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USGS2018

Evaluation of the Source and Transport of High Nitrate Concentrations in Ground Water, Warren Subbasin, California

Ground water historically has been the sole source of water supply for the Town of Yucca Valley in the Warren subbasin of the Morongo ground-water basin, California. An imbalance between ground-water recharge and pumpage caused ground-water levels in the subbasin to decline by as much as 300 feet from the late 1940s through 1994. In response, the local water district, Hi-Desert Water District, instituted an artificial recharge program in February 1995 using imported surface water to replenish the ground water. The artificial recharge program resulted in water-level recoveries of as much as 250 feet in the vicinity of the recharge ponds between February 1995 and December 2001; however, nitrate concentrations in some wells also increased from a background concentration of 10 milligrams per liter to more than the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 44 milligrams per liter (10 milligrams per liter as nitrogen). The objectives of this study were to: (1) evaluate the sources of the high-nitrate concentrations that occurred after the start of the artificial-recharge program, (2) develop a ground-water flow and solute-transport model to better understand the source and transport of nitrates in the aquifer system, and (3) utilize the calibrated models to evaluate the possible effect of a proposed conjunctive-use project. These objectives were accomplished by collecting water-level and water-quality data for the subbasin and assessing changes that have occurred since artificial recharge began. Collected data were used to calibrate the ground-water flow and solute-transport models. Data collected for this study indicate that the areal extent of the water-bearing deposits is much smaller (about 5.5 square miles versus 19 square miles) than that of the subbasin. These water-bearing deposits are referred to in this report as the Warren ground-water basin. Faults separate the ground-water basin into five hydrogeologic units: the west, the midwest, the mideast, the east and the northeast hydrogeologic units. Water-quality analyses indicate that septage from septic tanks is the primary source of the high-nitrate concentrations measured in the Warren ground-water basin. Water-quality and stable-isotope data, collected after the start of the artificial recharge program, indicate that mixing occurs between imported water and native ground water, with the highest recorded nitrate concentrations in the midwest and the mideast hydrogeologic units. In general, the timing of the increase in measured nitrate concentrations in the midwest hydrogeologic unit is directly related to the distance of the monitoring well from a recharge site, indicating that the increase in nitrate concentrations is related to the artificial recharge program. Nitrate-to-chloride and nitrogen-isotope data indicate that septage is the source of the measured increase in nitrate concentrations in the midwest and the mideast hydrogeologic units. Samples from four wells in the Warren ground-water basin were analyzed for caffeine and selected human pharmaceutical products; these analyses suggest that septage is reaching the water table. There are two possible conceptual models that explain how high-nitrate septage reaches the water table: (1) the continued downward migration of septage through the unsaturated zone to the water table and (2) rising water levels, a result of the artificial recharge program, entraining septage in the unsaturated zone. The observations that nitrate concentrations increase in ground-water samples from wells soon after the start of the artificial recharge program in 1995 and that the largest increase in nitrate concentrations occur in the midwest and mideast hydrogeologic units where the largest increase in water levels occur indicate the validity of the second conceptual model (rising water levels). The potential nitrate concentration resulting from a water-level rise in the midwest and mideast hydrogeologic units was estimated using a simple mixing-cell model. The estimated value is within the range of concentrations measured in samples from wells, further indicating the validity of the second conceptual model. A ground-water flow model and a solute-transport model were developed for the Warren ground-water basin for the period 1956-2001. MODFLOW-96 was used for the ground-water flow model and MOC3D was used for the solute-transport model. The model cell size is about 500 feet by 500 feet and the models were discretized vertically into three layers. The models were calibrated using a trial-and-error approach using water-level and nitrate-concentration data collected between 1956-2001. In order to better match the measured data, low fault hydraulic characteristic values were required, thereby compartmentalizing the ground-water basin. In addition, it was necessary to parameterize the specific yield distribution for the top model layer where unconfined ground-water conditions occur into three homogeneous zones. Separate sets of specific- yield values were needed to simulate the drawdown and subsequent water-level recovery. In addition, the calibrated natural recharge was about 83 acre-feet per year. The entrainment of unsaturated-zone septage was simulated as recharge having an associated nitrate concentration. The volume of recharge was a function of the measured water-level rise between 1994-98 and the moisture content of the unsaturated zone. The nitrate concentration of the recharge water was a weighted function of the assumed nitrate concentration in the infiltrating water associated with the overlying land use. The simulated hydraulic head and nitrate concentration results were in good agreement with the measured data indicating that the mechanism for the increase in nitrate concentrations was rising water levels entraining high-nitrate septage in the unsaturated-zone. The calibrated models were used to simulate the possible effects of a planned conjunctive-use project in the western part of the ground-water basin. The simulated project included the addition of a new recharge pond and a new extraction well. In addition, recharge at two existing recharge ponds was increased and three existing production wells were pumped, treated in a nitrate-removal facility, and used for water supply. The simulated hydraulic heads increased in the west, the mideast, and parts of the east hydrogeologic units; however, the simulated hydraulic heads decreased in the midwest and northeast hydrogeologic units. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter (10 milligrams per liter as nitrogen) in parts of the west as a result of the increase in simulated hydraulic head. The simulated nitrate concentrations decreased in part of the midwest hydrogeologic unit as a result of the artificial recharge and pumping from the nitrate-removal wells. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter in part of the mideast and parts of the east hydrogeologic units beneath commercial land-use areas.

California↗
USGS2003

Geologic framework and hydrogeologic characteristics of the Edwards aquifer, Uvalde County, Texas

The Edwards aquifer in Uvalde County is composed of Lower Cretaceous carbonate (mostly dolomitic limestone) strata of the Devils River Formation in the Devils River trend and of the West Nueces, McKnight, and Salmon Peak Formations in the Maverick basin. Rocks in the Devils River trend are divided at the bottom of the Devils River Formation into the (informal) basal nodular unit. Maverick basin rocks are divided (informally) into the basal nodular unit of the West Nueces Formation; into lower, middle, and upper units of the McKnight Formation; and into lower and upper units of the Salmon Peak Formation. The Edwards aquifer overlies the (Lower Cretaceous) Glen Rose Limestone, which composes the lower confining unit of the Edwards aquifer. The Edwards aquifer is overlain by the (Upper Cretaceous) Del Rio Clay, the basal formation of the upper confining unit. Upper Cretaceous and (or) Lower Tertiary igneous rocks intrude all stratigraphic units that compose the Edwards aquifer, particularly in the southern part of the study area. The Balcones fault zone and the Uvalde salient are the principal structural features in the study area. The fault zone comprises mostly en echelon, high-angle, and down-to-the-southeast normal faults that trend mostly from southwest to northeast. The Uvalde salient—resulting apparently from a combination of crustal uplift, diverse faulting, and igneous activity—elevates the Edwards aquifer to the surface across the central part of Uvalde County. Downfaulted blocks associated with six primary faults—Cooks, Black Mountain, Blue Mountain, Uvalde, Agape, and Connor—juxtapose the Salmon Peak Formation (Lower Cretaceous) in central parts of the study area against Upper Cretaceous strata in the southeastern part. The carbonate rocks of the Devils River trend and the Maverick basin are products of assorted tectonic and depositional conditions that affected the depth and circulation of the Cretaceous seas. The Devils River Formation formed in a fringing carbonate bank—the Devils River trend— in mostly open shallow marine environments of relatively high wave and current energy. The West Nueces, McKnight, and Salmon Peak Formations resulted mostly from partly restricted to open marine, tidal-flat, and restricted deep-basinal environments in the Maverick basin. The porosity of the Edwards aquifer results from depositional and diagenetic effects along specific lithostratigraphic horizons (fabric selective) and from structural and solutional features that can occur in any lithostratigraphic horizon (non-fabric selective). In addition to porosity depending upon the effects of fracturing and the dissolution of chemically unstable (soluble) minerals and fossils, the resultant permeability depends on the size, shape, and distribution of the porosity as well as the interconnection among the pores. Upper parts of the Devils River Formation and the upper unit of the Salmon Peak Formation compose some of the most porous and permeable rocks in Uvalde County.

Texas↗
USGS2003

Water quality and the effects of changes in phosphorus loading to Muskellunge Lake, Vilas County, Wisconsin

Muskellunge Lake is a productive, eutrophic lake because of high nutrient loading. Historical data indicate that water quality has only slightly degraded since the early 1970s, possibly because of phosphorus input from effluent from septic systems. A detailed phosphorus budget for the lake indicated that most of the phosphorus comes from natural sources?ground water and surface water flowing through relatively undeveloped areas surrounding the lake. Modeling results indicated that the natural input of phosphorus was sufficient to maintain the lake's eutrophic condition. Analysis of sediment cores confirmed that only small changes in nutrient and algal concentrations have occurred over the past 100 years; however, the analysis indicated that the macrophyte community has increased over this time period. The aeration system, installed to alleviate winter anoxia, maintains aerobic conditions throughout the main bays of the lake.

Wisconsin↗
USGS2003

Water-quality trends in New England rivers during the 20th century

Water-quality data from the Merrimack, Blackstone, and Connecticut Rivers in New England during parts of the 20th century were examined for trends in concentrations of sulfate, chloride, residue upon evaporation, nitrate, and total phosphorus. The concentrations of all five of these constituents show statistically significant trends during the century. Annual concentrations of sulfate and total phosphorus decreased during the second half of the century, whereas annual concentrations of nitrate, chloride, and residues increased throughout the century. In the Merrimack River, annual chloride concentrations increased by an order of magnitude. Annual nitrate concentrations also increased by an order of magnitude in the Merrimack and Connecticut Rivers. These changes in the water quality probably are related to changing human activities. Most notable is the relation between increasing use of road de-icing salts and chloride concentrations in rivers. In addition, changes in concentrations of nitrate and phosphorus probably are related to agricultural use of nitrogen and phosphorus fertilizers. For all the water-quality constituents assessed, concentrations were greatest in the Blackstone River. The Blackstone River Basin is smaller and more highly urbanized than the other basins studied. Data-collection programs that span multiple decades can provide valuable insight on the effects of changing human population and societal activities on the water quality of rivers. This study was done as part of the U.S. Geological Survey's National Water-Quality Assessment Program.

Water-Resources Investigations Report↗
USGS2003

Sediment quantity and quality in three impoundments in Massachusetts

As part of a study with an overriding goal of providing information that would assist State and Federal agencies in developing screening protocols for managing sediments impounded behind dams that are potential candidates for removal, the U.S Geological Survey determined sediment quantity and quality at three locations: one on the French River and two on Yokum Brook, a tributary to the west branch of the Westfield River. Data collected with a global positioning system, a geographic information system, and sediment-thickness data aided in the creation of sediment maps and the calculation of sediment volumes at Perryville Pond on the French River in Webster, Massachusetts, and at the Silk Mill and Ballou Dams on Yokum Brook in Becket, Massachusetts. From these data the following sediment volumes were determined: Perryville Pond, 71,000 cubic yards, Silk Mill, 1,600 cubic yards, and Ballou, 800 cubic yards. Sediment characteristics were assessed in terms of grain size and concentrations of potentially hazardous organic compounds and metals. Assessment of the approaches and methods used at study sites indicated that ground-penetrating radar produced data that were extremely difficult and time-consuming to interpret for the three study sites. Because of these difficulties, a steel probe was ultimately used to determine sediment depth and extent for inclusion in the sediment maps. Use of these methods showed that, where sampling sites were accessible, a machine-driven coring device would be preferable to the physically exhausting, manual sediment-coring methods used in this investigation. Enzyme-linked immunosorbent assays were an effective tool for screening large numbers of samples for a range of organic contaminant compounds. An example calculation of the number of samples needed to characterize mean concentrations of contaminants indicated that the number of samples collected for most analytes was adequate; however, additional analyses for lead, copper, silver, arsenic, total petroleum hydrocarbons, and chlordane are needed to meet the criteria determined from the calculations. Particle-size analysis did not reveal a clear spatial distribution pattern at Perryville Pond. On average, less than 65 percent of each sample was greater in size than very fine sand. The sample with the highest percentage of clay-sized particles (24.3 percent) was collected just upstream from the dam and generally had the highest concentrations of contaminants determined here. In contrast, more than 90 percent of the sediment samples in the Becket impoundments had grain sizes larger than very fine sand; as determined by direct observation, rocks, cobbles, and boulders constituted a substantial amount of the material impounded at Becket. In general, the highest percentages of the finest particles, clays, occurred in association with the highest concentrations of contaminants. Enzyme-linked immunosorbent assays of the Perryville samples showed the widespread presence of petroleum hydrocarbons (16 out of 26 samples), polycyclic aromatic hydrocarbons (23 out of 26 samples), and chlordane (18 out of 26 samples); polychlorinated biphenyls were detected in five samples from four locations. Neither petroleum hydrocarbons nor polychlorinated biphenyls were detected at Becket, and chlordane was detected in only one sample. All 14 Becket samples contained polycyclic aromatic hydrocarbons. Replicate quality-control analyses revealed consistent results between paired samples. Samples from throughout Perryville Pond contained a number of metals at potentially toxic concentrations. These metals included arsenic, cadmium, copper, lead, nickel, and zinc. At Becket, no metals were found in elevated concentrations. In general, most of the concentrations of organic compounds and metals detected in Perryville Pond exceeded standards for benthic organisms, but only rarely exceeded standards for human contact. The most highly contaminated samples were

Water-Resources Investigations Report↗
USGS2003

Development of regional curves of bankfull-channel geometry and discharge for streams in the non-urban, Piedmont Physiographic Province, Pennsylvania and Maryland

Stream-restoration projects utilizing natural stream designs frequently are based on the bankfull-channel characteristics of stream reaches that can accommodate streamflow and sediment transport without excessive erosion or deposition and lie within a watershed that has similar runoff characteristics. The bankfull channel at an ungaged impaired site or reference reach is identified by use of field indicators and is confirmed with tools such as regional curves. Channel dimensions were surveyed at 14 streamflow-measurement stations operated by the U.S. Geological Survey (USGS) in the Gettysburg-Newark Lowland Section, Piedmont Lowland Section, and the Piedmont Upland Section of the Piedmont Physiographic Province in Pennsylvania and Maryland. From the surveyed channel dimensions, regional curves were developed from regression analyses of the relations between drainage area and the cross-sectional area, mean depth, width, and streamflow of the bankfull channel at these sites. Bankfull cross-sectional area and bankfull discharge have the strongest relation to drainage area as evidenced by R 2 values of 0.94 and 0.93, respectively. The relation between bankfull crosssectional area and drainage area has a p-value of less than 0.001; no p-value is presented for the relation between bankfull discharge and drainage area because of a non-normal residual distribution. The relation between bankfull width and drainage area has an R 2 value of 0.80 and a p-value of less than 0.001 indicating a moderate linear relation between all stations. The relation between bankfull mean depth and drainage area, with an R 2 value of 0.72 and a p-value of less than 0.001, also indicates a moderate linear relation between all stations. The concept of regional curves can be a valuable tool to support efforts in stream restoration. Practitioners of stream restoration need to recognize it as such and realize the limitations. The small number of USGS streamflow-measurement stations available for analysis is a major limiting factor in the strength of the results of this investigation, as is the inherent problem of directly associating streamflow-measurement station data to geomorphic analysis of a stream reach. Subjective selection criteria may have unnecessarily eliminated streamflow-measurement stations that could have been included in the regional curves and (or) added those that may belong within a different region. A bankfull discharge with a recurrence interval within the 1- to 2-year range commonly is used as a criterion for the confirmation of the bankfull stage at each streamflow-measurement station. Many researchers accept this range for recurrence interval of the bankfull discharge; however, literature provides contradictory evidence.

Maryland, Pennsylvania↗
USGS2003

Detection and measurement of land subsidence using interferometric synthetic aperture radar and Global Positioning System, San Bernardino County, Mojave Desert, California

Land subsidence associated with ground-water-level declines has been recognized as a potential problem in parts of the Mojave Desert, California. Ground water has been the primary source of domestic, agricultural, and municipal water supplies in the desert since the early 1900s. Pumping of ground water from the Mojave River and Morongo ground-water basins in the southwestern Mojave Desert resulted in water-level declines of more than 30 meters (100 feet) between the 1950s and the 1990s. A Global Positioning System (GPS) survey of a geodetic network was used to determine the location, extent, and magnitude of vertical land-surface changes in Lucerne Valley in the Morongo ground-water basin. The GPS survey was conducted in 1998 to estimate historical elevation changes by comparing GPS-derived elevations with historical elevations (which were available for some of the monuments in the network as early as 1944) and to establish baseline values that can be used for comparisons with future GPS surveys. The GPS measurements indicated that about 600 millimeters (2 feet) [plus or minus 1,500 millimeters (5 feet)] of subsidence occurred at three of the monuments between 1969 and 1998 but that very little to no vertical change in position occurred at seven other monuments in the network. Water levels in the area of subsidence in Lucerne Valley declined about 15 meters (50 feet) during 1970-98. Interferometric synthetic aperture radar (InSAR) methods were used to characterize vertical land-surface changes in the Mojave River and Morongo ground-water basins during various intervals of time between 1992 and 1999. Interferograms, InSAR-generated displacement maps, show that subsidence ranging from 45 to 90 mm (0.15 to 0.3 ft) occurred in four areas of these two ground-water basins--the El Mirage, Lockhart-Harper Lake (dry), Newberry Springs, and Lucerne Valley areas. Some of the InSAR measurements were affected by the earthquakes at Landers and Hector Mine, California, and by atmospheric artifacts. Water-level data were examined for areas undergoing vertical land-surface changes to determine whether the vertical land-surface changes may be related to aquifer-system compaction caused by ground-water-level changes. Temporally relevant water-level data were sparse for some areas, particularly the El Mirage and Lockhart-Harper Lake (dry) areas. Water levels in wells proximate to the subsiding areas generally declined between 1992 and 1999; water levels in some wells proximate to the subsiding areas experienced seasonal periods of declines and recoveries.

California↗
USGS2003

Simulation of ground-water flow and land subsidence in the Antelope Valley ground-water basin, California

Antelope Valley, California, is a topographically closed basin in the western part of the Mojave Desert, about 50 miles northeast of Los Angeles. The Antelope Valley ground-water basin is about 940 square miles and is separated from the northern part of Antelope Valley by faults and low-lying hills. Prior to 1972, ground water provided more than 90 percent of the total water supply in the valley; since 1972, it has provided between 50 and 90 percent. Most ground-water pumping in the valley occurs in the Antelope Valley ground-water basin, which includes the rapidly growing cities of Lancaster and Palmdale. Ground-water-level declines of more than 200 feet in some parts of the ground-water basin have resulted in an increase in pumping lifts, reduced well efficiency, and land subsidence of more than 6 feet in some areas. Future urban growth and limits on the supply of imported water may continue to increase reliance on ground water. To better understand the ground-water flow system and to develop a tool to aid in effectively managing the water resources, a numerical model of ground-water flow and land subsidence in the Antelope Valley ground-water basin was developed using old and new geohydrologic information. The ground-water flow system consists of three aquifers: the upper, middle, and lower aquifers. The aquifers, which were identified on the basis of the hydrologic properties, age, and depth of the unconsolidated deposits, consist of gravel, sand, silt, and clay alluvial deposits and clay and silty clay lacustrine deposits. Prior to ground-water development in the valley, recharge was primarily the infiltration of runoff from the surrounding mountains. Ground water flowed from the recharge areas to discharge areas around the playas where it discharged either from the aquifer system as evapotranspiration or from springs. Partial barriers to horizontal ground-water flow, such as faults, have been identified in the ground-water basin. Water-level declines owing to ground-water development have eliminated the natural sources of discharge, and pumping for agricultural and urban uses have become the primary source of discharge from the ground-water system. Infiltration of return flows from agricultural irrigation has become an important source of recharge to the aquifer system. The ground-water flow model of the basin was discretized horizontally into a grid of 43 rows and 60 columns of square cells 1 mile on a side, and vertically into three layers representing the upper, middle, and lower aquifers. Faults that were thought to act as horizontal-flow barriers were simulated in the model. The model was calibrated to simulate steady-state conditions, represented by 1915 water levels and transient-state conditions during 1915-95 using water-level and subsidence data. Initial estimates of the aquifer-system properties and stresses were obtained from a previously published numerical model of the Antelope Valley ground-water basin; estimates also were obtained from recently collected hydrologic data and from results of simulations of ground-water flow and land subsidence models of the Edwards Air Force Base area. Some of these initial estimates were modified during model calibration. Ground-water pumpage for agriculture was estimated on the basis of irrigated crop acreage and crop consumptive-use data. Pumpage for public supply, which is metered, was compiled and entered into a database used for this study. Estimated annual pumpage peaked at 395,000 acre-feet (acre-ft) in 1952 and then declined because of declining agricultural production. Recharge from irrigation-return flows was estimated to be 30 percent of agricultural pumpage; the irrigation-return flows were simulated as recharge to the regional water table 10 years following application at land surface. The annual quantity of natural recharge initially was based on estimates from previous studies. During model calibration, natural recharge was reduced from the initial

Water-Resources Investigations Report↗
USGS2003

Reactive-transport simulation of phosphorus in the sewage plume at the Massachusetts Military Reservation, Cape Cod, Massachusetts

The subsurface transport of phosphorus introduced by the disposal of treated sewage effluent to ground-infiltration disposal beds at the Massachusetts Military Reservation on western Cape Cod was simulated with a three-dimensional reactive-transport model. The simulations were used to estimate the load of phosphorus transported to Ashumet Pond during operation of the sewage-treatment plant from 1936 to 1995 and for 60 years following cessation of sewage disposal. The model accounted for spatial and temporal changes in water discharge from the sewage-treatment plant, ground-water flow, transport of associated chemical constituents, and a set of chemical reactions, including phosphorus sorption on aquifer materials, dissolution and precipitation of iron- and manganese-oxyhydroxide and iron phosphate minerals, organic carbon sorption and decomposition, cation sorption, and irreversible denitrification. The flow and transport in the aquifer were simulated by using parameters consistent with those used in previous flow models of this area of Cape Cod, except that numerical dispersion was much larger than the physical dispersion estimated in previous studies. Sorption parameters were fit to data derived from phosphorus sorption and desorption laboratory column experiments. Rates of organic carbon decomposition were adjusted to match the location of iron concentrations in an anoxic iron zone within the sewage plume. The sensitivity of the simulated load of phosphorus transported to Ashumet Pond was calculated for a variety of processes and input parameters. Model limitations included large uncertainties associated with the loading of the sewage beds, the flow system, and the chemistry and sorption characteristics in the aquifer. The results of current model simulations indicate a small load of phosphorus transported to Ashumet Pond during 1965-85, but this small load was particularly sensitive to model parameters that specify flow conditions and the chemical process by which non-desorbable phosphorus is incorporated in the sediments. The uncertainties were large enough to make it difficult to determine whether loads of phosphorus transported to Ashumet Pond in the 1990s were greater or less than loads during the previous two decades. The model simulations indicate substantial discharge of phosphorus to Ashumet Pond after about 1965. After the period 2000-10 the simulations indicate that the load of phosphorus transported to Ashumet Pond decreases continuously, but the load of phosphorus remains substantial for many decades. The current simulations indicate a peak in phosphorus discharge to Ashumet Pond of about 1,000 kilograms per year during the 1990s; however, comparisons of simulated phosphorus concentrations with measured concentrations in 1993 indicate that the peak in phosphorus load transported to Ashumet Pond may be larger and moving more quickly in the model simulations than in the aquifer. The results of the three-dimensional reactive-transport simulations are consistent with the loading history, experimental laboratory data, and field measurements. The results of the simulations adequately reproduce the spatial distribution of phosphorus concentrations measured in 1993, the magnitude of changes in phosphorus concentration with time in a profile near the disposal beds following cessation of sewage disposal, the observed iron zone in the sewage plume, the approximate flow of treated sewage effluent into Ashumet Valley, and laboratory-column data for phosphorus sorption and desorption.

Massachusetts↗
USGS2003

A new cation-exchange method for accurate field speciation of hexavalent chromium

A new cation-exchange method for field speciation of Cr(VI) has been developed to meet present stringent regulatory standards and to overcome the limitations of existing methods. The new method allows measurement of Cr(VI) concentrations as low as 0.05 micrograms per liter, storage of samples for at least several weeks prior to analysis, and use of readily available analytical instrumentation. The sensitivity, accuracy, and precision of the determination in waters over the pH range of 2 to 11 and Fe concentrations up to 1 milligram per liter are equal to or better than existing methods such as USEPA method 218.6. Time stability of preserved samples is a significant advantage over the 24-hour time constraint specified for USEPA method 218.6.

Water-Resources Investigations Report↗
USGS2003

Determination of specific yield and water-table changes using temporal microgravity surveys collected during the second injection, storage, and recovery test at Lancaster, Antelope Valley, California, November 1996 through April 1997

To evaluate the feasibility of artificially recharging the ground-water system in the Lancaster area of the Antelope Valley, California, the U.S. Geological Survey, in cooperation with the Los Angeles County Department of Public Works and the Antelope Valley-East Kern Water Agency, conducted a series of injection, storage, and recovery tests between September 1995 and September 1998. A key component of this study was to measure the response of the water table to injection, which was difficult because the water table averaged 300 feet below land surface. Rather than install many expensive piezometers, microgravity surveys were conducted to determine specific yield and to measure the development of a ground-water mound during the injection of about 1,050 acre-feet of fresh water into an alluvial-aquifer system. The surveys were done prior to, during, and near the end of a 5-month injection period (November 12, 1996, to April 17, 1997). Results of the surveys indicate increases in gravity of as much as 66 microgals between a bedrock reference station and 20 gravity stations within a 1-square-mile area surrounding the injection site. The changes were assumed to have been caused by changes in the ground-water elevation. Gravity and ground-water levels were measured simultaneously at an existing well (7N/12W-34B1). The coupled measurements were used to calculate a specific yield of 0.13 for the alluvial aquifer near the well. To determine the gravitational effect of the injection mound on the gravity measurements made near well 7N/12W-34B1, a two-dimensional gravity model was used. Results of the model simulation show that the effect on gravity associated with the mass of the injection mound was minor and thus had a negligible effect on the calculation of specific yield. The specific yield of 0.13, therefore, was used to infer water-level changes at other gravity stations within the study area. The gravity-derived water-level changes were compared with simulated water-table changes.

Water-Resources Investigations Report↗
USGS2003

Characterization of instream hydraulic and riparian habitat conditions and stream temperatures of the Upper White River Basin, Washington, using multispectral imaging systems

Instream hydraulic and riparian habitat conditions and stream temperatures were characterized for selected stream segments in the Upper White River Basin, Washington. An aerial multispectral imaging system used digital cameras to photograph the stream segments across multiple wavelengths to characterize fish habitat and temperature conditions. All imageries were georeferenced. Fish habitat features were photographed at a resolution of 0.5 meter and temperature imageries were photographed at a 1.0-meter resolution. The digital multispectral imageries were classified using commercially available software. Aerial photographs were taken on September 21, 1999. Field habitat data were collected from August 23 to October 12, 1999, to evaluate the measurement accuracy and effectiveness of the multispectral imaging in determining the extent of the instream habitat variables. Fish habitat types assessed by this method were the abundance of instream hydraulic features such as pool and riffle habitats, turbulent and non-turbulent habitats, riparian composition, the abundance of large woody debris in the stream and riparian zone, and stream temperatures. Factors such as the abundance of instream woody debris, the location and frequency of pools, and stream temperatures generally are known to have a significant impact on salmon. Instream woody debris creates the habitat complexity necessary to maintain a diverse and healthy salmon population. The abundance of pools is indicative of a stream's ability to support fish and other aquatic organisms. Changes in water temperature can affect aquatic organisms by altering metabolic rates and oxygen requirements, altering their sensitivity to toxic materials and affecting their ability to avoid predators. The specific objectives of this project were to evaluate the use of an aerial multispectral imaging system to accurately identify instream hydraulic features and surface-water temperatures in the Upper White River Basin, to use the multispectral system to help establish baseline instream/riparian habitat conditions in the study area, and to qualitatively assess the imaging system for possible use in other Puget Sound rivers. For the most part, all multispectral imagery-based estimates of total instream riffle and pool area were less than field measurements. The imagery-based estimates for riffle habitat area ranged from 35.5 to 83.3 percent less than field measurements. Pool habitat estimates ranged from 139.3 percent greater than field measurements to 94.0 percent less than field measurements. Multispectral imagery-based estimates of turbulent habitat conditions ranged from 9.3 percent greater than field measurements to 81.6 percent less than field measurements. Multispectral imagery-based estimates of non-turbulent habitat conditions ranged from 27.7 to 74.1 percent less than field measurements. The absolute average percentage of difference between field and imagery-based habitat type areas was less for the turbulent and non-turbulent habitat type categories than for pools and riffles. The estimate of woody debris by multispectral imaging was substantially different than field measurements; percentage of differences ranged from +373.1 to -100 percent. Although the total area of riffles, pools, and turbulent and non-turbulent habitat types measured in the field were all substantially higher than those estimated from the multispectral imagery, the percentage of composition of each habitat type was not substantially different between the imagery-based estimates and field measurements.

Water-Resources Investigations Report↗
USGS2003

A stream-gaging network analysis for the 7-day, 10-year annual low flow in New Hampshire streams

The 7-day, 10-year (7Q10) low-flow-frequency statistic is a widely used measure of surface-water availability in New Hampshire. Regression equations and basin-characteristic digital data sets were developed to help water-resource managers determine surface-water resources during periods of low flow in New Hampshire streams. These regression equations and data sets were developed to estimate streamflow statistics for the annual and seasonal low-flow-frequency, and period-of-record and seasonal period-of-record flow durations. generalized-least-squares (GLS) regression methods were used to develop the annual 7Q10 low-flow-frequency regression equation from 60 continuous-record stream-gaging stations in New Hampshire and in neighboring States. In the regression equation, the dependent variables were the annual 7Q10 flows at the 60 stream-gaging stations. The independent (or predictor) variables were objectively selected characteristics of the drainage basins that contribute flow to those stations. In contrast to ordinary-least-squares (OLS) regression analysis, GLS-developed estimating equations account for differences in length of record and spatial correlations among the flow-frequency statistics at the various stations. A total of 93 measurable drainage-basin characteristics were candidate independent variables. On the basis of several statistical parameters that were used to evaluate which combination of basin characteristics contribute the most to the predictive power of the equations, three drainage-basin characteristics were determined to be statistically significant predictors of the annual 7Q10: (1) total drainage area, (2) mean summer stream-gaging station precipitation from 1961 to 90, and (3) average mean annual basinwide temperature from 1961 to 1990. To evaluate the effectiveness of the stream-gaging network in providing regional streamflow data for the annual 7Q10, the computer program GLSNET (generalized-least-squares NETwork) was used to analyze the network by application of GLS regression between streamflow and the climatic and basin characteristics of the drainage basin upstream from each stream-gaging station. Improvement to the predictive ability of the regression equations developed for the network analyses is measured by the reduction in the average sampling-error variance, and can be achieved by collecting additional streamflow data at existing stations. The predictive ability of the regression equations is enhanced even further with the addition of new stations to the network. Continued data collection at unregulated stream-gaging stations with less than 14 years of record resulted in the greatest cost-weighted reduction to the average sampling-error variance of the annual 7Q10 regional regression equation. The addition of new stations in basins with underrepresented values for the independent variables of the total drainage area, average mean annual basinwide temperature, or mean summer stream-gaging station precipitation in the annual 7Q10 regression equation yielded a much greater cost-weighted reduction to the average sampling-error variance than when more data were collected at existing unregulated stations. To maximize the regional information obtained from the stream-gaging network for the annual 7Q10, ranking of the streamflow data can be used to determine whether an active station should be continued or if a new or discontinued station should be activated for streamflow data collection. Thus, this network analysis can help determine the costs and benefits of continuing the operation of a particular station or activating a new station at another location to predict the 7Q10 at ungaged stream reaches. The decision to discontinue an existing station or activate a new station, however, must also consider its contribution to other water-resource analyses such as flood management, water quality, or trends in land use or climatic change.

Water-Resources Investigations Report↗
USGS2003

Overview of water resources in and near Wichita and Affiliated Tribes treaty lands in western Oklahoma

This report is an overview of water resources in and near the Wichita and Affiliated Tribes treaty lands in western Oklahoma. The tribal treaty lands are about 1,140 square miles and are bordered by the Canadian River on the north, the Washita River on the south, 98? west longitude on the east, and 98? 40' west longitude on the west. Seventy percent of the study area lies within the Washita River drainage basin and 30 percent of the area lies within the Canadian River drainage basin. March through June are months of greatest average streamflow, with 49 to 57 percent of the annual streamflow occurring in these four months. November through February, July, and August have the least average streamflow with only 26 to 36 percent of the annual streamflow occurring in these six months. Two streamflow-gaging stations, Canadian River at Bridgeport and Cobb Creek near Fort Cobb, indicated peak streamflows generally decrease with regulation. Two other streamflow-gaging stations, Washita River at Carnegie and Washita River at Anadarko, indicated a decrease in peak streamflows after regulation at less than the 100-year recurrence and an increase in peak streamflows greater than the 100-year recurrence. Canadian River at Bridgeport and Washita River at Carnegie had estimated annual low flows that generally increased with regulation. Cobb Creek near Fort Cobb had a decrease of estimated annual low flows after regulation. There are greater than 900 ground-water wells in the tribal treaty lands. Eighty percent of the wells are in Caddo County.The major aquifers in the study area are the Rush Springs Aquifer and portions of the Canadian River and Washita River valley alluvial aquifers. The Rush Springs Aquifer is used extensively for irrigation as well as industrial and municipal purposes, especially near population centers.The Canadian River and Washita River valley alluvial aquifers are not used extensively in the study area. Well yields from the Rush Springs Aquifer ranged from 11 to greater than 850 gallons per minute. The Rush Springs Aquifer is recharged by the infiltration of precipitation. The estimated recharge is about 1.80 inches per year evenly distributed over the outcrop of the aquifer in the study area. Principal factors affecting the water quality in the study area include geology, agricultural practices,and oil and gas production. Calcium, magnesium, sulfate, and bicarbonate are the dominant dissolved constituents in water in the study area. Interquartile dissolved-solids concentrations in surface-water samples in the study area generally were greater than interquartile concentrations in ground-water samples. Median dissolved-solids concentrations for ground-water samples from Canadian River, Ionine Creek, Spring Creek,and Washita River Basins, which ranged from 535 to 1,195 milligrams per liter,exceeded the U.S. Environmental Protection Agency Secondary Drinking Water Standard of 500 milligrams per liter. Interquartile sulfate concentrations in surface-water samples in the study area generally were greater than interquartile concentrations in ground-water samples. Median sulfate concentrations from ground-water samples in the Canadian River, IonineCreek,and Spring Creek Basins, which ranged from 385 to 570 milligrams per liter, exceeded the U.S. Environmental Protection Agency Secondary Drinking Water Standard of 250 milligrams per liter. Nitrite plus nitrate as nitrogen concentrations in surface-water samples in the study area generally were less than concentrations in ground-water samples. The median nitrite plus nitrate as nitrogen concentration in ground water was 9.8 milligrams per liter, suggesting almost one-half the ground-water samples exceeded the U.S. Environmental Protection Agency Primary Drinking Water Standard (10 milligrams per liter). An estimated 100 million gallons of water per day were withdrawn from surface and ground water for all uses in

Water-Resources Investigations Report↗
USGS2003

Sediment deposition and occurrence of selected nutrients, other chemical constituents, and diatoms in bottom sediment, Perry Lake, northeast Kansas, 1969–2001

A combination of bathymetric surveying and bottom-sediment coring was used to investigate sediment deposition and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 26 metals and trace elements, 15 organochlorine compounds, 1 radionuclide, and diatoms in bottom sediment of Perry Lake, northeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1969 through 2001 in the original conservation-pool area of the lake was 2,470 million cubic feet (56,700 acre-feet) and 97,200 million pounds (44,100 million kilograms), respectively. The estimated sediment volume occupied about 23 percent of the original conservation-pool, water-storage capacity of the lake. Mean annual net sediment deposition since 1969 was estimated to be 3,040 million pounds (1,379 million kilograms). Mean annual sediment yield from the Perry Lake Basin was estimated to be 2,740,000 pounds per square mile (4,798 kilograms per hectare). The estimated mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Perry Lake were 7,610,000 pounds per year (3,450,000 kilograms per year) and 3,350,000 pounds per year (1,520,000 kilograms per year), respectively. The estimated mean annual yields of total nitrogen and total phosphorus from the Perry Lake Basin were 6,850 pounds per square mile per year (12.0 kilograms per hectare per year) and 3,020 pounds per square mile per year (5.29 kilograms per hectare per year), respectively. A statistically significant positive trend for total nitrogen deposition in the bottom sediment of Perry Lake was indicated. However, the trend may be due solely to analytical variance. No statistically significant trend for total phosphorus deposition was indicated. Overall, the transport and deposition of these constituents have been relatively uniform throughout the history of Perry Lake. On the basis of nonenforceable sediment-quality guidelines established by the U.S. Environmental Protection Agency, concentrations of arsenic, chromium, copper, and nickel in the bottom sediment of Perry Lake typically exceeded the threshold-effects levels, which represent the concentrations above which toxic biological effects occasionally occur. Most nickel concentrations also exceeded the probable-effects level, which represents the concentration above which toxic biological effects usually or frequently occur. Sediment concentrations of metals and trace elements were relatively uniform over time. Statistically significant positive depositional trends for arsenic and manganese and statistically significant negative depositional trends for beryllium, chromium, titanium, and vanadium were indicated. However, the trends may be due solely to analytical variance. Organochlorine compounds either were not detected or were detected at concentrations less than the threshold-effects levels. Evidence of a negative depositional trend for DDE (degradation product of DDT) was consistent with the history of DDT use. Other organochlorine compounds detected were DDD and dieldrin. Diatom occurrence in the bottom sediment of Perry Lake was dominated by species that are indicators of eutrophic (nutrient-rich) conditions. Thus, it was concluded that eutrophic conditions have existed during much of the history of Perry Lake. However, an increase in the relative percentage abundance of the oligotrophic (nutrient-poor) species, combined with the significant positive depositional trends for two oligotrophic species ( Aulacoseira islandica and Cyclotella radiosa ) and the significant negative depositional trend for one eutrophic species ( Stephanodiscus niagarae ), indicated that conditions in Perry Lake may have become less eutrophic in recent years. Notable changes in human activity within the basin included a substantial decrease in alfalfa production and a substantial increase in soybean production from 1965 to 2000. These and other changes in human activity may have had some effect on the deposition of chemical constituents and diatoms in the bottom sediment of Perry Lake. It is uncertain whether changes in human activity may account, in part, for the possibility of Perry Lake becoming less eutrophic over time as indicated by trends in the deposition of several diatom species in the lake-bed sediment.

Kansas↗
USGS2003

Concentrations and loads of suspended sediment and nutrients in surface water of the Yakima River basin, Washington, 1999-2000 [electronic resource] : with an analysis of trends in concentrations

Spatial and temporal variations in concentrations and loads of suspended sediment and nutrients in surface water of the Yakima River Basin were assessed using data collected during 1999?2000 as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program. Samples were collected at 34 sites located throughout the Basin in August 1999 using a Lagrangian sampling design, and also were collected weekly and monthly from May 1999 through January 2000 at three of the sites. Nutrient and sediment data collected at various time intervals from 1973 through 2001 by the USGS, Bureau of Reclamation, Washington State Department of Ecology, and Roza-Sunnyside Board of Joint Control were used to assess trends in concentrations. During irrigation season (mid-March to mid-October), concentrations of suspended sediment and nutrients in the Yakima River increase as relatively pristine water from the forested headwaters moves downstream and mixes with discharges from streams, agricultural drains, and wastewater treatment plants. Concentrations of nutrients also depend partly on the proportions of mixing between river water and discharges: in years of ample water supply in headwater reservoirs, more water is released during irrigation season and there is more dilution of nutrients discharged to the river downstream. For example, streamflow from river mile (RM) 103.7 to RM 72 in August 1999 exceeded streamflow in July 1988 by a factor of almost 2.5, but loads of total nitrogen and phosphorus discharged to the reach from streams, drains, and wastewater treatment plants were only 1.2 and 1.1 times larger. In years of ample water supply, canal water, which is diverted from either the Yakima or Naches River, makes up more of the flow in drains and streams carrying agricultural return flows. The canal water dilutes nutrients (especially nitrate) transported to the drains and streams in runoff from fields and in discharges from subsurface field drains and the shallow ground-water system. The average concentration of total nitrogen in drains and streams discharging to the Yakima River from RM 103.7 to RM 72 in August 1999 was 2.63 mg/L, and in July 1988 was 3.16 mg/L; average concentrations of total phosphorus were 0.20 and 0.26 mg/L. After irrigation season, streamflow in agricultural drains decreases because irrigation water is no longer diverted from the Yakima and Naches Rivers. As a result, concentrations of total nitrogen in drains increase because nitrate, which constitutes much of total nitrogen, continues to enter the drains from subsurface drains and shallow ground water. Concentrations of total phosphorus and suspended sediment often decrease, because they are transported to the drains in runoff of irrigation water from fields. In Granger Drain, concentrations of total nitrogen ranged from 2-4 mg/L during irrigation season and increased to about 6 mg/L after irrigation season, and concentrations of total phosphorus, as high as 1 mg/L, decreased to about 0.2 mg/L. In calendar year 1999, Moxee Drain transported an average of 28,000 lb/d (pounds per day) of suspended sediment, 380 lb/d of total nitrogen, and 46 lb/d of total phosphorus to the Yakima River. These loads were about half the average loads transported by Granger Drain during the same period. Average streamflows were similar for the two drains, so the difference in loads was due to differences in constituent concentrations: those in Moxee Drain were about 40-60 percent less than those in Granger Drain. Loads of suspended sediment and total phosphorus in Moxee and Granger Drains were nearly four times higher during irrigation season than during the non-irrigation season because with increased flow during irrigation season, concentrations of suspended sediment and total phosphorus are usually higher. Loads of nitrate in the drains were about the same in both seasons because nitrate concentrations are higher during the non-irrigation season.

Water-Resources Investigations Report↗
USGS2003

External quality-assurance results for the National Atmospheric Deposition Program/National Trends Network, 1997-99

Five external quality-assurance programs were operated by the U.S. Geological Survey for the National Atmospheric Deposition Program/ National Trends Network (NADP/NTN) during 1997 through 1999: the intersite-comparison program, the blind-audit program, the field- audit program, the interlaboratory-comparison program, and the collocated-sampler program. The intersite-comparison program assesses the accuracy of pH and specific-conductance determinations made by NADP/NTN site operators. In two 1997 intersite-comparison studies, 83.7 and 85.8 percent of the pH determinations met the NADP/NTN accuracy goals, whereas 97.3 and 92.4 percent of the specific-conductance determinations met the NADP/NTN accuracy goals. The percentage of pH and specific-conductance determinations that met the accuracy goals in 1998 were, for the most part, higher than in 1997. In two 1998 studies, 90.9 and 90.3 percent of the pH determinations met the accuracy goals compared to 94.7 and 96.0 percent of the specific- conductance measurements meeting the accuracy goals. In one 1999 intersite-comparison study, 89.5 percent and 99.4 percent of pH and specific- conductance determinations, respectively, met the NADP/NTN accuracy goals. The blind-audit program evaluates the effects of routine sample handling, processing, and shipping on the analytical bias and precision of weekly precipitation samples. A portion of the blind-audit sample subject to the normal onsite handling and processing of a weekly precipitation sample is referred to as the bucket portion, whereas the portion receiving only minimal handling is referred to as the bottle portion. Positive bias in regard to blind-audit results indicates that the bucket portion has a higher concentration than the bottle portion. The paired t-test for the 1997 through 1999 blind- audit data indicates that routine sample handling, processing, and shipping introduced a positive bias (a=0.05) for calcium and chloride and a negative bias (cz=0.05) for hydrogen ion. During 1997 through 1999, the median paired differences between the bucket and bottle portions ranged from 0.00 milligram per liter for nitrate and ammonium to +0.010 milligram per liter for both chloride and sulfate. The median paired difference between the bucket and bottle portions for hydrogen ion was -1.086 microequivalents per liter, whereas for specific conductance, the median paired difference between the bucket and bottle portions was -0.200 microsiemen per centimeter during 1997 through 1999. Surface-chemistry effects due to variable amounts of precipitation contacting prewashed sample-collection and shipping-container surfaces were studied in the blind-audit program by using three different sample volumes. The sample- collection and shipping containers used for the blind-audit study were obtained from the site operator's supply and could have been used for precipitation samples. Results of a Kruskal-Wallis analysis of variance test of the relation between paired blind-audit sample differences in units of concentration and sample volume were statistically significant for magnesium, chloride, sulfate, and hydrogen ion during 1997 through 1999. Before 1994, at least 5 of the 10 analytes displayed a statistically significant difference between paired blind-audit differences in units of concentration and sample volume, supporting the premise that chemical reactions between the 13-liter bucket shipping container (primarily the butadiene o-ring lid of the shipping container) and the sample, which resulted in an increasing loss of hydrogen ion with increasing volume, have been eliminated by the new l-liter bottle sample- shipping protocol. The field-audit program measures the effects of field exposure, handling, and processing on the chemistry of NADP/NTN precipitation samples. In the field-audit program, the site operator is instructed to process and submit a quality- control sample following a standard 7-day, Tuesday-to-Tuesday sampling period with no

Water-Resources Investigations Report↗