Geology Reports⌕ Search

SEARCH · Geology Reports

Results for “The Mountaineer”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,225 records · Page 68Linked to original sources
USGS2015

Holocene environmental changes inferred from biological and sedimentological proxies in a high elevation Great Basin lake in the northern Ruby Mountains, Nevada, USA

Multi-proxy analyses were conducted on a sediment core from Favre Lake, a high elevation cirque lake in the northern Ruby Mountains, Nevada, and provide a ca. 7600 year record of local and regional environmental change. Data indicate that lake levels were lower from 7600-5750 cal yr BP, when local climate was warmer and/or drier than today. Effective moisture increased after 5750 cal yr BP and remained relatively wet, and possibly cooler, until ca. 3750 cal yr BP. Results indicate generally dry conditions but also enhanced climatic variability from 3750-1750 cal yr BP, after which effective moisture increased. The timing of major changes in the Favre Lake proxy data are roughly coeval and in phase with those recorded in several paleoclimate studies across the Great Basin, suggesting regional climatic controls on local conditions and similar responses at high and low altitudes.

Nevada↗
USGS2015

Isotopes in North American Rocky Mountain snowpack 1993–2014

We present ∼1300 new isotopic measurements (δ 18 O and δ 2 H) from a network of snowpack sites in the Rocky Mountains that have been sampled since 1993. The network includes 177 locations where depth-integrated snow samples are collected each spring near peak accumulation. At 57 of these locations snowpack samples were obtained for 10–21 years and their isotopic measurements provide unprecedented spatial and temporal documentation of snowpack isotope values at mid-latitudes. For environments where snowfall accounts for the majority of annual precipitation, snowmelt is likely to have the strongest influence on isotope values retained in proxy archives. In this first presentation of the dataset we (1) describe the basic features of the isotope values in relation to the Global Meteoric Water Line (GMWL), (2) evaluate space for time substitutions traditionally used to establish δ 18 O-temperature relations, (3) evaluate site-to-site similarities across the network and identify those that are the most regionally representative, (4) examine atmospheric circulation patterns for several years with spatially coherent isotope patterns, and (5) provide examples of the implications this new dataset has for interpreting paleoclimate records (Bison Lake, Colorado and Minnetonka Cave, Idaho). Results indicate that snowpack δ 18 O is rarely a simple proxy of temperature. Instead, it exhibits a high degree of spatial heterogeneity and temporal variance that reflect additional processes such as vapor transport and post-depositional modification. Despite these complexities we identify consistent climate-isotope patterns and regionally representative locations that serve to better define Holocene hydroclimate estimates and their uncertainty. Climate change has and will affect western U.S. snowpack and we suggest these changes can be better understood and anticipated by oxygen and hydrogen isotope-based reconstructions of Holocene hydroclimate using a process-based understanding of the controls on snowpack isotope ratios.

Colorado, Idaho, Montana, New Mexico, Wyoming↗
USGS2012

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado↗
USGS2018

Pharmaceuticals, hormones, pesticides, and other bioactive contaminants in water, sediment, and tissue from Rocky Mountain National Park, 2012–2013

Pharmaceuticals, hormones, pesticides, and other bioactive contaminants (BCs) are commonly detected in surface water and bed sediment in urban and suburban areas, but these contaminants are understudied in remote locations. In Rocky Mountain National Park (RMNP), Colorado, USA, BCs may threaten the reproductive success and survival of native aquatic species, benthic communities, and pelagic food webs. In 2012–2013, 67 water, 57 sediment, 63 fish, 10 frog, and 12 quality-control samples (8 water and 4 sediment) were collected from 20 sites in RMNP. Samples were analyzed for 369 parameters including 149 pharmaceuticals, 22 hormones, 137 pesticides, and 61 other chemicals or conditions to provide a representative assessment of BC occurrence within RMNP. Results indicate that BCs were detected in water and/or sediment from both remote and more accessible locations in RMNP. The most commonly detected BCs in water were caffeine, camphor, para-cresol, and DEET; and the most commonly detected BCs in sediment were indole, 3-methyl-1H-indole, para-cresol, and 2,6-dimethyl-naphthalene. Some detected contaminants, including carbaryl, caffeine, and oxycodone, are clearly attributable to direct local human input, whereas others may be transported into the park atmospherically (e.g., atrazine) or have local natural sources (e.g., para-cresol). One or more pharmaceuticals were detected in at least 1 sample from 15 of 20 sites. Most of the 29 detected pharmaceuticals are excreted primarily in human urine, not feces. Elevated net estrogenicity was observed in 18% of water samples, and elevated vitellogenin in blood was observed in 12% of male trout, both evidence of potential endocrine disruption. Hormone concentrations in sediment tended to be greater than concentrations in water. Most BCs were observed at concentrations below those not expected to pose adverse effects to aquatic life. Results indicate that even in remote locations aquatic wildlife can be exposed to pharmaceuticals, hormones, pesticides, and other bioactive contaminants.

Colorado↗
USGS2019

Return flows from beaver ponds enhance floodplain-to-river metals exchange in alluvial mountain catchments

River to floodplain hydrologic connectivity is strongly enhanced by beaver- ( Castor canadensis ) engineered channel water diversions. The hydroecological impacts are wide ranging and generally positive, however, the hydrogeochemical characteristics of beaver-induced flowpaths have not been thoroughly examined. Using a suite of complementary ground- and drone-based heat tracing and remote sensing methodology we characterized the physical template of beaver-induced floodplain exchange for two alluvial mountain streams near Crested Butte, Colorado, USA. A flowpath-oriented perspective to water quality sampling allowed characterization of the chemical evolution of channel water diverted through floodplain beaver ponds and ultimately back to the channel in ‘beaver pond return flows’. Subsurface return flow seepages were universally suboxic, while ponds and surface return flows showed a range of oxygen concentration due to in-situ photosynthesis and atmospheric mixing. Median concentrations of reduced metals: manganese (Mn), iron (Fe), aluminum (Al), and arsenic (As) were substantially higher along beaver-induced flowpaths than in geologically controlled seepages and upstream main channel locations. The areal footprint of reduced return seepage flowpaths were imaged with surface electromagnetic methods, indicating extensive zones of high-conductivity shallow groundwater flowing back toward the main channels and emerging at relatively warm bank seepage zones observed with infrared. Multiple-depth redox dynamics within one focused seepage zone showed coupled variation over time, likely driven by observed changes in seepage rate that may be controlled by pond stage. High-resolution times series of dissolved Mn and Fe collected downstream of the beaver-impacted reaches demonstrated seasonal dynamics in mixed river metal concentrations. Al time series concentrations showed proportional change to Fe at the smaller stream location, indicating chemically reduced flowpaths were sourcing Al to the channel. Overall our results indicated beaver-induced floodplain exchanges create important, and perhaps dominant, transport pathways for floodplain metals by expanding chemically-reduced zones paired with strong advective exchange.

Colorado↗
USGS2019

Inorganic nitrogen wet deposition gradients in the Denver-Boulder metropolitan area and Colorado Front Range – Preliminary implications for Rocky Mountain National Park and interpolated deposition maps

For the first time in the 40-year history of the National Atmospheric Deposition Program / National Trends Network (NADP/NTN), a unique urban-to-rural transect of wet deposition monitoring stations were operated as part of the NTN in 2017 to quantify reactive inorganic nitrogen wet deposition for adjacent urban and rural, montane regions. The transect of NADP stations (sites) was used to collect continuous precipitation depth and weekly wet-deposition samples in the Denver – Boulder, Colorado urban corridor. Gradients in reactive inorganic nitrogen (Nr) concentrations and wet deposition were identified along the transect, which included Rocky Mountain National Park. Back trajectory modeling and stable isotopes suggested contribution of agricultural ammonia (NH3) to urban Nr wet deposition in Denver, but apportionment of wet-deposited Nr to agricultural versus urban mobile sources was not possible for this study. The results demonstrate the importance of multiple monitoring sites across an urban area in defining fine-scale geographic patterns in atmospheric deposition and its sources. Data from new sites located within 50 km of the urban area demonstrate that the urban influence doesn't extend as far as the Inverse Distance Weighting would have suggested without such empirical monitoring data. It is important to determine the radius of influence of urban emissions and associated deposition on the interpolated deposition raster, which is constrained by a paucity of monitoring sites east of Denver.

Colorado↗
USGS2021

Reconnaissance of cumulative risk of pesticides and pharmaceuticals in Great Smoky Mountains National Park streams

The United States (US) National Park Service (NPS) manages protected public lands to preserve biodiversity. Exposure to and effects of bioactive organic contaminants in NPS streams are challenges for resource managers. Recent assessment of pesticides and pharmaceuticals in protected-streams within the urbanized NPS Southeast Region (SER) indicated the importance of fluvial inflows from external sources as drivers of aquatic contaminant-mixture exposures. Great Smoky Mountains National Park (GRSM), lies within SER, has the highest biodiversity and annual visitation of NPS parks, but, in contrast to the previously studied systems, straddles a high-elevation hydrologic divide; this setting limits fluvial-inflows of contaminants but potentially increases visitation-driven contaminant deliveries. We leveraged the unique characteristics of GRSM to test further the importance of fluvial contaminant inflows as drivers of protected-stream exposures and to inform the relative importance of potential additional contaminant transport mechanisms, by comparing the estimated risks of 328 pesticides and pharmaceuticals in water at 16 GRSM stream locations to those estimated previously in SER streams. Extensive mixtures (31 compounds) were only observed in an atypical reach on the boundary of GRSM downstream of a wastewater discharge, while limited mixtures (2–5 compounds) were observed in one stream with elevated visitation pressure (recreational “tube floating”). The insecticide, imidacloprid, used to eradicate hemlock woolly adelgid, was detected in 8 (50%) streams. Infrequent exceedances of a cumulative ToxCast-based, exposure-activity ratio (Σ EAR ) 0.001 screening-level of concern suggested limited risk to non-target, aquatic vertebrates, whereas exceedances of a cumulative benchmark-based, invertebrate toxicity quotient (Σ TQ ) 0.1 screening level at 8 locations indicated generally high risk to invertebrates. The results are consistent with the importance of fluvial transport from extra-park sources as a driver of bioactive-contaminant mixture exposures in protected streams and illustrate the potential additional risks from visitation-driven and tactical-use-pesticides.

Tennessee↗
USGS2017

Rapid exhumation of Cretaceous arc-rocks along the Blue Mountains restraining bend of the Enriquillo-Plantain Garden fault, Jamaica, using thermochronometry from multiple closure systems

The effect of rapid erosion on kinematic partitioning along transpressional plate margins is not well understood, particularly in highly erosive climates. The Blue Mountains restraining bend (BMRB) of eastern Jamaica, bound to the south by the left-lateral Enriquillo-Plantain Garden fault (EPGF), offers an opportunity to test the effects of highly erosive climatic conditions on a 30-km-wide restraining bend system. No previous thermochronometric data exists in Jamaica to describe the spatial or temporal pattern of rock uplift and how oblique (> 20°) plate motion is partitioned into vertical strain. To define the exhumation history, we measured apatite (n = 10) and zircon (n = 6) (U-Th)/He ages, 40Ar/39Ar (n = 2; amphibole and K-spar) ages, and U/Pb zircon (n = 2) crystallization ages. Late Cretaceous U/Pb and 40Ar/39Ar ages (74–68 Ma) indicate rapid cooling following shallow emplacement of plutons during north-south subduction along the Great Caribbean Arc. Early to middle Miocene zircon helium ages (19–14 Ma) along a vertical transect suggest exhumation and island emergence at ~ 0.2 mm/yr. Older zircon ages 10–15 km to the north (44–35 Ma) imply less rock uplift. Apatite helium ages are young (6–1 Ma) across the entire orogen, suggesting rapid exhumation of the BMRB since the late Miocene. These constraints are consistent with previous reports of restraining bend formation and early emergence of eastern Jamaica. An age-elevation relationship from a vertical transect implies an exhumation rate of 0.8 mm/yr, while calculated closure depths and thermal modeling suggests exhumation as rapid as 2 mm/yr. The rapid rock uplift rates in Jamaica are comparable to the most intense transpressive zones worldwide, despite the relatively slow (5–7 mm/yr) strike-slip rate. We hypothesize highly erosive conditions in Jamaica enable a higher fraction of plate motion to be accommodated by vertical deformation. Thus, strike-slip restraining bends may evolve differently depending on erosivity and local climate.

Tectonophysics↗
USGS2007

Effects of supplemental feeding on gastrointestinal parasite infection in Rocky Mountain Elk (Cervus elaphus): Preliminary observations

The effects of management practices on the spread and impact of parasites and infectious diseases in wildlife and domestic animals are of increasing concern worldwide, particularly in cases where management of wild species can influence disease spill-over into domestic animals. In the Greater Yellowstone Ecosystem, USA, winter supplemental feeding of Rocky Mountain elk ( Cervus elaphus ) may enhance parasite and disease transmission by aggregating elk on feedgrounds. In this study, we tested the effect of supplemental feeding on gastrointestinal parasite infection in elk by comparing fecal egg/oocyst counts of fed and unfed elk. We collected fecal samples from fed and unfed elk at feedground and control sites from January to April 2006, and screened all samples for parasites. Six different parasite types were identified, and 48.7% of samples were infected with at least one parasite. Gastrointenstinal (GI) nematodes (Nematoda: Strongylida), Trichuris spp., and coccidia were the most common parasites observed. For all three of these parasites, fecal egg/oocyst counts increased from January to April. Supplementally fed elk had significantly higher GI nematode egg counts than unfed elk in January and February, but significantly lower counts in April. These patterns suggest that supplemental feeding may both increase exposure and decrease susceptibility of elk to GI nematodes, resulting in differences in temporal patterns of egg shedding between fed and unfed elk.

Wyoming↗
USGS2001

Eddy covariance measurement of CO2 flux to the atmosphere from a area of high volcanogenic emissions, Mammoth Mountain, California

Three pilot studies were performed to assess application of the eddy covariance micrometeorological method in the measurement of carbon dioxide (CO 2 ) flux of volcanic origin. The selected study area is one of high diffuse CO 2 emission on Mammoth Mountain, CA. Because terrain and source characteristics make this a complex setting for this type of measurement, added consideration was given to source area and upwind fetch. Footprint analysis suggests that the eddy covariance measurements were representative of an upwind elliptical source area (3.8×10 3 m 2 ) which can vary with mean wind direction, surface roughness, and atmospheric stability. CO 2 flux averaged 8–16 mg m −2 s −1 (0.7–1.4 kg m −2 day −1 ). Eddy covariance measurements of flux were compared with surface chamber measurements made in separate studies [Geophys. Res. Lett. 25 (1998a) 1947; EOS Trans. 79 (1998) F941.] and were found to be similar.

Chemical Geology↗
USGS2001

Soil efflux and total emission rates of magmatic CO2 at the horseshoe lake tree kill, mammoth mountain, California, 1995-1999

We report the results of eight soil CO2 efflux surveys by the closed circulation chamber method at the Horseshoe Lake tree kill (HLTK) - the largest tree kill on Mammoth Mountain. The surveys were undertaken from 1995 to 1999 to constrain total HLTK CO2 emissions and to evaluate occasional efflux surveys as a surveillance tool for the tree kills. HLTK effluxes range from 1 to > 10,000 g m -2 day -1 (grams CO2 per square meter per day); they are not normally distributed. Station efflux rates can vary by 7-35% during the course of the 8- to 16-h surveys. Disturbance of the upper 2 cm of ground surface causes effluxes to almost double. Semivariograms of efflux spatial covariance fit exponential or spherical models; they lack nugget effects. Efflux contour maps and total CO2 emission rates based on exponential, spherical, and linear kriging models of survey data are nearly identical; similar results are also obtained with triangulation models, suggesting that the kriging models are not seriously distorted by the lack of normal efflux distributions. In addition, model estimates of total CO2 emission rates are relatively insensitive to the measurement precision of the efflux rates and to the efflux value used to separate magmatic from forest soil sources of CO2. Surveys since 1997 indicate that, contrary to earlier speculations, a termination of elevated CO2 emissions at the HLTK is unlikely anytime soon. The HLTK CO2 efflux anomaly fluctuated greatly in size and intensity throughout the 1995-1999 surveys but maintained a N-S elongation, presumably reflecting fault control of CO2 transport from depth. Total CO2 emission rates also fluctuated greatly, ranging from 46 to 136 t day-1 (metric tons CO2 per day) and averaging 93 t day-1. The large inter-survey variations are caused primarily by external (meteorological) processes operating on time scales of hours to days. The externally caused variations can mask significant changes occurring at depth; a striking example is the masking of a degassing event generated at depth and detected by a soil gas sensor network in September 1997 while an efflux survey was in progress. Thus, occasional efflux surveys are not an altogether effective surveillance tool for the HLTK, and making them effective by greatly increasing their frequency may not be practical. Published by Elsevier Science B.V.

Chemical Geology↗
USGS2003

Lithologic mapping in the Mountain Pass, California area using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data

Evaluation of an Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) image of the Mountain Pass, California area indicates that several important lithologic groups can be mapped in areas with good exposure by using spectral-matching techniques. The three visible and six near-infrared bands, which have 15-m and 30-m resolution, respectively, were calibrated by using in situ measurements of spectral reflectance. Calcitic rocks were distinguished from dolomitic rocks by using matched-filter processing in which image spectra were used as references for selected spectral categories. Skarn deposits and associated bright coarse marble were mapped in contact metamorphic zones related to intrusion of Mesozoic and Tertiary granodioritic rocks. Fe-muscovite, which is common in these intrusive rocks, was distinguished from Al-muscovite present in granitic gneisses and Mesozoic granite. Quartzose rocks were readily discriminated, and carbonate rocks were mapped as a single broad unit through analysis of the 90-m resolution, five-band surface emissivity data, which is produced as a standard product at the EROS Data Center. Three additional classes resulting from spectral-angle mapper processing ranged from (1) a broad granitic rock class (2) to predominately granodioritic rocks and (3) a more mafic class consisting mainly of mafic gneiss, amphibolite and variable mixtures of carbonate rocks and silicate rocks. ?? 2002 Elsevier Science Inc. All rights reserved.

Remote Sensing of Environment↗
USGS1998

Controls on denitrification in riparian soils in headwater catchments of a hardwood forest in the Catskill Mountains, U.S.A.

Denitrification in riparian soils is thought to be an important factor that reduces hydrologic export of nitrate from forested and agricultural catchments. A 2-y study to identify the soil factors most closely associated with denitrification in riparian soils in headwater catchments within the Catskill Mountains of New York, included field surveys of surface and subsurface denitrification rates, and an amendment experiment to assess the relative effects of increases in available carbon and substrate NO-/3 on denitrification rates. Denitrification rates were measured by acetylene inhibition during incubation of intact soil cores from eight soil types representing a range of drainage classes. Soil cores were analyzed for organic matter, total P, extractable NO-/3-N and NH+/4-N, organic N, pH, moisture, porosity, and water-filled pore space, to determine which of these factors were most closely associated with denitrification. The distribution of denitrification rates found during the field surveys was highly skewed, with many low or zero values and few high values. Denitrification rates were positively associated with high soil organic matter, total P, and water-filled pore space, and were highest in seep (poorly-drained) soils, toeslope (seasonally-drained) soils, and stream-edge (poorly- to moderately well-drained) soils in which these three soil characteristics were typically high. Denitrification rates in these wet locations were also positively associated with soil NH+/4-N concentration and pH, but not with NO-/3-N concentration, suggesting that the rate of NO-/3 supply (via nitrification or hydrologic transport) was more important than the instantaneous concentration of NO-/3-N in the soils. The amendment experiment indicated that denitrification in soil types studied was most responsive to added glucose alone or with NO-/3. Thus, in these soils, a combination of slow rates of NO-/3 supply and low available carbon appears to limit denitrification. Annual denitrification rates in spring-fed soils (0.74 to 1.43 kg N ha-1 y-1) were up to 5 times greater than in other surface soils, yet these soils accounted for only 1.8% of the catchment's N loss through denitrification because they represent less than 3% of the catchment area. Dry upland soils constituted 71% of the catchment area and accounted for 91% of the catchment's N loss through denitrification. Annual denitrification in the catchment equaled about 65% of stream NO-/3-N and NH+/4-N export and 14% of precipitation NO-/3-N and NH+/4-N inputs. Denitrification appears to be important relative to N input and export in these Catskill catchments.

Soil Biology and Biochemistry↗
USGS1997

Dual-porosity analysis of conservative tracer testing in saturated volcanic rocks at Yucca Mountain in Nye County, Nevada

A radially convergent conservative tracer injection test was conducted between boreholes UE-25 #2 and UE-25 c #3 of the C-hole complex at Yucca Mountain to determine effective porosity and longitudinal dispersivity. Approximately 47% of the tracer mass was recovered and a dual-porosity analytical model replicates the breakthrough curve. Fractured-rock analyses focus on the fracture-porosity and geometry as the controlling factors in transport.

International Journal of Rock Mechanics and Mining↗
USGS1996

Application of reflectance micro-Fourier Transform infrared analysis to the study of coal macerals: An example from the Late Jurassic to Early Cretaceous coals of the Mist Mountain Formation, British Columbia, Canada

The applicability of the reflectance micro-Fourier Transform infra-red spectroscopy (FTIR) technique for analyzing the distribution of functional groups in coal macerals is discussed. High quality of spectra, comparable to those obtained using other FTIR techniques (KBr pellet and transmission micro-FTIR), indicate this technique can be applied to characterizing functional groups under most conditions. The ease of sample preparation, the potential to analyze large intact samples, and ability to characterize organic matter in areas as small as 20 ??m are the main advantages of reflectance micro-FTIR. The quantitative aspects of reflectance micro-FTIR require further study. The examples from the coal seams of the Mist Mountain Formation, British Columbia show that at high volatile bituminous rank, reflectance micro-FTIR provides valuable information on the character of aliphatic chains of vitrinite and liptinite macerals. Because the character of aliphatic chains influences bond disassociation energies, such information is useful from a hydrocarbon generation viewpoint. In medium volatile bituminous coal liptinite macerals are usually not detectable but this technique can be used to study the degree of oxidation and reactivity of vitrinite and semifusinite.

International Journal of Coal Geology↗
USGS2003

Airflows and turbulent flux measurements in mountainous terrain: Part 1. Canopy and local effects

We have studied the effects of local topography and canopy structure on turbulent flux measurements at a site located in mountainous terrain within a subalpine, coniferous forest. Our primary aim was to determine whether the complex terrain of the site affects the accuracy of eddy flux measurements from a practical perspective. We observed displacement heights, roughness lengths, spectral peaks, turbulent length scales, and profiles of turbulent intensities that were comparable in magnitude and pattern to those reported for forest canopies in simpler terrain. We conclude that in many of these statistical measures, the local canopy exerts considerably more influence than does topographical complexity. Lack of vertical flux divergence and modeling suggests that the flux footprints for the site are within the standards acceptable for the application of flux statistics. We investigated three different methods of coordinate rotation: double rotation (DR), triple rotation (TR), and planar-fit rotation (PF). Significant variability in rotation angles at low wind speeds was encountered with the commonly used DR and TR methods, as opposed to the PF method, causing some overestimation of the fluxes. However, these differences in fluxes were small when applied to large datasets involving sensible heat and CO 2 fluxes. We observed evidence of frequent drainage flows near the ground during stable, stratified conditions at night. Concurrent with the appearance of these flows, we observed a positive bias in the mean vertical wind speed, presumably due to subtle topographic variations inducing a flow convergence below the measurement sensors. In the presence of such drainage flows, advection of scalars and non-zero bias in the mean vertical wind speed can complicate closure of the mass conservation budget at the site.

Agricultural and Forest Meteorology↗
USGS2003

Lithogeochemistry of Carlin-type gold mineralization in the Gold Bar district, Battle Mountain-Eureka trend, Nevada

The Gold Bar district contains five Carlin-type gold deposits and four resources for a combined gold endowment of 1.6 M oz [50 t]. The gold deposits are hosted in Devonian carbonate rocks below parautochthonous and allochthonous Paleozoic siliciclastic rocks emplaced during the Early Mississippian Antler orogeny. The district is in the Battle Mountain-Eureka trend, a long-lived structural feature that localized intrusions and ore deposits of different types and ages. The whole-rock geochemistry of four different mineralized and unmineralized Devonian carbonate rock units (two favorable and two unfavorable) were determined and interpreted in the context of the regional geology. A combination of basic statistics, R-mode factor analysis, isocon plots, and alteration diagrams were utilized to (1) identify favorable geochemical attributes of the host rocks, (2) characterize alteration and associated element enrichments and depletions, and (3) identify the mechanism of gold precipitation. This approach also led to the recognition of other types of alteration and mineralization in host rocks previously thought to be solely affected by Carlin-type mineralization. Unit 2 of the Upper Member of the Denay Formation, with the highest Al2O3, Fe2O3 and SiO2 contents and the lowest CaO content, is the most favorable host rock. Based on the high regression coefficients of data arrays on X-Y plots that project toward the origin, Al2O3 and TiO2 were immobile and K2O and Fe2O3 were relatively immobile during alteration and mineralization. Specific element associations identified by factor analysis are also prominent on isocon diagrams that compare the composition of fresh and altered equivalents of the same rock units. The most prominent associations are: Au, As, Sb, SiO2, TI, -CaO and -LOI, the main gold mineralizing event and related silicification and decalcification; Cd, Zn, Ag, P, Ni and Tl, an early base metal event; and MgO, early dolomitization. Alteration diagrams, consisting of X-Y plots of SiO2/Al2O3, K2O/Al2O3, CO2/Al2O3, that documented in classic Carlin-type gold deposits in the region, but the size of the deposits and the intensity of alteration and mineralization are less. The presence of other types of mineralization in the Gold Bar district is also common to most of the other Carlin-type districts located in major mineral belts. The approach used in this study is well suited to the interpretation of multi-element geochemical data from other study areas with superimposed alteration and mineralization. ?? 2002 Elsevier Science B.V. All rights reserved.

Ore Geology Reviews↗
USGS2003

Chemical analyses of pore water from boreholes USW SD-6 and USW WT-24, Yucca Mountain, Nevada

Analyses of pore water extracted from cores of boreholes USW SD-6 in the central part and USW WT-24 in the northern part of Yucca Mountain, Nevada, show significant vertical and lateral variations in dissolved-ion concentrations. Analyses of samples of only a few milliliters of pore water extracted by uniaxial or triaxial compression and by ultracentrifugation methods from adjacent core samples are generally in agreement, within the analytical error of 10% to 15%. However, the values of silica for water obtained by ultracentrifugation are consistently lower than values for water obtained by compression. The larger concentrations probably are due to localized pressure solution of silicate minerals during compression. The shallower water from core in borehole USW SD-6 was extracted from nonwelded units collectively referred to as the Paintbrush Tuff nonwelded (PTn). The deeper water was from core in both boreholes USW SD-6 and USW WT-24 in the nonwelded units referred to as the Calico Hills nonwelded (CHn). Significant differences in mean dissolved-ion concentrations in pore water between the PTn and CHn are (1) decreases in Ca, Mg, SO4, and NO3 and (2) increases in HCO3 and (Na+K)/(Ca+Mg) ratios. The decrease in NO3 and the increase in HCO3 could be the result of denitrification through the oxidation of organic matter. The decrease in Ca and associated increase in (Na+K)/(Ca+Mg) is the result of ion exchange with zeolites in the CHn in borehole USW WT-24. This effect is not nearly as pronounced in borehole USW SD-6, probably reflecting a smaller amount of zeolitization of the CHn in USW SD-6. Geochemical calculations using the PHREEQC code indicate that the pore water from both boreholes USW SD-6 and USW WT-24 is uniformly undersaturated in anhydrite, gypsum, and amorphous silica, but supersaturated in quartz and chalcedony. The saturation of calcite, aragonite, sepiolite, and dolomite is more variable from sample to sample. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology↗