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USGS2001

Geologic studies in Alaska by the U.S. Geological Survey, 1999

The collection of nine papers that follow continue the series of U.S. Geological Survey (USGS) investigative reports in Alaska under the broad umbrella of the geologic sciences. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from various parts of the State (fig. 1), serving to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics: Hazards, Geologic Framework, Environment and Climate, and Resources. This organization is intended to reflect the scope and objectives of USGS geologic programs currently active in Alaska. The two Hazards studies discuss volcano-related topics in the seismically active southcentral Alaska region. The first paper revisits the eruptive events of Redoubt Volcano that occurred more than a decade ago and the subsequent development of the Alaska Volcano Observatory (AVO). This treatise documents the historic impact of this eruption and briefly summarizes the state of our knowledge of the other Cook Inlet, Alaska Peninsula, and Aleutian Island volcanoes. Finally, it discusses the recent role that AVO has had in seismic station installation and hazard assessment at volcanically active sites throughout the world. The second paper discusses the eruptive history of Snowy Mountain in the upper Alaska Peninsula. Because subsets of its 25-30 lava flows erupted as packages in short episodes, calculation of the volcano's lifetime average volumetric eruption rate is problematic. A portion of the cone was hydrothermally weakened and collapsed in the late Holocene producing a 22-km2 debris avalanche. Geologic Framework studies provide background information that is the scientific basis for present and future earth science investigations. The first paper compares and contrasts the Insular-Intermontane suture zone (IISZ) of southeast Alaska with the Adria-Europe suture zone (AESZ) of Switzerland and Hungary. The study develops the hypothesis that the zones have distinct differences as well as similarities and neither is a simple lithotectonic terrane boundary. The second paper discusses the relation among volcanic, glacial, and tectonic activity in the Cold Bay and False Pass 1 :250,000-scale quadrangles on the Alaska Peninsula. During Pleistocene time, continental-shelf glaciations and two massive volcanic centers were the dominant controls over landscape development. The third paper gives detailed geologic information for Paleozoic rocks within the Taylor Mountains D-1 quadrangle portion of the Holitna Lowland of southwestern Alaska. Because of the excellent preservation of megafossils, these Silurian and Ordovician strata lend themselves to detailed statigraphic investigations. Further, low thermal alteration indices of this area have made them a potential target of petroleum exploration. The final report in this section discusses the development of a new spectral enhancement approach for interpreting Multispectral Scanner (MSS) and Thematic Mapper (TM) satellite images. This technique enhances the use of remote sensing data in identifying geologic units in areas that have been poorly investigated. This study used this technique to better define the distribution of a JMtu (mafic, ultramafic, and sedimentary) unit and a PzZrqs (pelitic and quartzitic schist) unit. Environment and climate studies are the emphasis of two papers. One presents the first radiocarbon-dated postglacial vegetation history of the Kenai Mountains of southcentral Alaska. This reconstruction is the result of the analysis of pollen assemblages and peat from sediments collected in Tern Lake and presents a minimum age for deglaciation of these interior valleys at 9,31 0±200 yr B .P. Current vegetation, however, developed within the past ca. 2,500 years. A second study discusses the cycling of arsenic and cadmium in sub-arctic boreal forest ecosystems typical of interior Alaska and defines the importance of various natural (geogenic) sources. The transport and uptake into vegetation of these elements from soils developed from loess as well as soils developed from the major rock units is presented. The bioaccumulation of cadmium in willow (Salix sp.) and its potential consequence to the health of browsing animals is discussed. Papers related to resource issues comprise the topic of the final report. This paper presents a brief statistical summary of the geochemistry of rock samples collected in the east-central portion of the Eagle 1 :250,000-scale quadrangle. This study helps define the rock unit source of both resource- and environmental-based chemical elements of interest in the Fortymile mining district. Two bibliographies at the end of the volume list reports covering Alaska earth science topics in USGS publications during 1999 and reports about Alaska by USGS authors in non-USGS publications during the same period.

Alaska↗

USGS1999

Assessment of landscape correlates of Eastern hemlock decline due to hemlock woolly adelgid

Eastern hemlock ( Tsuga canadensis ) is in decline throughout its range in the eastern US due to infestation by an exotic insect pest, the hemlock woolly adelgid ( Adelges tsugae ). In Shenandoah National Park, the hemlock woolly adelgid (HWA) rapidly killed many stands of hemlock after first appearing in the late-1980’s, while having only minor impact in other stands. At present, few investigators have examined the mechanisms that produce this discontinuous impact, although landscape factors are predicted to play a major role (Orwig and Foster, 1998: Perry 1988). In an effort to address possible landscape correlates to hemlock decline, we conducted a preliminary analysis of 5 years of hemlock health estimates in comparison to measures of terrain, stand isolation, and potential dispersal corridors at the stand level. We found that elevation, slope, light conditions, and distance to streams all exhibited relatively strong correlation with hemlock decline, although the relationship varied by year. In addition, there appears to be some evidence of spatial autocorrelation in decline, suggesting that similar environmental conditions are either controlling the adelgid or making hemlock stands more susceptible to HWA. We are using the results of this preliminary analysis to guide more detailed efforts aimed at modeling hemlock stand vulnerability as a result of site, landscape, and regional factors.

Virginia↗

USGS2010

Global change and water resources in the next 100 years

We are in the midst of a continental-scale, multi-year experiment in the United States, in which we have not defined our testable hypotheses or set the duration and scope of the experiment, which poses major water-resources challenges for the 21st century. What are we doing? We are expanding population at three times the national growth rate in our most water-scarce region, the southwestern United States, where water stress is already great and modeling predicts decreased streamflow by the middle of this century. We are expanding irrigated agriculture from the west into the east, particularly to the southeastern states, where increased competition for ground and surface water has urban, agricultural, and environmental interests at odds, and increasingly, in court. We are expanding our consumption of pharmaceutical and personal care products to historic high levels and disposing them in surface and groundwater, through sewage treatment plants and individual septic systems. These substances are now detectable at very low concentrations and we have documented significant effects on aquatic species, particularly on fish reproduction function. We don’t yet know what effects on human health may emerge, nor do we know if we need to make large investments in water treatment systems, which were not designed to remove these substances. These are a few examples of our national-scale experiment. In addition to these water resources challenges, over which we have some control, climate change models indicate that precipitation and streamflow patterns will change in coming decades, with western mid-latitude North America generally drier. We have already documented trends in more rain and less snow in western mountains. This has large implications for water supply and storage, and groundwater recharge. We have documented earlier snowmelt peak spring runoff in northeastern and northwestern States, and western montane regions. Peak runoff is now about two weeks earlier than it was in the first half of the 20th century. Decreased summer runoff affects water supply for agriculture, domestic water supply, cooling needs for thermoelectric power generation, and ecosystem needs. In addition to the reduced volume of streamflow during warm summer months, less water results in elevated stream temperature, which also has significant effects on cooling of power generating facilities and on aquatic ecosystem needs. We are now required to include fish and other aquatic species in negotiation over how much water to leave in the river, rather than, as in the past, how much water we could remove from a river. Additionally, we must pay attention to the quality of that water, including its temperature. This is driven in the US by the Endangered Species Act and the Clean Water Act. Furthermore, we must now better understand and manage the whole hydrograph and the influence of hydrologic variability on aquatic ecosystems. Man has trimmed the tails off the probability distribution of flows. We need to understand how to put the tails back on but can’t do that without improved understanding of aquatic ecosystems. Sea level rise presents challenges for fresh water extraction from coastal aquifers as they are compromised by increased saline intrusion. A related problem faces users of ‘run-of-the-river’ water-supply intakes that are threatened by a salt front that migrates further upstream because of higher sea level. We face significant challenges with water infrastructure. The U.S. has among the highest quality drinking water in the world piped to our homes. However, our water and sewage treatment plants and water and sewer pipelines have not had adequate maintenance or investment for decades. The US Environmental Protection Agency estimates that there are up to 3.5M illnesses per year from recreational contact with sewage from sanitary sewage overflows. Infrastructure investment needs have been put at 5 trillion nationally. Global change and water resources c

Conference Paper↗

USGS2013

Managing the effects of endocrine disrupting chemicals in wastewater-impacted streams

A revolution in analytical instrumentation circa 1920 greatly improved the ability to characterize chemical substances. This analytical foundation resulted in an unprecedented explosion in the design and production of synthetic chemicals during and post-World War II. What is now often referred to as the 2nd Chemical Revolution has provided substantial societal benefits; with modern chemical design and manufacturing supporting dramatic advances in medicine, increased food production, and expanding gross domestic products at the national and global scales as well as improved health, longevity, and lifestyle convenience at the individual scale. Presently, the chemical industry is the largest manufacturing sector in the United States (U.S.) and the second largest in Europe and Japan, representing approximately 5% of the Gross Domestic Product (GDP) in each of these countries. At the turn of the 21st century, the chemical industry was estimated to be worth more than $1.6 trillion and to employ over 10 million people, globally. During the first half of the 20th century, the chemical sector expanded rapidly, the chemical industry enjoyed a generally positive status in society, and chemicals were widely appreciated as fundamental to individual and societal quality of life. Starting in the 1960s, however, the environmental costs associated with the chemical industry increasingly became the focus, due in part to the impact of books like “Silent Spring” and “Our Stolen Future” and to a number of highly publicized environmental disasters. Galvanizing chemical industry disasters included the 1976 dioxin leak north of Milan, Italy, the Love Canal evacuations in Niagara, New York beginning in 1978, and the Union Carbide leak in Bhopal, India in 1984. Understanding the environmental impact of synthetic compounds is essential to any informed assessment of net societal benefit, for the simple reason that any chemical substance that is in commercial production or use will eventually find its way to the environment. Not surprisingly given the direct link to profits, manufacturers intensely investigate and routinely document the potential benefits of new chemicals and chemical products. In contrast, the environmental risks associated with chemical production and uses are often investigated less intensely and are poorly communicated. An imbalance in the risk-benefit analysis of any synthetic chemical substance or naturally occurring chemical, which presence and concentration in the environment largely reflects human activities and management, is a particular concern owing to the fundamental link between chemistry and biology. Biological organisms are intrinsically a homeostatic balance of innumerable internal and external chemical interactions and, thus, inherently sensitive to changes in the external chemical environment.

Book chapter↗

USGS2026

The effects of scientific uncertainty and values trade-offs on flow management decisions for an endangered fish

Consumptive use of freshwater is of concern in many estuarine ecosystems, and various frameworks have been used to prescribe environmental flows to benefit native species. However, few of these frameworks explicitly examine the potential trade-offs between socioeconomic and conservation-oriented values. This is exemplified in California, USA, where freshwater management has been an area of focus and controversy. Operations of numerous reservoirs and water diversion facilities distributed throughout the state, while critical for economic and public health benefits, have contributed to the decline of many native species. The endangered delta smelt ( Hypomesus transpacificus ) is endemic to the Sacramento-San Joaquin Delta, the heart of California's complex water conveyance system. To aid recovery of delta smelt, fall-timed freshwater pulse flows were implemented, which require water to be either released from reservoirs, or made unavailable to export for consumptive uses. Previous research has indicated that the effectiveness of the current pulse flow action could be improved by reconsidering the timing and magnitude; however, uncertainties in the predicted fish response to flow pulses may hinder decision-making about flow management. Using a water resource planning model, different iterations of an individual-based life cycle model, and decision analysis tools, we assessed the importance of sources of uncertainty to hypothetical flow management decisions, including uncertainty surrounding the predicted responses in delta smelt population growth rates, and variability of decision-maker's values. We found both the choice of which (if any) flow action to take for delta smelt, and the expected value of further research, depended on how decision-makers weight the delta smelt and water supply objectives. There was expected value of information (VOI) only if a decision-maker weighted the delta smelt objective ≥0.59, and within this range, research to improve estimates of changes in delta smelt prey items related to flow actions could be prioritized over other sources of uncertainty to improve outcomes of decision-making. Our study demonstrates how uncertainty, even if large, may not be equally relevant to different decision-makers (e.g., with different agency missions), and how VOI analysis can be used to guide management in an overallocated water system such as California.

California↗

USGS2008

Metals fate and transport modelling in streams and watersheds: state of the science and USEPA workshop review

Metals pollution in surface waters from point and non-point sources (NPS) is a widespread problem in the United States and worldwide (Lofts et al. , 2007; USEPA, 2007). In the western United States, metals associated with acid mine drainage (AMD) from hardrock mines in mountainous areas impact aquatic ecosystems and human health (USEPA, 1997a; Caruso and Ward, 1998; Church et al. , 2007). Metals fate and transport modelling in streams and watersheds is sometimes needed for assessment and restoration of surface waters, including mining-impacted streams (Runkel and Kimball, 2002; Caruso, 2003; Velleux et al. , 2006). The Water Quality Analysis Simulation Program (WASP; Wool et al. , 2001), developed by the US Environmental Protection Agency (USEPA), is an example of a model used for such analyses. Other approaches exist and appropriate model selection depends on site characteristics, data availability and modelling objectives. However, there are a wide range of assumptions, input parameters, data requirements and gaps, and calibration and validation issues that must be addressed by model developers, users and decision makers. Despite substantial work on model development, their successful application has been more limited because they are not often used by decision makers for stream and watershed assessment and restoration. Bringing together scientists, model developers, users and decision makers should stimulate the development of appropriate models and improve the applicability of their results. To address these issues, the USEPA Ofﬁce of Research and Development and Region 8 (Colorado, Montana, North Dakota, South Dakota, Utah and Wyoming) hosted a workshop in Denver, Colorado on February 13–14, 2007. The workshop brought together approximately 35 experts from government, academia and consulting to address the state of the art for modelling metals fate and transport, knowledge gaps and future directions in metals modelling. It focused on modelling metals in high-altitude streams, rivers and watersheds impacted by mine waste that are common in the western United States and require remediation. For example, there are over 100 000 abandoned or inactive mining sites across the United States, encompassing over 500 000 acres of land that may eventually require characterization and remediation, including the possible application of stream or watershed metals fate and transport modelling (USEPA, 1997a). This article provides a general overview of the state of the science on modelling metals fate and transport in streams and watersheds, including a review of presentations and discussions at the USEPA workshop. It builds on previous summaries of metals fate and transport models in aquatic systems, including USEPA (1997b, 2007), Allen (2002), Paquin et al. (2003), Nordstrom (2004) and Maest et al. (2005).

Colorado↗

USGS2016

Aqueous exposure to the progestin, levonorgestrel, alters anal fin development and reproductive behavior in the eastern mosquitofish (Gambusia holbrooki)

Endogenous progestogens are important regulators of vertebrate reproduction. Synthetic progestins are components of human contraceptive and hormone replacement pharmaceuticals. Both progestogens and progestins enter the environment through a number of sources, and have been shown to cause profound effects on reproductive health in various aquatic vertebrates. Progestins are designed to bind human progesterone receptors, but they also have been shown to strongly activate androgen receptors in fish. Levonorgestrel (LNG) activates fish androgen receptors and induces development of male secondary sex characteristics in females of other species. Although behavior has been postulated to be a sensitive early indicator of exposure to certain environmental contaminants, no such research on the reproductive behavior of gestagen-exposed fish has been conducted to date. The goal of our study was to examine the exposure effects of a human contraceptive progestin, LNG, on the reproductive development and behavior of the viviparous eastern mosquitofish ( Gambusia holbrooki ). Internal fertilization is a requisite characteristic of viviparous species, and is enabled by an androgen driven elongation of the anal fin into the male gonopodium (i.e., phallus). In this study, we exposed adult mosquitofish to ethanol (EtOH control), 10 ng/L, and 100 ng/L LNG for 8 d using a static replacement exposure design. After 8 d, a subset of males and females from each treatment were examined for differences in the 4:6 anal fin ratio. In addition, paired social interaction trials were performed using individual control males and control females or females treated 10 ng/L or 100 ng/L LNG. Female mosquitofish exposed to LNG were masculinized as evidenced by the elongation of the anal fin rays, a feature normal to males and abnormal to females. LNG caused significant increases in the 4:6 anal fin ratios of female mosquitofish in both the 10 ng/L and 100 ng/L treatments, although these differences were not significant between the two treatments. LNG caused significant increases in the 4:6 anal fin ratio of males exposed to 100 ng/L, with no effects observed in the 10 ng/L treatment. In addition, the reproductive behavior of control males paired with female mosquitofish exposed to 100 ng/L LNG was also altered, for these males spent more time exhibiting no reproductive behavior, had decreased attending behavior, and a lower number of gonopodial thrusts compared to control males paired to control female mosquitofish. Given the rapid effects on both anal fin morphology and behavior observed in this study, the mosquitofish is an excellent sentinel species for the detection of exposure to LNG and likely other 19-nortestosterone derived contraceptive progestins in the environment.

General and Comparative Endocrinology↗

USGS2002

Concentrations of chromium, manganese, and lead in air and in avian eggs

The expansion of urbanization introduces air pollution to wildlife areas. Some metal contaminants occurring in concentrations too small to have any measurable impact on adult birds may seriously affect embryos that are more sensitive to contaminants than the adult. Chromium, manganese, and lead are toxic and can be passed from the hen to the egg. This study relates the concentrations of these metals in eggs to their concentrations in air in three cities. Rock dove eggs were sampled and air pollution records were examined in the California cities of Riverside, Los Angeles, and San Francisco. The eggs from San Francisco did not differ from those of Los Angeles in lead concentration but the air did differ. The eggs collected in Los Angeles in 1998 had concentrations of chromium greater than in those from Riverside and from Los Angeles 1999 but the air had concentrations of chromium that did not differ among those three collections. Concentrations of manganese did not differ among the eggs but did differ among the air samples of the three cities. Exposures of embryos to chromium and manganese in this study were not at levels warranting concern. Although the concentration at which lead in eggs impairs avian health is not established, the highest concentrations found in this study exceed estimated safe concentrations. There is no indication that embryo exposure is directly related to atmospheric levels of these metals in the cities of this study.

California↗

USGS1998

Water quality in the central Columbia Plateau, Washington and Idaho, 1992-95

Water quality in the Central Columbia Plateau of eastern Washington and western Idaho has been adversely affected by agriculture, especially in irrigated areas, according to the results of a five-year investigation by the U. S. Geological Survey (USGS). Some improvements, however, are noticeable, such as less sediment being washed into streams. These improvements may be the result of increased use of best management practices (BMPs) by area farmers. Areas with intensive fertilizer use and irrigation, such as in the Columbia Basin Irrigation Project (CBIP), showed the greatest impacts on ground-water quality. (The CBIP includes parts of Franklin, Grant, and Adams counties in eastern Washington.) <Shallow wells, generally those less than 150 feet deep, are the most susceptible to contamination, the USGS report says. A reassuring aspect of this finding, however, is that many public water supplies draw from wells at greater depths and are less susceptible to contamination from agricultural practices. From the standpoint of human health, we were most concerned about checking for nitrate and pesticides in drinking water,' said Sandy Williamson, USGS hydrologist and chief of the study. 'We found nitrate levels exceeding the maximum contaminant level in about 20 percent of all wells.' (A maximum contaminant level-or MCL-is a drinking water regulatory standard that is set by the U.S. Environmental Protection Agency.) 'The story on pesticides is a mixed bag,' Williamson said. 'We found at least one pesticide in nearly half of the drinking water wells sampled, but pesticide levels were only a very small fraction of their MCLs.' As a cautionary note, however, Williamson said that about half of the pesticides detected in Central Columbia Plateau wells do not have MCLs established. A lack of information makes it difficult to assess the significance of finding pesticides in drinking water. 'As scientists, we don't know enough yet about what happens when these pesticides are combined,' he said. 'In some of the very shallow wells that the USGS installed for monitoring purposes, we found up to seven different pesticides.' Encouraging news is that none of the newer pesticides, which break down more rapidly in the environment, were found at concentrations exceeding MCLs. Compounds that exceed drinking water standards were found in only 1 percent of the wells sampled-and those compounds have not been sold as pesticides since the mid-1980s. However, agricultural impacts on water quality go beyond the concerns for drinking water-the aquatic ecosystem of the plateau also has been significantly affected. 'Very little surface water is used for drinking water in this area, but fish are harmed by decreased stream-water quality,' said Mark Munn, the biologist for the USGS study. 'Pesticides and habitat degradation are the main concerns.' He noted that stream sampling by the USGS showed seven currently used pesticides at concentrations above the limits recommended for protecting aquatic life. Soil erosion, a long-term problem for farmers in the Palouse River Basin, transports some soil to streams, degrading habitat and carrying with it older pesticides and their breakdown products. A breakdown product of the banned insecticide DDT was found in both streambed sediment and bottom fish at concentrations exceeding guidelines for the protection of aquatic life. 'Another problem for fish habitat is excessive plant growth caused by high levels of nutrients in streams,' said Munn, who explained that these nutrients enter streams in runoff from agricultural fields and discharge from urban wastewater treatment plants. Some agricultural practices, such as allowing cattle to graze near streams, are associated with higher rates of erosion. However, increased use of BMPs may improve water quality of the plateau. The USGS study showed that use of sprinkler or drip rather than furrow irrigation has decreased soil erosion in the CBIP area. In the Palouse, erosion

Circular↗

USGS1999

Radium in ground water from public-water supplies in northern Illinois

Concentrations of the naturally occurring radioactive isotopes radium-226 and radium-228 in excess of the U.S. Environmental Protection Agency standard for drinking water of 5 picocuries per liter have been detected in water from deep aquifers used for public supply that underly parts of northern Illinois. Radium, a known carcinogen, has the potential to cause bone and sinus cancer if ingested in sufficient amounts. This Fact Sheet briefly describes the formation and decay of radium, the health risks associated with radium ingestion, procedures for testing radium concentrations in water, and the occurrence of radium in ground water used for public-water supplies in northern Illinois and provides information on technologies that can reduce the amount of radium in drinking water.

Fact Sheet↗

USGS2020

The response of streams to changes in atmospheric deposition of sulfur and nitrogen in the Adirondack Mountains

Acidic deposition is the result of upwind sulfur (S) and nitrogen (N) emissions into the atmosphere from human activities. Environmental impacts from acidic deposition across forested landscapes include acidification of soil and drainage water, depletion of available soil nutrient bases, and impacts to and changes in forest and aquatic species composition and biodiversity. Acidic deposition can mobilize aluminum (Al) from soil-to-soil solution and subsequently to drainage water in forms that can be toxic to aquatic life. When exposed to decreasing levels of acidic deposition, which has been occurring in New York since the late 1970s, some soils and drainage waters have become gradually less acidic. Remaining questions relate to effects on stream resources, anticipated resource recovery under increasingly lower levels of deposition, and the levels of deposition (target loads, TLs) needed to reach a range of stream ecosystem recovery targets. Environmental scientists commonly estimate thresholds of air pollutant emissions and resulting atmospheric deposition at which adverse ecological effects are manifested. This analysis is often done using critical loads (CL) and/or TLs, using approaches that account for the spatial and temporal aspects of acidification and recovery. Exceedance represents the extent to which current levels of acidic deposition exceed the level expected to cause ecological harm. The research reported here is intended to help address S and N deposition TLs and ecosystem recovery of Adirondack streams, a resource that has been less thoroughly investigated than lakes. The overarching goal of this work is to highlight key considerations that will help inform decision-makers and ecosystem managers who are responsible for environmental policy in New York State and beyond. Salient aspects of stream TL modeling are discussed with an aim of informing not only scientists, but also policymakers, ecosystem managers, and nonscientists who are required to make decisions related to the effects of acidic deposition on natural ecosystems. Analyses reported herein quantify relations among chemical indicators and metrics of fish community health and biodiversity in streams of the Adirondack Park. This information is used to indicate levels of atmospheric deposition necessary to alleviate harmful effects on fish populations. Results of this investigation provide a framework that can be applied to better understand how modeled stream acid neutralizing capacity (ANC) values that are developed to support TL investigations can be adjusted to reflect high-flow ANC values that may be associated with toxic conditions. Since process models are often calibrated to a low-flow or average flow condition, the magnitude and spatial extent of TL exceedances increase substantially when episodic acidification is considered.

New York↗

USGS2009

Antidepressants at environmentally relevant concentrations affect predator avoidance behavior of larval fathead minnows (Pimephales promelas).

The effects of embryonic and larval exposure to environmentally relevant (ng/L) concentrations of common antidepressants, fluoxetine, sertraline, venlafaxine, and bupropion (singularly and in mixture) on C-start escape behavior were evaluated in fathead minnows (Pimephales promelas). Embryos (postfertilization until hatching) were exposed for 5 d and, after hatching, were allowed to grow in control well water until 12 d old. Similarly, posthatch fathead minnows were exposed for 12 d to these compounds. High-speed (1,000 frames/s) video recordings of escape behavior were collected and transferred to National Institutes of Health Image for frame-by- frame analysis of latency periods, escape velocities, and total escape response (combination of latency period and escape velocity). When tested 12 d posthatch, fluoxetine and venlafaxine adversely affected C-start performance of larvae exposed as embryos. Conversely, larvae exposed for 12 d posthatch did not exhibit altered escape responses when exposed to fluoxetine but were affected by venlafaxine and bupropion exposure. Mixtures of these four antidepressant pharmaceuticals slowed predator avoidance behaviors in larval fathead minnows regardless of the exposure window. The direct impact of reduced C-start performance on survival and, ultimately, reproductive fitness provides an avenue to assess the ecological relevance of exposure in an assay of relatively short duration.

Environmental Toxicology and Chemistry↗

USGS2006

U.S. Geological Survey Chesapeake Bay Studies: Scientific Solutions for a Healthy Bay and Watershed

The U.S. Geological Survey (USGS), the science agency for the Department of Interior (DOI), has the critical role of providing objective science to document and understand ecosystem change in the Chesapeake Bay and its watershed. The human population in the Bay watershed , which grew from 8.1 million in 1950 to almost 16 million in 2000, has resulted in degraded water quality, loss of habitat, and declines in fish and bird populations. USGS scientists are leaders in understanding cause and effect of human activities and natural changes on water quality and the health of the ecosystem. The USGS interacts with resource managers and policy makers to use the science to adapt approaches for implementation, and assess effectiveness of, management actions for ecosystem conservation, restoration, and sustainability. Since the mid-1980s, the USGS has been an active partner in the Chesapeake Bay Program (CBP) , a multi-agency partnership led by the U.S. Environmental Protection Agency, working to achieve the restoration goals set forth in the Chesapeake 2000 agreement . This agreement established over 100 restoration commitments to be addressed by 2010. In 2005, which was the mid-point of the agreement, there was growing concern at all levels of government and by the public that ecological conditions in the Bay and its watershed had not significantly improved. The slow rate of improvement, coupled with the projected impact of human-population increase in the Bay watershed (fig. 1) , implied that many desired ecological conditions will not be achieved by 2010. To address these challenges, the USGS wrote a new science plan for 2006-2011 , and is synthesizing key findings to highlight the accomplishments from science activities for 2000-2005.

Delaware, Maryland, New York, Pennsylvania, Virgin↗

USGS2016

Physical, chemical, and biological characteristics of selected headwater streams along the Allegheny Front, Blair County, Pennsylvania, July 2011–September 2013

The Altoona Water Authority (AWA) obtains all of its water supply from headwater streams that drain western Blair County, an area underlain in part by black shale of the Marcellus Formation. Development of the shale-gas reservoirs will require new access roads, stream crossing, drill-pad construction, and pipeline installation, activities that have the potential to alter existing stream channel morphology, increase runoff and sediment supply, alter streamwater chemistry, and affect aquatic habitat. The U.S. Geological Survey, in cooperation with Altoona Water Authority and Blair County Conservation District, investigated the water quality of 12 headwater streams and biotic health of 10 headwater streams. Channel morphology was characterized at 10 of 12 stream sites using 500-foot (minimum) longitudinal profiles, four cross-sections each, and pebble counts. Channel slopes ranged from 0.008 in Poplar Run near Newry to 0.045 in Mill Run. In general, streams draining watersheds of 5 square miles or less and at higher elevation had the steepest slopes. On the basis of the median particle size, determined during pebble counts, the streambed substrate can be characterized as cobble (Mill Run, Bells Gap Run, Tipton Run, and Sink Run), a mix of gravel and cobble (South Poplar Run, Dry Gap Run, Glenwhite Run, Sugar Run, Blair Gap Run), and gravel (Poplar Run, Newry). Daily mean values of gage height were determined, and continuous (30-minute interval) data consisting of specific conductance and water temperature were collected, at four sites; each site showed typical seasonal fluctuations and the effects of precipitation. Streamflow affected discrete water-quality. Dissolved oxygen always increased with increased streamflow. Most cations (including barium and strontium), along with pH, specific conductance, and total dissolved solids, decreased with greater streamflow, reflecting the dilution effect of moderately acidic surface runoff and precipitation on groundwater discharge (base flow) into the stream channels. Concentrations of trace elements varied by constituent and streamflow. On the basis of the results of water-quality analyses for the selected constituents, the water quality in 9 of the 12 streams can be considered fair or attaining with no measured constituent exceeding a U.S. Environmental Protection Agency maximum or secondary contaminant level. Abandoned mine drainage (AMD) affects Glenwhite Run, Blair Gap Run, and Sugar Run. For Sugar Run, the AMD is reflected in the elevated iron concentration (greater than 300 micrograms per liter). Manganese concentrations greater than 50 micrograms per liter were measured in Glenwhite Run, Sugar Run, and Blair Gap Run. A mixing curve based upon chloride/bromide ratios for two end points—precipitation and deicing salts—indicate that deicing salt is migrating to the streams. A similar curve representative of late-emerging flowback water from Marcellus gas wells indicated that the surface-water samples had not been influenced by such brines. On the basis of the concentration of major ions, the streams in the study area generally had mixed cation and anion compositions. Calcium is the dominant cation in one stream. Carbonate and bicarbonate are the dominant anions for two streams, and sulfate is dominant in three streams. The remaining six streams do not have a dominant ion. Biotic health was characterized at 10 of 12 stream sites; the two sites excluded were established late in the study period (May 2013) for refinement of water quality in the headwaters of Poplar Run and the location of Marcellus Formation gas wells. On the basis of the Maryland Index of Biotic Integrity (MdIBI) for fish assemblages, 8 of 10 streams can be considered in fair health. Tipton Run had the highest MdIBI score (3.75) and the greatest number of native species. South Poplar Run had the lowest MdIBI score (1.75); pollution tolerant blacknose dace was dominant. On the basis of the Pennsylvania Department of Environmental Protection macroinvertebrate index of biotic integrity, 9 of 10 streams were characterized as attaining, with scores as high as 88.9 at Tipton Run. Only Sugar Run was characterized as impaired, with a score of 40.4.

Pennsylvania↗

USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Ground-water quality in the Rio Grande flood plain, Cochiti Lake, New Mexico, to El Paso, Texas, 1995

From March to May of 1995, water samples were collected from 30 wells located in the flood plain of the Rio Grande between Cochiti Lake, New Mexico, and El Paso, Texas. These samples were analyzed for a broad host of constituents, including field parameters, major constituents, nutrients, dissolved organic carbon, trace elements, radiochemicals, pesticides, and volatile organic compounds. The main purpose of this study was to observe the quality of ground water in this part of the Rio Grande Valley study unit of the U.S. Geological Survey National Water-Quality Assessment program. The sampling effort was limited to the basin- fill aquifer beneath the above-defined reach of the Rio Grande flood plain because of the relative homogeneity of the hydrogeology, the large amount of ground-water use for public supply, and the potential for land-use activities to affect the quality of ground water. Most of the wells sampled for the study are used for domestic purposes, including drinking water. Depths to the tops of the sampling intervals in the 30 wells ranged from 10 to 345 feet below land surface, and the median was 161.5 feet; the sampling intervals in most of the wells spanned about 10 feet or less. Quality-control data were collected at three of the wells. A significant amount of variation was found in the chemical composition of ground water sampled throughout the study area, but the water generally was found to be of suitable chemical quality for use as drinking water, according to current enforceable standards established by the U.S. Environmental Protection Agency (EPA). Nutrients generally were measured at concentrations near or below their method reporting limits. The most dominant nutrient species was nitrite plus nitrate, at a maximum concentration of 1.9 milligrams per liter (as N). Only eight of the trace elements analyzed for had median concentrations greater than their respective minimum reporting levels. Water from one well exceeded the lifetime health advisory established by the EPA for molybdenum; water from a different well exceeded the proposed EPA maximum contaminant level for uranium. Gross alpha and gross beta particle activities generally appeared to strongly correlate with quantities of uranium and potassium, respectively, detected in ground water. However, water from one well exceeded the EPA maximum contaminant level for gross alpha particle activity and may exceed the EPA maximum contaminant level for beta particle and photon activity, although current data on gross beta particle activities are not conclusive on this point. Radon concentrations did not appear to directly correlate with uranium concentrations. The herbicide prometon was the only synthetic organic compound detected in ground water in the study area, and was detected in only one well, at a concentration of 0.038 microgram per liter. This well is shallow and is not used for drinking water. With the exception of the one detection of prometon, no strong evidence was found of effects on ground-water quality from human activities. Therefore, most of the water sampled probably recharged at the margins of the alluvial basins or recharged through the flood plain before human development began. With respect to major constituents, the concentrations of dissolved solids ranged from 209 to 3,380 milligrams per liter, and the median concentration was 409.5 milligrams per liter. There is evidence that the overall chemical composition of ground water in the study area may be affected by several processes, including cation exchange, feldspar weathering, calcite dissolution and precipitation, dissolution of volcanic glass, and microbial activity. Several chemical constituents in ground water showed relatively distinct spatial patterns that appear to be related to one or more of these processes.

Texas↗

USGS2018

Long Island South Shore Estuary Reserve Coordinated Water Resources Monitoring Strategy

Executive Summary The Long Island South Shore Estuary Reserve Coordinated Water Resources Monitoring Strategy (CWRMS) provides an overview of the water-quality and ecological monitoring within the Reserve and presents suggestions from stakeholders for future data collection, data management, and coordination among monitoring programs. The South Shore Estuary Reserve, hereafter referred to as the Reserve, is a 173-square-mile network of bays and tributaries shaped by the south shore of Long Island (New York) and the barrier islands that was formed as a result of the last ice age (roughly 18,000 years ago). This overview and coordination document is based on information assembled from a series of meetings, a workshop, and individual correspondences with the CWRMS Project Advisory Committee, which was formed in 2015 to help guide the creation of the document, which reflects the current (2017) status of the Reserve and the need for additional data to address its water-quality issues and ecological health and to respond to a changing climate. The U.S. Geological Survey (USGS), in cooperation with the New York State Department of State Office of Planning, Development and Community Infrastructure and the South Shore Estuary Reserve Office, compiled information and recommendations to help stakeholders efficiently evaluate waters currently being monitored and address areas where necessary data are lacking. Water-quality monitoring in the Reserve is ongoing on the Federal, State, and local levels, and coordination among the various programs administered by the U.S. Environmental Protection Agency; National Oceanic and Atmospheric Administration; USGS; Shinnecock Tribal Nation; New York State; Nassau and Suffolk Counties; the Towns of Hempstead, Oyster Bay, Babylon, Islip, Brookhaven, and Southampton; and local universities and nonprofit organizations is necessary to ensure cooperation and efficient use of limited resources. Proper collection and archival of data are critical to the usability of data and methods—a sample of available repositories for monitoring data are provided in this report. Equally important are quality assurances of data and proper techniques of archival such that water and ecological data are collected and analyzed in a consistent manner, regardless of their sources, and that differences in methodologies are identified that might result in discrepancies in the compiled data. Details on monitoring programs, data gaps that are perceived by stakeholders and researchers in the area, and Project Advisory Committee recommendations are provided in this report to promote discussion and coordination. In most cases, resources to fill data gaps are needed, and the use of citizen science volunteers has been shown to help extend programs and provide insight into previously unaddressed areas of concern. This document, in conjunction with the CWRMS website and interactive mapper, is intended to inform the latest iteration of the Comprehensive Management Plan for the Reserve. Moreover, resource managers can use the CWRMS and mapper to identify areas of potential overlap and initiate conversations with stakeholders about addressing needs for additional monitoring of water quality and ecological health in the bays and tributaries of the Reserve.

New York↗

USGS2020

Assessing the ecological risks of per‐ and polyfluoroalkyl substances: Current state‐of‐the science and a proposed path forward

Per‐ and poly‐fluoroalkyl substances (PFAS) encompass a large, heterogenous group of chemicals of potential concern to human health and the environment. Based on information for a few relatively well‐understood PFAS such as perfluorooctane sulfonate and perfluorooctanoate, there is ample basis to suspect that at least a subset can be considered persistent, bioaccumulative, and/or toxic. However, data suitable for determining risks in either prospective or retrospective assessments are lacking for the majority of PFAS. In August 2019, the Society of Environmental Toxicology and Chemistry sponsored a workshop that focused on the state‐of‐the‐science supporting risk assessment of PFAS. The present review summarizes discussions concerning the ecotoxicology and ecological risks of PFAS. First, we summarize currently available information relevant to problem formulation/prioritization, exposure, and hazard/effects of PFAS in the context of regulatory and ecological risk assessment activities from around the world. We then describe critical gaps and uncertainties relative to ecological risk assessments for PFAS and propose approaches to address these needs. Recommendations include the development of more comprehensive monitoring programs to support exposure assessment, an emphasis on research to support the formulation of predictive models for bioaccumulation, and the development of in silico, in vitro, and in vivo methods to efficiently assess biological effects for potentially sensitive species/endpoints. Addressing needs associated with assessing the ecological risk of PFAS will require cross‐disciplinary approaches that employ both conventional and new methods in an integrated, resource‐effective manner.

Environmental Toxicology and Chemistry↗

USGS2016

Contamination with bacterial zoonotic pathogen genes in U.S. streams influenced by varying types of animal agriculture

Animal waste, stream water, and streambed sediment from 19 small (< 32 km 2 ) watersheds in 12 U.S. states having either no major animal agriculture (control, n = 4), or predominantly beef ( n = 4), dairy ( n = 3), swine ( n = 5), or poultry ( n = 3) were tested for: 1) cholesterol, coprostanol, estrone, and fecal indicator bacteria (FIB) concentrations, and 2) shiga-toxin producing and enterotoxigenic Escherichia coli , Salmonella , Campylobacter , and pathogenic and vancomycin-resistant enterococci by polymerase chain reaction (PCR) on enrichments, and/or direct quantitative PCR. Pathogen genes were most frequently detected in dairy wastes, followed by beef, swine and poultry wastes in that order; there was only one detection of an animal-source-specific pathogen gene ( stx1 ) in any water or sediment sample in any control watershed. Post-rainfall pathogen gene numbers in stream water were significantly correlated with FIB, cholesterol and coprostanol concentrations, and were most highly correlated in dairy watershed samples collected from 3 different states. Although collected across multiple states and ecoregions, animal-waste gene profiles were distinctive via discriminant analysis. Stream water gene profiles could also be discriminated by the watershed animal type. Although pathogen genes were not abundant in stream water or streambed samples, PCR on enrichments indicated that many genes were from viable organisms, including several (shiga-toxin producing or enterotoxigenic E. coli , Salmonella , vancomycin-resistant enterococci) that could potentially affect either human or animal health. Pathogen gene numbers and types in stream water samples were influenced most by animal type, by local factors such as whether animals had stream access, and by the amount of local rainfall, and not by studied watershed soil or physical characteristics. Our results indicated that stream water in small agricultural U.S. watersheds was susceptible to pathogen gene inputs under typical agricultural practices and environmental conditions. Pathogen gene profiles may offer the potential to address both source of, and risks associated with, fecal pollution.

Arizona, Indiana, Iowa, Kentucky, Maryland, Michig↗