operation of telegraph systems. The Carrington magnetic storm, and an earlier storm that had occurred on August 28, 1859, caused spectacular displays of aurora borealis in the night-time sky over the entire United States and the western hemisphere, possibly all the way down to the equator. This was extremely unusual, so much so that an auroral event o

Weatherwise↗

Remote sensing of snow and ice

Monitoring of snow and ice on the Earth's surface will require increasing use of satellite remote sensing techniques. These techniques are evolving rapidly. Active and passive sensors operating in the visible, near infrared, thermal infrared, and microwave wavelengths are described in regard to general applications and in regard to specific USA or USSR satellites. Meteorological satellites (frequent images of relatively crude resolution) and Earth resources satellites such as Landsat (less frequent images of higher resolution) have been used to monitor the areal extent of seasonal snow, but problems exist with cloud cover or dense forest canopies. Snow mass (water equivalent) can be measured from a low-flying aircraft using natural radioactivity, but cannot yet be measured from satellite altitudes. A combination of active and passive microwave sensors may permit this kind of measurement, but not until more is known about radiation scattering in snow. Satellite observations are very useful in glacier inventories, correcting maps of glacier extent, estimating certain mass balance parameters, and monitoring calving or surging glaciers. Ground ice is virtually impossible to monitor from satellites; ice on rivers and lakes can be monitored only with very high-resolution sensors. Microwave sensors, due to their all-weather capability (the ability to see through clouds) provide exciting data on sea ice distribution. Analysis of digital tapes of satellite data requires the archiving and scanning of huge amounts of data. Simple methods for extracting quantitative data from satellite images are described.

Hydrological Sciences Bulletin↗