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USGS2003

Geologic framework and hydrogeologic features of the Glen Rose Limestone, Camp Bullis Training Site, Bexar County, Texas

The Glen Rose Limestone crops out over most of the Camp Bullis Training Site in northern Bexar County, Texas, where it consists of upper and lower members and composes the upper zone and the upper part of the middle zone of the Trinity aquifer. Uncharacteristically permeable in northern Bexar County, the Glen Rose Limestone can provide avenues for recharge to and potential contamination of the downgradient Edwards aquifer, which occupies the southeastern corner of Camp Bullis. The upper member of the Glen Rose Limestone characteristically is thin-bedded and composed mostly of soft limestone and marl, and the lower Glen Rose typically is composed mostly of relatively massive, fossiliferous limestone. The upper member, about 410 to 450 feet thick at Camp Bullis, was divided in this study into five hydrogeologic subdivisions, A through E (youngest to oldest). The approximately 120-foot-thick Interval A has an abundance of caves, which is indicative of its generally well developed fracture, channel, and cavern porosity that in places provides appreciable permeability. The 120- to 150-foot-thick Interval B is similar to Interval A but with less cave development and considerably less permeability. The 10- to 20-foot-thick Interval C, a layer of partly to mostly dissolved soluble carbonate minerals, is characterized by breccia porosity, boxwork permeability, and collapse structures that typically divert ground water laterally to discharge at land surface. The 135- to 180-foot-thick Interval D generally has low porosity and little permeability with some local exceptions, most notably the caprinid biostrome just below the top of the interval, which appears to be permeable by virtue of excellent moldic, vug, fracture, and cavern porosity. The 10- to 20-foot-thick Interval E, a layer of partly to mostly dissolved evaporites similar to Interval C, has similar hydrogeologic properties and a tendency to divert ground water laterally.

Texas↗
USGS2003

Chemical quality of water, sediment, and fish in Mountain Creek Lake, Dallas, Texas, 1994-97

The occurrence, trends, and sources of numerous inorganic and organic contaminants were evaluated in Mountain Creek Lake, a reservoir in Dallas, Texas. The study, done in cooperation with the Southern Division Naval Facilities Engineering Command, was prompted by the Navy’s concern for potential off-site migration of contaminants from two facilities on the shore of Mountain Creek Lake, the Naval Air Station Dallas and the Naval Weapons Industrial Reserve Plant. Sampling of stormwater (including suspended sediment), lake water, bottom sediment (including streambed sediment), and fish was primarily in Mountain Creek Lake but also was in stormwater outfalls from the Navy facilities, nearby urban streams, and small streams draining the Air Station. Volatile organic compounds, predominantly solvents from the Reserve Plant and fuel-related compounds from the Air Station, were detected in stormwater from both Navy facilities. Fuel-related compounds also were detected in Mountain Creek Lake at two locations, one near the Air Station inlet where stormwater from a part of the Air Station enters the lake and one at the center of the lake. Concentrations of volatile organic compounds at the two lake sites were small, all less than 5 micrograms per liter. Elevated concentrations of cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc, from 2 to 4 times concentrations at background sites and urban reference sites, were detected in surficial bottom sediments in Cottonwood Bay, near stormwater outfalls from the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls, compared to background and urban reference sites, were detected in surficial sediments in Cottonwood Bay. Elevated concentrations of polycyclic aromatic hydrocarbons, indicative of urban sources, also were detected in Cottonwood Creek, which drains an urbanized area apart from the Navy facilities. Elevated concentrations of polychlorinated biphenyls were detected in two inlets near the Air Station shoreline. Polycyclic aromatic hydrocarbon and heavy metal concentrations near the Air Station shoreline were not elevated compared to urban reference sites. Much larger concentrations of selected heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were detected in deeper, older sediments than in surficial sediments in Cottonwood Bay. The decreases in concentrations coincide with changes in wastewater discharge practices at the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls also were detected in older sediments in the Air Station inlet. On the basis of dated sediment cores and contaminant discharge histories, contaminant accumulation rates in Cottonwood Bay were much greater historically than recently. Most heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls that accumulated in the central and eastern parts of Cottonwood Bay appear to have come from the west lagoon on the Reserve Plant. Treated sewage and industrial-process wastewater were discharged to the west lagoon from about 1941 to 1974. Estimated annual contaminant accumulation rates in Cottonwood Bay decreased by from 1 to 2 orders of magnitude after 1974, when most point-source discharges to the west lagoon ceased. Polychlorinated biphenyls were detected in 61 of 62 individual fish-tissue samples. The largest average concentrations were in eviscerated channel catfish and the smallest were in largemouth bass fillets. Polychlorinated biphenyl and selenium concentrations from analyses of this study were large enough to prompt the Texas State Department of Health to issue a fish-possession ban for Mountain Creek Lake in 1996. Suspended sediments in stormwater at the lagoon outfalls and at sites on Cottonwood Creek were sampled and analyzed for major and trace elements, polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls. The suspended sediments from the outfalls contained about the same mixture of heavy metals and organic compounds, in elevated concentrations compared to reference sites, as bottom sediments from the lagoons and surficial bottom sediments in Cottonwood Bay. Diagnostic ratios of polycyclic aromatic hydrocarbons indicate that uncombusted fuel sources contribute to older sediments and that pyrogenic sources of polycyclic aromatic hydrocarbons dominate recently deposited sediments in Cottonwood Bay and along the Air Station shoreline.

Texas↗
USGS2004

Estimates of hydraulic properties from a one-dimensional numerical model of vertical aquifer-system deformation, Lorenzi site, Las Vegas, Nevada

Land subsidence related to aquifer-system compaction and ground-water withdrawals has been occurring in Las Vegas Valley, Nevada, since the 1930's, and by the late 1980's some areas in the valley had subsided more than 5 feet. Since the late 1980's, seasonal artificial-recharge programs have lessened the effects of summertime pumping on aquifer-system compaction, but the long-term trend of compaction continues in places. Since 1994, the U.S. Geological Survey has continuously monitored water-level changes in three piezometers and vertical aquifer-system deformation with a borehole extensometer at the Lorenzi site in Las Vegas, Nevada. A one-dimensional, numerical, ground-water flow model of the aquifer system below the Lorenzi site was developed for the period 1901-2000, to estimate aquitard vertical hydraulic conductivity, aquitard inelastic skeletal specific storage, and aquitard and aquifer elastic skeletal specific storage. Aquifer water-level data were used in the model as the aquifer-system stresses that controlled simulated vertical aquifer-system deformation. Nonlinear-regression methods were used to calibrate the model, utilizing estimated and measured aquifer-system deformation data to minimize a weighted least-squares objective function, and estimate optimal property values. Model results indicate that at the Lorenzi site, aquitard vertical hydraulic conductivity is 3 x 10-6 feet per day, aquitard inelastic skeletal specific storage is 4 x 10-5 per foot, aquitard elastic skeletal specific storage is 5 x 10-6 per foot, and aquifer elastic skeletal specific storage is 3 x 10-7 per foot. Regression statistics indicate that the model and data provided sufficient information to estimate the target properties, the model adequately simulated observed data, and the estimated property values are accurate and unique.

Water-Resources Investigations Report↗
USGS2003

Bathymetric mapping, sediment quality, and water quality of Lake Delhi, Iowa, 2001-02

Lake Delhi was formed in 1929 when the Interstate Power Company dammed the Maquoketa River near Delhi, Iowa, for generation of hydroelectric power. The resulting 450-acre lake became a popular area in eastern Iowa for boating, swimming, and fishing. Hydroelectric power generation ended in 1973, and lakeside residents purchased the dam to maintain the recreational opportunities of the lake. Increasing concerns about sediment deposition and water quality by lakeside residents led to a 2-year study that included a bathymetric survey, an assessment of sediment quality, and an assessment of water quality of Lake Delhi. A bathymetric map of Lake Delhi was constructed using more than 300,000 data points from echo sounding results and GIS (geographic information system) software. Results of bathymetric mapping showed that the upstream reach through most of the upstream-middle reach of Lake Delhi (approximately 3 miles) from about 0.25 mile upstream from the Greenslades coring site through Clair View Acres were particularly affected by sedimentation, with water depths ranging from less than 1 foot to a few areas that were as much as 10 feet deep. Numerous areas in the upstream-most 1-mile of the lake (about 0.25 mile upstream from the Greenslades coring site to just downstream from The Cedars coring site) had depths of only 1 to 2 feet and were nearly impassable by boats. The middle reach of Lake Delhi (an approximately 2.5-mile segment) from about one-half mile upstream from the Linden Acres coring site to just downstream from the Hartwick Dredge coring site was less affected by sedimentation with water depths from less than 1 to 16 feet. The deepest section (26 feet) of the lake was near the dam. Eleven trace metals and phosphorus were analyzed in 20 samples from seven lake-bottom sediment cores. The median and average traceelement concentrations from the sediment cores were less than the U.S. Environmental Protection Agency threshold-effects-level and probableeffects-level guidelines for toxic biological effects. Water-quality samples from eight sites (Maquoketa River, three lake sites, and four tributaries) were collected for five sampling periods (June 2001–July 2002). Water-quality samples were analyzed for physical properties (specific conductance, pH, temperature, turbidity, dissolved oxygen, and alkalinity), nutrients (nitrate, ammonia, and phosphorus), bacteria (total coliform and E. coli ), and suspended sediment. Selected water samples were analyzed for major ions, trace elements, and pesticides. Water-quality sampling results indicate areas affected by elevated nutrient and bacteria concentrations in the lake and tributary streams. The tributary streams had the highest median nitrate concentrations (12.1 milligrams per liter) when compared to median nitrate concentrations in the lake (8.7 milligrams per liter) or the Maquoketa River (10.5 milligrams per liter). The maximum nitrate concentrations detected for Maquoketa River, lake, and tributary sites were 13.5, 13.5, and 18.6 milligrams per liter, respectively. Nitrate concentrations in the late summer decreased from 2 Bathymetric Mapping, Sediment Quality, and Water Quality of Lake Delhi, Iowa, 2001–02 the upstream (7.8 milligrams per liter) to the downstream (5.0 milligrams per liter) one-third of Lake Delhi and most likely were the result of uptake of nitrate by algae and aquatic biota in the lake. Median concentrations of total coliform and E. coli bacteria for the lake sites were 450 and 17 colonies per 100 milliliters of sample, respectively. The U.S. Environmental Protection Agency criteria for full body contact (swimming or bathing) are 200 colonies per 100 milliliters for fecal bacteria and 126 colonies per 100 milliliters for E. coli bacteria. The highest bacteria concentrations in the lake occurred after a rain and were 25,000 colonies per 100 milliliters total coliform and 1,900 colonies per 100 milliliters E. coli .

Iowa↗
USGS2003

Changes in streamflow and summary of major-ion chemistry and loads in the North Fork Red River basin upstream from Lake Altus, northwestern Texas and western Oklahoma, 1945-1999

Upstream from Lake Altus, the North Fork Red River drains an area of 2,515 square miles. The quantity and quality of surface water are major concerns at Lake Altus, and water-resource managers and consumers need historical information to make informed decisions about future development. The Lugert-Altus Irrigation District relies on withdrawals from the lake to sustain nearly 46,000 acres of agricultural land. Kendall's tau tests of precipitation data indicated no statistically significant trend over the entire 100 years of available record. However, a significant increase in precipitation occurred in the last 51 years. Four streamflow-gaging stations with more than 10 years of record were maintained in the basin. These stations recorded no significant trends in annual streamflow volume. Two stations, however, had significant increasing trends in the base-flow index, and three had significant decreasing trends in annual peak flows. Major-ion chemistry in the North Fork Red River is closely related to the chemical composition of the underlying bedrock. Two main lithologies are represented in the basin upstream from Lake Altus. In the upper reaches, young and poorly consolidated sediments include a range of sizes from coarse gravel to silt and clay. Nearsurface horizons commonly are cemented as calcium carbonate caliche. Finer-grained gypsiferous sandstones and shales dominate the lower reaches of the basin. A distinct increase in dissolved solids, specifically sodium, chloride, calcium, and sulfate, occurs as the river flows over rocks that contain substantial quantities of gypsum, anhydrite, and dolomite. These natural salts are the major dissolved constituents in the North Fork Red River.

Oklahoma, Texas↗
USGS2003

Streamwater quality at selected sites in the Fraser River basin, Grand County, Colorado, water years 1991-2000

To determine the effect of population growth on streamwater quality in the Fraser River Basin, the U.S. Geological Survey did a study in cooperation with the Grand County Commissioners and the East Grand County Water Quality Board. During water years 1991 through 2000, the study determined that concentrations of un-ionized ammonia and nitrite plus nitrate in the streamwater of the basin are within Colorado State streamwater?quality standards. The study also found that concentrations of chloride are largest at the headwaters and decrease downstream; however, chloride loading in the stream has the opposite relation. Most nutrient loading to the Fraser River happens January through May. Concentrations of ammonia at Fraser River downstream from Vasquez Creek at Winter Park had a downward trend through the period of the study. Nitrite plus nitrate had upward and downward trends at different sites and over different time spans. Orthophosphorus concentrations had upward trends at two sites. In general, the streamwater quality in the Fraser River Basin is good and is not out of compliance with State standards.

Water-Resources Investigations Report↗
USGS2003

Fate and Transport Modeling of Selected Chlorinated Organic Compounds at Hangar 1000, U.S. Naval Air Station, Jacksonville, Florida

The Jacksonville Naval Air Station occupies 3,800 acres adjacent to the St. Johns River in Jacksonville, Florida. Two underground storage tanks at Hangar 1000 contained solvents from the late 1960s until they were removed in 1994. Ground-water samples at one of the tank sites had levels of trichloroethene (TCE) and total dichloroethene (DCE) of 8,710 micrograms per liter (mg/L) and 4,280 mg/L, respectively. Vinyl chloride (VC) at the site is the result of the biodegradation of DCE. Ground water beneath Hangar 1000 flows toward a storm sewer. TCE and DCE plumes travel with the ground water and presumably have reached the storm sewer, which discharges to the St. Johns River. Simulation of solute transport indicates that the traveltime from the storage tank site to the storm sewer is 16, 14, and 12 years for TCE, DCE, and VC respectively. TCE has the longest traveltime because it has the highest retardation factor at 2.5, DCE takes less time with a retardation factor of 2.0, and VC has the quickest traveltime because it has the lowest retardation factor of 1.7. Based on modeling results, the release of contaminants in the aquifer occurred more than 16 years ago. Model-derived dispersivity values at Hangar 1000 were: longitudinal 1.5 feet (ft), transverse 0.27 ft, and vertical 0.27 ft. The model-derived first order decay rates for biodegradation of TCE, DCE, and VC were 0.0002 per day (d-1), 0.0002 d-1, and 0.06 d-1, respectively. These rates are equivalent to half-lives of 13.7 years for TCE and DCE and 17 days for VC. Source area reductions in contaminant concentrations of 50 and 100 percent were modeled to simulate remediation. As expected, reducing the source concentration by 50 percent resulted in eventual TCE, DCE, and VC concentrations that were half of the original concentrations. About 16 years were needed for new steady-state TCE concentrations to develop, about 14 years for DCE, and about 12 years for VC. Reducing the source area concentrations by 100 percent in the model eventually resulted in zero concentrations of TCE, DCE, and VC. The modeled period of time for the contaminants to be removed from the aquifer once the source was removed was about 17 years for TCE, 15 years for DCE, and 13 years for VC.

Water-Resources Investigations Report↗
USGS2003

Simulation of net infiltration and potential recharge using a distributed-parameter watershed model of the Death Valley region, Nevada and California

This report presents the development and application of the distributed-parameter watershed model, INFILv3, for estimating the temporal and spatial distribution of net infiltration and potential recharge in the Death Valley region, Nevada and California. The estimates of net infiltration quantify the downward drainage of water across the lower boundary of the root zone and are used to indicate potential recharge under variable climate conditions and drainage basin characteristics. Spatial variability in recharge in the Death Valley region likely is high owing to large differences in precipitation, potential evapotranspiration, bedrock permeability, soil thickness, vegetation characteristics, and contributions to recharge along active stream channels. The quantity and spatial distribution of recharge representing the effects of variable climatic conditions and drainage basin characteristics on recharge are needed to reduce uncertainty in modeling ground-water flow. The U.S. Geological Survey, in cooperation with the Department of Energy, developed a regional saturated-zone ground-water flow model of the Death Valley regional ground-water flow system to help evaluate the current hydrogeologic system and the potential effects of natural or human-induced changes. Although previous estimates of recharge have been made for most areas of the Death Valley region, including the area defined by the boundary of the Death Valley regional ground-water flow system, the uncertainty of these estimates is high, and the spatial and temporal variability of the recharge in these basins has not been quantified. To estimate the magnitude and distribution of potential recharge in response to variable climate and spatially varying drainage basin characteristics, the INFILv3 model uses a daily water-balance model of the root zone with a primarily deterministic representation of the processes controlling net infiltration and potential recharge. The daily water balance includes precipitation (as either rain or snow), snow accumulation, sublimation, snowmelt, infiltration into the root zone, evapotranspiration, drainage, water content change throughout the root-zone profile (represented as a 6-layered system), runoff (defined as excess rainfall and snowmelt) and surface water run-on (defined as runoff that is routed downstream), and net infiltration (simulated as drainage from the bottom root-zone layer). Potential evapotranspiration is simulated using an hourly solar radiation model to simulate daily net radiation, and daily evapotranspiration is simulated as an empirical function of root zone water content and potential evapotranspiration. The model uses daily climate records of precipitation and air temperature from a regionally distributed network of 132 climate stations and a spatially distributed representation of drainage basin characteristics defined by topography, geology, soils, and vegetation to simulate daily net infiltration at all locations, including stream channels with intermittent streamflow in response to runoff from rain and snowmelt. The temporal distribution of daily, monthly, and annual net infiltration can be used to evaluate the potential effect of future climatic conditions on potential recharge. The INFILv3 model inputs representing drainage basin characteristics were developed using a geographic information system (GIS) to define a set of spatially distributed input parameters uniquely assigned to each grid cell of the INFILv3 model grid. The model grid, which was defined by a digital elevation model (DEM) of the Death Valley region, consists of 1,252,418 model grid cells with a uniform grid cell dimension of 278.5 meters in the north-south and east-west directions. The elevation values from the DEM were used with monthly regression models developed from the daily climate data to estimate the spatial distribution of daily precipitation and air temperature. The elevation values were also used to simulate atmosp

Water-Resources Investigations Report↗
USGS2003

Diazinon and chlorpyrifos loads in precipitation and urban and agricultural storm runoff during January and February 2001 in the San Joaquin River basin, California

The application of diazinon and chlorpyrifos on dormant orchards in 2001 in the San Joaquin River Basin was 24 percent less and 3.2 times more than applications in 2000, respectively. A total of 16 sites were sampled during January and February 2001 storm events: 7 river sites, 8 precipitation sites, and 1 urban storm drain. The seven river sites were sampled weekly during nonstorm periods and more frequently during storm runoff from a total of four storms. The monitoring of storm runoff at a city storm drain in Modesto, California, occurred simultaneously with the collection of precipitation samples from eight sites during a January 2001 storm event. The highest concentrations of diazinon occurred during the storm periods for all 16 sites, and the highest concentrations of chlorpyrifos occurred during weekly nonstorm sampling for the river sites and during the January storm period for the urban storm drain and precipitation sites. A total of 60 samples (41 from river sites, 10 from precipitation sites, and 9 from the storm drain site) had diazinon concentrations greater than 0.08 ?g/L, the concentration being considered by the California Department of Fish and Game as its criterion maximum concentration for the protection of aquatic habitats. A total of 18 samples (2 from river sites, 9 from precipitation sites, and 7 from the storm drain site) exceeded the equivalent California Department of Fish and Game guideline of 0.02 ?g/L for chlorpyrifos. The total diazinon load in the San Joaquin River near Vernalis during January and February 2001 was 23.8 pounds active ingredient; of this amount, 16.9 pounds active ingredient were transported by four storms, 1.06 pounds active ingredient were transported by nonstorm events, and 5.82 pounds active ingredient were considered to be baseline loads. The total chlorpyrifos load in the San Joaquin River near Vernalis during January and February 2001 was 2.17 pounds active ingredient; of this amount, 0.702 pound active ingredient was transported during the four storms, and 1.47 pounds active ingredient were considered as baseline load. The total January and February diazinon load in the San Joaquin River near Vernalis was 0.27 percent of dormant application; the total January and February chlorpyrifos load was 0.02 percent of dormant application. The precipitation samples collected during the January 2001 storm event were analyzed for pesticides to evaluate their potential contribution to pesticide loads in the study area. When the average concentrations of diazinon and chlorpyrifos in the precipitation samples were compared with concentrations in urban storm runoff samples, 68 percent of the diazinon concentration in the runoff could be accounted for in the precipitation. Chlorpyrifos, however, had average precipitation concentrations that were 2.5 times higher than what was detected in the runoff. Although no firm conclusions can be made from one storm event, preliminary results indicate that pesticides in precipitation can significantly contribute to pesticide loads in storm runoff.

Water-Resources Investigations Report↗
USGS2003

Simulation of Temperature, Nutrients, Biochemical Oxygen Demand, and Dissolved Oxygen in the Catawba River, South Carolina, 1996-97

Time-series plots of dissolved-oxygen concentrations were determined for various simulated hydrologic and point-source loading conditions along a free-flowing section of the Catawba River from Lake Wylie Dam to the headwaters of Fishing Creek Reservoir in South Carolina. The U.S. Geological Survey one-dimensional dynamic-flow model, BRANCH, was used to simulate hydrodynamic data for the Branched Lagrangian Transport Model. Waterquality data were used to calibrate the Branched Lagrangian Transport Model and included concentrations of nutrients, chlorophyll a, and biochemical oxygen demand in water samples collected during two synoptic sampling surveys at 10 sites along the main stem of the Catawba River and at 3 tributaries; and continuous water temperature and dissolved-oxygen concentrations measured at 5 locations along the main stem of the Catawba River. A sensitivity analysis of the simulated dissolved-oxygen concentrations to model coefficients and data inputs indicated that the simulated dissolved-oxygen concentrations were most sensitive to watertemperature boundary data due to the effect of temperature on reaction kinetics and the solubility of dissolved oxygen. Of the model coefficients, the simulated dissolved-oxygen concentration was most sensitive to the biological oxidation rate of nitrite to nitrate. To demonstrate the utility of the Branched Lagrangian Transport Model for the Catawba River, the model was used to simulate several water-quality scenarios to evaluate the effect on the 24-hour mean dissolved-oxygen concentrations at selected sites for August 24, 1996, as simulated during the model calibration period of August 23 27, 1996. The first scenario included three loading conditions of the major effluent discharges along the main stem of the Catawba River (1) current load (as sampled in August 1996); (2) no load (all point-source loads were removed from the main stem of the Catawba River; loads from the main tributaries were not removed); and (3) fully loaded (in accordance with South Carolina Department of Health and Environmental Control National Discharge Elimination System permits). Results indicate that the 24-hour mean and minimum dissolved-oxygen concentrations for August 24, 1996, changed from the no-load condition within a range of - 0.33 to 0.02 milligram per liter and - 0.48 to 0.00 milligram per liter, respectively. Fully permitted loading conditions changed the 24-hour mean and minimum dissolved-oxygen concentrations from - 0.88 to 0.04 milligram per liter and - 1.04 to 0.00 milligram per liter, respectively. A second scenario included the addition of a point-source discharge of 25 million gallons per day to the August 1996 calibration conditions. The discharge was added at S.C. Highway 5 or at a location near Culp Island (about 4 miles downstream from S.C. Highway 5) and had no significant effect on the daily mean and minimum dissolved-oxygen concentration. A third scenario evaluated the phosphorus loading into Fishing Creek Reservoir; four loading conditions of phosphorus into Catawba River were simulated. The four conditions included fully permitted and actual loading conditions, removal of all point sources from the Catawba River, and removal of all point and nonpoint sources from Sugar Creek. Removing the point-source inputs on the Catawba River and the point and nonpoint sources in Sugar Creek reduced the organic phosphorus and orthophosphate loadings to Fishing Creek Reservoir by 78 and 85 percent, respectively.

South Carolina↗
USGS2003

Sedimentation Survey of Lago El Guineo, Puerto Rico, October 2001

Lago El Guineo has lost about 17.5 percent of its original storage capacity in 70 years because of sediment accumulation. The water volume has been reduced from 2.29 million cubic meters in 1931, to 2.03 million cubic meters in 1986, and to 1.89 million cubic meters in 2001. The average annual storage-capacity loss (equal to the sedimentation rate) of Lago El Guineo was 4,727 cubic meters for the period of 1931 to July 1986 (or 0.21 percent per year), increasing to 5,714 cubic meters for the period of 1931 to October 2001 (or 0.25 percent per year). Discrepancies that could lead to substantial errors in volume calculations in a small reservoir like Lago El Guineo, were found when transferring the field-collected data into the geographic information system data base 1:20,000 U.S. Geological Survey Jayuya, Puerto Rico quadrangle. After verification and validation of field data, the Lago El Guineo shoreline was rectified using digital aerial photographs and differential global positioning data.

Water-Resources Investigations Report↗
USGS2003

Geohydrologic Framework of Recharge and Seawater Intrusion in the Pajaro Valley, Santa Cruz and Monterey Counties, California

Pajaro Valley is a coastal watershed of 160 square miles located along Monterey Bay north of Elkhorn Slough and south of the city of Santa Cruz. The valley has been predominantly developed for agriculture since the late 1800s. In 1984 the Pajaro Valley Water Management Agency (PVWMA) was formed and was delegated with the responsibility of the management of the water resources within the Pajaro Valley by the State of California. About 84 percent of the water is used for agriculture and 16 percent is used for industrial and municipal water supply; almost all of the demand is supplied by ground water. Ground-water pumpage varies with seasonal and climatic periods. The alluvial aquifers are composed of Quaternary- and Tertiary-aged sediments that are layered marine and terrestrial coarse-grained deposits separated by extensive fine-grained deposits that potentially restrict vertical movement of ground water and seawater intrusion in the coastal subareas. The coarse-grained deposits, which persist over large areas, control pumpage and related seawater intrusion. The Aromas Sand crops out throughout the north and central parts of the PVWMA area and offshore on the continental shelf and in Monterey submarine canyon. Because many of the wells in the coastal and inland subregions are screened at depths of 200 to 400 feet below land surface, a direct avenue is provided for seawater intrusion through the coarse-grained deposits of the shallower alluvium and Aromas Sand. Geophysical logs from monitoring wells indicate discrete zones of saline water that are related to pumpage and seawater intrusion in the aquifers of the shallower alluvium and upper Aromas Sand in the upper-aquifer system and to deeper saline waters in the lower Aromas Sand within the lower-aquifer system. The precipitation data indicate that there were at least nine dry and nine wet periods that range from 2 to 19 years during the period of record, 1880?1997. The ground-water pumpage, runoff, streamflow and related water quality of streamflow also vary with seasonal and climatic periods. Recharge occurs from deep percolation of precipitation and from infiltration of streamflow. Streamflow originates from local runoff and from outside the valley as inflow from the Pajaro River. Although partly regulated, streamflow in the Pajaro River at Chittenden is less than 200 cubic feet per second 88 percent of the time and is less than 12 cubic feet per second 50 percent of the time. Streamflow water-quality data suggest that there may be several sources of poor-quality water that contribute to elevated chloride, sulfate, and nitrate concentrations in streamflow. The poor water quality occurring during lower streamflows indicates that low flows may be an additional source of salinity for ground-water recharge as streamflow infiltration along the Pajaro River. The geochemical data from this study indicate that the two main sources of recharge are deep percolation of local runoff and streamflow infiltration of Pajaro River water. The geophysical and geochemical data suggest that only the shallow alluvial aquifer and parts of the upper Aromas Sand that constitute the upper-aquifer system are being replenished by recent recharge in the coastal areas of Pajaro Valley and represent the renewable ground-water resources. These data also suggest that there is very little vertical flow through the layered aquifer systems in the coastal regions. The confining aquitards are laterally extensive but may be missing in places owing to fluvial erosion or offsetting by fault movement. Geochemical and geophysical data indicate that the ground water from some parts of the upper and lower Aromas Sand in the coastal regions was recharged thousands of years ago and may, in part, represent nonrenewable ground-water resources. The analysis of major-ion chemistry, in combination with isotope and trace-element/chloride ratios, indicates that the coastal ground-water and surface-water samples

Water-Resources Investigations Report↗
USGS2003

The effect of chamber mixing velocity on bias in measurement of sediment oxygen demand rates in the Tualatin River basin, Oregon

Three sediment oxygen demand (SOD) measurement chambers were deployed in the Tualatin River near Tigard, Oregon, at river mile 10 in August 2000. SOD rates were calculated for three different circulation velocities during each chamber deployment. The SOD rate at each velocity was calculated from a graph of dissolved oxygen concentration versus elapsed time. An acoustic doppler current profiler (ADCP) was used to measure stream discharge and near-bottom water velocities in the Tualatin at river mile 10 and at two upstream locations. Measured river and chamber velocities were similar, indicating that results from the chambers were representative of instream effects. At low to moderate chamber circulation velocities (less than about 7.5 centimeters per second), the measured SOD rate appeared to be only slightly affected by the circulation velocity, indicating that the measured rates reflect the rate of oxygen utilization by chemical and biological reactions in the sediment rather than the rate of physical transport of oxygen to the sediment-water interface. Above about 7.5 centimeters per second, however, the measured oxygen depletion rate was affected by the circulation velocity, as sufficient energy was generated within the chamber to resuspend bottom sediment, as evidenced by increased turbidity. The resuspended sediment particles contributed to the measured oxygen loss rate by increasing the surface area of decomposing material in contact with the water column, resulting in a measured SOD rate that was anomalously high. Two different alignments of the chamber circulation diffusers were tested. With both diffuser alignments, SOD rates were similar at circulation velocities low enough to avoid sediment resuspension. The same resuspension effect probably exists in the Tualatin River during storm-runoff events following prolonged periods of low flow, when increased stream velocity may result in the resuspension of bottom sediments. The resuspension causes increased turbidity and increased oxygen demand, resulting in lower instream dissolved oxygen concentrations.

Water-Resources Investigations Report↗
USGS2003

Monitoring instream turbidity to estimate continuous suspended-sediment loads and yields and clay-water volumes in the upper North Santiam River Basin, Oregon, 1998-2000

Three real-time, instream water-quality and turbidity-monitoring sites were established in October 1998 in the upper North Santiam River Basin on the North Santiam River, the Breitenbush River, and Blowout Creek, the main tributary inputs to Detroit Lake, a large, controlled reservoir that extends from river mile 61 to 70. Suspended-sediment samples were collected biweekly to monthly at each station. Rating curves provided estimated suspended-sediment concentration in 30-minute increments from log transformations of the instream turbidity monitoring data. Turbidity was found to be a better surrogate than discharge for estimating suspended-sediment concentration. Daily and annual mean suspended-sediment loads were estimated using the estimated suspended-sediment concentrations and corresponding streamflow data. A laboratory method for estimating persistent (residual) turbidity from separate turbidity samples was developed. Turbidity was measured over time for each sample. Turbidity decay curves were derived as the suspended sediment settled. Each curve was used to estimate a turbidity value for a given settling time. Medium to fine clay particle (< 0.002 mm [millimeter] diameter) settling times of 8.5 hours were computed using Stokes Law. An average of 30 persistent turbidity samples was collected from each of the 3 sites. These samples were used to estimate the 0.002-mm-size clay particle persistent turbidity for each site. The monitored instream 30-minute turbidity values were converted to a calculated persistent turbidity value that would have resulted after 8.5 hours of settling in the laboratory. Persistent turbidities of 10 NTU and above were tabulated for each site. (Water of 10 NTU and above can interfere with or damage treatment filters and result in intake closures at drinking-water facilities.) A method was developed that used the persistent turbidity experiments, turbidity decay curves, and stream discharge to estimate the volume of water containing suspended clay that entered Detroit Lake from the three main tributaries. 'Suspended-clay water' was defined as water having a value of at least 10 NTU after settling the required 8.5 hours. The suspended-clay concentrations of 10 NTU or higher were paired with the corresponding stream discharge in the continuous record. These summed discharges represent the annual volume of water containing suspended clay that entered Detroit Lake from the three main tributaries. Higher yields (load per unit area) of suspended sediment and suspended-clay water were observed from the smaller Breitenbush River and Blowout Creek subbasins than from the main-stem North Santiam River for water years 1999 and 2000. The 3-day peak streamflow and turbidity events in 1999 and 2000 carried two-thirds of the annual suspended-sediment load for the three subbasins. Turbidity and suspended-sediment concentration relations within the upper North Santiam River Basin are basin specific and can change annually within a single subbasin. Techniques developed during this study will assist water resource planners in understanding and managing water quality in their watersheds, particularly those in which there are persistent-turbidity problems.

Water-Resources Investigations Report↗
USGS2003

Klamath River Basin Hydrologic Conditions Prior to the September 2002 Die-Off of Salmon and Steelhead

More than 33,000 salmon and steelhead died in the lower Klamath River in late September 2002 on their way to spawning areas upstream. According to the California Department of Fish and Game, the cause of death was infection by protozoan and bacterial pathogens. Two factors that may have contributed to the disease incidence are low streamflow and high water temperature. September streamflows throughout the Klamath Basin were low, among the four lowest September flows recorded on the main stem since 1960. The low streamflows were caused by below-average snowpack and long-term drought, with resulting reduced ground-water discharge to streams. On the basis of historical climate data from the Klamath Basin and historical water temperature data from an adjacent basin, September 2002 water temperatures were above the long-term average. Temperatures in the Klamath River above the fish die-off reach exceeded 65 degrees Fahrenheit for nearly all of September; multiple days of exposure by fish to temperatures at or above that level can greatly increase disease incidence. This report characterizes streamflow and water temperature conditions during the period leading up to the die-off and compares them to historical conditions in the Klamath River. This report is not an exploration of the causative mechanism of the die-off; rather, it is intended to provide detailed documentation of these conditions to be used by those examining the cause(s) of the die-off and to provide information that can contribute to decisions about future water management in the Klamath Basin.

Water-Resources Investigations Report↗
USGS2004

Chemical quality of base flow in 18 selected streams in the upper Susquehanna River basin, New York

The base-flow and runoff components of total streamflow at four selected sites in the upper Susquehanna River Basin in New York were calculated through hydrograph-separation techniques from long-term (1941-93) discharge records. Base flow was found to constitute more than 60 percent of the total annual flow of each stream. Base-flow samples were then collected at 18 stream sites several times during 2001 to define the chemical quality of base flow. The concentrations of selected common ions, nutrients, and pesticides were plotted in relation to the amount of agricultural land and carbonate bedrock in the drainage basin upstream of each site. Sites were selected at locations distant from and unaffected by development and urban areas. Twelve of the sites were again sampled in November 2001 for pesticide analysis. The predominant cations detected in the samples were calcium, magnesium, and sodium; the major anions were chloride, sulfate, and bicarbonate. The predominant nutrient was nitrate. Higher nitrate concentrations in the winter samples than in the summer samples are attributed to the seasonal decrease in plant growth and microbial activity in the streams during the winter, which allows nitrate to persist in the stream water. Lower nitrate concentrations in the summer samples probably result from nitrogen uptake by vegetation and microbial activity in the streams. Base-flow samples from the agricultural, carbonate-rich northern part of the study area had higher concentrations of most inorganic chemical constituents than those from the forested, noncarbonate (shale, siltstone, and sandstone) central and southern parts. The highest nitrate concentrations were in samples from subbasins dominated by agricultural land, and the lowest were in subbasins dominated by forest. The concentrations in samples from subbasins with forested as well as agricultural land were intermediate. Six pesticides were detected in samples from 10 of the 12 sites. All were herbicides. The highest concentrations of pesticides, and the most frequent pesticide detections, were in samples from agricultural subbasins and large main-stem subbasins with mixed land use and mixed bedrock geology. A correlation was indicated between land use and concentrations of atrazine and deethylatrazine. The concentrations of all six compounds were at least an order of magnitude lower than New York State and Federal water-quality standards. Ground water from four production wells in the villages of Afton, Sidney, Unadilla, and Otego was analyzed for chlorofluorocarbons (CFCs) to indicate the approximate age of the water in these wells and the potential for induced infiltration of river water. The water at two of these wells is probably between 26 and 50 years old; the ages of water at the other two wells could not be reliably estimated because of CFC contamination from a nonatmospheric source. The two wells for which CFC analysis gave reliable results (Afton and Otego) probably do not induce infiltration of river water into the aquifer.

New York↗
USGS2003

Estimating Ground-Water Recharge from Precipitation on Whidbey and Camano Islands, Island County, Washington, Water Years 1998 and 1999

Ground-water recharge from precipitation to unconsolidated deposits on Whidbey and Camano Islands, Washington, was estimated for water years 1998-99 using a near-surface water-balance method and a chloride mass-balance method. A daily near-surface water-balance method, the Deep Percolation Model (DPM), was used to simulate water budgets for October 1, 1997 through September 30, 1999 (water years 1998-99) for six small drainage basins?four on Whidbey Island and two on Camano Island. Adjusted parameters from the DPM for each small basin were then used in island-wide DPM simulations. A spatial distribution of annual recharge was simulated for each island, with island averages of 5.71 inches per year for Whidbey Island and 5.98 inches per year for Camano Island. The spatial distribution of simulated annual recharge for each island reflects variations in precipitation amounts and the distribution of surficial materials. DPM results indicate that recharge generally is higher in areas underlain by coarse-grained deposits (outwash) than in areas underlain by fine-grained deposits (till). A chloride mass-balance method was used to estimate combined recharge to unconsolidated deposits on Whidbey and Camano Islands. The average combined recharge for Whidbey and Camano Islands estimated by this method was 2.00 inches per year. The range of chloride concentrations in ground-water samples from selected wells indicates that the average recharge to unconsolidated deposits ranges from 0.78 to 7.81 inches per year. Sources of chloride in ground water other than from the atmosphere would cause recharge estimated by the chloride mass-balance method to be less than the actual recharge, therefore, these estimates may represent lower limits.

Water-Resources Investigations Report↗
USGS2003

Sedimentation survey of Lago de Matrullas, Puerto Rico, December 2001

Lago de Matrullas reservoir, constructed in 1934, is located at an altitude of approximately 730 meters above mean sea level in the municipality of Orocovis in central Puerto Rico, and has a drainage area of 11.45 square kilometers. The reservoir is part of the Puerto Rico Electric Power Authority Toro Negro Hydroelectric Project, which also includes the Lago El Guineo reservoir and a hydroelectric plant to the south of the insular hydrographic divide. Historically, the drainage area had been protected from soil erosion by dense vegetation and the lack of basin development. However, transportation, potable water, and electric power infrastructure construction has facilitated development in rural areas resulting in the clearing of land. This trend in land-use changes is impacting the useful life of Lago de Matrullas. The reservoir storage capacity has been reduced from 3.71 million cubic meters in 1934 to 3.08 million cubic meters in 2001. This represents a total storage-capacity loss of 0.63 million cubic meters by 2001 (17 percent), or a long-term annual storage loss of 0.25 percent per year. The sediment trapping efficiency of Lago de Matrullas has been estimated at approximately 90 percent. If the current long-term sedimentation rate continues, Lago de Matrullas would fill by the year 2328. However, this life expectancy could be reduced at a faster than predicted rate as a result of rural development in the Lago de Matrullas basin and the high sediment trapping efficiency of the reservoir.

Water-Resources Investigations Report↗