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Water-quality, bed-sediment, and biological data (October 2014 through September 2015) and statistical summaries of data for streams in the Clark Fork Basin, Montana

Water, bed sediment, and biota were sampled in selected streams from Butte to near Missoula, Montana, as part of a monitoring program in the upper Clark Fork Basin of western Montana. The sampling program was led by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the Clark Fork Basin, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water samples were collected periodically at 20 sites from October 2014 through September 2015. Bed-sediment and biota samples were collected once at 13 sites during August 2015. This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at sites from October 2014 through September 2015. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. At 12 sites, samples for analysis of dissolved organic carbon and turbidity were collected. In addition, samples for analysis of nitrogen (nitrate plus nitrite) were collected at two sites. Daily values of mean suspended-sediment concentration and suspended-sediment discharge were determined for three sites. Seasonal daily values of turbidity were determined for four sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of water-quality, bed-sediment, and biological data for sites in the upper Clark Fork Basin are provided for the period of record.

Montana↗

Water-quality, bed-sediment, and biological data (October 2015 through September 2016) and statistical summaries of data for streams in the Clark Fork Basin, Montana

Water, bed sediment, and biota were sampled in selected streams from Butte to near Missoula, Montana, as part of a monitoring program in the upper Clark Fork Basin of western Montana. The sampling program was led by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the Clark Fork Basin, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were on the Clark Fork and selected tributaries. Water samples were collected periodically at 20 sites from October 2015 through September 2016. Bed-sediment and biota samples were collected once at 13 sites during August 2016. This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at sites from October 2015 through September 2016. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Samples for analysis of turbidity were collected at 13 sites, whereas samples for analysis of dissolved organic carbon were collected at 10 sites. In addition, samples for analysis of nitrogen (nitrate plus nitrite) were collected at two sites. Daily values of mean suspended-sediment concentration and suspended-sediment discharge were determined for three sites. Seasonal daily values of turbidity were determined for five sites. Bed-sediment data include trace-element concentrations in the fine-grained (less than 0.063 millimeter) fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of water-quality, bed-sediment, and biological data for sites in the upper Clark Fork Basin are provided for the period of record.

Montana↗

Geologic map of the east half of the Bellevue South 7.5' x 15' quadrangle, Issaquah area, King County, Washington

The Issaquah area includes several of the most outstanding geologic features of the eastern Puget Lowland region. Folds have warped thousands of meters of Tertiary sedimentary and volcanic rocks. Several hundred meters of both glacial and postglacial sediment have accumulated in a deep glacial trough, which is now partly occupied by Lake Sammamish but which was previously the conduit for massive volumes of meltwater during ice-sheet occupation and retreat. The eastern projection of an east-west-oriented crustal structure, which reflects Tertiary through Holocene fault displacement, extends across the eastern part of the map area. In addition to these geologic features, some of the most rapid human alteration of the landscape in the entire Puget Lowland has occurred here. Since the 19th century, coal was extensively mined and, since the early 1980s, the region has been overtaken by urbanization. In places, this alteration has dramatically accelerated the rate of geomorphic processes. For example, the hillsides have been regraded as a result of mining and quarries throughout the southern one-third of the quadrangle; stream channels have recently incised above the eastern shores of Lake Sammamish; and sediments have deposited on the lakeshore and into the lake itself.

Washington↗

Quantification of trace element loading in the upper Tenmile Creek drainage basin near Rimini, Montana, September 2011

The principle sources of trace elements entering upper Tenmile Creek, Montana, during September 2011, four trace metals and the metalloid arsenic, were identified and quantified by combining and analyzing streamflow data determined from tracer injection with trace-element concentrations and related water-quality data determined from synoptic sampling. The study reach was along upper Tenmile Creek, beginning downstream from the city of Helena’s diversion and extending 5,020 feet downstream. Results from the 2011 study, completed by the U.S. Geological Survey in cooperation with the Montana Department of Environmental Quality, were compared to results from a similar study conducted in 1998 to assess the effectiveness of mine reclamation and remediation work to reduce trace-element loading to upper Tenmile Creek, which has been ongoing throughout the drainage basin. Main-stem concentrations of most trace elements analyzed were generally greater in 1998 than in 2011. However, the State of Montana human-health criteria for total-recoverable cadmium and arsenic were exceeded in parts of upper Tenmile Creek, and concentrations of cadmium and zinc exceeded the acute aquatic-life criteria at all main-stem sites during both studies. Total-recoverable copper concentrations observed in 2011 exceeded the chronic aquatic-life criterion upstream from the Lee Mountain adit, whereas, in 1998, all sites exceeded the acute aquatic-life criteria. Direct comparison of loads from the 1998 and 2011 tracer studies were complicated by the differences in hydrologic conditions. Streamflow in 1998 was about 10 percent of the 2011 streamflow. The Lee Mountain Mine and Susie Lode adit were identified as major contributors of trace elements to upper Tenmile Creek in both studies. However, trace-element loading from the Lee Mountain Mine area was substantially reduced between 1998 and 2011. Total-recoverable loads of all trace elements showed substantial loss in 1998 but increased in 2011 downstream from the Susie Lode adit to the end of the study reach. This reach was one of the primary sources of trace-element loading to upper Tenmile Creek in 2011. This difference indicated that the streambed may act as a sink or a source for trace elements, depending on hydrologic conditions.

Montana↗

Geophysical assessment of a proposed landfill site in Fredericktown, Missouri

In June 2018, U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency (EPA) collected geophysical measurements to help evaluate the suitability of a proposed landfill site for disposing mine-waste materials in Fredericktown, MO. The geophysical investigation included electromagnetic induction, electrical resistivity tomography, horizontal-to-vertical spectral ratio passive seismic, and shear-wave refraction to characterize the unconsolidated sediment or regolith above the bedrock and the depth to crystalline bedrock. Water-based electromagnetic surveys and forward looking infrared imagery were used along the lake shoreline to identify potential groundwater-surface water interactions. Nested piezometers were installed at two locations along the shoreline to further characterize and validate the groundwater-surface water interactions identified with geophysical methods. Collectively, geophysical surveys were used to evaluate the overall suitability of the proposed site for use as a mine waste-soil and sediment repository and to evaluate this suite of geophysical methods for rapid collection and assessment of very shallow sediments.

Missouri↗

Raster images of geologic maps of Middle Proterozoic Belt strata in parts of Benewah, Bonner, Kootenai and Shoshone Counties, Idaho and Lincoln, Mineral and Sanders Counties, Montana

Geologic maps of the western part of the Belt Basin of western Montana and northern Idaho were converted into digital raster (TIFF image) format to facilitate their manipulation in geographic information systems. The 85-mile x 100-mile map area mostly contains rocks belonging to the lower and middle Belt Supergroup. The area is of interest as these Middle Proterozoic strata contain vein-type lead-zinc-silver deposits in the Coeur d?Alene Mining District in the St. Regis and Revett formations and strata-bound copper-silver deposits, such as the Troy mine, within the Revett Formation. The Prichard Formation is also prospective for strata-bound lead-zinc deposits because equivalent Belt strata in southern British Columbia, Canada host the Sullivan lead-zinc deposit. Map data converted to digital images include 13 geological maps at scales ranging from 1:48,000 to 1:12,000. Geologic map images produced from these maps by color scanning were registered to grid tick coverages in a Universal Transverse Mercator (North American Datum of 1927, zone 11) projection using ArcView Image Analysis. Geo-registering errors vary from 10 ft to 114 ft.

Idaho, Montana↗

Chemical quality of surface water in the Allegheny River basin, Pennsylvania and New York

The Allegheny River is the principal source of water to many industries and to communities in the upper Ohio River Valley. The river and its many tributaries pass through 19 counties in northwestern and western Pennsylvania. The population in these counties exceeds 3 million. A major user of the Allegheny River is the city of Pittsburgh, which has a population greater than The Allegheny River is as basic to the economy of the upper Ohio River Valley in western Pennsylvania as are the rich deposits of bituminous coal, gas, and oil that underlie the drainage basin. During the past 5 years many streams that flow into the Allegheny have been low flowing because of droughts affecting much of the eastern United States. Consequently, the concentration of solutes in some streams has been unusually high because of wastes from coal mines and oil wells. These and other water-quality problems in the Allegheny River drainage basin are affecting the economic future of some areas in western Pennsylvania. Because of environmental factors such as climate, geology, and land and water uses, surface-water quality varies considerably throughout the river basin. The natural quality of headwater streams, for example, is affected by saltwater wastes from petroleum production. One of the streams most affected is Kinzua Creek, which had 2,900 parts per million chloride in a sample taken at Westline on September 2, 1959. However, after such streams as the Conewango, Brokenstraw, Tionesta, Oil, and French Creeks merge with the Allegheny River, the dissolved-solids and chloride concentrations are reduced by dilution. Central segments of the main river receive water from the Clarion River, Redbank, Mahoning, and Crooked Creeks after they have crossed the coal fields of west-central Pennsylvania. At times, therefore, these streams carry coal-mine wastes that are acidic. The Kiskiminetas River, which crosses these coal fields, discharged sulfuric acid into the Allegheny at a rate of 299 tons a day during the 1962 water year (October 1, 1961, to September 30, 1962). Mine water affects the quality of the Allegheny River most noticeably in its lower part where large withdrawals are made by the Pittsburgh Water Company at Aspinwall and the Wilkinsburg-Penn Joint Water Authority at Nadine. At these places raw river water is chemically .treated in modern treatment plants to control such objectionable characteristics as acidity and excessive concentrations of iron and manganese. Dissolved-solids content in the river varies along its entire length. In its upper reaches the water of the Allegheny River is a sodium chloride type, and at low flow, the sodium chloride is more than half the dissolved solids. In its lower reaches the water is a calcium sulfate .type, and at low flow the calcium sulfate is more than half the dissolved solids. In middle segments of the river from Franklin to Kittanning, water is more dilute and of a mixed type. Many small and several larger streams in the upper basin--such as the Conewango, Brokenstraw, Kinzua, Tionesta, and French Creeks--support large populations of game-fish. Even in segments of the Clarion River, Mahoning, and Redbank Creeks, which are at times affected by coal-mine wastes, fish are present. Although different species withstand varying amounts of contaminants in water, the continued presence of the fish indicates that the water is relatively pure and suitable for recreation and many other uses.

Water Supply Paper↗

Sand supply to San Francisco Bay from the Sacramento and San Joaquin Rivers of the Central Valley, California

Sediment from the Central Valley via the Sacramento-San Joaquin Delta (Delta) and Suisun Bay is a primary source of sand to San Francisco Bay, California. Sand is mined from San Francisco Bay for commercial purposes, such as for use in concrete for construction. To better understand the supply of sand to Suisun Bay and San Francisco Bay, the U.S. Geological Survey (USGS), in cooperation with the San Francisco Bay Estuary Institute (SFEI) and the San Francisco Bay Conservation Development Commission (BCDC), initiated this study to compile and synthesize historical data and estimate the total sediment and sand portion of sediment exiting the Delta to Suisun Bay for a 20-year period between water years 2001 and 2020. Sediment exiting the Delta is a combination of suspended sediment and bedload sediment. Seaward bedload transport was estimated using bedload transport equations and available hydraulic data at the two downstream-most streamgages in the Delta (where velocity is measured). Those two streamgages are about 25 kilometers upstream from the “exit” of the Delta at Mallard Island. The combined average annual net (seaward) bedload at these two streamgages was estimated to be 0.102 million cubic meters per year (Mm 3 /yr) for the study period. This volume of bedload is equivalent to 0.155 million metric tons per year (Mt/yr), assuming a bulk density of 1.517 metric tons per cubic meter (t/m 3 ). The bedload composition was estimated to be 88 percent sand. Between the two streamgages and Mallard Island, an annual average of 0.076 Mm 3 /yr of material was removed through mining during the study period, of which 97.5 percent was sand. In addition, 0.053 Mm 3 /yr was removed through dredging to support shipping and navigation, of which 76 percent was sand. The total volume of mined and dredged sediment material was approximately 0.128 Mm 3 /yr, equivalent to 0.194 Mt/yr, assuming a bulk density of 1.517 t/m 3 . Assuming the estimated bedload reaching Mallard Island was reduced by mining and dredging, a mean bedload flux of −0.009 Mm 3 /yr was computed (using a bulk density of 1.517 t/m 3 ), suggesting a deficit or landward transport of bedload. However, the total suspended-sediment and suspended-sand flux was in the seaward direction. The average total suspended flux of sediment to Suisun Bay through the cross section at the Mallard Island streamgage was estimated to be 0.482 million metric tons per year (Mt/yr; 0.015 Mt/yr sand) in the seaward direction. The results indicate a net flux out of the Delta of 0.469 Mt/yr of total sediment and 0.003 Mt/yr of sand. The primary limitation of the study was the lack of physical bedload measurements to validate the bedload estimates. To better refine the estimates of bedload, physical measurements of bedload or repeat bathymetry would be necessary for a range of flow conditions. Such measurements could be used to calibrate transport equations and quantify the uncertainty in such estimates.

California↗

Characteristic analysis-1981: Final program and a possible discovery

The latest ornewest version of thecharacteristicanalysis (NCHARAN)computer program offers the exploration geologist a wide variety of options for integrating regionalized multivariate data. The options include the selection of regional cells for characterizing deposit models, the selection of variables that constitute the models, and the choice of logical combinations of variables that best represent these models. Moreover, the program provides for the display of results which, in turn, makes possible review, reselection, and refinement of a model. Most important, the performance of the above-mentioned steps in an interactive computing mode can result in a timely and meaningful interpretation of the data available to the exploration geologist. The most recent application of characteristic analysis has resulted in the possible discovery of economic sulfide mineralization in the Grong area in central Norway. Exploration data for 27 geophysical, geological, and geochemical variables were used to construct a mineralized and a lithogeochemical model for an area that contained a known massive sulfide deposit. The models were applied to exploration data collected from the Gjersvik area in the Grong mining district and resulted in the identification of two localities of possible mineralization. Detailed field examination revealed the presence of a sulfide vein system and a partially inverted stratigraphic sequence indicating the possible presence of a massive sulfide deposit at depth. ?? 1983 Plenum Publishing Corporation.

Journal of the International Association for Mathe↗

Occurrence, distribution, and volume of metals-contaminated sediment of selected streams draining the Tri-State Mining District, Missouri, Oklahoma, and Kansas, 2011–12

Lead and zinc were mined in the Tri-State Mining District (TSMD) of southwest Missouri, northeast Oklahoma, and southeast Kansas for more than 100 years. The effects of mining on the landscape are still evident, nearly 50 years after the last mine ceased operation. The legacies of mining are the mine waste and discharge of groundwater from underground mines. The mine-waste piles and underground mines are continuous sources of trace metals (primarily lead, zinc, and cadmium) to the streams that drain the TSMD. Many previous studies characterized the horizontal extent of mine-waste contamination in streams but little information exists on the depth of mine-waste contamination in these streams. Characterizing the vertical extent of contamination is difficult because of the large amount of coarse-grained material, ranging from coarse gravel to boulders, within channel sediment. The U.S. Geological Survey, in cooperation with U.S. Fish and Wildlife service, collected channel-sediment samples at depth for subsequent analyses that would allow attainment of the following goals: (1) determination of the relation between concentration and depth for lead, zinc and cadmium in channel sediments and flood-plain sediments, and (2) determination of the volume of gravel-bar sediment from the surface to the maximum depth with concentrations of these metals that exceeded sediment-quality guidelines. For the purpose of this report, volume of gravel-bar sediment is considered to be distributed in two forms, gravel bars and the wetted channel, and this study focused on gravel bars. Concentrations of lead, zinc, and cadmium in samples were compared to the consensus probable effects concentration (CPEC) and Tri-State Mining District specific probable effects concentration (TPEC) sediment-quality guidelines. During the study, more than 700 sediment samples were collected from borings at multiple sites, including gravel bars and flood plains, along Center Creek, Turkey Creek, Shoal Creek, Tar Creek, and Spring River in order to characterize the vertical extent of mine waste in select streams in the TSMD. The largest concentrations of lead, zinc, and cadmium in gravel bar-sediment samples generally were detected in Turkey Creek and Tar Creek and the smallest concentrations were detected in Shoal Creek followed by the Spring River. Gravel bar-sediment samples from Turkey Creek exceeded the CPEC for cadmium (minimum of 70 percent of samples), lead (94 percent), and zinc (99 percent) at a slightly higher frequency than similar samples from Tar Creek (69 percent, 88 percent, and 96 percent, respectively). Gravel bar-sediment samples from Turkey Creek also contained the largest concentrations of cadmium (174 milligrams per kilogram [mg/kg]) and lead (7,520 mg/kg) detected; however, the largest zinc concentration (46,600 mg/kg) was detected in a gravel bar-sediment sample from Tar Creek. In contrast, none of the 65 gravel bar-sediment samples from Shoal Creek contained cadmium above the x-ray fluorescence reporting level of 12 mg/kg, and lead and zinc exceeded the CPEC in only 12 percent and 74 percent of samples, respectively. In most cases, concentrations of lead and zinc above the CPEC or TPEC were present at the maximum depth of boring, which indicated that nearly the entire thickness of sediment in the stream has been contaminated by mine wastes. Approximately 284,000 cubic yards of channel sediment from land surface to the maximum depth that exceeded the CPEC and approximately 236,000 cubic yards of channel sediment from land surface to the maximum depth that exceeded the TPEC were estimated along 37.6 of the 55.1 miles of Center Creek, Turkey Creek, Shoal Creek, and Tar Creek examined in this study. Mine-waste contamination reported along additional reaches of these streams is beyond the scope of this study. Flood-plain cores collected in the TSMD generally only had exceedances of the CPEC and TPEC for lead and zinc in the top 1 or 2 feet of soil with a few exceptions, such as cores in low areas near the stream or cores in areas disturbed by past mining.

Kansas, Missouri, Oklahoma↗

Ground magnetic and VLF studies at Midnite uranium mine, Stevens County, Washington

Ground magnetic and E-mode VLF measurements were made at more than 200 stations at the Midnite uranium Mine, Stevens County, Washington. The equipment was found to be light and foolproof, and each set of data was collected in one day, exclusive of surveying and marking the station points. The maps of contoured magnetic and VLF data resembled geologic maps of the area, showing many common features, as well as a few unique features on each map. Each showed some evidence of a small normal fault cutting the region; taken together, the evidence for this fault was judged to be much stronger, so that further structural details were inferred. Because of soil cover and inadequate outcrops, the presence of this fault had hitherto been unsuspected. A target area for further uranium mineralization north of the fault was indicated by this quick, inexpensive geophysical survey. The drilling program which Midnite Mine management had underway at that time had already outlined a mineralized zone in the indicated area.

Washington↗

The critical minerals initiative of the U.S. Geological Survey’s mineral deposit database project: USMIN

The objective of the US Geological Survey’s mineral deposit database project (USMIN) is to develop a comprehensive twenty-first century geospatial database that is the authoritative source of the most important mines, mineral deposits, and mineral districts of the US. Since May 2017, the project has focused on critical minerals. Data for critical minerals that are produced as products are relatively robust, whereas data for critical minerals that may be recovered as byproducts are commonly of much poorer quality. Similarly, more is known about critical minerals that occur in conventional deposits than where those critical minerals occur in unconventional deposits. For example, rare earth elements occur principally in deposits hosted by alkaline igneous rocks, but there is potential for their production from phosphate rock mining, which is less documented. Lithium (Li) has been recovered from pegmatites and brines, but other Li-bearing deposit types have been delineated that may go into production. Cobalt may be produced as a byproduct or coproduct from a wide range of mineral deposit types, whereas rhenium is a byproduct of copper ore. Significant opportunities for research exist that could help identify new sources of critical minerals, and may also help increase production and recovery from existing sources.

Mining, Metallurgy & Exploration (MME)↗

Magmatic ore deposits in layered intrusions - Descriptive model for reef-type PGE and contact-type Cu-Ni-PGE deposits

Layered, ultramafic to mafic intrusions are uncommon in the geologic record, but host magmatic ore deposits containing most of the world's economic concentrations of platinum-group elements (PGE) (figs. 1 and 2). These deposits are mined primarily for their platinum, palladium, and rhodium contents (table 1). Magmatic ore deposits are derived from accumulations of crystals of metallic oxides, or immiscible sulfide, or oxide liquids that formed during the cooling and crystallization of magma, typically with mafic to ultramafic compositions. "PGE reefs" are stratabound PGE-enriched lode mineralization in mafic to ultramafic layered intrusions. The term "reef" is derived from Australian and South African literature for this style of mineralization and used to refer to (1) the rock layer that is mineralized and has distinctive texture or mineralogy (Naldrett, 2004), or (2) the PGE-enriched sulfide mineralization that occurs within the rock layer. For example, Viljoen (1999) broadly defined the Merensky Reef as "a mineralized zone within or closely associated with an unconformity surface in the ultramafic cumulate at the base of the Merensky Cyclic Unit." In this report, we will use the term PGE reef to refer to the PGE-enriched mineralization, not the host rock layer. Within a layered igneous intrusion, reef-type mineralization is laterally persistent along strike, extending for the length of the intrusion, typically tens to hundreds of kilometers. However, the mineralized interval is thin, generally centimeters to meters thick, relative to the stratigraphic thickness of layers in an intrusion that vary from hundreds to thousands of meters. PGE-enriched sulfide mineralization is also found near the contacts or margins of layered mafic to ultramafic intrusions (Iljina and Lee, 2005). This contact-type mineralization consists of disseminated to massive concentrations of iron-copper-nickel-PGE-enriched sulfide mineral concentrations in zones that can be tens to hundreds of meters thick. The modes and textures of the igneous rocks hosting the mineralization vary irregularly on the scale of centimeters to meters; autoliths and xenoliths are common. Mineralization occurs in the igneous intrusion and in the surrounding country rocks. Mineralization can be preferentially localized along contact with country rocks that are enriched in sulfur-, iron-, or CO2-bearing lithologies. Reef-type and contact-type deposits, in particular those in the Bushveld Complex, South Africa, are the world's primary source of platinum and rhodium (tables 2 and 3; fig. 2). Reef-type PGE deposits are mined only in the Bushveld Complex (Merensky Reef and UG2), the Stillwater Complex (J-M Reef), and the Great Dyke (Main Sulphide Layer). PGE-enriched contact-type deposits are only mined in the Bushveld Complex. The other deposits in tables 2 and 3 are undeveloped; some are still under exploration.

Open-File Report↗

Database of significant deposits of gold, silver, copper, lead, and zinc in the United States

It has long been recognized that the largest mineral deposits contain most of the known mineral endowment (Singer and DeYoung, 1980). Sometimes called giant or world-class deposits, these largest deposits account for a very large share of historic and current mineral production and resources in industrial society (Singer, 1995). For example, Singer (1995) shows that the largest 10 percent of the world’s gold deposits contain 86 percent of the gold discovered to date. Many mineral resource issues and investigations are more easily addressed if limited to the relatively small number of deposits that contain most of the known mineral resources. An estimate of known resources using just these deposits would normally be sufficient, because considering smaller deposits would not add significantly to the total estimate. Land-use planning should treat mainly with these deposits due to their relative scarcity, the large share of known resources they contain, and the fact that economies of scale allow minerals to be produced much more cheaply from larger deposits. Investigation of environmental and other hazards that result from mining operations can be limited to these largest deposits because they account for most of past and current production. The National Mineral Resource Assessment project of the U.S. Geological Survey (USGS) has compiled a database on the largest known deposits of gold, silver, copper, lead, and zinc in the United States to complement the 1996 national assessment of undiscovered deposits of these same metals (Ludington and Cox, 1996). The deposits in this database account for approximately 99 percent of domestic production of these metals and probably a similar share of identified resources. These data may be compared with results of the assessment of undiscovered resources to characterize the nation’s total mineral endowment for these metals. This database is a starting point for any national or regional mineral-resource or mineral-environmental investigation.

Open-File Report↗

Water and sediment chemistry of selected existing and potential habitats of the Mohave tui chub, Mojave National Preserve, California, 2018

The Mohave tui chub ( Siphateles bicolor mohavensis ) was nearly extirpated from the Mojave River drainage in California by the mid-twentieth century and was listed as endangered in 1970. A source population of Mohave tui chub exists at MC Spring in Zzyzx, California, and has been used for several re-establishment efforts in previous decades. Two potential habitats in the Mojave National Preserve with perennial sources of water were identified by the National Park Service as candidates for additional Mohave tui chub re-establishment: West Pond and Rainbow Wells Pond. West Pond, an artificial pond at Zzyzx near MC Spring, contained a population of Mohave tui chub that died off in 1985 because of changes in water quality. The pond was rehabilitated in the past several years through re-excavation and by pumping fresh groundwater into the pond. Rainbow Wells Pond is an abandoned excavated mine site in the Cima Dome area. The bottom of the excavation intersects the water table, forming a pond. In cooperation with the National Park Service, the U.S. Geological Survey monitored water-quality conditions at West Pond and Rainbow Wells Pond for 1 year to characterize the suitability of spring habitat for re-establishment of Mohave tui chub populations. Data were also collected at three existing Mohave tui chub habitats in Mojave National Preserve to provide further information on the range of acceptable physical and chemical conditions. Initial water-quality results at West Pond indicate the pond has similar water quality as existing Mohave tui chub habitats. Initial water-quality results at Rainbow Wells Pond indicate the dissolved oxygen concentrations and springtime water temperatures are less than the long-term tolerable ranges for Mohave tui chub.

California↗

Report from Ground Zero: How geoscientists aid in the aftermath of environmental disasters

People around the world remember when they first learned of the attacks on New York City’s World Trade Center towers on Sept. 11, 2001. For me, the memories are vivid — my feelings of shock, horror and sadness were similarly etched on the faces of all the attendees of a mining and the environment workshop in Buenos Aires, Argentina, where I was speaking. At that time, I had no idea that our small research group at the U.S. Geological Survey in Denver, Colo., would soon be called upon to help public officials understand the potential health and environmental implications of the disaster and the ensuing rescue, recovery and cleanup efforts.

Earth Magazine↗

NASQAN: The design and implementation of a large-river suspended sediment and trace element flux programme

In 1996 the US Geological Survey (USGS) began a national flux-based water quality monitoring programme in the Mississippi, Columbia, Colorado, and Rio Grande basins. Suspended sediment flux estimates for periods greater than a year are generally accurate within ??15%. Discharge and suspended sediment concentrations varied much more than chemical levels. Most trace element concentrations are not elevated except Zn and Hg in the Ohio River, and Ag, Cu, Pb, Zn, Cd, Cr, Co, Ba, Mo, Sb, Hg, and Fe in the upper Columbia River, which is impacted by mining waste. The majority (???70%) of Cu, Zn, Cr, Ni, Ba, P, As, Fe, Mn, and Al are transported by suspended sediment; Sr transported seems dominated by the dissolved phase, whereas the transport of Li and TOC seem to be divided equally between both phases.In 1996 the US Geological Survey (USGS) began a national flux-based water quality monitoring programme in the Mississippi, Columbia, Colorado, and Rio Grande basins. Suspended sediment flux estimates for periods greater than a year are generally accurate within ??15%. Discharge and suspended sediment concentrations varied much more than chemical levels. Most trace element concentrations are not elevated except Zn and Hg in the Ohio River, and Ag, Cu, Pb, Zn, Cd, Cr, Co, Ba, Mo, Sb, Hg, and Fe in the upper Columbia River, which is impacted by mining waste. The majority (???70%) of Cu, Zn, Cr, Ni, Ba, P, As, Fe, Mn, and Al are transported by suspended sediment; Sr transported seems dominated by the dissolved phase, whereas the transport of Li and TOC seem to be divided equally between both phases.

Conference Paper↗

Fractional crystallization-induced variations in sulfides from the Noril’sk-Talnakh mining district (polar Siberia, Russia)

The distribution of platinum-group elements (PGE) within zoned magmatic ore bodies has been extensively studied and appears to be controlled by the partitioning behavior of the PGE during fractional crystallization of magmatic sulfide liquids. However, other chalcophile elements, especially TABS (Te, As, Bi, Sb, and Sn) have been neglected despite their critical role in forming platinum-group minerals (PGM). TABS are volatile trace elements that are considered to be mobile so investigating their primary distribution may be challenging in magmatic ore bodies that have been somewhat altered. Magmatic sulfide ore bodies from the Noril’sk-Talnakh mining district (polar Siberia, Russia) offer an exceptional opportunity to investigate the behavior of TABS during fractional crystallization of sulfide liquids and PGM formation as the primary features of the ore bodies have been relatively well preserved. In this study, new petrographic (2D and 3D) and whole-rock geochemical data from Cu-poor to Cu-rich sulfide ores of the Noril’sk-Talnakh mining district are integrated with published data to consider the role of fractional crystallization in generating mineralogical and geochemical variations across the different ore types (disseminated to massive). Despite textural variations in Cu-rich massive sulfides (lenses, veins, and breccias), these sulfides have similar chemical compositions, which suggests that Cu-rich veins and breccias formed from fractionated sulfide liquids that were injected into the surrounding rocks. Numerical modeling using the median disseminated sulfide composition as the initial sulfide liquid composition and recent DMSS/liq and DISS/liq predicts the compositional variations observed in the massive sulfides, especially in terms of Pt, Pd, and TABS. Therefore, distribution of these elements in the massive sulfides was likely controlled by their partitioning behavior during sulfide liquid fractional crystallization, prior to PGM formation. Our observations indicate that in the Cu-poor massive sulfides the PGM formed as the result of exsolution from sulfide minerals whereas in the Cu-rich massive sulfides the PGM formed by crystallization from late-stage fractionated sulfide liquids. We suggest that the significant amount of Sn-bearing PGM may be related to crustal contamination from granodiorite, whereas As, Bi, Te, and Sb were likely added to the magma along with S from sedimentary rocks. Large PGM that are scarce and randomly distributed may account for most of the whole-rock Pt budget. Based on our results, we propose a holistic genetic model for the formation of the magmatic sulfide ore bodies of the Noril’sk-Talnakh mining district.

Siberia↗