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Executive summary. In Second State of the Carbon Cycle Report (SOCCR2): A Sustained Assessment Report

Central to life on Earth, carbon is essential to the molecular makeup of all living things and plays a key role in regulating global climate. To understand carbon’s role in these processes, researchers measure and evaluate carbon stocks and fluxes. A stock is the quantity of carbon contained in a pool or reservoir in the Earth system (e.g., carbon in forest trees), and a flux is the direction and rate of carbon’s transfer between pools (e.g., the movement of carbon from the atmosphere into forest trees during photosynthesis). This document, the Second State of the Carbon Cycle Report (SOCCR2), examines the patterns of carbon stocks and fluxes—collectively called the “carbon cycle.” Emphasis is given to these patterns in specific sectors (e.g., agriculture and energy) and ecosystems (e.g., forests and coastal waters) and to the response of the carbon cycle to human activity. The purpose of SOCCR2 is to assess the current state of the North American carbon cycle and to present recent advances in understanding the factors that influence it. Concentrating on North America—Canada, the United States, and Mexico—the report describes carbon cycling for air, land, inland waters (streams, rivers, lakes, and reservoirs), and coastal waters (see Figure ES.1, p. 23). The questions framing the publication A U.S. Carbon Cycle Science Plan (Michalak et al., 2011) inspired development of three slightly modified questions that guide SOCCR2’s content and focus on North America in a global context: How have natural processes and human actions affected the global carbon cycle on land, in the atmosphere, in the ocean and other aquatic systems, and at ecosystem interfaces (e.g., coastal, wetland, and urban-rural)? How have socioeconomic trends affected atmospheric levels of the primary carbon-containing gases, carbon dioxide (CO2) and methane (CH4)? How have species, ecosystems, natural resources, and human systems been impacted by increasing greenhouse gas (GHG) concentrations, associated changes in climate, and carbon management decisions and practices? SOCCR2 synthesizes the most recent understanding of carbon cycling in North America, assessing new carbon cycle findings and information, the state of knowledge regarding core methods used to study the carbon cycle, and future research needed to best inform carbon management and policy options. Focusing on scientific developments in the decade since the First State of the Carbon Cycle Report (SOCCR1; CCSP 2007), SOCCR2 summarizes the past, current, and projected state of carbon sources, sinks, and natural processes, as well as contributions by human activities. In addition to CO2 and CH4, the report sometimes discusses nitrous oxide (N2O), a GHG associated with activities and processes that affect fluxes of carbon gases.1 SOCCR2 also describes improvements in analysis tools; developments in decision support; and new insights into ecosystem carbon cycling, human causes of changes in the carbon cycle, and social science perspectives on carbon. Since publication of SOCCR1, coordinated research from agencies in the three North American countries has enabled innovative observational, analytical, and modeling capabilities to further advance understanding of the North American carbon cycle (see Appendix D: Carbon Measurement Approaches and Accounting Frameworks, p. 834). Some of the report’s main conclusions, based on the Key Findings of each chapter, are highlighted in Box ES.1, Main Findings of SOCCR2, p. 24.

Report↗

Regional groundwater-flow model of the Lake Michigan Basin in support of Great Lakes Basin water availability and use studies

A regional groundwater-flow model of the Lake Michigan Basin and surrounding areas has been developed in support of the Great Lakes Basin Pilot project under the U.S. Geological Survey's National Water Availability and Use Program. The transient 2-million-cell model incorporates multiple aquifers and pumping centers that create water-level drawdown that extends into deep saline waters. The 20-layer model simulates the exchange between a dense surface-water network and heterogeneous glacial deposits overlying stratified bedrock of the Wisconsin/Kankakee Arches and Michigan Basin in the Lower and Upper Peninsulas of Michigan; eastern Wisconsin; northern Indiana; and northeastern Illinois. The model is used to quantify changes in the groundwater system in response to pumping and variations in recharge from 1864 to 2005. Model results quantify the sources of water to major pumping centers, illustrate the dynamics of the groundwater system, and yield measures of water availability useful for water-resources management in the region. This report is a complete description of the methods and datasets used to develop the regional model, the underlying conceptual model, and model inputs, including specified values of material properties and the assignment of external and internal boundary conditions. The report also documents the application of the SEAWAT-2000 program for variable-density flow; it details the approach, advanced methods, and results associated with calibration through nonlinear regression using the PEST program; presents the water-level, drawdown, and groundwater flows for various geographic subregions and aquifer systems; and provides analyses of the effects of pumping from shallow and deep wells on sources of water to wells, the migration of groundwater divides, and direct and indirect groundwater discharge to Lake Michigan. The report considers the role of unconfined conditions at the regional scale as well as the influence of salinity on groundwater flow. Lastly, it describes several categories of limitations and discusses ways of extending the regional model to address issues at the local scale. Results of the simulations portray a regional groundwater-flow system that, over time, has largely maintained its natural predevelopment configuration but that locally has been strongly affected by well withdrawals. The quantity of rainfall in the Lake Michigan Basin and adjacent areas supports a dense surface-water network and recharge rates consistent with generally shallow water tables and predominantly shallow groundwater flow. At the regional scale, pumping has not caused major modifications of the shallow flow system, but it has resulted in decreases in base flow to streams and in direct discharge to Lake Michigan (about 2 percent of the groundwater discharged and about 0.5 cubic foot per second per mile of shoreline). On the other hand, well withdrawals have caused major reversals in regional flow patterns around pumping centers in deep, confined aquifers - most noticeably in the Cambrian-Ordovician aquifer system on the west side of Lake Michigan near the cities of Green Bay and Milwaukee in eastern Wisconsin, and around Chicago in northeastern Illinois, as well as in some shallow bedrock aquifers (for example, in the Marshall aquifer near Lansing, Mich.). The reversals in flow have been accompanied by large drawdowns with consequent local decrease in storage. On the west side of Lake Michigan, groundwater withdrawals have caused appreciable migration of the deep groundwater divides. Before the advent of pumping, the deep Lake Michigan groundwater-basin boundaries extended west of the Lake Michigan surface-water basin boundary, in some places by tens of miles. Over time, the pumping centers have replaced Lake Michigan as the regional sink for the deep flow system. The regional model is intended to support the framework pilot study of water availability and use for the Great Lakes Basin (Reeves, in press).

Illinois, Indiana, Michigan, Wisconsin↗

2014 National Park visitor spending effects: economic contributions to local communities, states, and the nation

The National Park System covers more than 84 million acres and is comprised of more than 401 sites across the Nation. These lands managed by the National Park Service (NPS) serve as recreational destinations for visitors from across the Nation and around the world. On vacations or on day trips, NPS visitors spend time and money in the gateway communities surrounding NPS sites. Spending by NPS visitors generates and supports a considerable amount of economic activity within park gateway economies. The NPS has been measuring and reporting visitor spending and economic effects for the past 25 years. The 2012 analysis marked a major revision to the NPS visitor spending effects analyses, with the development of the Visitor Spending Effects model (VSE model) which replaced the previous Money Generation Model (see Cullinane Thomas et al. (2014) for a description of how the VSE model differs from the previous model). This report provides updated VSE estimates associated with 2014 NPS visitation. System-wide visitation estimates in 2014 increased by 7% (or 19.2 million visits) compared to 2013 (Ziesler, 2015). Visitation in 2014 rebounded from a 2013 decline that included a 16-day government shutdown and many park closures for repairs after Superstorm Sandy hit the Northeast in late 2012. The re-opening of the Washington Monument, some 21 months after it was rocked by an earthquake and repaired, also added to 2014 visitation numbers. Additionally, several national parks saw record-breaking visitation in 2014, including Joshua Tree, Rocky Mountain, Grand Teton and Glacier national parks. This report begins by presenting an overview of economic effects analyses, followed by details about the data and methods used for this analysis and 2014 model updates. Estimates of NPS visitor spending in 2014 and resulting economic effects at the local, state, regional, and national levels are then presented. The report concludes with a description of current data limitations. Park-level spending and economic effects estimates are included in the appendix. New this year, results from the Visitor Spending Effects report series are available online via an interactive tool. Users can explore current year visitor spending, jobs, labor income, value added, and output effects by sector for national, state, and local economies. This interactive tool is available via the NPS Social Science Program webpage at http://www.nature.nps.gov/socialscience/economics.cfm.

Natural Resource Report↗

A synoptic examination of causes of land loss in southern Louisiana as related to the exploitation of subsurface geologic resources

During the last 80 years, Louisiana has been losing wetlands at an average rate of 62 km 2 /y (24 mi 2 /y) for an accumulated loss of approximately 4900 km 2 (1900 mi 2 ). The loss seems to be the combined result of natural and anthropogenic causes that are behind primarily land subsidence averaging about 10 mm/y (0.4 in/y) coinciding with a sea level rise now at 3 mm/y (0.1 in/y), both contributing to coastal inundation. Upon completing extensive review of often controversial and conflicting views only synoptically reported here, conclusions reached by applying Monte Carlo simulation include: (1) geodetic measurements are consistent with independently postulated causes of regional subsidence; (2) ranking of subsidence factors shows that the main contributor to the regional subsidence is adjustment to sediment load in the form of lithosphere flexure followed by normal faulting dipping basinward, which combined, account on average for 70% of the subsidence, with compaction accounting for another 23%; and (3) production of oil and gas plays a tertiary role. The literature supports the historical view that before experiencing engineering modifications across the catchment area, sedimentation from the Mississippi River system was able to build a prograding coastline by overcoming subsidence rates of similar magnitude with more generous sediment loads of coarser particle size. Sea level rise will become an increasingly dominant factor in land loss only if the acceleration predicted by simulation model scenarios materializes. Wetland losses most likely will continue for as long as there is no compensation to counterbalance the negative effects of land subsidence and sea level rise, with the latter determining the pace of future losses.

Louisiana↗

Overview of a compre­hensive resource database for the assessment of recoverable hydrocarbons produced by carbon dioxide enhanced oil recovery

A database called the “Comprehensive Resource Database” (CRD) was prepared to support U.S. Geological Survey (USGS) assessments of technically recoverable hydrocarbons that might result from the injection of miscible or immiscible carbon dioxide (CO 2 ) for enhanced oil recovery (EOR). The CRD was designed by INTEK Inc., a consulting company under contract to the USGS. The CRD contains data on the location, key petrophysical properties, production, and well counts (number of wells) for the major oil and gas reservoirs in onshore areas and State waters of the conterminous United States and Alaska. The CRD includes proprietary data on petrophysical properties of fields and reservoirs from the “Significant Oil and Gas Fields of the United States Database,” prepared by Nehring Associates in 2012, and proprietary production and drilling data from the “Petroleum Information Data Model Relational U.S. Well Data,” prepared by IHS Inc. in 2012. This report describes the CRD and the computer algorithms used to (1) estimate missing reservoir property values in the Nehring Associates (2012) database, and to (2) generate values of additional properties used to characterize reservoirs suitable for miscible or immiscible CO 2 flooding for EOR. Because of the proprietary nature of the data and contractual obligations, the CRD and actual data from Nehring Associates (2012) and IHS Inc. (2012) cannot be presented in this report.

Techniques and Methods↗

Nitrogen and phosphorus sources and delivery from the Mississippi/Atchafalaya River Basin: An update using 2012 SPARROW models

Nitrogen (N) and phosphorus (P) inputs throughout the Mississippi/Atchafalaya River Basin (MARB) have been linked to the Gulf of Mexico hypoxia and water‐quality problems throughout the MARB. To describe N and P loading throughout the MARB, SPAtially Referenced Regression On Watershed attributes (SPARROW) models were previously developed based on nutrient inputs and management similar to 1992 and 2002. In this study, refined SPARROW models were developed with higher resolution basin delineation, updated (2012) source inputs, improved calibration (load) targets, and additional statistical techniques than used in the previous SPARROW models. Based on the refined models, consistent with past models, N and P loads/yields were the highest from the central part of the MARB (Corn Belt) and along the Mississippi River. Agricultural activities remained the most important N and P source, but more so for N because its input, which could now be distinguished from atmospheric deposition, could be estimated. Natural loss of P from geologic material throughout the MARB was an important source, contributing about 23% of the total P from the MARB, and resulted in specific areas, such as Kentucky and Tennessee, being larger sources of P than previously estimated. This information can help managers decide where efforts will have the largest effects (highest ranked areas) on reducing nutrient loading to the Gulf hypoxia and what are the most important sources of N and P in these areas.

Mississippi/Atchafalaya River Basin↗

Hydrogeology, water quality, water budgets, and simulated responses to hydrologic changes in Santa Rosa and San Simeon Creek ground-water basins, San Luis Obispo County, California

Santa Rosa and San Simeon Creeks are underlain by thin, narrow ground-water basins that supply nearly all water used for local agricultural and municipal purposes. The creeks discharge to the Pacific Ocean near the northwestern corner of San Luis Obispo County, California. The basins contain heterogeneous, unconsolidated alluvial deposits and are underlain by relatively impermeable bedrock. Both creeks usually stop flowing during the summer dry season, and most of the pumpage during that time is derived from ground-water storage. Annual pumpage increased substantially during 1956?88 and is now a large fraction of basin storage capacity. Consequently, dry-season water levels are lower and the water supply is more vulnerable to drought. The creeks are the largest source of ground-water recharge, and complete basin recharge can occur within the first few weeks of winter streamflow. Agricultural and municipal pumpages are the largest outflows and cause dry-season water-level declines throughout the San Simeon Basin. Pumping effects are more localized in the Santa Rosa Basin because of subsurface flow obstructions. Even without pumpage, a large quantity of water naturally drains out of storage at the upper ends of the basins during the dry season. Ground water is more saline in areas close to the coast than in inland areas. Although seawater intrusion has occurred in the past, it probably was not the cause of high salinity in 1988?89. Ground water is very hard, and concentrations of dissolved solids, chloride, iron, and manganese exceed drinking-water standards in some locations. Probability distributions of streamflow were estimated indirectly from a 120-year rainfall record because the periods of record for local stream-gaging stations were wetter than average. Dry-season durations with recurrence intervals between 5 and 43 years are likely to dry up some wells but not cause seawater intrusion. A winter with no streamflow is likely to occur about every 32 years and to result in numerous dry wells, seawater intrusion, and subsidence. Digital ground-water-flow models were used to estimate several items in the ground-water budgets and to investigate the effects of pumpage and drought. The models also were used to investigate the hydrologic effects of selected water-resources management alternatives. Selection of alternatives was not constrained by issues related to water rights, which were under dispute during the study. Increases in the area and intensity of irrigation could increase agricultural water demand by 26 to 35 percent, an increase that would lower water levels by as much as 10 feet and possibly cause subsidence in the lower Santa Rosa Basin. An additional municipal well in the lower Santa Rosa Basin could withdraw 100 acre-feet per year without causing seawater intrusion, but subsidence might occur. Transferring 270 acre-feet per year of treated wastewater from a percolation area near the coast to an area about 0.5 mile upstream of the municipal well field in the San Simeon Basin could raise upstream water levels by as much as 12 feet without causing significant water-table mounding or seawater intrusion. Decreases in agricultural pumping after a winter without streamflow could prevent seawater intrusion while allowing municipal pumping to continue at normal rates.

Water-Resources Investigations Report↗

Machine learning can assign geologic basin to produced water samples using major ion geochemistry

Understanding the geochemistry of waters produced during petroleum extraction is essential to informing the best treatment and reuse options, which can potentially be optimized for a given geologic basin. Here, we used the US Geological Survey’s National Produced Waters Geochemical Database (PWGD) to determine if major ion chemistry could be used to classify accurately a produced water sample to a given geologic basin based on similarities to a given training dataset. Two datasets were derived from the PWGD: one with seven features but more samples (PWGD7), and another with nine features but fewer samples (PWGD9). The seven-feature dataset, prior to randomly generating a training and testing (i.e., validation) dataset, had 58,541 samples, 20 basins, and was classified based on total dissolved solids (TDS), bicarbonate (HCO 3 ), Ca, Na, Cl, Mg, and sulfate (SO 4 ). The nine-feature dataset, prior to randomly splitting into a training and testing (i.e., validation) dataset, contained 33,271 samples, 19 basins, and was classified based on TDS, HCO 3 , Ca, Na, Cl, Mg, SO 4 , pH, and specific gravity. Three supervised machine learning algorithms—Random Forest, k-Nearest Neighbors, and Naïve Bayes—were used to develop multi-class classification models to predict a basin of origin for produced waters using major ion chemistry. After training, the models were tested on three different datasets: Validation7, Validation9, and one based on data absent from the PWGD. Prediction accuracies across the models ranged from 23.5 to 73.5% when tested on the two PWGD-based datasets. A model using the Random Forest algorithm predicted most accurately compared to all other models tested. The models generally predicted basin of origin more accurately on the PWGD7-based dataset than on the PWGD9-based dataset. An additional dataset, which contained data not in the PWGD, was used to test the most accurate model; results suggest that some basins may lack geochemical diversity or may not be well described, while others may be geochemically diverse or are well described. A compelling result of this work is that a produced water basin of origin can be determined using major ions alone and, therefore, deep basinal fluid compositions may not be as variable within a given basin as previously thought. Applications include predicting the geochemistry of produced fluid prior to drilling at different intervals and assigning historical produced water data to a producing basin.

Natural Resources Research↗

Sediment source fingerprinting as an aid to large-scale landscape conservation and restoration: A review for the Mississippi River Basin

Reliable quantitative information on sediment sources to rivers is critical to mitigate contamination and target conservation and restoration actions. However, the determination of the relative importance of sediment sources is complicated at the scale of large river basins by immense variability in erosional processes and sediment sources over space and time, heterogeneity in sediment transport and deposition, and a paucity of sediment monitoring data. Sediment source fingerprinting is an increasingly adopted field-based technique that identifies the nature and relative source contribution of sediment transported in waterways. Notably, sediment source fingerprinting provides information that is independent of other field, modeling, or remotely sensed techniques. However, the diversity in sediment fingerprinting sampling, analytical, and interpretive methods has been recognized as a problem in terms of developing standardized procedures for its application at the scale of large river basins. Accordingly, this review focuses on established sediment source fingerprinting studies conducted within the Mississippi River Basin (MRB), summarizes unique information provided by sediment source fingerprinting that is distinct from traditional monitoring techniques, evaluates consistency and reliability of methodological approaches among MRB studies, and provides prospects for the use of the sediment source fingerprinting technique as an aid to large-scale landscape conservation and restoration under current management frameworks. Most established MRB studies got creditable fingerprinting results and considered near-channel sources as the dominant sediment sources in most cases, while the comparability of their results suffers from a lack of standardization in procedural steps. Findings from MRB studies demonstrate that sediment source fingerprinting is a highly valuable and reliable sediment source assessment approach to assist land and water resource management under current management frameworks, but efforts are still needed to make this technique ready to be used in a more predominant way in large-scale landscape conservation and restoration efforts. We summarized research needs and suggested the best fingerprinting practices for management purposes with the aim of ensuring that this technique is as robust and reliable as it moves forward.

Mississippi River Basin↗

Chlorophyll a and inorganic suspended solids in backwaters of the upper Mississippi River system: Backwater lake effects and their associations with selected environmental predictors

The Long Term Resource Monitoring Program (LTRMP) uses a stratified random sampling design to obtain water quality statistics within selected study reaches of the Upper Mississippi River System (UMRS). LTRMP sampling strata are based on aquatic area types generally found in large rivers (e.g., main channel, side channel, backwater, and impounded areas). For hydrologically well-mixed strata (i.e., main channel), variance associated with spatial scales smaller than the strata scale is a relatively minor issue for many water quality parameters. However, analysis of LTRMP water quality data has shown that within-strata variability at the strata scale is high in off-channel areas (i.e., backwaters). A portion of that variability may be associated with differences among individual backwater lakes (i.e., small and large backwater regions separated by channels) that cumulatively make up the backwater stratum. The objective of the statistical modeling presented here is to determine if differences among backwater lakes account for a large portion of the variance observed in the backwater stratum for selected parameters. If variance associated with backwater lakes is high, then inclusion of backwater lake effects within statistical models is warranted. Further, lakes themselves may represent natural experimental units where associations of interest to management may be estimated.

Open-File Report↗

Estimation of baseline daily mean streamflows for ungaged locations on Pennsylvania streams, water years 1960-2008

Water-resource managers use daily mean streamflows to generate streamflow statistics and analyze streamflow conditions. An in-depth evaluation of flow regimes to promote instream ecological health often requires streamflow information obtainable only from a time series hydrograph. Historically, it has been difficult to estimate daily mean streamflow for an ungaged location. The U.S. Geological Survey (USGS), in cooperation with the Pennsylvania Department of Environmental Protection, Susquehanna River Basin Commission, and The Nature Conservancy, has developed the Ba seline S treamflow E stimator (BaSE) to estimate baseline streamflow at a daily time scale for ungaged streams in Pennsylvania using data collected during water years 1960–2008. Baseline streamflow is minimally altered by regulation, diversion, or mining, and other anthropogenic activities. Daily mean streamflow is estimated in BaSE using a methodology that equates streamflow as a percentile from a flow duration curve for a particular day at an ungaged location with streamflow as a percentile from the flow duration curve for the same day at a reference streamgage that is considered to be hydrologically similar to the ungaged location. An appropriate reference streamgage is selected using map correlation, in which variogram models are developed that correlate streamflow at one streamgage with streamflows at all other streamgages. The percentiles from a flow duration curve for the ungaged location are converted to streamflow through the use of regression equations. Regression equations used to predict 17 flow-duration exceedance probabilities were developed for Pennsylvania using geographic information system-derived basin characteristics. The standard error of prediction for the regression equations ranged from 11 percent to 92 percent with the mean of 31 percent. The map correlation method for estimating streamflow was tested at locations within two pilot basins, the Upper Delaware River Basin and the Lower Susquehanna River Basin, before being applied statewide. Reference streamgages within the pilot basins were used as ungaged locations for analyzing the map correlation method. Correlation using Spearman’s rho and centroid distance performed as well as, or better than, the method using the closest streamgage as a reference streamgage. Map correlation using the correlation metrics identified in the pilot basins was applied to 156 streamgages in and near Pennsylvania. BaSE uses the map correlation method and flow-duration exceedance probability regression equations to estimate baseline daily mean streamflow for an ungaged location. The output from BaSE is a Microsoft Excel® report file that summarizes the reference streamgage and ungaged location information, including basin characteristics, percent difference in basin characteristics between the two locations, any warning associated with the basin characteristics, mean and median streamflow for the ungaged location, and a daily hydrograph of streamflow for water years 1960–2008 for the ungaged location. The daily mean streamflow for the ungaged location can be exported as a text file to be used as input into other statistical software packages. BaSE estimates daily mean streamflow for baseline conditions only, and any alterations to streamflow from regulation, large water use, or substantial mining are not reflected in the estimated streamflow.

Pennsylvania↗

Estimating potential wetland extent along selected river reaches in Indiana using streamflow statistics and flood-inundation mapping techniques

In this study potential wetland extents were estimated for 12 river reaches covering about 750 river miles in Indiana and parts of Illinois and Ohio. The study was completed by the U.S. Geological Survey in cooperation with the U.S. Department of Agriculture, Natural Resources Conservation Service. This study follows and adds to the work completed in a pilot study and determines that potential wetland extents can be estimated using streamflow statistics, streamgage data, and flood-inundation mapping techniques. The study was designed to assist in the Agricultural Conservation Easement Program. The Agricultural Conservation Easement Program is a voluntary program administered by the Natural Resources Conservation Service that provides technical and financial assistance to private landowners and Tribes to restore, protect, and enhance wetlands in exchange for retiring eligible land from agriculture. For a site to be eligible for wetland restoration, it should be in a zone with sustained or frequent flooding. This study calculated the flows that lasted for a period of 7 consecutive days on average at least once every 2 years (a value termed the “7MQ2”) for all the U.S. Geological Survey streamgages within the selected river reaches. These 7MQ2 flows were related to the stage-discharge tables for each streamgage, and a corresponding water-surface elevation was determined. Maps of estimated wetland extent were prepared using the 7MQ2 inundation elevation data in conjunction with bare-earth land-surface elevation data made publicly available through the online geospatial data clearinghouses of Indiana, Illinois, and Ohio. Flood-inundation mapping techniques were applied with the aid of geographic information system software to generate water-surface planes that represent inundation elevations associated with the 7MQ2 streamflow. Land-surface elevation data from high-resolution digital elevation models were subtracted from the water-surface planes to produce maps of wetland extent. The 12 map products, including datasets and geoprocessing tools, produced from this study will aid the National Resources Conservation Service and its partners with the onsite inundation-zone verification in agricultural land for potential restoration.

Illinois, Indiana, Ohio↗

Rethinking groundwater flow on the South Rim of the Grand Canyon, USA: Characterizing recharge sources and flow paths with environmental tracers

In the arid landscape south of the Grand Canyon, natural springs and seeps are a critical resource for endemic species and Native American tribes. Groundwater is potentially threatened by expanding populations, visitations, and mineral extraction activities. Environmental tracers including noble gases, stable isotopes of hydrogen and oxygen in water, tritium, and carbon-14 were used to characterize recharge sources and flow paths in South Rim aquifers. Results confirm the regional Redwall-Muav Aquifer as the primary groundwater source to springs. However, a second local recharge source is required to explain the detection of tritium. Two probable sources are identified as: low-elevation infiltration of surface run-off with warm noble gas recharge temperatures, high excess air, and relatively low fractions of winter recharge, and high-elevation plateau recharge with cool recharge temperatures, low excess air, and fraction of winter recharge of ~ 1. Previous investigators have linked spring occurrence with regional faults and fractures. We show such features are also the likely control chemical mixing between the regional and local groundwater sources, the transport of deeply sourced and local recharge fluids, groundwater age, and thus the relative vulnerability of groundwater to depletion and contamination. The new conceptual model of groundwater sources and flow paths suggest many South Rim springs may respond on the order of 10s to 100s of years to groundwater depletion and contamination, even though the majority of groundwater flow is along longer flow paths with longer lag times. The magnitude of response to short term changes in the flow system remains unclear.

Arizona↗

USGS Arctic Ocean carbon cruise 2010: field activity H-03-10-AR to collect carbon data in the Arctic Ocean, August - September 2010

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form carbonic acid, a weak, naturally occurring acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗

Hydrogeology of the surficial and intermediate aquifer systems in Sarasota and adjacent counties, Florida

From 1991 to 1995, the hydrogeology of the surficial aquifer system and the major permeable zones and confining units of the intermediate aquifer system in southwest Florida was studied. The study area is a 1,400-square-mile area that includes Sarasota County and parts of Manatee, De Soto, Charlotte, and Lee Counties. Lithologic, geophysical, hydraulic property, and water-level data were used to correlate the hydrogeology and map the extent of the aquifer systems. Water chemistry was evaluated in southwest Sarasota County to determine salinity of the surficial and intermediate aquifer systems. The surficial aquifer is an unconfined aquifer system that overlies the intermediate aquifer system and ranges from a few feet to over 60 feet in thickness in the study area. Hydraulic properties of the surficial aquifer system determined from aquifer and laboratory tests, and model simulations vary considerably across the study area. The intermediate aquifer system, a confined aquifer system that lies between the surficial and the Upper Floridan aquifers, is composed of alternating confining units and permeable zones. The intermediate aquifer system has three major permeable zones that exhibit a wide range of hydraulic properties. Horizontal flow in the intermediate aquifer system is northeast to southwest. Most of the study area is in a discharge area of the intermediate aquifer system. Water ranges naturally from fresh in the surficial aquifer system and upper permeable zones of the intermediate aquifer system to moderately saline in the lower permeable zone. Water-quality data collected in coastal southwest Sarasota County indicate that ground-water withdrawals from major pumping centers have resulted in lateral seawater intrusion and upconing into the surficial and intermediate aquifer systems.

Florida↗

Evaluating water management strategies with the Systems Impact Assessment Model: SIAM version 4

Water from many of California's coastal rivers has been used for a wide variety of development ventures, including major agricultural diversions, hydropower generation, and contaminant assimilation from industry, agriculture and logging. Anthropogenic impacts often degrade water quality and decrease the quantity and quality of aquatic habitat. Reallocating streamflow away from uses that degrade water quality to uses that foster higher water quality is a critical step in restoring riverine habitat and the anadromous fish that rely on that habitat for a portion of their life cycle. Reallocation always brings with it the need to examine the economic efficiency of the proposed changes. If the dollar benefits of improving water quality are greater than the costs, the criterion of improving economic efficiency is satisfied, a fact that can be highly persuasive to decision makers contemplating reallocation. Previous related studies have examined nonmarket benefits of the Trinity River in northern California (Douglas and Taylor, 1998; Douglas and Taylor, 1999abc) but nothing of this kind had been done on the Klamath River, another system with numerous uses for and competition over water in times of drought. An economic survey is nearing completion for the mid- to lower Klamath River, including the Scott, Shasta, and Salmon Rivers, but excluding the Trinity River. This survey provides valuable insights about the magnitude of the benefits and nature of the costs of reallocating water from market uses to instream flows that improve water quality and assist in the recovery of Klamath River fish stocks. Preliminary survey results (Douglas and Johnson, 2002; Douglas and Sleeper, In Prep.) indicate that about 234,000 California, Oregon, and Nevada households made recreation trips to the Klamath River Basin 1997-1998 and that these users spent about $372 million on trip related expenditures. Clearly the prosperity of the region is closely linked to the demand for mid- and lower Klamath River Basin recreation trips. Further, respondents indicated that they would make roughly 36% more recreational trips per annum to the Klamath if the water quality and the fishery were restored to an unspoiled condition. Using two distinct types of survey data, these additional trips would yield benefits with a present value of approximately $9.6 billion (at a discount rate of 7.5%). Calculating costs to restore the fishery and raise water quality involved five major hypothetical restoration activities: (1) purchasing Klamath project farmland and environmentally sensitive forest lands, (2) allocating more water down the Trinity River to enhance the quantity and quality of Klamath flows below the confluence, (3) removing four mainstem dams along the Klamath River and losing their associated hydropower production, (4) eliminating all harvest of Klamath-Trinity fish stocks for a 12-year period including the acquisition of fishing rights from both tribal and commercial marine fishermen, and (5) operating all Klamath-Trinity fish hatcheries to restore self-reproducing stocks. In total, restoration costs were estimated to be about $1.7 to $2.3 billion. If the assumptions used in this study are valid, it is clear that the benefits ($9.6B) outweigh the costs of restoring water quality and the fishery. The apparent disparity between restoration benefits and costs for the Klamath River may suggest to some that water resources on the Klamath be reallocated to environmentally friendly nonmarket uses. The economic analysis rests in part on the information made available to the survey designers by the biological, hydrologic, and water quality data incorporated in The System Impact Assessment Model (SIAM). It is our hope that SIAM can be used to improve the river's water quality and fishery, and strengthen the important regional economy.

Open-File Report↗

Effects of Withdrawals on Ground-Water Levels in Southern Maryland and the Adjacent Eastern Shore, 1980-2005

Ground water is the primary source of water supply in most areas of Maryland?s Atlantic Coastal Plain, including Southern Maryland. The counties in this area are experiencing some of the most rapid growth and development in the State, resulting in an increased demand for ground-water production. The cooperative, basic water-data program of the U.S. Geological Survey and the Maryland Geological Survey has collected long-term observations of ground-water levels in Southern Maryland and parts of the Eastern Shore for many decades. Additional water-level observations were made by both agencies beginning in the 1970s, under the Power Plant Research Program of the Maryland Department of Natural Resources. These long-term water levels commonly show significant declines over several decades, which are attributed to ground-water withdrawals. Ground-water-level trends since 1980 in major Coastal Plain aquifers such as the Piney Point-Nanjemoy, Aquia, Magothy, upper Patapsco, lower Patapsco, and Patuxent were compared to water use and withdrawal data. Potentiometric surface maps show that most of the declines in ground-water levels can be directly related to effects from major pumping centers. There is also evidence that deep drawdowns in some pumped aquifers may be causing declines in adjacent, unpumped aquifers. Water-level hydrographs of many wells in Southern Maryland show linear declines in levels year after year, instead of the gradual leveling-off that would be expected as the aquifers equilibrate with pumping. A continual increase in the volumes of water being withdrawn from the aquifers is one explanation for why they are not reaching equilibrium. Although reported ground-water production in Southern Maryland has increased somewhat over the past several decades, the reported increases are often not large enough to account for the observed water-level declines. Numerical modeling simulations indicate that a steady, annual increase in the number of small wells could account for the observed aquifer behavior. Such wells, being pumped at rates below the minimum legal reporting threshold of 10,000 gallons per day, might be the source of the additional withdrawals. More detailed water-use data, especially from domestic wells, central-pivot irrigation wells, and other small users not currently reporting withdrawals to the State, may help to determine the cause of the aquifer declines.

Scientific Investigations Report↗

Simulation of groundwater flow and effects of groundwater irrigation on stream base flow in the Elkhorn and Loup River basins, Nebraska, 1895-2055: Phase Two

Regional groundwater-flow simulations for a 30,000-square-mile area of the High Plains aquifer, referred to collectively as the Elkhorn-Loup Model, were developed to predict the effects of groundwater irrigation on stream base flow in the Elkhorn and Loup River Basins, Nebraska. Simulations described the stream-aquifer system from predevelopment through 2005 [including predevelopment (pre-1895), early development (1895-1940), and historical development (1940 through 2005) conditions] and future hypothetical development conditions (2006 through 2033 or 2055). Predicted changes to stream base flow that resulted from simulated changes to groundwater irrigation will aid development of long-term strategies for management of hydrologically connected water supplies. The predevelopment through 2005 simulation was calibrated using an automated parameter-estimation method to optimize the fit to pre-1940 groundwater levels and base flows, 1945 through 2005 decadal groundwater-level changes, and 1940 through 2005 base flows. The calibration results of the pre-1940 period indicated that 81 percent of the simulated groundwater levels were within 30 feet of the measured water levels. The results did not indicate large areas of simulated groundwater levels that were biased too high or too low, indicating that the simulation generally captures the regional trends. Calibration results using 1945 through 2005 decadal groundwater-level changes indicated that a majority of the simulated groundwater-level changes were within 5 feet of the changes calculated from measured groundwater levels. Simulated groundwater-level rises generally were smaller than measured rises near surface-water irrigation districts. Simulated groundwater-level declines were larger than measured declines in several parts of the study area having large amounts of irrigated crops. Base-flow trends and volumes generally were reproduced by the simulation at most sites. Exceptions include downward trends of simulated base flow from the 1970s to the end of the calibration period for the Elkhorn River at Norfolk, Beaver Creek at Genoa, and Cedar River near Fullerton. Effects of groundwater irrigation on stream base flow were predicted using several methods: (1) simulated base-flow depletion was mapped to represent the percentage of water pumped from a hypothetical well during 2006 through 2055 that corresponds to base-flow depletions at the end of that 50-year period; (2) the groundwater-flow simulation predicted changes in stream base flow that result from modifying the number of irrigated acres in a 25-year period (2009 through 2033); and (3) a simulation-optimization model determined the minimum reduction of groundwater pumpage that would be necessary in the Elkhorn River Basin in a 25-year period (2009 through 2033) to comply with various hypothetical base-flow requirements for the Elkhorn River. The results are not intended to determine specific management plans that must be adopted, but rather to improve the understanding of how base flow is affected by irrigation. A 50-year simulation (2006-55) indicated that depletions of less than 10 percent of pumpage mainly occur in areas that are about 10 miles or farther from the Elkhorn and Loup Rivers and their tributaries. The calibrated simulation was used to predict the 25-year effect on base flow of a 10 percent decrease in irrigated acres and the effect of increasing acres at the presently (2010) allowed rate. Hypothesized changes to irrigated acres were applied only to areas where mapped base-flow depletions were at least 10 percent of pumpage. The effect of changes in irrigated acres includes the combined effects of changes to pumpage and additional recharge from irrigated acres. When irrigated acres were decreased by 10 percent within selected areas of four Natural Resources Districts (a total reduction of about 120,000 acres and a 5 percent reduction in irrigation pumpage), simulated base flow was predicted to inc

Nebraska↗