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Preserving prairies: Understanding temporal and spatial patterns of invasive annual bromes in the Northern Great Plains

Two Eurasian invasive annual brome grasses, cheatgrass ( Bromus tectorum ) and Japanese brome ( Bromus japonicus ), are well known for their impact in steppe ecosystems of the western United States where these grasses have altered fire regimes, reduced native plant diversity and abundance, and degraded wildlife habitat. Annual bromes are also abundant in the grasslands of the Northern Great Plains (NGP), but their impact and ecology are not as well studied. It is unclear whether the lessons learned from the steppe will translate to the mixed-grass prairie where native plant species are adapted to frequent fires and grazing. Developing a successful annual brome management strategy for National Park Service units and other NGP grasslands requires better understanding of (1) the impact of annual bromes on grassland condition; (2) the dynamics of these species through space and time; and (3) the relative importance of environmental factors within and outside managers' control for these spatiotemporal dynamics. Here, we use vegetation monitoring data collected from 1998 to 2015 in 295 sites to relate spatiotemporal variability of annual brome grasses to grassland composition, weather, physical environmental characteristics, and ecological processes (grazing and fire). Concern about the impact of these species in NGP grasslands is warranted, as we found a decline in native species richness with increasing annual brome cover. Annual brome cover generally increased over the time of monitoring but also displayed a 3- to 5-yr cycle of reduction and resurgence. Relative cover of annual bromes in the monitored areas was best predicted by park unit, weather, extant plant community, slope grade, soil composition, and fire history. We found no evidence that grazing reduced annual brome cover, but this may be due to the relatively low grazing pressure in our study. By understanding the consequences and patterns of annual brome invasion, we will be better able to preserve and restore these grassland landscapes for future generations.

Ecosphere

An aeromagnetic survey over the northwestern Ross Ice Shelf and the McMurdo Sound area

As part of the expedition GANOVEX VI 1990/91, the Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), the Alfred Wegener Institute for Polar and Marine Research (AWI), and the United States Geological Survey (USGS) carried out an airborne magnetic survey over the northwestern Ross Ice Shelf and McMurdo Sound between Ross Island, the Transantarctic Mountains, and Minna Bluff. The area planned for the aeromagnetic survey connects directly with the GANOVEX IV survey area (BGR & USGS 1987, BACHEM et al. 1989a) which terminated along an approximately cast-west line at about the latitude of Cape Bird. The GANOVEX IV survey covered the Victoria Land Basin - which is the westernmost of the three north/south striking basins in the Ross Sea - from its northern end in the Terra Nova Bay region to its known southern end at Ross Island. A possible southem extension of the Victoria Land Basin and its central graben structure (the Terror Rift as found from seismic surveys (COOPER et al. 1987) and what has been referred to as Victoria Graben in the aeromagnetic interpretation of the GANOVEX IV data (BOSUM et al. 1989) was one of the major targets for this survey. The survey was laid out in the form of blocks. A 135 km wide transect from the Transantarctic Mountains to about 175° W formed the focal block of the survey (Fig. 1) in which all major scientific objectives could be covered. Other survey blocks were planned to the south of this. During the course of the survey it turned out that in the time available no further area could be covered. Indeed, the unfavourable weather conditions made it impossible to complete even the above described main section fully. In detail, the lay-out of the survey area was closely following that of the GANOVEX IV survey to assure compatibility and direct continuation between the two data sets. The line spacing was chosen again to 4.4 km with a tic-line separation of 22 km. The survey altitude of 2,000 ft (610 m) corresponds to that of the Ross Sea section of the GANOVEX IV survey to which this survey area is directly adjacent. The profile lines were aligned approximately E-W, the tie-lines N-S. As part of the survey area is covered by the maps of the USGS Antarctica Reconnaissance Series 1:250,000 the Lambert conformal conic projection used for these maps was also used for the preparation of a flight line grid.

Polarforschung

Meteorite and meteoroid: New comprehensive definitions

Meteorites have traditionally been defined as solid objects that have fallen to Earth from space. This definition, however, is no longer adequate. In recent decades, man-made objects have fallen to Earth from space, meteorites have been identified on the Moon and Mars, and small interplanetary objects have impacted orbiting spacecraft. Taking these facts and other potential complications into consideration, we offer new comprehensive definitions of the terms "meteorite,""meteoroid," and their smaller counterparts: A meteoroid is a 10-??m to 1-m-size natural solid object moving in interplanetary space. A micrometeoroid is a meteoroid 10 ??m to 2 mm in size. A meteorite is a natural, solid object larger than 10 ??m in size, derived from a celestial body, that was transported by natural means from the body on which it formed to a region outside the dominant gravitational influence of that body and that later collided with a natural or artificial body larger than itself (even if it is the same body from which it was launched). Weathering and other secondary processes do not affect an object's status as a meteorite as long as something recognizable remains of its original minerals or structure. An object loses its status as a meteorite if it is incorporated into a larger rock that becomes a meteorite itself. A micrometeorite is a meteorite between 10 ??m and 2 mm in size. Meteorite- "a solid substance or body falling from the high regions of the atmosphere" (Craig 1849); "[a] mass of stone and iron that ha[s] been directly observed to have fallen down to the Earth's surface" (translated from Cohen 1894); "[a] solid bod[y] which came to the earth from space" (Farrington 1915); "A mass of solid matter, too small to be considered an asteroid; either traveling through space as an unattached unit, or having landed on the earth and still retaining its identity" (Nininger 1933); "[a meteoroid] which has reached the surface of the Earth without being vaporized" (1958 International Astronomical Union (IAU) definition, quoted by Millman 1961); "a solid body which has arrived on the Earth from outer space" (Mason 1962); "[a] solid bod[y] which reach[es] the Earth (or the Moon, Mars, etc.) from interplanetary space and [is] large enough to survive passage through the Earth's (or Mars', etc.) atmosphere" (Gomes and Keil 1980); "[a meteoroid] that survive[s] passage through the atmosphere and fall[s] to earth" (Burke 1986); "a recovered fragment of a meteoroid that has survived transit through the earth's atmosphere" (McSween 1987); "[a] solid bod[y] of extraterrestrial material that penetrate[s] the atmosphere and reach[es] the Earth's surface" (Krot et al. 2003). ?? The Meteoritical Society, 2010.

Meteoritics and Planetary Science

Development of the Coastal Storm Modeling System (CoSMoS) for predicting the impact of storms on high-energy, active-margin coasts

The Coastal Storm Modeling System (CoSMoS) applies a predominantly deterministic framework to make detailed predictions (meter scale) of storm-induced coastal flooding, erosion, and cliff failures over large geographic scales (100s of kilometers). CoSMoS was developed for hindcast studies, operational applications (i.e., nowcasts and multiday forecasts), and future climate scenarios (i.e., sea-level rise + storms) to provide emergency responders and coastal planners with critical storm hazards information that may be used to increase public safety, mitigate physical damages, and more effectively manage and allocate resources within complex coastal settings. The prototype system, developed for the California coast, uses the global WAVEWATCH III wave model, the TOPEX/Poseidon satellite altimetry-based global tide model, and atmospheric-forcing data from either the US National Weather Service (operational mode) or Global Climate Models (future climate mode), to determine regional wave and water-level boundary conditions. These physical processes are dynamically downscaled using a series of nested Delft3D-WAVE (SWAN) and Delft3D-FLOW (FLOW) models and linked at the coast to tightly spaced XBeach (eXtreme Beach) cross-shore profile models and a Bayesian probabilistic cliff failure model. Hindcast testing demonstrates that, despite uncertainties in preexisting beach morphology over the ~500 km alongshore extent of the pilot study area, CoSMoS effectively identifies discrete sections of the coast (100s of meters) that are vulnerable to coastal hazards under a range of current and future oceanographic forcing conditions, and is therefore an effective tool for operational and future climate scenario planning.

Natural Hazards

Satellite telemetry: A new tool for wildlife research and management

The U.S. Fish and Wildlife Service and the Alaska Department of Fish and Game have cooperated since 1984 to develop and evaluate satellite telemetry as a means of overcoming the high costs and logistical problems of conventional VHF (very high frequency) radiotelemetry systems. Detailed locational and behavioral data on caribou ( Rangifer tarandus ), polar bears ( Ursus maritimus ), and other large mammals in Alaska have been obtained using the Argos Data Collection and Location System (DCLS). The Argos system, a cooperative project of the Centre National d'Études Spatiales of France, the National Oceanic and Atmospheric Administration, and the National Aeronautics and Space Administration, is designed to acquire environmental data on a routine basis from anywhere on earth. Transmitters weighing 1.6-2.0 kg and functioning approximately 12-18 months operated on a frequency of 401.650 MHz. Signals from the transmitters were received by Argos DCLS instruments aboard two Tiros-N weather satellites in sun-synchronous, nearpolar orbits. Data from the satellites were received at tracking stations, transferred to processing centers in Maryland and France, and made available to users via computer tape, printouts, or telephone links. During 1985 and 1986, more than 25,000 locations and an additional 28,000 sets of sensor data (transmitter temperature and short-term and long-term indices of animal activity) were acquired for caribou and polar bears. Locations were calculated from the Doppler shift in the transmitted signal as the satellite approached and then moved away from the transmitter. The mean locational error for transmitters at known locations (n - 1,265) was 829 m; 90% of the calculated locations were within 1,700 m of the true location. Caribou transmitters provided a mean of 3.1 (+5.0. SD) locations per day during 6h of daily operation, and polar bear transmitters provided 1.7 (+6.9SD) locations during 12h of operation every third day. During the first 6 months of operation, the UHF (ultra-high frequency) signal failed on three of 32 caribou transmitters and 10 of 36 polar bear transmitters. A geographic information system (GIS) incorporating other databases (e.g., land cover, elevation, slope, aspect, hydrology, ice distribution) was used to analyze and display detailed locational and behavioral data collected via satellite. Examples of GIS applications to research projects using satellite telemetry and examples of detailed movement patterns of caribou and polar bears are presented. This report includes documentation for computer software packages for processing Argos data and presents developments, as of March 1987, in transmitter design, data retrieval using a local user terminal, computer software, and sensor development and calibration.

Resource Publication

Connecting regional-scale tree distribution models with seed dispersal kernels

Regional scale forest distribution models are important tools for biogeography and understanding the structure of forest communities in space. These models take climate and geographic variables as input and are therefore helpful for long-term decision support and climate adaptation planning. Generally, local processes of tree germination and seedling survival are resolved probabilistically with explanatory variables such as elevation, latitude, exposure, soil type, moisture availability, climate and weather inputs and `trained’ using landscape and regional presence-absence data and machine learning techniques. How seeds are distributed in these models, that is, determining the dispersal kernel, is far more problematic. The challenge is that variables conditioning vertebrate seed dispersal (motility and probability of utilization or caching in response to cover type) are not represented in large scale distribution models, and in fact vary on scales (10-100 meters) that are much smaller than the smallest pixel size for the distribution model (1-10 kilometers). We present a homogenized seed digestion kernel (HSDK) which incorporates this scale separation. Homogenization naturally links highly variable small-scale processes (like seed foraging and caching by birds and rodents) with large scale effects (like dispersal of seeds over tens of kilometers). We develop a homogenization strategy to predict seed dispersal on landscape scales, analytically linking small-scale variables (landscape fraction cover by tree type, gut residence times and cover type utilization by frugivorous birds) with large scale behaviors. Closed form approximations are developed in two dimensions for two limiting cases of seed handling behavior, and the approach is illustrated using landscape data and piñon-pine dispersal in a 630,000 square kilometer region in the southwestern US.

Applied Mathematics and Computation

Climate trends of the North American prairie pothole region 1906-2000

The Prairie Pothole Region (PPR) is unique to North America. Its millions of wetlands and abundant ecosystem goods and services are highly sensitive to wide variations of temperature and precipitation in time and space characteristic of a strongly continental climate. Precipitation and temperature gradients across the PPR are orthogonal to each other. Precipitation nearly triples from west to east from approximately 300 mm/year to 900 mm/year, while mean annual temperature ranges from approximately 1°C in the north to nearly 10°C in the south. Twentieth-century weather records for 18 PPR weather stations representing 6 ecoregions revealed several trends. The climate generally has been getting warmer and wetter and the diurnal temperature range has decreased. Minimum daily temperatures warmed by 1.0°C, while maximum daily temperatures cooled by 0.15°C. Minimum temperature warmed more in winter than in summer, while maximum temperature cooled in summer and warmed in winter. Average annual precipitation increased by 49 mm or 9%. Palmer Drought Severity Index (PDSI) trends reflected increasing moisture availability for most weather stations; however, several stations in the western Canadian Prairies recorded effectively drier conditions. The east-west moisture gradient steepened during the twentieth century with stations in the west becoming drier and stations in the east becoming wetter. If the moisture gradient continues to steepen, the area of productive wetland ecosystems will shrink. Consequences for wetlands would be especially severe if the future climate does not provide supplemental moisture to offset higher evaporative demand.

Climatic Change

HIMALA: climate impacts on glaciers, snow, and hydrology in the Himalayan region

Glaciers are the largest reservoir of freshwater on Earth, supporting one third of the world's population. The Himalaya possess one of the largest resources of snow and ice, which act as a freshwater reservoir for more than 1.3 billion people. This article describes a new project called HIMALA, which focuses on utilizing satellite-based products for better understanding of hydrological processes of the river basins of the region. With support from the US Agency for International Development (USAID), the International Centre for Integrated Mountain Development (ICIMOD), together with its partners and member countries, has been working on the application of satellite-based rainfall estimates for flood prediction. The US National Aeronautics and Space Administration (NASA) partners are working with ICIMOD to incorporate snowmelt and glacier melt into a widely used hydrological model. Thus, through improved modeling of the contribution of snow and ice meltwater to river flow in the region, the HIMALA project will improve the ability of ICIMOD and its partners to understand the impact of weather and climate on floods, droughts, and other water- and climate-induced natural hazards in the Himalayan region in Afghanistan, Bangladesh, Bhutan, China, India, Myanmar, Nepal, and Pakistan.

Himalayas

Calibration of a simple oilspill trajectory model using the Argo Merchant spill

An oil spill risk analysis was conducted to determine the relative envionmental hazards of developing oil in different regions of the Eastern Gulf of Mexico Outer Continental Shelf lease area. The study analyzed the probability of spill occurrence, likely paths of the spills, and locations in space and time of such objects as recreational and biological resources likely to be vulnerable. These results combined to yield estimates of the overall oilspill risk associated with development of the proposed lease area. This risk is compared to the existing oilspill risk from existing leases in the area. The analysis implicityly includes estimates of weathering rates and slick dispersion and an indication of the possible mitigating effects of cleanups. (Woodard-USGS)

Open-File Report

Application of deep electrical soundings for groundwater exploration in Hawaii

Forty-five resistivity soundings, using Schlumberger and equatorial dipole electrode configurations, were made on the islands of Oahu and Hawaii to determine the applicability of direct current resistivity methods for locating freshwater aquifers in the State of Hawaii. The soundings were made on the northwestern part of the island of Oahu near the town of Waialua and on the island of Hawaii on the "saddle" area near Pohakuloa and Humuula. Interpretation of 32 sounding curves obtained on the island of Oahu indicates that it is possible to correlate five stratigraphic units underlain by a vesicular basalt basement and that the determination of the approximate depth to the freshwater-saline-water interface within the basalt is feasible. Two of these Schlumberger soundings with electrode spacings AB/2 reaching 6000 ft yielded sounding curves of the maximum and minimum types whose terminal branches asymptotically approach a resistivity of about 30 ohm, which is believed to be the true resistivity of basalt saturated with sea water. Near the town of Waialua the aquifer is a coral zone as well as parts of the weathered vesicular basalt basement. On the island of Hawaii, near Pohakuloa, an exploratory well drilled in basalt to a depth of 1001 ft (prior to the resistivity survey) proved to be dry. Interpretation of thirteen deep soundings made with Schlumberger and equatorial arrays suggests that the minimum depth to a conductive layer, which may represent basalt saturated with fresh water, is about 2700 ft below land surface. The groundwater appears to be dike impounded.

Hawaii

The Lower Triassic Sorkh Shale Formation of the Tabas Block, east central Iran: Succesion of a failed-rift basin at the Paleotethys margin

The Lower Triassic Sorkh Shale Formation is a dominantly red colored marginal marine succession deposited in the north-south trending Tabas Basin of east central Iran. It is correlated with the unconformity-bounded lower limestone member of the Elika Formation of the Alborz Mountains of northern Iran. The Sorkh Shale is bounded by the pre-Triassic and post-Lower Triassic interregional unconformities and consists mainly of carbonates, sandstones, and evaporites with shale being a minor constituent. Detailed facies analysis of the Sorkh Shale Formation resulted in recognition of several genetically linked peritidal facies that are grouped into restricted subtidal, carbonate tidal flat, siliciclastic tidal flat, coastal plain and continental evaporite facies associations. These were deposited in a low energy, storm-dominated inner-ramp setting with a very gentle slope that fringed the Tabas Block of east central Iran and passed northward (present-day coordinates) into deeper water facies of the Paleotethys passive margin of northern Cimmerian Continent. Numerous carbonate storm beds containing well-rounded intraclasts, ooids and bioclasts of mixed fauna are present in the Sorkh Shale Formation of the northern Tabas Basin. The constituents of the storm beds are absent in the fair weather peritidal facies of the Sorkh Shale Formation, but are present throughout the lower limestone member of the Elika Formation. The Tabas Block, a part of the Cimmerian continent in east central Iran, is a rift basin that developed during Early Ordovician-Silurian Paleotethys rifting. Facies and sequence stratigraphic analyses of the Sorkh Shale Formation has revealed additional evidence supporting the Tabas Block as a failed rift basin related to the Paleotethys passive margin. Absence of constituents of the storm beds in the fair weather peritidal facies of the Sorkh Shale Formation, presence of the constituents of the storm beds in the fair weather facies of the Elika Formation (the Sorkh Shale equivalent in the Alborz Paleotethys margin) and southward paleocurrent directions of carbonate storm beds suggest that the low topographic gradient of the ramp in the Tabas failed rift basin was facing the Paleotethys Ocean, where the storms were generated. In addition, northward paleocurrent directions of the fair weather facies and northward increase in carbonate content of the Sorkh Shale sequence further indicate that the Tabas Basin was tectonically a part of the Paleotethys passive margin. It is apparent that relative sea level, basin geometry and tectonic movements along the bounding faults played significant roles during deposition of the Sorkh Shale Formation by controlling accommodation space and facies variations along the Tabas failed rift basin.

Carbonates and Evaporites

The Polar WRF downscaled historical and projected twenty-first century climate for the coast and foothills of Arctic Alaska

Climate change is most pronounced in the northern high latitude region. Yet, climate observations are unable to fully capture regional-scale dynamics due to the sparse weather station coverage, which limits our ability to make reliable climate-based assessments. A set of simulated data products was therefore developed for the North Slope of Alaska through a dynamical downscaling approach. The polar-optimized Weather Research and Forecast (Polar WRF) model was forced by three sources: The ERA-interim reanalysis data (for 1979–2014), the Community Earth System Model 1.0 (CESM1.0) historical simulation (for 1950–2005), and the CESM1.0 projected (for 2006–2100) simulations in two Representative Concentration Pathways (RCP4.5 and RCP8.5) scenarios. Climatic variables were produced in a 10-km grid spacing and a 3-h interval. The ERA-interim forced WRF (ERA-WRF) proves the value of dynamical downscaling, which yields more realistic topographical-induced precipitation and air temperature, as well as corrects underestimations in observed precipitation. In summary, dry and cold biases to the north of the Brooks Range are presented in ERA-WRF, while CESM forced WRF (CESM-WRF) holds wet and warm biases in its historical period. A linear scaling method allowed for an adjustment of the biases, while keeping the majority of the variability and extreme values of modeled precipitation and air temperature. CESM-WRF under RCP 4.5 scenario projects smaller increase in precipitation and air temperature than observed in the historical CESM-WRF product, while the CESM-WRF under RCP 8.5 scenario shows larger changes. The fine spatial and temporal resolution, long temporal coverage, and multi-scenario projections jointly make the dataset appropriate to address a myriad of physical and biological changes occurring on the North Slope of Alaska.

Alaska

Geohydrologic reconnaissance of the upper Potomac River basin

The upper Potomac River basin, in the central Appalachian region in Pennsylvania, Maryland, Virginia, and West Virginia, is a humid temperate region of diverse fractured rocks. Three geohydrologic terranes, which underlie large parts of the basin, are described in terms of their aquifer characteristics and of the magnitude and duration of their base runoff: (1) fractured rock having a thin regolith, (2) fractured rock having a thick regolith, and (3) carbonate rock. Crystalline rock in the mountainous part of the Blue Ridge province and shale with tight sandstone in the folded Appalachians are covered with thin regolith. Water is stored in and moves through fairly unmodified fractures. Average transmissivity (T) is estimated to be 150 feet squared per day, and average storage coefficient (S), 0.005. Base runoff declines rapidly from its high levels during spring and is poorly sustained during the summer season of high evapotranspiration. The rocks in this geohydrologic terrane are the least effective in the basin for the development of water supplies and as a source of dry-weather streamflow. Crystalline and sedimentary rocks in the Piedmont province and in the lowland part of the Blue Ridge province are covered with thick regolith. Water is stored in and moves through both the regolith and the underlying fractured rock. Estimated average values for aquifer characteristics are T, 200 feet squared per day, and S, 0.01. Base runoff is better sustained in this terrane than in the thin-regolith terrane and on the average .is about twice as great. Carbonate rock, in which fractures have been widened selectively by solution, especially near streams, has estimated average aquifer characteristics of T, 500 feet squared per day, and S, 0.03-0.04. This rock is the most effective in the basin in terms of water supply and base runoff. Where its fractures have not been widened by solution, the carbonate rock is a fractured-rock aquifer much like the noncarbonate rock. At low values the frequency of specific capacities of wells is much the same in all rocks in the basin, but high values of specific capacity are as much as 10 times more frequent in carbonate rock than in noncarbonate rock. Nearly all the large springs and high-capacity wells in the basin are in carbonate rock. Base runoff from the carbonate rock is better sustained during dry weather and on the average is about three times as great as base runoff from fractured rock having a thin regolith. The potential role of these water-bearing terranes in water management probably lies in the local development of large water supplies from the carbonate rock and in the possible manipulation of underground storage for such purposes as providing space for artificial recharge of ground water and providing ground water to be used for the augmentation of low streamflow. The chief water-quality problems in the basin--acidic mine-drainage water in the western part of the basin, local highly mineralized ground water, and the high nitrate content of ground water in some of the densely populated parts of the basin--would probably have little adverse affect on the use of ground water for low-flow augmentation.

Water Supply Paper

Gold enrichment and the Bi-Au association in pyrrhotite-rich massive sulfide deposits, Escanaba trough, Southern Gorda Ridge

High gold contents (to 10.1 ppm, avg 1.4 ppm, n = 34) occur in pyrrhotite-rich massive sulfide samples from the sediment-covered floor of the Escanaba trough, the slow-spreading, southernmost segment of Gorda Ridge. These concentrations reflect the presence of primary gold, formed during high-temperature hydrothermal activity in mounds and chimneys, and secondary gold deposited during sea-floor weathering of massive sulfide. Primary gold occurs as fine-grained (<2 ??m) gold, electrum, maldonite (Au2Bi), and a rare unnamed mineral (AuBi5S4) and is texturally and temporally associated with sulfarsenides (arsenopyrite, glaucodot, alloclastite, and cobaltite), arsenides (lo??llingite and safflorite), Bi minerals (native bismuth, Bi tellurides, Bi-Te sulfides, and bismuthinite), and galena. Larger (>2 ??m) secondary gold grains have a porous, flaky morphology and occur in samples in which pyrrhotite is oxidized and replaced by Fe oxyhydroxides, Fe sulfate, and sulfur. Mounds and chimneys dominated by pyrrhotite and containing lesser amounts of isocubanite, chalcopyrite, and Fe-rich sphalerite were formed by high-temperature (estimated range 325??-275??C), reduced, low-sulfur vent fluids. The mineral and fluid compositions during this main stage of hydrothermal venting reflect subsurface interaction between circulating hydrothermal fluids and turbiditic sediment containing as much as 1.1 percent organic carbon. As the deposition of pyrrhotite, Cu-Fe sulfides, and sphalerite waned, a volumetrically minor suite of sulfarsenide, arsenide, Bi, and Au minerals was deposited from highly reduced, late main-stage fluids diffusing through mounds and chimneys. The low solubility of Au as a bisulfide complex and the absence of fluid mixing during this stage of hydrothermal activity apparently inhibited the precipitation of gold directly from solution. Instead, gold precipitation is thought to be linked to elevated concentrations of Bi in the late main-stage fluids. The textural relationships of Au and Bi minerals in pyrrhotite-rich samples, low melting point of native bismuth (271.4??C), and recent experimental results on Au and Bi in hydrothermal fluids contribute to the hypothesis that gold was effectively scavenged from the Escanaba trough vent fluids by coexisting droplets of liquid bismuth. Additional phase relationships of alloys in the Au-Bi system indicate that deposition of native bismuth and maldonite occurred at temperatures as low as 241??C. Bismuth droplets trapped in void space between main-stage mineral grains scavenged gold from ambient hydrothermal fluid to a greater extent than bismuth enclosed by late-forming pyrrhotite. The limited solid solution of Au in Bi can explain the apparent exsolution texture in which gold blebs are hosted by native bismuth. The electrum, native bismuth (with gold inclusions), and galena represent the last traces of gold mineralization from late main-stage fluids. During sea-floor weathering and the oxidation of pyrrhotite in the mounds and chimneys, secondary gold formed as aggregates of colloidal particles along pH gradients between acidic pore waters and ambient seawater. Gold was mobilized from earlier formed primary gold minerals and transported as aqueous chloride complexes. The reduction of Au(III) by residual Fe2+ in partly altered pyrrhotite and adsorption of colloids by Fe oxyhydroxides may have influenced the location of secondary gold grains within the alteration front. Solubility differences between gold and silver chloride complexes at low temperature account for the low Ag content of secondary gold grains. The high concentrations of Bi, and thus the association of Au and Bi minerals in pyrrhotite-rich massive sulfide, can be ascribed to the extensive interaction of hydrothermal fluids with sediment in the Escanaba trough. In contrast, the absence of the Au-Bi association in massive sulfides at other ridges, including other sediment-covered sites at Middle Valley and the Guaymas basin

Economic Geology

Geology, mineralization, and hydrothermal alteration and relationships to acidic and metal-bearing surface waters in the Palmetto Gulch area, southwestern Colorado

The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study. The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study.

Colorado

Ground-water resources in the tri-state region adjacent to the Lower Delaware River

The purpose of this report is to appraise and evaluate the groundwater resources of a tri-state region adjacent to the lower Delaware River that is centered around Philadelphia, Pa., and Camden, N. J., and includes Wilmington, Del., and Trenton, N.J. Specifically, the region includes New Castle County, Del.; Burlington, Camden, Gloucester, Mercer, and Salem Counties in New Jersey; and Bucks, Chester, Delaware, Montgomery, and Philadelphia Counties in Pennsylvania. The peculiar advantages of ground water, such as its availability in many places without the necessity for expensive pipelines and its relatively uniform temperature and quality, make it an especially valuable resource in an industrial area. Large, readily available supplies of good, fresh water have contributed substantially to the recent rapid industrial growth of the lower Delaware River basin and will be vital to its continued prosperity. The major part of these supplies is drawn from the streams passing through the region, but very large quantities of ground water also are used. The region is divided almost equally by the Fall Line, which extends in a southwesterly direction along the general course of the Delaware River from Trenton, N.J., to Wilmington, Del., and beyond. Northwest of the Fall Line is a region of consolidated rocks in which ground water occurs mainly in cracks, crevices, and openings created or enlarged by weathering. The capacity of the various geologic formations to yield water depends largely upon the degree to which they have been fractured and weathered. The yield of individual wells in this part of the region is generally small to moderate and not readily predictable. Ground water in this part of the region is generally low in dissolved minerals and suitable for many uses without treatment. Southeast of the Fall Line lie the unconsolidated rocks of the Coastal Plain. Ground water occurs in these rocks largely in the pore spaces between the individual mineral grains. The major formations and the principal aquifers are rather uniform in their water-bearing characteristics over large areas. The yield of individual wells is moderate to very large and may be predicted with a reasonable degree of assurance. Sufficient quantities of ground water are available in most places for all ordinary purposes. The chemical quality of the ground water from the Coastal Plain aquifers is generally acceptable for most uses, but objectionable quantities of iron or other minerals are found in some places, and some waters have a low pH and are corrosive. More than 40 distinct geologic formations occur in the region. They range in age from Precambrian to Recent. Nearly all will yield some water to wells. However, only about a dozen yield water freely enough to be considered major aquifers. Of these, the sands of the Raritan and Magothy formations have been developed most intensively, and the Cohansey sand appears to have the greatest capacity for additional development. The present withdrawal of ground water in the region is estimated to average more than 200 mgd, of which more than half is drawn from the aquifers in the Raritan and Magothy formations. It is estimated that additional supplies of ground water, aggregating more than 1 billion gallons a day, can be developed within the region. Furthermore, substantial additional quantities can be developed outside the region for use within it if the need should ever arise. Induced recharge from the Delaware River supplies a substantial portion of the total water drawn from the Raritan and Magothy formations. In some areas, the quality of the water from these aquifers is approaching that of the river. Increased withdrawals of water from wells along the river will tend to increase induced recharge. Thus, the maintenance of a good quality of water in the river, which is desirable for many other reasons, is imperative if the quality of the ground-water supply is to be maintained. The proposed deepening of the Delaware River channel from Philadelphia to Trenton will greatly increase the opportunity for the interchange of water between the river and the adjacent aquifers. Whether this will be beneficial or detrimental to the ground-water supplies will depend upon the quality of the water in that reach of the river. If an acceptable quality of river water is maintained, the groundwater resources of the region will be augmented. If salt water from the ocean or excessive contamination from other sources should render the river water undesirable as a source of recharge, actual and potential ground-water supplies aggregating about 250 mgd would be endangered. The danger of salt-water encroachment into the aquifers normally yielding fresh water may limit the optimum yield of some of the most important aquifers in the region. Encroachment may come either from salt water in the surface-water bodies of the region or from parts of the aquifers, normally containing salt water. The protection of ground-water supplies against salt-water encroachment can be maintained only by constant vigilance, careful distribution of the pumping from the aquifers, regular sampling of outpost wells in exposed localities, and adjustment of rates of pumping in the light of changing conditions. The maximum beneficial utilization of the ground-water resources cannot be accomplished in haphazard fashion. It must be planned and controlled on the basis of sound, current information about the hydrology of the various aquifers. Continued and, in some areas, intensified investigations of the ground-water resources of the region should form the basis for such planning and control.

New Jersey, Pennsylvania, Delaware

Flood-inundation maps and wetland restoration suitability index for the Blue River and selected tributaries, Kansas City, Missouri, and vicinity, 2012

Digital flood-inundation maps for a 39.7-mile reach of the Blue River and selected tributaries (Brush Creek, Indian Creek, and Dyke Branch) at Kansas City, Missouri, and vicinity, were created by the U.S. Geological Survey (USGS) in cooperation with the City of Kansas City, Missouri. The flood-inundation maps, accessed through the USGS Flood-Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation/, depict estimates of the spatial extent and depth of flooding corresponding to selected water levels (stages) at 15 reference streamgages and associated stream reaches in the Blue River Basin. Near-real-time stage data from the streamgages may be obtained from the USGS National Water Information System at http://waterdata.usgs.gov/ or the National Weather Service (NWS) Advanced Hydrologic Prediction Service (AHPS) at http://water.weather.gov/ahps/, which also forecasts flood hydrographs at selected sites. Flood profiles were computed for each of 15 reaches by means of one-dimensional or two-dimensional hydraulic models. The models were calibrated by using the current stage-streamflow relations at 10 USGS streamgages and documented high-water marks from the flood of June 14, 2010. Hydraulic models were then used to compute water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datum and ranging from the National Weather Service Action stage, or near bankfull streamflow, through the stage corresponding to, or exceeding, the estimated 0.2-percent annual exceedance probability flood (500-year recurrence interval flood). The simulated water-surface profiles were then combined with a geographic information system (GIS) terrain model derived from light detection and ranging (lidar) data having a vertical accuracy of less than 0.6 foot and maximum nominal horizontal post spacing of 2.46&ndash;3.28 feet to delineate the area flooded at each 1-foot increment of stage. The availability of these flood-inundation maps, along with Internet information regarding current stage from the USGS streamgages and forecasted high-flow stages from the NWS, will provide emergency management personnel and residents with information that is critical for flood response activities such as evacuations and road closures, as well as for postflood recovery efforts. Additional information in this report includes maps of simulated stream velocity for an 8.2-mile, two-dimensional modeled reach of the Blue River and a Wetland Restoration Suitability Index (WRSI) generated for the study area that was based on hydrologic, topographic, and land-use digital feature layers. The calculated WRSI for the selected flood-plain area ranged from 1 (least suitable for possible wetland mitigation efforts) to 10 (most suitable for possible wetland mitigation efforts). A WRSI of 5 to 10 is most closely associated with existing riparian wetlands in the study area. The WRSI allows for the identification of lands along the Blue River and selected tributaries that are most suitable for restoration or creation of wetlands. Alternatively, the index can be used to identify and avoid disturbances to areas with the highest potential to support healthy sustainable riparian wetlands.

Missouri

The geobiology of sediment-hosted mineral deposits

The role of biological processes in the formation of sediment-hosted ore deposits has long been recognized. In this review, we focus on the biogeochemical cycling of C, Mn, Fe, and S as they relate to the formation of sediment-hosted Mn and Fe deposits, metalliferous black shales, clastic-dominated (CD) Pb-Zn deposits, and phosphorites. Biological mediation of ore-forming processes occurs over large spans of space and time. The most important step is oxygenic photosynthesis, a biological innovation dating from the Archean Eon that releases free oxygen into the surface oceans and atmosphere and delivers chemical potential, in the form of reduced carbon, to the seafloor. Photosynthetic oxygen is available to precipitate dissolved Fe 2 + and Mn 2 +, and therefore it augments the formation of sedimentary Mn and Fe deposits, and drives oxidative weathering of exposed crust, thereby delivering sulfate and transition metals to the ocean. Where reduced carbon accumulates in the deep oceans and on the seafloor, bacterial sulfate reduction produces hydrogen sulfide thereby facilitating the formation of metalliferous black shales, sediment-hosted Pb and Zn sulfide deposits, and phosphorites. Thus, an understanding of major biogeochemical processes and how they have evolved over time is required in order to refine genetic models for sediment-hosted ore deposits and to guide future mineral exploration. A close secular relationship between deposit formation and trends in major biogeochemical cycles provides a potentially powerful tool for mineral resource assessment. Sedimentary basins that formed during a time that is known to lack deposits of a particular metal can be eliminated during exploration programs, whereas others of permissive ages should be considered priorities. For example, sedimentary basins older than ca. 1.8 Ga are unlikely to contain large CD Pb-Zn deposits, and basins that formed between 1.6 and 0.6 Ga are not prospective for phosphorites. Recent technological advances in the application of nanometer-, micron-, and bulk-scale analytical techniques allow for imaging of complex biological structures and have provided new insights into the role of bacteria, not only in direct formation of mineral deposits, but also in leaching of metals from ore and mineralized rocks. Future exploration for, and exploitation of, mineral deposits may include offshore or land-based, low-grade, high-tonnage targets; understanding the role of bacteria in mineral growth, mineral dissolution, and redox transformations will aid in predicting where such deposits exist, and how metal extraction from ores can be enhanced.

Book chapter