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At least 1,243 records · Page 69Linked to original sources

Fractionation of families of major, minor, and trace metals across the melt-vapor interface in volcanic exhalations

Chemical families of metals fractionate systematically as they pass from a silicate melt across the interface with the vapor phase and on into a cooled volcanic plume. We measured three groups of metals in a small suite of samples collected on filters from the plumes of Kilauea (Hawaii, USA), Etna (Sicily), and Merapi (Java) volcanoes. These were the major, minor, and trace metals of the alkali and alkaline earth families (K, Rb, Cs, Ca, Sr, Ba), a group of ordinarily rare metals (Cd, Cu, In, Pb, Tl) that are related by their chalcophile affinities, and the radon daughter nuclides 210Po, 210Bi, and 210Pb. The measurements show the range and some details of systematic melt-vapor fractionation within and between these groups of metals. In the plumes of all three volcanoes, the alkali metals are much more abundant than the alkaline earth metals. In the Kilauea plume, the alkali metals are at least six times more abundant than the alkaline earth metals, relative to abundances in the melt; at Etna, the factor is at least 300. Fractionations within each family are, commonly, also distinctive; in the Kilauea plume, in addition to the whole alkaline earth family being depleted, the heaviest metals of the family (Sr, Ba) are progressively more depleted than the light metal Ca. In plumes of fumaroles at Merapi, K/Cs ratios were approximately three orders of magnitude smaller than found in other earth materials. This may represent the largest observed enrichment of the "light ion lithophile" (LIL) metals. Changes in metal ratios were seen through the time of eruption in the plumes of Kilauea and Etna. This may reflect degree of degassing of volatiles, with which metals complex, from the magma bodies. At Kilauea, the changes in fractionation were seen over about three years; fractionation within the alkaline earth family increased, and that between the two families decreased, over that time. All of the ordinarily rare chalcophile metals measured are extremely abundant in volcanic plumes, and Cd and Tl are enriched relative to the others. Indium is much more abundant in the plume of the hotspot volcano Kilauea than in the Etna plume (probably non-hotspot in character). It may be a useful indicator of the tapping of deep mantle zones, or could aid in the interpretation of reports of Pt group metals in exhalations from hot spot volcanoes. Indium in old glacial ice strata could help assess magnitude and variability of exhalations from hotspot volcanoes in past time. Strong melt-vapor fractionation of the alkali and alkaline earth metals may only be observed in plumes during quiescent degassing of volcanoes; when large amounts of ash or spatter (undifferentiated lava) enter the plume, its alkali and alkaline earth metal composition may approach that of the melt. Ratios among the chalcophile metals may not be much changed by addition of ash, because their concentrations in melt are so small, and masses of them in any plume may remain dominated by transfer across the melt-vapor interface. Radon daughter nuclides give information about state of volcanic activity at time of sampling. The precisely known origins, ultratrace detectability, decay systematics, and wide variations in volatility of these species provide information about residence times, degassing and travel histories, and identities of melt bodies in volcanic systems. ?? 1994.

Geochimica et Cosmochimica Acta↗

Compilation of mercury data and associated risk to human and ecosystem health, Bad River Band of Lake Superior Chippewa, Wisconsin

Mercury is an environmentally ubiquitous neurotoxin, and its methylated form presents health risks to humans and other biota, primarily through dietary intake. Because methylmercury bioaccumulates and biomagnifies in living tissue, concentrations progressively increase at higher trophic positions in ecosystem food webs. Therefore, the greatest health risks are for organisms at the highest trophic positions and for humans who consume organisms such as fish from these high trophic positions. Data on environmental mercury concentrations in various media and biota provide a basis for comparison among sites and regions and for evaluating ecosystem health risks. The U.S. Geological Survey, in cooperation with the Natural Resources Department, Bad River Band of Lake Superior Chippewa, have compiled a dataset from analyses of mercury concentrations in surface water, bed sediment, fish tissue, Rana clamitans (green frog) tissue, Haliaeetus leucocephalus (bald eagle) feathers, Lontra canadensis (North American river otter) hair, Zizania palustris (northern wild rice), and litterfall from samples collected in the Bad River watershed, Wisconsin during 2004–18. These data originated from either the Natural Resources Department or another agency based on samples collected within or near to Bad River Tribal lands before transfer to the U.S. Geological Survey for compilation and analysis at the onset of the project. This report describes the compiled mercury dataset, provides comparisons to similar measurements in the region and elsewhere, and evaluates health risks to humans and to the sampled biota. Except for litterfall, data were not collected on a consistent, regular basis over a sufficient period to evaluate temporal patterns. The reported mercury concentrations are generally similar to those reported elsewhere in the upper Great Lakes region. Reported values are consistent with atmospheric deposition as the principal source and reflect a favorable environment for mercury methylation. Fish mercury concentrations increased at higher food web positions and generally increased with length in most species measured. Sander vitreus (walleye) present the greatest risk to humans among fishes considered here because of their high trophic position and associated elevated mercury concentrations in combination with relatively high walleye consumption rates by the Native American community. Methylmercury concentrations in wild rice are generally low and likely pose little health risk. Despite reports of declining atmospheric mercury deposition across eastern North America during the past decade, a downward trend in litterfall mercury deposition was not evident in samples collected during 2012–18. Limitations in this data compilation and analysis were noted due to missing information such as collection dates and site locations for some samples. Regular monitoring of mercury in litterfall and surface waters along with periodic collection of fish would enable evaluation of temporal change in the mercury cycle that might affect future risk to humans and aquatic ecosystem inhabitants.

Wisconsin↗

The effect of time on the weathering of silicate minerals: Why do weathering rates differ in the laboratory and field?

The correlation between decreasing reaction rates of silicate minerals and increasing duration of chemical weathering was investigated for both experimental and field conditions. Column studies, using freshly prepared Panola Granite, produced ambient plagioclase weathering rates that decreased parabolically over 6 years to a final rate of 7.0×10 −14 mol m −2 s −1 . In contrast, the corresponding plagioclase reaction rate for partially kaolinized Panola Granite, after reaching steady-state weathering after 2 months of reactions, was significantly less (2.1×10 −15 mol m −2 s −1 ). Both rates were normalized to plagioclase content and BET surface area. Extrapolation of decreasing rates for the fresh plagioclase with time indicated that several thousand years of reaction would be required to replicate the rate of the naturally weathered plagioclase under identical experimental conditions. Both rates would remain orders of magnitude faster than field weathering rates previously measured for a weathering profile in the Panola Granite. Additional trends in weathering rates with time were established from a tabulation of previously reported experimental and field rates for plagioclase, K-feldspar, hornblende and biotite. Discrepancies in the literature, produced by normalization of weathering rates with respect to surface areas measured by gas absorption (BET) and geometric methods, were overcome by developing a time-dependent roughness factor. Regression curves through the corrected rates produced strong correlations with time that were similar for the four silicate minerals. The average silicate weathering rate R (mol m −2 s −1 ) was described by the power function R=3.1×10 −13 t −0.61 "> R=3.1×10 -13 t -0.61 which was similar to the relationship describing the decrease in the fresh Panola plagioclase with time and suggesting control by transport-limited reaction. The time dependency of silicate weathering is discussed in terms of processes intrinsic to the silicate mineral and those extrinsic to the weathering environment. Intrinsic surface area, which increases with the duration of weathering, was shown to account for a third of the exponential decrease in the weathering rate shown by the above equation. Other factors, including progressive depletion of energetically reactive surfaces and accumulation of leached layers and secondary precipitates, must explain differences for fresh and weathered plagioclase reacting under identical experimental conditions. Extrinsic controls, including low permeability, high mineral/fluid ratios and increased solute concentrations, produce weathering reactions close to thermodynamic equilibrium under field conditions compared to highly unsaturated conditions during experimental reaction of fresh and weathered plagioclase. These differences explain the time-dependent difference in field and lab rates.

Chemical Geology↗

Yellow-billed Cuckoo Distribution, Abundance, and Habitat Use Along the Lower Colorado River and Its Tributaries, 2007 Annual Report

This 2007 annual report details the second season of a 2-year study documenting western yellow-billed cuckoo (Coccyzus americanus occidentalis) distribution, abundance, and habitat use throughout the Lower Colorado River Multi-Species Conservation Program boundary area. We conducted cuckoo surveys at 40 sites within 14 areas, between 11 June and 9 September 2007. The 169 surveys across all sites yielded 163 yellow-billed cuckoo detections. Cuckoos were detected at 25 of the 40 sites, primarily at the Bill Williams River National Wildlife Refuge (NWR) study area (n = 139 detections; 85 percent of all detections). Detections declined slightly through the cuckoo breeding season, with most detections occurring in the first and second survey periods (n = 92; 54 percent). We detected breeding activity only at the Bill Williams River NWR, where we confirmed 27 breeding events, including two nesting observations. However, the breeding status of most detected birds was unknown. We used playback broadcast recordings to survey for yellow-billed cuckoos. Compared to simple point counts or surveys, this method increases the number of detections of this secretive, elusive species. It has long been suspected that cuckoos have a fairly low response rate, and that the standard survey method of using broadcast recordings might fail to detect all birds present in an area. In 2007, we found that the majority (84 percent) of cuckoo detections were solicited through broadcast at all study sites. The number of solicited detections was highest during the first survey period and declined as the breeding season progressed, while the number of unsolicited detections (cuckoos heard calling before broadcast was initiated) remained fairly constant through the first, second, and third survey periods. The majority (66 percent) of cuckoo detections, solicited or unsolicited, were aural, 23 percent were both heard and seen, and 11 percent were visual detections only. We also found that 50 percent of all responses by cuckoos were evenly split between the first and second broadcasts at sites with >10 detections, while 45 percent of responses occurred after a single broadcast at the sites with <10 detections. We refined our collection of vegetation data in 2007 and found that across the entire study area the dominant tree species were tamarisk (Tamarix spp.), willow (Salix spp.), and cottonwood (Populus spp.). The smallest size class (<8 cm diameter at breast height) trees were the most common and were dominated by tamarisk, but cottonwood and willows were well represented in the larger size classes. Sites that were occupied by yellow-billed cuckoos generally had higher canopies, denser cover in the upper layers of the canopy, and sparse shrub layers compared to unoccupied sites that consistently had higher densities of woody species. As most occupied sites were within the Bill Williams River NWR and most unoccupied sites were at Grand Canyon National Park/Lake Mead National Recreation Area, vegetation characteristics at these study areas drove the cuckoo distribution patterns we observed in 2007. However, there was a range of habitat conditions in locations that were used by yellow-billed cuckoos across the entire lower Colorado River Multi-Species Conservation Program study area. We measured microclimate variables (temperature, relative humidity, soil moisture) at occupied and unoccupied sites, and found that, across the entire study area, occupied sites were consistently cooler during the day and more humid during the day and night compared to unoccupied sites, but that soil moisture did not differ between occupied and unoccupied sites. While most cuckoo detections occurred at Bill Williams River NWR, with generally cooler and more humid conditions, cuckoos were also detected at study areas that had hotter and dryer microclimate conditions. We did not find any relationship of canopy cover characteristics to temperature or soil moisture, suggesting

Open-File Report↗

Structural evolution of a gold-bearing transtensional zone within the Archean Porcupine-Destor deformation zone, southern Abitibi greenstone belt, eastern Ontario, Canada

The Garrison camp comprises four structurally distinct orogenic gold deposits that formed in different host lithologies during progressive deformation. Detailed field mapping, drill core logging, and geochronological constraints suggest that the 2678 ± 2 Ma Garrison granitic stock played a fundamental rheological role in the location of the four deposits. Initial local shear movement occurred along the southwestern margin of the stock leading to the development of the NW-trending sinistral NE-side-up Buffonta shear zone, which hosts the Buffonta deposit. Subsequently, a transtensional zone formed between the NE-trending sinistral Porcupine-Destor and Munro deformation zones, which host the 903 and Jonpol deposits, respectively. Finally, a local change in shortening orientation from NE to NNW caused westerly directed extension resulting in the formation of the younger gold-bearing veins composing the Garrcon deposit. In situ U-Pb laser ablation-inductively coupled plasma-mass spectrometry performed on monazite grains formed within the shear fabric of the Munro deformation zone indicates that transtension occurred at 2657 ± 15 Ma. Therefore, at least three of the four deposits formed subsequent to crystallization of the Garrison granitic stock. The reported U-Pb dates represent the first direct age constraints on the movement along a gold-bearing deformation zone in the southern Abitibi greenstone belt.

Ontario↗

Reconnaissance borehole geophysical, geological, and hydrological data from the proposed hydrodynamic compartments of the Culpeper Basin in Loudoun, Prince William, Culpeper, Orange, and Fairfax Counties, Virginia

The Culpeper basin is part of a much larger system of ancient depressions or troughs, that lie inboard of the Atlantic Coastal Plain, and largely within the Applachian Piedmont Geologic Province of eastern North America, and the transition region with the neighboring Blue Ridge Geologic Province. This basin system formed during an abortive attempt to make a great ocean basin during the Late Triassic and Early Jurassic, and the eroded remnants of the basins record major episodes of sedimentation, igneous intrusion and eruption, and pervasive contact metamorphism. Altogether, some twenty nine basins formed between what is now Nova Scotia and Georgia. Many of these basins are discontinuous along their strike, and have therefore recorded isolated environments for fluvial and lacustrine sedimentation. Several basins (including the Culpeper, Gettysburg, and Newark basins) are fault-bounded on the west, and Mesozoic crustal stretching has produced assymetrical patterns of basin subsidence resulting in a progressive basin deepening to the west, and a virtual onlap relationship with the pre-basin Proterozoic rocks to the east. A result of such a pattern of basin deepening is the development of sequences of sandstones and siltstones that systemmatically increase in dip towards the accomodating western border faults. A second major structural theme in several of the major Mesozoic basins (including the Culpeper) concerns the geometry of igneous intrusion, as discussed below. Froelich (1982, 1985) and Lee and Froelich (1989) discuss the general geology of the Culpeper basin, and Smoot (1989) discusses the sedimentation environments and sedimentary facies of the Mesozoic with respect to fluvial and shallow lacustrine deposition in the Culpeper basin. Ryan and others, 2007a, b, discuss the role of diabase-induced compartmentalization in the Culpeper basin (and other Mesozoic basins), and illustrate (using alteration mineral suites within the diabase and adjacent hornfels, among other evidence) how this process has played a role in organizing the paleo- and contemporary-flow of crustal fluids at local and regional scales. Within this report, the Newark Supergroup nomenclature of Weems and Olsen (1997) is adopted.

Virginia↗

Faunal and stable isotopic analyses of benthic foraminifera from the Southeast Seep on Kimki Ridge offshore southern California, USA

We investigated the benthic foraminiferal faunal and stable carbon and oxygen isotopic composition of a 15-cm push core (NA075-092b) obtained on a Telepresence-Enabled cruise to the Southeast Seep on Kimki Ridge offshore southern California. The seep core was taken at a depth of 973 m in the vicinity of a Beggiatoa bacterial mat and vesicomyid clams (Calyptogena) and compared to previously published data of living assemblages from ~ 714 m, four reference cores obtained at ~ 1030 m, and another one at 739 m. All of the reference sites are also from the Inner Continental Borderland but with no evidence of methane seepage. No endemic species were found at the seep site and most of the taxa recovered there have been reported previously from other seep or low oxygen environments. Q- and R-mode cluster analyses clearly illustrated differences in the faunal assemblages o f the seep and non-seep sites. The living assemblage at Southeast Seep was characterized by abundant Takayanagia delicata, Cassidulina translucens, and Spiroplectammina biformis , whereas the non-seep San Pedro Basin reference assemblage was comprised primarily of Chilostomella oolina and Globobulimina pacifica . Density and species richness we re lower at the seep site compared to the non-seep site, reflecting the harsher living conditions there. The dead assemblage at the seep site was dominated by Gyroidina turgida compared to Cassidulina translucens at the ~ 1030 m non-seep site and Cassidulina translucens, Pseudoparrella pacifica, and Takayanagia delicata at the 739 m non-seep site. Density was three times lower at Southeast Seep than at the non-seep sites of comparable water depth but species richness was ~ 30% higher. Stable carbon isotopic values were considerably depleted in the seep samples compared to the non-seep samples, with a progression from lightest to heaviest average δ 13 C values evident at the seep site reflecting microhabitat preference and vital effect: the deep infaunal species of Globobulimina , the shallow infaunal species Uvigerina peregrina , the epifaunal species Cibicidoides wuellerstorfi , and the shallow infaunal but aragonite-shelled species Hoeglundina elegans . The δ 13 C values downcore among each benthic species indicates ongoing fluid seepage through at least the last 3800 cal yr B.P. at Southeast Seep. Besides the continual local seepage, evidence from δ 13 C values of planktic foraminifera in the seep core suggest two pulses of methane (at 3000 and 3700 cal yr B.P.) were released that were large enough to influence much of the water column. Paired benthic and planktic foraminiferal stable oxygen isotope records provide evidence that there were no paleoenvironmental changes such as increased bottom-water temperature or changes in oxygen isotopic composition of bottom and pore waters during this 3800-year record to induce the methane releases. Instead, Southeast Seep appears to be the result of local faulting providing pathways for fluid to flow to the seafloor at a fault stepover or transpressional bend in the regional strike-slip system.

California↗

Bed-material entrainment potential, Roaring Fork River at Basalt, Colorado

The Roaring Fork River at Basalt, Colorado, has a frequently mobile streambed composed of gravel, cobbles, and boulders. Recent urban and highway development on the flood plain, earlier attempts to realign and confine the channel, and flow obstructions such as bridge openings and piers have altered the hydrology, hydraulics, sediment transport, and sediment deposition areas of the Roaring Fork. Entrainment and deposition of coarse sediment on the streambed and in large alluvial bars have reduced the flood-conveying capacity of the river. Previous engineering studies have identified flood-prone areas and hazards related to inundation and high streamflow velocity, but those studies have not evaluated the potential response of the channel to discharges that entrain the coarse streambed. This study builds upon the results of earlier flood studies and identifies some potential areas of concern associated with bed-material entrainment. Cross-section surveys and simulated water-surface elevations from a previously run HEC?RAS model were used to calculate the boundary shear stress on the mean streambed, in the thalweg, and on the tops of adjacent alluvial bars for four reference streamflows. Sediment-size characteristics were determined for surficial material on the streambed, on large alluvial bars, and on a streambank. The median particle size (d50) for the streambed samples was 165 millimeters and for the alluvial bars and bank samples was 107 millimeters. Shear stresses generated by the 10-, 50-, and 100-year floods, and by a more common flow that just inundated most of the alluvial bars in the study reach were calculated at 14 of the cross sections used in the Roaring Fork River HEC?RAS model. The Shields equation was used with a Shields parameter of 0.030 to estimate the critical shear stress for entrainment of the median sediment particle size on the mean streambed, in the thalweg, and on adjacent alluvial bar surfaces at the 14 cross sections. Sediment-entrainment potential for a specific geomorphic surface was expressed as the ratio of the flood-generated boundary shear stress to the critical shear stress (to/tc) with respect to two threshold conditions. The partial entrainment threshold (to/tc=1) is the condition where the mean boundary shear stress (to) equals the critical shear stress for the median particle size (tc) at that cross section. At this threshold discharge, the d50 particle size becomes entrained, but movement of d50-size particles may be limited to a few individual particles or in a small area of the streambed surface. The complete entrainment threshold (to/tc=2) is the condition where to is twice the critical shear stress for the median particle size, the condition where complete or widespread mobilization of the d50 particle-size fraction is anticipated. Entrainment potential for a specific reference streamflow varied greatly in the downstream direction. At some cross sections, the bed or bar material was mobile, whereas at other cross sections, the bed or bar material was immobile for the same discharge. The significance of downstream variability is that sediment entrained at one cross section may be transported into, but not through, a cross section farther downstream, a situation resulting in sediment deposition and possibly progressive aggradation and loss of channel conveyance. Little or no sediment in the d50-size range is likely to be entrained or transported through much of the study reach by the bar-inundating streamflow. However, the entrainment potential at this discharge increases abruptly to more than twice the critical value, then decreases abruptly, at a series of cross sections located downstream from the Emma and Midland Avenue Bridges. Median particle-size sediment is mobile at most cross sections in the study reach during the 10-year flood; however, the bed material is immobile at cross sections just upstream from the Upper Bypass and Midland Avenue Bridges. A similar s

Water-Resources Investigations Report↗

An opportunity and an imperative: Chapter 11 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

Along the nearly 3,200 kilometers (almost 2,000 miles) of the United States–Mexican border, we are witnessing the expression of the challenges of the 21st century. The Borderlands have become a microcosm for the entire United States and Mexico; the issues faced in that region are felt throughout both nations—water availability and quality, ecosystem health, natural resource needs, safety from natural hazards, and human socioeconomic well-being. If these issues were not challenging enough, we now recognize that the difficulties of addressing them are exacerbated by the onset of climate change, and as we come to better understand the complexities of the components of these challenge themes, we discover that each part is inextricably intertwined with other overarching issues. Further, because we are a creative and progressive society, we all seek to understand and appreciate the natural environments associated with the Borderlands while at the same time benefitting from the region’s many social and economic values. It is little wonder that we as a society find it increasingly difficult to ask the right questions, much less find suitable answers to the questions we do ask. For the many scientists who have worked in the Borderlands and contributed to the preceding chapters, this circular is a way to describe to the two nations of the region the capabilities the U.S. Geological Survey can provide to assist in that quest for knowledge and understanding in preparation for the future.

United States-Mexico Borderlands↗

Overview and progress of the pallid sturgeon assessment framework redesign process

The Pallid Sturgeon Population Assessment Program (PSPAP) was initiated in 2003, and full implementation began in 2006, to monitor the trend of Scaphirhynchus albus (pallid sturgeon) and native fish communities in the Upper and Lower Missouri River Basins. The original PSPAP (v. 1.0) was a catch-effort based monitoring program where population abundance and trend were monitored using a relative index, catch per unit effort. In 2013, the Missouri River Recovery Program (MRRP), led by the U.S. Army Corps of Engineers (USACE) and the U.S. Fish and Wildlife Service (USFWS), began a reassessment of science and monitoring approaches to support a new river management plan. The need to redesign the PSPAP was triggered by the recognition that the PSPAP v. 1.0 would not be optimally effective in contributing information needed to make decisions about the pallid sturgeon fundamental management objective—to avoid jeopardizing the continued existence of the pallid sturgeon from USACE actions in the Missouri River—identified in the Missouri River Science and Adaptive Management Plan. The fundamental management objective includes two management subobjectives: (1) increase pallid sturgeon recruitment to age 1 and (2) maintain or increase numbers of pallid sturgeon as an interim measure until sufficient and sustained natural recruitment occurs. These two management subobjectives motivated the development of two fundamental information objectives for PSPAP v. 2.0: (1) to provide information needed to quantify recruitment to age 1 and (2) to quantify pallid sturgeon population abundance and trend. The charge to the authors of this report was to develop an approach to monitoring the pallid sturgeon population in the Missouri River that would contribute information toward gauging overall performance of management actions to achieve the fundamental objectives of the MRRP and to potentially improve understanding of linkages from the management activities to population responses. We used transparent and robust processes to identify alternative monitoring designs that meet the fundamental objectives for managing pallid sturgeon in the MRRP, with a focus on simulation models to evaluate the performance of varying monitoring. This report documents the process of comparing potential alternative monitoring design abilities to provide decision-relevant information for management of the species. The process includes evaluation of information content and attendant uncertainties and considers tradeoffs in types of information valued by stakeholders. The anticipated end product of this process will be synthesized in a decision-support tool that can be used to facilitate learning and iterative revisions of the monitoring roadmap.

Open-File Report↗

Ecological Requirements for Pallid Sturgeon Reproduction and Recruitment in the Lower Missouri River: A Research Synthesis 2005-08

This report provides a synthesis of results obtained between 2005 and 2008 from the Comprehensive Sturgeon Research Program, an interagency collaboration between the U.S. Geological Survey, Nebraska Game and Parks Commission, U.S. Fish and Wildlife Service, and the U.S. Army Corps of Engineers' Missouri River Recovery - Integrated Science Program. The goal of the Comprehensive Sturgeon Research Program is to improve fundamental understanding of reproductive ecology of the pallid sturgeon with the intent that improved understanding will inform river and species management decisions. Specific objectives include: *Determining movement, habitat-use, and reproductive behavior of pallid sturgeon; *Understanding reproductive physiology of pallid sturgeon and relations to environmental conditions; *Determining origin, transport, and fate of drifting pallid sturgeon larvae, and evaluating bottlenecks for recruitment of early life stages; *Quantifying availability and dynamics of aquatic habitats needed by pallid sturgeon for all life stages; and *Managing databases, integrating understanding, and publishing relevant information into the public domain. Management actions to increase reproductive success and survival of pallid sturgeon in the Lower Missouri River have been focused on flow regime, channel morphology, and propagation. Integration of 2005-08 Comprehensive Sturgeon Research Program research provides insight into linkages among flow regime, re-engineered channel morphology, and pallid sturgeon reproduction and survival. The research approach of the Comprehensive Sturgeon Research Program integrates opportunistic field studies, field-based experiments, and controlled laboratory studies. The field study plan is designed to explore the role of flow regime and associated environmental cues using two complementary approaches. An upstream-downstream approach compares sturgeon reproductive behavior between an upstream section of the Lower Missouri River with highly altered flow regime to a downstream section that maintains much of its pre-regulation flow variability. The upstream section also has the potential for an experimental approach to compare reproductive behavior in years with pulsed flow modifications ('spring rises') to years without. The reproductive cycle of the female sturgeon requires several years to progress through gonadal development, oocyte maturation, and spawning. Converging lines of evidence support the hypothesis that maturation and readiness to spawn in female sturgeon is cued many months before spawning. Information on reproductive readiness of shovelnose sturgeon indicates that sturgeon at different locations along the Lower Missouri River between St. Louis and Gavins Point Dam are all responding to the same early cue. Although not a perfect surrogate, the more abundant shovelnose sturgeon is morphologically, physiologically, and genetically similar to pallid sturgeon, and thereby provides a useful comparative model for the rarer species. Day length is the likely candidate to define a temporal spawning window. Within the spawning window, one or more additional, short-term, and specific cues may serve to signal ovulation and release of gametes. Of three potential spawning cues - water temperature, water discharge, and day of year - water temperature is the most likely proximate cue because of the fundamental physiological role temperature plays in sturgeon embryo development and survival, and the sensitivity of many fish hormones to temperature change. It also is possible that neither temperature nor discharge is cueing spawning; instead, reproductive behavior may result from the biological clock advancing an individual fish's readiness to spawn day after day through the spawning period until the right moment, independent of local environmental conditions. Separation of the individual effects of discharge events, water temperature, and other possible factors, such as proximity to male

Scientific Investigations Report↗

Coeur d’Alene Basin Environmental Monitoring Program, surface water, northern Idaho—Annual data summary, water year 2017

Streams within the Coeur d’Alene River drainage basin in northern Idaho have been extensively affected by historical mining activities and are subject to ongoing remedial actions as part of the Bunker Hill Mining & Metallurgical Complex Superfund Site. The U.S. Geological Survey (USGS) operates 12 real-time streamgages and collects surface-water-quality samples two to four times annually at 20 sites in the Spokane River and Coeur d’Alene River drainage basins. These data are used by the U.S. Environmental Protection Agency (USEPA) to monitor cleanup progress and to support decisions related to implementing remedial actions throughout the basin. USGS data collection highlights from water year 2017 include: • A rain-on-snow event in March 2017 produced high streamflows and flooding in the basin. • The March event mobilized high concentrations of total metals (cadmium, lead, zinc, and others) in the Coeur d’Alene River near Cataldo, at Rose Lake, and near Harrison; these concentrations were among the highest that have been measured at these sites during flood events sampled by the USGS. • Total lead and dissolved zinc and cadmium concentrations decreased in Canyon Creek in 2017 when compared with water years 2007–16; in contrast, concentrations of dissolved zi

Idaho↗

Initial-phase investigation of multi-dimensional streamflow simulations in the Colorado River, Moab Valley, Grand County, Utah, 2004

A multi-dimensional hydrodynamic model was applied to aid in the assessment of the potential hazard posed to the uranium mill tailings near Moab, Utah, by flooding in the Colorado River as it flows through Moab Valley. Discharge estimates for the 100- and 500-year recurrence interval and for the Probable Maximum Flood (PMF) were evaluated with the model for the existing channel geometry. These discharges also were modeled for three other channel-deepening configurations representing hypothetical scour of the channel at the downstream portal of Moab Valley. Water-surface elevation, velocity distribution, and shear-stress distribution were predicted for each simulation. The hydrodynamic model was developed from measured channel topography and over-bank topographic data acquired from several sources. A limited calibration of the hydrodynamic model was conducted. The extensive presence of tamarisk or salt cedar in the over-bank regions of the study reach presented challenges for determining roughness coefficients. Predicted water-surface elevations for the current channel geometry indicated that the toe of the tailings pile would be inundated by about 4 feet by the 100-year discharge and 25 feet by the PMF discharge. A small area at the toe of the tailings pile was characterized by velocities of about 1 to 2 feet per second for the 100-year discharge. Predicted velocities near the toe for the PMF discharge increased to between 2 and 4 feet per second over a somewhat larger area. The manner to which velocities progress from the 100-year discharge to the PMF discharge in the area of the tailings pile indicates that the tailings pile obstructs the over-bank flow of flood discharges. The predicted path of flow for all simulations along the existing Colorado River channel indicates that the current distribution of tamarisk in the over-bank region affects how flood-flow velocities are spatially distributed. Shear-stress distributions were predicted throughout the study reach for each discharge and channel geometry examined. Material transport was evaluated by applying these shear-stress values to empirically determined critical shear-stress values for grain sizes ranging from very fine sands to very coarse gravels.

Utah↗

Water and Streambed Sediment Quality, and Ecotoxicology of a Stream along the Blue Ridge Parkway, Adjacent to a Closed Landfill, near Roanoke, Virginia: 1999

A study was done of the effects of a closed landfill on the quality of water and streambed sediment and the benthic macroinvertebrate community of an unnamed stream and its tributary that flow through Blue Ridge Parkway lands in west-central Virginia. The primary water source for the tributary is a 4-inch polyvinyl chloride (PVC) pipe that protrudes from the slope at the base of the embankment bordering the landfill. An unusual expanse of precipitate was observed in the stream near the PVC pipe. Stream discharge was measured and water and streambed sediment samples were collected at a nearby reference site and at three sites downstream of the landfill in April and September 1999. Water samples were analyzed for major ions, nitrate, total and dissolved metals, total dissolved solids, total organic carbon, and volatile and semivolatile organic compounds, including organochlorine pesticides and polychlorinated biphenyls (PCBs). Streambed sediment samples were analyzed for total metals, total organic carbon, percent moisture, and volatile and semivolatile organic compounds, including organochlorine pesticides and PCBs. The benthic macroinvertebrate community within the stream channel also was sampled at the four chemical sampling sites and at one additional site in April and September. Each of the five sites was assessed for physical habitat quality. Water collected periodically at the PVC pipe discharge between November 1998 and November 1999 was used to conduct 48-hour acute and 7-day chronic toxicity tests using selected laboratory test organisms. Two 10-day chronic toxicity tests of streambed sediments collected near the discharge pipe also were conducted. Analyses showed that organic and inorganic constituents in water from beneath the landfill were discharged into the sampled tributary. In April, 79 percent of inorganic constituents detected in water had their highest concentrations at the site closest to the landfill; at the same site, 59 percent of inorganic constituents detected in streambed sediments were at their lowest concentration. The low dissolved-oxygen concentration and relatively low pH in ground water from beneath the landfill probably had a direct effect on the solubility of metals and other constituents, resulting in the high concentration of inorganic constituents in water, low concentration in sediment, and the development of the precipitate. Most constituents in water in April were progressively lower in concentration from the landfill site downstream. The highest concentrations for 59 percent of constituents detected in sediment were at the farthest downstream site, suggesting that the inorganic constituents came out of solution as the stream water was exposed to the atmosphere. In September, 52 percent of inorganic constituents detected in water were at their highest concentrations at the site nearest the landfill. Of inorganic constituents detected in streambed sediments in September, 60 percent were at their highest concentrations near the landfill. A storm that occurred a few days prior to the September sampling probably affected the preceding steady-state conditions and the distribution of constituents in sediment along the stream. Concentrations of many inorganic constituents in water remained elevated at the farthest downstream site in comparison to the reference site in April and September, indicating that concentrations did not return to background concentrations. In April and September, most of the 17 organic compounds detected in water, including volatile organic and semivolatile organic compounds, were collected in samples near the landfill, and most concentrations were below their respective reporting limits. Probably because of their volatility, few organic compounds were detected at sites downstream of that site. A total of 17 discrete organic compounds were detected in sediment samples in either April or September, including trichloroethene and tetrachloroethene along with their degrad

Water-Resources Investigations Report↗

Geologic map of the Vigo NE quadrangle, Lincoln County, Nevada

This map of the Vigo NE quadrangle, Lincoln County, Nevada records the distribution, stratigraphy, and structural relationships of Tertiary intracaldera lavas and tuffs in the southeastern part of the Kane Springs Wash caldera, extracaldera Tertiary and upper Paleozoic rocks, and late Cenozoic surficial deposits both within and outside the caldera. The alkaline to peralkaline Kane Springs Wash caldera is the youngest (14 Ma) of three chemically related metaluminous to peralkaline calderas (Boulder Canyon caldera, 15 Ma; Narrow Canyon caldera, 16 Ma) of the nested Kane Springs Wash caldera complex. The chemistry of this caldera complex became progressively more alkalic with time, in contrast to the older calc-alkalic calderas and caldera complexes to the north that migrated progressively southward in eastern Nevada. The increasingly peralkaline eruptions from the Kane Springs Wash caldera complex reached a climax that was simultaneous with the end of both rapid extension and magmatism in this part of the Basin and Range. Using the assumption that degree of tilting is related to the degree of extension, the rate of extension increased until the abrupt halt at about 14 Ma. Silicic volcanism terminated at the Kane Springs Wash caldera followed only by local sporadic basaltic eruptions that ended by about 8 Ma. The northern boundary of an east-west-trending amagmatic corridor appears in the Vigo NE quadrangle south of the Kane Springs Wash caldera.

Scientific Investigations Map↗

Plasma chloride and gill epithelial response of channel catfish to infection with Ichthyophthirius multifillis

Because infection with Ichthyophthirius multifiliis has been reported to result in osmotic stress, genesis of the plasma chloride and chloride cell response of channel catfish Ictalurus punctatus to the infection was studied from day 0 to day 7 postexposure (PE). Parasite population densities ranged from 0.08 to 0.22 trophonts per gill filament during days 1–5 PE and increased to 2.1 at day 7 PE. Population increases were the result of infection by a new generation of infective theronts and reproduction by the parasite on the host. Mean plasma chloride concentrations of fish were not significantly different among days 0–5 PE (range of means, 93.01–97.87 meq/L), but by day 7 PE the mean had declined significantly, to 83.73 meq/L. Maintenance of relatively stable plasma chloride concentrations for 5 d was associated with chloride cell proliferation. The number of interlamellar filament chloride cells had significantly increased by day 1 PE, and the number of chloride cells in the lamellae had significantly increased by day 5 PE. No further increase had occurred by day 7 PE. Vacuolization of chloride cells, examined by electron microscopy, became more common as infection progressed, and many chloride cells appeared to be degenerating by day 5 PE.

Journal of Aquatic Animal Health↗

Toward a four-dimensional petrogenetic model of a distributed volcanic field on the southern edge of the Colorado Plateau

A detailed characterization of the >3,000 square kilometer (km 2 ) Springerville volcanic field, located on the southern tip of the Colorado Plateau in Arizona, United States, with its more than 501 volcanic units and widely distributed >420 cinder cones and lava flows, provides constraints toward an integrated petrogenetic model for the field. Large-volume effusive tholeiitic eruptions at 2–1.5 mega-annum (Ma) transitioned to more numerous, smaller volume alkali olivine basalt (AOB) events at 1.5–1.0 Ma, with increasing abundances of evolved alkalic rocks (EARs), and a final 1.0–0.3 Ma period dominated by smaller volume, more explosive alkalic eruptions. Early large-scale melting in a relatively enriched lithospheric mantle (EM) source generated large-volume effusive tholeiitic magmas. Depths of tholeiite magma generation average about 90 kilometers (km) across the field, but depths for individual units decreased southward, consistent with lithospheric thinning toward the Colorado Plateau margin. Early and middle-stage transitional basalts, alkali olivine basalts (AOBs), and basanites originate from a progressively deeper (>100 km) region in a prevalent mantle (PREMA)-like asthenospheric source produced by increasingly smaller degrees of melting, as low as about 2 percent. The chemical signature of the basanites is consistent with small degrees of melting in a carbonated, asthenospheric source to depths of about 140 km. As heat waned, the last phase of volcanism was dominated by more explosive EARs derived at shallower lithospheric pressures but that have isotopic and trace element similarities to the deeper asthenospheric magmas. This suggests mixing between deeper basanitic and shallower tholeiitic magmas. With waning heat, eruptions became more localized along alignments, likely related to boundaries between blocks of Proterozoic crust with differing properties that affected magma ascent. The petrogenetic patterns are consistent with a variety of processes. Basin and Range Province extension, melting, and heat-induced weakening progressively eroded the Colorado Plateau’s thicker lithosphere, giving rise to relatively high degrees of partial melting from shallower (<90 km) sources that produced the early large volumes of effusive tholeiitic magma. Possible lithosphere delamination and removal, and a resulting steep boundary step with the asthenosphere, may have given rise to mantle edge convection, resulting in the mixing of basanitic and tholeiitic magmas. With plate motion, shear-driven upwelling likely gave an eastward component to convection, affecting relative amounts of melting at the field’s western boundary and corresponding with volcanism moving eastward during times of peak vent production by eruption of alkalic lavas, giving rise to more explosive and lower volume eruptions.

Arizona, New Mexico↗

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio↗