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USGS2022

Multi-factor biotopes as a method for detailed site characterization in diverse benthic megafaunal communities and habitats in deep-water off Morro Bay, California

Here we describe the methods and results for biological characterization of the benthos on a previously unexplored area of central California, USA seafloor. We conducted 40 remotely operated vehicle dives from 371 to 1173 m water depth. Seafloor habitats and megafauna (fish and invertebrates) were documented from 46.8 km of seafloor video footage. Our expanded development and analysis of biotopes from quantitative data allowed us to describe detailed biological communities, along with the physical characteristics and habitat associations within the study area. This method provides a framework for potential monitoring, detection of future environmental change (natural and anthropogenic) and comprehensive comparison to other deep water regions. From 185 h of observational video at 25 sites, nearly 120,000 annotations of organisms, habitat characters, biological detritus and anthropogenic debris were recorded and analyzed. We identified a total of 228 taxa, with 173 of them present on linear quantitative transects. Species richness for transects ranged from 0.04 to 0.28 m-2 (8–55 taxa), with densities ranging from 0.07 to 5.20 ind. m−2. Both were highest on hard substrate with greatest surface area. Densities decreased with depth. Within soft substratum zones was a large field of pockmarks, which are seafloor depressions averaging 175 m in diameter and 5 m in depth. Pockmarks have sometimes been associated with seafloor gas seepage, but here we found no biological evidence of chemosynthetic organisms. No significant differences were found in either density nor species richness at pockmark sites vs. non-pockmark sites. Mud draped greenish-black coarse sand occurred only in low oxygen areas, while hummocky, rugose mud supported somewhat different species than flat mud plains. Seventy percent of the transects occurred inside the oxygen minimum zone. We conclude that high rugosity, slope, and the presence of hard substratum were better predictors of species richness and density than oxygen concentration in this specific study. Abundant biological detritus, in the form of dead and dying pelagic pyrosomes and salps, created a large, presumably ephemeral flux of carbon to the seafloor during the study period.

California↗

USGS2013

Monitoring to assess progress toward meeting the total maximum daily load for phosphorus in the Assabet River, Massachusetts: phosphorus loads, 2008 through 2010

Wastewater discharges to the Assabet River contribute substantial amounts of phosphorus, which support accumulations of nuisance aquatic plants that are most evident in the river’s impounded reaches during the growing season. To restore the Assabet River’s water quality and aesthetics, the U.S. Environmental Protection Agency required the major wastewater-treatment plants in the drainage basin to reduce the amount of phosphorus discharged to the river by 2012. From October 2008 to December 2010, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection and in support of the requirements of the Total Maximum Daily Load for Phosphorus, collected weekly flow-proportional, composite samples for analysis of concentrations of total phosphorus and orthophosphorus upstream and downstream from each of the Assabet River’s two largest impoundments: Hudson and Ben Smith. The purpose of this monitoring effort was to evaluate conditions in the river before enhanced treatment-plant technologies had effected reductions in phosphorus loads, thereby defining baseline conditions for comparison with conditions following the mandated load reductions. The locations of sampling sites with respect to the impoundments enabled examination of the impoundments’ effects on phosphorus sequestration and on the transformation of phosphorus between particulate and dissolved forms. The study evaluated the differences between loads upstream and downstream from the impoundments throughout the sampling period and compared differences during two seasonal periods of relevance to aquatic plants: April 1 through October 31, the growing season, and November 1 through March 31, the nongrowing season, when existing permit limits allowed average monthly wastewater-treatment-plant-effluent concentrations of 0.75 milligram per liter (growing season) or 1.0 milligram per liter (nongrowing season) for total phosphorus. At the four sampling sites during the growing season, median weekly total phosphorus loads ranged from 110 to 190 kilograms (kg) and median weekly orthophosphorus loads ranged from 17 to 41 kg. During the nongrowing season, median weekly total phosphorus loads ranged from 240 to 280 kg and median weekly orthophosphorus loads ranged from 56 to 66 kg. During periods of low and moderate streamflow, estimated loads of total phosphorus upstream from the Hudson impoundment generally exceeded those downstream during the same sampling periods throughout the study; orthophosphorus loads downstream from the impoundment were typically larger than those upstream. When storm runoff substantially increased the streamflow, loads of total phosphorus and orthophosphorus both tended to be larger downstream than upstream. At the Ben Smith impoundment, both total phosphorus and orthophosphorus loads were generally larger downstream than upstream during low and moderate streamflow, but the differences were not as pronounced as they were at the Hudson impoundment. High flows were also associated with substantially larger total phosphorus and orthophosphorus loads downstream than those entering the impoundment from upstream. In comparing periods of growing- and nongrowing-season loads, the same patterns of loads entering and leaving were observed at both impoundments. That is, at the Hudson impoundment, total phosphorus loads entering the impoundment were greater than those leaving it, and orthophosphorus loads leaving the impoundment were greater than those entering it. At the Ben Smith impoundment, both total phosphorus and orthophosphorus loads leaving the impoundment were greater than those entering it. However, the loads were greater during the nongrowing seasons than during the growing seasons, and the net differences between upstream and downstream loads were about the same. The results indicate that some of the particulate fraction of the total phosphorus loads is sequestered in the Hudson impoundment, where particulate phosphorus probably undergoes some physical and biogeochemical transformations to the dissolved form orthophosphorus. The orthophosphorus may be taken up by aquatic plants or transported out of the impoundments. The results for the Ben Smith impoundment are less clear and suggest net export of total phosphorus and orthophosphorus. Differences between results from the two impoundments may be attributable in part to differences in their sizes, morphology, unmonitored tributaries, riparian land use, and processes within the impoundments that have not been quantified for this study.

Massachusetts↗

USGS2017

Development of a robust analytical framework for assessing landbird trends, dynamics and relationships with environmental covariates in the North Coast and Cascades Network

During 2015-2016, we completed development of a new analytical framework for landbird population monitoring data from the National Park Service (NPS) North Coast and Cascades Inventory and Monitoring Network (NCCN). This new tool for analysis combines several recent advances in modeling population status and trends using point-count data and is designed to supersede the approach previously slated for analysis of trends in the NCCN and other networks, including the Sierra Nevada Network (SIEN). Advances supported by the new model-based approach include 1) the use of combined data on distance and time of detection to estimate detection probability without assuming perfect detection at zero distance, 2) seamless accommodation of variation in sampling effort and missing data, and 3) straightforward estimation of the effects of downscaled climate and other local habitat characteristics on spatial and temporal trends in landbird populations. No changes in the current field protocol are necessary to facilitate the new analyses. We applied several versions of the new model to data from each of 39 species recorded in the three mountain parks of the NCCN, estimating trends and climate relationships for each species during 2005-2014. Our methods and results are also reported in a manuscript in revision for the journal Ecosphere (hereafter, Ray et al.). Here, we summarize the methods and results outlined in depth by Ray et al., discuss benefits of the new analytical framework, and provide recommendations for its application to synthetic analyses of long-term data from the NCCN and SIEN. All code necessary for implementing the new analyses is provided within the Appendices to this report, in the form of fully annotated scripts written in the open-access programming languages R and JAGS.

Natural Resource Report↗

USGS2025

Spatially resolved source apportionment of per- and polyfluoroalkyl substances (PFAS) within a post-industrial river catchment

Source apportionment of per- and polyfluoroalkyl substances (PFAS) in rivers is typically based on water concentrations, which cannot quantify PFAS loads or define geographical source areas. This study applied a river catchment-scale approach to identify PFAS source zones and assess the relative importance of industrial PFAS sources in the River Mersey, UK – a post-industrial, densely populated catchment with diverse PFAS sources. Synoptic sampling and PFAS river load analysis identified key sub-catchments and river stretches contributing the majority of PFAS. Notably, the highest PFAS concentrations did not always correspond to the greatest loads. Most PFOS (64 %), PFOA (49 %), 6:2FTS (46 %) and PFHxS (56 %) were exported from the Upper Mersey sub-catchment, despite higher concentrations in northern sub-catchments, emphasising the importance of load-based monitoring. Mass balance analysis of loads highlighted substantial inputs from specific river stretches, notably the Lower Irwell (Bolton to Manchester City Centre), River Tame (Marple Bridge to Stockport), and Upper Mersey (Stockport to Urmston). While PFAS loads generally scaled with catchment area, yield (load per unit area) analysis identified disproportionately high exports from small headwater catchments, notably the upper River Roch (PFOA, PFHpA and PFHxA) and Glaze Brook (PFBS). Industrial sources in these sub-catchments (a waste management facility and landfills, respectively) were confirmed using gadolinium anomaly analysis and consented discharge records. More widely, gadolinium data suggested industrial discharges may contribute to PFAS occurrence at 62 % of our sample sites throughout the catchment. These findings demonstrate that spatial analysis of PFAS loads, rather than concentrations alone, is critical for identifying PFAS source areas. We present a scalable monitoring framework for PFAS source apportionment applied at the river catchment-scale that can be used by environmental managers to target and prioritise PFAS source areas for detailed monitoring and remediation.

River Mersey↗

USGS1993

Flow recommendations for maintaining riparian vegetation along the Upper Missouri River, Montana

Montana Power Company, Inc. (MPC) submitted a final license application to the Federal Energy Regulatory Commission (FERC) on November 30, 1992. In this application, MPC proposed a plan for the protection of fish, wildlife, habitat, and water-quality resources. One concern was maintenance of woody riparian vegetation along the Missouri River, especially along the Wild and Scenic reach of the river, where the riparian forest occurs in relatively small discontinuous stands. The objectives of this project were 1) to recommend flows that would protect and enhance riparian forests along the Missouri River, and 2) to develop elements of an environmental monitoring program that could be used to assess the effectiveness of the recommended flows. Plains cottonwood ( Populus deltoides subsp. monilifera ) is the key structural component of riparian forests along the Missouri River. Therefore, we focused our analysis on factors affecting populations of this species. Previous work had demonstrated that the age structure of cottonwood populations is strongly influenced by aspects of flow that promote successfully establishment. In this study our approach was to determine the precise age of plains cottonwood trees growing along the Upper Missouri River and to relate years of establishment to the flow record. Our work was carried out between Coal Banks Landing and the Fred G. Robinson Bridge within the Wild and Scenic portion of the Missouri River. This segment of the river occupies a narrow valley and exhibits little channel migration. Maps and notes from the journals of Lewis and Clark (1804-1806) suggest that the present distribution and abundance of cottonwoods within the study reach is generally similar to presettlement conditions. Flows in the study reach are influenced by a number of dams and diversions, most importantly, Canyon Ferry and Tiber Dams. Although flow regulation has decreased peak flows and increased low flows, the gross seasonal pattern of flow has not been greatly altered. Most cottonwood establishment in our study reach occurred in years with a peak mean daily flow greater than 1,400 m 3 /s (49,434 cfs), or in the two years following such a flow. These years include 35 out of the 111 years of record, and account for establishment of 47 of 60 trees examined, a highly significant relationship. Infrequent establishment of cottonwood trees is not the result of scarcity of seed or seedlings. In the study reach seedlings become established most years on bare, relatively low surfaces deposited by the river. However, the high elevation of establishment of all trees dating to before 1978 indicates that only individuals established on high flood deposits are able to survive subsequent floods and ice jams. In order to maintain the present abundance of plains cottonwood in the study area we recommend flood flows in excess of 1,400 m 3 /s (49,434 cfs) measures as mean daily discharge at Fort Benton (U.S. Geological Survey gage 06090800) with a recurrence interval of approximately 9 years. Because cottonwood seeds remain viable for only a few weeks, and because seedling require a moist, bare surface, we further recommend maintenance of the historic timing of flooding with peak flood flows occurring between mid-May and late-June. Flow is not the only factor influencing cottonwood regeneration along this reach of the Missouri River. Land management, especially cattle grazing, is clearly having an impact, and changes in cottonwood populations could be expected if these practices were altered. However, the dependence of cottonwood establishment on high flow is clear in this reach in spite of the effects of other factors. Given the value of the resource, we strongly suggest establishment of a monitoring program to determine the effectiveness of the recommended flows and to provide the data necessary for refining them. We recommend a monitoring program that would include: 1) ten permanent, widely space channel cross sections for annual measurement of channel geometry and cottonwood establishment, growth, and survival; 2) five livestock enclosures to monitor the influence of grazing in the study area; and 3) low-elevation aerial photography of the reach every five years and after every flood to detect changes in channel geometry and forested area. Because cottonwood establishment is episodic, a long-term commitment to the monitoring effort is essential. In addition, cross sections and exclosures should be easy enough to access that measurements during flood years are possible.

Montana↗

USGS1999

Analysis of geophysical logs, at North Penn Area 6 Superfund Site, Lansdale, Montgomery County, Pennsylvania

The U.S. Geological Survey (USGS), as part of technical assistance to the U.S. Environmental Protection Agency (USEPA), collected borehole geophysical log data in 34 industrial, commercial, and public supply wells and 28 monitor wells at the North Penn Area 6 Superfund Site, in Lansdale, Pa., from August 22, 1995, through August 29, 1997. The wells range in depth from 50 to 1,027 feet below land surface and are drilled in Triassic-age shales and siltstones of the Brunswick Group and Lockatong Formation. The geophysical log data were collected to help describe the hydrogeologic framework in the area and to provide guidance in the reconstruction of the 28 monitor wells drilled during summer 1997. At the time of logging, all wells had open-hole construction. The geophysical logs, caliper, fluid-resistivity, and fluid-temperature, and borehole video logs were used to determine the vertical distribution of water-bearing fractures. Heatpulse-flowmeter measurements were used to determine vertical borehole flow under pumping and nonpumping conditions. The most productive fractures generally could be determined from heatpulse-flowmeter measurements under pumping conditions. Vertical borehole flow was measured under nonpumping conditions in most wells that had more than one water-bearing fracture. Upward flow was measured in 35 wells and probably is a result of natural head differences between fractures in the local ground-water-flow system. Downward flow was measured in 11 wells and commonly indicated differences in hydraulic heads of the fractures caused by nearby pumping. Both upward and downward flow was measured in three wells. No flow was detected in eight wells. Natural-gamma-ray logs were used to estimate the attitude of bedding. Thin shale marker beds, shown as spikes of elevated radioactivity in the natural-gamma logs of some wells throughout the area, enable the determination of bedding-plane orientation from three-point correlations. Generally, the marker beds in and near Lansdale strike about N. 48°-60° E. and dip about 11° NW. Acoustic televiewer logs run in selected boreholes indicate that the attitude of many water-bearing fractures commonly is similar to that of bedding.

Pennsylvania↗

USGS1996

A comparison of selenium and mercury concentrations in transplanted and resident bivalves from North San Francisco Bay

Many of the methodologies for effective use of organisms to monitor and study contamination in estuaries are well established (Phillips, 1980; Phillips and Rainbow, 1993). Understanding the processes that determine bioaccumulation and determining concentrations of contaminants in biological tissues are best employed in conjunction with analysis of other environmental media (e.g., water, suspended particulate material, or sediment). Together these provide complementary lines of field evidence indicative of complexities that affect the exposures of organisms to contaminants.

Report↗

USGS2010

Guidelines for the use of the semipermeable membrane device (SPMD) and the polar organic chemical integrative sampler (POCIS) in environmental monitoring studies

The success of an environmental monitoring study using passive samplers, or any sampling method, begins in the office or laboratory. Regardless of the specific methods used, the general steps include the formulation of a sampling plan, training of personnel, performing the field (sampling) work, processing the collected samples to recover chemicals of interest, analysis of the enriched extracts, and interpretation of the data. Each of these areas will be discussed in the following sections with emphasis on specific considerations with the use of passive samplers. Water is an extremely heterogeneous matrix both spatially and temporally (Keith, 1991). The mixing and distribution of dissolved organic chemicals in a water body are controlled by the hydrodynamics of the water, the sorption partition coefficients of the chemicals, and the amount of organic matter (suspended sediments, colloids, and dissolved organic carbon) present. In lakes and oceans, stratification because of changes in temperature, water movement, and water composition can occur resulting in dramatic changes in chemical concentrations with depth (Keith, 1991). Additional complications related to episodic events, such as surface runoff, spills, and other point source contamination, can result in isolated or short-lived pulses of contaminants in the water. The application of passive sampling technologies for the monitoring of legacy and emerging organic chemicals in the environment is becoming widely accepted worldwide. The primary use of passive sampling methods for environmental studies is in the area of surface-water monitoring; however, these techniques have been applied to air and groundwater monitoring studies. Although these samplers have no mechanical or moving parts, electrical or fuel needs which require regular monitoring, there are still considerations that need to be understood in order to have a successful study. Two of the most commonly used passive samplers for organic contaminants are the semipermeable membrane device (SPMD) and the polar organic chemical integrative sampler (POCIS). The tips given in this document focus on these two samplers but are applicable to most types of passive sampling devices. The information in this guide is heavily weighted towards the sampling of water; however, information specific to the use of SPMDs for air sampling will also be covered.

Techniques and Methods↗

USGS2026

As above, so below? A framework for integrating long-term water quantity trends reveals divergent patterns in groundwater and low streamflow across the United States

Climate, land-use, and disturbance drive long-term global trends in groundwater levels and streamflow. At large scales, these trends are typically considered separately, despite the well-established concept that groundwater and surface water comprise a single resource. Joint trend assessment at national scales is challenging because it requires pairing and aggregating data from spatially disparate streamflow and groundwater monitoring sites for which no established framework exists. Here, we evaluate alternative approaches for integrating groundwater and streamflow data to enable joint trend analysis—a critical step toward understanding how water-budget components respond concurrently and interactively to environmental drivers. Mann–Kendall trends were computed for individual groundwater (annual mean depth) and streamflow (annual low of 7 d averages) sites across the U.S over 21- (2000–2020), 31- (1990–2020), and 41-year (1980–2020) periods. Regional Kendall trends were calculated using five spatially contiguous and noncontiguous regional classifications for aggregation based on subsurface (e.g. aquifer, geology) and surface (e.g. watershed, landscape) characteristics. Site-level results revealed contrasting trends, with tendencies toward increasing low flows (wetting) and increasing groundwater depths (drying). Agreement between streamflow and groundwater trends increased with regional aggregation and longer timeframes, though persistent skew toward streamflow wetting and groundwater drying remained. Results varied by region and trend period, with notable consistencies: unified drying in the West/Southwest and wetting in the Upper Midwest. Directional mismatches in long-term trends were prominent in the High Plains and Mississippi Alluvial Plain, whereas near-term mismatches were most evident in the Northwest. Aggregation by hydrologic landscape regions (HLR) yielded the greatest agreement between groundwater and streamflow trends. These findings indicate that coupled responses may represent combined influences of climate, relief, and geology, as captured by HLR, more strongly than geography or geology alone. Integrated water availability assessments may benefit from a multi-characteristic classification framework to treat groundwater and surface water as a unified resource.

Environmental Research: Water↗

USGS1997

A study of the temporal variability of atrazine in private well water. Part I: Study design, implementation, and database development

In 1988, the Iowa Department of Natural Resources, along with the University of Iowa conducted the Statewide Rural Well Water Survey, commonly known as SWRL. A total of 686 private rural drinking water wells was selected by use of a probability sample and tested for pesticides and nitrates. Sixty-eight of these wells, the '10% repeat' wells, were additionally sampled in October, 1990 and June, 1991. Starting in November, 1991, the University of Iowa, with sponsorship from the United States Environmental Protection Agency, revisited these wells to begin a study of the temporal variability of atrazine and nitrates in wells. Other wells, which had originally tested positive for atrazine in SWRL but were not in the 10% repeat population, were added to the study population. Temporal sampling for a year-long period began in February of 1992 and concluded in January of 1993. All wells were sampled monthly, one subset was sampled weekly, and a second subset was sampled for 14-day consecutive periods. Two unique aspects of this study were the use of an immunoassay technique to screen for triazines before gas chromatography/mass spectrometry (GC/MS) analysis and quantification of atrazine, and the use of well owners to sample the wells. A total of 1771 samples from 83 wells are in the final data base for this study. This paper reviews the study design, the analytical methodologies, and development of the data base. A companion paper discusses the analysis of the data from this survey.

Environmental Monitoring and Assessment↗

USGS2000

Assessing the Kansas water-level monitoring program: An example of the application of classical statistics to a geological problem

Geologists may feel that geological data are not amenable to statistical analysis, or at best require specialized approaches such as nonparametric statistics and geostatistics. However, there are many circumstances, particularly in systematic studies conducted for environmental or regulatory purposes, where traditional parametric statistical procedures can be beneficial. An example is the application of analysis of variance to data collected in an annual program of measuring groundwater levels in Kansas. Influences such as well conditions, operator effects, and use of the water can be assessed and wells that yield less reliable measurements can be identified. Such statistical studies have resulted in yearly improvements in the quality and reliability of the collected hydrologic data. Similar benefits may be achieved in other geological studies by the appropriate use of classical statistical tools.

The Compass: Earth Science Journal of Sigma Gamma ↗

USGS2017

An “EAR” on environmental surveillance and monitoring: A case study on the use of Exposure–Activity Ratios (EARs) to prioritize sites, chemicals, and bioactivities of concern in Great Lakes waters

Current environmental monitoring approaches focus primarily on chemical occurrence. However, based on concentration alone, it can be difficult to identify which compounds may be of toxicological concern and should be prioritized for further monitoring, in-depth testing, or management. This can be problematic because toxicological characterization is lacking for many emerging contaminants. New sources of high-throughput screening (HTS) data, such as the ToxCast database, which contains information for over 9000 compounds screened through up to 1100 bioassays, are now available. Integrated analysis of chemical occurrence data with HTS data offers new opportunities to prioritize chemicals, sites, or biological effects for further investigation based on concentrations detected in the environment linked to relative potencies in pathway-based bioassays. As a case study, chemical occurrence data from a 2012 study in the Great Lakes Basin along with the ToxCast effects database were used to calculate exposure–activity ratios (EARs) as a prioritization tool. Technical considerations of data processing and use of the ToxCast database are presented and discussed. EAR prioritization identified multiple sites, biological pathways, and chemicals that warrant further investigation. Prioritized bioactivities from the EAR analysis were linked to discrete adverse outcome pathways to identify potential adverse outcomes and biomarkers for use in subsequent monitoring efforts.

Great Lakes↗

USGS2017

A field study of selected U.S. Geological Survey analytical methods for measuring pesticides in filtered stream water, June - September 2012

U.S. Geological Survey monitoring programs extensively used two analytical methods, gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry, to measure pesticides in filtered water samples during 1992–2012. In October 2012, the monitoring programs began using direct aqueous-injection liquid chromatography tandem mass spectrometry as a new analytical method for pesticides. The change in analytical methods, however, has the potential to inadvertently introduce bias in analysis of datasets that span the change. A field study was designed to document performance of the new method in a variety of stream-water matrices and to quantify any potential changes in measurement bias or variability that could be attributed to changes in analytical methods. The goals of the field study were to (1) summarize performance (bias and variability of pesticide recovery) of the new method in a variety of stream-water matrices; (2) compare performance of the new method in laboratory blank water (laboratory reagent spikes) to that in a variety of stream-water matrices; (3) compare performance (analytical recovery) of the new method to that of the old methods in a variety of stream-water matrices; (4) compare pesticide detections and concentrations measured by the new method to those of the old methods in a variety of stream-water matrices; (5) compare contamination measured by field blank water samples in old and new methods; (6) summarize the variability of pesticide detections and concentrations measured by the new method in field duplicate water samples; and (7) identify matrix characteristics of environmental water samples that adversely influence the performance of the new method. Stream-water samples and a variety of field quality-control samples were collected at 48 sites in the U.S. Geological Survey monitoring networks during June–September 2012. Stream sites were located across the United States and included sites in agricultural and urban land-use settings, as well as sites on major rivers. The results of the field study identified several challenges for the analysis and interpretation of data analyzed by both old and new methods, particularly when data span the change in methods and are combined for analysis of temporal trends in water quality. The main challenges identified are large (greater than 30 percent), statistically significant differences in analytical recovery, detection capability, and (or) measured concentrations for selected pesticides. These challenges are documented and discussed, but specific guidance or statistical methods to resolve these differences in methods are beyond the scope of the report. The results of the field study indicate that the implications of the change in analytical methods must be assessed individually for each pesticide and method. Understanding the possible causes of the systematic differences in concentrations between methods that remain after recovery adjustment might be necessary to determine how to account for the differences in data analysis. Because recoveries for each method are independently determined from separate reference standards and spiking solutions, the differences might be due to an error in one of the reference standards or solutions or some other basic aspect of standard procedure in the analytical process. Further investigation of the possible causes is needed, which will lead to specific decisions on how to compensate for these differences in concentrations in data analysis. In the event that further investigations do not provide insight into the causes of systematic differences in concentrations between methods, the authors recommend continuing to collect and analyze paired environmental water samples by both old and new methods. This effort should be targeted to seasons, sites, and expected concentrations to supplement those concentrations already assessed and to compare the ongoing analytical recovery of old and new methods to those observed in the summer and fall of 2012.

Scientific Investigations Report↗

USGS2007

Trends in summer chemistry linked to productivity in lakes recovering from acid deposition in the Adirondack region of New York

The US Environmental Protection Agency established the Adirondack Effects Assessment Program (AEAP) to evaluate and monitor the status of biological communities in lakes in the Adirondack region of New York that have been adversely affected by acid deposition. This program includes chemical analysis of 30 lakes, sampled two to three times each summer. Results of trends analysis for lake chemistry and chlorophyll a (chlor a) are presented for 1994 to 2003, and a general comparison is made with recent results of the Adirondack Long-Term Monitoring (ALTM) Program, which included chemical analysis of all but two of these lakes (plus an additional 24 lakes) monthly, year-round for 1992-2004. Increases in pH were found in 25 of the 30 AEAP lakes (P < 0.05) and increases in acid-neutralizing capacity (ANC) were found in 12 of the 30 lakes (P < 0.05). Concentrations of both SO 42- and Mg 2+ decreased in 11 lakes (P < 0.05), whereas concentrations of NO 3- decreased in 20 lakes (P < 0.05). Concentrations of NH 4+ decreased in 10 lakes at a significance level of P < 0.05 and in three other lakes based on P < 0.1. Concentrations of inorganic and organic monomeric aluminum generally were below the reporting limit of 1.5 ??mol L-1, but decreases were detected in four and five lakes, respectively (P < 0.1). Concentrations of chlor a increased in seven lakes at a significance level of P < 0.05 and two lakes at a significance level of P < 0.1. A significant inverse correlation was also found between chlor a and NO 3- concentrations in nine lakes at a significance level of P < 0.05 and two lakes at a significance level of P < 0.1. Results of AEAP analysis of lake chemistry were similar to those of the ALTM Program, although decreases in SO 42- concentrations were more evident in the year-round ALTM record. Overall, the results suggest (a) a degree of chemical recovery from acidification during the summer, (b) an increase in phytoplankton productivity, and (c) a decreasing trend in NO 3- concentrations resulting from the increased productivity. ?? 2007 Springer Science+Business Media, Inc.

Ecosystems↗

USGS2011

Histologic, immunologic and endocrine biomarkers indicate contaminant effects in fishes of the Ashtabula River

The use of fish as sentinels of aquatic ecosystem health is a biologically relevant approach to environmental monitoring and assessment. We examined the health of the Ashtabula River using histologic, immunologic, and endocrine biomarkers in brown bullhead (BB; Ameiurus nebulosus) and largemouth bass (Micropterus salmoides) and compared fish collected from a reference site (Conneaut Creek). Seasonal analysis was necessary to distinguish differences in fish between the two rivers. Overall BB from the Ashtabula River had a lower condition factor and significantly more macrophage aggregates than those from the reference site. Reduced bactericidal and cytotoxic-cell activity was observed in anterior kidney leukocytes from both BB and largemouth bass from the Ashtabula River. Lower plasma thyroxine and triiodo-L-thyronine in both species in the Ashtabula River indicated disruption of the thyroid axis. Differences in physiological biomarker responses were supported by body burden chemical concentrations when data were analyzed on a seasonal basis. The use of two fish species added a level of rigor that demonstrated biological effects were not exclusive to a single species. The results provide strong evidence that contaminants have affected fish in the Ashtabula River, a Great Lakes Area of Concern, and provide a baseline by which to evaluate remediation activities.

Ohio↗

USGS1986

Preliminary appraisal of ground water in and near the ancestral Missouri River Valley, northeastern Montana

A preliminary appraisal was conducted in and near the ancestral Missouri River valley in northeastern Montana to describe the groundwater resources and to establish a data base for the area. The data base then could be used for future evaluation of possible changes in water levels or water quality. In this area, consolidated aquifers are the Upper Cretaceous Fox Hills-lower Hell Creek aquifer and the overlying Paleocene Fort Union Formation. Unconsolidated aquifers are Pleistocene terrace gravel and glacial deposits and Holocene alluvial deposits. Aquifers are recharged by precipitation, infiltration of streamflow, and possibly leakage from lakes and potholes. Groundwater moves from topographically higher areas to the ancestral valley, then along the ancestral valley to the southwest. Water is discharged from aquifers by evapotranspiration, springs and seeps, movement directly into streams and lakes, and from pumping wells. Average well yields are greatest for irrigation wells completed in outwash gravel (886 gallons/min). Eighteen wells were completed in various aquifers to monitor potential long-term changes in water levels and water quality. Measured water levels declined about 2 ft. or less during the study (1982-85). Chemical analysis of groundwater samples indicated that concentrations of some dissolved constituents exceeded U.S. Environmental Protection Agency standards for drinking water.

Montana↗

USGS2012

Development of a new method for the determination of residues of the neonictinoid insecticide imidacloprid in juvenile Chinook (Oncorhynchus tyshawytscha) using ELISA detection

The neonicotinoid insecticide imidacloprid (IMI) has been proposed as an alternative to carbaryl for controlling indigenous burrowing shrimp on commercial oyster beds in Willapa Bay and Grays Harbor, Washington. A focus of concern over the use of this insecticide in an aquatic environment is the potential for adverse effects from exposure to non-target species residing in the Bay, such as juvenile Chinook (Oncorhynchus tshawytscha) and cutthroat trout (O. clarki). Federal registration and State permiting approval for the use of IMI will require confirmation that the compound does not adversely impact these salmonids following field applications. This will necessitate an environmental monitoring program for evaluating exposure in salmonids following the treatment of beds. Quantification of IMI residues in tissue can be used for determining salmonid exposure to the insecticide. Refinement of an existing protocol using liquid-chromatography mass spectrometry (LC-MS) detection would provide the low limits of quantification, given the relatively small tissue sample sizes, necessary for determining exposure in individual fish. Such an approach would not be viable for the environmental monitoring effort in Willapa Bay and Grays Harbor due to the high costs associated with running multiple analyses, however. A new sample preparation protocol was developed for use with a commercially available enzyme-linked immunosorbent assay (ELISA) for the quantification of IMI, thereby providing a low-cost alternative to LC-MS for environmental monitoring in Willapa Bay and Grays Harbor. Extraction of the analyte from the salmonid brain tissue was achieved by Dounce homogenization in 4.0 mL of 20.0 mM Triton X-100, followed by a 6 h incubation at 50–55 °C. Centrifugal ultrafiltration and reversed phase solid phase extraction were used for sample cleanup. The limit of quantification for an average 77.0 mg whole brain sample was calculated at 18.2 μg kg -1 (ppb) with an average recovery of 79%. This relatively low limit of quantification allows for the analysis of individual fish. Using controlled laboratory studies, a curvelinear relationship was found between the measured IMI residue concentrations in brain tissue and exposure concentrations in seawater. Additonally, a range of IMI brain residue concentrations was associated with an overt effect; illustrating the utility of the IMI tissue residue quantification approach for linking exposure with defined effects.

Journal of Environmental Monitoring↗

USGS2007

Evaluation of the status of anurans on a refuge in suburban Maryland

Because many anurans have well-defined breeding seasons and male anurans produce loud advertisement calls, surveys of these breeding choruses are believed to provide a dependable means of monitoring population trends. The Patuxent Research Refuge initiated such a calling survey in the spring of 1997, which uses volunteers to collect anuran (frog and toad) calling survey data. The primary goal of initiating the calling surveys at the Patuxent Refuge was to obtain baseline information on anuran populations, such as species occurrence, frequency of occurrence, and relative abundance over time. In this paper, we used the calling survey data to develop models for the "proportion of area occupied" by individual anuran species, a method in which analysis is focused on the proportion of sites that are occupied by a species, instead of the number of individuals present in the population. This type of analysis is ideal for use in large-scale monitoring programs focused on species that are difficult to count, such as anurans or birds. We considered models for proportion of area occupied that allow for imperfect detection (that is, a species may be present but go undetected during sampling) by incorporating parameters that describe detection probability and the response of detection probability to various environmental and sampling covariates. Our results indicate that anuran populations on the Patuxent Research Refuge have high rates of occupancy compared to areas nearby and that extinction and colonization rates are stable. The potential uses for "proportion of area occupied" analyses are far-reaching and will allow for more accurate quantification of data and better-informed management decisions for calling surveys on a larger scale.

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