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Acute toxicity of TFM and a TFM/niclosamide mixture to selected species of fish, including lake sturgeon ( Acipenser fulvescens ) and mudpuppies ( Necturus maculosus ), in laboratory and field exposures

The toxicity of the lampricides 3-trifluoromethyl-4-nitrophenol (TFM) and 2',5-dichloro-4'-nitrosalicylanilide (niclosamide) to non-target fishes has been a major point of concern since their use to control larval sea lamprey ( Petromyzon marinus ) populations began in the early 1960s. The toxicity of TFM to several non-target fish species has been demonstrated in previous studies. However, little information is available on the toxicity of the TFM/1% niclosamide mixture. One species of particular concern is the lake sturgeon ( Acipenser fulvescens ). Juvenile lake sturgeon of several size ranges were exposed to determine potential effects of the lampricides to individuals present in treatment streams. Sac fry were most resistant to the lampricides followed by fingerlings in the 200 to 225 mm size range. Swim-up fry and fingerlings less than 100 mm were the most sensitive. Concentrations that produced 50% mortality (LC50s) in juvenile lake sturgeon of these smaller size ranges were at or near the minimum lethal concentrations (MLCs) required for effective control of larval sea lampreys. The mudpuppy ( Necturus maculosus ), an amphibian native to several tributaries of the Great Lakes, have also become a species of interest in recent years. Laboratory tests conducted with TFM and a TFM/1% niclosamide mixture on adult mudpuppies indicate that although the amphibian is sensitive to the lampricides, an adequate margin of safety exists for adult mudpuppies to survive when exposed during stream treatments. Fifteen other fish species native to streams treated with lampricides were investigated in the laboratory to determine their sensitivity to the lampricides. Centrarchids, bluegill ( Lepomis macrochirus ) and green sunfish ( Lepomis cyanellus ) were the least sensitive to TFM, while ictalurids, black bullhead ( Ictalurus melas ), channel catfish ( Ictalurus punctatus ), and tadpole madtom ( Notorus gyrinus ) were the most sensitive. On-site bioassays conducted before lampricide treatments also revealed that lake sturgeon, channel catfish, and whitefish ( Coregonus clupeaformis ) were sensitive to the lampricides although considerably less sensitive compared to sea lamprey.

Journal of Great Lakes Research↗

Maps showing distribution of anomalous amounts of selected elements in stream-sediment and rock samples, Eagle quadrangle, Alaska

Maps showing the distribution of anomalous amounts of selected elements found in more than 1,600 stream-sediment and more than 1,500 rock samples have been prepared form results of semiquantitative spectrographic analyses. The samples were collected in the Eagle quadrangle, east-central Alaska, in the summers of 1968, 1969, 1970, and 1971. Figure 1 is a map showing localities for all stream-sediment samples analyzed and indicates by symbols those containing anomalous amounts of one or more of the following elements: gold (Au), silver (Ag), arsenic (As), bismuth (Bi), copper (Cu), chromium (Cr), molybdenum (Mo), nickel (Ni), lead (Pb), antimony (Sb), tin (Sn), tungsten (W), and zinc (Zn). Figure 2 shows the localities for analyzed rock samples and indicates those containing specified amounts of the same elements as selected from the stream-sediment samples. Maps similar to these which showed the distribution of anomalous amounts of selected elements in stream-sediment and rock samples from the Eagle quadrangle were compiled in 1971 and issued as a U.S. Geological Survey open-file report (Foster and Yount, 1971). The maps of this report are revised from the open-file maps to include the sampling in the summer of 1971.

Alaska↗

Groundwater/surface-water interactions in the Bad River Watershed, Wisconsin

A groundwater-flow model was developed for the Bad River Watershed and surrounding area by using the U.S. Geological Survey (USGS) finite-difference code MODFLOW-NWT. The model simulates steady-state groundwater-flow and base flow in streams by using the streamflow routing (SFR) package. The objectives of this study were to: (1) develop an improved understanding of the groundwater-flow system in the Bad River Watershed at the regional scale, including the sources of water to the Bad River Band of Lake Superior Chippewa Reservation (Reservation) and groundwater/surface-water interactions; (2) provide a quantitative platform for evaluating future impacts to the watershed, which can be used as a starting point for more detailed investigations at the local scale; and (3) identify areas where more data are needed. This report describes the construction and calibration of the groundwater-flow model that was subsequently used for analyzing potential locations for the collection of additional field data, including new observations of water-table elevation for refining the conceptualization and corresponding numerical model of the hydrogeologic system. The study area can be conceptually divided into three primary hydrogeologic environments. The first encompasses the southern uplands with relatively low topographic relief, where groundwater-flow is unconfined and occurs primarily in sandy till and glacial outwash overlying Archean-aged crystalline bedrock. The second includes a transitional area of higher topographic relief and shallow depth to bedrock, in the vicinity of ridges formed by steeply dipping, early-Proterozoic aged metasedimentary units of the Marquette Range Supergroup (including the Ironwood Formation), and late-Proterozoic igneous units associated with the Midcontinent Rift System (MRS). Groundwater-flow in this area likely occurs primarily through connected networks of bedrock fractures that are not well characterized, and also in isolated pockets of Quaternary deposits. The third and last hydrogeologic environment includes lowlands along Lake Superior where a deep sandstone aquifer is confined by thick deposits of clay-rich till. Model input was compiled by using both published and unpublished data. Constant flux boundary conditions for the model perimeter were developed from a regional analytic element model described in appendix 1 of this report. Pumping from 26 high-capacity wells within the model area was included. The SFR stream network was developed from the National Hydrography Dataset (NHDPlus Version 2) and hydrography from the Wisconsin Department of Natural Resources (WDNR). Hydraulic conductivity values were determined for each model cell by interpolation from a network of pilot points, within zones representing major hydrogeologic units. Recharge to the groundwater system was estimated on a cell-by-cell basis by using the Soil Water Balance code (SWB), with gridded daily temperature and precipitation data for the period 1980–2011, and GIS coverages of soil and land-surface conditions. Estimated recharge varies considerably, following spatial patterns in the precipitation and soil hydrologic group inputs. The lowest recharge values occur in the Superior lowlands, whereas the highest values occur in the upland areas, especially those underlain by sandy soils, and in the vicinity of bedrock hills. The model was calibrated to groundwater-levels and base flows obtained from the USGS National Water Information System (NWIS) database, and groundwater-levels obtained from the WDNR and Band River Band well-construction databases. Calibration was performed via nonlinear regression by using the parameter-estimation software suite PEST. Groundwater levels and base-flow observations in the calibration dataset were well simulated by the calibrated model, with reasonable values of hydraulic conductivity. The pilot-point parameters that were most constrained by observations during model calibration coincided with the locations containing the most wells (head observations)—especially the population centers of Ashland, Mellen, and other communities along the major highway corridors. Results from the calibrated model illustrate differences in the nature of groundwater-flow within the watershed. In the southern part of the watershed, where bedrock is shallow, groundwater flow paths are relatively short, extending from local recharge areas to adjacent first and second-order streams. In contrast, laterally continuous deposits of clay-rich till covering the Superior Lowlands isolate most smaller streams from the sandstone aquifer, allowing for longer flow paths toward larger streams such as the Bad, Marengo, and White Rivers. Approximately three-quarters of all first-order stream cells were dry in the Superior Lowlands, compared to only half of first-order stream cells in the southern bedrock uplands. The model was used to delineate the groundwatershed for the Bad and Kakagon Rivers. “Groundwatershed” is defined as the area contributing groundwater discharge to one of these streams and their tributaries. The groundwatershed was found to align closely with the surface-watershed, with the most notable exception occurring along the southwestern half of Birch Hill, where surface water drains southwest towards the Potato River, and groundwater flows north and east towards Lake Superior. Similarly, the contributing area of groundwater-flow to the Reservation was delineated. Results indicate the off-Reservation groundwater contributing area to be limited in comparison to the extent of the watershed, extending southward into the highlands underlain by MRS igneous rock units, but not further into the area underlain by the Marquette Range Supergroup. Stable isotope samples were collected from 54 wells within the watershed, to investigate sources of groundwater. Oxygen-18 (δ 18 O) values lower than -13.0 per mil were documented in the sampling, and likely indicate the presence of recharge water from the last glacial period (>9,500 years old) beneath the northern portion of the Reservation, in the vicinity of Odanah, Wisconsin. Finally, a new data-worth analysis of potential new monitoring-well locations was performed by using the model. The relative worth of new measurements was evaluated based on their ability to increase confidence in model predictions of groundwater levels and base flows at 35 locations, under the condition of a proposed open-pit iron mine. Results of the new data-worth analysis, and other inputs and outputs from the Bad River model, are available through an online dynamic web mapping service at ( http://wim.usgs.gov/badriver/ ).

Wisconsin↗

Predicting the locations of naturally fishless lakes

1. Fish have been introduced into many previously fishless lakes throughout North America over the past 100+ years. It is difficult to determine the historical distribution of fishless lakes, however, because these introductions have not always been well-documented. 2. Due to its glacial history and low human population density, the state of Maine (U.S.A.) may host the greatest number of naturally fishless lakes in the northeastern United States. However, less than one-quarter of Maine's 6000+ lakes have been surveyed for fish presence, and no accurate assessments of either the historical or current abundance and distribution of fishless lakes exist. 3. We developed methods to assess the abundance and distribution of Maine's naturally fishless lakes (0.6-10.1 ha). We hypothesized that the historical distribution of fishless lakes across a landscape is controlled by geomorphic and geographic conditions. 4. We used ArcGIS to identify landscape-scale geomorphic and geographic factors (e.g. connectivity, surrounding slope) correlated with fish absence in two geomorphic regions of Maine - the western and interior mountains and the eastern lowlands and foothills. By using readily available geographic information systems data our method was not limited to field-visited sites. We estimated the likelihood that a particular lake is fishless with a stepwise logistic regression model developed for each region. 5. The absence of fish from western lakes is related to altitude (+), minimum percent slope in the 500 m buffer (+), maximum percent slope in the 500 m buffer (+) and percent cover of herbaceous-emergent wetland in 1000 m buffer (-). The absence of fish from eastern lakes is related to the lack of a stream within 50 m of the lake. 6. The models predict that a total of 4% (131) of study lakes in the two regions were historically fishless, with the eastern region hosting a greater proportion than the western region. 7. We verified the model predictions with two complementary approaches. First we visited 21 lakes predicted to be fishless and assessed current fish presence with gillnetting. Second, we used paleolimnological techniques based on the abundance of Chaoborus americanus mandibles in the bottom segments of sediment cores. Fifteen of the 21 lakes predicted to be fishless currently contain fish. Paleolimnological evidence, however, suggests that nine of the 15 lakes were historically fishless and thus were subject to undocumented fish introductions. 8. Our approach efficiently predicts the distribution Maine's naturally fishless lakes, and our results indicate that these habitats have declined due to fish introductions. Our method could be applied to other regions with similar geographic and geomorphic constraints on fish distributions as a tool to enhance conservation of a limited resource that provides habitat for unique biological communities. ?? 2007 Blackwell Publishing Ltd.

Freshwater Biology↗

Seasonal variation in size-dependent survival of juvenile Atlantic salmon (Salmo salar): Performance of multistate capture-mark-recapture models

We estimated the magnitude and shape of size-dependent survival (SDS) across multiple sampling intervals for two cohorts of stream-dwelling Atlantic salmon (Salmo salar) juveniles using multistate capture-mark-recapture (CMR) models. Simulations designed to test the effectiveness of multistate models for detecting SDS in our system indicated that error in SDS estimates was low and that both time-invariant and time-varying SDS could be detected with sample sizes of >250, average survival of >0.6, and average probability of capture of >0.6, except for cases of very strong SDS. In the field (N ??? 750, survival 0.6-0.8 among sampling intervals, probability of capture 0.6-0.8 among sampling occasions), about one-third of the sampling intervals showed evidence of SDS, with poorer survival of larger fish during the age-2+ autumn and quadratic survival (opposite direction between cohorts) during age-1+ spring. The varying magnitude and shape of SDS among sampling intervals suggest a potential mechanism for the maintenance of the very wide observed size distributions. Estimating SDS using multistate CMR models appears complementary to established approaches, can provide estimates with low error, and can be used to detect intermittent SDS. ?? 2008 NRC Canada.

Canadian Journal of Fisheries and Aquatic Sciences↗

Direct behavioral evidence that unique bile acids released by larval sea lamprey (Petromyzon marinus) function as a migratory pheromone

Four behavioral experiments conducted in both the laboratory and the field provide evidence that adult sea lamprey ( Petromyzon marinus ) select spawning rivers based on the odor of larvae that they contain and that bile acids released by the larvae are part of this pheromonal odor. First, when tested in a recirculating maze, migratory adult lamprey spent more time in water scented with larvae. However, when fully mature, adults lost their responsiveness to larvae and preferred instead the odor of mature individuals. Second, when tested in a flowing stream, migratory adults swam upstream more actively when the water was scented with larvae. Third, when migratory adults were tested in a laboratory maze containing still water, they exhibited enhanced swimming activity in the presence of a 0.1 nM concentration of the two unique bile acids released by larvae and detected by adult lamprey. Fourth, when adults were exposed to this bile acid mixture within flowing waters, they actively swam into it. Taken together, these data suggest that adult lamprey use a bile acid based larval pheromone to help them locate spawning rivers and that responsiveness to this cue is influenced by current flow, maturity, and time of day. Although the precise identity and function of the larval pheromone remain to be fully elucidated, we believe that this cue will ultimately prove useful as an attractant in sea lamprey control.

Canadian Journal of Fisheries and Aquatic Sciences↗

Channel movement of meandering Indiana streams

The process of channel movement in a meander system involves rotation and translation of meander loops and an increasing path length. The amount of path-length increase is directly proportional to the impulse supplied by discharge and is inversely proportional to the silt-clay percentage of the material composing the channel perimeter. Comparable paths have been obtained by standardizing measurements with a sine-generated curve and a moving reference axis. Analysis of previous investigations and time-of-travel data indicates that the discharge effective in channel formation consists of the range beginning just higher than the average and continuing throughout all higher discharges. Of six field sites investigated, three meander systems had path-length increases of sufficient magnitude to correlate with above-average discharge volume, one had no discernible change over a 30-year period, and two had changes which were too small for correlation owing to the short period of time covered by the available data. Because of the consistency of yearly above-average discharge volumes, it was possible to develop a general relation between path-length increase per thousand cubic-feet-per-second-days per square mile of drainage area above average discharge and the width-depth ratio of the channel. Little progress was made toward defining relationships for rotation and translation.

Indiana↗

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri↗

Direct behavioral evidence that unique bile acids released by larval sea lamprey (Petromyzon marinus) function as a migratory pheromone

Four behavioral experiments conducted in both the laboratory and the field provide evidence that adult sea lamprey (Petromyzon marinus) select spawning rivers based on the odor of larvae that they contain and that bile acids released by the larvae are part of this pheromonal odor. First, when tested in a recirculating maze, migratory adult lamprey spent more time in water scented with larvae. However, when fully mature, adults lost their responsiveness to larvae and preferred instead the odor of mature individuals. Second, when tested in a flowing stream, migratory adults swam upstream more actively when the water was scented with larvae. Third, when migratory adults were tested in a laboratory maze containing still water, they exhibited enhanced swimming activity in the presence of a 0.1 nM concentration of the two unique bile acids released by larvae and detected by adult lamprey. Fourth, when adults were exposed to this bile acid mixture within flowing waters, they actively swam into it. Taken together, these data suggest that adult lamprey use a bile acid based larval pheromone to help them locate spawning rivers and that responsiveness to this cue is influenced by current flow, maturity, and time of day. Although the precise identity and function of the larval pheromone remain to be fully elucidated, we believe that this cue will ultimately prove useful as an attractant in sea lamprey control.

Canadian Journal of Fisheries and Aquatic Sciences↗

Reconnaissance of geology and ground water in the lower Grand River valley, South Dakota, with a section on Chemical quality of the ground water

The area described in this report is the flood plain of the Grand River and the bordering benchlands in Perkins and Corson Counties, S. Dak., from a point about 6 miles west of the town of Shadehill to the confluence of the Grand and Missouri Rivers near Mobridge. The exposed bedrock formations include the Pierre shale, the Fox Hills sandstone, and the Hell Creek formation of Late Cretaceous age, and-the Ludlow member of the Fort Union formation of Tertiary (Paleocene) age. Some stringers of the Cannonball formation probably interfinger with beds of the Ludlow member but none of the former was identified during the field investigations. The Pierre shale is exposed from the mouth of the Grand River to approximately the center of the area. Although a few wells in the area obtain water from this formation, it is not generally considered to be a source of supply. The Fox Hills sandstone, the Hell Creek formation, and the Ludlow member of the Fort Union formation are exposed successively upstream and, where saturated, yield small to moderate quantities of water to wells. Unconsolidated deposits of silt, sand, and gravel occur in several physiographic positions; they underlie the high benchland on both sides of the river, the poorly defined terraces along the river, and the flood plain throughout its entire length. Possibly all these unconsolidated deposits are water bearing; however, where the deposits on the benchland and in the terraces are dissected by streams, they probably contain little or no water. The average depth to ground water along the lower Grand River valley is about 17 feet. Probably, the flow of ground water in the bottom lands is nearly parallel to and slightly toward the surface stream. The measurements of the water level in observation wells for the period 1946-48 indicate that the fluctuations of the water table are small. The results of analyses of 13 samples of ground water from the alluvium and the Hell Creek formation show that the suitability of the ground water for use varies because of the considerable range in mineralization and composition. Dissolved solids ranged from 343 to 4,250 parts per million (ppm), hardness from 11 to 1,130 ppm, and percentage of sodium from 25 to 98. Concentrations of some of the individual constituents exceed standards of the United States Public Health Service. The water is moderately hard and contains undesirable amounts of iron and moderate to large amounts of dissolved solids. In general, the water quality ranges from excellent to unsuitable for irrigation use. The result of the mixing of the ground water with recharge water from Shadehill Reservoir cannot be predicted on the basis of available data. The geologic and hydrologic data in this report were obtained from earlier reports and from field observations during the period 1946-48. The report includes a geologic map and tabulated well records.

South Dakota↗

Abundance of host fish and frequency of glochidial parasitism in fish assessed in field and laboratory settings and frequency of juvenile mussels or glochidia recovered from hatchery-held fish, central and southeastern Texas, 2012-13

In 2012–13, the U.S. Geological Survey (USGS), in cooperation with the U.S. Fish and Wildlife Service (USFWS), completed the first phase of a two-phase study of mussel host-fish relations for five endemic mussel species in central and southeastern Texas that were State-listed as threatened on January 17, 2010: (1) Texas fatmucket ( Lampsilis bracteata ), (2) golden orb ( Quadrula aurea ), (3) smooth pimpleback ( Quadrula houstonensis ), (4) Texas pimpleback ( Quadrula petrina ), and (5) Texas fawnsfoot ( Truncilla macrodon ). On October 6, 2011, the USFWS announced the completion of a status review and determined that the five mussel species warranted listing under the Endangered Species Act; however, listing of these species at that time was precluded by higher priority listing actions, and currently (December 2014), they remained unlisted. Freshwater mussels are long-lived, sedentary organisms that spend their larval stage as obligate parasites on the gills or fins of fishes, and many of these larvae, which are referred to as “glochidia,” can survive only on a narrow range of host-fish species. Results from both study phases are likely to provide information useful for propagation of rare mussels, reintroduction of host fish, population and reproduction monitoring, habitat restoration and enhancement, and adaptive management. The abundance of host fish, frequency of parasitism in fish, and frequency of juvenile mussels or glochidia recovered from hatchery-held fish was assessed by collecting fish and mussels at 14 sites distributed among seven streams in central and southeastern Texas (juvenile mussels and glochidia were not differentiated in hatchery-held fish). All fish collected and assessed in this study were wild-caught. Qualitative surveys of the resident mussel communities were made, focusing on the five candidate species. A subsample (3 percent in 2012 and 19 percent in 2013) of the fish collected during aquatic biota surveys was submitted to the USFWS San Marcos National Fish Hatchery and Technology Center to collect juvenile mussels and glochidia recovered from the host fish, which were held for 28 days in holding tanks to allow time for most of the attached glochidia to release from the gills of the fish after transforming into juvenile mussels. All fish not sent to the hatchery were assessed for glochidia in the field or in the USGS Texas Water Science Center laboratory in Austin, Tex. Juvenile mussels and glochidia that were recovered from fish at the hatchery were submitted for use in the second phase of this study, the development of deoxyribonucleic acid (DNA) identification keys to determine mussel and host-fish relationships through DNA-based molecular identification (DNA typing of the juvenile mussels and glochidia). Reporting on the results of DNA-based molecular identification research is beyond the scope of this report. In 2012, the majority of the fish that were collected, in terms of total number and species types, belonged to the sunfish family Centrarchidae (centrarchids; 1,277 individuals and at least 10 species). Redbreast sunfish ( Lepomis auritus ) was the most common species collected in 2012 (603 individuals), but the largemouth bass ( Micropterus salmoides ) species was caught at all 10 sites. The largest number of species (19) was collected at the San Saba Menard site (San Saba River near Menard, Tex.) on May 22, 2012. In 2013, most of the fish that were collected, in terms of total number and species types, were centrarchids (763 individuals) and cyprinids (10 species), respectively. Blacktail shiner ( Cyprinella venusta ) was the most common species collected in 2013 (287 individuals), but bluegill ( Lepomis macrochirus ) was the only species that was caught at all nine sites. The largest number of individuals (382) and species (19) was collected from the Colorado Columbus site (Colorado River near Columbus, Tex.) on June 11, 2013. A minimum of two fish (any species) parasitized with glochidia was collected from each of the 10 sites sampled during 2012. The highest percentage of parasitized fish (19.1 percent) was measured at the Guadalupe Victoria site (Guadalupe River near Victoria, Tex.). The catfish family Ictaluridae (ictalurids) exhibited the highest proportion of parasitized fish (12.1 percent). Of the nine sites sampled in 2013, the Pedernales Fredericksburg site (Pedernales River near Fredericksburg, Tex.) had the highest proportion of parasitized fish at 22.7 percent. Ictalurids again exhibited the highest frequency of parasitism (26.5 percent). Of the fish that were not sent to the hatchery but assessed for glochidia in the field or in the laboratory in 2012, at least 13 species were parasitized, and longear sunfish ( Lepomis megalotis ) was the species with the highest percentage of parasitized individuals (17.3 percent). Of the fish that were not sent to the hatchery but assessed for glochidia in the field or in the laboratory in 2013, only eight species were parasitized, and flathead catfish ( Pylodictis olivaris ) was the species with the highest percentage of parasitized individuals (42.9 percent). With the exception of the San Antonio Charco site, fish were submitted to the hatchery from all sampling sites in 2013. During the first sampling period in 2013 (April 1–5), slightly more than half (16 out of 29) of the fish species (on a per site basis) that were submitted to the hatchery released juvenile mussels and glochidia. Compared to the other sampling periods in 2013, substantially fewer glochidia per fish were present on fish submitted to the hatchery during the second sampling period in 2013 (April 29–May 2). Although only two sites were sampled during the third sampling period in 2013 (June 10–11), more juvenile mussels and glochidia were recovered at the hatchery during this sampling period (107) than were recovered during the first two sampling periods in 2013 combined (102). An average of 17 juvenile mussels or glochidia was recovered per largemouth bass submitted to the hatchery from the Guadalupe Victoria site during the third sampling period. A total of 19 fish species collected at nine sites was submitted to the hatchery in 2013, and 14 of these species had juvenile mussels or glochidia that were recovered at the hatchery. The three most productive species, in terms of the average number of juvenile mussels or glochidia recovered, were longear sunfish, spotted bass, and largemouth bass, each of which averaged more than two juvenile mussels or glochidia recovered per individual.

Texas↗

Prevalence and potential for biological effects of several chemicals of interest in Lake Superior tributaries

Lake Superior is typically assumed to have excellent water quality, but its tributaries have been understudied for contaminants relative to other Great Lakes. This study monitored polycyclic aromatic hydrocarbons (PAHs), alkylphenols (AP) and alkylphenol ethoxylates (APEs), bisphenols, and neonicotinoid pesticides in 18 sites on 17 United States tributaries to Lake Superior in 2022. Contaminants were analyzed from 54 surface water and 17 stream bed sediment samples. PAHs were the most prevalent contaminant class. Among 17 PAHs in 17 samples (289 instances), 71 % were positive detections. Surface water samples were not analyzed for PAHs. Next, among 4 APs and APEs analyzed, 35 % of sediment sample instances and 21 % of instances in 54 water samples were positive detections. Bisphenol analogues were detected in 2 % of sediment sample instances and 4 % of water sample instances. Bisphenol A (BPA) was not quantified due to field blank contamination, but bisphenol AF (BPAF), bisphenol E (BPE), bisphenol F (BPF), and bisphenol S (BPS) were detected in environmental samples. Neonicotinoids were detected in 0.5 % of sediment sample instances and 0.4% of water samples instances. Low detection frequencies for contaminants precluded analyses with watershed land use characteristics, but four sites (Tischer Creek, Miller Creek, Carp River and Iron River) emerged as locations with relatively elevated contaminant concentrations. Comparison of concentrations with ToxCast and other water quality guidelines suggested potential for biological effects from some samples. This study provides a baseline of low contaminant prevalence in Lake Superior tributaries while identifying a few locations that may warrant further monitoring.

Michigan, Minnesota, Wisconsin↗

Drainage effects on stream nitrate-N and hydrology in south-central Minnesota (USA)

Excessive nitrate-N in south-central Minnesota ditches and streams is related to land-use change, and may be contributing to the development of the zone of hypoxia in the Gulf of Mexico. Intensive land-use (agricultural management) has progressively increased as subsurface drainage has improved crop productivity over the past 25 years. We have examined water at varying scales for ??18O and, nitrate-N concentrations. Additionally, analysis of annual peak flows, and channel geomorphic features provided a measure of hydrologic change. Laboratory and field results indicate that agricultural drainage has influenced riverine source waters, concentrations of nitrate-N, channel dimensions and hydrology in the Blue Earth River (BER) Basin. At the mouth of the BER shallow ground water comprises the largest source water component. The highest nitrate-N concentrations in the BER and tributaries typically occurred in May and June and ranged from 7-34 mg L-1. Peak flows for the 1.01-2-yr recurrence intervals increased by 20-to-206% over the past 25 years. Geomorphic data suggest that small channels (ditches) were entrenched by design, whereas, natural channels incised. Increased frequent peak flows in the BER have created laterally confined channels that are disconnected from an accessible riparian corridor. Frequent access to a functioning riparian zone is important for denitrification.

Environmental Monitoring and Assessment↗

Water-resources investigations in Wisconsin: Programs and activities of the U.S. Geological Survey, 1991-92

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for: regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for water-quality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in "Water Resources Data Wisconsin."

Wisconsin↗

Water-resources investigations in Wisconsin, 1993

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development. An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for: regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for water-quality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in "Water Resources Data Wisconsin."

Wisconsin↗

Water-resources investigations in Wisconsin

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development. An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also LOCATION: Statewide PROJECT CHIEF: Barry K. Holmstrom PERIOD OF PROJECT: July 1913-Continuing designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for waterquality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in the report "Water Resources Data-Wisconsin."

Wisconsin↗

Using CO 2 Prophet to estimate recovery factors for carbon dioxide enhanced oil recovery

Introduction The Oil and Gas Journal’s enhanced oil recovery (EOR) survey for 2014 (Koottungal, 2014) showed that gas injection is the most frequently applied method of EOR in the United States and that carbon dioxide (CO 2 ) is the most commonly used injection fluid for miscible operations. The CO 2 -EOR process typically follows primary and secondary (waterflood) phases of oil reservoir development. The common objective of implementing a CO 2 -EOR program is to produce oil that remains after the economic limit of waterflood recovery is reached. Under conditions of miscibility or multicontact miscibility, the injected CO 2 partitions between the gas and liquid CO2 phases, swells the oil, and reduces the viscosity of the residual oil so that the lighter fractions of the oil vaporize and mix with the CO 2 gas phase (Teletzke and others, 2005). Miscibility occurs when the reservoir pressure is at least at the minimum miscibility pressure (MMP). The MMP depends, in turn, on oil composition, impurities of the CO 2 injection stream, and reservoir temperature. At pressures below the MMP, component partitioning, oil swelling, and viscosity reduction occur, but the efficiency is increasingly reduced as the pressure falls farther below the MMP. CO 2 -EOR processes are applied at the reservoir level, where a reservoir is defined as an underground formation containing an individual and separate pool of producible hydrocarbons that is confined by impermeable rock or water barriers and is characterized by a single natural pressure system. A field may consist of a single reservoir or multiple reservoirs that are not in communication but which may be associated with or related to a single structural or stratigraphic feature (U.S. Energy Information Administration [EIA], 2000). The purpose of modeling the CO 2 -EOR process is discussed along with the potential CO 2 -EOR predictive models. The data demands of models and the scope of the assessments require tradeoffs between reservoir-specific data that can be assembled and simplifying assumptions that allow assignment of default values for some reservoir parameters. These issues are discussed in the context of the CO 2 Prophet EOR model, and their resolution is demonstrated with the computation of recovery-factor estimates for CO 2 -EOR of 143 reservoirs in the Powder River Basin Province in southeastern Montana and northeastern Wyoming.

Scientific Investigations Report↗

Flow of variably fluidized granular masses across three-dimensional terrain 2. Numerical predictions and experimental tests

Numerical solutions of the equations describing flow of variably fluidized Coulomb mixtures predict key features of dry granular avalanches and water-saturated debris flows measured in physical experiments. These features include time-dependent speeds, depths, and widths of flows as well as the geometry of resulting deposits. Threedimensional (3-D) boundary surfaces strongly influence flow dynamics because transverse shearing and cross-stream momentum transport occur where topography obstructs or redirects motion. Consequent energy dissipation can cause local deceleration and deposition, even on steep slopes. Velocities of surge fronts and other discontinuities that develop as flows cross 3-D terrain are predicted accurately by using a Riemann solution algorithm. The algorithm employs a gravity wave speed that accounts for different intensities of lateral stress transfer in regions of extending and compressing flow and in regions with different degrees of fluidization. Field observations and experiments indicate that flows in which fluid plays a significant role typically have high-friction margins with weaker interiors partly fluidized by pore pressure. Interaction of the strong perimeter and weak interior produces relatively steep-sided, flat-topped deposits. To simulate these effects, we compute pore pressure distributions using an advection-diffusion model with enhanced diffusivity near flow margins. Although challenges remain in evaluating pore pressure distributions in diverse geophysical flows, Riemann solutions of the depthaveraged 3-D Coulomb mixture equations provide a powerful tool for interpreting and predicting flow behavior. They provide a means of modeling debris flows, rock avalanches, pyroclastic flows, and related phenomena without invoking and calibrating Theological parameters that have questionable physical significance.

Journal of Geophysical Research B: Solid Earth↗