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Sedimentologic characteristics of recent washover deposits from Assateague Island, Maryland

The U.S. Geological Survey has a long history of responding to and documenting the impacts of storms along the Nation’s coasts and incorporating these data into storm impact and coastal change vulnerability assessments. Although physical changes caused by tropical and extratropical storms to the sandy beaches and dunes fronting barrier islands are generally well documented, the interaction between sandy shoreline erosion and overwash with the back-barrier wetland and estuarine environments is poorly constrained. The goal of the Barrier Island and Estuarine Wetland Physical Change Assessment project is to integrate a wetland-change assessment with existing coastal-change assessments for the adjacent sandy dunes and beaches, initially focusing on Assateague Island along the Maryland and Virginia coastline. Assateague Island was impacted by waves and storm surge associated with the passage of Hurricane Sandy in October 2012, causing erosion and overwash along the ocean-facing sandy shoreline as well as erosion and overwash deposition in the back-barrier and estuarine bay environments. This report describes sediment data collected using sand augers in active overwash zones on Assateague Island in Maryland. Samples were collected by the U.S. Geological Survey (USGS) during two surveys in March/April and October 2014 (USGS Field Activity Numbers [FAN] 2014-301-FA and 2014-322-FA, respectively). The physical characteristics (for example, sediment texture or bedding structure) of and spatial differences among these deposits will provide information about overwash processes and sediment transport from the sandy barrier-island reaches to the back-barrier environments. Metrics derived from these data, such as mean grain size or deposit thicknesses, can be used to ground-truth remote sensing and geophysical data and can also be incorporated into sediment transport models. Data products, including sample location tables, descriptive core logs, core photographs and x-radiographs, the results of sediment grain-size analyses, and Geographic Information System (GIS) data files with accompanying formal Federal Geographic Data Committee (FGDC) metadata can be downloaded from the Data Downloads page.

Maryland↗

South Florida wetlands ecosystem; biogeochemical processes in peat

The South Florida wetlands ecosystem is an environment of great size and ecological diversity (figs. 1 and 2). The landscape diversity and subtropical setting of this ecosystem provide a habitat for an abundance of plants and wildlife, some of which are unique to South Florida. South Florida wetlands are currently in crisis, however, due to the combined effects of agriculture, urbanization, and nearly 100 years of water management. Serious problems facing this ecosystem include (1) phosphorus contamination producing nutrient enrichment, which is causing changes in the native vegetation, (2) methylmercury contamination of fish and other wildlife, which poses a potential threat to human health, (3) changes in the natural flow of water in the region, resulting in more frequent drying of wetlands, loss of organic soils, and a reduction in freshwater flow to Florida Bay, (4) hypersalinity, massive algal blooms, and seagrass loss in parts of Florida Bay, and (5) a decrease in wildlife populations, especially those of wading birds. This U.S. Geological Survey (USGS) project focuses on the role of organic-rich sediments (peat) of South Florida wetlands in regulating the concentrations and impact of important chemical species in the environment. The cycling of carbon, nitrogen, phosphorus, and sulfur in peat is an important factor in the regulation of water quality in the South Florida wetlands ecosystem. These elements are central to many of the contamination issues facing South Florida wetlands, such as nutrient enrichment, mercury toxicity, and loss of peat. Many important chemical and biological reactions occur in peat and control the fate of chemical species in wetlands. Wetland scientists often refer to these reactions as biogeochemical processes, because they are chemical reactions usually mediated by microorganisms in a geological environment. An understanding of the biogeochemical processes in peat of South Florida wetlands will provide a basis for evaluating the effects on water quality of (1) constructing buffer wetlands to alleviate nutrient contamination and (2) replumbing the ecosystem to restore natural water flow. The results may also suggest new approaches for solving problems of contamination and water quality in these wetlands. A second focus of this project will be on the geochemical history of the South Florida ecosystem. Peat is a repository of the history of past environmental conditions in the wetland. Before effective action can be taken to correct many of the problems facing these wetlands, we must first study the biogeochemistry of the peat at depth in order to understand whether current problems are the result of recent human activity or are part of a long-term natural cycle. Coordination with other (USGS) projects for South Florida is ongoing. These projects are studying the biological history of the ecosystem by using pollen and shells buried in the peat, together with procedures for dating the peat at various depths, to develop an overall ecosystem history model, with emphasis on the last 100 years.

Fact Sheet↗

Environmental health science at the U.S. Geological Survey

USGS environmental health science focuses on the environment-health interface. Research characterizes the processes that affect the interaction among the physical environment, the living environment, and people, as well as the factors that affect ecological and human exposure to disease agents and the resulting toxicologic or infectious disease. The mission of USGS in environmental health science is to contribute scientific information to environmental, natural resource, agricultural, and public-health managers, who use that information to support sound decisionmaking. Coordination with partners and stakeholders will enable USGS to focus on the highest priority environmental health issues, to make relevant, timely, and useable contributions, and to become a “partner of first choice” for environmental health science.

Fact Sheet↗

Water resources of Wisconsin — Central Wisconsin River basin

LOCATION AND EXTENT OF STUDY AREA The central Wisconsin River basin is the middle part of the entire Wisconsin River basin. The basin is about 5,050 square miles in area, and extends about 110 miles south from Merrill to Wisconsin Dells. The basin includes all or parts of the following counties: Adams, Clark, Columbia, Jackson, Juneau, Langlade, Lincoln, Marathon, Marquette, Monroe, Portage, Sauk, Taylor, Waushara, and Wood. PURPOSE AND SCOPE This study provides a background of hydrologic knowledge suitable for use by water-resource planners and managers, and it provides a framework for more detailed water-resource studies in the future. Specifically, the purposes of this report are to: (1) Describe the geologic and hydrologic environments of the central Wisconsin River basin. (2) Describe the water resources of the central Wisconsin River basin including their sources, uses, quality, interrelationships, availability, and behavior within the basin environment. Much of the information in this report has been generalized to allow presentation in the atlas format. Liberal use was made of available data from many sources and interpretations from published reports. Additional material was collected and analyzed to allow a balanced presentation on water resources and the physical environment. This study is part of an investigation of the water resources of the major river basins in Wisconsin. The completed basin studies and those being studied are shown on the cover envelope. The information in this report should be adequate for the broad aspects of planning water-resource development and management. However, individual problems and water needs will require more specific information than is given in this report.

Wisconsin↗

Selected hydrologic data, through water year 1998, Black Hills Hydrology Study, South Dakota

This report presents water-level and water-quality data that have been collected or compiled, through water year 1998, for the Black Hills Hydrology Study. This study is a long-term cooperative effort between the U.S. Geological Survey, the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District (which represents various local and county cooperators). This report is the third in a series of project data reports produced for the study. Daily water-level data are presented for 71 observation wells and 2 cave sites in the Black Hills area of western South Dakota. The wells include a network of observation wells that are maintained in cooperation with the South Dakota Department of Environment and Natural Resources and are completed in various bedrock formations that are utilized as aquifers in the Black Hills area of western South Dakota. Both cave sites are located within outcrops of the Madison Limestone. Data presented include site descriptions, hydrographs, and tables of daily water levels. Annual measurements of water levels collected during water years 1995-98 from a net-work of 18 additional, miscellaneous wells are presented. These wells are part of a statewide network of wells completed in bedrock aquifers that was operated from 1959 through 1989 in cooperation with the South Dakota Department of Environment and Natural Resources. Site descriptions and hydrographs for the entire period of record for each site also are presented. Water-quality data are presented for 9 surface-water sites, 19 ground-water sites, and 30 sites that have been classified as areas of surface- and ground-water interaction in the Black Hills area. The surface- and ground-water interaction sites are further divided into three categories that include 11 loss zone sites, 8 headwater spring sites, and 11 downgradient spring sites.

South Dakota↗

Continental shelf GIS for the Monterey Bay National Marine Sanctuary

A marine sanctuary is an environment where the interests of science and society meet. Sanctuary managers need access to the best scientific data available that describe the environment and environmental processes in sanctuaries. Seafloor mapping and sampling in the Monterey Bay National Marine Sanctuary have revealed new details about the geology, morphology, and active geologic processes of this region. Data from sidescan sonar, multibeam sonar bathymetry, physical samples, and instrument moorings, are consolidated with new and existing maps in a geographic information system (GIS). The GIS provides researchers and policymakers a view of the relationship among data sets to assist science studies and to help with economic and social policy-making decisions regarding this protected environment.

California↗

Tampa Bay Integrated Science Pilot Study: Baseline mapping, land surface dynamics and predictive modeling, and hazards vulnerability studies

Tampa Bay and its environs have experienced phenomenal urban growth and significant changes in land cover and land-use practices over the past 50 years. This trend is expected to continue, with the impact of human activity broadening geographically and intensifying throughout the region. One of the immediate impacts of urban growth is the creation of additional impervious surfaces, which in turn, generate increased urban runoff that contributes to higher levels of nutrient loading in water bodies throughout the area. To better understand these and other anthropogenic affects on the ecology of the natural environment of the region, this component of the Tampa Bay Pilot Study took a broad basin-wide view. This regional view was intended to provide geographic and temporal context for the smaller intensely studied sample field site locations within the estuarine environment.

Open-File Report↗

Preliminary Mineralogic and Stable Isotope Studies of Altered Summit and Flank Rocks and Osceola Mudflow Deposits on Mount Rainier, Washington

About 5600 years ago part of Mount Rainier?s edifice collapsed with the resultant Osceola Mudflow traveling more than 120 km and covering an area of at least 505 km2. Mineralogic and stable isotope studies were conducted on altered rocks from outcrops near the summit and east flank of the volcano and samples of clasts and matrix from the Osceola Mudflow. Results of these analyses are used to constrain processes responsible for pre-collapse alteration and provide insight into the role of alteration in edifice instability prior to the Osceola collapse event. Jarosite, pyrite, alunite, and kaolinite occur in hydrothermally altered rock exposed in summit scarps formed by edifice collapse events and in altered rock within the east-west structural zone (EWSZ) of the volcano?s east flank. Deposits of the Osceola Mudflow contain clasts of variably altered and unaltered andesite within a clay-rich matrix. Minerals detected in samples from the edifice are also present in many of the clasts. The matrix includes abundant smectite, kaolinite and variably abundant jarosite. Hydrothermal fluid compositions calculated from hydrogen and oxygen isotope data of alunite, and smectite on Mount Rainier reflect mixing of magmatic and meteoric waters. The range in the dD values of modern meteoric water on the volcano (-85 to 155?) reflect the influence of elevation on the dD of precipitation. The d34S and d18OSO4 values of alunite, gypsum and jarosite are distinct but together range from 1.7 to 17.6? and -12.3 to 15.0?, respectively; both parameters increase from jarosite to gypsum to alunite. The variations in sulfur isotope composition are attributed to the varying contributions of disproportionation of magmatic SO2, the supergene oxidation of hydrothermal pyrite and possible oxidation of H2S to the parent aqueous sulfate. The 18OSO4 values of jarosite are the lowest recorded for the mineral, consistent with a supergene origin. The mineralogy and isotope composition of alteration minerals define two and possibly three environments of alteration. At deeper levels magmatic vapor, H2S, SO2 and other gases from venting magmas migrated upward and condensed into the meteoric water. Disproportionation of SO2 into aqueous sulfate and H2S resulted in acid-sulfate (alunite + kaolinite + pyrite) and related argillic and propylitic alteration envelopes in a magmatic hydrothermal environment. At shallow levels H2S reacted with andesite to form pyrite that is associated with smectite along fractures on both the flanks and upper edifice. It is not clear to what extent H2S was oxidized by atmospheric O2 to form aqueous sulfate in a steam-heated environment. Near the ground surface, pyrite is oxidized by atmospheric oxygen resulting in soluble iron-and aluminum-hydroxysulfates. These supergene hydroxysulfates, which may also form around fumaroles from the oxidation of H2S, are subject to continuous solution and redeposition.

Open-File Report↗

Sediment-hosted copper deposits of the world: Deposit models and database

Introduction This publication contains four descriptive models and four grade-tonnage models for sediment hosted copper deposits. Descriptive models are useful in exploration planning and resource assessment because they enable the user to identify deposits in the field and to identify areas on geologic and geophysical maps where deposits could occur. Grade and tonnage models are used in resource assessment to predict the likelihood of different combinations of grades and tonnages that could occur in undiscovered deposits in a specific area. They are also useful in exploration in deciding what deposit types meet the economic objectives of the exploration company. The models in this report supersede the sediment-hosted copper models in USGS Bulletin 1693 (Cox, 1986, and Mosier and others, 1986) and are subdivided into a general type and three subtypes. The general model is useful in classifying deposits whose features are obscured by metamorphism or are otherwise poorly described, and for assessing regions in which the geologic environments are poorly understood. The three subtypes are based on differences in deposit form and environments of deposition. These differences are described under subtypes in the general model. Deposit models are based on the descriptions of geologic environments and physical characteristics, and on metal grades and tonnages of many individual deposits. Data used in this study are presented in a database representing 785 deposits in nine continents. This database was derived partly from data published by Kirkham and others (1994) and from new information in recent publications. To facilitate the construction of grade and tonnage models, the information, presented by Kirkham in disaggregated form, was brought together to provide a single grade and a single tonnage for each deposit. Throughout the report individual deposits are defined as being more than 2,000 meters from the nearest adjacent deposit. The deposit models are presented here as a PDF file. The database can be most conveniently read in FileMaker Pro. For those who do not have the FileMaker application, Microsoft-Excel, tab-delimited-ASCII and comma-separated-value files are included. The reader may be interested in a similar publication on porphyry copper deposits (Singer and others, 2005) also available online. The Google Earth image is not intended to be viewed at the highest possible magnification because the resolution of the database is plus or minus two kilometers. At extreme zoom settings, the deposit locations may not coincide with the Google-Earth images of the mine workings.

Open-File Report↗

PCB concentrations in Pere Marquette River and Muskegon River watersheds, 2002

Polychlorinated biphenyl compounds (PCBs) are a class of209 individual compounds (known as congeners) for which there are no known natural sources. PCBs are carcinogenic and bioaccumulative compounds. For over 40 years, PCBs were manufactured in the United States. The flame resistant property of PCBs made them ideal chemicals for use as flame-retardants, and as coolants and lubricants in transformers and other electrical equipment. PCBs were also used in heating coils, carbonless paper, degreasers, varnishes, lacquers, waterproofing material, and cereal boxes. In addition, they were frequently used in the manufacturing of plastics, adhesives, and paints. During the manufacturing period of PCBs, these chemicals entered the environment though atmospheric release during manufacturing and burning of PCB products, leaks and spills, and improper disposal. Although PCB manufacturing was banned over 20 years ago, PCBs still enter the environment from hazardous waste sites, improper disposals of PCB-containing products, weathering of asphalt and other substances containing PCBs, burning of PCB containing products, leakage from old equipment, leaching from landfills, and release from contaminated sediments. PCBs do not readily break down in the environment, thus remain there for long periods of time. A small amount may remain dissolved in water but most adhere to organic particles and bottom sediments. In sufficient concentrations, PCBs affect human, wildlife, and aquatic health. PCBs accumulate in fatty tissues of animals and fish and are passed on to those that eat them. PCBs are animal teratogens and potentially carcinogenic. They can cause death of animals, fish, and birds; death or low growth rate of plants; shortened lifespan; reproductive problems; and lower fertility. Women who are exposed to high levels of PCBs may have babies with slightly lower birth weights and transfer the PCBs through the breast milk, which may affect the immune system and motor development of the child. Rule 323.1057 (Toxic Substances) of the Part 4. Water Quality Standards gives procedure for calculating water-quality values to protect human, wildlife and aquatic life. For total PCB, the applicable Rule 57 water-quality value is the human cancer value (HCV=0.26 ng/L), In 2002, U. S. Geological Survey (USGS) and Michigan Department of Environmental Quality (MDEQ) cooperatively planned and executed a monitoring program for PCBs in water and sediment from the Pere Marquette River and Muskegon River watersheds. The Pere Marquette and Muskegon River are in the west central part of Michigan's Lower Peninsula (fig. 1). The Pere Marquette River watershed is about 750 square miles, and the Muskegon River is about 2700 square miles. Both rivers are popular recreational waters, and the Pere Marquette River is a Michigan designated Natural River (Part 305 of the Natural Rivers and Environmental Protection Act 451 of 1994).

Michigan↗

Descriptions and preliminary report on sediment cores from the southwest coastal area, Everglades National Park, Florida

Sediment cores were collected from five locations in the southwest coastal area of Everglades National Park, Florida, in May 2004 for the purpose of determining the ecosystem history of the area and the impacts of changes in flow through the Shark River Slough. An understanding of natural cycles of change prior to significant human disturbance allows land managers to set realistic performance measures and targets for salinity and other water quality and quantity quality measures. Preliminary examination of the cores indicates significant changes have taken place over the last 1000-2000 years. The cores collected from the inner bays — the most landward bays — are distinctly different from other estuarine sediment cores examined in Florida Bay and Biscayne Bay. Peats in the inner-bay cores from Big Lostmans Bay, Broad River Bay, and Tarpon Bay were deposited at least 1000 years before present (BP) based on radiocarbon analyses. The peats are overlain by poorly sorted organic muds and sands containing species indicative of deposition in a freshwater to very low salinity environment. The Alligator Bay core, the most northern inner-bay core, is almost entirely sand; no detailed faunal analyses or radiometric dating has been completed on this core. The Roberts River core, taken from the mouth of the River where it empties into Whitewater Bay, is lithologically and faunally similar to previously examined cores from Biscayne and Florida Bays; however, the basal unit was deposited ~2000 years before the present based on radiocarbon analyses. A definite trend of increasing salinity over time is seen in the Roberts River core, from sediments representing a terrestrially dominated freshwater environment at the bottom of the core to those representing an estuarine environment with a strong freshwater influence at the top. The changes seen at Roberts River could represent a combination of factors including rising sea-level and changes in freshwater supply, but the timing and extent of the changes needs to be determined. The preliminary information on the cores collected in 2004 will be combined with data from cores collected in July 2005. The 2005 cores were collected along transects moving from the inner bays out towards the coast. These transects, combining information from the 2004 and 2005 cores, will allow us to examine long term trends in freshwater supply, sea-level rise, and potentially the impact of storms on the coastal ecosystem.

Florida↗

Coastal circulation and sediment dynamics in Hanalei Bay, Kaua'i, Hawaii. Part III: Studies of sediment toxicity

Toxicity tests are commonly conducted as a measure of the bioavailability of toxic chemicals to biota in an environment. Chemical analyses alone are insufficient to determine whether contaminants pose a threat to biota. Porewater toxicity tests are extremely sensitive to a broad range of contaminants in marine environments and provide ecologically relevant data on sensitive life stages. The inclusion of porewater toxicity testing as an additional indicator of sediment quality provides a more comprehensive picture of contaminant effects in these sensitive habitats. In this study purple-spined sea urchin (Arbacia punctulata) fertilization and embryological development porewater toxicity tests were used to evaluate the sediments collected from the coastal environment around Hanalei Bay, Kaua’i, Hawaii. These tests have been used previously to assess the bioavailability of contaminants associated with sediments in the vicinity of coral reefs.

Hawaii↗

Reconnaissance of arsenic concentrations in ground water from bedrock and unconsolidated aquifers in eight northern-tier counties of Pennsylvania

Samples of ground water for analysis of total-arsenic concentrations were collected in eight counties--Potter, Tioga, Bradford, Susquehanna, Wayne, Pike, Sullivan, and Wyoming--and from eight bedrock formations (bedrock aquifers) and overlying glacial aquifers in the north-central and northeastern parts of Pennsylvania in July 2005 and from March through June 2006. The samples were collected from a total of 143 domestic wells, 2 stock wells, 4 non-community wells, 2 community water-system wells, and 3 domestic springs by well or spring owners using sampling kits provided by the U.S. Geological Survey (USGS). An additional 15 domestic wells were sampled by the USGS for analysis of total arsenic. These 15 samples were collected using the same methods and sampling kits provided to the homeowners. Samples were analyzed for total arsenic by the Pennsylvania Department of Environmental Protection Laboratory using a minimum reporting level of 4.0 µg/L (micrograms per liter). Arsenic was detected in water from 18 domestic wells in four counties--Bradford (3 wells), Sullivan (1 well), Tioga (13 wells), and Wayne (1 well). The median concentration of total arsenic was less than 4.0 µg/L, and the maximum concentration was 188 µg/L. Water from 10 wells had concentrations of total arsenic greater than the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 µg/L. Detectable concentrations of total arsenic were measured in water from wells that ranged in depth from 29 to 400 feet, and that were completed in three aquifers--Lock Haven Formation, Catskill Formation, and unconsolidated glacial sediments; no springs had detectable concentrations of total arsenic. Water samples representing the Lock Haven Formation were collected from 60 wells; water from 12 of these wells had detectable concentrations of total arsenic. Water samples representing the Catskill Formation were collected from 57 wells; water from 4 wells had detectable concentrations of total arsenic. Water samples representing the unconsolidated glacial sediments were collected from 17 wells; 2 wells had water with detectable concentrations of total arsenic. Contingency tables tested for significant differences in total arsenic between aquifers, topographic settings, and well depths. Concentrations of total arsenic were significantly greater (95-percent confidence level) in the Lock Haven Formation than in the other bedrock units. Concentrations of total arsenic also varied significantly by topographic setting. Wells completed in the Lock Haven Formation and located in valleys had significantly greater concentrations of total arsenic than similar wells located on hilltops or slopes. Concentrations of total arsenic did not vary significantly by topographic setting in the Catskill Formation. Concentrations of total arsenic did not vary significantly by well depth for any aquifer. Iron staining, hydrogen-sulfide odor, or both were common complaints of well owners. Iron staining was a complaint of 44 well owners. Hydrogen-sulfide odor was a complaint of 35 well owners. Fourteen well owners complained of both iron staining and hydrogen sulfide. No correlation to the presence of arsenic in the wells sampled was found with iron staining, hydrogen-sulfide odor, or both. Water from 8 of the 10 wells that contained concentrations of total arsenic greater than 10 µg/L were sampled by USGS personnel for the determination of concentrations of dissolved arsenic (minimum reporting level 0.3 µg/L) and arsenic species {arsenite [As (III)], arsenate [As (V)], monomethylarsonate (MMA), and dimethylarsinate (DMA)} at the USGS National Water Quality Laboratory. Analytical results from these samples showed a median concentration of 38.7 µg/L dissolved arsenic in water and a maximum of 178 µg/L. As (III) was the most common arsenic species present in the water for seven of the eight wells and was found in water characteristic of reducing environments [pH 8.2 to 9.1, dissolved oxygen 0.06 to 0.29 milligrams per liter (mg/L), and oxidation reduction potential -63 to -203 millivolts (mv)]. As (V) was the dominant arsenic species in water characteristic of an oxidizing environment (pH 4.8, dissolved oxygen 2.15 mg/L, oxidation reduction potential 265 mv). The arsenic species MMA and DMA were detected in the water from two wells. The arsenic species MMA was detected at an estimated concentration of 0.9 µg/L in water from one well; the concentration was less than 1.2 µg/L in water from seven wells. The arsenic species DMA was detected at concentrations of 1.0 and 1.5 µg/L in water from two wells; the concentration was less than 0.6 µg/L in water from six wells. Both wells that contained detectable concentrations of MMA and DMA produced water that was characteristic of reducing environments.

Pennsylvania↗

Chemical data for rock, sediment, biological, precipitate, and water samples from abandoned copper mines in Prince William Sound, Alaska

Introduction In the early 20th century, approximately 6 million metric tons of copper ore were mined from numerous deposits located along the shorelines of fjords and islands in Prince William Sound, Alaska. At the Beatson, Ellamar, and Threeman mine sites (fig. 1), rocks containing Fe, Cu, Zn, and Pb sulfide minerals are exposed to chemical weathering in abandoned mine workings and remnant waste piles that extend into the littoral zone. Field investigations in 2003 and 2005 as well as analytical data for rock, sediment, precipitate, water, and biological samples reveal that the oxidation of sulfides at these sites is resulting in the generation of acid mine drainage and the transport of metals into the marine environment (Koski and others, 2008; Stillings and others, 2008). At the Ellamar and Threeman sites, plumes of acidic and metal-enriched water are flowing through beach gravels into the shallow offshore environment. Interstitial water samples collected from beach sediment at Ellamar have low pH levels (to ~3) and high concentrations of metals including iron, copper, zinc, cobalt, lead, and mercury. The abundant precipitation of the iron sulfate mineral jarosite in the Ellamar gravels also signifies a low-pH environment. At the Beatson mine site (the largest copper mine in the region) seeps containing iron-rich microbial precipitates drain into the intertidal zone below mine dumps (Foster and others, 2008). A stream flowing down to the shoreline from underground mine workings at Beatson has near-neutral pH, but elevated levels of zinc, copper, and lead (Stillings and others, 2008). Offshore sediment samples at Beatson are enriched in these metals. Preliminary chemical data for tissue from marine mussels collected near the Ellamar, Threeman, and Beatson sites reveal elevated levels of copper, zinc, and lead compared to tissue in mussels from other locations in Prince William Sound (Koski and others, 2008). Three papers presenting results of this ongoing investigation of sulfide oxidation in Prince William Sound are in press. Koski and others (2008) provide an overview of rock alteration, surface water chemistry, and the distribution of metals at the Ellamar, Threeman, and Beatson mine sites. Based on a 60-day, stream-discharge experiment at Beatson in 2005, Stillings and others (2008) analyze changes in water chemistry during storm events and the flux of metals to the shoreline. Foster and others (2008) investigate the biomass and diversity of microbial communities present in surface waters (streams, seeps, pore waters) using fatty acid methyl ester (FAMES) data and principal component analysis. The publications cited above contain a subset of the total chemical data for rock, sediment, biological, precipitate, and water samples collected from the three mine sites in 2003 and 2005. The purpose of this report is the presentation of complete chemical data sets for all samples collected during the two field periods of fieldwork. Data for a small number of samples collected at two other mines (Schlosser and Fidalgo, fig. 1), visited in 2003, are also included in the tables.

Alaska↗

Chemical data for rock, sediment, biological, precipitate, and water samples from abandoned copper mines in Prince William Sound, Alaska

In the early 20th century, approximately 6 million metric tons of copper ore were mined from numerous deposits located along the shorelines of fjords and islands in Prince William Sound, Alaska. At the Beatson, Ellamar, and Threeman mine sites (fig. 1), rocks containing Fe, Cu, Zn, and Pb sulfide minerals are exposed to chemical weathering in abandoned mine workings and remnant waste piles that extend into the littoral zone. Field investigations in 2003 and 2005 as well as analytical data for rock, sediment, precipitate, water, and biological samples reveal that the oxidation of sulfides at these sites is resulting in the generation of acid mine drainage and the transport of metals into the marine environment (Koski and others, 2008; Stillings and others, 2008). At the Ellamar and Threeman sites, plumes of acidic and metal-enriched water are flowing through beach gravels into the shallow offshore environment. Interstitial water samples collected from beach sediment at Ellamar have low pH levels (to ~3) and high concentrations of metals including iron, copper, zinc, cobalt, lead, and mercury. The abundant precipitation of the iron sulfate mineral jarosite in the Ellamar gravels also signifies a low-pH environment. At the Beatson mine site (the largest copper mine in the region) seeps containing iron-rich microbial precipitates drain into the intertidal zone below mine dumps (Foster and others, 2008). A stream flowing down to the shoreline from underground mine workings at Beatson has near-neutral pH, but elevated levels of zinc, copper, and lead (Stillings and others, 2008). Offshore sediment samples at Beatson are enriched in these metals. Preliminary chemical data for tissue from marine mussels collected near the Ellamar, Threeman, and Beatson sites reveal elevated levels of copper, zinc, and lead compared to tissue in mussels from other locations in Prince William Sound (Koski and others, 2008). Three papers presenting results of this ongoing investigation of sulfide oxidation in Prince William Sound are in press. Koski and others (2008) provide an overview of rock alteration, surface water chemistry, and the distribution of metals at the Ellamar, Threeman, and Beatson mine sites. Based on a 60-day, stream-discharge experiment at Beatson in 2005, Stillings and others (2008) analyze changes in water chemistry during storm events and the flux of metals to the shoreline. Foster and others (2008) investigate the biomass and diversity of microbial communities present in surface waters (streams, seeps, pore waters) using fatty acid methyl ester (FAMES) data and principal component analysis. The publications cited above contain a subset of the total chemical data for rock, sediment, biological, precipitate, and water samples collected from the three mine sites in 2003 and 2005. The purpose of this report is the presentation of complete chemical data sets for all samples collected during the two field periods of fieldwork. Data for a small number of samples collected at two other mines (Schlosser and Fidalgo, fig. 1), visited in 2003, are also included in the tables.

Alaska↗

Sidescan-sonar imagery and surficial geologic interpretations of the sea floor in central Rhode Island Sound

The U.S. Geological Survey (USGS) has been working with the National Oceanic and Atmospheric Administration (NOAA) to interpret the surficial geology of areas along the northeastern coast of the United States. During 2004, the NOAA Ship RUDE conducted Hydrographic Survey H11321 in Rhode Island Sound. This sidescan-sonar and bathymetry survey covers an area of 93 km? located 12 km southeast of Brenton Point, RI in water depths of 28-39 m (fig. 1). The purpose of this report is to delineate sea floor features and sedimentary environments of this area in central Rhode Island Sound using sidescan-sonar and bathymetric data from NOAA Survey H11321 and seismic-reflection data from a previous USGS field study (Needell and others, 1983a). This is important for the study of benthic habitats and provides a framework for future research. Prior work in this area includes the mapping of surface sediments and surficial geology. McMaster (1960) collected sediment samples from Rhode Island Sound and Narragansett Bay and mapped our study area as having a sandy sea floor. In addition, one sample of sand from the National Ocean Service (NOS) Hydrographic Database came from a location in the northeast part of our study area in 1939 (fig. 2; Poppe and others, 2003). McMaster and others (1968) used seismic-reflection profiles to map the locations of a cuesta of Cretaceous sediments crossing Rhode Island Sound and post-Cretaceous drainage channels. Knebel and others (1982) identified sedimentary environments in Rhode Island Sound using sidescan sonographs. Needell and others (1983b) studied the Quaternary geology and mapped the structure, sedimentary environments, and geologic hazards in Rhode Island Sound using sidescan-sonar and seismic-reflection data. Sidescan-sonar and bathymetric data from NOAA Survey H11320, which overlaps the far eastern edge of our study area, was interpreted to consist of basins surrounded by a moraine and bathymetric highs composed of till with areas of rocks, sand waves, hummocks, glaciolacustrine erosional outliers, small scarps and elongate hills (fig. 1; McMullen and others, 2007). Some of those features extend into this study area.

Rhode Island↗

Extended abstracts from the Coastal Habitats in Puget Sound (CHIPS) 2006 Workshop

Puget Sound is the second largest estuary in the United States. Its unique geology, climate, and nutrient-rich waters produce and sustain biologically productive coastal habitats. These same natural characteristics also contribute to a high quality of life that has led to a significant growth in human population and associated development. This population growth, and the accompanying rural and urban development, has played a role in degrading Puget Sound ecosystems, including declines in fish and wildlife populations, water-quality issues, and loss and degradation of coastal habitats. In response to these ecosystem declines and the potential for strategic large-scale preservation and restoration, a coalition of local, State, and Federal agencies, including the private sector, Tribes, and local universities, initiated the Puget Sound Nearshore Ecosystem Restoration Project (PSNERP). The Nearshore Science Team (NST) of PSNERP, along with the U.S. Geological Survey, developed a Science Strategy and Research Plan (Gelfenbaum and others, 2006) to help guide science activities associated with nearshore ecosystem restoration. Implementation of the Research Plan includes a call for State and Federal agencies to direct scientific studies to support PSNERP information needs. In addition, the overall Science Strategy promotes greater communication with decision makers and dissemination of scientific results to the broader scientific community. On November 14–16, 2006, the U.S. Geological Survey sponsored an interdisciplinary Coastal Habitats in Puget Sound (CHIPS) Research Workshop at Fort Worden State Park, Port Townsend, Washington. The main goals of the workshop were to coordinate, integrate, and link research on the nearshore of Puget Sound. Presented research focused on three themes: (1) restoration of large river deltas; (2) recovery of the nearshore ecosystem of the Elwha River; and (3) effects of urbanization on nearshore ecosystems. The more than 35 presentations covered a wide range of ongoing inter-disciplinary research, including studies of sediment geochemistry of aquatic environments, sediment budgets, tracking fish pathways, expansion of invasive forams, beach and nearshore sedimentary environments, using influence diagrams as a decision support tool, forage fish, submarine groundwater, and much, much more. The primary focus within these themes was on developing information on the physical, chemical, and biological processes, as well as the human dimensions, associated with the restoration or rehabilitation of the nearshore environment. The workshop was an excellent opportunity for USGS scientists and collaborators who are working on Puget Sound coastal habitats to present their preliminary findings, discuss upcoming research, and to identify opportunities for interdisciplinary collaboration. A compilation of extended abstracts from workshop participants, this proceedings volume serves as a useful reference for attendees of the workshop and for those unable to attend. Taken together, the abstracts in this report provide a view of the current status of USGS multidisciplinary research on Puget Sound coastal habitats.

Open-File Report↗

The effects of sediment and mercury mobilization in the South Yuba River and Humbug Creek confluence area, Nevada County, California: Concentrations, speciation, and environmental fate – Part 1: Field characterization

Millions of pounds of mercury (Hg) were deposited in the river and stream channels of the Sierra Nevada from placer and hard-rock mining operations in the late 1800s and early 1900s. The resulting contaminated sediments are relatively harmless when buried and isolated from the overlying aquatic environment. The entrained Hg in the sediment constitutes a potential risk to human and ecosystem health should it be reintroduced to the actively cycling portion of the aquatic system, where it can become methylated and subsequently bioaccumulated in the food web. Each year, sediment is mobilized within these fluvial systems during high stormflows, transporting hundreds of tons of Hg-laden sediment downstream. The State of California and resource-management agencies, including the Bureau of Land Management (BLM) and the U.S. Forest Service, are concerned about additional disturbances, such as from suction gold dredging activities, which have the potential to mobilize Hg associated with buried sediment layers elevated in Hg that are otherwise likely to remain buried under normal storm conditions. The BLM initiated a study looking at the feasibility of removing Hg-contaminated sediment at the confluence of the South Yuba River and Humbug Creek in the northern Sierra Nevada of California by using standard suction-dredge technology. Additionally, the California State Water Resources Control Board (SWRCB) supported a comprehensive characterization of the intended dredge site. Together, the BLM and SWRCB supported a comprehensive characterization of Hg contamination at the site and the potential effects of sediment disturbance at locations with historical hydraulic mining debris on downstream environments. The comprehensive study consisted of two primary components: field studies and laboratory experiments. The field component, described in this report, had several study elements: 1) a preliminary, smallscale, in-stream dredge test; 2) comprehensive characterization of grain size distribution, Hg speciation, and mineralogy of bed and suspended sediment; 3) a determination of the past and current sources of sediment in the study area; 4) an assessment of Hg bioaccumulation in the local invertebrate population; and 5) a comparison of potential Hg transport caused by natural storm disturbances with potential Hg mobilization caused by suction dredging as a method of Hg removal at the study site. The laboratory component of the study assessed the potential influence of the disturbance of Hg-contaminated sediment through experiments designed to simulate in-stream transport, deposition, and potential methylation of Hg, described in a companion report (see Marvin-DiPasquale and others, 2011). Results of the field studies indicate that the fine-grained fraction (silt-clay, less than 0.063 millimeters) contains the greatest concentration of Hg in contaminated sediment. Because the fine-grained fraction is the most susceptible to longrange fluvial transport, disturbance of Hg-contaminated sediment is likely to increase the concentration and load of Hg in downstream waters. The preliminary, small-scale dredge test showed an increase in the concentration of fine particles and Hg in the water column caused by the dredge activity, despite relatively low concentrations of fine particles and Hg (about 300 nanograms per gram) at the dredge site. Characterization of sediment from two test pits and other sites in the vicinity of the confluence of the South Yuba River and Humbug Creek revealed a highly variable distribution of fine- and coarse-grained sediment. The highest levels of Hg contamination (up to 11,100 ng/g) were associated with the fine-grained fraction of sediment from the bedrock contact zone of Pit 2, a horizon which also yielded grains of gold and gold-Hg amalgam. A closed-circuit tank experiment with a venturi dredge at the base of Pit 1, in a gravel bar within the South Yuba River, resulted in fine-grained suspended sediment remaining in suspension more than 40 hours following the disturbance simulation. Although the volumetric concentration of Hg declined over time as particles settled out, the concentration of Hg on the suspended particles increased over time as the suspended material became finer grained, because Hg is preferentially adsorbed on to clay-sized particles. Mineralogical and chemical analyses indicated that the buried fine-grained material with the greatest Hg contamination was derived from hydraulic mining debris, which consist primarily of Eocene gravels mined in the Malakoff Diggins, North Bloomfield, and Lake City areas within the South Yuba River watershed. Coarse material and more recently deposited sediment were derived primarily from upstream sources on the South Yuba River. The biota assessment indicated that invertebrate taxa collected from all sites on the South Yuba River in 2007, including lower Humbug Creek, had elevated concentrations of total mercury (THg) and methylmercury (MeHg) compared to a reference site on the Bear River, upstream of mining effects. Differences with the reference site were less pronounced in 2008 when a significant reduction in MeHg concentrations was observed in biota across all taxa from concentrations in 2007. It is possible that the inter-annual variation was related to the fact that suction dredging was active in the South Yuba River in 2007 but not in 2008 when a local moratorium was imposed by the BLM. There were significant variations among taxa for both THg and MeHg concentrations, with the water striders (Gerridae) having the highest concentrations of both THg and MeHg; variation among sites was not as strong as between years or among taxa. These results suggest that additional monitoring would be helpful to investigate the possible linkage between variations in MeHg bioaccumulation and levels of suction dredge activity in areas of historical gold mining. Results from the field studies indicate that disturbance of the finegrained Hg-contaminated sediment would likely lead to enhanced mobilization of Hg to downstream environments; therefore, the use of suction dredging to remove Hg at the South Yuba River and Humbug Creek confluence area would likely result in enhanced Hg transport downstream relative to natural conditions.

California↗