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Chemistry of ground water in the Silver Springs basin, Florida, with an emphasis on nitrate

The Silver Springs group, in central Marion County, Florida, has a combined average discharge rate of 796 cubic feet per second and forms the headwaters of the Silver River. The springs support a diverse ecosystem and are an important cultural and economic resource. Concentrations of nitrite-plus-nitrate (nitrate-N) in water from the Main Spring increased from less than 0.5 milligrams per liter (mg/L) in the 1960s to about 1.0 mg/L in 2003. The Upper Floridan aquifer supplies the ground water to support spring discharge. This aquifer is at or near land surface in much of the ground-water basin; nutrients leached at land surface can easily percolate downward into the aquifer. Sources of nitrogen in ground water in the Silver Springs basin include atmospheric deposition, fertilizers used by agricultural and urban activities, and human and animal wastes. During 2000-2001, 56 wells in the area contributing recharge to Silver Springs were sampled for major ions, nutrients, and some trace constituents. Selected wells also were sampled for a suite of organic constituents commonly found in domestic and industrial wastewater and for the ratio of nitrogen isotopes (15N/14N) to better understand the sources of nitrate. Wells were selected to be representative of both confined and unconfined conditions of the Upper Floridan aquifer, as well as a variety of land-use types. Data from this study were compared to data collected from 25 wells in 1989-90. Concentrations of nitrate-N in ground water during this study ranged from less than the detection limit of 0.02 to 12 mg/L, with a median of 1.2 mg/L. For data from 1989-90, the range was from less than 0.02 to 3.6 mg/L, with a median of 1.04 mg/L. Water from wells in agricultural land-use areas had the highest median nitrate-N concentration (1.7 mg/L), although it is uncertain if the 12 mg/L maximum concentration was influenced by land-use activities or proximity to a septic tank. The median value for all urban land-use areas was 1.15 mg/L. Because fewer wells were in rangeland or forested areas, those categories were grouped together. The median concentration for that group was 0.09 mg/L. The ratio of 15N/14N in ground-water samples ranged from -0.5 to 11.5 per mil. The median value for ground-water samples from 35 wells, 4.9 per mil, is near the top of the range that indicates inorganic nitrogen sources. In agricultural areas, the median 15N/14N was 4.8 per mil, indicating mostly inorganic (fertilizer) sources. In urban areas, the median 15N/14N was 5.4 per mil, indicating more influence of organic nitrogen (N) sources. Thus, in both agricultural and urban areas, fertilizer is an important inorganic source of N in ground water (and, therefore, in spring water as well). The influence of organic N is more apparent in urban areas than in agricultural areas. Two distinct 15N/14N values were observed in water from the Main Spring, one indicating an inorganic nitrogen source and the other indicating a mixture of sources with a strong influence of organic nitrogen. Thirty-five wells and three springs of the Silver Springs group (the Main Spring, the Abyss, and the Blue Grotto) were sampled for a suite of 63 compounds common in wastewater. A total of 38 compounds was detected, nearly all in very low concentrations. The most frequently detected compound was the insecticide N,N-diethyl-meta-toluamide (DEET), which was detected in water from 27 wells and all three springs. The presence or absence of DEET in ground-water samples did not seem to be related to land use; however, hydrogeologic conditions at the well sites (confined or unconfined) generally did affect the presence or absence of DEET in the ground water. DEET also appears to be a useful tracer for the presence of reused water. Water samples were collected from the Main Spring and two other springs of the Silver Springs group and analyzed for concentrations of dissolved gasses and for chlorofluorocarbons (CFCs), sulfur hexaflu

Scientific Investigations Report↗

Ground-water-quality assessment of the central Oklahoma Aquifer, Oklahoma — Geochemical and geohydrologic investigations

Ground-water samples, core samples, and hydrologic measurements were obtained in the Central Oklahoma Aquifer as part of the pilot National Water-Quality Assessment Program. This report examines ground-water recharge and discharge, the potentiometric surface, the chemical and isotopic composition of ground water, and the abundances and textures of minerals in core materials to determine the rates and directions of ground-water flow and the geochemical reactions occurring within the aquifer.

Oklahoma↗

Estimated Ground-Water Withdrawals from the Death Valley Regional Flow System, Nevada and California, 1913-98

Ground-water withdrawals from 1913 through 1998 from the Death Valley regional flow system have been compiled to support a regional, three-dimensional, transient ground-water flow model. Withdrawal locations and depths of production intervals were estimated and associated errors were reported for 9,300 wells. Withdrawals were grouped into three categories: mining, public-supply, and commercial water use; domestic water use; and irrigation water use. In this report, groupings were based on the method used to estimate pumpage. Cumulative ground-water withdrawals from 1913 through 1998 totaled 3 million acre-feet, most of which was used to irrigate alfalfa. Annual withdrawal for irrigation ranged from 80 to almost 100 percent of the total pumpage. About 75,000 acre-feet was withdrawn for irrigation in 1998. Annual irrigation withdrawals generally were estimated as the product of irrigated acreage and application rate. About 320 fields totaling 11,000 acres were identified in six hydrographic areas. Annual application rates for high water-use crops ranged from 5 feet in Penoyer Valley to 9 feet in Pahrump Valley. The uncertainty in the estimates of ground-water withdrawals was attributed primarily to the uncertainty of application rate estimates. Annual ground-water withdrawal was estimated at about 90,000 acre-feet in 1998 with an assigned uncertainty bounded by 60,000 to 130,000 acre-feet.

Water-Resources Investigations Report↗

Research opportunities in interdisciplinary ground-water science in the U.S. Geological Survey

This report is written for the scientifically literate reader but is not limited to those who are involved in ground-water science. The report is intended to encourage U.S. Geological Survey scientists to develop a sense of excitement about ground-water science in the agency, to inform scientists about existing and potential ground-water science opportunities, and to engage scientists and managers in interdisciplinary discussions and collaboration. The report is intended for use by U.S. Geological Survey and Department of the Interior management to formulate long-term ground-water science programs and to continue sustained support of ground-water monitoring and research, some of which may not have an immediate impact. Finally, the report can be used to communicate the U.S. Geological Survey's vision of ground-water science to Congress, partners, other agencies, and the research community at large with the goals of enhancing collaborative opportunities, sharing information, and maintaining dialogue regarding the directions of U.S. Geological Survey ground-water science.

Circular↗

Ground-water levels and quality at Crex Meadows Wildlife Area, Burnett County, Wisconsin

During 1984, above-normal ground-water levels flooded the fields and basements in the vicinity of the Crex Meadows Wildlife Area. In response to concerns of neighboring farmers and homeowners, the Wisconsin Department of Natural Resources and the U.S. Geological Survey began a cooperative study to assess ground-water conditions in the area and to determine the causes of above-normal ground-water levels in and around the Crex Meadows Wildlife Area. Data from an inventory of water levels in the Crex Meadows area measured in 1935 and 1937 were compared with data collected in 1986 and 1987. The comparison indicates that 1986 water levels were 5 to 10 feet higher throughout the area than in 1935 and 1937. Water levels declined about 5 feet throughout much of the area during 1987 and were only 0–5 feet higher than in the late 1930's. Hydrographs of water levels measured from 1985 to the fall of 1987 also indicate that water levels rose in 1985 and 1986 and fell abruptly in 1987. Water levels in two wells, one in northern Burnett County and the other in Polk County, were compared to those in the wildlife area to determine whether the wetland impoundments contributed significantly to above-normal water levels measured in 1986 or whether levels were high throughout northwestern Wisconsin. Water-levels at long-term observation wells Bt-2 (1936–present) and Pk-40 (1951–present) (13 miles northeast and 20 miles southeast of Crex Meadows, respectively) during 1986 were the highest of record. Long-term discharge records for the St. Croix River upstream (Danbury) and downstream (St. Croix Falls) from Crex Meadows indicate that the river reached its highest historical discharge volume during 1986. Hydrographs showing cumulative departure from mean annual precipitation at two stations (Danbury and St. Croix Falls) indicate that the above-normal ground-water levels in 1986 were preceded by several years of above-normal precipitation. It is probable that the above-normal ground-water levels and surface- water discharge throughout the area can be attributed to above-normal precipitation. Groundwater- level fluctuations corresponded directly to variations in precipitation during 1985–87. Chemical analyses of water samples from 20 observation wells indicate that calcium and bicarbonate are the predominant ions in ground water in the Crex Meadows area. Iron concentrations ranged from 45 to 45,000 micrograms per liter, and 17 of 20 samples exceeded the 300-micrograms-per-liter recommended drinking-water standard of the Wisconsin Department of Natural Resources.

Wisconsin↗

Ground-water conditions in Utah, spring of 1997

This is the thirty-fourth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources, provide data to enable interested parties to keep aware of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas for which applicable data are available and are important to a discussion of changing ground-water conditions. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1996. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Rights and Water Resources.

Utah↗

Estimating nitrogen loading to ground water and assessing vulnerability to nitrate contamination in a large karstic springs Basin, Florida

A nitrogen (N) mass-balance budget was developed to assess the sources of N affecting increasing ground-water nitrate concentrations in the 960-km 2 karstic Ichetucknee Springs basin. This budget included direct measurements of N species in rainfall, ground water, and spring waters, along with estimates of N loading from fertilizers, septic tanks, animal wastes, and the land application of treated municipal wastewater and residual solids. Based on a range of N leaching estimates, N loads to ground water ranged from 262,000 to 1.3 million kg/year; and were similar to N export from the basin in spring waters (266,000 kg/year) when 80-90% N losses were assumed. Fertilizers applied to cropland, lawns, and pine stands contributed about 51% of the estimated total annual N load to ground water in the basin. Other sources contributed the following percentages of total N load to ground water: animal wastes, 27%; septic tanks, 12%; atmospheric deposition, 8%; and the land application of treated wastewater and biosolids, 2%. Due to below normal rainfall (97.3 cm) during the 12-month rainfall collection period, N inputs from rainfall likely were about 30% lower than estimates for normal annual rainfall (136 cm). Low N-isotope values for six spring waters (??15N-NO3 = 3.3 to 6.3???) and elevated potassium concentrations in ground water and spring waters were consistent with the large N contribution from fertilizers. Given ground-water residence times on the order of decades for spring waters, possible sinks for excess N inputs to the basin include N storage in the unsaturated zone and parts of the aquifer with relatively sluggish ground-water movement and denitrification. A geographical-based model of spatial loading from fertilizers indicated that areas most vulnerable to nitrate contamination were located in closed depressions containing sinkholes and other dissolution features in the southern half of the basin. ?? 2009 American Water Resources Association.

Journal of the American Water Resources Associatio↗

Monitoring-well network and sampling design for ground-water quality, Wind River Indian Reservation, Wyoming

The Wind River Indian Reservation, located in parts of Fremont and Hot Springs Counties, Wyoming, has a total land area of more than 3,500 square miles. Ground water on the Wind River Indian Reservation is a valuable resource for Shoshone and Northern Arapahoe tribal members and others who live on the Reservation. There are many types of land uses on the Reservation that have the potential to affect the quality of ground-water resources. Urban areas, rural housing developments, agricultural lands, landfills, oil and natural gas fields, mining, and pipeline utility corridors all have the potential to affect ground-water quality. A cooperative study was developed between the U.S. Geological Survey and the Wind River Environmental Quality Commission to identify areas of the Reservation that have the highest potential for ground-water contamination and develop a comprehensive plan to monitor these areas. An arithmetic overlay model for the Wind River Indian Reservation was created using seven geographic information system data layers representing factors with varying potential to affect ground-water quality. The data layers used were: the National Land Cover Dataset, water well density, aquifer sensitivity, oil and natural gas fields and petroleum pipelines, sites with potential contaminant sources, sites that are known to have ground-water contamination, and National Pollutant Discharge Elimination System sites. A prioritization map for monitoring ground-water quality on the Reservation was created using the model. The prioritization map ranks the priority for monitoring ground-water quality in different areas of the Reservation as low, medium, or high. To help minimize bias in selecting sites for a monitoring well network, an automated stratified random site-selection approach was used to select 30 sites for ground-water quality monitoring within the high priority areas. In addition, the study also provided a sampling design for constituents to be monitored, sampling frequency, and a simple water-table level observation well network.

Scientific Investigations Report↗

Ground-water conditions in Utah, spring of 2009

This is the forty-sixth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2008. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights. utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/ GW2009.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2008

This is the forty-fifth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2007. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2008.pdf .

Utah↗

Ground-water conditions in Utah, spring of 2007

This is the forty-fourth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2006. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/ and http://ut.water.usgs.gov/newUTAH/GW2007.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2006

This is the forty-third in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable inter­ested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water with­drawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2005. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/techinfo/wwwpub/gw2006.pdf and http://ut.water.usgs. gov/publications/GW2006.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2005

This is the forty-second in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable inter­ested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water with­drawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2004. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources. This report is available online at http://www.waterrights.utah.gov/techinfo/ wwwpub/gw2005.pdf and http://ut.water.usgs.gov/publications/GW2005.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2004

This is the forty-first in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2003. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2002

This is the thirty-ninth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2001. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2001

This is the thirty-eighth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2000. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2000

This is the thirty-seventh in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1999. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Rights and Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 1999

This is the thirty-sixth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1998. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Rights and Water Resources.

Utah↗