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Pesticides in surface water from three agricultural basins in south-central Georgia, 1993-97

Twenty-two of 43 pesticides analyzed were detected in 128 water samples collected from the Tucsawhatchee Creek, the Little River, and the Withlacoochee River. These streams drain agricultural basins in south-central Georgia and were sampled from March 1993 through June 1995. Herbicides were detected more frequently than insecticides. The most frequently detected herbicides were atrazine and metolachlor and the most frequently detected insecticide was carbaryl. Pesticide concentrations in the three streams were low and did not exceed U.S. Environmental Protection Agency drinking water standards. The maximum pesticide concentration was 2.6 mg/L (micrograms per liter) for propargite, a miticide detected in only one sample. The maximum concentrations of the remaining 21 pesticides were less than 0.25 mg/L. The median concentrations were equal to the method detection limit for all pesticides except atrazine (0.008 mg/L) and metolachlor (0.012 mg/L). The ratio of herbicide detections to nondetections was largest in the planting season, smaller in the harvest season and smallest in the fallow season for the three basins. The same pattern existed for the insecticide ratios in the Little River and the Withlacoochee River. Pairwise correlations between concentrations of atrazine and metolachlor, and four parameters (discharge, and concentrations of dissolved organic carbon, suspended organic carbon, and suspended sediment) were evaluated for each stream. The strongest correlations existed between metolachlor and mean daily discharge, and metolachlor and sediment in the Withlacoochee River. The only significant correlation for the Little River was between atrazine and suspended sediment.

Georgia

Assessment of extreme subsurface hydrologic conditions captured during atmospheric river storms in the San Francisco Bay area (California, USA) with applications to shallow landslide early warning

An increase in soil pore water pressure is the typical trigger for the majority of landslides caused by rainfall. Atmospheric river storms, common to the west coast of North America during the winter season, can deliver landslide triggering rainfall resulting in severe impacts to coastal communities. Using a network of hydrologic monitoring stations situated within landslide-prone terrain in the San Francisco Bay area of California (USA), we assess the meteorologic conditions and resulting hydrologic and landslide response resulting from eight consecutive storm events that caused thousands of shallow landslides during the winter of 2022–2023. We find disparate hydrological responses and resultant degrees of observed landsliding ranging from < 1 landslide/km2 to 18 landslides/km2 at the monitoring sites that reflect the interplay and differences between rainfall delivery, subsurface hydrological characteristics, and geotechnical properties at each site. Antecedent soil moisture from both early season rainfall and the first storm in the sequence played a critical role in setting up some hillslopes for failure. Subsequent storms then generated elevated pore water pressures for several hours with associated landsliding. However, we find that the occurrence of widespread landsliding required not only sufficient pore water pressure magnitude in susceptible hillslopes, but also full and prolonged effective soil saturation throughout hillslope profiles. Landslides may still occur at lower values and durations of effective saturation but are likely to be less extensive regionally. We present these findings within the context of research directions and improvements to landslide early warning systems first suggested by researchers 40 years ago.

California

Hydrogeologic conceptualization of the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory, Edwards Air Force Base, Antelope Valley, California, 2017–21

Research and testing within the Air Force Research Laboratory at Edwards Air Force Base in the southwestern Mojave Desert has been conducted since the 1950s. This testing requires large quantities of groundwater for cooling and operations involving hazardous constituents that have entered the groundwater. To better understand the potential movement of contaminants through the groundwater system, the U.S. Geological Survey entered into a cooperative agreement with the U.S. Air Force Civil Engineer Center with the purpose of (1) gaining a more detailed understanding of the hydraulic connection between the unconsolidated basin-fill sediment and the underlying weathered and crystalline bedrock and (2) investigating faults and their potential effect on groundwater flow. This study was specific to the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory. The refined hydrogeologic characterization was derived by evaluating surface geologic maps, a regional gravity model, new subsurface geophysical surveys, lithology data from boreholes, and groundwater-level data. Refinement of the hydrogeologic characterization of the study area involved developing a map of basin-fill sediment thickness, estimating the geometry and depth to bedrock, determining the presence of weathered bedrock material, and identifying the location of faults and subsurface structures. The thickness of basin-fill sediment was derived from a regional gravity model. Basin-fill sediment ranges from less than 20 feet (ft) thick to about 150 ft thick and increases substantially toward a deep structural basin in the northwestern part of the study area. The top of bedrock estimated from the new surface geophysical surveys is generally deeper than the top of bedrock from the regional gravity model. These differences in interpreted bedrock tops indicate that there may be a zone of weathered bedrock in the subsurface, overlying crystalline bedrock. Additional subsurface data evaluating the geometry and thickness of weathered bedrock are necessary for a comprehensive evaluation of weathered bedrock in the study area. Previously unmapped extensions of the Leuhman Fault, Spring Fault Zone, and Boron Gate Fault were identified in the new surface geophysical surveys. Evaluation of groundwater flow between bedrock and basin-fill sediment, and the effects of faults on groundwater flow, was done using groundwater-level data from 2020. The groundwater table was in crystalline bedrock throughout most of the Arroyos and Northeast Air Force Research Laboratory subareas, with a few exceptions where it was in basin-fill sediment and weathered bedrock. Basin-fill sediment, and likely weathered bedrock, was partially saturated in parts of the study area where basin-fill sediment was as thick as 150 ft. Weathered bedrock material may be present near the Spring Fault Zone, and if so, was likely saturated in 2020. The groundwater-level data near and within Spring Fault Zone indicate that the Spring Fault Zone acts as a vertical-along-strike conduit for, and as an across-strike impediment to, groundwater flow. In addition, steep groundwater-level gradients in the southeastern part of the study area indicate that a subsurface structure affecting groundwater flow could be related to the Leuhman Fault. Sufficient groundwater-level data were not available to conclusively determine if the Arroyos, Rich, and Boron Gate Faults, and their inferred extensions from the geophysical surveys, affect the movement or direction of groundwater flow.

California

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Stream habitat characteristics at selected sites in the Georgia-Florida coastal plain

Habitat characterization is part of a multidisciplinary approach to water-quality assessment implemented by the National Water-Quality Assessment Program. Habitat data were collected in the Georgia-Florida Coastal Plain study unit at 24 sites during 1993-95. Data were collected for habitat characteristics at three spatial scales: basin, segment, and reach. Basin data include physiography, land resource provinces, and land use, providing a description of the environmental setting at each site. Segment data include length, gradient, and sinuosity. A Kendall correlation analysis performed on segment characteristics and the log-of-basin area showed a correlation between segment gradient and the log-of-basin area and a correlation between sinuosity and segment length. Reach data consist of field-collected measurements of both instream and riparian habitats. Sand and detritus were the most common channel-bed substrates among the sampled sites. Measurements of channel width, water depth, and bank width and height were used to create cross-sectional profiles of each sampled area. Elevations of selected durations plotted on cross sections illustrated the percentage of time that the banks were inundated at each site. Sites were divided into two groups based on duration of bank inundation (less than or equal to 1 percent and greater than 1 percent). Bank woody vegetation was also sampled and a clustering algorithm known as Two-Way INdicator SPecies ANalysis (TWINSPAN) was used to analyze these data. TWINSPAN divided the sites into two groups based on their vegetation composition. A statistical comparison of the two types of site groups (duration of bank inundation and vegetation) was performed. The significant association between these groups was consistent with the hypothesis that inundation frequency affected riparian vegetation.

Florida, Georgia

Special issue "Effects of surface geology on seismic motion (ESG): General state-of-research"

To understand and predict the behaviors of strong ground motions incurred during devastating earthquakes, studies focused on the “effects of surface geology (ESG) on seismic motions” (following tradition, herein contracted as: “ESG”) have progressed steadily in the last three decades. These ESG studies typically involve in situ measurements of the wavefield and commonly apply both analytical and computational approaches. Concurrently, improvements in ESG related research can be readily attributed to the proliferation of openly accessible strong motion data, as well as advances in computational power. Nevertheless, there remain significant shortfalls in our understanding of the epistemic and aleatory uncertainties associated with the ESG as demonstrated by phenomena from recent deadly earthquake-related site effects. Thus, investigations toward addressing these deficiencies should be underscored in future earthquake related disaster mitigation efforts. This special issue of Earth, Planets, and Space (EPS) is dedicated to the ongoing efforts by the International Association of Seismology and Physics of the Earth’s Interior (IASPEI) and the International Association of Earthquake Engineering (IAEE) that champion activities promoting studies related to the ESG.

Earth, Planets and Space

Scientific opportunities in the National Landscape Conservation System

The National Landscape Conservation System consists of unique and beautiful places across America’s landscapes where identified resources and values are protected and science is highlighted. The mission of the National Landscape Conservation System (NLCS), which is managed by the Bureau of Land Management and is often referred to as the agency’s National Conservation Lands, is to conserve, protect, and restore nationally significant landscapes for their cultural, ecological, and scientific values. This clear inclusion of science in the NLCS mission sets the stage for individual units to serve as places of learning, teaching, discovery, and innovation. Science is an integral part of managing the National Conservation Lands, and science conducted within and across the more than 900 units that make up the NLCS can inform and influence conservation and public land management well beyond its boundaries. Here, we highlight seven core aspects of National Conservation Lands that present valuable science opportunities: (1) the scientific values for which individual units are designated; (2) the many other resources, objects, and values within units; (3) the value of units as “control” sites for understanding the effects of activities such as mineral extraction that commonly occur elsewhere on multiple-use public lands but are often prohibited within National Conservation Lands; (4) the value of units for studying the effects of activities such as recreation that regularly occur and may be intensified on National Conservation Lands; (5) the high visibility of units, which draws strong interest and engagement from scientists, partners, and the public; (6) the functioning of the units as a network managed for a common purpose, which provides an opportunity to explore cross-cutting science questions across widely varying contexts and geographies; and (7) the opportunities units provide to promote and apply Indigenous Knowledge to scientific research to manage natural and cultural resources. Because of all of these characteristics, National Conservation Lands can serve as hubs for basic and applied science that can inform management of all public lands and resources into the future. We highlight these science opportunities through examples from existing units and suggest two actions that could help further science activities and impact on National Conservation Lands.

Parks Stewardship Forum

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal

Estimation of magnitude and frequency of floods for streams in Puerto Rico: New empirical models

Flood-peak discharges and frequencies are presented for 57 gaged sites in Puerto Rico for recurrence intervals ranging from 2 to 500 years. The log-Pearson Type III distribution, the methodology recommended by the United States Interagency Committee on Water Data, was used to determine the magnitude and frequency of floods at the gaged sites having 10 to 43 years of record. A technique is presented for estimating flood-peak discharges at recurrence intervals ranging from 2 to 500 years for unregulated streams in Puerto Rico with contributing drainage areas ranging from 0.83 to 208 square miles. Loglinear multiple regression analyses, using climatic and basin characteristics and peak-discharge data from the 57 gaged sites, were used to construct regression equations to transfer the magnitude and frequency information from gaged to ungaged sites. The equations have contributing drainage area, depth-to-rock, and mean annual rainfall as the basin and climatic characteristics in estimating flood peak discharges. Examples are given to show a step-by-step procedure in calculating a 100-year flood at a gaged site, an ungaged site, a site near a gaged location, and a site between two gaged sites.

Puerto Rico

Simulation of the effects of development of the ground-water flow system of Long Island, New York

Extensive development on Long Island since the late 19th century and projections of increased urbanization and ground-water use makes effective water-resource management essential for preservation of the island's hydrologic environment and maintenance of a reliable source of water supply. This report presents results of a ground-water flow simulation analysis of the effects of development on the Long Island ground-water system. It describes ground-water levels, stream-flow, and the ground-water budget for the predevelopment period (pre-1900), the 1960's drought, and a more recent (1968-83) period with significant hydrologic stress. The report also presents estimated effects of a proposed water-supply strategy for the year 2020. Long Island has three major aquifers-the upper glacial (water-table), the Magothy, and the Lloyd aquifers-that are separated to varying degrees by confining units. Before development, recharge from precipitation entered the ground-water system at a rate of more than 1.1 billion gallons per day. An equal amount discharged to streams (41 percent), the shore (52 percent), and subsea boundaries (7 percent) . Urbanization and withdrawal of more than 400 Mgal/d (million gallons per day) from wells have resulted in local effects that include declines in ground-water levels, drying up and burial of streams and wetlands, reduction of ground-water recharge by increased overland flow to the ocean, a general decrease in ground-water discharge, and salt water intrusion. In some areas, the reduction in recharge is mitigated by leakage from water-supply and wastewater disposal lines, and infiltration of storm water through recharge basins. During 1968-83, a net loss of 240 Mgal/d from the ground-water system caused a decrease in ground-water discharge to streams (135 Mgal/d), to the shore (82 Mgal/d), and to subsea boundaries (23Mgal/d).The greatest adverse effects have been in western Long Island, where the most severe development has occurred. This analysis shows stream base flow to be highly sensitive to water-table fluctuations, and long streams to be more sensitive than short ones. A water-supply scenario for the year 2020 was simulated that employs redistribution of pumping centers to mitigate extreme local effects . Although the net stress on the ground-water system was projected to increase 57 Mgal/d (24 percent) above that of 1968-83, redistribution of ground-water withdrawals across the island would allow recovery of cones of depression in western Long Island, thereby reducing the threat of salt water intrusion and increasing base flow of some streams . The increased stress would cause a net decrease in base flow island wide of 44 Mgal/d; total base flow would be 281 Mgal/d - 39 percent below predevelopment levels or 14 percent below 1968-83 levels. The most severe effects would be in Nassau and western Suffolk Counties.

New York

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming

Quality assurance and analysis of water levels in wells on Pahute Mesa and vicinity, Nevada Test Site, Nye County, Nevada

Periodic and continual water-level data from 1963 to 1998 were compiled and quality assured for 65 observation wells on Pahute Mesa and vicinity, Nye County, Nevada. As part of the quality assurance of all water levels, ancillary data pertinent to computing hydraulic heads in wells were compiled and analyzed. Quality-assured water levels that were not necessarily in error but which did not represent static heads in the regional aquifer system, or required some other qualification, were flagged. Water levels flagged include those recovering from recent pumping or well construction, water levels affected by nuclear tests, and measurements affected by borehole deviations. A cursory examination of about 30 wells with available water-level and down-hole temperature data indicate that water levels in most wells on Pahute Mesa would not be significantly affected by temperature if corrected to 95 degrees Fahrenheit. Wells with large corrections (greater than 10 feet) are those with long water columns (greater than 1,500 feet of water above the assumed point of inflow) in combination with mean water-column temperatures exceeding 105 degrees Fahrenheit. Water-level fluctuations in wells on Pahute Mesa are caused by several factors including infiltration of precipitation, barometric pressure, Earth tides, ground-water pumpage, and seismic events caused by tectonic activity and underground nuclear testing. No observed water-level fluctuations were attributed to a naturally occurring earthquake. The magnitude and duration of changes in water levels caused by nuclear tests are affected by the test size and the distance from a well to the test. Identifying water levels that might be affected by past nuclear tests is difficult because pre-testing water-level data are sparse. Hydrologically significant trends were found in 13 of 25 wells with multiple years of water-level record. The largest change in water levels (1,029 feet in 25 years) occurred in well U-19v PS 1D as a result of the Almendro nuclear test. Likely explanations for trends in most of the wells are either changes in precipitation patterns that affect recharge rates to the ground-water system, pumping effects from water-supply well U-20 WW, or a combination of these two factors.

Nevada

Integrity of production wells and confining unit at the Naval Weapons Industrial Reserve Plant, Dallas, Texas, 1995

Ground water in the shallow alluvial aquifer is contaminated at the Naval Weapons Industrial Reserve Plant, Dallas, Texas. Five production wells at the site are cased through the alluvial aquifer and underlying units and are screened in either the Paluxy or Twin Mountains aquifers. Three abandoned wells, originally completed in the Twin Mountains aquifer but filled with drilling mud in 1958, also penetrate the alluvial aquifer. The Paluxy and Twin Mountains aquifers are used for drinking-water supplies in and around the Dallas-Fort Worth metroplex. Trichloroethylene and its degradation products, dichloroethylene and vinyl chloride, and the metal chromium previously have been detected in the shallow alluvial aquifer. Current (1995) analyses of water-quality samples taken from the static water column of the five production wells and one of the abandoned wells indicate no trichloroethylene, dichloroethylene, or vinyl chloride in the water column of these wells. Chromium was detected in all samples, but concentrations were less than the practical quantitation limit, which is the regulatory action level for this site. The results of borehole geophysical log analysis indicate that two of the production wells could have vertically connected intervals where cement bonding in the well annulus is poor. The other production wells have overall good bonding. Temperature logs do not indicate flow behind casing except in the screened interval of one well. Geophysical logs show the Eagle Ford Shale ranges from 147 to 185 feet thick at the site. The Eagle Ford Shale has low permeability and a high plasticity index. These physical characteristics make the Eagle Ford Shale an excellent confining unit.

Texas

Comparison of hydrologic data and water budgets between 2003–08 and 2018–23 for the eastern part of the Arbuckle-Simpson aquifer, south-central Oklahoma

The Arbuckle-Simpson aquifer is divided spatially into three parts (eastern, central, and western). The largest groundwater withdrawals are from the eastern part of the Arbuckle-Simpson aquifer, which provides water to approximately 39,000 people in Ada and Sulphur, Oklahoma, and surrounding areas. The Arbuckle-Simpson aquifer, including the eastern part, is designated a sole source aquifer for its service area. Based primarily on data collected between 2003 and 2008, a series of comprehensive hydrologic studies of the Arbuckle-Simpson aquifer was published to provide the information necessary to perform groundwater-flow model simulations so that the Oklahoma Water Resources Board could determine how much water could be withdrawn from the aquifer while maintaining flow to springs and streams. As part of the Phase 1 studies, an aquifer water budget was developed from a numerical model for the period 2003–08. For this report, Phase 1 refers to the 2003–08 data collection period, although for some of the analyses, data collected prior to 2003 were used to inform model development work. Allocation of water from this aquifer was then established by the Oklahoma Water Resources Board in 2013. Additional well-spacing rules were also established by the Oklahoma Water Resources Board for sensitive sole source groundwater basins. To determine how the water budget for the eastern part of the Arbuckle-Simpson aquifer has changed over time, recently collected hydrologic data (2018–23) were compared to data collected during 2003–08. The analysis of changes in the aquifer water budget from 2003–08 to 2018–23 could help resource managers better understand changes in the overall balance of water in storage and the potential effects on streamflow, changes in groundwater levels, and the effects of different water uses in the aquifer area on available water in the eastern part of the Arbuckle-Simpson aquifer and streams overlying the eastern part of the Arbuckle-Simpson aquifer.

Oklahoma

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Cecil Field Naval Air Station, Jacksonville, Florida

As part of the Installation Restoration Program, Cecil Field Naval Air Station, Jacksonville, Florida, is considering remedialaction alternatives to control the possible movement of contaminants from sites that may discharge to the surface. This requires a quantifiable understanding of ground-water flow through the surficial aquifer system and how the system will respond to any future stresses. The geologic units of interest in the study area consist of sediments of Holocene to Miocene age that extend from land surface to the base of the Hawthorn Group. The hydrogeology within the study area was determined from gamma-ray and geologists' logs. Ground-water flow through the surficial aquifer system was simulated with a seven-layer, finite-difference model that extended vertically from the water table to the top of the Upper Floridan aquifer. Results from the calibrated model were based on a long-term recharge rate of 6 inches per year, which fell in the range of 4 to 10 inches per year, estimated using stream hydrograph separation methods. More than 80 percent of ground-water flow circulates within the surficial-sand aquifer, which indicates that most contaminant movement also can be expected to move through the surficial-sand aquifer alone. The surficial-sand aquifer is the uppermost unit of the surficial aquifer system. Particle-tracking results showed that the distances of most flow paths were 1,500 feet or less from a given site to its discharge point. For an assumed effective porosity of 20 percent, typical traveltimes are 40 years or less. At all of the sites investigated, particles released 10 feet below the water table had shorter traveltimes than those released 40 feet below the water table. Traveltimes from contaminated sites to their point of discharge ranged from 2 to 300 years. The contributing areas of the domestic supply wells are not very extensive. The shortest traveltimes for particles to reach the domestic supply wells from their respective contributing areas ranged from 70 to 200 years.

Florida

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Estimating the probability of elevated nitrate (NO2+NO3-N) concentrations in ground water in the Columbia Basin Ground Water Management Area, Washington

Logistic regression was used to relate anthropogenic (man-made) and natural factors to the occurrence of elevated concentrations of nitrite plus nitrate as nitrogen in ground water in the Columbia Basin Ground Water Management Area, eastern Washington. Variables that were analyzed included well depth, depth of well casing, ground-water recharge rates, presence of canals, fertilizer application amounts, soils, surficial geology, and land-use types. The variables that best explain the occurrence of nitrate concentrations above 3 milligrams per liter in wells were the amount of fertilizer applied annually within a 2-kilometer radius of a well and the depth of the well casing; the variables that best explain the occurrence of nitrate above 10 milligrams per liter included the amount of fertilizer applied annually within a 3-kilometer radius of a well, the depth of the well casing, and the mean soil hydrologic group, which is a measure of soil infiltration rate. Based on the relations between these variables and elevated nitrate concentrations, models were developed using logistic regression that predict the probability that ground water will exceed a nitrate concentration of either 3 milligrams per liter or 10 milligrams per liter. Maps were produced that illustrate the predicted probability that ground-water nitrate concentrations will exceed 3 milligrams per liter or 10 milligrams per liter for wells cased to 78 feet below land surface (median casing depth) and the predicted depth to which wells would need to be cased in order to have an 80-percent probability of drawing water with a nitrate concentration below either 3 milligrams per liter or 10 milligrams per liter. Maps showing the predicted probability for the occurrence of elevated nitrate concentrations indicate that the irrigated agricultural regions are most at risk. The predicted depths to which wells need to be cased in order to have an 80-percent chance of obtaining low nitrate ground water exceed 600 feet in the irrigated agricultural regions, whereas wells in dryland agricultural areas generally need a casing in excess of 400 feet. The predicted depth to which wells need to be cased to have at least an 80-percent chance to draw water with a nitrate concentration less than 10 milligrams per liter generally did not exceed 800 feet, with a 200-foot casing depth typical of the majority of the area.

Washington