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614 records · Page 7Linked to original sources

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan

Permafrost thaw controls iron flux from wetlands and sulfide-bearing rocks to Arctic rivers and streams

Recent warming has caused widespread iron mobilization into Arctic waterbodies that degrades ecosystems and threatens natural resources. Yet, understanding where and when iron flux occurs remains limited. Here, we investigate iron loading across regional to local scales in Arctic Alaska using climate, water chemistry, and borehole data together with mapped geology and permafrost presence. We show that both anoxic microbial iron reduction and acid rock drainage from iron-sulfide oxidation mobilize iron. Iron influx is strongly associated with lowland wetlands, sulfide-rich upland bedrock, and near-surface permafrost. Acid rock drainage chemistry correlates very strongly with the depth of seasonal thaw above permafrost from the previous year, indicating a one-year lag. These findings clarify the spatial and temporal dynamics of Arctic river rusting, provide a mechanistic understanding of the phenomenon, and may allow anticipation of its occurrence and assessment of its implications for aquatic ecosystem health and subsistence resources under ongoing climate change.

Alaska

U.S.-Mexico Borderland & vegetation community map

People on both sides of the United States-Mexico border need a high-resolution, binational vegetation community map that spans the entire United States-Mexico borderlands. Traditionally, mapping efforts in this region were impeded by complex logistics related to the international border, differing national needs and plans, and resource allocations and priorities. To address this need, scientists from the U.S. Geological Survey (USGS) Southwest Biological Science Center partnered with the Sonoran Joint Venture, the U.S. Fish and Wildlife Service (FWS) Migratory Bird Program, data engineers from the Department of Biosystems Engineering at the University of Arizona, and collaborators from the Wildlands Network, the Borderlands Program to produce the first prototype land cover map within the overlapping Mojave Desert, Sonoran Desert, and the North American Bird Conservation Initiative’s Bird Conservation Region 33 (BCR33) using Landsat satellite data . BCR33 is an area of high biodiversity, providing habitat for bird species of concern and other wildlife. The land cover map supports FWS recovery plan efforts related to conservation planning activities for many species, including Yellow-billed Cuckoo ( Coccyzus americanus ), Cactus Ferruginous Pygmy-Owl ( Glaucidium brasilianum cactorum ), Southwestern Willow Flycatcher ( Empidonax traillii extimus ), Yuma Ridgway’s Rail ( Rallus obsoletus yumanensis ), Bendire’s thrasher ( Toxostoma bendirei ), LeConte’s thrasher ( Toxostoma lecontei ), Masked Bobwhite ( Colinus virginianus ridgwayi ), jaguar ( Panthera onca ), and endangered plants such as Bartram’s stonecrop ( Graptopetalum bartramii ) and the Pima pineapple cactus ( Coryphantha robustispina ssp. robustispina ). In 2024, a Phase-II map for the full BCR33 region was completed, increasing the understanding of the binational nature of natural communities. The published map and associated paper can be found here .

Borderland

Airborne geophysical efforts for critical mineral systems mapping in the southern Midcontinent, USA

The increasing global demand for critical minerals to support energy and technological advancement has accelerated exploration and research efforts for these essential resources. Since 2019, the United States Geological Survey (USGS) Earth Mapping Resources Initiative (EMRI) has worked to modernize geologic mapping of the Nation to better understand its critical mineral resources. To further this initiative, the USGS has flown a series of high-resolution airborne magnetic and radiometric surveys over large areas of the southern Midcontinent. The surveys cover known critical mineral deposits and areas with the potential to host additional critical minerals based on the presence of one or more overlapping mineral systems. One aspect of EMRI emphasizes close collaboration between the USGS and the Association of American State Geologists, as well as other government and industry partners to leverage geophysical, geological, and geochemical expertise on both regional and local scales. The EMRI high-resolution airborne survey data provide new insights into the geophysical framework of the southern Midcontinent and its critical mineral endowment. Additionally, discoveries made from the data have directed new studies for critical mineral exploration.

southern Midcontinent

Using a temporary emigration model to estimate abundance of stream fishes from hybrid removal surveys with and without block nets

Monitoring programs are often faced with a decision to allocate resources into either robust spatiotemporal coverage to estimate a population index (e.g., not true abundance) or confirming closed sampling conditions (e.g., with block nets) for an unbiased population estimate at the cost of spatiotemporal coverage. However, making accurate and precise abundance estimates at robust spatiotemporal scales is possible when combining open and closed sampling designs with integrated modeling techniques. We used simulations and a case study of backpack electrofishing surveys in the Santa Ana River, California to test the efficacy of an integrated abundance model (temporary emigration model, TE) to estimate abundance of fishes using removal sampling methods with a hybrid sampling design (sampling with and without block nets during removal sampling). We found that the TE model performed well under most modeling scenarios (sample size, amount of closure violation, number of samples collected during closure), although at least a few samples with block nets were necessary for all parameters to be estimable. When applied to fish surveys in the Santa Ana River, we found that catch of the fishes fit to the TE model (Santa Ana Sucker, Arroyo Chub, Channel Catfish, Largemouth Bass, Yellow Bullhead) showed little evidence that the closure assumption was violated when block nets were not used. Additionally, we found that the abundance of non-native fishes negatively affected the abundance of the native Santa Ana Sucker, which was also found to adversely affect the native fish’s access to critical habitat consisting of gravel and cobble substrate. Our results indicate that the TE model presents a viable solution to common sampling problems that impact many monitoring programs, where precise and accurate population estimates can be made at large spatiotemporal scales even when most samples violate the closure assumption.

California

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island

A joint Gaussian process model of geochemistry, geophysics, and temperature for groundwater TDS in the San Ardo Oil Field, California, USA

Decline in availability of fresh groundwater has expanded interest in brackish groundwater resources; however, the distribution of brackish groundwater is poorly understood. Water resources in sedimentary basins across the United States often overlie oil and gas development. Mapping of groundwater total dissolved solids (TDS) using data from oil well geophysical logs has become an important technique for identifying fresh and brackish groundwater. Existing geophysical log analysis methods use porosity and temperature to relate formation resistivity to TDS. Typically, natural geothermal gradients are used to estimate temperature at the location of collected resistivity. However, in thermally enhanced oil fields, steam is injected into the subsurface to mobilize high viscosity oil, creating variable temperature distributions. Furthermore, TDS derived from resistivity also depends on the fractions of dominant ions. Typically, chloride and bicarbonate fractions must be determined. It is also necessary to model TDS across many geologic units with heterogenous porosity distributions. Collectively, each quantity used to estimate TDS (resistivity, porosity, temperature, bicarbonate fraction) varies in space and time, and available data points are rarely collocated. Here, we present a new method of mapping groundwater TDS that continuously models each quantity together with a joint Gaussian process. This method enables mapping fresh and brackish water with practically available data. We apply this method to the San Ardo Oil Field in Monterey County, California, where steam injection occurs. In some areas of the aquifer system overlying the oil zone, the temperature is ∼75 °C, roughly twice the natural background value. Groundwater TDS is typically <1,500 mg/L in the aquifer and increases with depth to ∼9,000 mg/L in the oil-producing zone. A low-permeability clay layer delineates the fresh and brackish water, likely by inhibiting surface recharge from penetrating the deeper zones, allowing higher-TDS connate water to remain in place. Weaker lateral TDS trends may be controlled by recharge patterns associated with the Salinas River. Our model reveals with high certainty that groundwater has freshened in one localized part of the oil-producing zone and suggests with less certainty that more widespread freshening has also occurred. The lowering of TDS was possibly from decades of low-TDS steam injection and the associated fluid production and disposal operations.

California

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California

Distinguishing natural from mining-related metal sources by including streambank groundwater data in a stream mass loading study

Distinguishing stream metal loading caused by mine features from that caused by natural background sources remains challenging, yet this distinction is essential for making effective remedial decisions at many legacy mine sites. We combine a stream tracer injection and synoptic sampling study with data from shallow near-stream groundwater wells to estimate left-bank versus right-bank metal loading contributions at the 100-m spatial scale. The study was performed in the East Mancos River, a mountain headwater stream in Colorado, USA. The dominant source of elevated stream metal concentrations could be either groundwater infiltration through right-bank Doyle Mine waste piles or natural acid rock drainage from hydrothermally altered bedrock located mainly on the left bank. For the five metals of concern (Cu, Al, Zn, Cd, and Mn), we find that 15 % of the load contributed by diffuse groundwater inputs in the section potentially influenced by Doyle mine waste originates from the right bank. This right-bank potential mine contribution equates to only 3 % of the total watershed instream load for these metals. Furthermore, apparent 3 H/ 3 He groundwater ages in segments contributing most of the right-bank metal loading are sufficiently old (9–12 yr) to suggest that infiltration through the waste piles, located only 140–180 m from the stream, is unlikely. Estimated potential Doyle mine loading contributions can therefore be considered maximum values. Study results thus indicate that Doyle mine waste piles are a minor source of metal loading under low-flow conditions, and streambank groundwater data can provide valuable additional information in stream mass loading studies.

Colorado

Favorability mapping for hydrothermal power resource assessments of the Great Basin, USA

The U.S. Geological Survey (USGS) is updating the 2008 assessment of conventional hydrothermal resources for the Great Basin in the western United States. As part of this work, the workflow for hydrothermal resource favorability maps is being modified to integrate modern data-driven machine learning (ML) methods. Improvements include: [1] using new and refined evidence layers (features); [2] using an order of magnitude more training sites (labeled examples); [3] utilizing simple but non-linear supervised ML algorithms; [4] representing positive training sites (wells with measured heat flow) with their ordinal value proportional to the magnitude of convective upflow (i.e., low, high, or very high convective signals instead of past strategies using positive-negative labels); [5] supplementing training sites with additional sites with low convective signals to represent diverse under-sampled areas where hydrothermal systems are unlikely to exist; [6] comparing with competing approaches; and [7] utilizing Monte Carlo cross-validation to estimate and evaluate prediction uncertainty. For the new favorability map, over half of the power-producing systems (i.e., 15 of 28) are predicted in the 99th percentile of most favorable locations (i.e., the highest 1 % of favorability, corresponding to 1 % of the map area), exceeding the performance of past models that have explicitly used power plants as training sites. Previous favorability maps predicted approximately half of the power-producing hydrothermal systems above the 80th percentile (i.e., 20 % of the map area). For the new favorability map, 93 % of power-producing systems (i.e., 26 of 28) are above the 80th percentile. The power-producing systems for which the new model does not perform well are either comparatively small, low-temperature systems or systems also not predicted well by prior modeling approaches, suggesting that these few systems are unusual when compared with most power-producing systems. Focusing research on these known, seemingly different systems may yield new insights and subsequent discovery of new prospects.

California, Idaho, Nevada, Oregon, Utah

Enhanced hydrologic monitoring and characterization of groundwater drainage features

Groundwater drains to the land surface, generating the baseflow of streams, lakes, and wetlands. The hydrologic resilience of baseflow during prolonged dry periods and after disturbance can be assessed with evolving remote sensing analysis paired with localized monitoring of groundwater drainage features and creative model calibration strategies.

Nature Water

Long-term monotonic trends in water budget components in the contiguous United States: Insights from two hydrologic models

Characterizing changes to water availability for domestic, industrial, agricultural, and other uses is essential to support water management. To better quantify these changes, the U.S. Geological Survey and National Science Foundation National Center for Atmospheric Research produced two hydrologic models simulating water budget components from 1980 to 2021 over the contiguous United States (CONUS). Both hydrologic models were driven by a common atmospheric forcing dataset and aggregated to common spatial and temporal scales, which enables a novel evaluation of congruency between the models. We present annual and seasonal trends in six water budget components (precipitation, evapotranspiration, streamflow, groundwater recharge, soil saturation, and snow water equivalent) based on the Mann–Kendall test for monotonic trend and Theil-Sen slope estimate for the water year 1983–2021 period for ~86,000 catchments in CONUS. Additional components and metrics from our analysis pipeline are available in an associated published dataset, which contains more than 46 million trend results. The water budget trends showed broad agreement with prior observational and modeling studies that indicate increasing trends in the northeast and decreasing trends in southwestern CONUS. We found the seasonal variability in water budget trends was greatest in the southern, central, and northwest CONUS. These findings support integrated trend assessments when coupled with trends in water quality and use.

Contiguous United States

An optimized network for phosphorus load monitoring for Lake Okeechobee, Florida

Phosphorus load data were evaluated for Lake Okeechobee, Florida, for water years 1982 through 1991. Standard errors for load estimates were computed from available phosphorus concentration and daily discharge data. Components of error were associated with uncertainty in concentration and discharge data and were calculated for existing conditions and for 6 alternative load-monitoring scenarios for each of 48 distinct inflows. Benefit-cost ratios were computed for each alternative monitoring scenario at each site by dividing estimated reductions in load uncertainty by the 5-year average costs of each scenario in 1992 dollars. Absolute and marginal benefit-cost ratios were compared in an iterative optimization scheme to determine the most cost-effective combination of discharge and concentration monitoring scenarios for the lake. If the current (1992) discharge-monitoring network around the lake is maintained, the water-quality sampling at each inflow site twice each year is continued, and the nature of loading remains the same, the standard error of computed mean-annual load is estimated at about 98 metric tons per year compared to an absolute loading rate (inflows and outflows) of 530 metric tons per year. This produces a relative uncertainty of nearly 20 percent. The standard error in load can be reduced to about 20 metric tons per year (4 percent) by adopting an optimized set of monitoring alternatives at a cost of an additional $200,000 per year. The final optimized network prescribes changes to improve both concentration and discharge monitoring. These changes include the addition of intensive sampling with automatic samplers at 11 sites, the initiation of event-based sampling by observers at another 5 sites, the continuation of periodic sampling 12 times per year at 1 site, the installation of acoustic velocity meters to improve discharge gaging at 9 sites, and the improvement of a discharge rating at 1 site.

Florida

New measurements indicate that natural geologic methane emissions from microseepage in the Michigan Basin are likely negligible

The magnitude of natural geologic methane (CH 4 ) emissions to the atmosphere (including emissions of fossil CH 4 from offshore and onshore gas and oil seeps, diffuse microseepage, mud volcanoes, volcanic vents, and geothermal areas) is highly uncertain. The largest component of geologic emissions is thought to be microseepage, which is the diffuse flux of CH 4 from soils across large areas of productive hydrocarbon basins. The accuracy of existing bottom-up estimates of microseepage is limited by low spatial coverage of published microseepage measurements. We present the first soil—atmosphere CH 4 flux measurements from Michigan Basin, USA. Results from 335 measurements taken during summer and winter seasons across a large portion of the basin suggest microseepage is nonexistent in the sampled region. Even areas with predictive features for microseepage (e.g., underlying mature, organically rich source rocks, proven gas accumulations, faults, and lineaments) yield null or negative fluxes, suggesting that CH 4 emissions from microseepage are negligible throughout our study region. A Monte Carlo method was used to place an upper limit on the regional-mean microseepage flux, in which synthetic patchy microseepage distributions were generated and tested against our observations to assess the impact of possible emission hot spots that were missed by our sampling strategy. Our analysis finds it is very unlikely that regional-mean emissions are as high as assumed in a previous global microseepage study. The observed lack of seepage may be explained by groundwater flow, active methanotrophy, glacial sediments, and bedded salt deposits, which could inhibit vertical gas migration and release to atmosphere.

Michigan

Selected aquatic biological investigations in the Great Salt Lake basins, 1875-1998, National Water-Quality Assessment Program

This report summarizes previous investigations of aquatic biological communities, habitat, and contaminants in streams and selected large lakes within the Great Salt Lake Basins study unit as part of the U.S. Geological Survey’s National Water-Quality Assessment Program (NAWQA). The Great Salt Lake Basins study unit is one of 59 such units designed to characterize water quality through the examination of chemical, physical, and biological factors in surface and ground waters across the country. The data will be used to aid in the planning, collection, and analysis of biological information for the NAWQA study unit and to aid other researchers concerned with water quality of the study unit. A total of 234 investigations conducted during 1875-1998 are summarized in this report. The studies are grouped into three major subjects: (1) aquatic communities and habitat, (2) contamination of streambed sediments and biological tissues, and (3) lakes. The location and a general description of each study is listed. The majority of the studies focus on fish and macroinvertebrate communities. Studies of algal communities, aquatic habitat, riparian wetlands, and contamination of streambed sediment or biological tissues are less common. Areas close to the major population centers of Salt Lake City, Provo, and Logan, Utah, are generally well studied, but more rural areas and much of the Bear River Basin are lacking in detailed information, except for fish populations.

Idaho, Utah, Wyoming

Hydrologic response of groundwater and streamflow to natural and anthropogenic drivers of change in headwaters of the upper Colorado River basin during recent wet (1982–1999) and drought (2000–2022) conditions

Study region: Headwaters of the upper Colorado River basin (UCOL), USA Study focus: Surface-water and groundwater numerical models incorporating water-use information were used to investigate changes in climate, water use, and simulated hydrologic responses of snow processes, evapotranspiration, groundwater, and streamflow during recent wet (1982–1999) and drought (2000–2022) periods in the headwater subregions of the upper Colorado River basin. New hydrologic insights for the region: Decreases in average streamflow between wet and drought periods ranged from 20 % in the Colorado River headwaters subregion to 23 % in the Gunnison River headwaters subregion. Like streamflow, average surface runoff was statistically less during the drought than the wet period, with decreases from 24–31 % in the headwaters. On a volume basis, runoff decreases were greater than streamflow decreases in both the Colorado River and Gunnison River headwaters. Although the amount of water-year groundwater discharge to streams remained nearly the same between the wet and drought periods, groundwater as a percentage of streamflow increased between the wet and drought periods, highlighting the importance of groundwater in sustaining streamflow during drought conditions. Multiple linear regression analyses revealed that snowmelt-only models were better than the best precipitation and temperature models at explaining streamflow variability from all headwater subregions for both the wet and drought periods.

Arizona, Colorado, New Mexico, Utah, Wyoming