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At least 1,261 records · Page 70Linked to original sources

Sea surface temperatures of the mid-Piacenzian Warm Period: A comparison of PRISM3 and HadCM3

It is essential to document how well the current generation of climate models performs in simulating past climates to have confidence in their ability to project future conditions. We present the first global, in-depth comparison of Pliocene sea surface temperature (SST) estimates from a coupled ocean–atmosphere climate model experiment and a SST reconstruction based on proxy data. This enables the identification of areas in which both the climate model and the proxy dataset require improvement. In general, the fit between model-produced SST anomalies and those formed from the available data is very good. We focus our discussion on three regions where the data–model anomaly exceeds 2 °C. 1) In the high latitude North Pacific, a systematic model error may result in anomalies that are too cold. Also, the deeper Pliocene thermocline may cause disagreement along the California margin; either the upwelling in the model is too strong or the modeled thermocline is not deep enough. 2) In the North Atlantic, the model predicts cooling in the center of a data-based warming trend that steadily increases with latitude from + 1.5 °C to >+ 6 °C. The discrepancy may arise because the modeled North Atlantic Current is too zonal compared to reality, which is reinforced by the lowering of the altitude of the Pliocene Western Cordillera Mountains. In addition, the model's use of modern bathymetry in the higher latitudes may have led the model to underestimate the northward penetration of warmer surface water into the Arctic. 3) Finally, though the data and model show good general agreement across most of the Southern Ocean, a few locations show offsets due to the modern land–sea mask used in the model. Additional considerations could account for many of the modest data–model anomalies, such as differences between calibration climatologies, the oversimplification of the seasonal cycle, and differences between SST proxies (i.e. seasonality and water depth). New SST estimates from data-sparse and regionally important areas will greatly enhance our ability to judge model performance.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

Paleoceanographic, and paleoclimatic constraints on the global Eocene diatom and silicoflagellate record

Eocene diatom and silicoflagellate biostratigraphy are summarized and correlated with the most recent geologic time scale as well as with the global oxygen isotope and eustatic sea level curves. The global distribution of Eocene diatom/silicoflagellate-bearing sediments varies considerably, reflecting changing oceanic gateways and paleoceanography with changing patterns that are punctuated by four major depositional events. Event 1 (~ 49 million years ago, Ma), at the end of the Early Eocene Climatic Optimum (EECO), saw the cessation of diatom/silicoflagellate deposition in epicontinental regions of the North Sea region and in the northern Russia and the onset of biosilica deposition in the Arctic. Event 2 (~ 46 Ma), which coincided with intensification of the Middle Eocene cooling trend, marked the widespread expansion of diatom/silicoflagellate deposition in both the North and South Atlantic. A shift of diatom/silicoflagellate deposition from the Atlantic to the Pacific began at Event 3, at the end of the Middle Eocene Climatic Optimum (MECO) (~ 40 Ma), that was likely tied to the initial opening of the Drake Passage between Antarctica and South America. Event 4 (~ 39 Ma) coincided with a major sea level fall and a widespread deep-sea hiatus in the latest Middle Eocene. Late Eocene diatom/silicoflagellate deposition became more concentrated in middle-to-high latitude regions and coastal upwelling regions, particularly in the Pacific Ocean. Tabulation of the first and last occurrences of 132 biostratigraphically-important diatoms suggests increased species turnover during the latest Paleocene to earliest Eocene that may be in part due to a monographic effect. An increasing rate of evolution of new diatom species between ~ 46 and 43 Ma and after ~ 40 Ma coincides respectively with the widespread expansion of diatom deposition in the Atlantic and with an increased pole-to-equator thermal gradient that witnessed the expansion of diatoms in high latitude oceans and coastal upwelling settings.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

A 1300-year microfaunal record from the Beaufort Sea shelf indicates exceptional climate-related environmental changes over the last two centuries

The environments of Arctic Ocean nearshore areas experience high intra- and inter-annual variability, making it difficult to evaluate the impact of anthropogenic warming. However, a sediment record from the southern Canadian Beaufort Sea allowed us to reconstruct the impacts of climate and environmental changes over the last 1300 years along the northern Yukon coast, Canada. The coring site (PG2303; 69.513°N, 138.895°W; water depth 32 m) is located in the Herschel Basin, where high sedimentation rates (0.1–0.5 cm a −1 ) allowed analyses at sub-centennial to decadal resolutions. Benthic foraminiferal, ostracod, and tintinnid assemblages, as well as the stable isotope composition of the foraminifera Elphidium clavatum and Cassidulina reniforme were used as paleoclimatic and ecological indicators, while the age model was based on the combined radiometric data of 14 C, 210 Pb and 137 Cs . From ca 700 to 1050 CE, our data suggest penetration of offshore shelf-break waters inferred by the dominance of C. reniforme followed by the relatively abundant Triloculina trihedra in the foraminiferal assemblages as both species are associated with stable saline conditions. Afterwards, the occurrence of ostracods Kotoracythere arctoborealis and Normanicythere leioderma suggests influx of Pacific-sourced waters until ca. 1150 CE. From ∼1150–1650 CE, persistent frigid waters, limited sediment supply, and low abundances of microfossils suggest cold conditions with pervasive annual sea-ice cover that may have restricted upwelling of oceanic waters. After ∼1800 CE, the co-occurrence of Tintinnopsis fimbriata and bacterial/complex organic carbon feeder foraminifera ( Quinqueloculina stalkeri , Textularia earlandi and Stetsonia horvathi ), suggest an increased influence of freshwater rich in particulate organic matter, which may be related to the spreading of the Mackenzie River plume and/or increased coastal permafrost erosion during longer ice-free seasons. Based on these proxy data, the shift at ∼1800 CE marks the onset of regional warming, which further intensified after ∼1955 CE, likely in response to the anthropogenic forcing.

Alaska, Yukon↗

Lateglacial and Holocene climate, disturbance and permafrost peatland dynamics on the Seward Peninsula, western Alaska

Northern peatlands have accumulated large carbon (C) stocks, acting as a long-term atmospheric C sink since the last deglaciation. How these C-rich ecosystems will respond to future climate change, however, is still poorly understood. Furthermore, many northern peatlands exist in regions underlain by permafrost, adding to the challenge of projecting C balance under changing climate and permafrost dynamics. In this study, we used a paleoecological approach to examine the effect of past climates and local disturbances on vegetation and C accumulation at a peatland complex on the southern Seward Peninsula, Alaska over the past ∼15 ka (1 ka = 1000 cal yr BP). We analyzed two cores about 30 m apart, NL10-1 (from a permafrost peat plateau) and NL10-2 (from an adjacent thermokarst collapse-scar bog), for peat organic matter (OM), C accumulation rates, macrofossil, pollen and grain size analysis. A wet rich fen occurred during the initial stages of peatland development at the thermokarst site (NL10-2). The presence of tree pollen from Picea spp. and Larix laricinia at 13.5–12.1 ka indicates a warm regional climate, corresponding with the well-documented Bølling–Allerød warm period. A cold and dry climate interval at 12.1–11.1 ka is indicated by the disappearance of tree pollen and increase in Poaceae pollen and an increase in woody material, likely representing a local expression of the Younger Dryas (YD) event. Following the YD, the warm Holocene Thermal Maximum (HTM) is characterized by the presence of Populus pollen, while the presence of Sphagnum spp. and increased C accumulation rates suggest high peatland productivity under a warm climate. Toward the end of the HTM and throughout the mid-Holocene a wet climate-induced several major flooding disturbance events at 10 ka, 8.1 ka, 6 ka, 5.4 ka and 4.7 ka, as evidenced by decreases in OM, and increases in coarse sand abundance and aquatic fossils (algae Chara and water fleas Daphnia ). The initial peatland at permafrost site (NL10-1) is characterized by rapid C accumulation (66 g C m −2 yr −1 ), high OM content and a peak in Sphagnum spp. at 5.8–4.6 ka, suggesting the lack of permafrost. A transition to extremely low C accumulation rates of 6.3 g C m −2 yr −1 after 4.5 ka at this site suggests the onset of permafrost aggradation, likely in response to Neoglacial climate cooling as documented across the circum-Arctic region. A similar decrease in C accumulation rates also occurred at non-permafrost site NL10-2. Time-weighted C accumulation rates are 21.8 g C m −2 yr −1 for core NL10-1 during the last ∼6.5 ka and 14.8 g C m −2 yr −1 for core NL10-2 during the last ∼15 ka. Evidence from peat-core analysis and historical aerial photographs shows an abrupt increase in Sphagnum spp. and decrease in area of thermokarst lakes over the last century, suggesting major changes in hydrology and ecosystem structure, likely due to recent climate warming. Our results show that the thermokarst–permafrost complex was much more dynamic with high C accumulation rates under warmer climates in the past, while permafrost was stabilized and C accumulation slowed down following the Neoglacial cooling in the late Holocene. Furthermore, permafrost presence at local scales is controlled by both regional climate and site-specific factors, highlighting the challenge in projecting responses of permafrost peatlands and their C dynamics to future climate change.

Alaska↗

Evaluating CO2 and CH4 dynamics of Alaskan ecosystems during the Holocene Thermal Maximum

The Arctic has experienced much greater warming than the global average in recent decades due to polar amplification. Warming has induced ecological changes that have impacted climate carbon-cycle feedbacks, making it important to understand the climate and vegetation controls on carbon (C) dynamics. Here we used the Holocene Thermal Maximum (HTM, 11–9 ka BP, 1 ka BP = 1000 cal yr before present) in Alaska as a case study to examine how ecosystem Cdynamics responded to the past warming climate using an integrated approach of combining paleoecological reconstructions and ecosystem modeling. Our paleoecological synthesis showed expansion of deciduous broadleaf forest (dominated by Populus ) into tundra and the establishment of boreal evergreen needleleaf and mixed forest during the second half of the HTM under a warmer- and wetter-than-before climate, coincident with the occurrence of the highest net primary productivity, cumulative net ecosystem productivity, soil C accumulation and CH 4 emissions. These series of ecological and biogeochemical shifts mirrored the solar insolation and subsequent temperature and precipitation patterns during HTM, indicating the importance of climate controls on C dynamics. Our simulated regional estimate of CH 4 emission rates from Alaska during the HTM ranged from 3.5 to 6.4 Tg CH 4 yr −1 and highest annual NPP of 470 Tg C yr −1 , significantly higher than previously reported modern estimates. Our results show that the differences in static vegetation distribution maps used in simulations of different time slices have greater influence on modeled C dynamics than climatic fields within each time slice, highlighting the importance of incorporating vegetation community dynamics and their responses to climatic conditions in long-term biogeochemical modeling.

Alaska↗

A satellite snow depth multi-year average derived from SSM/I for the high latitude regions

The hydrological cycle for high latitude regions is inherently linked with the seasonal snowpack. Thus, accurately monitoring the snow depth and the associated aerial coverage are critical issues for monitoring the global climate system. Passive microwave satellite measurements provide an optimal means to monitor the snowpack over the arctic region. While the temporal evolution of snow extent can be observed globally from microwave radiometers, the determination of the corresponding snow depth is more difficult. A dynamic algorithm that accounts for the dependence of the microwave scattering on the snow grain size has been developed to estimate snow depth from Special Sensor Microwave/Imager (SSM/I) brightness temperatures and was validated over the U.S. Great Plains and Western Siberia. The purpose of this study is to assess the dynamic algorithm performance over the entire high latitude (land) region by computing a snow depth multi-year field for the time period 1987-1995. This multi-year average is compared to the Global Soil Wetness Project-Phase2 (GSWP2) snow depth computed from several state-of-the-art land surface schemes and averaged over the same time period. The multi-year average obtained by the dynamic algorithm is in good agreement with the GSWP2 snow depth field (the correlation coefficient for January is 0.55). The static algorithm, which assumes a constant snow grain size in space and time does not correlate with the GSWP2 snow depth field (the correlation coefficient with GSWP2 data for January is - 0.03), but exhibits a very high anti-correlation with the NCEP average January air temperature field (correlation coefficient - 0.77), the deepest satellite snow pack being located in the coldest regions, where the snow grain size may be significantly larger than the average value used in the static algorithm. The dynamic algorithm performs better over Eurasia (with a correlation coefficient with GSWP2 snow depth equal to 0.65) than over North America (where the correlation coefficient decreases to 0.29). ?? 2007 Elsevier Inc. All rights reserved.

Remote Sensing of Environment↗

Elevated levels of radiocarbon in methane dissolved in seawater reveal likely local contamination from nuclear powered vessels

Measurements of the natural radiocarbon content of methane ( 14 C-CH 4 ) dissolved in seawater and freshwater have been used to investigate sources and dynamics of methane. However, during investigations along the Atlantic, Pacific, and Arctic Ocean Margins of the United States, as well as in the North American Great Lakes, some samples revealed highly elevated 14 C-CH 4 values, as much as 4–5 times above contemporary atmospheric 14 C-CH 4 levels. Natural production of the 14 CH 4 isotopologue is too low to cause these observations nor can it explain the variations in location and depth. Numerous lab and field validation tests and blanks, as well as the relatively small number of samples that display these elevated values, all suggest that these signals are not derived from an unknown procedural issue. Here we suggest that the byproducts of nuclear power generation include localized discharges of the 14 CH 4 isotopologue into marine and aquatic environments, severely altering the measured 14 C-CH 4 isotopic signals. Since several of our sample sites are distant from on-land nuclear powerplants, we conduct further calculations concluding that the most elevated anomalies in 14 C-CH 4 likely originate with discharge from nuclear-powered vessels.

Maryland, North Carolina, Oregon, Virginia, Washin↗

Seasonal comparisons of sea ice concentration estimates derived from SSM/I, OKEAN, and RADARSAT data

The Special Sensor Microwave Imager (SSM/I) microwave satellite radiometer and its predecessor SMMR are primary sources of information for global sea ice and climate studies. However, comparisons of SSM/I, Landsat, AVHRR, and ERS-1 synthetic aperture radar (SAR) have shown substantial seasonal and regional differences in their estimates of sea ice concentration. To evaluate these differences, we compared SSM/I estimates of sea ice coverage derived with the NASA Team and Bootstrap algorithms to estimates made using RADARSAT, and OKEAN-01 satellite sensor data. The study area included the Barents Sea, Kara Sea, Laptev Sea, and adjacent parts of the Arctic Ocean, during October 1995 through October 1999. Ice concentration estimates from spatially and temporally near-coincident imagery were calculated using independent algorithms for each sensor type. The OKEAN algorithm implemented the satellite's two-channel active (radar) and passive microwave data in a linear mixture model based on the measured values of brightness temperature and radar backscatter. The RADARSAT algorithm utilized a segmentation approach of the measured radar backscatter, and the SSM/I ice concentrations were derived at National Snow and Ice Data Center (NSIDC) using the NASA Team and Bootstrap algorithms. Seasonal and monthly differences between SSM/I, OKEAN, and RADARSAT ice concentrations were calculated and compared. Overall, total sea ice concentration estimates derived independently from near-coincident RADARSAT, OKEAN-01, and SSM/I satellite imagery demonstrated mean differences of less than 5.5% (S.D.<9.5%) during the winter period. Differences between the SSM/I NASA Team and the SSM/I Bootstrap concentrations were no more than 3.1% (S.D.<5.4%) during this period. RADARSAT and OKEAN-01 data both yielded higher total ice concentrations than the NASA Team and the Bootstrap algorithms. The Bootstrap algorithm yielded higher total ice concentrations than the NASA Team algorithm. Total ice concentrations derived from OKEAN-01 and SSM/I satellite imagery were highly correlated during winter, spring, and fall, with mean differences of less than 8.1% (S.D.<15%) for the NASA Team algorithm, and less than 2.8% (S.D.<13.8%) for the Bootstrap algorithm. Respective differences between SSM/I NASA Team and SSM/I Bootstrap total concentrations were less than 5.3% (S.D.<6.9%). Monthly mean differences between SSM/I and OKEAN differed annually by less than 6%, with smaller differences primarily in winter. The NASA Team and Bootstrap algorithms underestimated the total sea ice concentrations relative to the RADARSAT ScanSAR no more than 3.0% (S.D.<9%) and 1.2% (S.D.<7.5%) during cold months, and no more than 12% and 7% during summer, respectively. ScanSAR tended to estimate higher ice concentrations for ice concentrations greater than 50%, when compared to SSM/I during all months. ScanSAR underestimated total sea ice concentration by 2% compared to the OKEAN-01 algorithm during cold months, and gave an overestimation by 2% during spring and summer months. Total NASA Team and Bootstrap sea ice concentration estimates derived from coincident SSM/I and OKEAN-01 data demonstrated mean differences of no more than 5.3% (S.D.<7%), 3.1% (S.D.<5.5%), 2.0% (S.D.<5.5%), and 7.3% (S.D.<10%) for fall, winter, spring, and summer periods, respectively. Large disagreements were observed between the OKEAN and NASA Team results in spring and summer for estimates of the first-year (FY) and multiyear (MY) age classes. The OKEAN-01 algorithm and data tended to estimate, on average, lower concentrations of young or FY ice and higher concentrations of total and MY ice for all months and seasons. Our results contribute to the growing body of documentation about the levels of disparity obtained when seasonal sea ice concentrations are estimated using various types of satellite data and algorithms.

Remote Sensing of Environment↗

Offshore-onshore correlation of upper Pleistocene strata, New Jersey Coastal Plain to continental shelf and slope

High-resolution seismic reflection profiles (~ 1-5 m resolution), including Geopulse(TM), Uniboom(TM), minisparker, small air gun, and water gun sources, are used to trace the ?? 18O stage 5 portion of the outcropping Cape May Formation across the shelf to the continental slope. The ?? 18O stage 5/6 boundary identified at Ocean Drilling Project (ODP) Site 903 on the continental slope anchors the onshore-offshore seismic correlations. Above the ?? 18O stage 5 sequence, there are distinguishable lowstand systems tracts (LST), transgressive systems tracts (TST) and highstand systems tracts (HST) that correlate with ?? 18O stages 4 through 1. Atlantic Margin Coring Project (AMCOR) holes 6009, 6010, 6011, 6020, and 6021C provide age and paleoenvironmental indicators that agree with these correlations. The sub-arctic paleoenvironmental indicators in sequences of ?? 18O stage 3 agree with the cooler temperatures and lower sea-level highstands of that time. Thicker ?? 18O stage 3 and 4 sequences are preserved in the Paleo-Hudson River incised valley across the shelf. The expanded ice sheets during stage ?? 18O 3 compared to ?? 18O stages 1 and 5 probably increased sediment discharge in the Hudson River drainage system. (C) 2000 Elsevier Science B.V. All rights reserved.

Conference Paper↗

Sea-ice processes in the Laptev Sea and their importance for sediment export

Based on remote-sensing data and an expedition during August-September 1993, the importance of the Laptev Sea as a source area for sediment-laden sea ice was studied. Ice-core analysis demonstrated the importance of dynamic ice-growth mechanisms as compared to the multi-year cover of the Arctic Basin. Ice-rafted sediment (IRS) was mostly associated with congealed frazil ice, although evidence for other entrainment mechanisms (anchor ice, entrainment into freshwater ice) was also found. Concentrations of suspended particulate matter (SPM) in patches of dirty ice averaged at 156 g m-3 (standard deviation ?? = 140 g m-3), with a background concentration of 5 g m-3. The potential for sediment entrainment over the broad, shallow Laptev Sea shelf during fall freeze-up was studied through analysis of remote-sensing data and weather-station records for the period 1979-1994. Freeze-up commences on 26 September (?? = 7 d) and is completed after 19 days (?? = 6 d). Meteorological conditions as well as ice extent prior to and during freeze-up vary considerably, the open-water area ranging between 107 x 103 and 447 x 103 km2. Ice motion and transport of IRS were derived from satellite imagery and drifting buoys for the period during and after the expedition (mean ice velocities of 0.04 and 0.05 m s-1, respectively). With a best-estimate sediment load of 16 t km-2 (ranging between 9 and 46 t km-2), sediment export from the eastern Laptev Sea amounts to 4 x 10-6 t yr-1, with extremes of 2 x 10-6 and 11 x 106 t yr-1. Implications for the sediment budget of the Laptev shelf, in particular with respect to riverine input of SPM, which may be of the same order of magnitude, are discussed.

Continental Shelf Research↗

Regional analysis of spiculite faunas in the permian phosphoria basin: Implications for paleoceanography

The sponge spiculites of the Permian Phosphoria basin, Antler high, and eastern Havallah basin were the southernmost expression of one of the largest spiculite belts in the Earth's history. This spiculite belt extended from Nevada to the Barents Sea. In Idaho and Nevada, the spicule populations of this belt are dominated by demosponge spicules and are distinctive for their abundant rhax microscleres, large monaxons, and lithistid desmas. They form an Eastern Belt of spiculites that interfingers with spicule assemblages derived from choristid demosponges and hexactinellids that lived along the eastern margin of the deeper Havallah basin. The Havallah basin assemblages are similar to those in Permian arc terranes to the west, and together the sponge populations in this domain constitute a dis- tinct Central Belt. Radiolarians are virtually absent in the siliceous microfossil populations of the Eastern Belt, abundant in the populations of the Central Belt, and dominant in the populations of a Western Belt confined to Mesozoic accretionary complexes in the Pacific Coast States. The scattered sponge spicules in the Western Belt radiolarites were derived from hexactinellids. During the Permian, the relative abundance and apparent diversity of siliceous sponges expanded over a wide range of depths in the basins from Nevada and Idaho to the open ocean. Radiolarian preservation and apparent diversity increased in the deeper Cordilleran basins as well. In the Arctic regions, significant sponge spiculites were deposited in epicratonic basins. At the same time that siliceous sponge populations expanded along the northwestern margin of Pangea, warm-water carbonate producers disappeared. Suppression of carbonate-producing organisms along the margin was critical to the accu- mulation and preservation of both the demosponge spiculites in the Eastern Belt and the spicule-rich argillites of the Central Belt. Vigorous thermohaline circulation was the major control on the paleobiogeography of the late Early, Middle, and early Late Permian along northwest Pangea. It was driven by cold, nutrient- and oxygen-rich northern waters and it produced a coastal current that swept down the margin of the supercontinent. The upwelling associated with deposition of world-class phosphorites in the Phosphoria basin was a part of this larger oceanographic system.

Handbook of Exploration and Environmental Geochemi↗

Overview of the oxygen isotope systematics of land snails from North America

Continental paleoclimate proxies with near-global coverage are rare. Land snail δ 18 O is one of the few proxies abundant in Quaternary sediments ranging from the tropics to the high Arctic tundra. However, its application in paleoclimatology remains difficult, attributable in part to limitations in published calibration studies. Here we present shell δ 18 O of modern small (<10 mm) snails across North America, from Florida (30°N) to Manitoba (58°N), to examine the main climatic controls on shell δ 18 O at a coarse scale. This transect is augmented by published δ 18 O values, which expand our coverage from Jamaica (18°N) to Alaska (64°N). Results indicate that shell δ 18 O primarily tracks the average annual precipitation δ 18 O. Shell δ 18 O increases 0.5–0.7‰ for every 1‰ increase in precipitation δ 18 O, and 0.3–0.7‰ for every 1°C increase in temperature. These relationships hold true when all taxa are included regardless of body size (ranging from ~1.6 to ~58 mm), ecology (herbivores, omnivores, and carnivores), or behavior (variable seasonal active periods and mobility habits). Future isotopic investigations should include calibration studies in tropical and high-latitude settings, arid environments, and along altitudinal gradients to test if the near linear relationship between shell and meteoric precipitation δ 18 O observed on a continental scale remains significant.

Quaternary Research↗

Late Neogene marine Ostracoda from Tjornes, Iceland

On the western side of the Tjörnes Peninsula in northern Iceland exposures of fossiliferous marine sediments, basalts, and glacial tills record the climatic history of this region of the North Atlantic Ocean. Seventy-five marine ostracode species were recovered from the Pliocene Tjörnes sediments and Quaternary sediments known as the Breidavik beds. The ostracode assemblages contain many warm-water genera that do not inhabit Iceland today and indicate early to middle Pliocene (4.5–3.0 Ma) winter and summer bottom-water temperatures that averaged 5–6°C and 14–16°C, respectively (maximum 20°C in summer, rarely below 3°C in winter except during a brief cooling 3.5–3.2 Ma). An intensified North Atlantic Drift and a diminished or absent East Greenland Current account for warm-water oceanographic conditions at 66°N. Late Pliocene marine climates were cooler with winter and summer averages of about 9°C and 8°C. Early Pleistocene ostracode assemblages dated at 1.7–1.3 Ma contain extant arctic–subarctic species that indicate winter and summer temperatures of about − 1.5°C and 4–5°C. New species Bensonocythere eirikssoni, Robertsonites williamsi, Hemicythere rekaensis, Thaerocythere mayburyae, Thaerocythere whatleyi, Leptocythere tjornesensis, Tetracytherura bardarsoni , and Cytheromorpha einarssoni are described.

Journal of Paleontology↗

Trends and population estimate of the threatened Buff-breasted Sandpiper Calidris subruficollis wintering in coastal grasslands of southern Brazil

Information about population sizes, trends, and habitat use is key for species conservation and management. The Buff-breasted Sandpiper Calidris subruficollis (BBSA) is a long-distance migratory shorebird that breeds in the Arctic and migrates to south-eastern South America, wintering in the grasslands of southern Brazil, Uruguay, and Argentina. Most studies of Nearctic migratory species occur in the Northern Hemisphere, but monitoring these species at non-breeding areas is crucial for conservation during this phase of the annual cycle. Our first objective was to estimate trends of BBSA at four key areas in southern Brazil during the non-breeding season. We surveyed for BBSA and measured vegetation height in most years from 2008/09 to 2019/20. We used hierarchical distance sampling models in which BBSA abundance and density were modelled as a function of vegetation height and corrected for detectability. Next, we used on-the-ground surveys combined with satellite imagery and habitat classification models to estimate BBSA population size in 2019/20 at two major non-breeding areas. We found that abundance and density were negatively affected by increasing vegetation height. Abundance fluctuated five- to eight-fold over the study period, with peaks in the middle of the study (2014/15). We estimated the BBSA wintering population size as 1,201 (95% credible interval [CI]: 637–1,946) birds in Torotama Island and 2,232 (95% CI: 1,199–3,584) in Lagoa do Peixe National Park during the 2019/20 austral summer. Although no pronounced trend was detected, BBSA abundance fluctuated greatly from year to year. Our results demonstrate that only two of the four key areas hold high densities of BBSA and highlight the positive effect of short grass on BBSA numbers. Short-grass coastal habitats used by BBSA are strongly influenced by livestock grazing and climate, and are expected to shrink in size with future development and climatic changes.

Bird Conservation International↗

Fifteen years of WRTDS for advancing water-quality science: A critical review of methodological developments and global applications

Contamination by nutrients, major ions, and metals poses a major threat to global water sustainability. Understanding how these pollutants vary across time and space requires long-term monitoring and robust statistical approaches. Traditional methods, however, often struggle to account for streamflow variability, seasonality, and nonlinear responses. Introduced in 2010, the Weighted Regressions on Time, Discharge, and Season (WRTDS) method offers a flexible, data-driven framework that generates both observed and flow-normalized estimates of concentration and load. Over the past 15 years, WRTDS has become a state-of-the-art tool for water-quality science and management, with applications spanning a wide range of hydrologic, climatic, and policy contexts─including major watersheds across North America, Europe, Asia, Australia, and the Arctic. In this review of WRTDS, we document the method’s major advancements, examine its expanding geographic and thematic applications, and summarize its relevance to water-quality management programs and policies worldwide. We also discuss its performance relative to other regression and machine-learning approaches. Finally, we identify key priorities for future development to support the continued evolution of WRTDS as a trusted and practical tool for scientists and managers working to protect and sustain water resources.

Environmental Science and Technology↗

Ecological change drives a decline in mercury concentrations in southern Beaufort Sea polar bears

We evaluated total mercury (THg) concentrations and trends in polar bears from the southern Beaufort Sea subpopulation from 2004 to 2011. Hair THg concentrations ranged widely among individuals from 0.6 to 13.3 μg g –1 dry weight (mean: 3.5 ± 0.2 μg g –1 ). Concentrations differed among sex and age classes: solitary adult females ≈ adult females with cubs ≈ subadults > adult males ≈ yearlings > cubs-of-the-year ≈ 2 year old dependent cubs. No variation was observed between spring and fall samples. For spring-sampled adults, THg concentrations declined by 13% per year, contrasting recent trends observed for other Western Hemispheric Arctic biota. Concentrations also declined by 15% per year considering adult males only, while a slower, nonsignificant decrease of 4.4% per year was found for adult females. Lower THg concentrations were associated with higher body mass index (BMI) and higher proportions of lower trophic position food resources consumed. Because BMI and diet were related, and the relationship to THg was strongest for BMI, trends were re-evaluated adjusting for BMI as the covariate. The adjusted annual decline was not significant. These findings indicate that changes in foraging ecology, not declining environmental concentrations of mercury, are driving short-term declines in THg concentrations in southern Beaufort Sea polar bears.

Alaska↗

Crystal chemistry of thallium in marine ferromanganese deposits

Our understanding of the up to 7 orders of magnitude partitioning of thallium (Tl) between seawater and ferromanganese (FeMn) deposits rests upon two foundations: (1) being able to quantify the Tl(I)/Tl(III) ratio that reflects the extent of the oxidative scavenging of Tl by vernadite (δ-MnO 2 ), the principle manganate mineral in oxic and suboxic environments, and (2) being able to determine the sorption sites and bonding environments of the Tl(I) and Tl(III) complexes on vernadite. We investigated these foundations by determining the oxidation state and chemical form of Tl in FeMn crusts and nodules from the global oceans at a Tl concentration ranging from several hundred ppm (mg/kg) down to the low ppm level. Seventeen hydrogenetic crusts and eleven nodules from the Pacific, Atlantic, Arctic, and Indian Oceans and Baltic Sea were characterized by chemical analysis, X-ray diffraction, Raman spectroscopy, Mn K-edge X-ray absorption near-edge structure (XANES) spectroscopy, Tl L 3 -edge high energy-resolution XANES (HR-XANES) spectroscopy, and extended X-ray absorption fine structure (EXAFS) spectroscopy. The Tl concentration increases linearly from 1.5 to 319 ppm with the Mn/Fe ratio in Fe-vernadite from hydrogenetic crusts, whereas the percentage of Tl(III) to total Tl varies between 62 and 100% independent of both the Mn/Fe and Mn(III)/Mn(IV) ratios. The data, complemented by molecular modeling of the Tl(III) coordination and by XANES calculations, suggest that the enrichment of Tl in Fe-vernadite is driven by (1) the oxidative uptake of octahedrally coordinated Tl(III) above the vacant Mn(IV) sites and on the layer edges of the vernadite layers, and (2) the sorption of Tl(I) on the crystallographic site of Ba at the surface of the vernadite layers, which is an analogue to the surface site of K. Thus, Tl has a high affinity for vernadite regardless of its oxidation state, and the lack of correlation between Tl(III) and the Mn/Fe ratio in FeMn crusts is explained by the affinity of Tl(I) for the Ba site. The Tl concentration varies between 2 and 112 ppm in surface and buried nodules independent of the Mn/Fe ratio, and the percentage of Tl(III) varies between 0 and 100%. Nodules subjected to sediment diagenesis with replacement of layered vernadite by tunneled todorokite are depleted in Tl and have more reduced thallium. Knowledge of the complex interplay of mineralogy, surface chemical processes, and crystallographic siting is required to understand the variability of Tl concentrations, redox state, and acquisition processes by marine FeMn deposits.

ACS Earth and Space Chemistry↗

Methane clumped isotopologue variability from ebullition in a mid-latitude lake

Methane is a greenhouse gas and is an important component of carbon cycling in freshwater environments. Isotope ratios of methane ( 13 C/ 12 C and D/H) are used extensively as tracers to identify methane sources. Recent advances in the measurement of clumped methane isotopologues ( 13 CH 3 D, 12 CH 2 D 2 ) offer new opportunities to constrain sources and sinks of atmospheric methane. Previous measurements of clumped methane isotopologues from freshwater environments have been spatially and temporally limited. The abundance of 13 CH 3 D and methane flux from ebullition in the deep basin of Upper Mystic Lake were measured from May to November 2021 to characterize the source isotopologue signatures and methane fluxes for mid-latitude lakes. The trends in δ 13 C and δD values support decreased methane oxidation in the early summer compared to fall. The Δ 13 CH 3 D values from this study range from 2.0 to 4.2‰, reflecting methane oxidation occurring anaerobically in lake sediments and euxinic bottom waters at sample sites. The relatively large variation in the Δ 13 CH 3 D values observed within this lake basin aligns with previous observations of bubbles from arctic lakes. The values of Δ 13 CH 3 D do not correlate with methane flux, suggesting that Δ 13 CH 3 D measurements from background ebullition are not sensitive as a proxy for ebullition rates. This study presents a uniquely large ( n = 40) set of freshwater Δ 13 CH 3 D values from a single lake basin, which we use to recommend a sampling strategy of ≥9 samples to constrain the Δ 13 CH 3 D source signal within ∼0.5‰ from similar environments. This data demonstrates the utility of clumped methane isotopologues to gain insights into local biogeochemical processes from field studies and points to the challenge of using clumped isotopologue measurements to constrain global freshwater–methane sources to the atmosphere.

ACS Earth and Space Chemistry↗