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Ground-water quality in Wisconsin through 1972

Ground water, a plentiful and largely underdeveloped resource of Wisconsin, has good to excellent chemical quality in most places. This resource is readily available in most parts of the State for municipal, industrial, and rural uses. In 1970, about 0.5 billion gallons of ground water a day was pumped in Wisconsin for all uses (Murray and Reeves, 1972). In addition, underground reservoirs discharge an average of 16 billion gallons per day of water of relatively constant temperature and uniform quality, which maintains the base flow of streams and the level of lakes (Holt, 1964).

Wisconsin↗

Atrazine and metolachlor occurrence in shallow ground water of the United States, 1993 to 1995: Relations to explanatory factors

Since 1991, the U.S. Geological Survey has been conducting the National Water Quality Assessment (NAWQA) Program to determine the quality of the Nation's water resources. In an effort to obtain a better understanding of why pesticides are found in shallow ground water on a national scale, a set of factors likely to affect the fate and transport of two herbicides in the subsurface were examined. Atrazine and metolachlor were selected for this discussion because they were among the most frequently detected pesticides in ground water during the first phase of the NAWQA Program (1993 to 1995), and each was the most frequently detected compound in its chemical class (triazines and acetanilides, respectively). The factors that most strongly correlated with the frequencies of atrazine detection in shallow ground-water networks were those that provided either: (1) an indication of the potential susceptibility of ground water to atrazine contamination, or (2) an indication of relative ground-water age. The factors most closely related to the frequencies of metolachlor detection in ground water, however, were those that estimated or indicated the intensity of the agricultural use of metolachlor. This difference is probably the result of detailed use estimates for these compounds being available only for agricultural settings. While atrazine use is relatively extensive in nonagricultural settings, in addition to its widespread agricultural use, metolachlor is used almost exclusively for agricultural purposes. As a result, estimates of agricultural applications provide a less reliable indication of total chemical use for atrazine than for metolachlor. A multivariate analysis demonstrated that the factors of interest explained about 50 percent of the variance in atrazine and metolachlor detection frequencies among the NAWQA land-use studies examined. The inclusion of other factors related to pesticide fate and transport in ground water, or improvements in the quality and accuracy of the data employed for the factors examined, may help explain more of the remaining variance in the frequencies of atrazine and metolachlor detection.

Journal of the American Water Resources Associatio↗

Effects of urban storm-runoff control on ground-water recharge in Nassau County, New York

Before urban development, most ground-water recharge on Long Island, New York, occurred during the dormant season, when evapotranspiration is low. The use of recharge basins for collection and disposal of urban storm runoff in Nassau County has enabled ground-water recharge to occur also during the growing season. In contrast, the use of storm sewers to route storm runoff to streams and coastal waters has resulted in a decrease in ground-water recharge during the dormant season. The net result of these two forms of urban storm-runoff control has been an increase in annual recharge of about 12 percent in areas served by recharge basins and a decrease of about 10 percent in areas where storm runoff is routed to streams and tidewater. On a countywide basis, annual ground-water recharge has remained nearly the same as under predevelopment conditions, but its distribution pattern has changed. Redistribution resulted in increased recharge in the eastern and central parts of the county, and decreased recharge in the western and nearshore areas. Model simulation of recharge indicates that the water-table altitude has increased by as much as 5 ft above predevelopment levels in areas served by recharge basins and declined by as much as 3 feet in areas where stormwater is discharged to streams and tidewater.

Groundwater↗

Assessment of severity and distribution of corrosive ground water in Pennsylvania

Relations between corrosive ground water, water chemistry, and geology in Pennsylvania were evaluated by use of a modified version of the Langelier Saturation Index (LSIsn) and a geologic contact dataset in a Geographic Information System. Water-chemistry information for water samples collected from 4,839 combined private and public-supply wells from 1900 to 1993 was used to calculate the LSIsn. Thirty-eight lithologic subgroups within four major rock types-carbonate, siliciclastic, crystalline, and unconsolidated-in Pennsylvania were grouped together if the mean of ranked LSIsn values were not significantly different. A water is considered corrosive if the LSIsn value is negative, preventing the precipitation of calcium carbonate, therefore, allowing corrosive reactions with the interior of piping systems. Statistical tests of the LSIsn values show the least corrosive waters are in the carbonate lithologic subgroup, and the most corrosive waters are in the quartzite lithologic subgroup. Approximately 58 percent of the 4,839 LSIsn values were considered moderately to extremely corrosive. A map showing the location of 4,839 wells and associated corrosivity range within 11 lithologic subgroups will aid in identifying potential areas of corrosive ground water in Pennsylvania.

Open-File Report↗

Hydrogeology and simulation of ground-water flow at the South Well Field, Columbus, Ohio

The City of Columbus, Ohio, operates four radial collector wells in southern Franklin County. The 'South Well Field' is completed in permeable outwash and ice-contact deposits, upon which flow the Scioto River and Big Walnut Creek. The wells are designed to yield approximately 42 million gallons per day; part of that yield results from induced infiltration of surface water from the Scioto River and Big Walnut Creek. The well field supplied up to 30 percent of the water supply of southern Columbus and its suburbs in 1991. This report describes the hydrogeology of southern Franklin County and a tran sient three-dimensional, numerical ground-water- flow model of the South Well Field. The primary source of ground water in the study area is the glacial drift aquifer. The glacial drift is composed of sand, gravel, and clay depos ited during the Illinoian and Wisconsinan glaciations. In general, thick deposits of till containing lenses of sand and gravel dominate the drift in the area west of the Scioto River. The thickest and most productive parts of the glacial drift aquifer are in the buried valleys in the central and eastern parts of the study area underlying the Scioto River and Big Walnut Creek. Horizontal hydraulic conductivity of the glacial drift aquifer differs spa tially and ranges from 30 to 375 feet per day. The specific yield ranges from 0.12 to 0.30. The secondary source of ground water within the study area is the underlying carbonate bedrock aquifer, which consists of Silurian and Devonian limestones, dolomites, and shales. The horizontal hydraulic conductivity of the carbonate bedrock aquifer ranges from 10 to 15 feet per day. The storage coefficient is about 0.0002. The ground-water-flow system in the South Well Field area is recharged by precipitation, regional ground-water flow, and induced stream infiltration. Yearly recharge rates varied spatially and ranged from 4.0 to 12.0 inches. The three-dimensional, ground-water-flow model was constructed by use of the U.S. Geological Survey three-dimensional finite-difference ground-water-flow code. Recharge, boundary flux, and river leakage are the principal sources of water to the flow system. The study area is bounded on the north and south by streamlines, with flow entering the area from the east and west. Areal recharge is contributed throughout the study area, although a comparatively high percentage of precipitation reaches the water table in the area east of the Scioto River where little surface drain age exists. Ground-water flow is downward in the uplands of the Scioto River, and upward near the river in the glacial drift and carbonate bedrock aquifers. The numerical model contains 53 rows, 45 columns, and 3 layers. The uppermost two layers represent the glacial drift. The bottom layer represents the carbonate bedrock. The horizontal model grid is variably spaced to account for differences in available data and to simulate heads accurately in specific areas of interest. The length and width of grid cells range from 200 to 2,000 feet; the finer spacings are designed to increase detail in the areas near the collector wells. The model uses 7,155 active nodes. Measurements of water levels from October 1979 were used to represent steady-state conditions before municipal pumping at the well field began. Measurements made during March 1986 were used to represent steady-state conditions after commencement of pumping at the well field. Water levels measured during March 1986 - June 1991 were used for calibration targets in the transient simulations. The transient model was discretized into eight stress periods of 93 to 487 days on the basis of recharge, well-field pumpage, and available water-level data. Transient model calibration was based on seven sets of hydraulic-head measure ments made during March 1986 - June 1991. This time period includes large-scale increases in well- field production associated with a drought in the summer of 1988, an

Water-Resources Investigations Report↗

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [ 18 O/ 16 O (δ 18 O), 2 H/ 1 H (δD), 13 C/ 12 C (δ 13 C), tritium ( 3 H), and strontium‐87/strontium‐86 ( 87 Sr/ 86 Sr)] along with geochemical mass‐balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (δ 18 O and <δD) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass‐balance calculations, based on differences in δ 18 O and δD, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18 O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, δ 13 C and 87 Sr/ 86 Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post‐ 1950s concentrations of 3 H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.

Ground Water↗

Ground-water quality data for Oklahoma, 1981

The U.S. Geological Survey has collected data on Oklahoma's ground-water resources since 1934. Most of these data were collected as part of specific ground-water studies conducted in cooperation with various Federal, State, and local agencies. Ground-water quality data, as well as data on construction, yield, water levels, and other physical well parameters collected prior to 1981 are available from the U.S. Geological Survey, Oklahoma District Office. Although water-quality data for wells, test holes, and springs have been published, they are scattered though a variety of reports and are not readily available on a statewide basis. The purpose of this report is to make available, annually, all of the ground-water quality data collected by the U.S. Geological Survey in the Sate of Oklahoma. This report contains ground-water quality data collected in 1981 from 524 sites in 15 counties, predominately in eastern Oklahoma.

Open-File Report↗

Simulated effects of impoundment of lake seminole on ground-water flow in the upper Floridan Aquifer in southwestern Georgia and adjacent parts of Alabama and Florida

Hydrologic implications of the impoundment of Lake Seminole in southwest Georgia and its effect on components of the surface- and ground-water flow systems of the lower Apalachicola?Chattahoochee?Flint (ACF) River Basin were investigated using a ground-water model. Comparison of simulation results of postimpoundment drought conditions (October 1986) with results of hypothetical preimpoundment conditions (a similar drought prior to 1955) provides a qualitative measure of the changes in hydraulic head and ground-water flow to and from streams and Lake Seminole, and across State lines caused by the impoundment. Based on the simulation results, the impoundment of Lake Seminole changed ground-water flow directions within about 20?30 miles of the lake, reducing the amount of ground water flowing from Florida to Georgia southeast of the lake. Ground-water storage was increased by the impoundment, as indicated by a simulated increase of as much as 26 feet in the water level in the Upper Floridan aquifer. The impoundment of Lake Seminole caused changes to simulated components of the ground-water budget, including reduced discharge from the Upper Floridan aquifer to streams (315 million gallons per day); reduced recharge from or increased discharge to regional ground-water flow at external model boundaries (totaling 183 million gallons per day); and reduced recharge from or increased discharge to the undifferentiated overburden (totaling 129 million gallons per day).

Alabama, Florida, Georgia↗

Ground-water levels and directions of flow in the vicinity of a well field, Elkhart, Indiana, December 1989

Water levels were measured in 51 observation wells in the vicinity of the Elkhart Water Works Main Street well field during 5 days of normal pumping at the well field and little or no recharge to the ground water from precipitation. Water levels were measured once each day during December 18-22, 1989. Water-level altitudes were plotted and contoured on maps to determine the distribution of ground-water levels and directions of flow in the unconfined sand and gravel aquifer tapped by the well field. Measured ground-water levels ranged from about 7.5 to 30 feet below land surface. Ground-water levels were highest north and northwest of the Main Street well field and lowest at the Main Street well field and near the St. Joseph River. Regional ground-water flow is toward the south or southeast. Ground-water levels near the river are higher than the river stage, indicating that ground water discharges to the river. As a result of pumping, three cones of depression have formed in the water table in the mapped area. A small cone of depression northwest of the Main Street well field is caused by industrial pumping. Two cones of depression have formed at the Main Street well field-one in the eastern part of the well field and one in the western part of the well field. Horizontal hydraulic gradients are variable in the study area but are largest in the eastern part of the Main Street well field and near the St. Joseph River. In general, water levels measured in seven sets of paired wells do not indicate a vertical hydraulic gradient; however, a downward gradient was measured in one set of paired wells near a pumped area at the Main Street well field.

Indiana↗

Pesticides in surface and ground water of the San Joaquin-Tulare basins, California: Analysis of available data, 1966 Through 1992

Available pesticide data (1966-92) for surface and ground water were analyzed for the San Joaquin-Tulare Basins, California, one of 60 large hydrologic systems being studied as part of the National Water-Quality Assessment Program of the U.S. Geological Survey. Most of the pesticide data were for the San Joaquin Valley, one of the most intensively farmed and irrigated areas of the United States. Data were obtained from the Storage and Retrieval data base of the U.S. Environmental Protection Agency, the water-quality data base of the U.S. Geological Survey, and from data files of State agencies. Pesticides detected in surface water include organochlorine pesticides, organophosphate pesticides, carbamate pesticides, and triazine herbicides. Pesticides detected in ground water include triazine and other organonitrogen herbicides and soil fumi gants. Surface-water data indicate seasonal patterns for the detection of organophosphate and carbamate pesticides, which are attributed to their use on almond orchards and alfafa fields. Organochlorine pesticides were detected primarily in river-bed sediments. Concentrations detected in bed sediments of the San Joaquin River near Vernalis are among the highest of any major river system in the United States. Patterns and timing of pesticide use indicate that pesticides might be present in surface-water systems during most months of a year. The most commonly detected pesticide in ground water is the soil fumigant, dibromochloropropane. Dibromochloropropane, used primarily on vineyards and orchards, was detected in ground water near the city of Fresno. Triazine and other organonitrogen herbicides were detected near vineyards and orchards in the same general locations as the detections of dibromochloropropane. Pesticides were detected in ground water of the east side of the valley floor, where the soils are sandy or coarsegrained, and water-soluble pesticides with long environmental half-lives were used. In contrast, fewer pesticides were detected in ground water of the west side of the valley, where soils generally are finer grained.

California↗

Technology Transfer Opportunities: Automated Ground-Water Monitoring, A Proven Technology

Introduction The U.S. Geological Survey (USGS) has developed and tested an automated ground-water monitoring system that measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automated ground-water monitoring systems can be used to monitor known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, to serve as early warning systems monitoring ground-water quality near public water-supply wells, and for ground-water quality research.

Fact Sheet↗

Geochemical patterns of arsenic-enriched ground water in fractured, crystalline bedrock, Northport, Maine, USA

High mean As concentrations of up to 26.6 ??mol/L (1990 ??g/L) occur in ground water collected from a fractured-bedrock system composed of sulfidic schist with granitic to dioritic intrusions. Sulfides in the bedrock are the primary source of the As in the ground water, but the presence of arsenopyrite in rock core retrieved from a borehole with As concentrations in the ground water barely above the detection limit of 2.0 ??mol/L, shows that there are complicating factors. Chemical analyses of water from 35 bedrock wells throughout a small watershed reveal spatial clustering of wells with high As concentrations. Stiff diagrams and box plots distinguish three distinct types; calcium-bicarbonate-dominated water with low As concentrations (CaHCO 3 type), sodium-bicarbonate-dominated water with moderately high As concentrations (NaHCO3 type), and calcium-bicarbonate-dominated water with very high As concentrations (High-As type). It is proposed that differences in recharge area and ground-water evolution, and possible bedrock composition difference are responsible for the chemical distinctions within the watershed. Lack of correlation of As concentrations with pH indicates that desorption of As is an insignificant control on As concentration. Correlations of As concentrations with Fe and redox parameters indicates that reductive dissolution of Fe(III) oxyhydroxides may play a role in the occurrence of high As concentrations in the NaHCO3 and High-As type water. The oxidation of sulfide minerals occurs within the ground-water system and is ultimately responsible for the existence of As in the ground water, but there is no correlation between As and SO4 concentrations, probably due to precipitation of Fe(III) oxyhydroxides and adsorption of As under oxidizing conditions. Crown Copyright ?? 2006 Published by Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

Ground-water hydrology and simulated effects of development in the Milford area, an arid basin in southwestern Utah

A three-dimensional, finite-difference model was constructed to simulate ground-water flow in the Milford area. The purpose of the study was to evaluate present knowledge and concepts of the groundwater system, to analyze the ability of the model to represent past and current (1984) conditions, and to estimate the effects of various groundwater development alternatives. The alternative patterns of groundwater development might prove effective in capturing natural discharge from the basin-fill aquifer while limiting water-level declines. Water levels measured during this study indicate that ground water in the Milford area flows in a northwesterly direction through consolidated rocks in the northern San Francisco Mountains toward Sevier Lake. The revised potentiometric surface shows a large area for probable basin outflow, indicating that more water leaves the Milford area than the 8 acre-feet per year estimated previously. Simulations made to calibrate the model were able to approximate steady-state conditions for 1927, before ground-water development began, and transient conditions for 1950-82, during which groundwater withdrawal increased. Basin recharge from the consolidated rocks and basin outflow were calculated during the calibration process. Transient simulations using constant and variable recharge from surface water were made to test effects of large flows in the Beaver River. Simulations were made to project water-level declines over a 37- year period (1983-2020) using the present pumping distribution. Ground-water withdrawals were simulated at 1, 1.5, and 2 times the 1979-82 average rate. The concepts of "sustained" yield, ground-water mining, and the capture of natural discharge were tested using several hypothetical pumping distributions over a 600-year simulation period. Simulations using concentrated pumping centers were the least efficient at capturing natural discharge and produced the largest water-level declines. Simulations using strategically placed ground-water withdrawals in the discharge area were the most efficient at eliminating natural discharge with small water-level declines.

Utah↗

Trend analysis of ground-water levels and spring discharge in the Yucca Mountain Region, Nevada and California, 1960-2000

Ground-water level and discharge data from 1960 to 2000 were analyzed for the Yucca Mountain region of southern Nevada and eastern California. Included were water-level data from 37 wells and a fissure (Devils Hole) and discharge data from five springs and from a flowing well. Data were evaluated for variability and for upward, downward, or cyclic trends with an emphasis on the period 1992-2000. Potential factors causing trends in water levels and discharge include ground-water withdrawal, infiltration of precipitation, earthquakes, evapotranspiration, barometric pressure, and earth tides. Statistically significant trends in ground-water levels or spring discharge from 1992 to 2000 were upward at 12 water-level sites and downward at 14 water-level sites and 1 spring-discharge site. In general, the magnitude of the change in water level from 1992 to 2000 was small (less than 2 feet), except where influenced by pumping or local effects such as possible equilibration from well construction or diversion of nearby surface water. Seasonal trends are superimposed on some of the long-term (1992-2000) trends in water levels and discharge. Factors causing seasonal trends include barometric pressure, evapotranspiration, and pumping. The magnitude of seasonal change in water level can vary from as little as 0.05 foot in regional aquifers to greater than 5 feet in monitoring wells near large supply wells in the Amargosa Farms area. Three major episodes of earthquake activity affected water levels in wells in the Yucca Mountain region between 1992 and 2000: the Landers/Little Skull Mountain, Northridge, and Hector Mine earthquakes. The Landers/Little Skull Mountain earthquakes, in June 1992, had the largest observed effect on water levels and on discharge during the study period. Monthly measurements of wells in the study network show that earthquakes affected water levels from a few tenths of a foot to 3.5 feet. In the Ash Meadows area, water levels remained relatively stable from 1992 to 2000, with some water levels showing small rising trends and some declining slightly. Possible reasons for water-level fluctuations at sites AD-6 (Tracer Well 3), AM-5 (Devils Hole Well), and AM-4 (Devils Hole) from 1960 to 2000 include climate change, local and regional ground-water withdrawals, and tectonic activity. In Jackass Flats, water levels from 1992 to 2000 in six wells adjacent to Fortymile Wash displayed either small upward trends or no upward or downward trend. Comparison of trends in water levels from 1983 to 2000 for these six wells shows good correlations between all wells and suggests a common mechanism controlling water levels in the area. Of the likely controls on the system--precipitation or pumping in Jackass Flats--precipitation appears to be the predominant factor controlling water levels near Fortymile Wash. Water levels in the heavily pumped Amargosa Farms area declined from about 10 to 30 feet from 1964 to 2000. Water-level declines accelerated beginning in the early 1990's as pumping rates increased substantially. Pumping in the Amargosa Farms area may affect water levels in some wells as far away as 5-14 miles. The water level at site DV-3 (Travertine Point 1 Well) and discharge at site DV-2 (Navel Spring), both in the Death Valley hydrographic area, had downward trends from 1992 to 2000. The cause of these downward trends may be linked to earthquakes, pumping in the Amargosa Farms area, or both.

Water-Resources Investigations Report↗

Chlorofluorocarbons, sulfur hexafluoride, and dissolved permanent gases in ground water from selected sites in and near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994-97

From July 1994 through May 1997, the U.S. Geological Survey in cooperation with the Department of Energy, sampled 86 wells completed in the Snake River Plain aquifer at and near the Idaho N ationa1 Engineering and Environmental Laboratory (INEEL). The wells were sampled for a variety of constituents including one- and two-carbon halocarbons. Concentrations of dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11) and trichlorotrifluororoethane (CFC-113) were determined. The samples for halocarbon analysis were collected in 62-milliliter flame sealed borosilicate glass ampoules in the field. The data will be used to evaluate the ages of ground waters at INEEL. The ages of the ground water will be used to determine recharge rates, residence time, and travel time of water in the Snake River Plain aquifer in and near INEEL. The chromatograms of 139 ground waters are presented showing a large number of halomethanes, haloethanes, and haloethenes present in the ground waters underlying the INEEL. The chromatograms can be used to qualitatively evaluate a large number of contaminants at parts per trillion to parts per billion concentrations. The data can be used to study temporal and spatial distribution of contaminants in the Snake River Plain aquifer. Representative compressed chromatograms for all ground waters sampled in this study are available on two 3.5-inch high density computer disks. The data and the program required to decompress the data can be obtained from the U.S. Geological Survey office at Idaho Falls, Idaho. Sulfur hexafluoride (SF6) concentrations were measured in selected wells to determine the feasibility of using this environmental tracer as an age dating tool of ground water. Concentrations of dissolved nitrogen, argon, carbon dioxide, oxygen, and methane were measured in 79 ground waters. Concentrations of dissolved permanent gases are tabulated and will be used to evaluate the temperature of recharge of ground water in and near the INEEL.

Idaho↗

Ground-water-flow conditions within a bottomland hardwood wetland, eastern Arkansas

Water levels were measured monthly at 9 staff gages and 35 wells along two transects within the Black Swamp bottomland hardwood wetland and perpendicular to the Cache River in eastern Arkansas from December 1989 to September 1992 in order to (1) describe the ground-water-flow conditions at locations within a bottomland hardwood wetland and (2) determine the relation between the frequency of different ground-water-flow conditions and physical characteristics within the wetland. Three ground-water-flow conditions predominated at various times in the Black Swamp: (1) discharge of water from the alluvial aquifer to the wetland, (2) recharge of water from the wetland into the alluvial aquifer, and (3) flow of water from the wetland into the alluvial aquifer and then to the nearby Cache River (local flow). Analyses of hydraulic head differences between surface and ground water indicate that discharge occurred 31% of the measurement times at both transects. Recharge occurred 39% of the measurement times and tended to occur more often at locations that are far from the Cache River and that overlie low ground-water levels in the lower part of the alluvial aquifer. Local ground-water flow occurred 28% of the measurement times and tended to occur more often at locations close to the Cache River. Ground-water pumpage results in water-level declines in the lower part of the alluvial aquifer near the Black Swamp wetland. When compared with an area not affected by pumping, these lower ground-water levels increased the frequency of recharge of Black Swamp water into the alluvial aquifer by nearly a factor of 7, decreased the frequency of local ground-water flow to the Cache River to less than half, and decreased the frequency of discharge by about 22%.

Arkansas↗

Ground water in the San Juan metropolitan area, Puerto Rico

Ground water in the San Juan, Puerto Rico, area has played a declining role in water supply since the completion of the Lofza reservoir project in the early 1950's. Ground-water potential is limited because of the small size of the aquifers and susceptibility to seawater intrusion. Of the 30 million gallons per day about half is being used. Two water-bearing zones are present: an artesian aquifer, composed of the San Sebastian Formation and the lower Cibao Formation that yields an average of 244 gallons per minute to wells; and, a water-table aquifer composed of the upper Cibao Formation and the Aguada and Aymamon Limestones that yields an average of 515 gallons per minute to wells. Ground water is less mineralized inland and in the artesian aquifer. Mean concentrations of dissolved solids are 363 milligrams per liter for the artesian aquifer and 525 milligrams per liter for the water-table aquifer. (Woodard-USGS)

Water-Resources Investigations Report↗

Nitrate retention in riparian ground water at natural and elevated nitrate levels in North Central Minnesota

The relationship between local ground water flows and NO3− transport to the channel was examined in three well transects from a natural, wooded riparian zone adjacent to the Shingobee River, MN. The hillslope ground water originated as recharge from intermittently grazed pasture up slope of the site. In the hillslope transect perpendicular to the stream, ground water NO3− concentrations decreased from ∼3 mg N L−1 beneath the ridge (80 m from the channel) to 0.01 to 1.0 mg N L−1 at wells 1 to 3 m from the channel. The Cl− concentrations and NO3/Cl ratios decreased toward the channel indicating NO3− dilution and biotic retention. In the bankside well transect parallel to the stream, two distinct ground water environments were observed: an alluvial environment upstream of a relict beaver dam influenced by stream water and a hillslope environment downstream of the relict beaver dam. Nitrate was elevated to levels representative of agricultural runoff in a third well transect located ∼5 m from the stream to assess the effectiveness of the riparian zone as a NO3− sink. Subsurface NO3− injections revealed transport of up to 15 mg N L−1 was nearly conservative in the alluvial riparian environment. Addition of glucose stimulated dissolved oxygen uptake and promoted NO3− retention under both background and elevated NO3− levels in summer and winter. Disappearance of added NO3− was followed by transient NO2− formation and, in the presence of C2H2, by N2O formation, demonstrating potential denitrification. Under current land use, most NO3− associated with local ground water is biotically retained or diluted before reaching the channel. However, elevating NO3− levels through agricultural cultivation would likely result in increased NO3− transport to the channel.

Minnesota↗