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Rift flank uplifts and Hinterland Basins: Comparison of the Transantarctic Mountains with the Great Escarpment of southern Africa

Uplifted rift margins are a common feature of continents and oceans. Two variants of rift flank morphologies have been recognized: One in which the topography warps down from an inland high toward the continental margin, and one where the tropographic peak lies close to the continental margin. The Great Escarpment of southern Africa and the Transantarctic Mountains are examples of the first and the second variants of rift flanks, respectively. Both rift flanks are bordered on their landward side by broad continental basins: the Kalahari and the Wilkes hinterland basins. If these basins are interpreted as flexural “outer lows” that deepen in unison with the uplift of the rift flanks, the lithosphere on the uplifted side is very rigid in both cases (elastic thickness T e of 100 ± 20 km for southern Africa and 110 ± 20 km for East Antarctica). We suggest that the variation in rift flank morphology is caused by the isostatic response to uplift forces of elastic plates sharing different boundary conditions. We model the uplift of the Transantarctic Mountains as an upward deflection of an elastic plate which is broken at the front of the Transantarctic Mountains, and we model the uplift of the Great Escarpment as an upward deflection of a continuous elastic plate that is modified by the downward load of sediments on the continental margin. Although the Transantarctic Mountain uplift is young (60–0 Ma) and the southern African uplift is old (<100 Ma), the different isostatic responses of the two margins are not a function of age, because most loading (sedimentation) and unloading (erosion) took place shortly after rifting. Detailed modeling of topography, gravity, geological markers, and the locations of depocenters suggests that lithospheric rigidity decreases under the Transantarctic Mountains, whereas in southern Africa the decrease occurs not under the Great Escarpment but far seaward under the continental shelf and slope. If the distribution of lithospheric rigidity is indicative of the thermal regime of the lithosphere, then uplifted rift flanks are not always underlain by a thermal anomaly. This and other geological evidence indicate that a single mechanism cannot explain the uplift of both the Antarctic and the African margins.

Journal of Geophysical Research B: Solid Earth↗

Structured heterogeneity in a marine terrace chronosequence: Upland mottling

Soil mottles generally are interpreted as a product of reducing conditions during periods of water saturation. The upland soils of the Santa Cruz, CA, marine terrace chronosequence display an evolving sequence of reticulate mottling from the youngest soil (65 ka) without mottles to the oldest soil (225 ka) with well-developed mottles. The mottles consist of an interconnected network of clay and C-enriched regions (gray, 2.5Y 6/1) bordered by leached parent material (white, 2.5Y 8/1) within a diminishing matrix of oxidized parent material (orange, 7.5YR 5/8). The mottles develop in soils that formed from relatively uniform nearshore sediments and occur below the depth of soil bioturbation. To explore how a presumably wetland feature occurs in an unsaturated upland soil, physical and chemical characteristics of mottle separates (orange, gray, and white) were compared through the deep time represented by the soil chronosequence. Mineralogical, isotopic, and surface-area differences among mottle separates indicate that rhizogenic centimeter-scale mass transfer acting across millennia is an integral part of weathering, pedogenesis, and C and nutrient transfer. Elemental analysis, electron microscopy, and Fe-isotope systematics indicate that mottle development is driven by deep roots together with their fungal and microbial symbionts. Taken together, these data suggest that deep soil horizons on old stable landforms can develop reticulate mottling as the long-term imprint of rhizospheric processes. The processes of rhizogenic mottle formation appear to regulate pedogenesis, nutrients, and C sequestration at depth in unsaturated zones.

California↗

Crested wheatgrass-cheatgrass seedling competition in a mixed-density design

Plant competition experiments have historically used designs that are difficult to interpret due to confounding problems. Recently, designs based on a 'response function' approach have been proposed and tested in various plant mixture settings. For this study, 3 species were used that are important in current revegetation practices in the Intermountain West. 'Nordan' ( Agropyron desertorum [Fish. ex Link] Shult.) and 'Hycrest' ( A. cristatum [L.] Gaertn. x desertorum ) crested wheatgrass are commonly-used revegetation species on rangelands susceptible to cheatgrass ( Bromus tectorum L.) invasion, although little quantitative data exist that compare their competitive abilities. We evaluated the competitive ability of Hycrest and Nordan seedlings in 2-species mixtures with cheatgrass in a greenhouse study. Linear and nonlinear models were developed for a range of densities (130- 520 seeds m -2 ) for each species to predict median above-ground biomass and tiller numbers and to further test the usefulness of this design for evaluating species to rehabilitate rangelands. In both experiments, increasing Hycrest and Nordan densities reduced their own biomass and tiller production while increasing Hycrest densities reduced cheatgrass biomass and tiller production. Nordan did not affect cheatgrass biomass and tiller production. However, increasing cheatgrass densities reduced Hycrest and Nordan biomass and tiller production, and its own biomass and tiller production. The competition index i.e. substitution rate, indicated that Hycrest seedlings were better competitors with cheatgrass than Nordan, although in all mixtures, cheatgrass plants were the superior competitors. Further field research using this design, where environmental inputs are less optimal and diverse, is needed to validate these results and to further evaluate the use of this approach in examining effects of intra- and interspecific competition.

Journal of Range Management↗

Changing patterns of Pennsylvanian coal-swamp vegetation and implications of climatic control on coal occurrence

Improved regional and interregional stratigraphic correlations of Pennsylvanian strata permit comparisons of vegetational changes in Euramerican coal swamps. The coal-swamp vegetation is known directly from in situ coal-ball peat deposits from more than 65 coals in the United States and Europe. Interpretations of coal-swamp floras on the basis of coal-ball peat studies are extended to broader regional and stratigraphic patterns by use of coal palynology. Objectives of the quantitative analyses of the vegetation in relation to coal are to determine the botanical constituents at the peat stage and their environmental implications for plant growth and peat accumulation. Morphological and paleoecological analyses provide a basis for deducing freshwater regimes of coal swamps. Changes in composition of Pennsylvanian coal-swamp vegetation are quire similar from one paralic coal region to another and show synchrony that is attributable to climate. Paleobotany and paleogeography of the Euramerican province indicate a moist tropical paleoclimate. Rainfall, runoff and evapotranspiration were the variable climatic controls in the distribution of coal-swamp vegetation, peat accumulation and coal resources. In relative terms of climatic wetness the Pennsylvanian Period is divisible into five intervals, which include two relatively drier intervals that developed during the Lower-Middle and Middle-Upper Pennsylvanian transitions. The climate during Early Pennsylvanian time was moderately wet and the median in moisture availability. Early Middle Pennsylvanian was drier, probably seasonally dry-wet; late Middle Pennsylvanian was the wettest in the Midcontinent; early Late Pennsylvanian was the driest; and late Late Pennsylvanian was probably the wettest in the Dunkard Basin. The five climatic intervals represent a general means of dividing coal resources within each region into groups with similar botanical constituents and environments of peat accumulation. Regional differences in basinal geology and climate were significant variables, but the synchronous control of paleoclimate was of primary importance.

International Journal of Coal Geology↗

Seismic reflection images of the crust of the northern part of the Chugach terrane, Alaska: Results of a survey for the Trans-Alaska Crustal Transect (TACT)

Deep crustal seismic reflection data show strong reflections from the middle and lower crust of the convergent continental margin near the eastern end of the Aleutian trench. These data were collected across the Border Ranges fault system, a major suture zone that separates the Peninsular and Chugach tectonostratigraphic terranes. The Chugach terrane consists of metamorphosed, strongly deformed flysch, subduction melange as well as blueschist- and greenschist-facies rocks. Even so, highly reflective rocks lie at great depth within or beneath this terrane. The shallow part of the seismic section (0–5 s) reveals only a few reflections, which undulate and interweave, indicating that some of them originate outside of the plane of the seismic section. Other undulating events could reveal early Cenozoic granitic plutons or antiformal stacks of rock imbricated along thrust faults. In contrast to this shallow reflection pattern, three reflection bands contain most of the events on the middle part of the seismic section (5–12 s or 12–34 km). We interpret divergent reflections within the uppermost band (5–5.5 s) as gently north dipping thrust faults, and subparallel reflections truncated at the boundaries of the upper and middle bands may image a metamorphic foliation or thrust faults. If the truncated reflections represent thrust faults, then the reflection geometry suggests that subparallel roof and floor thrust faults bound imbricated rocks, forming duplex structures. The upper and middle bands are separated by an area on the seismic section that reveals few reflections. This area correlates approximately in depth with a high velocity (7.5 km/s) layer evident in refraction models. The poorly reflective, high velocity unit might be volcanic rocks like those exposed in the structurally lowest part of the Chugach terrane. If so, then the bottom of the poorly reflective rocks indicates the base of the Chugach terrane. Rocks that cause the upper and middle reflection bands and the intervening, poorly reflective volcanic rocks may form a midcrustal shear zone that is about 10 km thick. The deepest band of subparallel reflections (30–35 km) correlates closely in depth with the top of the Wadati-Benioff zone associated with the underthrusting Pacific plate. The reflections probably stem from the decollement that separates lithospheric plates within the subduction zone. This reflection band increases abruptly in thickness, possibly indicating local underplating of subducted sediment. No events from the oceanic Moho have been recognized. Neither the Border Ranges fault system, the suture between the Chugach and Peninsular terranes, nor deep crustal layers of the Peninsular terrane are evident in these seismic reflection data.

Journal of Geophysical Research Solid Earth↗

Granular avalanches across irregular three-dimensional terrain: 1. Theory and computation

To establish a theoretical basis for predicting and interpreting the behavior of rapid mass movements on Earth's surface, we develop and test a new computational model for gravity-driven motion of granular avalanches across irregular, three-dimensional (3-D) terrain. The principles embodied in the model are simple and few: continuum mass and momentum conservation and intergranular stress generation governed by Coulomb friction. However, significant challenges result from the necessity of satisfying these principles when deforming avalanches interact with steep and highly variable 3-D terrain. We address these challenges in four ways. (1) We formulate depth-averaged governing equations that are referenced to a rectangular Cartesian coordinate system (with z vertical) and that account explicitly for the effect of nonzero vertical accelerations on depth-averaged mass and momentum fluxes and stress states. (2) We compute fluxes of mass and momentum across vertical cell boundaries using a high-resolution finite volume method and Roe-type Riemann solver. Our algorithm incorporates flux difference splitting, an entropy correction for the flux, and eigenvector decomposition to embed the effects of driving and resisting forces in Riemann solutions. (3) We use a finite element method and avalanche displacements predicted by Riemann solutions to compute Coulomb stresses conjugate to the displacements in 3-D stress space. (4) We test the model output against analytical solutions, a sand cone conceptual experiment, and (in a companion paper) data from detailed laboratory experiments. Model results illustrate a complex interplay of basal traction and internal stress, and they successfully predict not only the gross behavior but also many details of avalanche motion from initiation to deposition.

Journal of Geophysical Research Earth Surface↗

Evaluation of blood and muscle tissues for molecular detection and characterization of hematozoa infections in northern pintails ( Anas acuta ) wintering in California

Information on the molecular detection of hematozoa from different tissue types and multiple years would be useful to inform sample collection efforts and interpret results of meta-analyses or investigations spanning multiple seasons. In this study, we tested blood and muscle tissue collected from northern pintails ( Anas acuta ) during autumn and winter of different years to evaluate prevalence and genetic diversity of Leucocytozoon , Haemoproteus , and Plasmodium infections in this abundant waterfowl species of the Central Valley of California. We first compared results for paired blood and wing muscle samples to assess the utility of different tissue types for molecular investigations of haemosporidian parasites. Second, we explored inter-annual variability of hematozoa infection in Central Valley northern pintails and investigated possible effects of age, sex, and sub-region of sample collection on estimated parasite detection probability and prevalence. We found limited evidence for differences between tissue types in detection probability and prevalence of Leucocytozoon , Haemoproteus , and Plasmodium parasites, which supports the utility of both sample types for obtaining information on hematozoan infections. However, we detected 11 haemosporidian mtDNA cyt b haplotypes in blood samples vs. six in wing muscle tissue collected during the same sample year suggesting an advantage to using blood samples for investigations of genetic diversity. Estimated prevalence of Leucocytozoon parasites was greater during 2006&ndash;2007 as compared to 2011&ndash;2012 and four unique haemosporidian mtDNA cyt b haplotypes were detected in the former sample year but not in the latter. Seven of 15 mtDNA cyt b haplotypes detected in northern pintails had 100% identity with previously reported hematozoa lineages detected in waterfowl ( Haemoproteus and Leucocytozoon ) or other avian taxa ( Plasmodium ) providing support for lack of host specificity for some parasite lineages.

California↗

Results of the collaborative Lake Ontario bloater restoration stocking and assessment, 2012–2020

Bloater, Coregonus hoyi , are deepwater planktivores native to the Laurentian Great Lakes and Lake Nipigon. Interpretations of commercial fishery time series suggest they were common in Lake Ontario through the early 1900s but by the 1950s were no longer captured by commercial fishers. Annual bottom trawl surveys that began in 1978 and sampled extensively across putative bloater habitat only yielded one individual (1983), suggesting that the species had been locally extirpated. In 2012, a multiagency restoration program stocked bloater into Lake Ontario from gametes collected in Lake Michigan. From 2012 to 2020, 1,028,191 bloater were stocked into Lake Ontario. Bottom trawl surveys first detected stocked fish in 2015, and through 2020 ten bloater have been caught (total length mean = 129 mm, s.d. = 44 mm, range: 96–240 mm). Hatchery applied marks and genetic analyses confirmed the species identification and identified stocking location for some individuals. Trawl capture locations and acoustic telemetry suggested that stocked fish dispersed throughout the main lake within months or sooner, and the depth distribution of recaptured bloater was similar to historic distributions in Lake Ontario and other Great Lakes. Predicted bloater trawl catches, based on modeled population abundance and trawl survey efficiency, were similar to observed catches, suggesting that post-stocking survival is less than 20% and contemporary bottom trawl surveys can quantify bloater abundance at low densities and track restoration.

Lake Ontario↗

Relating Tmax and hydrogen index to vitrinite and solid bitumen reflectance in hydrous pyrolysis residues: Comparisons to natural thermal indices

Vitrinite reflectance (VR o ; %) generally is considered the most reliable technique to determine the thermal maturity of sedimentary rocks. However, it is a time-consuming process to collect reflectance (R o ; %) measurements and is subjective to the interpretation of each trained technician, who must be able to discern between vitrinite and solid bitumen and other organic matter types. Inadvertent misidentification of solid bitumen for vitrinite can lead to reports of ‘suppressed’ VR o , especially at lower thermal maturities (< 1.0% R o ). Programmed pyrolysis data, such as T max and hydrogen index (HI), are comparatively inexpensive and more time-efficient to obtain than R o data and are determined by instrument settings, rather than by operator decision, and are therefore independent of operator-based training or experience bias. This study uses hydrous pyrolysis (HP) residues from various coals and shales to relate measured VR o and solid bitumen reflectance (BR o ; %) values to their respective T max and HI values and determines whether these relationships can be used as a proxy to calculate R o in naturally matured samples. Although the estimation of R o is not always accurate, the results demonstrate that relational equations for shales and coals derived from the T max and HI data of HP residues can effectively calculate R o in natural series. Approximately 60% of calculated R o from T max and 83% of calculated R o from HI relational equations are within interlaboratory reproducibility limits (± 0.2% shale BR o ; ± 0.06% coal VR o ) when compared to their respective measured R o values from natural series. Variables that may affect accuracy of the applied relational equations include variable sedimentary organic matter composition of samples, differences of maturation reaction kinetics of the sedimentary organic matter in experimental versus natural settings, and decreasing reliability of all thermal proxy measurements at higher maturities.

International Journal of Coal Geology↗

Comparison of three qualitative habitat indices and their applicability to prairie streams

Qualitative stream habitat indices are important tools in classifying, interpreting, and assessing the conditions of stream ecosystems. Habitat indices are numerical values produced from scoring various features of a stream. Three commonly used habitat indices are the qualitative habitat evaluation index (QHEI), the rapid bioassessment protocols (RBP), and the riparian, channel, and environmental inventory (RCE). All three indices were used to assess the habitat conditions of 18 prairie streams of different sizes and environmental settings in the Red River of the North basin. Correlations suggest that these three indices provide similar results (r ranged from 0.83 to 0.85, P ≤ 0.003); however, the indices emphasize different aspects of the stream environment. Metrics from each index were classified as one of the following: channel geomorphology, riparian zone, substrate related, and instream cover and biota. The QHEI and RBP indices emphasize channel geomorphology metrics (41% of total score for the QHEI and 42% of the total score for the RBP). The RCE had a more balanced emphasis among the four classes but emphasized riparianzone metrics (32% of total score). There is redundancy within indices. Several metrics showed high correlations (e.g., r = 0.74 for land use and riparian-zone width in QHEI; r = 0.86 for bank vegetative protection and bank condition in RBP; r = 0.83 for macrobenthos and fish in RCE). To evaluate biological applicability, index scores were correlated to scores of the index of biotic integrity and fish community statistics of species richness, evenness, diversity, and percent of individuals in four trophic groups. No significant correlations were identified. We concluded that the metrics making up the habitat indices were either not applicable or not weighted appropriately for northern prairie streams.

North American Journal of Fisheries Management↗

Fluvial-aeolian interactions in sediment routing and sedimentary signal buffering: an example from the Indus Basin and Thar Desert

Sediment production and its subsequent preservation in the marine stratigraphic record offshore of large rivers are linked by complex sediment-transfer systems. To interpret the stratigraphic record it is critical to understand how environmental signals transfer from sedimentary source regions to depositional sinks, and in particular to understand the role of buffering in obscuring climatic or tectonic signals. In dryland regions, signal buffering can include sediment cycling through linked fluvial and eolian systems. We investigate sediment-routing connectivity between the Indus River and the Thar Desert, where fluvial and eolian systems exchanged sediment over large spatial scales (hundreds of kilometers). Summer monsoon winds recycle sediment from the lower Indus River and delta northeastward, i.e., downwind and upstream, into the desert. Far-field eolian recycling of Indus sediment is important enough to control sediment provenance at the downwind end of the desert substantially, although the proportion of Indus sediment of various ages varies regionally within the desert; dune sands in the northwestern Thar Desert resemble the Late Holocene&ndash;Recent Indus delta, requiring short transport and reworking times. On smaller spatial scales (1&ndash;10 m) along fluvial channels in the northern Thar Desert, there is also stratigraphic evidence of fluvial and eolian sediment reworking from local rivers. In terms of sediment volume, we estimate that the Thar Desert could be a more substantial sedimentary store than all other known buffer regions in the Indus basin combined. Thus, since the mid-Holocene, when the desert expanded as the summer monsoon rainfall decreased, fluvial-eolian recycling has been an important but little recognized process buffering sediment flux to the ocean. Similar fluvial-eolian connectivity likely also affects sediment routing and signal transfer in other dryland regions globally.

Indus Basin, Thar Desert↗

Spirit Mars Rover Mission to the Columbia Hills, Gusev Crater: Mission overview and selected results from the Cumberland Ridge to Home Plate

This paper summarizes the Spirit rover operations in the Columbia Hills of Gusev Crater from sols 513 to 1476 and provides an overview of selected findings that focus on synergistic use of the Athena Payload and comparisons to orbital data. Results include discovery of outcrops (Voltaire) on Husband Hill that are interpreted to be altered impact melt deposits that incorporated local materials during emplacement. Evidence for extensive volcanic activity and aqueous alteration in the Inner Basin is also detailed, including discovery and characterization of accretionary lapilli and formation of sulfate, silica, and hematite‐rich deposits. Use of Spirit's data to understand the range of spectral signatures observed over the Columbia Hills by the Mars Reconnaissance Orbiter's Compact Reconnaissance Imaging Spectrometer (CRISM) hyperspectral imager (0.4–4 μ m) is summarized. We show that CRISM spectra are controlled by the proportion of ferric‐rich dust to ferrous‐bearing igneous minerals exposed in ripples and other wind‐blown deposits. The evidence for aqueous alteration derived from Spirit's data is associated with outcrops that are too small to be detected from orbital observations or with materials exposed from the shallow subsurface during rover activities. Although orbital observations show many other locations on Mars with evidence for minerals formed or altered in an aqueous environment, Spirit's data imply that the older crust of Mars has been altered even more extensively than evident from orbital data. This result greatly increases the potential that the surface or shallow subsurface was once a habitable regime.

Journal of Geophysical Research E: Planets↗

Holocene reef accretion: southwest Molokai, Hawaii, U.S.A.

Two reef systems off south Molokai, Hale O Lono and Hikauhi (separated by only 10 km), show strong and fundamental differences in modern ecosystem structure and Holocene accretion history that reflect the influence of wave-induced near-bed shear stresses on reef development in Hawaii. Both sites are exposed to similar impacts from south, Kona, and trade-wind swell. However, the Hale O Lono site is exposed to north swell and the Hikuahi site is not. As a result, the reef at Hale O Lono records no late Holocene net accretion while the reef at Hikauhi records consistent and robust accretion over late Holocene time. Analysis and dating of 24 cores from Hale O Lono and Hikauhi reveal the presence of five major lithofacies that reflect paleo-environmental conditions. In order of decreasing depositional energy they are: (1) coral-algal bindstone; (2) mixed skeletal rudstone; (3) massive coral framestone; (4) unconsolidated floatstone; and (5) branching coral framestone-bafflestone. At Hale O Lono, 10 cores document a backstepping reef ranging from ∼ 8,100 cal yr BP (offshore) to ∼ 4,800 cal yr BP (nearshore). A depauperate community of modern coral diminishes shoreward and seaward of ∼ 15 m depth due to wave energy, disrupted recruitment activities, and physical abrasion. Evidence suggests a change from conditions conducive to accretion during the early Holocene to conditions detrimental to accretion in the late Holocene. Reef structure at Hikauhi, reconstructed from 14 cores, reveals a thick, rapidly accreting and young reef (maximum age ∼ 900 cal yr BP). Living coral cover on this reef increases seaward with distance from the reef crest but terminates at a depth of ∼ 20 m where the reef ends in a large sand field. The primary limitation on vertical reef growth is accommodation space under wave base, not recruitment activities or energy conditions. Interpretations of cored lithofacies suggest that modern reef growth on the southwest corner of Molokai, and by extension across Hawaii in general, is controlled by wave-induced near-bed shear stress related to refracted North Pacific swell. Holocene accretion patterns here also reflect the long-term influence of wave-induced near-bed shear stress from north swell during late Holocene time. This finding is consistent with other studies (e.g., Grigg 1998; Cabioch et al. 1999) that reflect the dominance of swell energy and sea level in controlling modern and late Holocene accretion elsewhere in Hawaii and across the Pacific and Indian oceans. Notably, however, this result is refined and clarified for Hawaii in the hypothesis of Rooney et al. (2003) stating that enhancement of the El Niño Southern Oscillation beginning approximately 5000 years ago led to increased north swell energy and signaled the end to net accretion along exposed coastlines in Hawaii. The exposure of Hale O Lono to north swell and the age of sea floor there (ca. 4,800 cal yr BP), coupled with the lack of north swell incidence at Hikauhi and the continuous accretion that has occurred there over the last millennium, strongly supports the ENSO reef hypothesis as outlined by Rooney et al. (2003). Other factors controlling Holocene reef accretion at the study site are relative sea-level position and rate of rise, and wave sheltering by Laau Point. Habitat suitable for reef accretion on the southwest shore of Molokai has shrunk throughout the Holocene.

Hawai'i↗

Post-wildfire hydrologic recovery in Mediterranean climates: A systematic review and case study to identify current knowledge and opportunities

Post-fire hydrologic research typically focuses on the first few years after a wildfire , leading to substantial uncertainty regarding the longevity of impacts. The time needed for hydrologic function to return to pre-fire conditions is critical information for post-fire land and water management decisions. This is particularly true in Mediterranean climates , where water is scarce and in high demand, and the severity and area burned by wildfires are increasing. In part, uncertainty about hydrologic recovery is due to lack of a consistent definition or interpretation of what constitutes “recovery.” Here, we systematically reviewed empirical studies from Mediterranean climates with at least three years of post-fire hydrologic data with the objectives of (a) assessing the recovery period, (b) identifying a definition of post-fire hydrologic recovery, (c) demonstrating a simple analytical approach to aid in assessment of recovery, and (d) outlining research needs and opportunities to better quantify post-fire recovery. We assessed the hydrologic effects reported in 38 sites that were monitored for 3–20 years. Eighteen sites were considered recovered within seven years; however, the recovery time was inconsistent across sites and was not related to location, response variable, or study design. The likelihood of recovery within the study period also decreased with increasing proportion of the watershed area burned. Importantly, we have also proposed a standardized definition and an approach to quantifying hydrologic recovery that may facilitate cross-study comparisons and a deeper understanding of recovery. Specifically, we propose hydrologic recovery has occurred when a specific post-fire hydrologic function or condition of interest returns to the 95% confidence interval of the pre-fire condition. In support of this definition, we have demonstrated applying this simple approach to assess recovery and presented future research topics to improve our understanding of long-term post-fire catchment responses. In addition to the need for more studies that quantify hydrologic responses farther into the post-fire period, understanding post-fire changes in soil structural and hydraulic properties through time will improve our mechanistic understanding of post-fire hydrologic responses and recovery.

Journal of Hydrology↗

Keanakākoʻi Tephra produced by 300 years of explosive eruptions following collapse of Kīlauea's caldera in about 1500 CE

The Keanakākoʻi Tephra at Kīlauea Volcano has previously been interpreted by some as the product of a caldera-forming eruption in 1790 CE. Our study, however, finds stratigraphic and 14 C evidence that the tephra instead results from numerous eruptions throughout a 300-year period between about 1500 and 1800. The stratigraphic evidence includes: (1) as many as six pure lithic ash beds interleaved in sand dunes made of earlier Keanakākoʻi vitric ash, (2) three lava flows from Kīlauea and Mauna Loa interbedded with the tephra, (3) buried syneruptive cultural structures, (4) numerous intraformational water-cut gullies, and (5) abundant organic layers rich in charcoal within the tephra section. Interpretation of 97 new accelerator mass spectrometry (AMS) 14 C ages and 4 previous conventional ages suggests that explosive eruptions began in 1470–1510 CE, and that explosive activity continued episodically until the early 1800s, probably with two periods of quiescence lasting several decades. Kīlauea's caldera, rather than forming in 1790, predates the first eruption of the Keanakākoʻi and collapsed in 1470–1510, immediately following, and perhaps causing, the end of the 60-year-long, 4–6 km 3 ʻAilāʻau eruption from the east side of Kīlauea's summit area. The caldera was several hundred meters deep when the Keanakākoʻi began erupting, consistent with oral tradition, and probably had a volume of 4–6 km3. The caldera formed by collapse, but no eruption of lava coincided with its formation. A large volume of magma may have quickly drained from the summit reservoir and intruded into the east rift zone, perhaps in response to a major south-flank slip event, leading to summit collapse. Alternatively, magma may have slowly drained from the reservoir during the prolonged ʻAilāʻau eruption, causing episodic collapses before the final, largest downdrop took place. Two prolonged periods of episodic explosive eruptions are known at Kīlauea, the Keanakākoʻi and the Uwēkahuna Tephra (Fiske et al., 2009), and both occurred when a deep caldera existed, probably with a floor at or below the water table, and external water could readily interact with the magmatic system. The next period of intense explosive activity will probably have to await the drastic deepening of the present caldera (or Halemaʻumaʻu Crater) or the formation of a new caldera.

Hawai'i↗

Hydrogeology of the Hawaii Scientific Drilling Project borehole KP-1 2. Groundwater geochemistry and regional flow patterns

A series of downhole and surface water samples were taken from the 1‐km‐deep KP‐1 borehole located on the eastern flank of the island of Hawaii. Early samples from depths of more than 700 m showed salinities nearly equivalent to seawater but having anomalous cation concentrations that are attributed to ion exchange between formation fluids and residual drilling mud clays. Later deep samples found only minor variations from seawater cation chemistry that are consistent with low‐temperature weathering of basalts; δ 18 O values are equivalent to seawater values and are consistent with this interpretation. Carbon 14 activities of dissolved inorganic carbonate indicate a water age ranging from 5890 to 7170 years B.P. and fluid transport rates of 1.8 to 2.2 m/yr. Fluid samples from perforations at 310 m in the borehole demonstrate that a freshwater aquifer is present at the Mauna Kea/Mauna Loa interface; borehole resistivity logs indicate that it is ∼200 m thick. Although it has not yet been possible to obtain samples of the freshwater zone without contamination from the deep saline fluids, the chloride concentrations of the low‐salinity zone are estimated using a mixing enthalpy calculation to be less than 100 mg/L. Light stable isotope data indicate that the fresh water at 320 m is derived from recharge entering the island at an average elevation of 2000 m. Inferred 14 C activities of the dissolved bicarbonate in the freshwater zone indicate an average calibrated age of 2200 years B.P. and an average fluid velocity of at least 14 m/yr. A regional water flow model is proposed that suggests that the fresh water found at the 320‐m depth is derived from rainfall recharge from the middle elevations of Mauna Kea volcano. This rainfall is channeled beneath the Mauna Loa lavas by the thick soil layer separating the two volcanoes. A second shallow fresh‐to‐brackish water zone, derived from Mauna Loa recharge, is also inferred to exist below the carbonate formation that underlies the shallow basal lens. The results of our preliminary study of the groundwater system below the KP‐1 drill site demonstrate that intervolcano and interflow aquicludes can have a substantial impact on water circulation and discharge from young island volcanoes.

Journal of Geophysical Research B: Solid Earth↗

Petrographic maturity parameters of a Devonian shale maturation series, Appalachian Basin, USA. ICCP Thermal Indices Working Group interlaboratory exercise

This paper presents results of an interlaboratory exercise on organic matter optical maturity parameters using a natural maturation series comprised by three Devonian shale samples (Huron Member, Ohio Shale) from the Appalachian Basin, USA. This work was conducted by the Thermal Indices Working Group of the International Committee for Coal and Organic Petrology (ICCP) Commission II (Geological Applications of Organic Petrology). This study aimed to compare: 1. maturation predicted by different types of petrographic parameters (vitrinite reflectance and spectral fluorescence of telalginite), 2. reproducibility of the results for these maturation parameters obtained by different laboratories, and 3. improvements in the spectral fluorescence measurement obtained using modern detection systems in comparison with the results from historical round robin exercises. Mean random vitrinite reflectance measurements presented the highest level of reproducibility (group standard deviation 0.05) for low maturity and reproducibility diminished with increasing maturation (group standard deviation 0.12). Corrected fluorescence spectra, provided by 14 participants, showed a fair to good correspondence. Standard deviation of the mean values for spectral parameters was lowest for the low maturity sample but was also fairly low for higher maturity samples. A significant improvement in the reproducibility of corrected spectral fluorescence curves was obtained in the current exercise compared to a previous investigation of Toarcian organic matter spectra in a maturation series from the Paris Basin. This improvement is demonstrated by lower values of standard deviation and is interpreted to reflect better performance of newer photo-optical measuring systems. Fluorescence parameters measured here are in good agreement with vitrinite reflectance values for the least mature shale but indicate higher maturity than shown by vitrinite reflectance for the two more mature shales. This red shift in λ max beyond 0.65% vitrinite reflectance was also observed in studies of Devonian shale in other basins, suggesting that the accepted correlation for these two petrographic thermal maturity parameters needs to be re-evaluated. A good linear correlation between λ max and T max for this maturation series was observed and λ max 600 nm corresponds to T max of 440 °C. Nevertheless if a larger set of Devonian samples is included, the correlation is polynomial with a jump in λ max ranging from 540 to 570 nm. Up to 440 °C of T max , the λ max , mostly, reaches up to 500 nm; beyond a T max of 440 °C, λ max is in the range of 580–600 nm. This relationship places the “red shift” when the onset of the oil window is reached at T max of 440 °C. Moreover, the correlation between HI and λ max (r 2 = 0.70) shows a striking inflection and decrease in HI above a λ max of 600 nm, coincident with the approximate onset of hydrocarbon generation in these rocks.

International Journal of Coal Geology↗

Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe 2 O 3 ) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm −1 and by the absence of silicate fundamentals in the 1000 cm −1 region. Spectral features resulting from atmospheric CO 2 , dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles <5–10 μm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ∼10% (>30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5–10 μm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

Journal of Geophysical Research E: Planets↗