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Preliminary evaluations of regional ground-water quality in relation to land use

Preliminary results from New York, New Jersey, Connecticut, Florida, Nebraska, and Colorado indicate that regional ground-water quality has been affected by human activities. The frequencies of detection of volatile organic compounds and some trace elements were larger in ground water underlying urban or industrial areas in comparison to undeveloped areas. Ground water in agricultural areas generally had larger concentrations of nitrate and an increased frequency of detection of pesticides. Effects of human activities on water quality increased as the intensity of urbanization or irrigation increased. Ground-water pumpage, waste-water discharges into a stream that is hydraulically connected to an alluvial aquifer, and consumptive use of ground water affected the ground-water quality in one study area to a greater extent than land-use practices.

Ground Water↗

Water in, no water out—How a rain garden reduced stormwater at City Hall in Gary, Indiana

Introduction Urban stormwater runoff can be an issue in many communities because it may cause flooding, overwhelm sewage treatment plants, and negatively affect water quality in local streams, lakes, and other waterbodies. Stormwater runoff can be controlled by using "green infrastructure," which consists of engineered structures that imitate nature to collect stormwater runoff, reduce the amount of runoff, and improve water quality. In 2014, the city of Gary, Indiana implemented green infrastructure to reduce the negative effects of urban stormwater on Lake Michigan and its tributaries. From November 2016 to June 2017, the mostly impermeable parking lot in front of Gary City Hall was removed and rebuilt with a rain garden. The U.S. Geological Survey studied how the rain garden reduced stormwater runoff and published results in Scientific Investigations Report 2022–5101.

Indiana↗

Hydrogeology and hydrogeologic terranes of the Blue Ridge and Piedmont Physiographic Provinces in the eastern United States

Severe and prolonged droughts between 1961 and 1988, combined with increased demands for freshwater supplies in the United States, have resulted in a critical need to assess the potential for development of ground- and surface-water supplies. Rapid industrial growth and urban expansion have caused existing freshwater supplies to be used at or near maximum capacity. Begun in 1978, the Regional Aquifer-System Analysis (RASA) Program of the U.S. Geological Survey (USGS) is a systematic effort to study a number of the Nation's most important aquifer systems, which, in aggregate, underlie much of the country and represent an important component of the Nation's total water supply. The broad objective for each of the 28 studies in the program is to assemble geologic, hydrologic, and geochemical information, to analyze and develop an understanding of the system, and to develop predictive capabilities that will contribute to the effective management of the system. In 1988, as part of the RASA Program, the USGS began a 6-year study of the ground-water resources of parts of 11 States in the Eastern United States (Swain and others, 1991). The study was designated the Appalachian Valley and Piedmont Regional Aquifer-System Analysis (APRASA). The APRASA team investigated ground-water resources primarily in the unglaciated part of the Valley and Ridge, the Blue Ridge, the New England, and the Piedmont Physiographic Provinces (fig. 1). For the purposes of this report, the small area in the New England Physiographic Province that is within the study area in New Jersey and Pennsylvania was considered part of the Piedmont Physiographic Province. The results of the APRASA are contained in about 50 reports and abstracts, including reports on simulation of ground-water flow in three type areas, this atlas, and chapters in Professional Paper 1422. These chapters include the summary (Chapter A), descriptions of recharge rates and surface- and ground-water relations (Chapter B), hydrogeologic terranes in the Valley and Ridge Physiographic Province (Chapter C), and ground-water geochemistry (Chapter D). The purposes of this atlas are to summarize the hydrogeology, to describe an analysis of maps and well records, and to present a classification and map of the hydrogeologic terranes of the Blue Ridge and Piedmont Physiographic Provinces within the APRASA study area. Hydrogeologic terranes are defined for this atlas as regionally mappable areas characterized by similar water-yielding properties of a grouping of selected rock types. The hydrogeologic terranes represent areas of distinct hydrologic character. The terranes are intended to help water users locate and develop adequate water supplies and to help hydrologists interpret the regional hydrogeology. Previous investigations provide maps and descriptions of the geologic units, describe the local quantity and quality of ground water within these units, and establish the statistical methods for comparing the water-yielding properties of these units. State geologic maps show the distribution of geologic units at a scale of 1:500,000 for Alabama (Osborne and others, 1989), Georgia (Lawton and others, 1976), North Carolina (Brown and Parker, 1985), and Virginia (Calver and Hobbs, 1963). State maps show geologic units at a scale of 1:250,000 for Maryland (Cleaves and others, 1968), New Jersey (Lewis and Kummel, 1912), Pennsylvania (Berg and others, 1980), South Carolina (Overstreet and Bell, 1965), Tennessee (Hardeman, 1966), and West Virginia (Cardwell and others, 1968). Quadrangle geologic maps show geologic units at a scale of 1:24,000 for parts of Delaware within the APRASA area (Woodruff and Thompson, 1972, 1975). Many reports have been published describing the groundwater resources of a county, parts of a county, multi-county areas, or river basins. The statistical methods used in this atlas are based largely on those used by Helsel and Hirsch (1992) and by Knopman (1990, p. 7-9). In her analysis of well records in the USGS Ground-Water Site Inventory (GWSI) data base, Knopman (1990) ranked factors that must be taken into account when assessing the water-yielding potential of the rocks in the Valley and Ridge, the Blue Ridge, and the Piedmont Physiographic Provinces in Pennsylvania. Readers are referred to Helsel and Hirsch (1992) and Knopman (1990) for details regarding statistical methods.

Alabama, Delaware, Georgia, Maryland, New Jersey, ↗

Monitoring Colonias Development along the United States-Mexico Border: A Process Application using GIS and Remote Sensing in Douglas, Arizona, and Agua Prieta, Sonora

The U.S. Department of Housing and Urban Development (HUD) and the U.S. Geological Survey (USGS) have developed a joint project to create Internet-enabled geographic information systems (GIS) that will help cities along the United States-Mexico border deal with issues related to colonias. HUD defines colonias as rural neighborhoods in the United States-Mexico border region that lack adequate infrastructure or housing and other basic services. They typically have high poverty rates that make it difficult for residents to pay for roads, sanitary water and sewer systems, decent housing, street lighting, and other services through assessment. Many Federal agencies recognize colonias designations and provide funding assistance. It is the intention of this project to empower Arizona-Sonora borderland neighborhoods and community members by recognizing them as colonias. This recognition will result in eligibility for available economic subsidies and accessibility to geospatial tools and information for urban planning. The steps to achieve this goal include delineation of colonia-like neighborhoods, identification of their urbanization over time, development of geospatial databases describing their infrastructure, and establishment of a framework for distributing Web-based GIS decision support systems. A combination of imagery and infrastructure information was used to help delineate colonia boundaries. A land-use change analysis, focused on urbanization in the cities over a 30-year timeframe, was implemented. The results of this project are being served over the Internet, providing data to the public as well as to participating agencies. One of the initial study areas for this project was the City of Douglas, Ariz., and its Mexican sister-city Agua Prieta, Sonora, which are described herein. Because of its location on the border, this twin-cities area is especially well suited to international manufacturing and commerce, which has, in turn, led to an uncontrolled spread of colonias. The USGS worked with local organizations in developing the Web-based GIS database. Community involvement ensured that the database and map server would meet the current and long-term needs of the communities and end users. Partners include Federal agencies, State agencies, county officials, town representatives, universities, and youth organizations, as well as interested local advocacy groups and individuals. A significant component of this project was development of relationships and partnerships in the border towns for facilitating binational approaches to land management.

Open-File Report↗

Changes in nutrient and pesticide concentrations in urban and agricultural areas of the South Platte River Basin, Colorado, Wyoming, and Nebraska, 1994–2000

As part of the National Water-Quality Assessment (NAWQA) Program, the U.S. Geological Survey (USGS) monitored two sites on the main-stem South Platte River? an urban site in Denver and a mixed urban/agricultural site near Kersey?to determine changes in nutrient and pesticide concentrations from 1994 through 2000. Concentrations of nitrate, nitrite, ammonia, and orthophosphorus decreased at the Denver site during the study period, likely due to an increase in instream dilution of wastewater-treatment plant (WWTP) discharge and upgrades at the WWTPs. In contrast, only concentrations of orthophosphorus decreased at the Kersey site; agricultural inputs between Denver and Kersey may have offset the observed decreases in other nutrients upstream. During the extreme low-flow conditions in 1994, when there was relatively little snowmelt to dilute instream pesticide concentrations, total median pesticide concentrations at both sites were the highest of the study period. During the less extreme conditions in 1997 through 2000, greater amounts of snowmelt likely led to lower total median pesticide concentrations at both sites. Because pesticide-use data are not available, the contribution of changes in the amount and type of pesticides applied on the land to changes in the concentration of pesticides in the river is not known but likely was substantial. In general, insecticides predominated at the Denver site, whereas herbicides predominated at the Kersey site.

Colorado, Nebraska, Wyoming↗

Storm surge propagation and flooding in small tidal rivers during events of mixed coastal and fluvial influence

The highly urbanized estuary of San Francisco Bay is an excellent example of a location susceptible to flooding from both coastal and fluvial influences. As part of developing a forecast model that integrates fluvial and oceanic drivers, a case study of the Napa River and its interactions with the San Francisco Bay was performed. For this application we utilize Delft3D-FM, a hydrodynamic model that computes conservation of mass and momentum on a flexible mesh grid, to calculate water levels that account for tidal forcing, storm surge generated by wind and pressure fields, and river flows. We simulated storms with realistic atmospheric pressure, river discharge, and tidal forcing to represent a realistic joint fluvial and coastal storm event. Storm conditions were applied to both a realistic field-scale Napa river drainage as well as an idealized geometry. With these scenarios, we determine how the extent, level, and duration of flooding is dependent on these atmospheric and hydrologic parameters. Unsurprisingly, the model indicates that maximal water levels will occur in a tidal river when high tides, storm surge, and large fluvial discharge events are coincident. Model results also show that large tidal amplitudes diminish storm surge propagation upstream and that phasing between peak fluvial discharges and high tide is important for predicting when and where the highest water levels will occur. The interactions between tides, river discharge, and storm surge are not simple, indicating the need for more integrated flood forecasting models in the future.

California↗

Spatial and temporal patterns in concentrations of perfluorinated compounds in bald eagle nestlings in the Upper Midwestern United States

Perfluorinated chemicals (PFCs) are of concern due to their widespread use, persistence in the environment, tendency to accumulate in animal tissues, and growing evidence of toxicity. Between 2006 and 2011 we collected blood plasma from 261 bald eagle nestlings in six study areas from the upper Midwestern United States. Samples were assessed for levels of 16 different PFCs. We used regression analysis in a Bayesian framework to evaluate spatial and temporal trends for these analytes. We found levels as high as 7370 ng/mL for the sum of all 16 PFCs (∑PFCs). Perfluorooctanesulfonate (PFOS) and perfluorodecanesulfonate (PFDS) were the most abundant analytes, making up 67% and 23% of the PFC burden, respectively. Levels of ∑PFC, PFOS, and PFDS were highest in more urban and industrial areas, moderate on Lake Superior, and low on the remote upper St. Croix River watershed. We found evidence of declines in ∑PFCs and seven analytes, including PFOS, PFDS, and perfluorooctanoic acid (PFOA); no trend in two analytes; and increases in two analytes. We argue that PFDS, a long-chained PFC with potential for high bioaccumulation and toxicity, should be considered for future animal and human studies.

Minnesota, Wisconsin↗

Preliminary hydrogeologic assessment and study plan for a regional ground-water resource investigation of the Blue Ridge and Piedmont provinces of North Carolina

Prolonged drought, allocation of surface-water flow, and increased demands on ground-water supplies resulting from population growth are focuses for the need to evaluate ground-water resources in the Blue Ridge and Piedmont Provinces of North Carolina. Urbanization and certain aspects of agricultural production also have caused increased concerns about protecting the quality of ground water in this region. More than 75 percent of the State's population resides in the Blue Ridge and Piedmont Provinces in an area that covers 30,544 square miles and 65 counties. Between 1940 and 2000, the population in the Piedmont and Blue Ridge Provinces increased from 2.66 to 6.11 million; most of this increase occurred in the Piedmont. Of the total population, an estimated 1.97 million people, or 32.3 percent (based on the 1990 census), relied on ground water for a variety of uses, including commercial, industrial, and most importantly, potable supplies. Ground water in the Blue Ridge and Piedmont traditionally has not been considered as a source for large supplies, primarily because of readily available and seemingly limitless surface-water supplies, and the perception that ground water in the Blue Ridge and Piedmont Provinces occurs in a complex, generally heterogeneous geologic environment. Some reluctance to use ground water for large supplies derives from the reputation of aquifers in these provinces for producing low yields to wells, and the few high-yield wells that are drilled seem to be scattered in areas distant from where they are needed. Because the aquifers in these provinces are shallow, they also are susceptible to contamination by activities on the land surface. In response to these issues, the North Carolina Legislature supported the creation of a Resource Evaluation Program to ensure the long-term availability, sustainability, and quality of ground water in the State. As part of the Resource Evaluation Program, the North Carolina Division of Water Quality, Groundwater Section, in cooperation with the U.S. Geological Survey, initiated a multiyear study of ground water in the Blue Ridge and Piedmont Provinces. The study began in 1999. Most of the study area is underlain by a complex, two-part, regolith-fractured crystalline rock aquifer system. Thickness of the regolith throughout the study area is highly variable and ranges from 0 to more than 150 feet. The regolith consists of an unconsolidated or semiconsolidated mixture of clay and fragmental material ranging in grain size from silt to boulders. Because porosities range from 35 to 55 percent, the regolith provides the bulk of the water storage within the Blue Ridge and Piedmont ground-water system. At the base of the regolith is the transition zone where saprolite grades into unweathered bedrock. The transition zone has been identified as a potential conduit for rapid ground-water flow. If this is the case, the transition zone also may serve as a conduit for rapid movement of contaminants to nearby wells or to streams with channels that cut into 1 U.S. Geological Survey, Raleigh, North Carolina. 2 North Carolina Department of Environment and Natural Resources, Division of Water Quality, Groundwater Section. or through the transition zone. How rapidly a contaminant moves through the system largely may be a function of the characteristics of the transition zone. The transition zone is one of several topics identified during the literature review and data synthesis, for which there is a deficiency in data and understanding of the processes involved in the movement of ground water to surface water. Because the Blue Ridge and Piedmont study area is so large, and the hydrogeology diverse, it is not feasible to study all of the area in detail. A more feasible approach is to select areas that are most representative of the land use, geology, and hydrology to obtain an understanding of the hydrologic processes in the selected areas, and transfer the knowledge from these local "type areas" to similar regional hydrogeologic areas. For the purpose of this study, the term "type area" applies to a 10- to 100-square mile area within a hydrogeologic terrane where information is sufficient to develop and test a concept of ground-water flow by using analytical or numerical methods that can be validated by field measurements. Ideally, these type areas are selected to be representative of the flow system that is present wherever a particular hydrogeologic terrane is present. This report consists of two basic parts. The first part describes the results of a comprehensive review and synthesis of information and literature that provides the basic background for the study. This includes current (2002) knowledge regarding general geology and the hydrogeologic framework of the fractured-rock aquifer system that underlies the Blue Ridge and Piedmont Provinces. In spite of the quantity of information identified during the literature review and the amount of past work that has been documented, there are still research needs to be met. The second part of the report describes State ground-water issues and problems, available data, and data deficiencies. It also describes the design and implementation of efforts to characterize ground-water quality and to quantify factors that influence the movement and availability of ground water in the hydrogeologic terranes characterized by (1) massive or foliated crystalline rocks overlain by thick regolith and (2) massive or foliated crystalline rocks overlain by thin regolith. As of September 2001, seven sites had been identified as potential study sites to be used to characterize the hydrogeology and water quality of ype areas considered representative of the larger terranes. Detailed geologic mapping, core drilling, well installation, and surface and borehole geophysical surveys are in progress at four of the sites.

North Carolina↗

Low-flow frequency and flow duration of selected South Carolina streams in the Savannah and Salkehatchie River Basins through March 2014

An ongoing understanding of streamflow characteristics of the rivers and streams in South Carolina is important for the protection and preservation of the State’s water resources. Information concerning the low-flow characteristics of streams is especially important during critical flow periods, such as during the historic droughts that South Carolina has experienced in the past few decades. In 2008, the U.S. Geological Survey, in cooperation with the South Carolina Department of Health and Environmental Control, initiated a study to update low-flow statistics at continuous-record streamgaging stations operated by the U.S. Geological Survey in South Carolina. This report presents the low-flow statistics for 28 selected streamgaging stations in the Savannah and Salkehatchie River Basins in South Carolina. The low-flow statistics include daily mean flow durations for the 5-, 10-, 25-, 50-, 75-, 90-, and 95-percent probability of exceedance and the annual minimum 1-, 3-, 7-, 14-, 30-, 60-, and 90-day mean flows with recurrence intervals of 2, 5, 10, 20, 30, and 50 years, depending on the length of record available at the streamgaging station. The low-flow statistics were computed from records available through March 31, 2014. Low-flow statistics are influenced by length of record, hydrologic regime under which the data were collected, analytical techniques used, and other factors, such as urbanization, diversions, and droughts that may have occurred in the basin. To assess changes in the low-flow statistics from the previously published values, a comparison of the low-flow statistics for the annual minimum 7-day average streamflow with a 10-year recurrence interval (7Q10) from this study was made with the most recently published values. Of the 28 streamgaging stations for which recurrence interval computations were made, 14 streamgaging stations were suitable for comparing to low-flow statistics that were previously published in U.S. Geological Survey reports. These comparisons indicated that seven of the streamgaging stations had values lower than the previous values, two streamgaging stations had values higher than the previous values, and two streamgaging stations had values that were unchanged from previous values. The remaining three stations for which previous 7Q10 values were computed, which are located on the main stem of the Savannah River, were not compared with current estimates because of differences in the way the pre-regulation and regulated flow data were analyzed.

South Carolina↗

Status of water quality in groundwater resources used for drinking-water supply in the southeastern San Joaquin Valley, 2013–15—California GAMA Priority Basin Project

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) investigated water quality of groundwater resources used for drinking-water supplies in the Madera-Chowchilla, Kings, Kaweah, Tule, and Tulare Lake groundwater subbasins of the southeastern San Joaquin Valley during 2013–15. The study focused primarily on groundwater resources used for domestic-supply wells in the southeastern San Joaquin Valley (SESJV-D), which correspond mostly to shallower parts of aquifer systems, compared to the groundwater resources used for public-supply wells in the southeastern San Joaquin Valley (SESJV-P). The investigation had three components: (1) characterization of the status of water quality in the SESJV-D, (2) comparison between water quality in the SESJV-D and SESJV-P, and (3) identification of natural and anthropogenic factors that potentially could affect water quality in these resources. The characterization of water quality in the SESJV-D was based on data collected from 198 domestic wells sampled during 2013–15 by the U.S. Geological Survey (USGS); characterization of water quality in the SESJV-P was based on data collected from 124 wells sampled by the USGS during 2005–18 and an additional 1,577 wells with publicly available data reported to the California State Water Resources Control Board Division of Drinking Water (SWRCB-DDW). Measured concentrations were compared to regulatory and non-regulatory drinking-water quality benchmarks. A grid-based method was used to estimate the areal proportions of each study area and the whole southeastern San Joaquin Valley with high (greater than benchmark concentration), moderate (greater than half of the benchmark for inorganic and one-tenth of the benchmark for organic), and low concentrations relative to those benchmarks. Natural and anthropogenic factors that could affect groundwater quality for the SESJV-D were identified in the context of the hydrogeologic setting of the southeastern San Joaquin Valley. The considered factors represented hydrologic conditions and position in the groundwater flow system (well depth, lateral position, presence of hydric soils, percentage of coarse-grained sediment, and aridity index), land-use characteristics (percentages of agricultural, urban, and natural land use, percentage of orchard or vineyard land use, and densities of septic tanks and underground storage tanks near the wells), and geochemical conditions (groundwater age class, oxidation-reduction class, pH, and dissolved oxygen and bicarbonate concentrations). Factors are compared between SESJV-D and SESJV-P at the scale of the five study areas. One or more inorganic constituents with U.S. Environmental Protection Agency (EPA) or California maximum contaminant levels (MCLs) were detected at high concentrations in 47 percent of the SESJV-D and in 32 percent of the SESJV-P. The inorganic constituents most commonly present at high concentrations in the SESJV-D were nitrate, uranium, and arsenic. Within the SESJV-D, the proportion of the study area with high concentrations of inorganic constituents ranged from 19 percent in Madera-Chowchilla to 60 percent in Kings and Tulare Lake. One or more inorganic constituents with California State Water Resources Control Board Division of Drinking Water secondary maximum contaminant levels (SMCL-CAs) were detected at high concentrations in 14 percent of the SESJV-D and in 19 percent of the SESJV-P. The constituents most commonly present at high concentrations were manganese, iron, and total dissolved solids (TDS). Although the proportion of SESJV-D and SESJV-P with high concentrations of TDS greater than the upper SMCL were similar at 4 percent, the proportion of the SESJV-D with moderate concentrations (between the recommended and upper SMCL-CA), 30 percent, was greater than the proportion of the SESJV-P with moderate concentrations, 12 percent. One or more organic constituents with MCLs were present at high concentrations in 19 percent of the SESJV-D and in 12 percent of the SESJV-P. All the constituents detected at high concentrations in the SESJV-D were fumigants, primarily 1,2,3-trichloropropane (1,2,3-TCP) and 1,2-dibromo-3-chloropropane (DBCP). Fumigants also were the constituents most commonly detected at high concentrations in the SESJV-P, although high concentrations of solvents also were detected. The SESJV-D dataset included analysis of many organic constituents without MCL benchmarks and with detection levels far below drinking water benchmark concentrations; detections at these low concentrations can be used as tracers of anthropogenic influence on groundwater. Pesticides and degradates of pesticides were detected in 60 percent of the SESJV-D; the most frequently detected pesticides were the herbicides simazine, didealkylatrazine (CAAT, a degradate of simazine and atrazine), diuron, and bromacil.

California↗

Stream restoration milestones: Monitoring scales determine successes and failures

Urban stream restoration is growing globally, but there is much to learn from successes, failures, and evaluating tradeoffs in restoration practices. Significant time and resources have been invested towards restoring the structure and function of urban ecosystems and understanding and slowing the drivers of degradation. However, the rapid pace of urbanization and its effects on urban waters present an ever-growing challenge to environmental managers and restoration practitioners when identifying and prioritizing effective strategies for restoration and monitoring outcomes. Here, we synthesize major findings and papers originating from the 5th Symposium on Urbanization and Stream Ecology (SUSE5) and propose a new concept for monitoring restoration based on lessons learned. Efforts from SUSE5 showed that urban disturbances and restoration activities have strong localized impacts that can be challenging to detect and disentangle across broader watershed scales and longitudinal flowpaths. Most urban stream restoration projects are monitored at only one or a few locations that do not capture significant variability across stream reaches and longer flowpaths. Based on knowledge from SUSE5, we present a new concept called ‘restoration milestones.’ The restoration milestones concept proposes that the scale of stream monitoring over space and time can influence whether a stream restoration project is considered a success or failure. Therefore, answers to questions regarding restoration effectiveness and durability can be affected by spatial and temporal monitoring scales. Setting realistic restoration milestones involves establishing monitoring strategies that account for spatial and temporal variability. Tracking restoration performance through time across stream reaches along longitudinal flowpaths could aid in more accurately assessing project performance. We explore applications for evaluating restoration milestones along longitudinal stream flowpaths including: (1) identifying target areas of improvement along drainage networks, (2) accurately accounting for tradeoffs in habitat, protection of infrastructure, and water quality along flowpaths, and (3) detecting how far downstream the effects of stream restoration and stormwater management can be propagated. Monitoring across different spatial and temporal scales is an overlooked but critical factor in determining restoration success. Additionally, the scale of the restoration project itself can determine the type and magnitude of improvements. Expectations for what a restoration project can accomplish in terms of water quality improvements should be calibrated to the project’s spatial scale and evolution over time. Longitudinal studies of stream restoration help identify successes and failures along flowpaths.

Urban Ecosystems↗

Remotely mapping gullying and incision in Maryland Piedmont headwater streams using repeat airborne lidar

Headwater streams can contribute significant amounts of fine sediment to downstream waterways, especially when severely eroded and incised. Potential upstream sediment source identification is crucial for effective management of water quality, aquatic habitat, and sediment loads in a watershed. This study explored topographic openness (TO) derived from 1-m lidar for its ability to predict incision in headwater streams and to remotely detect changes in incision over time. Field surveys were conducted in one forested and two recently urbanized headwater watersheds in the Maryland Piedmont physiographic province, USA to characterize the level of stream channel incision (none, moderate, or severe) in the main stem of each watershed. Predictions of the severity of stream channel incision derived from TO were compared against the field surveys. Channel incision was detected with an overall accuracy of 67 %, with best performance in reaches with either severe or no incision (79–86 % accuracy). The method was also applied to repeat lidar collected over the same area to model the extent of channel incision in 2002 before urban development began and in 2008 and 2013 during active construction in the urban watersheds. Results showed increasing incision over time in all three watersheds, with similar patterns in the forested and urban watersheds. This new method of remotely measuring channel incision can be used to identify potential sediment sources across a watershed, enhance water and habitat quality predictions, and detect changes over time where multiple years of overlapping lidar are available.

Maryland↗

A review of benthic faunal surveys in San Francisco Bay

During the past 60 years, considerable effort has been expended in studies of the relations of the biotic community and physicochemical characteristics of San Francisco Bay water. In very recent years these studies have emphasized the relations between the 'state of health' of bottom-living invertebrates (the benthos) and the levels of pollutants in the bay. Benthic organisms, generally sessile, are unable to escape deleterious environmental changes, and they reflect these changes in alterations of normal species composition of assemblages and species abundance. Data that expands understanding of these relations in urbanized areas such as San Francisco Bay are critical. Because of the implications of such data in control of water quality, the U.S. Geological Survey undertook a review of the results and major conclusions of San Francisco Bay benthic surveys. The size and species composition of faunal assemblages are largely controlled by the salinity of the water, the texture of the bottom sediments, and locally by wastes discharged into the bay. Efforts to describe the structure and function of benthic communities of the bay and to quantify the effects of waste discharge on them have been hampered by inconsistent and often faulty sampling methodology and species identification. Studies made show a lack of information on the normal life processes of the organisms concerned. The diversity index (a mathematical expression of the number of kinds of organisms present at a location), commonly used to describe the 'health' of the benthic community, has been employed without regard for the need for standardizing methodology and species identifications or for understanding natural biological processes that affect such mathematical indices. There are few reliable quantitative data on the distribution of benthic organisms in San Francisco Bay with which future assessments of the 'health' of the benthic community might be compared. Methods for study of the benthos must be standardized, identifications of species verified by trained taxonomists, and new field and laboratory studies undertaken before we can expect to obtain an accurate description of the benthic fauna and its relations with the environment.

Circular↗

Experimental shifts of hydrologic residence time in a sandy urban stream sediment-water interface alter nitrate removal and nitrous oxide fluxes

The sediment–water interfaces (SWI) of streams serve as important biogeochemical hotspots in watersheds and contribute to whole-catchment reactive nitrogen budgets and water-quality conditions. Recently, the SWI has been identified as an important source of nitrous oxide (N 2 O) produced in streams, with SWI residence time among the principal controls on its production. Here, we conducted a series of controlled manipulations of SWI exchange in an urban stream that has high dissolved N 2 O concentrations and where we concurrently evaluated less-mobile porosity dynamics. Our experiments took place within isolated portions of two sediment types: a coarse sandy stream bed resulting from excess road-sand application in the watershed, and a coarse sand mixed with clay and organic particles. In these manipulation experiments we systematically varied SWI vertical-flux rates and residence times to evaluate their effect on the fate of nitrate and production rates of N 2 O. Our experiments demonstrate that the fate and transport of nitrate and N 2 O production are influenced by hydrologic flux rates through SWI sediments and associated residence times. Specifically, we show that manipulations of hydrologic flux systematically shifted the depth of the bulk oxic–anoxic interface in the sediments, and that nitrate removal increased with residence time. Our results also support the emerging hypothesis of a ‘Goldilocks’ timescale for the production of nitrous oxide, when transport and reaction timescales favor incomplete denitrification. Areal N 2 O production rates were up to threefold higher during an intermediate residence-time experiment, compared to shorter or longer residence times. In our companion study we documented that the studied sediments were dominated by a long-residence-time less-mobile porosity domain, which could explain why we observed N 2 O production even in bulk-oxic sediments. Overall, we have experimentally demonstrated that changes to SWI hydrologic residence times and SWI substrate associated with urbanization can change the biogeochemical function of the river corridor.

Massachusetts↗

A nationwide evaluation of crowd-sourced ambient temperature data

Growing concerns about heat in urban areas paired with the sparsity of weather stations have resulted in individuals drawing on data from citizen science sensor networks to fill in data gaps. The PurpleAir are the most widely-used low-cost air quality sensors in the contiguous United States with 14,777 deployed between 1 Jan 2017 and 20 July 2021. Although the air quality data from PurpleAir sensors have been widely studied, less attention has been paid to reported temperature. We compare temperature metrics reported by PurpleAir sensors with a gridded temperature product, the North American Land Data Assimilation System (NLDAS)-2, which although not a gold-standard measure of temperature, is widely used in epidemiologic research. We evaluate the lag between indoor and outdoor PurpleAir temperatures. We report associations of the difference between outdoor PurpleAir temperatures and NLDAS-2 temperatures, an indicator of degradation, and the duration of sensor operation. Finally, based on the temperature range recorded by the outdoor PurpleAir sensors vis.a.vis NLDAS-2 temperatures, we provide a list of 271 (2.5%) sensors potentially misclassified as outdoor and likely located indoors. We observed that outdoor PurpleAir sensors agreed well with NLDAS-2 (R2 > 0.82). This association broke down under warm conditions (daily average NLDAS ≥ 21.1oC). Landcover and climate zone were significant modifiers of the association between PurpleAir and NLDAS-2 temperature metrics with the poorest PurpleAir- NLDAS-2 agreement in urban areas. Indoor PurpleAir temperatures lagged hourly NLDAS temperatures by two hours across almost all climate zones. The mean difference in hourly PurpleAir and NLDAS-2 temperatures increased by 0.57oC for every operational year, suggesting that careful attention must be paid to degradation. Overall, we find for use in epidemiological studies, that the PurpleAir sensor data is a reliable metric of daytime mean air temperature, but researchers should be aware of its limitations when examining extreme heat, or when aggregating sensor data across multiple years.

Frontiers of Environmental Science and Engineering↗

The quality of our nation's waters: Nutrients in the nation's streams and groundwater, 1992-2004

National Findings and Their Implications Although the use of artificial fertilizer has supported increasing food production to meet the needs of a growing population, increases in nutrient loadings from agricultural and, to a lesser extent, urban sources have resulted in nutrient concentrations in many streams and parts of aquifers that exceed standards for protection of human health and (or) aquatic life, often by large margins. Do NAWQA findings substantiate national concerns for aquatic and human health? National Water-Quality Assessment (NAWQA) findings indicate that nutrient concentrations in streams and groundwater in basins with significant agricultural or urban development are substantially greater than naturally occurring or “background” levels. For example, median concentrations of total nitrogen and phosphorus in agricultural streams are about 6 times greater than background levels. Findings also indicate that concentrations in streams routinely were 2 to 10 times greater than regional nutrient criteria recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic life. Such large differences in magnitude suggest that significant reductions in sources of nutrients, as well as greater use of land management strategies to reduce the transport of nutrients to streams, are needed to meet recommended criteria for streams draining areas with significant agricultural and urban development. Nitrate concentrations above the Federal drinking-water standard—or Maximum Contaminant Level (MCL)—of 10 milligrams per liter (mg/L, as nitrogen) are relatively uncommon in samples from streams used for drinking water or from relatively deep aquifers; the MCL is exceeded, however, in more than 20 percent of shallow (less than 100 feet below the water table) domestic wells in agricultural areas. This finding raises concerns for human health in rural agricultural areas where shallow groundwater is used for domestic supply and may warn of future contamination of deeper groundwater pumped from public‑supply wells. Are levels of nutrients in water increasing or decreasing? A decadal assessment of trends in concentrations of nitrogen and phosphorus from about 1993 to 2003 shows minimal changes in those concentrations in the majority of studied streams across the Nation, and more upward than downward trends in concentrations at sites with changes. These findings underscore the need for reductions in nutrient inputs or management strategies that would reduce transport of nutrients to streams. Upward trends were evident among all land uses, including those only minimally affected by agricultural and (or) urban development, which suggests that additional protection of some of our Nation’s most pristine streams warrants consideration. The median of nitrate concentrations in groundwater from 495 wells also increased significantly from 3.2 to 3.4 mg/L (6 percent) during about the same period, and the proportion of wells with concentrations of nitrate greater than the MCL increased from 16 to 21 percent. Nitrate concentrations in water in deep aquifers are likely to increase during the next decade as shallow groundwater with elevated concentrations moves downward. The potential for future contamination of the deep aquifers requires attention because these aquifers commonly are used for public water supply, and because restoration of groundwater is costly and difficult. Long-term and consistent monitoring of nutrients, improved accounting of nutrient sources, and improved tracking and modeling of climatic and landscape changes will be essential for distinguishing trends in nutrient concentrations, understanding the causes of those trends, and accurately tracking the effectiveness of strategies implemented to manage nutrients.

Circular↗

Nutrients and organic compounds in Deer Creek and south branch Plum Creek in southwestern Pennsylvania, April 1996 through September 1998

This report presents results of an analysis of nutrient and pesticide data from two surface-water sites and volatile organic compound (VOC) data from one of the sites that are within the Allegheny and Monongahela River Basins study unit of the National Water-Quality Assessment Program of the U.S. Geological Survey. The Deer Creek site was located in a 27.0 square-mile basin within the Allegheny River Basin in Allegheny County. The primary land uses consist of small urban areas, large areas of residential housing, and some agricultural land in the upper part of the basin. The South Branch Plum Creek site was located in a 33.3 square-mile basin within the Allegheny River Basin in Indiana County. The primary land uses throughout this basin are mostly agriculture and forestland. Water samples for analysis of nutrients were collected monthly and during high-flow events from April 1996 through September 1998. Concentrations of dissolved nitrite, dissolved ammonia plus organic nitrogen, and dissolved phosphorus were less than the method detection limits in more than one-half of the samples collected. The median concentration of dissolved nitrite plus nitrate in South Branch Plum Creek was 0.937 mg/L and 0.597 mg/L in Deer Creek. The median concentration of dissolved orthophosphate was 0.01 mg/L in both streams. High loads of nitrate were measured in both streams from March to June. Concentrations of dissolved ammonia nitrogen, dissolved nitrate, and total phosphorus were lower during the summer months. Measured concentrations of nitrate nitrogen in both streams were well below the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 10 mg/L. Water samples for analysis of pesticides were collected throughout 1997 in both streams and during a storm event on August 25-26, 1998, in Deer Creek. Samples were collected monthly at both sites and more frequently during the spring and early summer months to coincide with application of pesticides. Seventy-eight pesticides and 7 pesticide metabolites were analyzed in 31 samples collected in Deer Creek and in 18 samples collected in South Branch Plum Creek. Of the 85 pesticides and pesticide metabolites analyzed, 25 of the pesticides were detected at least once in Deer Creek, and 20 of the pesticides were detected at least once in South Branch Plum Creek. Atrazine was the most commonly detected pesticide in both streams. There was a distinct seasonal pattern of atrazine, simazine, and metolachlor concentrations measured at both sites. Prometon was detected in 3 of the 18 samples collected in South Branch Plum Creek in 1997 and in 28 of the 31 samples collected in Deer Creek in both 1997 and 1998. Prometon generally is applied in conjunction with asphalt paving projects and is commonly used in residential areas. The highest measured concentrations of prometon detected in Deer Creek were in the five storm samples collected on August 25-26, 1998. At the Deer Creek site, 9 of the 25 pesticides detected throughout the study were detected only in the sample collected on June 13, 1997. Those nine pesticides included acifluorfen, bentazon, bromoxynil, dicamba, dichlorprop, fenuron, linuron, MCPA, and neburon. Nine other pesticides also were detected in that sample. All concentrations of pesticides were well below established drinking-water guidelines. The maximum measured concentration of diazinon in Deer Creek (0.097 µg/L) and South Branch Plum Creek (0.974 µg/L) exceeded the aquatic life guideline of 0.009 µg/L established by the National Academy of Sciences/National Academy of Engineers. The maximum measured concentration of azinphos-methyl in South Branch Plum Creek (an estimated value of 0.033 µg/L) exceeded the chronic aquatic-life guideline of 0.01 µg/L established by the USEPA. Twenty-five samples were collected from Deer Creek and analyzed for volatile organic compounds (VOCs). Of 87 VOCs analyzed for, 22 were detected at least once, and 12 were gasoline-related compounds. Acetone, benzene, carbon disulfide, meta/paraxylene, methyl chloride, MTBE, p-isopropyl toluene, toluene, and 1,2,4-trimethylbenzene were each detected in five or more samples. VOCs generally were detected during the colder winter months and not frequently during the summer months. The maximum measured concentrations of benzene, ethylbenzene, o-dichlorobenzene, styrene, and toluene were two or more orders of magnitude lower than the MCLs established by the USEPA.

Pennsylvania↗

Effects of urbanization, and habitat composition on site occupancy of two snake species using regional monitoring data from southern California

Detection data from a regional, reptile-monitoring program conducted by the U.S. Geological Survey were analyzed to understand the effects of urbanization and habitat composition on site occupancy of the coachwhip ( Masticophis flagellum ) and striped racer ( M. lateralis ) in coastal southern California. Likelihood-based occupancy models indicated striped racers responded to habitat composition, favoring scrub-dominated sites. Coachwhips also responded to habitat composition, favoring open habitats. However, unlike racers, coachwhip spatial population dynamics were strongly associated with the fragmentation and isolation of natural areas caused by urbanization. The odds of coachwhips occupying a site were 64 times greater in large connected areas than the most urbanized and fragmented sites. For coachwhips within urbanized and fragmented sites, the odds of extinction were 10 times greater and odds of colonization were five times lower than in large connected sites. Observed differences between both species in habitat use and specificity are supported by telemetry studies and corroborate existing knowledge of historical patterns of occurrence within the region. Movement data on the coachwhip and striped racer indicate the coachwhip is a wider-ranging species with a greater propensity to encounter roads and other edge environments. Collectively, the results suggest there is widespread loss of the coachwhip from the region, and that long-term persistence of remaining populations is dependent on metapopulation dynamics. The substantially different response of the two species to land-use change serves as a caution against the casual use of closely related species as surrogates in the development of species-specific conservation plans.

California↗