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At least 1,207 records · Page 67Linked to original sources

USGS1996

Selected geochemical characteristics of ground water from the Marshall aquifer in the central Lower Peninsula of Michigan

Chemistry and stable-isotope data for water from wells completed in the Marshall aquifer within the Michigan Basin were used to prepare maps that show area! variations of δ 18 O; distribution of dissolved solids, dissolved chloride, dissolved iron, and dissolved sulfate; and distribution of hydrochemical facies. Delta oxygen-18 values indicate the presence of modern meteoric water ( δ 18 O approximately -10 parts per mil) as well as isotopically light meteoric water ( δ 18 O less than -15 parts per mil). Isotopically light ground water is present in the Michigan Lowland. Dissolved-solids concentrations range from 273 to 412,000 milligrams per liter, and dissolved-chloride concentrations range from less than 10 to greater than 250,000 milligrams per liter. Dissolved-solids and dissolved-chloride concentrations increase toward the center of the study area. Dissolved-iron concentrations which range from less than 0.002 to 100 milligrams per liter, are low in the subcrop areas, and increase toward the center of the study area. Dissolved-sulfate concentrations range from 4.5 to 3,500 milligrams per liter and generally increase then decrease from the subcrop area toward the center of the study area. Most ground water in the Marshall aquifer is classified as either a calcium bicarbonate or a sodium chloride type.

Michigan↗

USGS1988

KAr ages, chemical composition and geothermal significance of cenozoic basalt near the Jordan rift

Late Cenozoic mafic lavas crop out locally along the Jordan rift. Some of these lavas are spatially associated with thermal springs, and this association has prompted some workers to hypothesize that the hot water derives its thermal energy from the shallow, still hot intrusive roots of the volcanic rocks. However, all of the volcanic rocks appear to represent mantle-derived mafic magma that rose rather quickly to the Earth's surface, without filling crustal reservoirs within which differentiation would have produced evolved, derivative products. Moreover, the lavas are too old and of too small a volume to represent the surface expression of an active reservoir of magma within the crust. These interpretations of the volcanic geology are consistent with conclusions drawn from the chemistry of the thermal water; the water has equilibrated with host rocks at no more than 110°C, probably at depths of 2–3 km. Thus, thermal springs along the Jordan rift appear to reflect heating during circulation through a regional regime of average crustal heat flow (Galanis et at. , 1986). The magmatic activity may only be a second or third order contributor to this heat flow.

Geothermics↗

USGS1961

Uranium migration and geochemistry of uranium deposits in sandstone above, at, and below the water table; Part 2, Relationship of uranium migration dates, geology, and chemistry of the uranium deposits

The time of U migration in deposits in sandstone can be determined by correlating apparent age calculations, based on radiochemical analyses, with the geology of a particular deposit. Data were obtained from U ore samples representing deposits above the water table, deposits just above and below perched water tables, and deposits at least 250 ft. below the water table in the Hulett Creek area, Wyoming. The first U deposition occurred more than 250,000 years ago for the deposits now at or above the water table. Approximately 60,000 to 80,000 years ago these deposits were oxidized, leached, and locally enriched. Accumulation of U in the deposits below the water table probably did not start before 180,000 years ago and has continued to the present.

Montana, South Dakota, Wyoming↗

USGS1991

Chloride cycling in two forested lake watersheds in the west-central Adirondack Mountains, New York, U.S.A.

The chemistry of precipitation, throughfall, soil water, ground water, and surface water was evaluated in two forested lake-watersheds over a 4-yr period to assess factors controlling C1- cycling. Results indicate that C1- cycling in these watersheds is more complex than the generally held view of the rapid transport of atmospherically derived C1- through the ecosystem. The annual throughfall Cl- flux for individual species in the northern hardwood forest was 2 to 5 times that of precipitation (56 eq ha-1), whereas the Na+ throughfall flux, in general, was similar to the precipitation flux. Concentrations of soil-water Cl- sampled from ceramic tension lysimeters at 20 cm below land surface generally exceeded the Na+ concentrations and averaged 31 ??eq L-1, the highest of any waters sampled in the watersheds, except throughfall under red spruce which averaged 34 ??eq L-1. Chloride was concentrated prior to storms and mobilized rapidly during storms as suggested by increases in streamwater Cl- concentrations with increasing flow. Major sources of Cl- in both watersheds are the forest floor and hornblende weathering in the soils and till. In the Panther Lake watershed, which contains mainly thick deposits of till( > 3 m), hornblende weathering results in a net Cl- flux 3 times greater than that in the Woods Lake watershed, which contains mainly thin deposits of till. The estimated accumulation rate of Cl- in the biomass of the two watersheds was comparable to the precipitation Cl- flux.The chemistry of precipitation, throughfall, soil water, ground water, and surface water was evaluated in two forested lake-watersheds over a 4-yr period to assess factors controlling Cl- cycling. Results indicate that Cl- cycling in these watersheds is more complex than the generally held view of the rapid transport of atmospherically derived Cl- through the excosystem. The annual throughfall Cl- flux for individual species in the northern hardwood forest was 2 to 5 times that of precipitation (56 eq ha-1), whereas the Na+ throughfall flux, in general, was similar to the precipitation flux. Concentrations of soil-water Cl- sampled from ceramic tension lysimeters at 20 cm below land surface generally exceeded the Na+ concentrations and averaged 31 ??eq L-1, the highest of any waters sampled in the watersheds, except throughfall under red spruce which averaged 34 ??eq L-1. Chloride was concentrated prior to storms and mobilized rapidly during storms as suggested by increases in streamwater Cl- concentrations with increasing flow. Major sources of Cl- in both watersheds are the forest floor and hornblende weathering in the soils and till. In the Panther Lake watershed, which contains mainly thick deposits of till (> 3 m), hornblende weathering results in a net Cl- flux 3 times greater than that in the Woods Lake watershed, which contains mainly thin deposits of till. The estimated accumulation rate of Cl- in the biomass of the two watersheds was comparable to the precipitation Cl- flux.

Water, Air, & Soil Pollution↗

USGS2011

Fluoride geochemistry of thermal waters in Yellowstone National Park: I. Aqueous fluoride speciation

Thermal water samples from Yellowstone National Park (YNP) have a wide range of pH (1–10), temperature, and high concentrations of fluoride (up to 50 mg/l). High fluoride concentrations are found in waters with field pH higher than 6 (except those in Crater Hills) and temperatures higher than 50 °C based on data from more than 750 water samples covering most thermal areas in YNP from 1975 to 2008. In this study, more than 140 water samples from YNP collected in 2006–2009 were analyzed for free-fluoride activity by ion-selective electrode (ISE) method as an independent check on the reliability of fluoride speciation calculations. The free to total fluoride concentration ratio ranged from <1% at low pH values to >99% at high pH. The wide range in fluoride activity can be explained by strong complexing with H + and Al 3+ under acidic conditions and lack of complexing under basic conditions. Differences between the free-fluoride activities calculated with the WATEQ4F code and those measured by ISE were within 0.3–30% for more than 90% of samples at or above 10 −6 molar, providing corroboration for chemical speciation models for a wide range of pH and chemistry of YNP thermal waters. Calculated speciation results show that free fluoride, F − , and major complexes ( HF ( aq ) 0 "> HF(aq)0 , AlF 2+ , AlF 2 + "> AlF2+ and AlF 3 0 "> AlF30 ) account for more than 95% of total fluoride. Occasionally, some complex species like AlF 4 - "> AlF4- , FeF 2+ , FeF 2 + "> FeF2+ , MgF + and BF 2 ( OH ) 2 - "> BF2(OH)2- may comprise 1–10% when the concentrations of the appropriate components are high. According to the simulation results by PHREEQC and calculated results, the ratio of main fluoride species to total fluoride varies as a function of pH and the concentrations and ratios of F and Al.

Yellowstone National Park↗

USGS2001

Unusual bacterioplankton community structure in ultra-oligotrophic Crater Lake

The bacterioplankton assemblage in Crater Lake, Oregon (U.S.A.), is different from communities found in other oxygenated lakes, as demonstrated by four small subunit ribosomal ribonucleic acid (SSU rRNA) gene clone libraries and oligonucleotide probe hybridization to RNA from lake water. Populations in the euphotic zone of this deep (589 m), oligotrophic caldera lake are dominated by two phylogenetic clusters of currently uncultivated bacteria: CL120-10, a newly identified cluster in the verrucomicrobiales, and ACK4 actinomycetes, known as a minor constituent of bacterioplankton in other lakes. Deep-water populations at 300 and 500 m are dominated by a different pair of uncultivated taxa: CL500-11, a novel cluster in the green nonsulfur bacteria, and group I marine crenarchaeota. b-Proteobacteria, dominant in most other freshwater environments, are relatively rare in Crater Lake (<=16% of nonchloroplast bacterial rRNA at all depths). Other taxa identified in Crater Lake libraries include a newly identified candidate bacterial division, ABY1, and a newly identified subcluster, CL0-1, within candidate division OP10. Probe analyses confirmed vertical stratification of several microbial groups, similar to patterns observed in open-ocean systems. Additional similarities between Crater Lake and ocean microbial populations include aphotic zone dominance of group I marine crenarchaeota and green nonsulfur bacteria. Comparison of Crater Lake to other lakes studied by rRNA methods suggests that selective factors structuring Crater Lake bacterioplankton populations may include low concentrations of available trace metals and dissolved organic matter, chemistry of infiltrating hydrothermal waters, and irradiation by high levels of ultraviolet light.

Limnology and Oceanography↗

USGS2006

Methods for measuring denitrification: Diverse approaches to a difficult problem

Denitrification, the reduction of the nitrogen (N) oxides, nitrate (NO 3 − ) and nitrite (NO 2 − ), to the gases nitric oxide (NO), nitrous oxide (N 2 O), and dinitrogen (N 2 ), is important to primary production, water quality, and the chemistry and physics of the atmosphere at ecosystem, landscape, regional, and global scales. Unfortunately, this process is very difficult to measure, and existing methods are problematic for different reasons in different places at different times. In this paper, we review the major approaches that have been taken to measure denitrification in terrestrial and aquatic environments and discuss the strengths, weaknesses, and future prospects for the different methods. Methodological approaches covered include (1) acetylene-based methods, (2) 15 N tracers, (3) direct N 2 quantification, (4) N 2 :Ar ratio quantification, (5) mass balance approaches, (6) stoichiometric approaches, (7) methods based on stable isotopes, (8) in situ gradients with atmospheric environmental tracers, and (9) molecular approaches. Our review makes it clear that the prospects for improved quantification of denitrification vary greatly in different environments and at different scales. While current methodology allows for the production of accurate estimates of denitrification at scales relevant to water and air quality and ecosystem fertility questions in some systems (e.g., aquatic sediments, well-defined aquifers), methodology for other systems, especially upland terrestrial areas, still needs development. Comparison of mass balance and stoichiometric approaches that constrain estimates of denitrification at large scales with point measurements (made using multiple methods), in multiple systems, is likely to propel more improvement in denitrification methods over the next few years.

Ecological Applications↗

USGS2018

General introduction for the “National Field Manual for the Collection of Water-Quality Data”

Background As part of its mission, the U.S. Geological Survey (USGS) collects data to assess the quality of our Nation’s water resources. A high degree of reliability and standardization of these data are paramount to fulfilling this mission. Documentation of nationally accepted methods used by USGS personnel serves to maintain consistency and technical quality in data-collection activities. “The National Field Manual for the Collection of Water-Quality Data” (NFM) provides documented guidelines and protocols for USGS field personnel who collect water-quality data. The NFM provides detailed, comprehensive, and citable procedures for monitoring the quality of surface water and groundwater. Topics in the NFM include (1) methods and protocols for sampling water resources, (2) methods for processing samples for analysis of water quality, (3) methods for measuring field parameters, and (4) specialized procedures, such as sampling water for low levels of mercury and organic wastewater chemicals, measuring biological indicators, and sampling bottom sediment for chemistry. Personnel who collect water-quality data for national USGS programs and projects, including projects supported by USGS cooperative programs, are mandated to use protocols provided in the NFM per USGS Office of Water Quality Technical Memorandum 2002.13. Formal training, for example, as provided in the USGS class, “Field Water-Quality Methods for Groundwater and Surface Water,” and field apprenticeships supplement the guidance provided in the NFM and ensure that the data collected are high quality, accurate, and scientifically defensible.

Techniques and Methods↗

USGS1989

Ground-water quality assessment of the central Oklahoma aquifer, Oklahoma - Analysis of available water-quality data through 1987

Beginning in 1986, the Congress annually has appropriated funds for the U.S. Geological Survey to test and refine concepts for a National Water-Quality Assessment (NAWQA) Program. The long-term goals of a full-scale program would be to: Provide a nationally consistent description of current water-quality conditions for a large part of the Nation's surface- and ground-water resources; Define long-term trends (or lack of trends) in water quality; and Identify, describe, and explain, as possible, the major factors that affect the observed water-quality conditions and trends. The results of the NAWQA Program will be made available to water managers, policy makers, and the public, and will provide an improved scientific basis for evaluating the effectiveness of water-quality management programs. At present (1988), the assessment program is in a pilot phase in seven project areas throughout the country that represent diverse hydrologic environments and water-quality conditions. The Central Oklahoma aquifer project is one of three pilot ground-water projects. One of the initial activities performed by each pilot project was to compile, screen, and interpret the large amount of water-quality data available within each study unit. The purpose of this report is to assess the water quality of the Central Oklahoma aquifer using the information available through 1987. The scope of the work includes compiling data from Federal, State, and local agencies; evaluating the suitability of the information for conducting a regional water-quality assessment; mapping regional variations in major-ion chemistry; calculating summary statistics of the available water-quality data; producing maps to show the location and number of samples that exceeded water-quality standards; and performing contingency-table analyses to determine the relation of geologic unit and depth to the occurrence of chemical constituents that exceed water-quality standards. This report provides an initial description of water-quality conditions in the Central Oklahoma aquifer study unit. No attempt was made in this report to determine the causes for regional variations in major-ion chemistry or to examine the reasons that some chemical constituents exceed water-quality standards.

Oklahoma↗

USGS2019

Alternative stable states in inherently unstable systems

Alternative stable states are nontransitory states within which communities can exist. However, even highly dynamic communities can be viewed within the framework of stable‐state theory if an appropriate “ecologically relevant” time scale is identified. The ecologically relevant time scale for dynamic systems needs to conform to the amount of time needed for a system's community to complete an entire cycle through its normal range of variation. For some systems, the ecologically relevant period can be relatively short (eg, tidal systems), for others it can be decadal (eg, prairie wetlands). We explore the concept of alternative stable states in unstable systems using the highly dynamic wetland ecosystems of North America's Prairie Pothole Region. The communities in these wetland ecosystems transition through multiple states in response to decadal‐long climate oscillations that cyclically influence ponded‐water depth, permanence, and chemistry. The perspective gained by considering dynamic systems in the context of stable‐state theory allows for an increased understanding of how these systems respond to changing drivers that can push them past tipping points into alternative states. Incorporation of concepts inherent to stable‐state theory has been suggested as a key scientific element upon which to base sustainable environmental management.

Alberta, Iowa, Manitoba, Minnesota, Montana, North↗

USGS2023

Storms and pH of dam releases affect downstream phosphorus cycling in an arid regulated river

Reservoirs often bury phosphorus (P), leading to seasonal or persistent reductions in P supply to downstream rivers. Here we ask if observed variation in the chemistry of dam release waters stimulates downstream sediment P release and biological activity in an arid, oligotrophic system, the Colorado River below Lake Powell, Arizona, USA. We use bottle incubations to simulate a range of observed pH (6–8.8) and oxygen (0–9.4 mg L −1 ) levels, with the hypothesis that either oxygen concentrations or pH regulates P release from sediments to the water column. We found support for pH-mediated P release from calcite across the three sites we sampled. The magnitude of this effect was lower in bottles filled with tailwater sediment, but at downriver sites low pH resulted in declining water column dissolved inorganic nitrogen:soluble reactive P (DIN:SRP) ratios, which dropped below the Redfield ratio of 16:1, increasing water column total protein production, and down-regulating alkaline phosphatase production. Additional 7-day incubations showed that tributary storm inputs can temporarily elevate riverine P availability from < 1.5 µg L −1 total dissolved P (TDP) pre-storm to 6.7 µg L −1 TDP post storm. Taken together, our lab incubation and long-term observational results highlight the importance of pH, and ultimately reservoir management and storm dynamics, in regulating P availability and biological processes both now and into the future.

Biogeochemistry↗

USGS2011

Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Coring operations, core sedimentology, and lithostratigraphy

In February 2007, BP Exploration (Alaska), the U.S. Department of Energy, and the U.S. Geological Survey completed the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert well) in the Milne Point Unit on the Alaska North Slope. The program achieved its primary goals of validating the pre-drill estimates of gas hydrate occurrence and thickness based on 3-D seismic interpretations and wireline log correlations and collecting a comprehensive suite of logging, coring, and pressure testing data. The upper section of the Mount Elbert well was drilled through the base of ice-bearing permafrost to a casing point of 594 m (1950 ft), approximately 15 m (50 ft) above the top of the targeted reservoir interval. The lower portion of the well was continuously cored from 606 m (1987 ft) to 760 m (2494 ft) and drilled to a total depth of 914 m. Ice-bearing permafrost extends to a depth of roughly 536 m and the base of gas hydrate stability is interpreted to extend to a depth of 870 m. Coring through the targeted gas hydrate bearing reservoirs was completed using a wireline-retrievable system. The coring program achieved 85% recovery of 7.6 cm (3 in) diameter core through 154 m (504 ft) of the hole. An onsite team processed the cores, collecting and preserving approximately 250 sub-samples for analyses of pore water geochemistry, microbiology, gas chemistry, petrophysical analysis, and thermal and physical properties. Eleven samples were immediately transferred to either methane-charged pressure vessels or liquid nitrogen for future study of the preserved gas hydrate. Additional offsite sampling, analyses, and detailed description of the cores were also conducted. Based on this work, one lithostratigraphic unit with eight subunits was identified across the cored interval. Subunits II and Va comprise the majority of the reservoir facies and are dominantly very fine to fine, moderately sorted, quartz, feldspar, and lithic fragment-bearing to -rich sands. Lithostratigraphic and palynologic data indicate that this section is most likely early Eocene to late Paleocene in age. The examined units contain evidence for both marine and non-marine lithofacies, and indications that the depositional environment for the reservoir facies may have been shallower marine than originally interpreted based on pre-drill wireline log interpretations. There is also evidence of reduced salinity marine conditions during deposition that may be related to the paleo-climate and depositional conditions during the early Eocene.

Alaska↗

USGS1998

The chemical evolution of Kurnub Group palcowater in the Sinai-Negev province - A mass balance approach

The chemical evolution of the Kurnub Group paleowater was studied starting from rainwater in recharge areas of the Sinai and along groundwater flowpaths leading to the natural outlets of this regional aquifer. This was achieved by investigating the chemical composition of groundwater, ionic ratios, degrees of saturation with common mineral species, normative analysis of dissolved salts and by modeling of rock/water interaction and mixing processes occurring along groundwater flow paths. The initial groundwater composition used is from the Nakhel well in Sinai. It evolves from desert rainwater percolating through typical Kurnub Group lithology in Sinai. This rainwater dissolves mainly gypsum, halite and dolomite together with smaller amounts of marine aerosol and K-feldspar. At the same time it precipitates calcite, SiO2, smectite and degasses CO2. Between the area of Nakhel and the northern Negev the chemistry of Kurnub Group waters is influenced by dissolution of halite and lesser amounts of gypsum of surficial origin in recharge areas, small amounts of feldspars and of dolomite cement in sandstones eroded from the Arabo-Nubian igneous massif of Sinai and organic degradation-derived CO2. Concomitantly, there is precipitation of calcite, smectite, SiO2 and probably analcime characteristic of sediments in continental closed basins. North of the Negev, the Kurnub Group fluids are diluted and altered by mixing with Judea Group aquifer groundwaters. On the E there is mixing with residual brines from the water body ancestral to the Dead Sea, prior to discharge into the Arava valley. Rock/water interaction indicated by NETPATH and PHREEQC modeling is in agreement with lithology and facies changes previously observed in the Kurnub Group sequence.

Applied Geochemistry↗

USGS2013

Baseline monitoring of the western Arctic Ocean estimates 20% of the Canadian Basin surface waters are undersaturated with respect to aragonite

Marine surface waters are being acidified due to uptake of anthropogenic carbon dioxide, resulting in surface ocean areas of undersaturation with respect to carbonate minerals, including aragonite. In the Arctic Ocean, acidification is expected to occur at an accelerated rate with respect to the global oceans, but a paucity of baseline data has limited our understanding of the extent of Arctic undersaturation and of regional variations in rates and causes. The lack of data has also hindered refinement of models aimed at projecting future trends of ocean acidification. Here, based on more than 34,000 data records collected in 2010 and 2011, we establish a baseline of inorganic carbon data (pH, total alkalinity, dissolved inorganic carbon, partial pressure of carbon dioxide, and aragonite saturation index) for the western Arctic Ocean. This data set documents aragonite undersaturation in ~20% of the surface waters of the combined Canada and Makarov basins, an area characterized by recent acceleration of sea ice loss. Conservative tracer studies using stable oxygen isotopic data from 307 sites show that while the entire surface of this area receives abundant freshwater from meteoric sources, freshwater from sea ice melt is most closely linked to the areas of carbonate mineral undersaturation. These data link the Arctic Ocean’s largest area of aragonite undersaturation to sea ice melt and atmospheric CO 2 absorption in areas of low buffering capacity. Some relatively supersaturated areas can be linked to localized biological activity. Collectively, these observations can be used to project trends of ocean acidification in higher latitude marine surface waters where inorganic carbon chemistry is largely influenced by sea ice meltwater.

PLoS ONE↗

USGS2010

Cartographic Production for the FLaSH Map Study: Generation of Rugosity Grids, 2008

Project Summary This series of raster data is a U.S. Geological Survey (USGS) Data Series release from the Florida Shelf Habitat Project (FLaSH). This disc contains two raster images in Environmental Systems Research Institute, Inc. (ESRI) raster grid format, jpeg image format, and Geo-referenced Tagged Image File Format (GeoTIFF). Data is also provided in non-image ASCII format. Rugosity grids at two resolutions (250 m and 1000 m) were generated for West Florida shelf waters to 250 m using a custom algorithm that follows the methods of Valentine and others (2004). The Methods portion of this document describes the specific steps used to generate the raster images. Rugosity, also referred to as roughness, ruggedness, or the surface-area ratio (Riley and others, 1999; Wilson and others, 2007), is a visual and quantitative measurement of terrain complexity, a common variable in ecological habitat studies. The rugosity of an area can affect biota by influencing habitat, providing shelter from elements, determining the quantity and type of living space, influencing the type and quantity of flora, affecting predator-prey relationships by providing cover and concealment, and, as an expression of vertical relief, can influence local environmental conditions such as temperature and moisture. In the marine environment rugosity can furthermore influence current flow rate and direction, increase the residence time of water in an area through eddying and current deflection, influence local water conditions such as chemistry, turbidity, and temperature, and influence the rate and nature of sedimentary deposition. State-of-the-art computer-mapping techniques and data-processing tools were used to develop shelf-wide raster and vector data layers. Florida Shelf Habitat (FLaSH) Mapping Project (http://coastal.er.usgs.gov/flash) endeavors to locate available data, identify data gaps, synthesize existing information, and expand our understanding of geologic processes in our dynamic coastal and marine systems.

Data Series↗

USGS2010

Chemistry of selected core samples, concentrate, tailings, and tailings pond waters: Pea Ridge iron (-lanthanide-gold) deposit, Washington County, Missouri

The Minerals at Risk and for Emerging Technologies Project of the U.S. Geological Survey (USGS) Mineral Resources Program is examining potential sources of lanthanide elements (rare earth elements) as part of its objective to provide up-to-date geologic information regarding mineral commodities likely to have increased demand in the near term. As part of the examination effort, a short visit was made to the Pea Ridge iron (-lanthanide-gold) deposit, Washington County, Missouri in October 2008. The deposit, currently owned by Wings Enterprises, Inc. of St. Louis, Missouri (Wings), contains concentrations of lanthanides that may be economic as a primary product or as a byproduct of iron ore production. This report tabulates the results of chemical analyses of the Pea Ridge samples and compares rare earth elements contents for world class lanthanide deposits with those of the Pea Ridge deposit. The data presented for the Pea Ridge deposit are preliminary and include some company data that have not been verified by the USGS or by the Missouri Department of Natural Resources, Division of Geology and Land Survey (DGLS), Geological Survey Program (MGS). The inclusion of company data is for comparative purposes only and does not imply an endorsement by either the USGS or MGS.

Missouri↗

USGS2014

Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013

Wayne County, Pennsylvania, is underlain by the Marcellus Shale, which currently (2014) is being developed elsewhere in Pennsylvania for natural gas. All residents of largely rural Wayne County rely on groundwater for water supply, primarily from bedrock aquifers (shales and sandstones). This study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for Wayne County prior to development of the natural gas resource in the Marcellus Shale. Selected wells completed in the Devonian-age Catskill Formation, undifferentiated; the Poplar Gap and Packerton Members of the Catskill Formation, undivided; and the Long Run and Walcksville Members of the Catskill Formation, undivided, were sampled. Water samples were collected once from 34 domestic wells during August 2011 and August and September 2013 and analyzed to characterize their physical and chemical quality. Samples were analyzed for 45 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. The quality of the sampled groundwater was generally within U.S. Environmental Protection Agency (USEPA) drinking-water standards, although in some samples, the concentrations of a few constituents exceeded USEPA drinking-water standards and health advisories. The pH of water samples ranged from 5.5 to 9.3 with a median of 7.0. The pH was outside the USEPA secondary maximum contaminant level (SMCL) range of 6.5 to 8.5 in water samples from 14 of the 34 wells (41 percent). Eleven samples had a pH less than 6.5, and three samples had a pH greater than 8.5. Dissolved oxygen concentrations ranged from 0.2 to 11.5 milligrams per liter (mg/L) with a median of 4.7 mg/L. The dissolved oxygen concentration was less than 1 mg/L in water samples from 6 wells; 5 of these 6 water samples had a pH greater than 7.7. Concentrations of dissolved methane ranged from less than 0.00006 to 3.3 mg/L. Methane was detectable in 22 of the 34 wells sampled (65 percent). Methane concentrations were greatest in the 5 samples with pH of 7.8 or higher, ranging from 0.040 to 3.3 mg/L. These samples also had among the lowest concentrations of dissolved oxygen. Three water samples, which had sufficient dissolved methane concentrations (greater than 0.9 mg/L), were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell within (two samples) or close to (one sample) the range for a thermogenic natural gas source. The total dissolved solids concentration ranged from 33 to 346 mg/L; the median concentration was 126 mg/L. Sodium concentrations ranged from 1.07 to 116 mg/L; the median concentration was 9.42 mg/L. The sodium concentration exceeded the USEPA health advisory for sodium of 20 mg/L in water samples from 7 of the 34 wells (21 percent). Concentrations of dissolved arsenic ranged from less than 0.06 to 21.8 micrograms per liter (µg/L); the median concentration was 0.59 µg/L. Water samples from 2 of the 34 wells (6 percent) exceeded the USEPA maximum contaminant level (MCL) of 10 µg/L for arsenic. Concentrations of dissolved manganese ranged from less than 0.15 to 61.5 µg/L; the median concentration was 0.42 µg/L. A water sample from 1 of the 34 wells (3 percent) exceeded the USEPA SMCL of 50 µg/L for manganese; the concentration was less than the USEPA lifetime health advisory of 300 µg/L for manganese. Activities of radon-222 in water from the 34 sampled wells ranged from 110 to 7,180 picocuries per liter (pCi/L); the median activity was 2,105 pCi/L. Water samples from 33 of the 34 wells (97 percent) exceeded the proposed USEPA MCL of 300 pCi/L, and 4 water samples (12 percent) exceeded the USEPA proposed alternative MCL of 4,000 pCi/L for radon-222. Differences in groundwater chemistry were related to pH. Water with a pH greater than 7.6 generally had low dissolved oxygen concentrations, indicating reducing conditions in the aquifer. These high pH waters also had relatively elevated concentrations of methane, arsenic, boron, bromide, fluoride, lithium, and sodium but low concentrations of copper, nickel, and zinc. Water samples with a pH greater than 7.8 had methane concentrations equal to or greater than 0.04 mg/L.

Pennsylvania↗

USGS1994

Hydrologic data for the Puerco River basin, western New Mexico, October 1, 1991, through September 30, 1992

Hydrologic data collected during October 1, 1991, through September 30, 1992, in the Puerco River Basin, Western New Mexico, are summarized. The effects of uranium mining and a 1979 tailings pond spill, in combination with naturally occurring and potentially hazardous trace elements, have created a concern that surface water and ground water in the Puerco River Basin may be unsafe for irrigation, livestock watering, and domestic use; therefore, a data collection network was established to monitor the suitability of the water resources in the Puerco River Basin. The data collection network consisted of one streamflow-gaging station, three water-well dusters, and nine streambed sites. The network is located along a reach of the Puerco River beginning near the confluence of the Puerco River and Pipeline Arroyo and ending approximately 9 miles upstream from the New Mexico-Arizona State line. Data tabulated and presented include mean daily discharge, ground-water hydrographs, water quality, and sediment chemistry and particle-size distribution.

Open-File Report↗