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At least 1,243 records · Page 69Linked to original sources

USGS2007

Mercury speciation in piscivorous fish from mining-impacted reservoirs

Guadalupe Reservoir (GUA), California, and Lahontan Reservoir (LAH), Nevada, U.S. are both affected either directly or indirectly by the legacy of gold and silver mining in the Sierra Nevada during the nineteenth century. Analysis of total mercury in fish from these lentic systems consistently indicate elevated concentrations (>1 μg·g-1 wet weight; hereinafter, all concentrations are reported as wet weight unless indicated otherwise) well above the U.S. Environmenal Protection Agency's human consumption advisory level for fish (<0.3 μg·g-1). Replicate X-ray absorption near edge structure (XANES) analyses on largemouth bass and hybrid striped bass from GUA and LAH were performed to determine predominant chemical species of mercury accumulated by these high-trophic-level piscivores that are exposed to elevated mercury through trophic transfer in mining-impacted lentic systems. Despite distinct differences in mercury source, the proximity of the source, and concentrations of complexing ligands, results of XANES analysis clearly indicated that mercury accumulated in these individual fish from the two reservoirs were dominated by methylmercury cysteine complexes. These findings are consistent with results from commercial fish species inhabiting marine environments which are presumed to include differing mercury sources (e.g., atmospheric, hydrothermal, or benthic). The dominance of methylmercury cysteine complexes in muscle tissues of fish obtained from such contrasting environments and exposure conditions suggests that a generic toxicological model for the consumption of fish could be applicable over a wide range of ecologic settings.

Environmental Science & Technology↗

USGS1999

New method for the direct determination of dissolved Fe(III) concentration in acid mine waters

A new method for direct determination of dissolved Fe(III) in acid mine water has been developed. In most present methods, Fe(III) is determined by computing the difference between total dissolved Fe and dissolved Fe(II). For acid mine waters, frequently Fe(II) ≫ Fe(III); thus, accuracy and precision are considerably improved by determining Fe(III) concentration directly. The new method utilizes two selective ligands to stabilize Fe(III) and Fe(II), thereby preventing changes in Fe reduction−oxidation distribution. Complexed Fe(II) is cleanly removed using a silica-based, reversed-phase adsorbent, yielding excellent isolation of the Fe(III) complex. Iron(III) concentration is measured colorimetrically or by graphite furnace atomic absorption spectrometry (GFAAS). The method requires inexpensive commercial reagents and simple procedures that can be used in the field. Calcium(II), Ni(II), Pb(II), Al(III), Zn(II), and Cd(II) cause insignificant colorimetric interferences for most acid mine waters. Waters containing >20 mg of Cu/L could cause a colorimetric interference and should be measured by GFAAS. Cobalt(II) and Cr(III) interfere if their molar ratios to Fe(III) exceed 24 and 5, respectively. Iron(II) interferes when its concentration exceeds the capacity of the complexing ligand (14 mg/L). Because of the GFAAS elemental specificity, only Fe(II) is a potential interferent in the GFAAS technique. The method detection limit is 2 μg/L (40 nM) using GFAAS and 20 μg/L (0.4 μM) by colorimetry.

Environmental Science & Technology↗

USGS2000

Carbonate ions and arsenic dissolution by groundwater

Samples of Marshall Sandstone, a major source of groundwater with elevated arsenic levels in southeast Michigan, were exposed to bicarbonate ion under controlled chemical conditions. In particular, effects of pH and redox conditions on arsenic release were evaluated. The release of arsenic from the aquifer rock was strongly related to the bicarbonate concentration in the leaching solution. The results obtained suggest that the carbonation of arsenic sulfide minerals, including orpiment (As2S3) and realgar (As2S2), is an important process in leaching arsenic into groundwater under anaerobic conditions. The arseno-carbonate complexes formed, believed to be As(CO3)2-, As(CO3)(OH)2-, and AsCO3+, are stable in groundwater. The reaction of ferrous ion with the thioarsenite from carbonation process can result in the formation of arsenopyrite which is a common mineral in arsenic-rich aquifers.Samples of Marshall Sandstone, a major source of groundwater with elevated arsenic levels in southeast Michigan, were exposed to bicarbonate ion under controlled chemical conditions. In particular, effects of pH and redox conditions on arsenic release were evaluated. The release of arsenic from the aquifer rock was strongly related to the bicarbonate concentration in the leaching solution. The results obtained suggest that the carbonation of arsenic sulfide minerals, including orpiment (As2S3) and realgar (As2S2), is an important process in leaching arsenic into groundwater under anaerobic conditions. The arseno-carbonate complexes formed, believed to be As(CO3)2-, As(CO3)(OH)2-, and AsCO3+, are stable in groundwater. The reaction of ferrous ion with the thioarsenite from carbonation process can result in the formation of arsenopyrite which is a common mineral in arsenic-rich aquifers.The role of bicarbonate in leaching arsenic into groundwater was investigated by conducting batch experiments using core samples of Marshall Sandstone from southeast Michigan and different bicarbonate solutions. The effects of pH and redox conditions on As dissolution were examined. Results showed that As was not leached significantly out of the Marshall Sandstone samples after 3 d using either deionized water or groundwater, but As was leached efficiently by sodium bicarbonate, potassium bicarbonate, and ferric chloride solutions. The leaching rate with sodium bicarbonate was about 25% higher than that with potassium bicarbonate. The data indicated that bicarbonate ion was involved primarily in As dissolution and that hydroxyl radical ion did not affect As dissolution to any significant degree. The amount of As leached was dependent upon the sodium bicarbonate concentration, increasing with reaction time for each concentration. Significant As leaching was found in the extreme pH ranges of <1.9 and 8.0-10.4. The resulting arseno-carbonate complexes formed were stable in groundwater.

Environmental Science & Technology↗

USGS2002

A fluorimetric study of the thorium-morin system

Thorium reacts with morin to yield a yellow complex that fluoresces when irradiated with ultraviolet light. The effect on the fluorescence of such variables as concentration of acid, alcohol, thorium, morin, and complex; time, temperature and wave length of exciting light are studied to determine experimental conditions yielding maximum fluorescence. The effects of Zr+4, Al+3, Fe+3, Ca+2 and La+3 are discussed. The fundamental relationships between light absorption and fluorescence are expressed in a general equation that applies to a three-component system when the fluorescence is measured in a transmission-type fluorimeter. This general equation is used to obtain an expression for the fluorescence of the thoriummorin system. Equations, derived from experimental data, relate both the fraction of thorium reacted to form complex and the fraction of unquenched fluorescence to the concentration of uncombined morin. These functions, when combined with the general equation, give an expression whichrelates the total net fluorescence to the amount of uncombined morin in the solution. This last equation can be used to determine the one region for the concentration of uncombined morin that gives maximum sensitivity for the system. Calculated standard curves are in good agreement with experimental curves.

Journal of the American Chemical Society↗

USGS2004

Driving mechanisms for >40 km of exhumation during contraction and extension in a continental arc, Cascades core, Washington

In the NW North American Cordillera, the Cascades core region of the Coast Plutonic Complex underwent Late Cretaceous (>96 Ma to locally 73 Ma) SW-NE contraction and crustal thickening followed by dextral transpression (???73 to 55 Ma), then transtension (<55 Ma). Exhumation occurred during all three phases. During contraction, slow exhumation (???0.6 mm/yr) occurred along the margins of the core, driven by isostatic rebound and erosion, and faster exhumation (>3 mm /yr) by local thrusting in regions undergoing crustal thickening. In the central part of the core (Chelan block), >40 km of exhumation occurred between 91 and 45 Ma, about half of which occurred during early contraction (driven by thrusting) and half during top-to-north, arc-oblique shear during reactivation of a midcrustal Cretaceous thrust, the Dinkelman decollement. The footwall of this thrust consists of the Swakane Biotite Gneiss, a Cretaceous, metaclastic assemblage with recorded pressures of 10-12 kbar, no arc-related magmatism, and structures dominated by pervasive top-to-north shearing. The hanging wall consists of the Napeequa Complex, an oceanic assemblage with recorded pressures of 6-12 kbar, voluminous arc-related magmatism, and complex structures indicating early top-to-WSW shearing, younger top-to-north shearing, and widespread folding. In the Napeequa, top-to-north shearing started by 73 Ma during melt-present conditions at pressures ???6 kbar. Top-to-north shearing in both hanging wall and footwall continued during exhumation (???1.6 mm/yr) and cooling to greenschist facies conditions during which slip became increasingly localized, eventually resulting in formation of pseudotachylite on discrete slip surfaces. We suggest that arc-oblique extension was driven by along-arc heterogeneity in displacements/ erosion, initially during transpression and underplating of continental sediments, and later during transtension. Copyright 2004 by the American Geophysical Union.

Tectonics↗

USGS2011

Proposed initiative would study Earth's weathering engine

At the Earth's surface, a complex suite of chemical, biological, and physical processes combines to create the engine that transforms bedrock into soil (Figure 1). Earth's weathering engine provides nutrients to nourish ecosystems and human society mediates the transport of toxic components within the biosphere, creates water flow paths that carve and weaken bedrock, and contributes to the evolution of landscapes at all temporal and spatial scales. At the longest time scales, the weathering engine sequesters CO 2 , thereby influencing long-term climate change. Despite the importance of soil, our knowledge of the rate of soil formation is limited because the weathering zone forms a complex, ever-changing interface, and because scientific approaches and funding paradigms have not promoted integrated research agendas to investigate such complex interactions. No national initiative has promoted a systems approach to investigation of weathering science across the broad array of geology, soil science, ecology and hydrology. Such a program is certainly needed, and this article describes a platform on which to build the initiative to answer the following question: How does the Earth weathering engine break down rock to nourish ecosystems, carve terrestrial landscapes, and control carbon dioxide in the global atmosphere?

Eos Science News↗

USGS2020

Linking magma storage and ascent to eruption volume and composition at an arc caldera

Conceptual models of magma storage and transport under calderas favor a connected system of sills and dikes. These features are individually below the resolution of standard seismic tomography, but radial seismic anisotropy can reveal where they exist in aggregate. We model radial anisotropy at Okmok caldera, Alaska, to demonstrate the presence of a caldera-centered stacked sill complex and surrounding dike system. We show that ascending magma, inferred from seismicity, either intersects the sill complex, resulting in a larger volume eruption of evolved magma, or bypasses the overlying sill complex via dikes, resulting in a low-volume mafic eruption. Our results exemplify how the locations of magma storage and paths of transport impact eruption size and composition. As this type of crustal storage is likely common to many calderas, this analysis offers a potential new framework for volcano observatories to forecast the size of impending eruptions.

Alaska↗

USGS2022

Modeling of barrier breaching during Hurricanes Sandy and Matthew

Physical processes driving barrier island change during storms are important to understand to mitigate coastal hazards and to evaluate conceptual models for barrier evolution. Spatial variations in barrier island topography, landcover characteristics, and nearshore and back-barrier hydrodynamics can yield complex morphological change that requires models of increasing resolution and physical complexity to predict. Using the Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST) modeling system, we investigated two barrier island breaches that occurred on Fire Island, NY during Hurricane Sandy (2012) and at Matanzas, FL during Hurricane Matthew (2016). The model employed a recently implemented infragravity (IG) wave driver to represent the important effects of IG waves on nearshore water levels and sediment transport. The model simulated breaching and other changes with good skill at both locations, resolving differences in the processes and evolution. The breach simulated at Fire Island was 250 m west of the observed breach, whereas the breach simulated at Matanzas was within 100 m of the observed breach. Implementation of the vegetation module of COAWST to allow three-dimensional drag over dune vegetation at Fire Island improved model skill by decreasing flows across the back-barrier, as opposed to varying bottom roughness that did not positively alter model response. Analysis of breach processes at Matanzas indicated that both far-field and local hydrodynamics influenced breach creation and evolution, including remotely generated waves and surge, but also surge propagation through back-barrier waterways. This work underscores the importance of resolving the complexity of nearshore and back-barrier systems when predicting barrier island change during extreme events.

Florida, New York↗

USGS2010

Paleozoic ophiolitic assemblages within the southern New England orogen of eastern Australia: Implications for growth of the Gondwana margin

Several ophiolitic assemblages occur in the southern New England orogen. The development of these rocks and their relations to the rest of the orogen have major implications for the tectonic evolution of eastern Gondwana. A major, narrow but elongate belt of Early Cambrian suprasubduction zone ophiolite crops out along and near the PeelManning Fault System and is juxtaposed against younger arc and subduction complex terranes. No pre-Permian links with the rest of the New England orogen have been established for this terrane. It may represent portions of Lachlan Fold Belt basement which underlies younger, westward overthrust New England terranes, and has been diapirically emplaced at higher crustal levels as serpentinite-matrix melange. Middle to Late Devonian ophiolitic rocks in the Yarras Complex comprise basement to the Birpai subterrane and represent a crustal cross section through a rifted island arc. Correlatives of this terrane also occur within the more extensive Gamilaroi terrane to the west of which deeper crustal levels are not exposed. The various components of serpentinite-matrix melange in the Ngamba terrane at Port Macquarie superficially appear to represent a dismembered ophiolite association. However, the various components of the melange exhibit a wide range of ages, metamorphism, and tectonic affinities, rendering a genetically related origin unlikely. This terrane includes fragments of ocean floor accreted into a Late Devonian subduction complex, which was later affected by Early Carboniferous forearc serpentinite diapirism and high Mg series magmatism. Zircon inheritance in Triassic dikes, which intrude the melange attest to the development or later emplacement of this forearc region over an older Lachlan Fold Belt basement. Ultramafic rocks of the Bundjalung terrane in the east of the New England region probably formed at deep levels in an intraoceanic island arc and are intruded by boninitic dikes. The tectonic development of the NEO was significantly more complicated than has been suggested in earlier published models. Periodic accretion of island arc systems, some of which are now represented by suprasubduction zone ophiolites, to the eastern margin of Gondwana suggests multiple phases of subduction with the possibility of polarity reversals throughout the history of accretion. Lateral accretion was not the only means by which Gondwana continental crust grew, and there was considerable postaccretion continentward overthrusting of younger terranes.

New South Wales↗

USGS1997

Metamorphic and structural evidence for significant vertical displacement along the Ross Lake fault zone, a major orogen-parallel shear zone in the Cordillera of western North America

Results of an investigation of the petrology and structure of the Skymo complex and adjacent terranes constrain the amount, timing, and sense of motion on a segment of the > 600-km-long Late Cretaceous - early Tertiary Ross Lake fault zone (RLFZ), a major orogen-parallel shear zone in the Cordillera of western North America. In the study area in the North Cascades, Washington state, the RLFZ accommodated significant pre-middle Eocene vertical displacement, and it juxtaposes the Skymo complex with upper amphibolite facies (650°–690°C and 6–7 kbar) Skagit Gneiss of the North Cascades crystalline core to the SW and andalusite-bearing phyllite of the Little Jack terrane (Intermontane superterrane) to the NE. The two main lithologic units of the Skymo complex, a primitive mafic intrusion and a fault-bounded block of granulite facies metasedimentary rocks, are unique in the North Cascades. Granulite facies conditions were attained during high-temperature (> 800°C), low pressure (≤ 4 kbar) contact metamorphism associated with intrusion of the mafic magma. P-T estimates and reaction textures in garnet-orthopyroxene gneiss suggest that contact metamorphism followed earlier, higher pressure regional metamorphism. There is no evidence that the Skagit Gneiss experienced high-T - low-P contact metamorphism. In the Little Jack terrane, however, texturally late cordierite ± spinel and partial replacement of andalusite by sillimanite near the terrane's fault contact with Skymo gabbro suggest that the Little Jack terrane experienced high-T (∼ 600°C) - low-P (≤ 4 kbar) contact metamorphism following earlier low-grade regional metamorphism. Similarities in the protoliths of metasedimentary rocks in the Skymo and Little Jack indicate that they may be part of the same terrane. Differences in pressure estimates for the Little Jack versus Skymo for regional metamorphism that preceded contact metamorphism indicate vertical displacement of ∼ 10 km (west side up) on the strand of the RLFZ that now separates the two structural blocks. High-angle faults in the study area are dextral-reverse mylonitic shear zones that experienced later brittle normal slip. Vertical motion on these shear zones before intrusion of Skymo gabbro can account for metamorphic discontinuities indicated by P-T results. The terranes have also been internally deformed by nonintersecting but coeval dextral and sinistral shear zones that formed after the terranes were brought together in the RLFZ and intruded by Eocene dikes. These results show that the RLFZ has accommodated significant vertical displacement but perhaps no more than tens of kilometers of early Tertiary lateral movement. Structural evidence for earlier, large-magnitude strike-slip displacement is not preserved.

Washington↗

USGS2012

The crustal structure of the Wrangellia Terrane along the East Glenn Highway, eastern‐southern Alaska

Recently acquired seismic refraction data from eastern‐southern Alaska provide new information on the structure and composition of the Wrangellia and adjacent terranes. The data comprise a 160‐km‐long refraction profile along the East Glenn (Tok‐Cutoff) Highway that was collected as part of the U.S. Geological Survey's multidisciplinary Trans‐Alaska Crustal Transect program. The upper 3 km of the Wrangellia terrane and associated rocks is characterized by low compressional wave velocities (V p = 1.9, 3.3, 4.6, 5.6 km s −1 ) and high‐velocity gradients common to most onshore seismic refraction profiles. There is also clear seismic expression of the West Fork fault system as a steep, down‐to‐the‐southwest fault that separates the Peninsular terrane to the southwest and the metamorphic complex of Gulkana River to the northeast. In contrast, no seismic expression occurs for the Paxson Lake fault, which separates the Wrangellia terrane from the metamorphic complex of Gulkana River. Adjacent to the Denali fault, within the Wrangellia terrane, two high‐velocity bodies (V p = 6.6 km s −1 ) occur in the upper crust. One of these extends to ∼10‐km depth and correlates with a late Paleozoic dioritic complex, suggesting that the Wrangellia terrane is at least 10 km thick in this part of Alaska. From 5 to 23 km depth, the crust appears seismically homogeneous, with velocity increasing from V p = 6.2 to V p = 6.6 km s −1 . Beneath this level, the crust is less well resolved, although evidence exists for a low‐velocity zone between 23 and 26 km and a possible southwest dipping interface at 35 km. No identifiable mantle refraction or reflection is observed, possibly indicating a crust as thick as 55 km. The relatively low seismic velocities in the upper 23 km of the crust compare favorably with laboratory‐measured velocities on pelitic schists and intermediate‐composition plutonic rocks (granites and granodiorites), both of which are recognized in Wrangellia. We interpret the seismic velocities to indicate that silicic‐to‐intermediate‐composition rocks are important constituents of the basement of this part of Wrangellia. Geologic evidence indicates that the Alaskan part of the Wrangellia terrane is a Paleozoic and Mesozoic island arc: our seismic evidence indicates it may have been built mostly on continental crust as opposed to the fragment of Wrangellia from Vancouver Island which was probably built on oceanic crust.

Alaska↗

USGS2012

Geophysical constraints on Washington convergent margin structure

Gravity and magnetic maps of western Washington reveal the lateral structure and fabric of the Washington Coast Range, Puget Basin, and southern Washington Cascade Range. The magnetic and gravity maps show large amplitude positive anomalies associated with the shallow but largely buried section of Washington Coast Range mafic rocks which are separated by negative anomalies over deep sedimentary basins. The positive anomalies indicate that the Coast Range mafic basement extends farther east than previously thought, at least as far east as the longitude of Seattle. Linear and steep gravity and magnetic gradients indicate many unmapped, often buried faults in the Washington Coast Range Province. Magnetic highs are also associated with mapped batholiths in the Cascade arc. Several magnetic highs observed east of the Coast Range rocks and west of these batholiths may be associated with buried Tertiary plutons or ophiolites. Two-dimensional gravity and magnetic modeling constrained with geological and other geophysical data indicate that the Coast Range Province rocks are about 1 km thick at the coast, thickening to as much as 30 km near their postulated eastern edge. A maximum boundary on the average density of the upper 15–20 km of the rocks that compose the Coast Range Province of 2920 kg/m 3 was established by the modeling, suggesting a composition largely of basalt and gabbro with little interbedded sediments. Under these rocks may be mantle or a subduction complex composed of dense mafic, ultramafic, and sedimentary rocks like that proposed to underlie Vancouver Island. Previous gravity models of the Washington margin include lower densities for the proposed subduction complex than for Vancouver Island, suggesting a lower component of mafic and ultramafic rocks than the rocks underlying Vancouver Island. However, my Washington model requires that the proposed subduction complex be more dense than the trench sediments and, therefore, that material denser than sediments be incorporated within it. The absence of continental mantle and the modeled wedge shape of the Coast Range Province upper crust suggest that erosion of the bottom of the overriding plate by subduction processes may have occurred.

Washington↗

USGS2010

Extensional faulting in the southern Klamath Mountains, California

Large northeast striking normal faults in the southern Klamath Mountains may indicate that substantial crustal extension occurred during Tertiary time. Some of these faults form grabens in the Jurassic and older bedrock of the province. The grabens contain continental Oligocene or Miocene deposits (Weaverville Formation), and in two of them the Oligocene or Miocene is underlain by Lower Cretaceous marine formations (Great Valley sequence). At the La Grange gold placer mine the Oligocene or Miocene strata dip northwest into the gently southeast dipping mylonitic footwall surface of the La Grange fault. The large normal displacement required by the relations at the La Grange mine is also suggested by omission of several kilometers of structural thickness of bedrock units across the northeast continuation of the La Grange fault, as well as by significant changes in bedrock across some northeast striking faults elsewhere in the Central Metamorphic and Eastern Klamath belts. The Trinity ultramafic sheet crops out in the Eastern Klamath terrane as part of a broad northeast trending arch that may be structurally analogous to the domed lower plate of metamorphic core complexes found in eastern parts of the Cordillera. The northeast continuation of the La Grange fault bounds the southeastern side of the Trinity arch in the Eastern Klamath terrane and locally cuts out substantial lower parts of adjacent Paleozoic strata of the Redding section. Faults bounding the northwestem side of the Trinity arch generally trend northeast and juxtapose stacked thrust sheets of lower Paleozoic strata of the Yreka terrane against the Trinity ultramafic sheet. Geometric relations suggest that the Tertiary extension of the southern Klamath Mountains was in NW-SE directions and that the Redding section and the southern part of the Central Metamorphic terrane may be a large Tertiary allochthon detached from the Trinity ultramafic sheet. Paleomagnetic data indicate a lack of rotation about a vertical axis during the extension. We propose that the Trinity ultramafic sheet is structurally analogous to a metamorphic core complex; if so, it is the first core complex to be described that involves ultramafic rocks. We infer that Mesozoic terrane accretion produced a large gravitational instability in the crust that spread laterally during Tertiary extension

California↗

USGS2011

Superficial simplicity of the 2010 El Mayorg-Cucapah earthquake of Baja California in Mexico

The geometry of faults is usually thought to be more complicated at the surface than at depth and to control the initiation, propagation and arrest of seismic ruptures 1 , 2 , 3 , 4 , 5 , 6 . The fault system that runs from southern California into Mexico is a simple strike-slip boundary: the west side of California and Mexico moves northwards with respect to the east. However, the M w 7.2 2010 El Mayor–Cucapah earthquake on this fault system produced a pattern of seismic waves that indicates a far more complex source than slip on a planar strike-slip fault 7 . Here we use geodetic, remote-sensing and seismological data to reconstruct the fault geometry and history of slip during this earthquake. We find that the earthquake produced a straight 120-km-long fault trace that cut through the Cucapah mountain range and across the Colorado River delta. However, at depth, the fault is made up of two different segments connected by a small extensional fault. Both segments strike N130° E, but dip in opposite directions. The earthquake was initiated on the connecting extensional fault and 15 s later ruptured the two main segments with dominantly strike-slip motion. We show that complexities in the fault geometry at depth explain well the complex pattern of radiated seismic waves. We conclude that the location and detailed characteristics of the earthquake could not have been anticipated on the basis of observations of surface geology alone.

California, Arizona↗

USGS2020

Subduction megathrust heterogeneity characterized from 3D seismic data

Megathrust roughness and structural complexity are thought to be controls on earthquake slip at subduction zones because they result in heterogeneity in shear strength and resolved stress. However, because active megathrust faults are difficult to observe, the causes and scales of complexity are largely unknown. Here we measured the in situ properties of the megathrust of the Middle America subduction zone in a three-dimensional seismic reflection volume to determine how fault properties vary. We quantify spatial variability in the megathrust roughness, overburden and rock physical properties. Heterogeneity in the megathrust roughness exists at length scales of a few kilometres because the megathrust is dissected by active lower-plate normal faults, which offset the megathrust and renewed fault roughness. Spatial variations in the rock physical properties at the plate interface are characterized by correlation length scales of hundreds of metres. Frontal prism taper, historical seismicity and the variation in earthquake stress drop values local to the megathrust are all affected by the heterogeneity at these length scales. Both geometric and rheological complexities may therefore control the mechanical behaviour of the subduction plate interface, which includes earthquake rupture characteristics.

Central America megathrust, Pacific Ocean↗

USGS2018

Integrative taxonomy resolves taxonomic uncertainty for freshwater mussels being considered for protection under the U.S. Endangered Species Act

Objectively delimiting species boundaries remains an important challenge in systematics and becomes urgent when unresolved taxonomy complicates conservation and recovery efforts. We examined species boundaries in the imperiled freshwater mussel genus Cyclonaias (Bivalvia: Unionidae) using morphometrics, molecular phylogenetics, and multispecies coalescent models to help guide pending conservation assessments and legislative decisions. Congruence across multiple lines of evidence indicated that current taxonomy overestimates diversity in the C. pustulosa species complex. The only genetically and morphologically diagnosable species in the C. pustulosa species complex were C. pustulosa and C. succissa and we consider C. aurea , C. houstonensis, C. mortoni , and C. refulgens to be synonyms of C. pustulosa . In contrast, all three species in the C. nodulata complex ( C. necki , C. nodulata , and C. petrina ) were genetically, geographically, and morphologically diagnosable. Our findings have important conservation and management implications, as three nominal species ( C. aurea , C. houstonensis , and C. petrina ) are being considered for protection under the Endangered Species Act.

Scientific Reports↗

USGS2022

RNA-seq reveals potential gene biomarkers in fathead minnows (Pimephales promelas) for exposure to treated wastewater effluent

Discharged wastewater treatment plant (WWTP) effluent greatly contributes to the generation of complex mixtures of contaminants of emerging concern (CECs) in aquatic environments which often contain neuropharmaceuticals and other emerging contaminants that may impact neurological function. However, there is a paucity of knowledge on the neurological impacts of these exposures to aquatic organisms. In this study, caged fathead minnows ( Pimephales promelas ) were exposed in situ in a temperate-region effluent-dominated stream ( i.e. , Muddy Creek) in Coralville, Iowa, USA upstream and downstream of a WWTP effluent outfall. The pharmaceutical composition of Muddy Creek was recently characterized by our team and revealed many compounds there were at a low microgram to high nanogram per liter concentration. Total RNA sequencing analysis on brain tissues revealed 280 gene isoforms that were significantly differentially expressed in male fish and 293 gene isoforms in female fish between the upstream and downstream site. Only 66 (13%) of such gene isoforms overlapped amongst male and female fish, demonstrating sex-dependent impacts on neuronal gene expression. By using a systems biology approach paired with functional enrichment analyses, we identified several potential novel gene biomarkers for treated effluent exposure that could be used to expand monitoring of environmental effects with respect to complex CEC mixtures. Lastly, when comparing the results of this study to those that relied on a single-compound approach, there was relatively little overlap in terms of gene-specific effects. This discovery brings into question the application of single-compound exposures in accurately characterizing environmental risks of complex mixtures and for gene biomarker identification.

Iowa↗

USGS1986

Electrothermal atomisation atomic absorption conditions and matrix modifications for determining antimony, arsenic, bismuth, cadmium, gallium, gold, indium, lead, molybdenum, palladium, platinum, selenium, silver, tellurium, thallium and tin following back-extraction of organic aminohalide extracts

A multi-element organic-extraction and back-extraction procedure, that had been developed previously to eliminate matrix interferences in the determination of a large number of trace elements in complex materials such as geological samples, produced organic and aqueous solutions that were complex. Electrothermal atomisation atomic absorption conditions and matrix modifications have been developed for 13 of the extracted elements (Ag, As, Au, Bi, Cd, Ga, In, Pb, Sb, Se, Sn, Te and Tl) that enhance sensitivity, alleviate problems resulting from the complex solutions and produce acceptable precision. Platinum, Pd and Mo can be determined without matrix modification directly on the original unstripped extracts.

Journal of Analytical Atomic Spectrometry↗