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At least 1,207 records · Page 67Linked to original sources

Origin of Comb Layering and Orbicular Structure, Sierra Nevada Batholith, California

A new descriptive term, comb layering , is proposed to replace the informal term Willow Lake-type layering , first introduced by Poldervaart and Taubeneck (1959) to describe layering in granitoid rocks in which constituent crystals are oriented approximately perpendicular to individual layers. The term schlieren layering is proposed to describe the “normal” layering of granitic rocks defined by alternating layers enriched or depleted in the normal mafic minerals. In such layers, elongate minerals commonly lie in the plane of the layering. Comb layering is widespread in plutonic rocks of California and is commonly associated with orbicular diorites. Evidence from a detailed study of three localities in the Sierra Nevada indicates that comb layering forms chiefly in overturned troughs along overhanging walls of plutons or along walls of dikes or pipes that cut country rocks adjoining plutons. Orbicular rocks associated with the comb layering are formed by a nucleus surrounded by multiple comb layers. The growth direction in comb layers can be determined by the branching and widening of plagioclase and hornblende crystals and is invariably toward the parent pluton. Field data indicate that comb layering cannot have formed from silicate magma, and further suggest that the layers have been deposited by large volumes of aqueous fluids that migrated upward along contacts between magma and wallrock or along the interface between magma and previously solidified melt. Comb layering and orbicules are largely restricted to structural traps into which upwardly migrating, solute-rich water was channeled owing to its low density. The comb layers grew on the solid walls of fluid-filled channels, whereas orbicules formed by precipitation of comb layers on hobbling inclusions suspended within the upward-flowing fluid.

California↗

Rocks and geology in the San Francisco Bay region

The landscape of the San Francisco Bay region is host to a greater variety of rocks than most other regions in the United States. This introductory guide provides illustrated descriptions of 46 common and important varieties of igneous, sedimentary, and metamorphic rock found in the region. Rock types are described in context of their identification qualities, how they form, and where they occur in the region. The guide also provides discussion about of regional geology, plate tectonics, the rock cycle, the significance of the selected rock types in relation to both earth history and the impact of mineral resources on the development in the region. Maps and text also provide information where rocks, fossils, and geologic features can be visited on public lands or in association with public displays in regional museums, park visitor centers, and other public facilities.

California↗

Chabazite in siliceous tuffs of a Pliocene lacustrine deposit near Durkee, Baker County, Oregon

A relatively pure chabazite deposit of at least 75 X 10 6 metric tons occurs near the Durkee type locality of erionite. This erionite is in a welded tuff interbedded with lacustrine rocks- of a closed Pliocene basin. The zeolites, chabazite, erionite, clinoptilolite, and other authigenic silicate minerals are confined to a 27-square-kilometer area of altered rocks enclosed in relatively freshwater lacustrine beds. About 135 meters of the lower part of the 350-m stratigraphic section at the southeastern part of the lake basin contain zeolitic tuff. The chabazite is an early product of the reaction between glass of rhyolitic or dacitic composition and alkaline (pH>9) saline lake waters. Erionite, clinoptilolite, analcime, and potassium feldspar follow chabazite in the paragenetic sequence. At the erionite type locality, chabazite and clinoptilolite form megascopic crystal clusters within fractures and cavities in unaltered welded tuff. Elsewhere in the basin, most zeolite crystals in the altered airfall or reworked tuffs are less than 80 micrometers long. Chemical analyses, unit-cell determinations, and mean indices of refraction show that fine-grained chabazite varies in composition and physical parameters.

Oregon↗

Comparative properties of saponitic fault gouge and serpentinite muds cored from mud volcanoes of the Mariana subduction zone

We obtained 12 core samples for physical and chemical characterization from three serpentinite mud volcanoes (Yinazao, Asùt Tesoru, and Fantangisña) located on the forearc of the Mariana subduction system, that were drilled during International Ocean Discovery Program Expedition 366. Two samples from the Fantangisña mud volcano are interpreted to be clay-rich fault gouges derived from the subduction channel. Their bulk compositions are intermediate between the serpentinites and oceanic basalts. The oceanic crustal materials in the gouges have been thoroughly metasomatized and the serpentinites extensively altered to the trioctahedral, Mg-rich smectite clays saponite and corrensite. The only relict phases in clasts of crustal rock are accessory Ti- and P-bearing minerals. The two fault gouge samples have lower frictional strengths ( μ < 0.2) than the serpentinites ( μ = 0.2–0.4), and their measured permeabilities are also somewhat lower. Their physical and compositional properties correspond to saponitic gouges from other faults that juxtapose serpentinite against crustal rocks, in particular gouges from the two creeping traces of the San Andreas Fault recovered in the core from the San Andreas Fault Observatory at Depth. The décollement beneath Fantangisña mud volcano is thus expected to be very weak and likely characterized by stable slip.

Geophysics, Geochemistry, Geosystems↗

Cretaceous to Oligocene magmatic and tectonic evolution of the western Alaska Range: Insights from U-Pb and 40Ar/39Ar geochronology

New U-Pb and 40 Ar/ 39 Ar ages integrated with geologic mapping and observations across the western Alaska Range constrain the distribution and tectonic setting of Cretaceous to Oligocene magmatism along an evolving accretionary plate margin in south-central Alaska. These rocks were emplaced across basement domains that include Neoproterozoic to Jurassic carbonate and siliciclastic strata of the Farewell terrane, Triassic and Jurassic plutonic and volcanic rocks of the Peninsular terrane, and Jurassic and Cretaceous siliciclastic strata of the Kahiltna assemblage. Plutonic rocks of different ages also host economic mineralization including intrusion-related Au, porphyry Cu-Mo-Au, polymetallic veins and skarns, and peralkaline intrusion-related rare-earth elements. The oldest intrusive suites were emplaced ca. 104–80 Ma into the Peninsular terrane only prior to final accretion. Deformation of the northern Kahiltna succession and underlying Farewell terrane occurred at ca. 97 Ma, and more widespread deformation ca. 80 Ma involved south-vergent folding and thrusting of the Kahiltna assemblage that records collisional accretion of the Peninsular-Wrangellia terrane and juxtaposition of sediment wedges formed on the inboard and outboard terranes. More widespread magmatism ca. 75–55 Ma occurred in two general pulses, each having distinct styles of localized deformation. Circa 75–65 Ma plutons were emplaced in a transpressional setting and stitch the accreted Peninsular and Wrangellia terranes to the Farewell terrane. Circa 65–55 Ma magmatism occurred across the entire range and extends for more than 200 km inboard from the inferred position of the continental margin. The Paleocene plutonic suite generally reflects shallower emplacement depths relative to older suites and is associated with more abundant andesitic to rhyolitic volcanic rocks. Deformation ca. 58–56 Ma was concentrated along two high-strain zones, the most prominent of which is 1 km wide, strikes east-northeast, and accommodated dextral oblique motion. Emplacement of widespread intermediate to mafic dikes ca. 59–51 Ma occurred before a notable magmatic lull from ca. 51–44 Ma reflecting a late Paleocene to early Eocene slab window. Magmatism resumed ca. 44 Ma, recording the transition from slab window to renewed subduction that formed the Aleutian-Meshik arc to the southwest. In the western Alaska Range, Eocene magmatism included emplacement of the elongate north-south Merrill Pass pluton and large volumes of ca. 44–37 Ma andesitic flows, tuffs, and lahar deposits. Finally, a latest Eocene to Oligocene magmatic pulse involved emplacement of a compositionally variable but spatially concentrated suite of magmas ranging from gabbro to peralkaline granite ca. 35–26 Ma, followed by waning magmatism that coincided with initiation of Yakutat shallow-slab subduction. Cretaceous to Oligocene magmatism throughout the western Alaska Range collectively records terrane accretion, translation, and integration together with evolving subduction dynamics that have shaped the southern Alaska margin since the middle Mesozoic.

Alaska↗

Mineralization, alteration, and hydrothermal metamorphism of the ophiolite-hosted Turner-Albright sulfide deposit, southwestern Oregon

The Turner-Albright sulfide deposit, part of the Josephine ophiolite, formed on and below the seafloor during Late Jurassic volcanism at a back arc spreading center. Ore fluids were probably localized by faults which were active on the seafloor at the time of sulfide deposition. The uppermost massive sulfide formed on the seafloor at hydrothermal vents, similar to sulfide-depositing hot springs on modern spreading centers. The bulk of the sulfide mineralization formed below the seafloor within olivine basalt hyaloclastite erupted near the time of mineralization. Infiltration of hydrothermal fluid into the hyalo-clastite altered the rock to quartz + Fe-chlorite and quartz + sericite + Fe-chlorite. Intense alteration resulted in replacement of the protolith by quartz + sulfide. The fluid responsible for the hydrothermal alteration was evolved seawater with low p H and Mg and high Fe. Sulfide δ 534 S values average 4.7‰ and indicate contribution of sulfur from both basalt and seawater sulfate. The average value of sulfide δ 34 S and the difference between sulfide and contemporaneous seawater sulfate δ 34 S values are similar to ophiolite-hosted sulfide deposits in Cyprus. Chlorite-rich hydrothermally altered basalt has δ 18 O values of 3.0–6.8‰ due to high-temperature (250°–350°C) reaction with a seawater-derived ore fluid. Quartz in silicified basalt has higher δ 18 O values of 12.3–15.5‰, probably reflecting lower-temperature recrystallization of amorphous silica formed during initial alteration of basalt. Mudstone and clinopyroxene basalt above the sulfide horizons were not altered by the ore-transporting hydrothermal fluid, but these rocks were hydrothermally metamorphosed by altered seawater heated by deep circulation into hot oceanic crust. This subseafloor metamorphism produced a mineral assemblage typical of prehnite-pumpellyite facies metamorphism. Exchange with altered seawater increased the whole-rock δ 18 O of the basalts to values of 9.4–11.2‰.

Journal of Geophysical Research Solid Earth↗

A comparison of pre- and post-remediation water quality, Mineral Creek, Colorado

Pre- and post-remediation data sets are used herein to assess the effectiveness of remedial measures implemented in the headwaters of the Mineral Creek watershed, where contamination from hard rock mining has led to elevated metal concentrations and acidic pH. Collection of pre- and post-remediation data sets generally followed the synoptic mass balance approach, in which numerous stream and inflow locations are sampled for the constituents of interest and estimates of streamflow are determined by tracer dilution. The comparison of pre- and post-remediation data sets is confounded by hydrologic effects and the effects of temporal variation. Hydrologic effects arise due to the relatively wet conditions that preceded the collection of pre-remediation data, and the relatively dry conditions associated with the post-remediation data set. This difference leads to a dilution effect in the upper part of the study reach, where pre-remediation concentrations were diluted by rainfall, and a source area effect in the lower part of the study reach, where a smaller portion of the watershed may have been contributing constituent mass during the drier post-remediation period. A second confounding factor, temporal variability, violates the steady-state assumption that underlies the synoptic mass balance approach, leading to false identification of constituent sources and sinks. Despite these complications, remedial actions completed in the Mineral Creek headwaters appear to have led to improvements in stream water quality, as post-remediation profiles of instream load are consistently lower than the pre-remediation profiles over the entire study reach for six of the eight constituents considered (aluminium, arsenic, cadmium, copper, iron, and zinc). Concentrations of aluminium, cadmium, copper, lead, and zinc remain above chronic aquatic-life standards, however, and additional remedial actions may be needed. Future implementations of the synoptic mass balance approach should be preceded by an assessment of temporal variability, and modifications to the synoptic sampling protocol should be made if necessary.

Colorado↗

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado↗

Petrogenesis and geological history of a uranium source rock: a case study in northeastern Washington, U.S.A.

A small (4 km 2 ) drainage basin in northeastern Washington contains highly uraniferous groundwater and highly uraniferous peaty sediments of Holocene age. The U is derived from granitic bedrock that underlies the entire drainage basin and that contains 9–16 ppm U. This local bedrock was studied by petrographic, chemical and isotopic methods to determine conditions of its petrogenesis and post-emplacement history that may have contributed to its present high U content and source-rock capability. The original magma was derived by anatexis of Precambrian continental crust of probable mixed metaigneous and metasedimentary character. Mineral-melt partitioning controlled the enrichment of U in chemically evolved phases of the crystallizing melt. Following emplacement in the upper crust at ∼100Ma, the pluton interacted with meteoric-hydrothermal water at ambient temperatures 300°C. Locally intense fracturing promoted alteration, and fracturing and alteration probably continued during later regional uplift in the Eocene. Regional uplift was followed by low-temperature alteration and weathering in the middle to late Tertiary. The combined result of hydrothermal alteration and low-temperature alteration and weathering was the redistribution of U from primary mineral hosts such as allanite to new sites on fracture surfaces and in secondary minerals such as hematite. Zones of highly fractured and altered rock show the most obvious evidence of this process. A model is proposed in which high-angle fractures beneath the drainage basin were the sites of Tertiary supergene enrichments of U. Recent glacio-isostatic uplift has elevated these older enriched zones to shallow levels where they are now being leached by oxidizing groundwater. The chemistry, mineralogy, texture and geological history of this U source-rock suggest criteria for locating other granitic terrane that may contain uraniferous waters and associated young surficial U deposits. The details of U distribution and mobility at this site also apply to the general topic of U mobility in granitic rocks.

Washington↗

Reconnaissance geology of the Precambrian rocks in the Bi'r Ghamrah quadrangle, Kingdom of Saudi Arabia

Three sequences of volcanic and sedimentary rocks are identified in the Precambrian rocks of the Bi'r Ghamrah quadrangle at the eastern edge of the Precambrian Shield in central Saudi Arabia. The oldest sequence is called the Bi'r Khountina Group. It consists of conglomerate marble, andesite, and graywacke. Unconformably overlying this group is a sequence of graywacke with minor lava called the Murdama Group. In a small area in the southern part of the quadrangle, these rocks are unconformably overlain by rhyolitic tuff and rhyolite tentatively correlated with the Shammar Rhyolite. The older of these sedimentary and volcanic rocks were intruded by diorite and gabbro and by a large pluton of alkalic granite. A contact metamorphic aureole was formed in the Bi'r Khountina and Murdama Groups adjacent to the granite, and feeder dikes of the Sbmmmar Rhyolite(?) intrude the granite. The Bi'r Khountina Group is folded into a south-plunging asymmetrical anticlinorium, the west limb of which is repeated across northwest-trending faults. The Murdama Group appears to have been folded along the same axes, but the contact aureole against the alkalic granite and the imprint of the west-northwest striking Najd fault zone cause the rocks of the Murdama Group to appear to trend westward. Results of spectrographic and chemical analyses of wadi sand, heavy-mineral concentrates, and detrital magnetite show small anomalies. The ultramafic rocks intruded prior to the deposition of the Murdama Group are the source of anomalous chromium and lanthanum and of threshold nickel, scandium, and vanadium. The intrusive rocks younger than the Murdama Group are sources for anomalous lead and threshold silver, boron, barium, beryllium, zirconium, lanthanum, and tin. One small ancient working, probably opened for gold, is present, and at least four places in the Precambrian part of the quadrangle ere potentially favorable for gold, silver, and lead. Chromite is a potential resource in the northeastern part of the quadrangle.

Open-File Report↗

Magmatic differentiation in tertiary and quaternary volcanic rocks from Adak and Kanaga Islands, Aleutian Islands, Alaska

Samples of 17 volcanic rocks of Tertiary and Quaternary age from Adak and Kanaga islands have been chemically analyzed and studied microscopically. Spectrograms have been made of 10 of them. The rocks from Adak represent one center of possibly older Tertiary age and two centers of younger Tertiary or Quaternary age. The rocks from Kanaga Island represent both a shield volcano of possibly Tertiary age, partly destroyed by the formation of a caldera, and a young cone of Quaternary age that has grown within the caldera. All the rocks are basalt or andesite. Modally, all are characterized by relatively large crystals of plagioclase more calcic than andesine, and by one or more of the following ferromagnesian minerals: olivine, hypersthene, augite, and hornblende. Apatite and iron ores are common, and late silica minerals and orthoclase occur interstitially in the groundmasses of some rocks . As analyses of no more than four samples are available for each center, the small differences between sets of analyses representing different centers are of doubtful significance. Consequently, the analyses representing all the centers have been plotted on each of the several diagrams used. The several types of variation diagrams show that the province is a calc-alkaline one. The alkali-lime index is in the neighborhood of 63. This very high value is comparable with that for Katmai and is only slightly less than the maximum for the Japanese volcanic rock series. The quantities of minor constituents present are not exceptional for the rock types analyzed; the rocks from Adak are apparently more strontium-rich than those from Kanaga . The chemical analyses of the more basic rock types, as compared with the average analysis of plateau basalt, suggest that the Aleutian parental magma could have been derived from a plateau basalt magma by the addition of plagioclase and the subtraction of pyroxene, iron ore, and some quartz. The distribution of the minor elements can be explained more easily by postulating that, at least on Kanaga Island , some sediments have been assimilated. The derivation of the analyzed rocks from the Aleutian parental magma is most easily explained by the hypothesis that the plagioclase remained in suspension while the ferromagnesian minerals were settling out.

Alaska↗

Correlation between geophysical data and rock types in the Piedmont and coastal plain of northeast Virginia and related areas

Physical, chemical, and mineralogic characteristics of rock units in parts of the northeast Virginia Piedmont are reflected in the aeromagnelic, aeroradioactivity, and gravity data for this area. Magnetic anomalies show the areal distribution of rocks containing magnetite. Aeroradiometric anomalies in the Piedmont and Coastal Plain provinces are directly related to the K 2 O content of the formations. In the crystalline rocks of the Piedmont this is reflected in their muscovite and microcline content, whereas in the Coastal Plain province it is related to the glauconite content of the Aquia Formation. Locally, in the crystalline rocks of the Piedmont, uranium- and thorium-bearing mineral content is of greater importance than K 2 O-bearing mineral content in producing aeroradiometric anomalies. The region also is characterized by (1) a northern gravity high, (2) a southern gravity high presumed to be caused by mafic rocks, and (3) an intervening zone characterized by low gravity relief and underlain by schist and gneiss. Geologic and geophysical extrapolation southward toward the Arvonia area show that the Chopawamsic Formation and the volcanic rocks of the Evington group are coeval. Also, on the northwest side of these volcanic rocks is a belt of small rootless mafic and ultramafic rocks diapirically ceplaced in folded rocks of Early Cambrian (?) age.

Virginia↗

Exploration possibilities in the Western Chagai District, West Pakistan

A northerly-trending group of quartz diorite stocks that cut Cretaceous, Eocene, 01igocene(?) and Pleistocene( ?) sedimentary rocks near Saindak, West Pakistan , contain oxidized disseminated copper minerals which may occur in commercial concentrations at depth. The stocks are enclosed by an aureole of albite-epidote hornfels about 4 miles wide that locally is cut by veins containing sparse lead and copper minerals. Within the contact aureole the few thin beds of limestone and lenticular limestone reefs have been metasomatically replaced by iron sulfide or iron oxide. The sulfide is largely oxidized near the surface. The areas of metamorphosed rocks to which the veins are mostly restricted can be recognized on panchromatic aerial photographs and from a considerable distance on the ground by their rugged topography, dark color, and by the local abundance of dikes, thus greatly reducing the area requiring field examination during a prospecting program. The red and yellow soils mantling the sulfide-rich rocks are easily recognized from short distances on the ground, but cannot be differentiated from the unmetamorphosed rocks on conventional aerial photographs. Color photography or limited-spectral photo techniques probably can be used to reveal these distinctive soils and thus define the areas of sulfide mineralization.

west Pakistan↗

Questa baseline and pre-mining ground-water quality investigation. 17. Geomorphology of the Red River Valley, Taos County, New Mexico, and influence on ground-water flow in the shallow alluvial aquifer

In April 2001, the U.S. Geological Survey (USGS) and the New Mexico Environment Department (NMED) began a cooperative study to infer the pre-mining ground-water chemistry at the Molycorp molybdenum mine site in the Red River Valley of north-central New Mexico. This report is one in a series of reports that can be used to determine pre-mining ground-water conditions at the mine site. Molycorp’s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The bedrock of the Taos Range surrounding the Red River is composed of Proterozoic rocks of various types, which are intruded and overlain by Oligocene volcanic rocks associated with the Questa caldera. Locally, these rocks were altered by hydrothermal activity. The alteration zones that contain sulfide minerals are particularly important because they constitute the commercial ore bodies of the region and, where exposed to weathering, form sites of rapid erosion referred to as alteration scars. Over the past thousand years, if not over the entire Holocene, erosion rates were spatially variable. Forested hillslopes eroded at about 0.04 millimeter per year, whereas alteration scars eroded at about 2.7 millimeters per year. The erosion rate of the alteration scars is unusually rapid for naturally occurring sites that have not been disturbed by humans. Watersheds containing large alteration scars delivered more sediment to the Red River Valley than the Red River could remove. Consequently, large debris fans, as much as 80 meters thick, developed within the valley. The geomorphology of the Red River Valley has had several large influences on the hydrology of the shallow alluvial aquifer, and those influences were in effect before the onset of mining within the watershed. Several reaches where alluvial ground water emerges to become Red River streamflow were observed by a tracer dilution study conducted in 2001. The aquifer narrows where erosion-resistant bedrock, which tends to form vertical cliffs, restricts the width of the valley bottom. Although the presence of a shallow bedrock sill, overlain by shallow alluvium, is a plausible cause of ground-water emergence, this cause was not demonstrated in the study area. The water-table gradient can locally decrease in the downstream direction because of changes in the hydraulic properties of the alluvium, and this may be a contributing cause of ground-water emergence. However, at one site (near Cabin Springs), ground-water emergence could not be explained by spatial changes in geometric or hydraulic properties of the aquifer. Furthermore, the available evidence demonstrates that ground water flowing through bedrock fractures or colluvium entered the north side of the alluvial aquifer, and is the cause of ground-water emergence. At that location the alluvial aquifer was already flowing full, causing the excess water to emerge into the stream. An indirect consequence of altered rock in the tributary watersheds is the rapid erosion rate of alteration scars combined with the hydraulic properties of sediments shed from those scars. Where alteration scars are large the debris fans at the mouths of the tributary watersheds substantially encroach into the Red River Valley. At such locations debris-fan materials dominate the width and thickness of the alluvium in the valley and reduce the rate of flow of ground water within the Red River alluvial aquifer. Most sites of groundwater emergence are located immediately upstream from or along the margins of debris fans. A substantial fraction of the ground water approaching a debris fan can emerge to become streamflow. This last observation has three implications. First, very little water can flow the entire length of the study area entirely within the alluvial aquifer because the ground water repeatedly contacts debris-fan sediments over that length. Second, it follows that emerging water containing unique elemental constituents must have entered the alluvial aquifer at a relatively short distance upstream. Third, a gravel aquifer downstream from a large debris fan can transmit more ground water than flows into it through the debris fan. This observation explains how the water table can be naturally, and permanently, located well beneath the level of the bed of a perennial stream.

New Mexico↗

The East Slope No. 2 uranium prospect, Piute County, Utah

The secondary uranium minerals autunite, metatorbernite, uranophane(?), and schroeckingerite occur in altered hornfels at the East Slope No. 9. uranium prospect. The deposit, in sec. 6, T. 9.7 S., R. 3 W., Piute County, Utah, is about 1 mile west of the Bullion Monarch mine which is in the central producing area of the Marysvale uranium district. Hornfels, formed by contact metamorphism of rocks of the Bullion Canyon volcanics borderhug the margin of a quartz monzonite stock, is in fault contact with the later Mount Belknap rhyolite. The hornfels was intensely altered by hydrothermal solutions in pre-Mount Belknap time. Hematite-alunite-quartz-kaolinite rock, the most completely altered hornfels, is surrounded by orange to white argillized hornfels containing beidellite-montmorillonite clay, and secondary uranium minerals. The secondary uranium minerals probably have been derived from pitchblende, the primary ore mineral in other deposits of the Marysvale area. The two uranium-rich zones, 4 feet ad 5 feet thick, have been traced on the surface for 60 feet and 110 feet, respectively. Channel samples from these zones contained as much as 0.047 percent uranium. The deposit is significant because of its position outside the central producing area and because of the association of uranium minerals with alunitic rock in hydrothermally altered hornfels of volcanic rocks of early Tertiary age.

Circular↗

Hydrous carbonates on Mars?: Evidence from Mariner 6/7 infrared spectrometer and ground‐based telescopic spectra

Absorption features at 2.28 and 5.4 μm identified in Mariner 6/7 infrared spectrometer and terrestrial telescopic spectra are consistent with the spectra of hydrous magnesium carbonates such as hydromagnesite and artinite. Spectral characteristics of these hydrous carbonates are different from those of the anhydrous carbonates, as the former do not have the strong spectral features typically associated with anhydrous carbonates such as calcite and siderite. Theoretical mixing indicates that, depending on the type of hydrous carbonate, 10–20 wt % can be incorporated into the regolith without contradicting the spectral observations or the Viking x ray fluorescence chemical analysis. Hydrous carbonates form as weathering products of mafic minerals in the presence of H 2 O and CO 2 , even in the Antarctic. Their formation as evaporite minerals from either original magmas or hydrothermally altered rocks is consistent with the Martian environment, provided liquid water is or has been at least transiently present. On Earth, formation of hydrous Mg carbonates is associated with the production of amorphous iron oxides, which is consistent with both the environment and the inferred surface mineralogy of Mars. These minerals are about 60 wt % H 2 O, CO 3 , and OH; if they are abundant everywhere at the 10% level, then about 6% of the surface weight could be volatiles bound in this type of mineral. Although the stability of hydrous carbonates in a Martian environment is uncertain, there may be kinetic factors inhibiting the dehydration of these minerals, which may persist metastably in the current environment. Although the spectroscopic evidence for anhydrous carbonates is scant, the possible presence of hydrous carbonates provides an appealing mechanism for the existence of carbonates on Mars.

Journal of Geophysical Research↗