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At least 127 records · Page 7Linked to original sources

Groundwater observation network design for the Kansas groundwater management districts, U.S.A.

Concerns about the efficiency and economic soundness of the Kansas groundwater monitoring program led to a systematic redesign of this network, a tentative phase of which is presented in this study. The objectives of this paper include monitoring of major aquifers within each groundwater management district at a spatially more uniform level of accuracy, elimination of redundant measurements and optimization of the information gained from each observation well. The theory of regionalized variables is employed to estimate the amount of spatial variability of the water table, on which the network design is based. This study shows that it is not practical to attempt to reduce the already existing level of uncertainty uniformly throughout the various districts; to do so would tremendously increase the cost of well monitoring, which is already very high. Assuming that the currently existing network is satisfactory for the State's objectives, a reduced network consisting of one well every 6.4 km is equally satisfactory. The reduced network yields district-wide maps that do not differ significantly from those produced using the present network and at the same time it reduces the already-existing network by 18–47%. Therefore, adoption of a rearranged square well network is recommended, which is reduced to a 6.4-km spacing to achieve both a uniform level of information about the water table and a minimum required accuracy.

Kansas↗

The local effects of groundwater pumpage within a fault-influenced groundwater basin, Ash Meadows, Nye County, Nevada, U.S.A.

Large-scale groundwater pumpage and water-level decline data are used in a preliminary attempt to identify the hydraulic connection between several wells and Devils Hole, a small pond in Nye County, Nevada, U.S.A. Results indicate that despite the discontinuous nature of the local aquifers, many wells have good hydraulic connection with Devils Hole. Hydraulic connection between the wells and Devils Hole exhibits a complex spatial variability typical of carbonate terrane. Zones or directions of minimal hydraulic connection may result from fault-controlled structural discontinuities. Zones or directions of enhanced hydraulic connection point to the presence of large-scale groundwater flow through fractures or conduits. The orientation of waterbearing fractures or conduits inferred from this study is qualitatively consistent with the major orientation of local and regional structural features.

Nevada↗

Knowledge, transparency, and refutability in groundwater models, an example from the Death Valley regional groundwater flow system

This work demonstrates how available knowledge can be used to build more transparent and refutable computer models of groundwater systems. The Death Valley regional groundwater flow system, which surrounds a proposed site for a high level nuclear waste repository of the United States of America, and the Nevada National Security Site (NNSS), where nuclear weapons were tested, is used to explore model adequacy, identify parameters important to (and informed by) observations, and identify existing old and potential new observations important to predictions. Model development is pursued using a set of fundamental questions addressed with carefully designed metrics. Critical methods include using a hydrogeologic model, managing model nonlinearity by designing models that are robust while maintaining realism, using error-based weighting to combine disparate types of data, and identifying important and unimportant parameters and observations and optimizing parameter values with computationally frugal schemes. The frugal schemes employed in this study require relatively few (10–1000 s), parallelizable model runs. This is beneficial because models able to approximate the complex site geology defensibly tend to have high computational cost. The issue of model defensibility is particularly important given the contentious political issues involved.

California, Nevada↗

Methods for using groundwater model predictions to guide hydrogeologic data collection, with application to the Death Valley regional groundwater flow system

Calibrated models of groundwater systems can provide substantial information for guiding data collection. This work considers using such models to guide hydrogeologic data collection for improving model predictions by identifying model parameters that are most important to the predictions. Identification of these important parameters can help guide collection of field data about parameter values and associated flow system features and can lead to improved predictions. Methods for identifying parameters important to predictions include prediction scaled sensitivities (PSS), which account for uncertainty on individual parameters as well as prediction sensitivity to parameters, and a new “value of improved information” (VOII) method presented here, which includes the effects of parameter correlation in addition to individual parameter uncertainty and prediction sensitivity. In this work, the PSS and VOII methods are demonstrated and evaluated using a model of the Death Valley regional groundwater flow system. The predictions of interest are advective transport paths originating at sites of past underground nuclear testing. Results show that for two paths evaluated the most important parameters include a subset of five or six of the 23 defined model parameters. Some of the parameters identified as most important are associated with flow system attributes that do not lie in the immediate vicinity of the paths. Results also indicate that the PSS and VOII methods can identify different important parameters. Because the methods emphasize somewhat different criteria for parameter importance, it is suggested that parameters identified by both methods be carefully considered in subsequent data collection efforts aimed at improving model predictions.

California, Nevada↗

Groundwater “fast paths” in the Snake River Plain aquifer: Radiogenic isotope ratios as natural groundwater tracers

Preferential flow paths are expected in many groundwater systems and must be located because they can greatly affect contaminant transport. The fundamental characteristics of radiogenic isotope ratios in chemically evolving waters make them highly effective as preferential flow path indicators. These ratios tend to be more easily interpreted than solute-concentration data because their response to water-rock interaction is less complex. We demonstrate this approach with groundwater 87 Sr/ 86 Sr ratios in the Snake River Plain aquifer within and near the Idaho National Engineering and Environmental Laboratory. These data reveal slow-flow zones as lower 87 Sr/ 86 Sr areas created by prolonged interaction with the host basalts and a relatively fast flowing zone as a high 87 Sr/ 86 Sr area.

Idaho↗

Spatial variability of groundwater recharge and its effect on shallow groundwater quality in southern New Jersey

Point estimates of groundwater recharge at 48 sediment-coring locations vary substantially (−18.5–1840 cm yr −1 ) in a 930-km 2 area of southern New Jersey. Darcian estimates of steady, long-term recharge made at depth in the unsaturated zone were estimated using pedotransfer functions of soil texture and interpolated (mapped) with nonparametric methods to assess aquifer vulnerability in the area. The probability of exceeding the median recharge (29.1 cm yr −1 ) is low in the southwestern and northeastern portions of the study area and high in the eastern and southeastern portions. Estimated recharge is inversely related to measured percentage clay and positively related to the percentage of well-drained soils near wells. Spatial patterns of recharge estimates, exceedance probabilities, and clay content indicate that sediment texture controls recharge in the study area. Relations with land elevation and a topographic wetness index were statistically insignificant. Nitrate concentration and atrazine (6-chloro- N 2 -ethyl- N 4 -isopropyl-1,3,5-triazine-2,4-diamine) percentage detection in samples of shallow groundwater (typically <10 m) are higher for low recharge sites (≤29.1 cm yr −1 ) than for high recharge sites (>29.1 cm yr −1 ) in agricultural and urban areas. Differences between high and low recharge sites in these areas are highly significant for NO 3 concentration, but not for atrazine concentration.

New Jersey↗

Groundwater data for selected wells within the Eastern San Joaquin Groundwater Subbasin, California, 2003-8

Data were collected by the U.S. Geological Survey from 2003 through 2008 in the Eastern San Joaquin Groundwater Subbasin, 80 miles east of San Francisco, California, as part of a study of the increasing chloride concentrations in groundwater processes. Data collected include geologic, geophysical, chemical, and hydrologic data collected during and after the installation of five multiple-well monitoring sites, from three existing multiple-well sites, and from 79 selected public-supply, irrigation, and domestic wells. Each multiple-well monitoring site installed as part of this study contained three to five 2-inch diameter polyvinyl chloride (PVC)-cased wells ranging in depth from 68 to 880 feet below land surface. Continuous water-level data were collected from the 19 wells installed at these 5 sites and from 10 existing monitoring wells at 3 additional multiple-well sites in the study area. Thirty-one electromagnetic logs were collected seasonally from the deepest PVC-cased monitoring well at seven multiple-well sites. About 200 water samples were collected from 79 wells in the study area. Coupled well-bore flow data and depth-dependent water-quality data were collected from 12 production wells under pumped conditions, and well-bore flow data were collected from 10 additional wells under unpumped conditions.

California↗

Groundwater resources of the Wood River Valley, Idaho--A groundwater-flow model for resource management

The U.S. Geological Survey (USGS), in collaboration with the Idaho Department of Water Resources (IDWR), will use the current understanding of the Wood River Valley aquifer system to construct a MODFLOW numerical groundwater-flow model to simulate potential anthropogenic and climatic effects on groundwater and surface-water resources. This model will serve as a tool for water rights administration and water-resource management and planning. The study will be conducted over a 3-year period from late 2012 until model and report completion in 2015.

Idaho↗

Groundwater quality and groundwater levels in Dougherty County, Georgia, April 2020 through January 2023

The Upper Floridan aquifer is the uppermost reliable groundwater source in southwest Georgia. The aquifer lies on top of the Claiborne, Clayton, and Cretaceous aquifers, all of which exhibited water-level declines in the 1960s and 1970s. The U.S. Geological Survey has been working cooperatively with Albany Utilities to monitor groundwater quality and availability in these aquifers since 1977. Flow direction in the Upper Floridan aquifer is to the south and toward the Flint River. During the past 3 years, water levels varied above and below period-of-record median values. Water levels in the Upper Floridan aquifer were primarily above or at median levels during 2020 and 2021 and at or below median levels during 2022. Water levels in the Claiborne aquifer were above median levels, whereas water levels in the Clayton aquifer were at or below median levels, and in the Cretaceous aquifer system were close to median levels. During January 2021, eight wells were sampled for major ions, including nitrate plus nitrite as nitrogen (N). Nitrate plus nitrite as N concentrations ranged from 2.3 to 10.5 milligrams per liter (mg/L). During December 2021, seven wells were sampled for major ions, including nitrate plus nitrite as N. Nitrate plus nitrite as N concentrations ranged from 3.9 to 9.9 mg/L. During November 2022, eight wells were sampled for major ions, including nitrate plus nitrite as N. Nitrate plus nitrite as N concentrations ranged from 3.9 to 10.0 mg/L. Two wells were also sampled for per- and polyfluoroalkyl substances during November 2022.

Georgia↗

Groundwater tracing used to delineate recharge areas and map karst groundwater pathways for subterranean streams at Oregon Caves National Monument and Preserve

Oregon Caves National Monument and Preserve in southwestern Oregon is a 4,554-​acre area managed by the National Park Service that is home to several cave systems, including Oregon Caves, which is the longest cave in Oregon, with 3.03 miles of mapped passages. Because of the interconnected nature of karst hydrologic systems, it is critical to understand the areas that can influence water quality and quantity in karst environments. Toward this goal, dye tracing was conducted by the U.S. Geological Survey from 2021 to 2024 to better understand the pathways that karst groundwater follows at Oregon Caves National Monument and Preserve and to delineate recharge areas for two caves, Oregon Caves and Cave Next Door. During the project, eight dye injections were conducted, delineating a 0.51-​square-​mile recharge area for Oregon Caves and a 0.69-​square-​mile recharge area for Cave Next Door. Additionally, the study helped to identify three resurgences associated with Oregon Caves that were previously unknown and showed that the recharge areas for the two caves were distinct from one another. The dye traces also illuminated some unique recharge characteristics of the karst at Oregon Caves, including a high variance in karst groundwater velocities, retention within the karst aquifers, and a significant diffuse-​flow component.

Oregon↗

Using groundwater age distributions to understand changes in methyl tert-butyl ether (MtBE) concentrations in ambient groundwater, northeastern United States

Temporal changes in methyl tert-butyl ether (MtBE) concentrations in groundwater were evaluated in the northeastern United States, an area of the nation with widespread low-level detections of MtBE based on a national survey of wells selected to represent ambient conditions. MtBE use in the U.S. peaked in 1999 and was largely discontinued by 2007. Six well networks, each representing specific areas and well types (monitoring or supply wells), were each sampled at 10 year intervals between 1996 and 2012. Concentrations were decreasing or unchanged in most wells as of 2012, with the exception of a small number of wells where concentrations continue to increase. Statistically significant increasing concentrations were found in one network sampled for the second time shortly after the peak of MtBE use, and decreasing concentrations were found in two networks sampled for the second time about 10 years after the peak of MtBE use. Simulated concentrations from convolutions of estimates for concentrations of MtBE in recharge water with age distributions from environmental tracer data correctly predicted the direction of MtBE concentration changes in about 65 percent of individual wells. The best matches between simulated and observed concentrations were found when simulating recharge concentrations that followed the pattern of national MtBE use. Some observations were matched better when recharge was modeled as a plume moving past the well from a spill at one point in time. Modeling and sample results showed that wells with young median ages and narrow age distributions responded more quickly to changes in the contaminant source than wells with older median ages and broad age distributions. Well depth and aquifer type affect these responses. Regardless of the timing of decontamination, all of these aquifers show high susceptibility for contamination by a highly soluble, persistent constituent.

Science of the Total Environment↗

Using groundwater temperature data to constrain parameter estimation in a groundwater flow model of a wetland system

Parameter estimation is a powerful way to calibrate models. While head data alone are often insufficient to estimate unique parameters due to model nonuniqueness, flow‐and‐heat‐transport modeling can constrain estimation and allow simultaneous estimation of boundary fluxes and hydraulic conductivity. In this work, synthetic and field models that did not converge when head data were used did converge when head and temperature were used. Furthermore, frequency domain analyses of head and temperature data allowed selection of appropriate modeling timescales. Inflows in the Wilton, Wisconsin, wetlands could be estimated over periods such as a growing season and over periods of a few days when heads were nearly steady and groundwater temperature varied during the day. While this methodology is computationally more demanding than traditional head calibration, the results gained are unobtainable using the traditional approach. These results suggest that temperature can efficiently supplement head data in systems where accurate flux calibration targets are unavailable.

Water Resources Research↗

Groundwater quality and groundwater levels in Dougherty County, Georgia, April 2019 through March 2020

The Upper Floridan aquifer is the uppermost, reliable aquifer in southwest Georgia. The aquifer lies on top of the Claiborne, Clayton, and Cretaceous aquifers, all of which exhibited water level declines in the 1960s and 1970s. The U.S. Geological Survey has been working cooperatively with Albany Utilities to monitor groundwater quality and availability in these aquifers since 1977. During January 2020, nine wells were sampled—six for anions, metals, and nitrate plus nitrite as nitrogen, and three for anions, metals, and pesticides. Nitrate plus nitrite as nitrogen concentrations ranged from 2.4 milligrams per liter (mg/L) to 10.4 mg/L, and no pesticides were detected. Nitrate plus nitrite as nitrogen concentrations in well 12L277, open to the Upper Floridan aquifer, have been above the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 mg/L for nitrates in drinking water since 2014. Flow direction in the Upper Floridan aquifer is to the south and toward the Flint River. Water levels varied during the past year above and below period of record median values. Water levels in the Upper Floridan aquifer were primarily above median levels. Water levels in the Claiborne aquifer were above median levels, whereas water levels in the Clayton and Cretaceous aquifers were below median levels.

Georgia↗

Effects of groundwater withdrawal on borehole flow and salinity measured in deep monitor wells in Hawai'i: implications for groundwater management

Water-resource managers in Hawai`i rely heavily on salinity profiles from deep monitor wells to estimate the thickness of freshwater and the depth to the midpoint of the transition zone between freshwater and saltwater in freshwater-lens systems. The deep monitor wells are typically open boreholes below the water table and extend hundreds of feet below sea level. Because of possible borehole-flow effects, there is concern that salinity profiles measured in these wells may not accurately reflect the salinity distribution in the aquifer and consequently lead to misinterpretations that adversely affect water-resource management. Steplike changes in salinity or temperature with depth in measured profiles from nonpumped deep monitor wells may be indicative of water moving within the well, and such changes are evident to some extent in all available profiles. The maximum vertical step length, or displacement, in measured profiles ranges from 7 to 644 feet. Vertical steps longer than 70 feet exceed the typical thickness of massive lava flows; they therefore cannot be attributed entirely to geologic structure and may be indicative of borehole flow. The longest vertical steps occur in monitor wells located in southern O'ahu, coinciding with the most heavily developed part of the aquifer. Although regional groundwater withdrawals have caused a thinning of the freshwater lens over the past several decades, the measured midpoint of the transition zone in most deep monitor wells has shown only inconsequential depth displacement in direct response to short-term variations in withdrawals from nearby production wells. For profiles from some deep monitor wells, however, the depth of the measured top of the transition zone, indicated by a specific-conductance value of 1,000 microsiemens per centimeter, has risen several hundred feet in response to withdrawals from nearby production wells. For these deep monitor wells, monitoring the apparent top of the transition zone may not provide an accurate indication of water quality in the adjacent aquifer. Hence, the measured midpoint in boreholes is a better proxy for freshwater-lens thickness. Brackish water transported upward in a deep monitor well can exit the borehole in the upper, freshwater part of the aquifer and affect the water quality in nearby production wells. Piezometers installed at different depths will provide the best information on aquifer salinity because they are unaffected by borehole flow. Despite the effects of borehole flow, monitoring the midpoint in deep monitor wells is still useful to identify long-term trends in the movement of the transition zone.

Hawaii↗

Hydrogeology, numerical simulation of groundwater flow, and effects of future water use and drought for reach 1 of the Washita River alluvial aquifer, Roger Mills and Custer Counties, western Oklahoma, 1980–2015

The Washita River alluvial aquifer is a valley-fill and terrace alluvial aquifer along the valley of the Washita River in western Oklahoma that provides a productive source of groundwater for agricultural irrigation and water supply. The Oklahoma Water Resources Board (OWRB) has designated the westernmost section of the aquifer in Roger Mills and Custer Counties, Okla., as reach 1 of the Washita River alluvial aquifer; reach 1 is the focus of this report. The OWRB issued an order on November 13, 1990, that established the maximum annual yield (MAY; 120,320 acre-feet per year [acre-ft/yr]) and equal-proportionate-share (EPS) pumping rate (2.0 acre-feet per acre per year [(acre-ft/acre)/yr]) for reach 1 of the Washita River alluvial aquifer. The MAY and EPS were based on hydrologic investigations that evaluated the effects of potential groundwater withdrawals on groundwater availability in the Washita River alluvial aquifer. Every 20 years, the OWRB is statutorily required to update the hydrologic investigation on which the MAY and EPS were based. Because 30 years have elapsed since the last order was issued, the U.S. Geological Survey, in cooperation with the OWRB, conducted a new hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater flow and availability in the Washita River alluvial aquifer. The Washita River is the primary source of inflow to Foss Reservoir, a Bureau of Reclamation reservoir constructed in 1961 for flood control, water supply, and recreation. Foss Reservoir provides water for Bessie, Clinton, New Cordell, and Hobart, Okla. Nearly 98 percent of the total groundwater use from the Washita River alluvial aquifer during 1967 to 2015 was for irrigation; other uses of groundwater in the study area include public supply, mining, and agriculture. A hydrogeologic framework was developed for the Washita River alluvial aquifer and included the physical characteristics of the aquifer, the geologic setting, the hydraulic properties of hydrogeologic units, the potentiometric surface (water table), and groundwater-flow directions at a scale that captures the regional controls on groundwater flow. The Washita River alluvial aquifer consists of alluvium and terrace deposits that were transported primarily by water and range from clay to gravel in size. The terrace includes windblown deposits of silt size and, in some cases, contains gravel laid down at several levels along former courses of present-day rivers. A conceptual flow model is a simplified description of the aquifer system that includes hydrologic boundaries, major inflow and outflow sources of the groundwater-flow system, and a conceptual water budget with the estimated mean flows between those hydrologic boundaries. During the study period 1980–2015, mean annual groundwater withdrawals, predominantly used for agricultural irrigation, totaled 5,502 acre-ft/yr, or 14 percent of aquifer outflows. When applied across the 132-square-mile aquifer area used for modeling purposes (84,366 acres), mean annual recharge of 3.15 inches per year corresponds to a mean annual recharge volume of 22,169 acre-ft/yr, or 56 percent of aquifer inflows. The annual saturated-zone evapotranspiration outflow was 11,828 acre-ft/yr for the Washita River alluvial aquifer, or about 30 percent of aquifer outflows. For the Washita River alluvial aquifer, lateral flow was 17,157 acre-ft/yr, or 44 percent of the aquifer inflows. The conceptual flow model and hydrogeologic framework were used to conceptualize, design, and build the numerical groundwater-flow model. A numerical groundwater-flow model of the Washita River alluvial aquifer was constructed by using MODFLOW-2005. The Washita River alluvial aquifer groundwater-model grid was spatially discretized into 350-foot (ft) cells and two layers. Layer 1 represented the undifferentiated alluvium and terrace deposits of Quaternary age, and layer 2 represented the bedrock of Permian age, which was given a uniform nominal thickness of 100 ft. The groundwater-simulation period was temporally discretized into 433 monthly transient stress periods, representing January 1980 to December 2015. An initial 365-day steady-state stress period was configured to represent mean annual inflows and outflows from the Washita River alluvial aquifer for the study period. The groundwater-flow model was calibrated manually and by automated adjustment of model inputs by using PEST++. Calibration targets for the Washita River alluvial aquifer model included groundwater-level observations and reservoir-stage observations, as well as base-flow and stream-seepage estimates. Three groundwater-availability scenarios were used in the calibrated groundwater model to (1) estimate the EPS pumping rate that retains the saturated thickness that meets the minimum 20-year life of the aquifer, (2) quantify the effects of projected pumping rates on groundwater storage over a 50-year period, and (3) evaluate how projected pumping rates extended 50 years into the future and sustained hypothetical drought conditions over a 10-year period affect base flow and groundwater in storage. The results of the groundwater-availability scenarios could be used by the OWRB to reevaluate the established MAY of groundwater from the Washita River alluvial aquifer. EPS scenarios for the Washita River alluvial aquifer were run for periods of 20, 40, and 50 years. The 20-, 40-, and 50-year EPS pumping rates under normal recharge conditions were 1.7, 1.6, and 1.6 (acre-ft/acre)/yr, respectively. Given the aquifer area used for modeling purposes (84,366 acres), these rates correspond to annual yields of 142,579, 134,986, and 134,986 acre-ft/yr, respectively. Groundwater storage at the end of the 20-year EPS scenario was about 281,000 acre-feet (acre-ft), or about 306,000 acre-ft (52 percent) less than the starting storage. Considering the land-surface area of the Washita River alluvial aquifer and using a specific yield of 0.12, this decrease in storage was equivalent to a mean groundwater-level decline of about 30 ft. The Washita River downstream from Foss Reservoir and most of the streams in the study area were dry at the end of the 20-year EPS scenario. Foss Reservoir stage was below the dead-pool stage of 1,597 ft after about 7 years of pumping in the 20-year EPS scenario. Four projected 50-year groundwater-use scenarios were used to simulate the effects of selected well withdrawal rates on groundwater storage in the Washita River alluvial aquifer. These four scenarios used (1) no groundwater use, (2) groundwater use at the 2015 pumping rate, (3) mean groundwater use for the simulation period, and (4) increasing groundwater use. Groundwater storage after 50 years with no groundwater use was 545,249 acre-ft, or 693 acre-ft (0.1 percent) greater than the initial groundwater storage; this groundwater storage increase is equivalent to a mean groundwater-level increase of 0.1 ft. Groundwater storage at the end of the 50-year period with 2015 pumping rates was 543,831 acre-ft, or 723 acre-ft (0.1 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage after 50 years with the mean pumping rate for the study period was 543,202 acre-ft, or 1,349 acre-ft (0.2 percent) less than the initial groundwater storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.1 ft. Groundwater storage at the end of the 50-year period with an increasing demand groundwater-pumping rate, which was 38 percent greater than the 2015 groundwater-pumping rate, was 542,584 acre-ft, or 1,967 acre-ft (0.4 percent) less than the initial storage; this groundwater storage decrease is equivalent to a mean groundwater-level decrease of 0.2 ft. A hypothetical 10-year-drought scenario was used to simulate the effects of a prolonged period of reduced recharge on groundwater storage in the Washita River alluvial aquifer and Foss Reservoir stage and storage. To simulate the hypothetical drought, recharge in the calibrated model was reduced by 50 percent during the simulated drought period (1983–1992). Groundwater storage at the end of the drought period in December 1992 was 562,000 acre-ft, or 36,000 acre-ft (6 percent) less than the groundwater storage of the calibrated groundwater model (598,000 acre-ft). At the end of the hypothetical drought, the largest changes in saturated thickness (as great as 43.5 ft) were in the area upgradient from Foss Reservoir, particularly in the terrace at the model boundary. Substantial decreases in the Foss Reservoir stage began during the fall of 1985 in conjunction with base-flow decreases of up to 100 percent at U.S. Geological Survey streamgage 07324200 Washita River near Hammon, Okla. These lake-stage declines outpaced groundwater-level declines in the surrounding aquifer. The minimum Foss Reservoir storage simulated during the drought period was 77,954 acre-ft, which was a decrease of 46 percent from the nondrought storage.

Oklahoma↗

Groundwater quality in the Western San Joaquin Valley study unit, 2010: California GAMA Priority Basin Project

Water quality in groundwater resources used for public drinking-water supply in the Western San Joaquin Valley (WSJV) was investigated by the USGS in cooperation with the California State Water Resources Control Board (SWRCB) as part of its Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The WSJV includes two study areas: the Delta–Mendota and Westside subbasins of the San Joaquin Valley groundwater basin. Study objectives for the WSJV study unit included two assessment types: (1) a status assessment yielding quantitative estimates of the current (2010) status of groundwater quality in the groundwater resources used for public drinking water, and (2) an evaluation of natural and anthropogenic factors that could be affecting the groundwater quality. The assessments characterized the quality of untreated groundwater, not the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on data collected from 43 wells sampled by the U.S. Geological Survey for the GAMA Priority Basin Project (USGS-GAMA) in 2010 and data compiled in the SWRCB Division of Drinking Water (SWRCB-DDW) database for 74 additional public-supply wells sampled for regulatory compliance purposes between 2007 and 2010. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and SWRCB-DDW regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a spatially weighted, grid-based method to estimate the proportion of the groundwater resources used for public drinking water that has concentrations for particular constituents or class of constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale within the WSJV study unit, and permits comparison of the two study areas to other areas assessed by the GAMA Priority Basin Project statewide. Groundwater resources used for public drinking water in the WSJV study unit are among the most saline and most affected by high concentrations of inorganic constituents of all groundwater resources used for public drinking water that have been assessed by the GAMA Priority Basin Project statewide. Among the 82 GAMA Priority Basin Project study areas statewide, the Delta–Mendota study area ranked above the 90th percentile for aquifer-scale proportions of groundwater resources having concentrations of total dissolved solids (TDS), sulfate, chloride, manganese, boron, chromium(VI), selenium, and strontium above benchmarks, and the Westside study area ranked above the 90th percentile for TDS, sulfate, manganese, and boron. In the WSJV study unit as a whole, one or more inorganic constituents with regulatory or non-regulatory, health-based benchmarks were present at concentrations above benchmarks in about 53 percent of the groundwater resources used for public drinking water, and one or more organic constituents with regulatory health-based benchmarks were detected at concentrations above benchmarks in about 3 percent of the resource. Individual constituents present at concentrations greater than health-based benchmarks in greater than 2 percent of groundwater resources used for public drinking water included: boron (51 percent, SWRCB-DDW notification level), chromium(VI) (25 percent, SWRCB-DDW maximum contaminant level (MCL)), arsenic (10 percent, EPA MCL), strontium (5.1 percent, EPA Lifetime health advisory level (HAL)), nitrate (3.9 percent, EPA MCL), molybdenum (3.8 percent, EPA HAL), selenium (2.6 percent, EPA MCL), and benzene (2.6 percent, SWRCB-DDW MCL). In addition, 50 percent of the resource had TDS concentrations greater than non-regulatory, aesthetic-based SWRCB-DDW upper secondary maximum contaminant level (SMCL), and 44 percent had manganese concentrations greater than the SWRCB-DDW SMCL. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors, inferences from geochemical and age-dating tracer results, and by considering the water-quality results in the context of the hydrogeologic setting of the WSJV study unit. Natural factors, particularly the lithologies of the source areas for groundwater recharge and of the aquifers, were the dominant factors affecting groundwater quality in most of the WSJV study unit. However, where groundwater resources used for public supply included groundwater recharged in the modern era, mobilization of constituents by recharge of water used for irrigation also affected groundwater quality. Public-supply wells in the Westside study area had a median depth of 305 m and primarily tapped groundwater recharged hundreds to thousands of years ago, whereas public-supply wells in the Delta–Mendota study area had a median depth of 85 m and primarily tapped either groundwater recharged within the last 60 years or groundwater consisting of mixtures of this modern recharge and older recharge. Public-supply wells in the WSJV study unit are screened in the Tulare Formation and zones above and below the Corcoran Clay Member are used. The Tulare Formation primarily consists of alluvial sediments derived from the Coast Ranges to the west, except along the valley trough at the eastern margin of the WSJV study unit where the Tulare Formation consists of fluvial sands derived from the Sierra Nevada to the east. Groundwater from wells screened in the Sierra Nevada sands had manganese-reducing or manganese- and iron-reducing oxidation-reduction (redox) conditions. These redox conditions commonly were associated with elevated arsenic or molybdenum concentrations, and the dominance of arsenic(III) in the dissolved arsenic supports reductive dissolution of iron and manganese oxyhydroxides as the mechanism. In addition, groundwater from many wells screened in Sierra Nevada sands contained low concentrations of nitrite or ammonium, indicating reduction of nitrate by denitrification or dissimilatory processes, respectively. Geology of the Coast Ranges westward of the study unit strongly affects groundwater quality in the WSJV. Elevated concentrations of TDS, sulfate, boron, selenium and strontium in groundwater were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by Cretaceous-to-Miocene age, organic-rich, reduced marine shales, known as the source of selenium in WSJV soils, surface water, and groundwater. Low sulfur-isotopic values (δ34S) of dissolved sulfate indicate that the sulfate was largely derived from oxidation of biogenic pyrite from the shales, and correlations with trace element concentrations, geologic setting, and groundwater geochemical modeling indicated that distributions of sulfate, strontium, and selenium in groundwater were controlled by dissolution of secondary sulfate minerals in soils and sediments. Elevated concentrations of chromium(VI) were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by the Franciscan Complex and ultramafic rocks. The Franciscan Complex also has boron-rich, sodium-chloride dominated hydrothermal fluids that contribute to elevated concentrations of boron and TDS. Groundwater from wells screened in Coast Ranges alluvium was primarily oxic and relatively alkaline (median pH value of 7.55) in the Delta–Mendota study area, and primarily nitrate-reducing or suboxic and alkaline (median pH value of 8.4) in the Westside study area. Many groundwater samples from those wells have elevated concentrations of arsenic(V), molybdenum, selenium, or chromium(VI), consistent with desorption of metal oxyanions from mineral surfaces under those geochemical conditions. High concentrations of benzene were associated with deep wells located in the vicinity of petroleum deposits at the southern end of the Westside study area. Groundwater from these wells had premodern age and anoxic geochemical conditions, and the ratios among concentrations of hydrocarbon constituents were different from ratios found in fuels and combustion products, which is consistent with a geogenic source for the benzene rather than contamination from anthropogenic sources. Water stable-isotope compositions, groundwater recharge temperatures, and groundwater ages were used to infer four types of groundwater: (1) groundwater derived from natural recharge of water from major rivers draining the Sierra Nevada; (2) groundwater primarily derived from natural recharge of water from Coast Ranges runoff; (3) groundwater derived from recharge of pumped groundwater applied to the land surface for irrigation; and (4) groundwater derived from recharge during a period of much cooler paleoclimate. Water previously used for irrigation was found both above and below the Corcoran Clay, supporting earlier inferences that this clay member is no longer a robust confining unit. Recharge of water used for irrigation has direct and indirect effects on groundwater quality. Elevated nitrate concentrations and detections of herbicides and fumigants in the Delta–Mendota study area generally were associated with greater agricultural land use near the well and with water recharged during the last 60 years. However, the extent of the groundwater resource affected by agricultural sources of nitrate was limited by groundwater redox conditions sufficient to reduce nitrate. The detection frequency of perchlorate in Delta–Mendota groundwater was greater than expected for natural conditions. Perchlorate, nitrate, selenium, and strontium concentrations were correlated with one another and were greater in groundwater inferred to be recharge of previously pumped groundwater used for irrigation. The source of the perchlorate, selenium, and strontium appears to be salts deposited in the soils and sediments of the arid WSJV that are dissolved and flushed into groundwater by the increased amount of recharge caused by irrigation. In the Delta–Mendota study area, the groundwater with elevated concentrations of selenium was found deeper in the aquifer system than it was reported by a previous study 25 years earlier, suggesting that this transient front of groundwater with elevated concentrations of constituents derived from dissolution of soil salts by irrigation recharge is moving down through the aquifer system and is now reaching the depth zone used for public drinking water supply.

California↗

Evaluation of groundwater-flow models for estimating drawdown from proposed groundwater development in Tule Desert, Nevada

At the request of the Bureau of Land Management (BLM), the U.S. Geological Survey (USGS) is releasing with this open-file report (OFR) a previously unpublished review and comparison of two numerical models for Tule Desert, Nevada. The original review was performed in spring 2013, and only minor editorial revisions were made in the current (2019) OFR for clarity and to reformat the original interagency correspondence to the USGS OFR template. No revisions have been made to the technical content of the original review for this OFR release. Report content presented in the purpose and scope statement, and all subsequent sections of the OFR, are original content submitted to BLM in May 2013. Model review and comparisons described in the following paragraphs are based on, in part, results of a long-term (more than 2 years) aquifer test mandated by Nevada State Engineer Order 1169. Additional information on Order 1169 and associated aquifer test results can be found at the State of Nevada Division of Water Resources website (State of Nevada, 2019).

Nevada↗