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At least 1,225 records · Page 68Linked to original sources

USGS2021

Piloting urban ecosystem accounting for the United States

In this study, we develop urban ecosystem accounts in the U.S., using the System of Environmental-Economic Accounting Experimental Ecosystem Accounting (SEEA EEA) framework. Most ecosystem accounts focus on regional and national scales, which are appropriate for many ecosystem services. However, ecosystems provide substantial services in cities, improving quality of life and contributing to resiliency for substantial parts of the population. Our models estimate energy savings for indoor cooling resulting from heat mitigated by trees and rainfall intercepted by trees. Both models cover major cities in the contiguous U.S. and report the results through physical supply and use tables for multiple accounting periods (2011 and 2016). Using conservative assumptions, urban trees provide substantial heat mitigation (4,098 and 4,229 GWh, valued at $523 and $539 million in 2011 and 2016, respectively) and rainfall interception (2,422 and 2,627 million m 3 , valued at $434 and $425 million for 2011 and 2016, respectively). Interannual differences largely reflect variations in weather patterns. Our work shows how Earth observation data can support urban ecosystem accounting. We provide model code within a public repository to facilitate model runs elsewhere, enabling the SEEA EEA and Earth observation user communities to reuse our models and provide feedback for improvement.

Ecosystem Services↗

USGS2010

Mg isotope constraints on soil pore-fluid chemistry: Evidence from Santa Cruz, California

Mg isotope ratios ( 26 Mg/ 24 Mg) are reported in soil pore-fluids, rain and seawater, grass and smectite from a 90 kyr old soil, developed on an uplifted marine terrace from Santa Cruz, California. Rain water has an invariant 26 Mg/ 24 Mg ratio (expressed as δ26 Mg> δ26 Mg ) at −0.79 ± 0.05‰, identical to seawater δ26 Mg> δ26 Mg . Detrital smectite (from the base of the soil profile, and therefore unweathered) has a δ26Mg"> δ26Mg value of 0.11‰, potentially enriched in 26 Mg by up to 0.3‰ compared to the bulk silicate Earth Mg isotope composition (although within the range of all terrestrial silicates). The soil pore-waters show a continuous profile with depth for δ26 Mg> δ26 Mg , ranging from −0.99‰ near the surface to −0.43‰ at the base of the profile. Shallow pore-waters (<1 m) have δ26 Mg> δ26 Mg values that are similar to, or slightly lower than the rain waters. This implies that the degree of biological cycling of Mg in the pore-waters is relatively small and is quantified as <32%, calculated using the average Mg isotope enrichment factor between grass and rain ( δ26 Mggrass- δ26 Mgrain> δ26 Mggrass- δ26 Mgrain ) of 0.21‰. The deep pore-waters (1–15 m deep) have δ26 Mg> δ26 Mg values that are intermediate between the smectite and rain, ranging from −0.76‰ to −0.43‰, and show a similar trend with depth compared to Sr isotope ratios. The similarity between Sr and Mg isotope ratios confirms that the Mg in the pore-waters can be explained by a mixture between rain and smectite derived Mg, despite the fact that Mg and Sr concentrations may be buffered by the exchangeable reservoir. However, whilst Sr isotope ratios in the pore-waters span almost the complete range between mineral and rain inputs, Mg isotopes compositions are much closer to the rain inputs. If Mg and Sr isotope ratios are controlled uniquely by a mixture, the data can be used to estimate the mineral weathering inputs to the pore-waters, by correcting for the rain inputs. This isotopic correction is compared to the commonly used chloride correction for precipitation inputs. A consistent interpretation is only possible if Mg isotope ratios are fractionated either by the precipitation of a secondary Mg bearing phase, not detected by conventional methods, or selective leaching of 24 Mg from smectite. There is therefore dual control on the Mg isotopic composition of the pore-waters, mixing of two inputs with distinct isotopic compositions, modified by fractionation. The data provide (1) further evidence for Mg isotope fractionation at the surface of the Earth and (2) the first field evidence of Mg isotope fractionation during uptake by natural plants. The coherent behaviour of Mg isotope ratios in soil environments is encouraging for the development of Mg isotope ratios as a quantitative tracer of both weathering inputs of Mg to waters, and the physicochemical processes that cycle Mg, a major cation linked to the carbon cycle, during continental weathering.

California↗

USGS2005

Animating the biodynamics of soil thickness using process vector analysis: A dynamic denudation approach to soil formation

This paper expands the dynamic denudation framework of landscape evolution by providing new process insights and details on how soil and its signature morphological feature, the biomantle, form and function in the environment. We examine soils and their biomantles from disparate parts of the world, from the tropics through midlatitudes and hyperarid through perhumid, a range that exhibits varying environments for, and of, life. We then explicate the process pathways that cause soils to thicken and thin, and to even disappear, then reform. We do this by examining thickness relationships, where soil thickness stand biomantle thickness bt are functions of upbuilding u and deepening d minus removal r processes, hence st/bt=f(u+d-r). Upbuilding has two subsets, u1, which includes all exogenous (allochthonous-outside) mineral and/or organic inputs to the soil system, and u2, which includes all endogenous (autochthonous-in situ) processes and productions, including weathering. Exogenous u1 inputs include eolian and slopewash inputs (sedimentations) of mineral and organic materials, mass wasting accumulations and the like. Endogenous u2 processes and productions include the sum of in situ bioturbations, biosynthetic productions, organic accumulations, biovoid productions, weathering and volume increases caused by their sum. Endogenous upbuildings, which dominantly occur in the biomantle, are basically biodynamic bd processes and productions, hence u2=bd. Therefore, if exogenous upbuildings u1 are minimal or zero, then biomantle thickness bt is expressed by bt=f(u2-r) or bt=f(bd-r). Drawing on these relationships, we employ a graphic-conceptual device called process vector analysis in a digital animation (see supplementary materials or cf. https://netfiles.uiuc.edu/jdomier/www/temp/ biomantle.html) that illustrates the main pathways that form both Earth's soil and its unique epidermis, the biomantle. We then discuss the main elements of the animation using still frames that represent thickness turning points. We end by encouraging researchers, instructors and students to view Earth's landforms and soils as integrated dynamic entities that are constantly coevolving elements of a global subaerial-subaqueous continuum. ?? 2004 Elsevier B.V. All rights reserved.

Geomorphology↗

USGS2010

The sedimentology and dynamics of crater-affiliated wind streaks in western Arabia Terra, Mars and Patagonia, Argentina

Wind streaks comprise recent aeolian deposits that have been extensively documented on Venus, Earth and Mars. Martian wind streaks are among the most abundant surface features on the planet and commonly extend from the downwind margins of impact craters. Previous studies of wind streaks emerging from crater interior deposits suggested that the mode of emplacement was primarily related to the deposition of silt-sized particles as these settled from plumes. We have performed geologic investigations of two wind streaks clusters; one situated in western Arabia Terra, a region in the northern hemisphere of Mars, and another in an analogous terrestrial site located in southern Patagonia, Argentina, where occurrences of wind streaks emanate from playas within maar craters. In both these regions we have identified bedforms in sedimentary deposits on crater floors, along wind-facing interior crater margins, and along wind streaks. These observations indicate that these deposits contain sand-sized particles and that sediment migration has occurred via saltation from crater interior deposits to wind streaks. In Arabia Terra and in Patagonia wind streaks initiate from crater floors that contain lithic and evaporitic sedimentary deposits, suggesting that the composition of wind streak source materials has played an important role in development. Spatial and topographic analyses suggest that regional clustering of wind streaks in the studied regions directly correlates to the areal density of craters with interior deposits, the degree of proximity of these deposits, and the craters' rim-to-floor depths. In addition, some (but not all) wind streaks within the studied clusters have propagated at comparable yearly (Earth years) rates. Extensive saltation is inferred to have been involved in its propagation based on the studied terrestrial wind streak that shows ripples and dunes on its surface and the Martian counterpart changes orientation toward the downslope direction where it extends into an impact crater. ?? 2009 Elsevier B.V.

Geomorphology↗

USGS2021

Modern Mars' geomorphological activity, driven by wind, frost, and gravity

Extensive evidence of landform-scale martian geomorphic changes has been acquired in the last decade, and the number and range of examples of surface activity have increased as more high-resolution imagery has been acquired. Within the present-day Mars climate, wind and frost/ice are the dominant drivers, resulting in large avalanches of material down icy, rocky, or sandy slopes; sediment transport leading to many scales of aeolian bedforms and erosion; pits of various forms and patterned ground; and substrate material carved out from under subliming ice slabs. Due to the ability to collect correlated observations of surface activity and new landforms with relevant environmental conditions with spacecraft on or around Mars, studies of martian geomorphologic activity are uniquely positioned to directly test surface-atmosphere interaction and landform formation/evolution models outside of Earth. In this paper, we outline currently observed and interpreted surface activity occurring within the modern Mars environment, and tie this activity to wind, seasonal surface CO2 frost/ice, sublimation of subsurface water ice, and/or gravity drivers. Open questions regarding these processes are outlined, and then measurements needed for answering these questions are identified. In the final sections, we discuss how many of these martian processes and landforms may provide useful analogs for conditions and processes active on other planetary surfaces, with an emphasis on those that stretch the bounds of terrestrial-based models or that lack terrestrial analogs. In these ways, modern Mars presents a natural and powerful comparative planetology base case for studies of Solar System surface processes, beyond or instead of Earth.

Geomorphology↗

USGS2023

Poleward amplification, seasonal rainfall and forest heterogeneity in the Miocene of the eastern USA

Paleoclimate reconstructions can provide a window into the environmental conditions in Earth history when atmospheric carbon dioxide concentrations were higher than today. In the eastern USA, paleoclimate reconstructions are sparse, because terrestrial sedimentary deposits are rare. Despite this, the eastern USA has the largest population and population density in North America, and understanding the effects of current and future climate change is of vital importance. Here, we provide terrestrial paleoclimate reconstructions of the eastern USA from Miocene fossil floras. Additionally, we compare proxy paleoclimate reconstructions from the warmest period in the Miocene, the Miocene Climatic Optimum (MCO), to those of an MCO Earth System Model. Reconstructed Miocene temperatures and precipitation north of 35°N are higher than modern. In contrast, south of 35°N, temperatures and precipitation are similar to today, suggesting a poleward amplification effect in eastern North America. Reconstructed Miocene rainfall seasonality was predominantly higher than modern, regardless of latitude, indicating greater variability in intra-annual moisture transport. Reconstructed climates are almost uniformly in the temperate seasonal forest biome, but heterogeneity of specific forest types is evident. Reconstructed Miocene terrestrial temperatures from the eastern USA are lower than modeled temperatures and coeval Atlantic sea surface temperatures. However, reconstructed rainfall is consistent with modeled rainfall. Our results show that during the Miocene, climate was most different from modern in the northeastern states, and may suggest a drastic reduction in the meridional temperature gradient along the North American east coast compared to today.

Global and Planetary Change↗

USGS2021

Zircon surface crystallization ages for the extremely reduced magmatic products of the Millennium Eruption, Changbaishan Volcano (China/North Korea)

The Millennium Eruption (ME) of Changbaishan volcano (Baitoushan, Paektu) at 946 CE (Common Era) is one of the largest explosive eruptions on Earth during Holocene times. We date unpolished zircon crystal faces from diverse ME products collected from the southern side of Changbaishan volcano where the ME pumice and welded and non-welded pyroclastic flow deposits (PFD) are better exposed. All zircons from a pumice sample of the southern caldera rim and the youngest (Group 1) zircons from a welded pumiceous PFD sample yield an isochron crystallization age of 0.7 ± 1.8 ka (2σ). Zircons from the welded pumiceous PFD sample yield additional two age groups at ~10 ka and ~ 100 ka. Zircons from a non-welded charcoal-containing PFD have only one age population at 100 ka. Our work shows that different eruption products from ME have different zircon surface age distributions and may tap different levels of a zoned felsic magma chamber. In addition, the results indicate that ion microprobe U-Th dating of zircon crystal surfaces from ME pumices can effectively date the Millennium eruption age. Previously reported zircon U-series ages for Qixangzhan eruption (12.2 ± 1.1 ka, 2σ) and Yuanchi eruption (7.3 ± 1.8 ka, 2σ) at Changbaishan are also likely to date their respective eruption ages. The occurrence of 100 ka zircons in welded and non-welded PFDs reveals an important magmatic event for the Changbaishan volcano. Zircon and Fe-rich clinopyroxene crystallized at similar temperature at 770–750 °C, indicative of early zircon crystallization in peralkaline magmas. Another important result is the extremely low oxygen fugacity (fO 2 = ΔFMQ-2) of the Changbaishan samples. Minerals in ME magmas were crystallized under some of the most reducing magmatic environments on Earth. Highly reducing conditions of magmas from Changbaishan supports a continental rift setting and argues against significant involvements of subduction-related oxidizing fluids during magma genesis.

Changbaishan Volcano↗

USGS2023

The Far-Field imprint of the late Paleozoic Ice Age, its demise, and the onset of a dust-house climate across the Eastern Shelf of the Midland Basin, Texas

The late Paleozoic is a period of pronounced climatic and tectonic change, characterized by the onset and disappearance of continental-scale glaciers across polar Gondwana, the formation of Pangea, and widespread large igneous province volcanism. The low-latitude equatorial tropics are assumed to be places of persistent warm and wet climatic conditions throughout the Phanerozoic, which through intense silicate weathering, exert a major influence on Earth’s climate via the consumption of atmospheric carbon through carbonic hydrolytic weathering, formation of clay minerals and deliverability of alkalinity to ocean basins. Here we investigate the late Paleozoic sedimentary record of the Eastern Shelf of the Midland Basin in order to refine the climatic and provenance record of this region. The Eastern Shelf of the Midland Basin was situated within the equatorial tropics throughout the late Paleozoic and was connected to the open ocean through a network of fluvial systems that drained into the marine Midland Basin. We present new U-Pb zircon geochronology (19 samples, 2591 analyses) and sedimentary petrography (11 samples, 5800 grain counts), which we integrate with previously published paleobotany, paleosol chemistry and clay mineralogy to provide a holistic climate and tectonic record from this region. We observe major changes in sedimentary processes that we attribute to the formation of Pangea, eustatic changes linked to a dynamic high-latitude glaciation and teleconnections with low latitude hydrology, and a long-term shift in the Earth climate system all of which result in a dynamic sediment provenance history. Late Pennsylvanian and earliest Permian deposits are enriched in zircons with local affinity and interpreted to reflect local uplift and repeat incision across the basin margin, the latter a result of glacioeustatic forcing during an “everwet” climate. A major paleoenvironmental shift occurs in the late early Permian, which is reflected by the transition from fluvial to mixed fluvial-aeolian and ultimately aeolian dominant sedimentation by the late Permian. The transition from fluvial to aeolian dominant sedimentation is accompanied by a change in clay chemistry, sedimentary rock textual maturity, paleosol morphology and a threefold increase in Paleozoic zircons in the mid to late Permian strata. Widespread loess deposits across equatorial Pangea during the Permian have been used to argue for the possibility of equatorial glaciers situated in highland settings during the early Permian. Conversely, our data suggest initiation of a substantial component of aeolian deposition across the field areas, which is coincident with widespread ice loss across high latitude Gondwana, and ultimately highlights the teleconnections between high latitude glaciation and the low latitude hydrologic cycle.

Texas↗

USGS2013

A new dry hypothesis for the formation of Martian linear gullies

Long, narrow grooves found on the slopes of martian sand dunes have been cited as evidence of liquid water via the hypothesis that melt-water initiated debris flows eroded channels and deposited lateral levées. However, this theory has several short-comings for explaining the observed morphology and activity of these linear gullies. We present an alternative hypothesis that is consistent with the observed morphology, location, and current activity: that blocks of CO 2 ice break from over-steepened cornices as sublimation processes destabilize the surface in the spring, and these blocks move downslope, carving out levéed grooves of relatively uniform width and forming terminal pits. To test this hypothesis, we describe experiments involving water and CO 2 blocks on terrestrial dunes and then compare results with the martian features. Furthermore, we present a theoretical model of the initiation of block motion due to sublimation and use this to quantitatively compare the expected behavior of blocks on the Earth and Mars. The model demonstrates that CO 2 blocks can be expected to move via our proposed mechanism on the Earth and Mars, and the experiments show that the motion of these blocks will naturally create the main morphological features of linear gullies seen on Mars.

Icarus↗

USGS2015

Physical abrasion of mafic minerals and basalt grains: application to Martian aeolian deposits

Sediment maturity, or the mineralogical and physical characterization of sediment deposits, has been used to locate sediment source, transport medium and distance, weathering processes, and paleoenvironments on Earth. Mature terrestrial sands are dominated by quartz, which is abundant in source lithologies on Earth and is physically and chemically stable under a wide range of conditions. Immature sands, such as those rich in feldspars or mafic minerals, are composed of grains that are easily physically weathered and highly susceptible to chemical weathering. On Mars, which is predominately mafic in composition, terrestrial standards of sediment maturity are not applicable. In addition, the martian climate today is cold, dry and sediments are likely to be heavily influenced by physical weathering rather than chemical weathering. Due to these large differences in weathering processes and composition, martian sediments require an alternate maturity index. Abrason tests have been conducted on a variety of mafic materials and results suggest that mature martian sediments may be composed of well sorted, well rounded, spherical basalt grains. In addition, any volcanic glass present is likely to persist in a mechanical weathering environment while chemically altered products are likely to be winnowed away. A modified sediment maturity index is proposed that can be used in future studies to constrain sediment source, paleoclimate, mechanisms for sediment production, and surface evolution. This maturity index may also provide details about erosional and sediment transport systems and preservation processes of layered deposits.

Icarus↗

USGS2021

Sentinel-2 and WorldView-3 atmospheric correction and signal normalization based on ground-truth spectroradiometric measurements

Remote sensing satellite Earth Observing Systems (EOS) provide a variety of products for monitoring Earth surface processes at varying spatial and spectral resolutions. Combining information from high and medium spatial resolution images is valuable for monitoring ground cover and vegetation status in cropland, grassland, forests, and other natural settings. However, coupling information from different EOS requires compensating for atmospheric and view angle effects before integrating comparable surface reflectance (SR) values. The objectives of this study were i) to assess how different atmospheric constituents affect the atmospheric correction results in Sentinel-2 and WorldView-3 imagery, ii) to establish a relationship with field spectra measurements, and iii) to develop an empirical approach to ensure that SR values extracted from different EOS can be normalized for use in monitoring vegetation and land cover status. We compared surface reflectance values derived from Sentinel-2 images corrected with Sen2Cor, MODTRAN or FLAASH atmospheric correction approaches for the visible-to-near infrared regions. Additionally, this information was compared to SR values extracted from WorldView-3 imagery acquired from the same dates and location (Central Spain) and corrected with MODTRAN and FLAASH approaches. Assessment of the atmospheric correction was conducted by comparing satellite image SR with ground-truth spectra acquired with a FieldSpec hand-held spectroradiometer. The results emphasized the importance of using common atmospheric parameters collected from ancillary data sources (i.e. MODIS Atmosphere & Land products) to ensure a reliable SR comparison. When compared to field-collected spectral data, SR from corrected Sentinel-2 push-broom imagery showed a reliable match (<4% difference in the visible bands and <0.52% difference in the near infrared bands). However, SR imagery from the pointable WorldView-3 instrument showed significant deviation, likely resulting from the effects of steep off-nadir acquisition angles (24.6° to 39.1°) combined with surface anisotropy. The magnitude and sign of the deviation in SR differed depending on the vegetation type, wavelength and sun-surface-sensor geometry. Therefore, it was necessary to account for angular effects to ensure reliable comparisons of imagery from the different EOS. In this study, an empirical angular correction approach was developed based on calibrating each WorldView-3 band against the ground-truth spectra. This correction allowed for the accurate signal normalization of WorldView-3 and Sentinel-2 imagery SR in the visible-to-near infrared regions.

ISPRS Journal of Photogrammetry and Remote Sensing↗

USGS2012

Age-specific light preferences and vertical migration patterns of a Great Lakes invasive invertebrate, Hemimysis anomala

We use a combination of spectral sensitivity analyses, laboratory behavioral observations and field distributions of a vertically migrating invertebrate, Hemimysis anomala (a recent invasive species to the Laurentian Great Lakes of North America), to determine if light preference and timing of emergence has an ontogenetic component. Juvenile Hemimysis (< 4.5 mm) preferred light levels between 10 −3.4 and 10 −2.4 mylux— a Hemimysis -specific unit of brightness derived from visual pigment analyses (wavelength of maximum absorbance = 500 nm; 1 mylux ~ 159 lx). These preferred light levels are equivalent to those present during nautical twilight on the Earth's surface and were several orders of magnitude brighter than those most preferred by adults (> 4.5 mm) in the laboratory (10 −6.4 to 10 −7.4 mylux). Both size classes completely avoided light levels of 10 −0.4 mylux and greater, which are representative of daytime light levels at the Earth's surface. Net hauls taken at ~ 20-min intervals from sunset to the end of nautical twilight on two sampling occasions on Seneca Lake, New York (sampling depth = 2 m) revealed that juveniles emerged into the water column during civil twilight. Adult Hemimysis emerged later during nautical twilight when juveniles had already reached their maximum abundance in the water column. Laboratory-derived light preferences successfully predicted the timing of emergence and time of maximal abundance of both size classes on both sampling occasions. This study is one of the first to demonstrate that Hemimysis diel vertical migration has an ontogenetic component and to report the specific light levels likely to initiate and limit vertical movements.

Great Lakes↗

USGS2011

Demonstration of a conceptual model for using LiDAR to improve the estimation of floodwater mitigation potential of Prairie Pothole Region wetlands

Recent flood events in the Prairie Pothole Region of North America have stimulated interest in modeling water storage capacities of wetlands and their surrounding catchments to facilitate flood mitigation efforts. Accurate estimates of basin storage capacities have been hampered by a lack of high-resolution elevation data. In this paper, we developed a 0.5 m bare-earth model from Light Detection And Ranging (LiDAR) data and, in combination with National Wetlands Inventory data, delineated wetland catchments and their spilling points within a 196 km2 study area. We then calculated the maximum water storage capacity of individual basins and modeled the connectivity among these basins. When compared to field survey results, catchment and spilling point delineations from the LiDAR bare-earth model captured subtle landscape features very well. Of the 11 modeled spilling points, 10 matched field survey spilling points. The comparison between observed and modeled maximum water storage had an R 2 of 0.87 with mean absolute error of 5564 m 3 . Since maximum water storage capacity of basins does not translate into floodwater regulation capability, we further developed a Basin Floodwater Regulation Index. Based upon this index, the absolute and relative water that could be held by wetlands over a landscape could be modeled. This conceptual model of floodwater downstream contribution was demonstrated with water level data from 17 May 2008.

Journal of Hydrology↗

USGS2006

The changing shapes of active volcanoes: History, evolution, and future challenges for volcano geodesy

At the very heart of volcanology lies the search for the 'plumbing systems' that form the inner workings of Earth’s active volcanoes. By their very nature, however, the magmatic reservoirs and conduits that underlie these active volcanic systems are elusive; mostly they are observable only through circumstantial evidence, using indirect, and often ambiguous, surficial measurements. Of course, we can infer much about these systems from geologic investigation of materials brought to the surface by eruptions and of the exposed roots of ancient volcanoes. But how can we study the magmatic processes that are occurring beneath Earth’s active volcanoes? What are the geometry, scale, physical, and chemical characteristics of magma reservoirs? Can we infer the dynamics of magma transport? Can we use this information to better forecast the future behavior of volcanoes? These questions comprise some of the most fundamental, recurring themes of modern research in volcanology. The field of volcano geodesy is uniquely situated to provide critical observational constraints on these problems. For the past decade, armed with a new array of technological innovations, equipped with powerful computers, and prepared with new analytical tools, volcano geodesists have been poised to make significant advances in our fundamental understanding of the behavior of active volcanic systems. The purpose of this volume is to highlight some of these recent advances, particularly in the collection and interpretation of geodetic data from actively deforming volcanoes. The 18 papers that follow report on new geodetic data that offer valuable insights into eruptive activity and magma transport; they present new models and modeling strategies that have the potential to greatly increase understanding of magmatic, hydrothermal, and volcano-tectonic processes; and they describe innovative techniques for collecting geodetic measurements from remote, poorly accessible, or hazardous volcanoes. To provide a proper context for these studies, we offer a short review of the evolution of volcano geodesy, as well as a case study that highlights recent advances in the field by comparing the geodetic response to recent eruptive episodes at Mount St. Helens. Finally, we point out a few areas that continue to challenge the volcano geodesy community, some of which are addressed by the papers that follow and which undoubtedly will be the focus of future research for years to come.

Journal of Volcanology and Geothermal Research↗

USGS2025

Ultraviolet and visible remote sensing of volcanic gases

As magma rises in volcanic systems, volatile species exsolve from the silicate melt and are emitted as gases into the atmosphere. Measuring the magnitude and composition of gas emissions from volcanoes provides insights into processes occurring deep within the Earth and helps constrain the impact of volcanic degassing on atmospheric chemistry. Optical remote sensing techniques allow volcanic gas emissions to be characterized without the need to access hazardous areas near active volcanic vents. This paper reviews the state of the art in ultraviolet and visible volcanic gas remote sensing from the ground, air, and space. Special attention is given to discussing the physics of atmospheric radiative transfer on which these techniques are based. The functionality and limitations of different remote sensing instruments are examined, making clear that the ideal choice of instrumentation will depend on the volcanic system to which it is applied and the sought measurement parameters. Common algorithms for determining trace gas column densities, gas burdens, and volcanic emission rates from measurements of spectral radiance are outlined and compared, showing how some algorithms attempt to model the physics of the measurement while others maximize sensitivity. Several examples demonstrate how remote sensing measurements continue to advance our understanding of volcanic systems and their impact on the atmosphere. Finally, a few promising directions of inquiry are suggested that could lead to improvements in remote sensing instrumentation and analysis techniques. By combining spectroscopic and imaging techniques, improving our understanding of atmospheric radiative transfer, expanding the suite of target gases, and increasing the coverage and frequency of observations, we stand to significantly improve our ability to detect and quantify volcanic gas emissions and gain new insights into important Earth-system processes.

Journal of Volcanology and Geothermal Research↗

USGS2015

Critical metals in manganese nodules from the Cook Islands EEZ, abundances and distributions

The Cook Islands (CIs) Exclusive Economic Zone (EEZ) encompasses 1,977,000 km 2 and includes the Penrhyn and Samoa basins abyssal plains where manganese nodules flourish due to the availability of prolific nucleus material, slow sedimentation rates, and strong bottom currents. A group of CIs nodules was analyzed for mineralogical and chemical composition, which include many critical metals not before analyzed for CIs nodules. These nodules have varying sizes and nuclei material; however all are composed predominantly of δ-MnO 2 and X-ray amorphous iron oxyhydroxide. The mineralogy, Fe/Mn ratios, rare earth element contents, and slow growth rates (mean 1.9 mm/10 6 years) reflect formation primarily by hydrogenetic precipitation. The paucity of diagenetic input can be explained by low primary productivity at the surface and resultant low organic matter content in seafloor sediment, producing oxic seafloor and sub-seafloor environments. The nodules contain high mean contents of Co (0.41%), Ni (0.38%), Ti (1.20%), and total rare earth elements plus yttrium (REY; 0.167%), and also high contents of Mo, Nb, V, W, and Zr. Compiled data from a series of four cruises by the Japan International Cooperation Agency and the Mining agency of Japan from 1985 to 2000 were used to generate a map that defines the statistical distribution of nodule abundance throughout the EEZ, except the Manihiki Plateau. The abundance distribution map shows a belt of high nodule abundance (19–45 kg/m 2 ) that starts in the southeast corner of the EEZ, runs northwest, and also bifurcates into a SW trending branch. Small, isolated areas contain abundances of nodules of up to 58 kg/m 2 . Six ~ 20,000 km 2 areas of particularly high abundance were chosen to represent potential exploration areas, and maps for metal concentration were generated to visualize metal distribution and to extrapolate estimated metal tonnages within the six sites and the EEZ as a whole. Grades for Mn, Cu, and Ni are low in CIs nodules in areas of high abundance; however, Ti, Co, and REY show high contents where nodule abundances are high. Of the six areas identified to represent a range of metal contents, one at the northern end of the N-S abundance main belt optimizes the most metals and would yield the highest dry metric tons for Mn (61,002,292), Ni (1,247,834), Mo (186,166), V (356,247), W (30,215), and Zr (195,323). When compared with the Clarion–Clipperton Zone, the CIs nodules show higher nodule abundances (> 25 kg/m 2 over ~ 123,844 km 2 ), and are more enriched in the green-tech, high-tech, and energy metals Co, Ti, Te, Nb, REY, Pt, and Zr. The CIs EEZ shows a significant resource potential for these critical metals due to their high prices, high demand, and the high nodule abundance, which will allow for a smaller footprint for a 20-year mine site and therefore smaller environmental impact.

Ore Geology Reviews↗

USGS2020

Apatite trace element geochemistry and cathodoluminescent textures—Acomparison between regional magmatism and the Pea Ridge IOA-REE andBoss IOCG deposits, southeastern Missouri iron metallogenic province, USA

The southeast Missouri iron metallogenic province contains a remarkable wealth of historically important Fe, Cu, Au, and rare earth element (REE) deposits including the Pea Ridge iron oxide-apatite-rare earth element (IOA-REE) deposit and the Boss iron oxide-copper-gold (IOCG) deposit. These deposits are coeval with silicic and intermediate composition magmatism in the St. Francois Mountains terrane. Magmatism, iron-oxide (±Cu, Au, Co) and apatite formation, and REE mineralization overlapped in space and time, but the specific role of regional magmatism in the metallogenesis of these deposits remains unclear and basic petrogenetic models are still debated. We report results from high-spatial resolution textural and geochemical analyses of apatite from regional igneous and ore rocks to elucidate their petrogenetic histories and evaluate deposit models. Backscattered electron and spectral cathodoluminescence imaging of apatite reveal no primary igneous zoning, but show different domains with intricate rims and dissolution/reprecipitation textures, each with distinctive REE patterns in many samples. Apatite from all samples are nearly endmember fluorapatite containing up to ~1.3 wt% Cl and F/Cl ratios span nearly three orders of magnitude. Fresh igneous fluorapatite contain low Na2O (0.15 wt%) while most Pea Ridge ore samples contain higher Na2O (up to ~0.45 wt%), and concentrations of sulfur in fluorapatite of all types are generally moderate to low (0.3 wt% SO3). Significant amounts of Fe (60,000 ppm), Mg (30,000 ppm), Mn (7,000 ppm), and Sr (12,000 ppm) are contained in fluorapatite of all sample types, and they also have moderate amounts of As (4,000 ppm), Ba (2,000 ppm), Th (400 ppm), and U (80 ppm). Fluorapatite show an extraordinarily large range of REE (~0.1-2.0 wt%) and Y (~100-7000 ppm) concentrations. While fresh igneous fluorapatite share many geochemical features with metasomatized igneous fluorapatite and ore-stage fluorapatite from the Pea Ridge IOA and Boss IOCG ore zones, they also have distinct geochemical signatures that are indicative of unique trace element partitioning and substitution mechanisms. These distinguishing textural and geochemical signatures preclude ore-zone fluorapatite genesis directly from a magma (i.e., crystallization directly from a silicate melt) but are permissive of ore-zone fluorapatite formation by magmatic-hydrothermal fluids derived from the regional magmas. Basinal brines may play an important role in the formation of fluorapatite, especially from the Pea Ridge hematite and Boss magnetite-rich zones. Fluorapatite from different ore zones likely formed by crystallization during pulses of hydrothermal fluids with varying Cl-, Na-, and F-contents, which fundamentally controlled the carrying capacity and solubility of REE+Y and generated geochemically distinctive generations of fluorapatite. Exploration geologists using fluorapatite trace element geochemistry to identify IOA and IOCG deposits should proceed with caution, as more high-quality data from these deposits are needed to improve multivariate discrimination analysis. Fluorapatite from IOA/IOCG deposits can be reasonably discriminated from that of other mineral deposit types (e.g., porphyry/epithermal, skarn, orogenic), but no criteria successfully discriminate yet between IOA and IOCG deposits.

Missouri↗

USGS2011

Sensitivity of Pliocene ice sheets to orbital forcing

The stability of the Earth's major ice sheets is a critical uncertainty in predictions of future climate and sea level change. One method of investigating the behaviour of the Greenland and the Antarctic ice sheets in a warmer-than-modern climate is to look back at past warm periods of Earth history, for example the Pliocene. This paper presents climate and ice sheet modelling results for the mid-Pliocene warm period (mPWP; 3.3 to 3.0 million years ago), which has been identified as a key interval for understanding warmer-than-modern climates (Jansen et al., 2007). Using boundary conditions supplied by the United States Geological Survey PRISM Group (Pliocene Research, Interpretation and Synoptic Mapping), the Hadley Centre coupled ocean–atmosphere climate model (HadCM3) and the British Antarctic Survey Ice Sheet Model (BASISM), we show large reductions in the Greenland and East Antarctic Ice Sheets (GrIS and EAIS) compared to modern in standard mPWP experiments. We also present the first results illustrating the variability of the ice sheets due to realistic orbital forcing during the mid-Pliocene. While GrIS volumes are lower than modern under even the most extreme (cold) mid-Pliocene orbit (losing at least 35% of its ice mass), the EAIS can both grow and shrink, losing up to 20% or gaining up to 10% of its present-day volume. The changes in ice sheet volume incurred by altering orbital forcing alone means that global sea level can vary by more than 25 m during the mid-Pliocene. However, we have also shown that the response of the ice sheets to mPWP orbital hemispheric forcing can be in anti-phase, whereby the greatest reductions in EAIS volume are concurrent with the smallest reductions of the GrIS. If this anti-phase relationship is in operation throughout the mPWP, then the total eustatic sea level response would be dampened compared to the ice sheet fluctuations that are theoretically possible. This suggests that maximum eustatic sea level rise does not correspond to orbital maxima, but occurs at times where the anti-phasing of Northern and Southern Hemisphere ice sheet retreat is minimised.

Palaeogeography, Palaeoclimatology, Palaeoecology↗