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Hydrogeologic conceptualization of the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory, Edwards Air Force Base, Antelope Valley, California, 2017–21

Research and testing within the Air Force Research Laboratory at Edwards Air Force Base in the southwestern Mojave Desert has been conducted since the 1950s. This testing requires large quantities of groundwater for cooling and operations involving hazardous constituents that have entered the groundwater. To better understand the potential movement of contaminants through the groundwater system, the U.S. Geological Survey entered into a cooperative agreement with the U.S. Air Force Civil Engineer Center with the purpose of (1) gaining a more detailed understanding of the hydraulic connection between the unconsolidated basin-fill sediment and the underlying weathered and crystalline bedrock and (2) investigating faults and their potential effect on groundwater flow. This study was specific to the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory. The refined hydrogeologic characterization was derived by evaluating surface geologic maps, a regional gravity model, new subsurface geophysical surveys, lithology data from boreholes, and groundwater-level data. Refinement of the hydrogeologic characterization of the study area involved developing a map of basin-fill sediment thickness, estimating the geometry and depth to bedrock, determining the presence of weathered bedrock material, and identifying the location of faults and subsurface structures. The thickness of basin-fill sediment was derived from a regional gravity model. Basin-fill sediment ranges from less than 20 feet (ft) thick to about 150 ft thick and increases substantially toward a deep structural basin in the northwestern part of the study area. The top of bedrock estimated from the new surface geophysical surveys is generally deeper than the top of bedrock from the regional gravity model. These differences in interpreted bedrock tops indicate that there may be a zone of weathered bedrock in the subsurface, overlying crystalline bedrock. Additional subsurface data evaluating the geometry and thickness of weathered bedrock are necessary for a comprehensive evaluation of weathered bedrock in the study area. Previously unmapped extensions of the Leuhman Fault, Spring Fault Zone, and Boron Gate Fault were identified in the new surface geophysical surveys. Evaluation of groundwater flow between bedrock and basin-fill sediment, and the effects of faults on groundwater flow, was done using groundwater-level data from 2020. The groundwater table was in crystalline bedrock throughout most of the Arroyos and Northeast Air Force Research Laboratory subareas, with a few exceptions where it was in basin-fill sediment and weathered bedrock. Basin-fill sediment, and likely weathered bedrock, was partially saturated in parts of the study area where basin-fill sediment was as thick as 150 ft. Weathered bedrock material may be present near the Spring Fault Zone, and if so, was likely saturated in 2020. The groundwater-level data near and within Spring Fault Zone indicate that the Spring Fault Zone acts as a vertical-along-strike conduit for, and as an across-strike impediment to, groundwater flow. In addition, steep groundwater-level gradients in the southeastern part of the study area indicate that a subsurface structure affecting groundwater flow could be related to the Leuhman Fault. Sufficient groundwater-level data were not available to conclusively determine if the Arroyos, Rich, and Boron Gate Faults, and their inferred extensions from the geophysical surveys, affect the movement or direction of groundwater flow.

California

Ground-motion simulations for the 2024 Mw 4.8 Tewksbury, New Jersey, earthquake

Ground-motion simulations of notable earthquakes in the central and eastern United States are limited and typically assume one-dimensional (1D) Earth structure. In this study, we use a three-dimensional (3D) seismic velocity model to better constrain the depth and focal mechanism of the April 5th, 2024, moment magnitude 4.8 Tewksbury earthquake and investigate the spatial variability of earthquake ground motions and the effects of nearby sedimentary basins. We perform earthquake ground-motion simulations up to 0.5 Hz using the 3D spectral-element wave-propagation solver SPECFEM3D over a region 280-km wide by 260-km long by 77-km deep. Topography and subsurface geophysical structure are assigned using the U.S. Geological Survey National Crustal Model with a minimum shear-wave velocity of 200 m/s. We use earthquake time series from 13 broadband seismic stations in the region that have a uniform azimuthal distribution and epicentral distances ranging from 76 to 131 km to compare with synthetics and explore the effects of 1D versus 3D seismic structure on focal mechanism and depth solutions. Ground-motion intensity metrics are also presented relative to the NGA-East ground-motion models (GMMs) currently used in seismic hazard assessments for the region. We find that the 3D model, which reveals a wide spatial variability of period-dependent ground motions, yields better predictions of earthquake ground motions relative to the 1D model and the NGA-East ergodic ground-motion model, with 76 percent reduction of residual variance in observed ground motions averaged over 3-, 5-, 7-, and 10-second periods. Use of the 3D model to solve for a focal mechanism yields a shallower focal depth at 4 km and a shallower east-dipping focal plane relative to the U.S. Geological Survey regional moment tensor and Global Centroid Moment Tensor. Our study demonstrates that use of 3D seismic velocity models can improve estimates of earthquake focal mechanisms, ground motions, and seismic hazard.

New Jersey

The petrogenesis of Þingmúli volcano, East Fjords, Iceland

In this work we revisit Þingmúli volcano (Þ = Th), a classic locality known as an example of a complete tholeiitic differentiation. Þingmúli is a ~ 9.5 Ma extinct central volcano located in the East Fjords of Iceland, in which the whole compositional spectrum from basalt to rhyolites have erupted. These volcanic products have been previously considered as petrogenetically related by an ideal fractionation trend, regardless any temporal relationship or volumetric considerations. Here we report new whole-rock geochemistry, mineral chemistry, isotope analyses, estimation of residence times of the different eruptive deposits, and an update of the original petrogenetic model. Our results highlight that an enriched source, likely spinel lherzolites, generated transitional-alkaline basaltic melts after 15–20% of partial melting at depths of 40–45 km. Many of these basaltic melts erupted at various stages of the volcano's history, while others remained longer in the volcanic plumbing system. These evolved by fractional crystallisation into basaltic andesite magmas with a residence time of ~5 years based on the crystal size distribution of the plagioclase population. Isotopic differences between the basalts/basaltic andesites ( 87 Sr/ 86 Sr ~ 0.7034; 143 Nd/ 144 Nd ~ 0.51315) and the erupted rhyolites ( 87 Sr/ 86 Sr ~ 0.7037; 143 Nd/ 144 Nd ~ 0.51304) indicate that the latter are not petrogenetically related to the former. Therefore, instead of a fractional crystallisation mechanism to generate the rhyolites, we propose the partial melting of ignimbrite layers located beneath the volcano. The broad range of trace element concentrations in andesites and dacites and their different isotopic values compared to the basalts strongly suggest that these magmas have been generated by magma mixing between basaltic and rhyolitic melts, similar to modern day Icelandic volcanoes such as Hekla. These results highlight the need to revisit previously studied Icelandic classic localities and reassess their traditionally proposed petrogenetic models.

Þingmúli volcano, East Fjords

Confocal laser-scanning microscopy (CLSM)-based thermal maturity of Tasmanites and progress in standardization of fluorescence microspectrometry

Evaluation of thermal maturity in vitrinite-free or vitrinite-deficient sediments via fluorescence microspectrometry can provide relevant information related to petroleum exploration and thermal history assessment. However, variation in spectral fluorescence properties of alginite macerals with increasing thermal maturity is largely underexplored. Here, authors of this study have applied confocal laser-scanning microscopy (CLSM) in conjunction with fluorescence microspectrometry to a maturity series of marine Upper Devonian Tasmanites algae from the Ohio Shale (Huron Member) and a single sample from the Marcellus Formation of the Appalachian Basin. Spectral fluorescence properties of Tasmanites were evaluated in relation to orientation, measurement location, and the number of measurements per sample, and were compared to published literature. Emission spectra of Tasmanites from continuous wave laser excitation (405 nm) were acquired from sections perpendicular and parallel to bedding and at different positions within individual Tasmanites bodies. The results showed a progressive red-shift in emission maxima (λ max ) in a large sample sized maturity series ( N = 19), e.g., 493 to 578 nm for the perpendicular section at middle position. Further, blue-shifted apex and mineral-adjacent positions within sections perpendicular to bedding were observed, with the latter being reported here for the first time. While blue-shift at apex positions can be attributed to mechanical deformation-induced reorientation of photoselected fluorophores, the blue-shifted mineral-adjacent positions could result from strain loading and development of a plastic deformation region at the mineral contact zone with Tasmanites . A decrease in standard deviation with increasing number of measured emission maxima is well-observed, and 15 to 20 individual measurements per sample appears sufficient for low standard deviation and coefficient of variance. CLSM-derived thermal maturity parameters indicated that a moderate positive correlation of red/green quotient (Q 650/500 ; R 2 = 0.67) with solid bitumen reflectance (BR o in %) exists. For reproducible results, the determination of λ max and Q 650/500 should be conducted exclusively in the middle position at perpendicular and parallel sections of the polished whole-rock pellets, where the lowest standard deviation in measurement was observed. These results strengthen the suitability and relevance of the CLSM technique in thermal maturity studies of dispersed organic matter (DOM) and contribute to the standardization of fluorescence microspectrometry methods in organic petrology investigation.

Kentucky, Ohio, Virginia, West Virginia

Open-source gravity reduction workflows for geothermal resource assessment

Potential-field geophysical data such as gravity can enhance understanding of geothermal resources at all stages of the resource life cycle, including assessment, exploration, development, and monitoring, and at multiple scales, from the reservoir scale to regional scale. However, to make gravity data useful for geothermal resource characterization, several processing steps are required to isolate the effects of density variations in the Earth’s crust to enable the identification of structural features associated with geothermal resources. Although this process is well-established, standard computational implementations for processing gravity data that are FAIR (Findable, Accessible, Interoperable, and Reproduceable) are still lacking. This paper details ongoing efforts at the U.S. Geological Survey (USGS) to develop a standard set of open-source Python tools for gravity data reduction that align with the FAIR principles. This workflow makes use of existing open-source tools for geophysical data processing with the goal of maximizing opportunities for rapid improvements, interoperability, and adaptability to other types of geophysical data.

Conference Paper

Deaf, deafblind, and hard of hearing university student experiences with earthquake early warning in the United States: Evaluating language planning and technology access

The growing literature on deaf and hard of hearing (DHH+) populations and disasters demonstrates that emergency communication (including alerts) is not reaching global DHH + individuals with dangerous impacts for morbidity and mortality. This is the first research study in the U.S. to qualitatively explore the experiences of DHH + persons with earthquake early warning (EEW) through group-based dialogue sessions. The study investigates eight DHH + university students'past earthquake experiences, access to EEW alerts, and perceptions of ShakeAlert Ⓡ , an EEW system for detecting earthquakes and alerting residents of California, Oregon, and Washington. Findings highlight key gaps in disaster alert usability within four thematic areas: lack of messaging in participants' language(s), unclear alert messaging, deficient message delivery mechanisms for deafblind persons, and insufficient access to earthquake information and training that leads to dependence on informal information networks. Weaknesses identified in these four themes reduce DHH + trust in EEW systems and compromise the capacity of alert recipients to take swift protective action or to mentally prepare before shaking starts. The study also underscores structural factors such as insufficient linguistic representation in disaster language planning and technology design, which ignores the linguistic and sensory access needs of DHH + individuals. Building on disaster language planning frameworks, we recommend involving DHH + populations to co-develop EEW alerts. By centering DHH + perspectives, this research contributes to ongoing efforts to ensure that EEW systems reach everyone.

California

Mineral chemistry perspective on remobilization of stored magma at Kamakai'a Hills, Southwest Rift Zone of Kilauea, Island of Hawai'i, USA

Differentiated magmas stored in the rift zones of Kīlauea have received more attention in recent years following eruption of andesite during the early phase of 2018 lower East Rift Zone activity. Despite this growing interest, some of the most voluminous eruptions of differentiated rift zone magmas remain poorly studied. One such eruption, and the most voluminous exposed differentiated flow field at Kīlauea, is the Kamakaiʻa Hills. This eruption took place in the Southwest Rift Zone of Kīlauea, a region that is hypothesized to contain a long-lived rift zone reservoir. The Kamakaiʻa Hills flow field encompasses >250 × 10 6 m 3 of basaltic andesite and basalt compositions with a mineral assemblage of orthopyroxene + clinopyroxene + plagioclase during its early ʻaʻā phase and clinopyroxene + plagioclase + olivine during its late pāhoehoe phase. To better understand storage conditions and magma accumulation, this study focuses on major, minor, and trace elements from the mineral assemblage present within the early ʻaʻā and late pāhoehoe phases. The diversity of clinopyroxene and plagioclase compositions within the early ʻaʻā and late pāhoehoe phases, as well as diverse compositions of plagioclase and orthopyroxene within the early ʻaʻā phase, suggest multiple magma bodies and limited pre-eruption magma mixing within the broader Kamakaiʻa Hills reservoir. Oscillatory zoning patterns (particularly in clinopyroxene) imply processes such as recharge events, magma mixing or mingling, or convection within a differentially cooling, chemically stratified reservoir over protracted time intervals, whereas only limited resorbed mineral textures indicate incomplete mixing of heat and chemically distinct magmas during the dike intrusion that triggered the eruption. Mineral-mineral and mineral-melt thermobarometry indicate predominantly shallow (≤2.5 km depth) crustal storage conditions of the cooled, differentiated magma (∼1100 °C and cooler for the basaltic andesites) to hotter temperatures for the basalts (all >1100 °C). Despite the known large standard errors estimated for mineral-melt and mineral-mineral barometry (10s to >100 MPa), the calculated pressures and depths broadly correspond with earthquake swarm depths beneath the Kamakaiʻa Hills, and drill core and fluid inclusion barometry storage depths of differentiated magmas within the lower East Rift Zone. The Kamakaiʻa Hills differentiated magmas have H 2 O contents (∼0.5 wt%, using plagioclase-melt hygrometry) equivalent to typical Kīlauea basalts. Our data and interpretations demonstrate a complex, long-lived rift zone storage system that consisted of multiple magma bodies and was mobilized into eruption through intrusion of a hotter and more primitive summit-derived (uprift) magma.

Hawaii

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal

Small-volume tephra deposits of the May 1924 explosions from Halemaʻumaʻu, Kīlauea volcano, and their origin

More than 50 explosive eruptions occurred from Halemaʻumaʻu at Kīlauea volcano over 17 days from May 11 to 27, 1924. Ballistics weighing as much as 14,000 kg were ejected and most landed within 2 km of the vent. Fine ash made up a major component of the tephra and was dispersed tens of kilometers downwind. Draining of the Halemaʻumaʻu lava lake occurred in late February 1924, with the crater floor eventually subsiding by a further ∼70 m (to ∼180 m below the crater rim) by the time the first explosions took place during the night of May 10–11. The largest explosions occurred on May 17–18 and smaller explosions continued until May 27, at which point Halemaʻumaʻu had more than doubled in width and depth. The explosions generated plumes reaching up to ∼10 km high with ballistics ejected up to 2 km from the crater. Almost 100 years later, we investigate and characterize the preserved tephra deposits within ∼3 km of the 1924 crater rim. Grain size and shape analyses were performed on 202 samples collected from 34 tephra profiles using dynamic image analysis, with a subset of layers from nine tephra profiles used for componentry (200 grains per layer in the 0.5–1 mm size fraction). Additionally, we characterize the average diameters (using the five largest clasts) at 216 locations and measure the average diameters of 2291 ballistics (largest per ∼100 m 2 area). Physical descriptions from fieldwork and grain size distributions were used to subdivide the tephra layers into five lithofacies: coarse homogeneous, fine homogenous, red ash, accretionary lapilli-bearing, and finely laminated. Grain size versus shape data show a range of values that demonstrate most grains are dense, smooth, and equant, in alignment with lithic clasts dominating the tephra componentry. The fine grained and accretionary lapilli-bearing nature of some of these lithofacies confirms that water influenced the style of the explosions. However, we also note juvenile clasts within many of the tephra layers, indicating that many of the layers were formed during phreatomagmatic explosions (sensu stricto), despite the eruptive mechanism being dominantly phreatic. Juvenile clasts are more abundant higher in the tephra profiles, suggesting that juvenile magma was more involved later in the explosive sequence. Thermal and hydrologic modeling indicate that groundwater inflow into a short-lived, small-diameter volcanic conduit (10-m to 120-m-diameter used for modeling) during the 78–85 days preceding the first explosion provides a physically plausible mechanism for this eruptive sequence.

Hawaii

Examining the compositional selectivity of hydrocarbon oxidation products using liquid–liquid extraction and solid-phase extraction techniques

The effect of extraction methods on detecting hydrocarbon oxidation products (HOPs) in groundwater remains unclear. HOPs are polar, water-soluble byproducts of petroleum biodegradation. Our previous work showed that liquid–liquid extraction (LLE), a method commonly used in regulatory monitoring, has a significantly lower extraction efficiency for HOPs compared to solid-phase extraction (SPE). In this study, we evaluate the analytical limitations and compositional selectivity of LLE and SPE using groundwater samples from the Bemidji, MN, crude oil spill site. Optical properties were characterized using excitation–emission matrix spectroscopy (EEMs), and a three-component PARAFAC model was validated, showing consistent trends across both extracts and whole water samples. Ultrahigh-resolution mass spectrometry (UHR-MS) revealed that LLE selectively recovered aliphatic-like compounds but underrepresented more polar oxygenated HOPs. In contrast, SPE methods were more effective at isolating highly oxidized compound classes. These differences were consistent across a gradient of contamination. Overall, the LLE was less precise and less representative of polar HOPs, introducing bias in the characterization of HOPs. This study is the first to quantitatively demonstrate the compositional selectivity and analytical bias of LLE versus SPE for HOPs using combined EEM-PARAFAC and UHR-MS techniques, with implications for long-term monitoring and site assessment protocols.

Environmental Science and Technology

VIPER site analysis

We needed to evaluate available orbital data of NASA’s Volatiles Investigating Polar Exploration Rover (VIPER) mission area in order to derive a variety of maps to help the science team identify scientifically interesting places for the rover to visit and to provide scientific context for our mission. Some of these maps also fulfilled engineering and mission design needs to enable safe and efficient landing and roving. We incorporated data from the Lunar Reconnaissance Orbiter Camera, the Lunar Orbital Laser Altimeter, the Mini-RF instrument, the Chandrayaan-2 Orbital High Resolution Camera, the Korean Pathfinder Lunar Orbiter’s Shadowcam, the Kaguya Spectral Profiler and Multiband Imager, and the Chandrayaan-1 Moon Mineralogy Mapper. We used a variety of techniques to build these maps, including stereogrammetry, shape-from-shading, ice stability depth and surface temperature calculations, and the horizon method for solar illumination and direct-to-Earth communications maps. Altogether, these maps allowed us to survey for boulders, evaluate features in permanently shadowed regions that VIPER might explore, provide mineralogic context for what VIPER’s instruments may learn, estimate the ages and radar properties of craters in the VIPER mission area, and evaluate the potential for gravity traverses with the rover. These data and techniques provided a rich set of information from which both the VIPER science team and engineering teams were able to draw in order to plan a safe landing and to plan a VIPER surface mission that will be both scientifically valuable and robust from an operational perspective.

The Planetary Science Journal

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio

Rapid emplacement of the Keaiwa Lava Flow of 1823 from the Great Crack in the Southwest Rift Zone of Kilauea volcano

The Keaīwa Lava Flow of 1823 in the Southwest Rift Zone of Kīlauea volcano is unusual for its expansive pāhoehoe sheet flow morphology and lack of constructive vent topography, despite having a similar tholeiitic basalt composition to other lavas erupted from Kīlauea. This lava flow issued from a ∼10-km-long continuous fissure now known as the Great Crack, and has an unusually thin sheet flow morphology with margin thicknesses of ∼15–110 cm (average of 42 cm). Based on field observations of the lava flow at its fissure vent (e.g., drain-back features), we propose that the Great Crack formed, or at least significantly widened, just prior to and syn-eruptively with this 1823 eruption. The absence of pyroclastic cones or spatter ramparts indicates that the eruption consisted of a rapid outpouring of relatively degassed lava as the fissure unzipped. The rapidly moving lava flow overtopped pre-existing tumuli and scoria cones (e.g., Lava Plastered Cones) up to ∼10 m tall. Glass and whole-rock chemistry yield homogeneous compositions for the lavas erupted from the Great Crack, with glass compositions of 6.40 ± 0.10 wt% MgO and whole-rock compositions of 7.39 ± 0.07 wt% MgO. Lava pads erupted from a short western fissure system are richer in mafic minerals (e.g., olivine and clinopyroxene), and show slightly more MgO-rich whole-rock compositions (7.79 ± 0.05 wt%). MgO-in-glass thermometry on juvenile spatter yield eruption temperatures of 1153 ± 13°C that are typical of Kīlauea lavas. Thus, the extensive sheet-like lava flow morphology is not a direct consequence of unusual magmatic or rheological conditions (i.e., low viscosity). Instead, the flow morphology is associated with high effusion rates caused by sudden drainage of uprift magma as it erupted from the Great Crack. Lava flow modeling on a 2-m-resolution digital elevation model indicates that a minimum bulk effusion rate of ∼5800 m 3 /s (∼3500 m 3 /s dense rock equivalent) and a minimum flow velocity of ∼11 m/s are required for the lava flow to overcome the topography of the Lava Plastered Cones. This effusion rate is among the highest inferred for eruptions in Hawaiʻi and around the world. This study highlights a less frequent eruption style at Hawaiian volcanoes characterized by a sudden outpouring of lava from an unusual fissure system. Local eyewitness accounts indicate that the 1823 eruption was preceded by seismicity. Given the complex magmatic-volcanic-tectonic relations across Kīlauea, we speculate that the south flank could have slipped over one or more events that ultimately triggered unzipping of the Great Crack and passive release of briefly stored uprift magma. An eruption similar to 1823 at Kīlauea or Mauna Loa, with an eruptive timeframe that could be as short as an hour, with high effusion rates and rapid flow front velocities, would not easily allow for a timely response.

Hawaii

Determination of baseline water-quality conditions using continuous specific conductance and discrete measurements of total dissolved solids and selected major ions, Arkansas River Basin, Colorado

From 2022 through 2024, the U.S. Geological Survey (USGS) in cooperation with the Regional Resources Planning Group (Southeastern Colorado Water Conservancy District, Colorado Springs Utilities, Pueblo Water, Lower Arkansas Valley Water Conservancy District, Aurora Water, and Upper Arkansas Water Conservancy District) established a basinwide water-quality monitoring network in the Arkansas River Basin in Colorado. The study leveraged ongoing continuous measurements of streamflow and specific conductance (SC) at 13 sites along the main stem Arkansas River and Fountain Creek from the USGS 07108600 Arkansas River at Granite, Colo., (Ark Granite) site to the USGS 07137500 Arkansas River near Coolidge, Kansas, (Ark Coolidge) site. Baseline water-quality conditions were established using data from October 1989 through September 2022 to help identify changes in water quality that could result from changes in land and water use. Total dissolved solids (TDS) concentration was the main indicator of general water quality in this study because it can be accurately estimated from SC and is sensitive to changes in streamflow, water operations, and source contributions. Median TDS concentrations in Arkansas River samples (October 1989 through December 2023) ranged from 75 milligrams per liter (mg/L) at Ark Granite near the headwaters to 3,660 mg/L at Ark Coolidge near the Colorado–Kansas State line. Distinct seasonal differences in median streamflow and TDS were apparent during the winter and summer months. Seasonal Kendall tests showed no significant trends in monthly mean streamflow (October 1995 through September 2022) at Arkansas River sites upstream from Pueblo Reservoir. Upward trends in TDS concentrations and loads occurred only at Ark Granite. Downward trends in streamflow, TDS concentrations, and TDS loads occurred at Arkansas River sites from USGS 07109500 Arkansas River near Avondale, Colo., to Ark Coolidge. Downward trends in streamflow and SC (surrogate for TDS) were more prevalent during winter base flow months and may indicate changes in groundwater quantity, and possibly groundwater quality, potentially affecting the river water-quality condition.

Colorado

Long-term monotonic trends in water budget components in the contiguous United States: Insights from two hydrologic models

Characterizing changes to water availability for domestic, industrial, agricultural, and other uses is essential to support water management. To better quantify these changes, the U.S. Geological Survey and National Science Foundation National Center for Atmospheric Research produced two hydrologic models simulating water budget components from 1980 to 2021 over the contiguous United States (CONUS). Both hydrologic models were driven by a common atmospheric forcing dataset and aggregated to common spatial and temporal scales, which enables a novel evaluation of congruency between the models. We present annual and seasonal trends in six water budget components (precipitation, evapotranspiration, streamflow, groundwater recharge, soil saturation, and snow water equivalent) based on the Mann–Kendall test for monotonic trend and Theil-Sen slope estimate for the water year 1983–2021 period for ~86,000 catchments in CONUS. Additional components and metrics from our analysis pipeline are available in an associated published dataset, which contains more than 46 million trend results. The water budget trends showed broad agreement with prior observational and modeling studies that indicate increasing trends in the northeast and decreasing trends in southwestern CONUS. We found the seasonal variability in water budget trends was greatest in the southern, central, and northwest CONUS. These findings support integrated trend assessments when coupled with trends in water quality and use.

Contiguous United States

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research

Continental-scale prediction of hydrologic signatures and processes

Understanding how dominant hydrologic processes and their drivers vary across diverse continental-scale landscapes is critical for hydrologic modeling and water management applications. Our research addresses this question by synthesizing large-sample watershed datasets, Caravan and GAGES-II, and developing random forest models to identify patterns in hydrologic function. We assessed dominant processes by examining hydrologic signatures – summary indicators of watershed function derived from hydroclimatic time series and random forest models across 14 146 gauged United States watersheds. The results reveal clear continental-scale gradients in hydrologic processes, including baseflow, overland flow, storage, and water balance losses. Our map of dominant processes highlights, for example, the transition from baseflow to fast responses and back to baseflow along the elevation gradient from the Appalachian spine, through the Piedmont, to the Eastern Coastal Plain; a distinct outer ring around the Great Lakes region; and sharp contrasts between coastal and inland processes in the West. Variable importance analysis from random forest models show that processes in the western U.S. are primarily controlled by climate, whereas in the eastern U.S., soil, geology, and topography play larger roles, with distinct human influences apparent in urban areas. Our approach of estimating dominant processes and their drivers facilitates extending process knowledge from research watersheds to the continental scale, assessing current hydrological understanding, and evaluating hydrological model structures.

conterminous United States

Drone-based radiometric surveys provide high-resolution mine waste characterization

Airborne radiometric surveys use passive geophysical techniques to characterize geochemical variations at or near earth’s surface. These methods have been used for a variety of mapping applications, including mineral resource evaluation. However, detailed characterization of smaller geologic targets, including mine waste features, requires flying at lower altitudes and with tighter line spacing than is feasible with traditional aircraft. Here, a small uncrewed aircraft system (sUAS) equipped with a radiometric sensor was used to acquire high-resolution gamma-spectrometry over small mine waste features and a low-grade stockpile in southwestern New Mexico. The sUAS radiometric system mapped local variability within each survey area and revealed ~2–10 m wide zones where radioelements K, Th, and U may be elevated 2–10× the surrounding material. Additionally, the sUAS radiometric data revealed radioelement variability across survey sites, which correlated reasonably well with variability seen in geochemical samples at each survey site, even though samples collected from individual sites showed high local variability. The sUAS data characterized local heterogeneity within mine waste and other small geologic targets at scales of a few meters to tens of meters, which is not possible with traditional crewed aircraft, and with continuity of coverage that is not possible with ground surveys, thus filling a key gap in geophysical survey spatial resolution.

New Mexico