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USGS2010

Thermomagmatic evolution of Mesoproterozoic crust in the Blue Ridge of SW Virginia and NW North Carolina: Evidence from U-Pb geochronology and zircon geothermometry

New geologic mapping, petrology, and U-Pb geochronology indicate that Mesoproterozoic crust near Mount Rogers consists of felsic to mafic meta-igneous rocks emplaced over 260 m.y. The oldest rocks are compositionally diverse and migmatitic, whereas younger granitoids are porphyritic to porphyroclastic. Cathodoluminescence imaging indicates that zircon from four representative units preserves textural evidence of multiple episodes of growth, including domains of igneous, metamorphic, and inherited origin. Sensitive high-resolution ion microprobe (SHRIMP) trace-element analyses indicate that metamorphic zircon is characterized by lower Th/U, higher Yb/Gd, and lower overall rare earth element (REE) concentrations than igneous zircon. SHRIMP U-Pb isotopic analyses of zircon define three episodes of magmatism: 1327 ± 7 Ma, 1180–1155 Ma, and 1061 ± 5 Ma. Crustal recycling is recorded by inherited igneous cores of 1.33–1.29 Ga age in 1161 ± 7 Ma meta-monzogranite. Overlapping ages of igneous and metamorphic crystallization indicate that plutons of ca. 1170 and 1060 Ma age were emplaced during episodes of regional heating. Local development of hornblende + plagioclase + quartz ± clinopyroxene indicates that prograde metamorphism at 1170–1145 Ma and 1060–1020 Ma reached upper-amphibolite-facies conditions, with temperatures estimated using Ti-in-zircon geothermometry at ~740 ± 40 °C during both episodes. The chemical composition of 1327 ± 7 Ma orthogranofels from migmatite preserves the first evidence of arc-generated rocks in the Blue Ridge, indicating a subduction-related environment that may have been comparable to similar-age systems in inliers of the Northern Appalachians and the Composite Arc belt of Canada. Granitic magmatism at 1180–1155 Ma and ca. 1060 Ma near Mount Rogers was contemporaneous with anorthosite-mangerite-charnockite-granite (AMCG) plutonism in the Northern Appalachian inliers and Canadian Grenville Province. Metamorphism at ca. 1160 and 1060 Ma correlates temporally with the Shawinigan orogeny and Ottawan phase of the Grenvillian orogeny, respectively, suggesting that the Blue Ridge was part of Rodinia dating back to ca. 1180 Ma.

North Carolina;Virginia↗

USGS2016

Low-δD hydration rinds in Yellowstone perlites record rapid syneruptive hydration during glacial and interglacial conditions

Hydration of silicic volcanic glass forms perlite, a dusky, porous form of altered glass characterized by abundant “onion-skin” fractures. The timing and temperature of perlite formation are enigmatic and could plausibly occur during eruption, during post-eruptive cooling, or much later at ambient temperatures. To learn more about the origin of natural perlite, and to fingerprint the hydration waters, we investigated perlitic glass from several synglacial and interglacial rhyolitic lavas and tuffs from the Yellowstone volcanic system. Perlitic cores are surrounded by a series of conchoidal cracks that separate 30- to 100-µm-thick slivers, likely formed in response to hydration-induced stress. H 2 O and D/H profiles confirm that most D/H exchange happens together with rapid H 2 O addition but some smoother D/H variations may suggest separate minor exchange by deuterium atom interdiffusion following hydration. The hydrated rinds (2–3 wt% H 2 O) transition rapidly (within 30 µm, or by 1 wt% H 2 O per 10 µm) to unhydrated glass cores. This is consistent with quenched “hydration fronts” where H 2 O diffusion coefficients are strongly dependent on H 2 O concentrations. The chemical, δ 18 O, and δD systematics of bulk glass records last equilibrium between ~110 and 60 °C without chemical exchange but with some δ 18 O exchange. Similarly, the δ 18 O of water extracted from glass by rapid heating suggests that water was added to the glass during cooling at <200 °C. Our observations support fast hydration at temperatures as low as 60 °C; prolonged exposure to high temperature of 175°–225° during water addition is less likely as the glass would lose alkalies and should alter to clays within days. A compilation of low-temperature hydration diffusion coefficients suggests ~2 orders of magnitude higher rates of diffusion at 60–110 °C temperatures, compared with values expected from extrapolation of high-temperature (>400 °C) experimental data. The thick hydration rinds in perlites, measuring hundreds of microns, preserve the original D/H values of hydrating water as a recorder of paleoclimate conditions. Measured δD values in perlitic lavas are −150 to −191 or 20–40 ‰ lower than glass hydrated by modern Yellowstone waters. This suggests that Yellowstone perlites record the low-δD signature of glacial ice. Cooling calculations, combined with the observed high water diffusion coefficients noted for 60–150 °C, suggest that if sufficient hot water or steam is available, any rhyolite flow greater than ~5 m thick can develop the observed ~250-µm hydration rinds within the expected timescale of cooling (weeks–years). As the process of hydration involves shattering of 30- to 100-µm-thick slivers to expose unhydrated rhyolite glass, the time required for hydration may be even shorter. Rapid hydration and formation of relatively thick-walled glass shards allow perlites to provide a snapshot view of the meteoric water (and thus climate) at the time of initial alteration. Perlites retain their initial hydration D/H signal better than thin-walled ash, which in contrast hydrates over many thousands of years with time-averaged precipitation.

Contributions to Mineralogy and Petrology↗

USGS2016

ChemCam activities and discoveries during the nominal mission of the Mars Science Laboratory in Gale crater, Mars

At Gale crater, Mars, ChemCam acquired its first laser-induced breakdown spectroscopy (LIBS) target on Sol 13 of the landed portion of the mission (a Sol is a Mars day). Up to Sol 800, more than 188 000 LIBS spectra were acquired on more than 5800 points distributed over about 650 individual targets. We present a comprehensive review of ChemCam scientific accomplishments during that period, together with a focus on the lessons learned from the first use of LIBS in space. For data processing, we describe new tools that had to be developed to account for the uniqueness of Mars data. With regard to chemistry, we present a summary of the composition range measured on Mars for major-element oxides (SiO 2 , TiO 2 , Al 2 O 3 , FeO T , MgO, CaO, Na 2 O, K 2 O) based on various multivariate models, with associated precisions. ChemCam also observed H, and the non-metallic elements C, O, P, and S, which are usually difficult to quantify with LIBS. F and Cl are observed through their molecular lines. We discuss the most relevant LIBS lines for detection of minor and trace elements (Li, Rb, Sr, Ba, Cr, Mn, Ni, and Zn). These results were obtained thanks to comprehensive ground reference datasets, which are set to mimic the expected mineralogy and chemistry on Mars. With regard to the first use of LIBS in space, we analyze and quantify, often for the first time, each of the advantages of using stand-off LIBS in space: no sample preparation, analysis within its petrological context, dust removal, sub-millimeter scale investigation, multi-point analysis, the ability to carry out statistical surveys and whole-rock analyses, and rapid data acquisition. We conclude with a discussion of ChemCam performance to survey the geochemistry of Mars, and its valuable support of decisions about selecting where and whether to make observations with more time and resource-intensive tools in the rover's instrument suite. In the end, we present a bird's-eye view of the many scientific results: discovery of felsic Noachian crust, first observation of hydrated soil, discovery of manganese-rich coatings and fracture fills indicating strong oxidation potential in Mars' early atmosphere, characterization of soils by grain size, and wide scale mapping of sedimentary strata, conglomerates, and diagenetic materials.

Journal of Analytical Atomic Spectrometry↗

USGS2013

Discerning crystal growth from diffusion profiles in zoned olivine by in situ Mg–Fe isotopic analyses

Mineral zoning is used in diffusion-based geospeedometry to determine magmatic timescales. Progress in this field has been hampered by the challenge to discern mineral zoning produced by diffusion from concentration gradients inherited from crystal growth. A zoned olivine phenocryst from Kilauea Iki lava lake (Hawaii) was selected for this study to evaluate the potential of Mg and Fe isotopes for distinguishing these two processes. Microdrilling of the phenocryst (∼300 μm drill holes) followed by MC-ICPMS analysis of the powders revealed negatively coupled Mg and Fe isotopic fractionations (δ 26 Mg from +0.1‰ to −0.2‰ and δ 56 Fe from −1.2‰ to −0.2‰ from core to rim), which can only be explained by Mg–Fe exchange between melt and olivine. The data can be explained with ratios of diffusivities of Mg and Fe isotopes in olivine scaling as D 2 /D 1 = (m 1 /m 2 )β with β Mg ∼0.16 and β Fe ∼0.27. LA-MC-ICPMS and MC-SIMS Fe isotopic measurements are developed and are demonstrated to yield accurate δ 56 Fe measurements within precisions of ∼0.2‰ (1 SD) at spatial resolutions of ∼50 μm. δ 56 Fe and δ 26 Mg stay constant with Fo# in the rim (late-stage overgrowth), whereas in the core (original phenocryst) δ 56 Fe steeply trends toward lighter compositions and δ 26 Mg trends toward heavier compositions with higher Fo#. A plot of δ 56 Fe vs. Fo# immediately distinguishes growth-controlled from diffusion-controlled zoning in these two regions. The results are consistent with the idea that large isotopic fractionation accompanies chemical diffusion in crystals, whereas fractional crystallization induces little or no isotopic fractionation. The cooling timescale inferred from the chemical-isotope zoning profiles is consistent with the documented cooling history of the lava lake. In the absence of geologic context, in situ stable isotopic measurements may now be used to interpret the nature of mineral zoning. Stable isotope measurements by LA-MC-ICPMS and MC-SIMS can be used as standard petrologic tools to identify samples for diffusion-based geospeedometry.

Geochimica et Cosmochimica Acta↗

USGS1985

Paleomagnetic and petrologic evidence bearing on the age and origin of uranium deposits in the Permian Cutler Formation, Lisbon Valley, Utah

An approximate age for uranium deposits in red beds of the Permian Cutler Formation, Lisbon Valley salt anticline, Utah, was obtained using paleomagnetic techniques. Progressive thermal demagnetization of samples of mineralized sandstone isolates stable magnetization components having high (≳400 °C) unblocking temperatures that define a tilt-corrected mean direction of D = 358.1°, I = 65.5°, α 95 = 3.3°. This direction is close to expected Late Cretaceous to middle Tertiary mean directions at Lisbon Valley. In contrast, thermal cleaning of samples of unmineralized sandstone isolates tilt-corrected southeasterly, shallow mean directions (D = 140.5°, I = −9.5°, α 95 = 8.6°, and D = 155.9°, I = −4.4°, α 95 = 10.9°, for two localities in the Lisbon Valley area). These results are closely similar to results from the Cutler Formation elsewhere on the Colorado Plateau and from other Lower Permian strata in North America. In unmineralized sandstone, the stable remanent magnetization is carried predominantly by martite of postdepositional or detrital origin, whereas in mineralized sandstone, the stable magnetization is carried largely by authigenic specular hematite as uranium- and vanadium-bearing clusters in interstitial areas, and it thus reflects the time of mineralization. Partial dissolution of martite grains and grain-coating ferric oxide pigment prior to formation of abundant interstitial specular hematite has minimized or eliminated the influence of late Paleozoic magnetic components in mineralized sandstone. These results, combined with information on the structural development of the Lisbon Valley area and on nearby uranium deposits in the Triassic Chinle Formation, suggest that the growth of the Lisbon Valley anticline during Late Cretaceous to early or middle Tertiary time promoted oxidative destruction of Chinle orebodies and led to a redistribution of uranium and iron from the Chinle into the Cutler. Acidic solutions generated during destruction of sulfide minerals in Chinle orebodies may account for the simultaneous transport of significant quantities of iron and uranium and for the partial dissolution of martite in the Cutler host beds. Neutralization of these solutions by reaction with host-rock constituents (especially calcite) caused precipitation of amorphous ferric oxide, which incorporated uranium by adsorption and which aged to form specular hematite.

Utah↗

USGS2011

Petrologic, tectonic, and metallogenic evolution of the Ancestral Cascades magmatic arc, Washington, Oregon, and northern California

Present-day High Cascades arc magmatism was preceded by ∼40 m.y. of nearly cospatial magmatism represented by the ancestral Cascades arc in Washington, Oregon, and northernmost California (United States). Time-space-composition relations for the ancestral Cascades arc have been synthesized from a recent compilation of more than 4000 geochemical analyses and associated age data. Neither the composition nor distribution of ancestral Cascades magmatism was uniform along the length of the ancestral arc through time. Initial (>40 to 36 Ma) ancestral Cascades magmatism (mostly basalt and basaltic andesite) was focused at the north end of the arc between the present-day locations of Mount Rainier and the Columbia River. From 35 to 18 Ma, initial basaltic andesite and andesite magmatism evolved to include dacite and rhyolite; magmatic activity became more voluminous and extended along most of the arc. Between 17 and 8 Ma, magmatism was focused along the part of the arc coincident with the northern two-thirds of Oregon and returned to more mafic compositions. Subsequent ancestral Cascades magmatism was dominated by basaltic andesite to basalt prior to the post–4 Ma onset of High Cascades magmatism. Transitional tholeiitic to calc-alkaline compositions dominated early (before 40 to ca. 25 Ma) ancestral Cascades eruptive products, whereas the majority of the younger arc rocks have a calc-alkaline affinity. Tholeiitic compositions characteristic of the oldest ancestral arc magmas suggest development associated with thin, immature crust and slab window processes, whereas the younger, calc-alkaline magmas suggest interaction with thicker, more evolved crust and more conventional subduction-related magmatic processes. Presumed changes in subducted slab dip through time also correlate with fundamental magma composition variation. The predominance of mafic compositions during latest ancestral arc magmatism and throughout the history of modern High Cascades magmatism probably reflects extensional tectonics that dominated during these periods of arc magmatism. Mineral deposits associated with ancestral Cascades arc rocks are uncommon; most are small and low grade relative to those found in other continental magmatic arcs. The small size, low grade, and dearth of deposits, especially in the southern two-thirds of the ancestral arc, probably reflect many factors, the most important of which may be the prevalence of extensional tectonics within this arc domain during this magmatic episode. Progressive clockwise rotation of the forearc block west of the evolving Oregon part of the ancestral Cascades magmatism produced an extensional regime that did not foster significant mineral deposit formation. In contrast, the Washington arc domain developed in a transpressional to mildly compressive regime that was more conducive to magmatic processes and hydrothermal fluid channeling critical to deposit formation. Small, low-grade porphyry copper deposits in the northern third of the ancestral Cascades arc segment also may be a consequence of more mature continental crust, including a Mesozoic component, beneath Washington north of Mount St. Helens.

California, Oregon, Washington↗

USGS2003

Volcano seismology

A fundamental goal of volcano seismology is to understand active magmatic systems, to characterize the configuration of such systems, and to determine the extent and evolution of source regions of magmatic energy. Such understanding is critical to our assessment of eruptive behavior and its hazardous impacts. With the emergence of portable broadband seismic instrumentation, availability of digital networks with wide dynamic range, and development of new powerful analysis techniques, rapid progress is being made toward a synthesis of high-quality seismic data to develop a coherent model of eruption mechanics. Examples of recent advances are: (1) high-resolution tomography to image subsurface volcanic structures at scales of a few hundred meters; (2) use of small-aperture seismic antennas to map the spatio-temporal properties of long-period (LP) seismicity; (3) moment tensor inversions of very-long-period (VLP) data to derive the source geometry and mass-transport budget of magmatic fluids; (4) spectral analyses of LP events to determine the acoustic properties of magmatic and associated hydrothermal fluids; and (5) experimental modeling of the source dynamics of volcanic tremor. These promising advances provide new insights into the mechanical properties of volcanic fluids and subvolcanic mass-transport dynamics. As new seismic methods refine our understanding of seismic sources, and geochemical methods better constrain mass balance and magma behavior, we face new challenges in elucidating the physico-chemical processes that cause volcanic unrest and its seismic and gas-discharge manifestations. Much work remains to be done toward a synthesis of seismological, geochemical, and petrological observations into an integrated model of volcanic behavior. Future important goals must include: (1) interpreting the key types of magma movement, degassing and boiling events that produce characteristic seismic phenomena; (2) characterizing multiphase fluids in subvolcanic regimes and determining their physical and chemical properties; and (3) quantitatively understanding multiphase fluid flow behavior under dynamic volcanic conditions. To realize these goals, not only must we learn how to translate seismic observations into quantitative information about fluid dynamics, but we also must determine the underlying physics that governs vesiculation, fragmentation, and the collapse of bubble-rich suspensions to form separate melt and vapor. Refined understanding of such processes—essential for quantitative short-term eruption forecasts—will require multidisciplinary research involving detailed field measurements, laboratory experiments, and numerical modeling.

Pure and Applied Geophysics↗

USGS1986

The evolution of young silicic lavas at Medicine Lake Volcano, California: Implications for the origin of compositional gaps in calc-alkaline series lavas

At Medicine Lake Volcano, California, the compositional gap between andesite (57-62 wt.% SiO2) and rhyolite (73-74 wt.% SiO2) has been generated by fractional crystallization. Assimilation of silicic crust has also occurred along with fractionation. Two varieties of inclusions found in Holocene rhyolite flows, hornblende gabbros and aphyric andesites, provide information on the crystallization path followed by lavas parental to the rhyolite. The hornblende gabbros are magmatic cumulate residues and their mineral assemblages are preserved evidence of the phases that crystallized from an andesitic precursor lava to generate the rhyolite lavas. The andesitic inclusions represent samples of a parental andesite and record the early part of the differentiation history. Olivine, plagioclase and augite crystallization begins the differentiation history, followed by the disappearance of olivine and augite through reaction with the liquid to form orthopyroxene and amphibole. Further crystallization of the assemblage plagioclase, amphibole, orthopyroxene, magnetite, and apatite from a high-SiO2 andesite leads to rhyolite. This final crystallization process occurs on a cotectic that is nearly horizontal in temperature-composition space. Since a large amount of crystallization occurs over a limited temperature interval, a compositional gap develops between rhyolite and high SiO2 andesite. Liquidus surfaces with shallow slopes in temperature-composition space are characteristic of several late-stage crystallization assemblages in the andesite to rhyolite compositional range. Experimentally produced plagioclase+ amphibole+orthopyroxene+magnetite and plagioclase+ augite+low-Ca pyroxene+magnetite cotectics have liquidus slopes that are nearly flat. At other calc-alkaline volcanic centers crystallization processes involving large compositional changes over small temperature intervals may also be important in the development of bimodal volcanism (i.e. the existence of a composition gap). At Mt. Mazama and Mt. St. Helens, USA and Aso Caldera and Shikotsu, Japan the amphibole-bearing assemblage was important. At Krakatau, Indonesia and Katmai, USA, an augite+orthopyroxene-bearing assemblage was important. In addition to its role in the production of a compositional gap between intermediate and rhyolitic lavas, the crystallization process increases the H2O content of the residual liquid. This rapid increase in residual liquid volatile content which results from the precipitation of a large proportion of crystalline solids may be an important factor among several that lead to explosive silicic eruptions. ?? 1986 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2012

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth↗

USGS2012

Organic geochemistry and petrology of subsurface Paleocene-Eocene Wilcox and Claiborne Group coal beds, Zavala County, Maverick Basin, Texas, USA

Coal samples from a coalbed methane exploration well in northern Zavala County, Maverick Basin, Texas, were characterized through an integrated analytical program. The well was drilled in February, 2006 and shut in after coal core desorption indicated negligible gas content. Cuttings samples from two levels in the Eocene Claiborne Group were evaluated by way of petrographic techniques and Rock–Eval pyrolysis. Core samples from the Paleocene–Eocene Indio Formation (Wilcox Group) were characterized via proximate–ultimate analysis in addition to petrography and pyrolysis. Two Indio Formation coal samples were selected for detailed evaluation via gas chromatography, and Fourier transform infrared (FTIR) and 13 C CPMAS NMR spectroscopy. Samples are subbituminous rank as determined from multiple thermal maturity parameters. Elevated rank (relative to similar age coal beds elsewhere in the Gulf Coast Basin) in the study area is interpreted to be a result of stratigraphic and/or structural thickening related to Laramide compression and construction of the Sierra Madre Oriental to the southwest. Vitrinite reflectance data, along with extant data, suggest the presence of an erosional unconformity or change in regional heat flow between the Cretaceous and Tertiary sections and erosion of up to >5 km over the Cretaceous. The presence of liptinite-rich coals in the Claiborne at the well site may indicate moderately persistent or recurring coal-forming paleoenvironments, interpreted as perennially submerged peat in shallow ephemeral lakes with herbaceous and/or flotant vegetation. However, significant continuity of individual Eocene coal beds in the subsurface is not suggested. Indio Formation coal samples contain abundant telovitrinite interpreted to be preserved from arborescent, above-ground woody vegetation that developed during the middle portion of mire development in forested swamps. Other petrographic criteria suggest enhanced biological, chemical and physical degradation at the beginning and end of Indio mire development. Fluorescence spectra of sporinite and resinite are consistent and distinctly different from each other, attributed to the presence of a greater proportion of complex asphaltene and polar molecules in resinite. Gas chromatography of resinite-rich coal shows sesquiterpenoid and diterpenoid peaks in the C 14–17 range, which are not present in resinite-poor coal. Quantities of extracts suggest bitumen concentration below the threshold for effective source rocks [30–50 mg hydrocarbon/g total organic carbon (HC/g TOC)]. Saturate/aromatic and pristane/phytane (Pr/Ph) ratios are different from values for nearby Tertiary-reservoired crude oil, suggesting that the Indio coals are too immature to source liquid hydrocarbons in the area. However, moderately high HI values (200–400 mg HC/g rock) may suggest some potential for naphthenic–paraffinic oil generation where buried more deeply down stratigraphic/structural dip. Extractable phenols and C 20+ alkanes are suggested as possible intermediates for acetate fermentation in microbial methanogenesis which may, however, be limited by poor nutrient supply related to low rainfall and meteoric recharge rate or high local sulfate concentration.

Texas↗

USGS2010

Organic petrology of subbituminous carbonaceous shale samples from Chalāw, Kabul Province, Afghanistan: Considerations for paleoenvironment and energy resource potential

Neogene (?) subbituminous carbonaceous shale deposits from Chalāw, Afghanistan, were investigated through organic petrology techniques and standard coal analyses to determine paleoenvironment and potential for resource utilization. The Chalāw deposit, approximately 30 km southeast of Kabul, currently is exploited for brick making and domestic heating and cooking. Three multiple-bench channel samples of the mined bed at Chalāw were collected and evaluated. The presence of significant huminite (ranging from 0.2 to 59.0 vol.%, mineral-inclusive basis) is suggestive of a terrestrial lignin-rich precursor plant material. Measured reflectance values of 0.38–0.55% indicate subbituminous rank. This rank suggests burial depths of approximately 1500 m and maximum temperatures of approximately 50 °C. Structured liptinite macerals generally are absent except for some fluorescing morphologies interpreted to be poorly-preserved root cork suberinite. Sponge spicule bioliths including gemmoscleres and megascleres are common. These petrographic observations, in addition to high mineral matter content (33 to > 95 vol.%), medium to high sulfur content (2.1–11.5 wt.%, dry basis; db), and the presence of common gastropod? shell fragments and an aragonite-needle chalk bed are consistent with, but not directly indicative of, a marginal marine or estuarine mangrove depositional environment. However, additional data are necessary to confirm this hypothesis and deposition in a freshwater environment cannot be ruled out at this time. Commercial-scale development and utilization of the Chalāw deposit as a thermal fuel resource may be possible using a fluidized bed combustion system which could accept the low-quality mine product currently produced. Samples examined herein contain high-ash yield (45–90 wt.%, db), high total moisture content (17–39 wt.%), low calorific value (980–6860 Btu/lb, m,mmf), and have poor agglomerating properties (FSI = 0), consistent with fuels utilized in fluidized bed combustors. However, delineation of the extent of the deposit through field investigation will be necessary to make a quantified resource estimate for mine planning.

Kabul Province↗

USGS2014

40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been migrating toward, and subparallel to, the northeast margin of the Colorado Plateau since the middle Miocene. Quaternary volcanism within this northern Rio Grande rift corridor is evidence that the rift is continuing to evolve.

Colorado↗

USGS2011

Peninsular terrane basement ages recorded by Paleozoic and Paleoproterozoic zircon in gabbro xenoliths and andesite from Redoubt volcano, Alaska

Historically Sactive Redoubt volcano is an Aleutian arc basalt-to-dacite cone constructed upon the Jurassic–Early Tertiary Alaska–Aleutian Range batholith. The batholith intrudes the Peninsular tectonostratigraphic terrane, which is considered to have developed on oceanic basement and to have accreted to North America, possibly in Late Jurassic time. Xenoliths in Redoubt magmas have been thought to be modern cumulate gabbros and fragments of the batholith. However, new sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages for zircon from gabbro xenoliths from a late Pleistocene pyroclastic deposit are dominated by much older, ca. 310 Ma Pennsylvanian and ca. 1865 Ma Paleoproterozoic grains. Zircon age distributions and trace-element concentrations indicate that the ca. 310 Ma zircons date gabbroic intrusive rocks, and the ca. 1865 Ma zircons also are likely from igneous rocks in or beneath Peninsular terrane basement. The trace-element data imply that four of five Cretaceous–Paleocene zircons, and Pennsylvanian low-U, low-Th zircons in one sample, grew from metamorphic or hydrothermal fluids. Textural evidence of xenocrysts and a dominant population of ca. 1865 Ma zircon in juvenile crystal-rich andesite from the same pyroclastic deposit show that this basement has been assimilated by Redoubt magma. Equilibration temperatures and oxygen fugacities indicated by Fe-Ti–oxide minerals in the gabbros and crystal-rich andesite suggest sources near the margins of the Redoubt magmatic system, most likely in the magma accumulation and storage region currently outlined by seismicity and magma petrology at ∼4–10 km below sea level. Additionally, a partially melted gabbro from the 1990 eruption contains zircon with U-Pb ages between ca. 620 Ma and ca. 1705 Ma, as well as one zircon with a U-Th disequilibrium model age of 0 ka. The zircon ages demonstrate that Pennsylvanian, and probably Paleoproterozoic, igneous rocks exist in, or possibly beneath, Peninsular terrane basement. Discovery of Pennsylvanian gabbro similar in age to Skolai arc plutons 500 km to the northeast indicates that the Peninsular terrane, along with the Wrangellia and Alexander terranes, has been part of the Wrangellia composite terrane since at least Pennsylvanian time. Moreover, the zircon data suggest that a Paleoproterozoic continental fragment may be present in the mid-to-upper crust in southern Alaska.

Alaska↗

USGS2008

The evolution of volcano-hosted geothermal systems based on deep wells from Karaha-Telaga Bodas, Indonesia

Temperature and pressure surveys, fluid samples, and petrologic analyses of rock samples from deep drill holes at the Karaha - Telaga Bodas geothermal field on the volcanic ridge extending northward from Galunggung Volcano, West Java, have provided a unique opportunity to characterize the evolution of an active volcano-hosted geothermal system. Wells up to 3 km in depth have encountered temperatures as high as 353??C and a weakly altered granodiorite that intruded to within 2 to 3 km of the surface. The intrusion is shallowest beneath the southern end of the field where an acid lake overlies a nearly vertical low resistivity structure (<10 ohm-m) defined by magnetotelluric measurements. This structure is interpreted to represent a vapor-dominated chimney that provides a pathway to the surface for magmatic gases. Four distinct hydrothermal mineral assemblages document the evolution of the geothermal system and the transition from liquid- to vapor-dominated conditions. The earliest assemblage represents the initial liquid-dominated system generated during emplacement of the granodiorite between 5910 ?? 76 and 4200 ?? 150 y BP. Tourmaline, biotite, actinolite, epidote and clay minerals were deposited contemporaneously at progressively greater distances from the intrusive contact (assemblage 1). At 4200 ?? 150 y BP, flank collapse and the formation of the volcano's crater, Kawah Galunggung, resulted in catastrophic decompression and boiling of the hydrothermal fluids. This event initiated development of the modern vapor-dominated regime. Chalcedony and then quartz were deposited as the early low salinity liquids boiled (assemblage 2). Both vapor- and liquid-rich fluid inclusions were trapped in the quartz crystals. Liquid-rich fluid inclusions from the southern part of the field record salinities ranging from 0 to 26 weight percent NaCl- CaCl2 equivalent and locally contain fluorite daughter crystals. We suggest, based on temperature-salinity relationships and evidence of boiling, that these fluids were progressively concentrated as steam was lost from the system. However, mixing with fluids derived from the underlying intrusion or generated during the formation of acid SO4 water on the vapor-dominated chimney margins could have contributed to the observed salinities. As pressures declined, CO2- and SO4-rich steam-heated water drained downward, depositing anhydrite and calcite (assemblage 3) in the fractures, limiting further recharge. Fluid inclusions with salinities up to 31 weight percent NaCl equivalent were trapped in these minerals as the descending water vaporized. The final assemblage is represented by precipitates of NaCl, KCl and FeClx deposited on rock surfaces in portions of the vapor-dominated zone that boiled dry. Vapor-dominated conditions extend over a distance of at least 10 km and to depths below sea level. Deep wells drilled into the underlying liquid-dominated reservoir in the northern and central part of the volcanic ridge produce low salinity fluids representing recent recharge of meteoric and steam-heated water. The evolution of volcanic-hosted vapor-dominated geothermal systems can be described by a five stage model. Stage 1 involves the formation of an over-pressured liquid-dominated geothermal system soon after magmatic intrusion. In Stages 2 and 3, pressures progressively decrease, and a curtain of steam-heated water surrounding a magmatic vapor-dominated chimney at 350??C and 14 ?? 2 MPa develops. The relatively low pressure near the base of the chimney causes liquid inflow adjacent to the intrusion and the development of a secondary marginal vapor-dominated zone. In Stage 4, the magmatic vapor discharge from the intrusion becomes small, vapor pressure declines, and the secondary vapor-dominated zone expands above the intrusion. In Stage 5, the vapor-dominated zone floods because heat from the intrusion is insufficient to boil all liquid inflow. A more common, liquid-dominated volcanic-hosted system the

American Journal of Science↗

USGS1989

Significance of loessite in the Maroon Formation (Middle Pennsylvanian to Lower Permian), Eagle Basin, northwest Colorado

Quaternary loess deposits are widespread on the earth's surface, yet pre-Quaternary loess deposits have rarely been reported. The Maroon Formation (Middle Pennsylvanian to Lower Permian) of the Eagle Basin, northwest Colorado, includes a siltstone-dominated facies interpreted as loessite (lithified loess) along its downwind basin margin. The section of inferred loessite in the Maroon Formation is locally at least 490 m thick and consists in large part of structureless and nearly structureless beds of homogeneous sandy siltstone. Bed contacts are generally planar to undulatory and are either horizontal or are characterized by gentle relief. Loessite beds are separated by common claystone drapes and weakly developed paleosols, and by rare pond deposits, channel deposits, and eolian-ripple-laminated deposits. The loess interpretation is based on 1) the homogeneity and dominance of the sandy silt grain-size; 2) the relative lack of primary sedimentary structures; 3) the gentle character of most bedding contacts and the common mantling of irregular depositional topography; 4) the inferred paleogeographic setting; and 5) the absence of suitable alternative interpretations. The loessite grades laterally into mixed fluvial-eolian deposits of the Maroon Formation in the main part of Eagle Basin, which served as the loessite sediment source. Deposition of the Maroon Formation was probably strongly affected by cyclic climatic changes synchronous with fluctuations in late Paleozoic continental ice sheets. The paleogeography and paleoclimatology of the Maroon Formation depositional system are not unique, suggesting that there are probably many other ancient loessites that have gone unrecognized.

Journal of Sedimentary Petrology↗

USGS2006

Distribution of recent volcanism and the morphology of seamounts and ridges in the GLIMPSE study area: Implications for the lithospheric cracking hypothesis for the origin of intraplate, non-hot spot volcanic chains

Lithospheric cracking by remotely applied stresses or thermoelastic stresses has been suggested to be the mechanism responsible for the formation of intraplate volcanic ridges in the Pacific that clearly do not form above fixed hot spots. As part of the Gravity Lineations Intraplate Melting Petrology and Seismic Expedition (GLIMPSE) project designed to investigate the origin of these features, we have mapped two volcanic chains that are actively forming to the west of the East Pacific Rise using multibeam echo sounding and side-scan sonar. Side-scan sonar reveals the distribution of rough seafloor corresponding to recent, unsedimented lava flows. In the Hotu Matua volcanic complex, recent flows and volcanic edifices are distributed over a region 450 km long and up to 65 km wide, with an apparent, irregular age progression from older flows in the west to younger in the east. The 550-km-long Southern Cross Seamount/Sojourn Ridge/Brown Ridge chain appears to have been recently active only at its eastern end near the East Pacific Rise. A third region of recent flows is found 120 km north of Southern Cross Seamount in seafloor approximately 9 Myr old. No indication of lithospheric extension in the form of faulting or graben formation paralleling the trend of the volcanic chains is found in the vicinity of recent flows or anywhere else in the study area. Thermoelastic cracking could be a factor in the formation of a few small, very narrow volcanic ridges, but most of the volcanic activity is broadly distributed in wide swaths with no indication of formation along narrow cracks. The Sojourn and Brown chains appear to begin as distributed zones of small seamounts that later develop into segmented ridges, perhaps under the influence of membrane stresses from self-loading. We suggest that the linear volcanic chains are created by moving melting anomalies in the asthenosphere and that lithospheric cracking plays at most a secondary role. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS1987

Integration of channel and floodplain suites. I. Developmental sequence and lateral relations of alluvial paleosols.

The lower Eocene Willwood Formation of the Bighorn Basin, northwest Wyoming, consists of about 770 m of alluvial rocks that exhibit extensive mechanical and geochemical modifications resulting from Eocene pedogenesis. Willwood paleosols vary considerably in their relative degrees of maturity; maturity is defined as stage of development as a function of the amount of time required to form. Five arbitrary stages are proposed to distinguish these soils of different maturities in the Willwood Formation. Stage 1 soils, the least mature, are entisols; stage 2 and stage 3 soils are intermediate in maturity and are probably alfisols; and stage 4 and stage 5 soils, the most mature, are spodosols. These stages are not only time-progressive elements of an in situ maturation sequence for Willwood soil formation, but, in the lateral dimension, they are also usually distributed sequentially. Study of Willwood paleosols indicates that an inverse relationship exists between soil maturity and short-term sediment accumulation rate. The least mature Willwood paleosols formed in areas of relatively high net rates of sediment accumulation on 1) channel, levee, and crevasse-splay sediments of the proximal alluvial ridge, and 2) deposits filling large and small paleovalleys formed by major episodes of gullying (lowered baselevels). In contrast, the fine-grained sediments of the distal floodplain, where net sediment accumulation rates were relatively low, experienced development of much more mature soils. Soils of intermediate maturities occur in the order of their stage on intervening proximal floodplain and distal alluvial ridge sediments. Adjacent bodies of sedimentary rock that differ in their ancient soil properties because of distance from areas of relatively high sediment accumulation are denoted by the new term pedofacies . The remarkable sequence of paleosols in the Willwood Formation clearly illustrates several important principles of soil-sediment interrelationships in aggrading alluvial systems that have broad application to other deposits. This is especially true in view of the widespread distribution of paleosols in nearly all ancient fluvial rocks. Further study of Willwood paleosols will not only enable precise lateral correlation of coeval alluvial sediments, and thereby fluvial sedimentary events, from the distal to the proximal realms of the floodplain but will also contribute to increasingly informative evaluations of the nature, tempo, and mode of alluvial succession.

Journal of Sedimentary Petrology↗

USGS2021

A petrological and conceptual model of Mayon volcano (Philippines) as an example of an open-vent volcano

Mayon is a basaltic andesitic, open-vent volcano characterized by persistent passive degassing from the summit at 2463 m above sea level. Mid-size (<0.1 km3) and mildly explosive eruptions and occasional phreatic eruptions have occurred approximately every 10 years for over a hundred years. Mayon’s plumbing system structure, processes, and time scales driving its eruptions are still not well-known, despite being the most active volcano in the Philippines. We investigated the petrology and geochemistry of its crystal-rich lavas (~50 vol% phenocrysts) from nine historical eruptions between 1928 and 2009 and propose a conceptual model of the processes and magmatic architecture that led to the eruptions. The whole-rock geochemistry and mineral assemblage (plagioclase + orthopyroxene + clinopyroxene + Fe-Ti oxide ± olivine) of the lavas have remained remarkably homogenous (54 wt% SiO2,~4 wt% MgO) from 1928 to 2009. However, electron microscope images and microprobe analyses of the phenocrysts and the existence of three types of glomerocrysts testify to a range of magmatic processes, including long-term magma residence, magma mixing, crystallization, volatile fluxing, and degassing. Multiple mineral-melt geothermobarometers suggest a relatively thermally buffered system at 1050±25 °C, with several magma residence zones, ranging from close to the surface, through reservoirs at ~4–5 km, and as deep as ~ 20 km. Diffusion chronometry on >200 orthopyroxene crystals reveal magma mixing timescales that range from a few days to about 65 years, but the majority are shorter than the decadal inter-eruptive repose period. This implies that magma intrusion at Mayon has been nearly continuous over the studied time period, with limited crystal recycling from one eruption to the next. The variety of plagioclase textures and zoning patterns reflect fluxing of volatiles from depth to shallower melts through which they eventually reach the atmosphere through an open conduit. The crystal-rich nature of the erupted magmas may have developed during each inter-eruptive period. We propose that Mayon has behaved over almost 100 years as a steady state system, with limited variations in eruption frequency, degassing flux, magma composition, and crystal content that are mainly determined by the amount and composition of deep magma and volatile input in the system. We explore how Mayon volcano’s processes and working model can be related to other open-vent mafic and water-rich systems such as Etna, Stromboli, Villarrica, or Llaima. Finally, our understanding of open-vent, persistently active volcanoes is rooted in historical observations, but volcano behavior can evolve over longer time frames. We speculate that these volcanoes produce specific plagioclase textures that can be used to identify similar volcanic behavior in the geologic record.

Mayon volcano↗