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USGS2015

Magmatism and Epithermal Gold-Silver Deposits of the Southern Ancestral Cascade Arc, Western Nevada and Eastern California

Many epithermal gold-silver deposits are temporally and spatially associated with late Oligocene to Pliocene magmatism of the southern ancestral Cascade arc in western Nevada and eastern California. These deposits, which include both quartz-adularia (low- and intermediate-sulfidation; Comstock Lode, Tonopah, Bodie) and quartz-alunite (high-sulfidation; Goldfield, Paradise Peak) types, were major producers of gold and silver. Ancestral Cascade arc magmatism preceded that of the modern High Cascades arc and reflects subduction of the Farallon plate beneath North America. Ancestral arc magmatism began about 45 Ma, continued until about 3 Ma, and extended from near the Canada-United States border in Washington southward to about 250 km southeast of Reno, Nevada. The ancestral arc was split into northern and southern segments across an inferred tear in the subducting slab between Mount Shasta and Lassen Peak in northern California. The southern segment extends between 42°N in northern California and 37°N in western Nevada and was active from about 30 to 3 Ma. It is bounded on the east by the northeast edge of the Walker Lane. Ancestral arc volcanism represents an abrupt change in composition and style of magmatism relative to that in central Nevada. Large volume, caldera-forming, silicic ignimbrites associated with the 37 to 19 Ma ignimbrite flareup are dominant in central Nevada, whereas volcanic centers of the ancestral arc in western Nevada consist of andesitic stratovolcanoes and dacitic to rhyolitic lava domes that mostly formed between 25 and 4 Ma. Both ancestral arc and ignimbrite flareup magmatism resulted from rollback of the shallowly dipping slab that began about 45 Ma in northeast Nevada and migrated south-southwest with time. Most southern segment ancestral arc rocks have oxidized, high potassium, calc-alkaline compositions with silica contents ranging continuously from about 55 to 77 wt%. Most lavas are porphyritic and contain coarse plagioclase ± hornblende, biotite, and pyroxene phenocrysts. Seven epithermal gold-silver deposits with >1 Moz gold production, several large elemental sulfur deposits, and many large areas (10s to >100 km2) of hydrothermally altered rocks are present in the southern ancestral arc, especially south of latitude 40°N. These deposits are principally hosted by intermediate to silicic lava dome complexes; only a few deposits are associated with mafic- to intermediate-composition stratovolcanoes. Large deposits are most abundant and well developed in volcanic fields whose evolution spanned millions of years. Most deposits are hundreds of thousands to several million years younger than their host rocks, although some quartz-alunite deposits are essentially coeval with their host rocks. Variable composition and thickness of crustal basement is the primary control on mineralization along the length of the southern ancestral arc; most deposits and large alteration zones are localized in basement rock terranes with a strong continental affinity, either along the edge of the North American craton (Goldfield, Tonopah) or in an accreted terrane with continental affinities (Walker Lake terrane; Aurora, Bodie, Comstock Lode, Paradise Peak). Epithermal deposits and quartz-alunite alteration zones are scarce to absent in the northern part of the ancestral arc above an accreted island arc (Black Rock terrane) or unknown basement rocks (Modoc Plateau). Walker Lane structures and areas that underwent large magnitude extension during the Late Cenozoic (areas with Oligocene-early Miocene volcanic rocks dipping >40°) do not provide regional control on mineralization. Instead, these features may have served as local-scale conduits for mineralizing fluids.

Eastern California and Western Nevada↗

USGS1961

Tephroite in California manganese deposits

Recent studies of manganese deposits and mineral specimens in the Sierran belt of sedimentary rocks as well as in the Klamath Mountains to the north and in the Rand Mountains to the south, have shown the presence of tephroite , the orthosilicate of manganese (Mn2Si04), at numerous localities. Earlier studies of these deposits have shown that the original layered deposits of carbonate and hydrous silicates of manganese have been widely altered by metamorphism to spessartite (Mn3Al2-(SiO.),), rhodonite (MnSi03), and piedmontite (Ca2(Al,Mn"',Fe"')3-Si3Oi2(OH)). Recent work shows that layered manganese oxides also were present in the original sedimentary rocks. It shows also, that tephroite has formed widely in the original assemblage of carbonate, silicate, and oxide of manganese ; in several localities, a little alleghanyite (2Mn2-S1O4 - Mn(OH,F)2) has been formed. Rhodonite, spessartite, and piedmontite uniformly follow the tephroite ; in places, bementite and neotocite are present. In one deposit a little pyroxmangite ( (Mn,Fe,Ca)Si03) has been noted and in another, some crystals that are probably pyrophanite (MnTi03), not yet recorded in the United States. By contrast, the restudy of large collections of material from deposits in sedimentary rocks of the Franciscan formation in the Coast Ranges indicates the tephroite is very uncommon; it has been recognized with assurance at only one locality-Alum Rock Park, Santa Clara County. In the Coast Ranges, rhodonite and spessartite, the high manganese garnet, are very uncommon. The assemblages of manganese silicates indicate that the layered deposits of manganese minerals in the Sierra belt have been metamorphosed to a higher degree than those of the Coast Ranges. This review also shows the presence of axinite, the boro-silicate of aluminum, calcium, and manganese , in three deposits .

California↗

USGS1952

Geology of the Copper King Mine area, Prairie Divide, Larimer County, Colorado (Part 1)

The Copper King mine, in Larimer County, Colo., in the northern part of the Front Range of Colorado, was operated for a short time prior to World War II for copper and zino, but since 1949, when pitchblende was discovered on the mine dump, it has been worked for uranium. The bedrock in the mine area consists predominantly of pre-Cambrian (Silver Plums) granite with minor migmatite and metasediments--biotite-quartz-plagioclase gneiss, biotite schist, quartzite, amphibolite, amphibole skarn, and biotite skols. The metasediments occur as inclusions that trend northeast in the granite. This trend is essentially parallel to the prevailing foliation in the granite. At places the metasediments are crosscut sharply by the granite to form angular, partly discordant, steep-walled bodies in the granite. Faults, confined to a narrow zone that extends through the mine, cut both the pre-Cambrian rocks and the contained sulfide deposits. The Copper King fault, a breccia zone, contains a deposit of pitchblende; the other faults are believed to be later than the ore. The two types of mineral deposits--massive sulfide and pitchblende deposits--in the mine area, are of widely different mineralogy, age, and origin. The massive sulfide deposits are small and consist of pyrite, sphalerite, chalcopyrite, pyrrhotite, and in places magnetite in amphibole skarn, mice skols, and quartzite. The deposit at the Copper King mine has yielded small quantities of high-grade sphalerite ore. The massive sulfides are pyrometasomatic deposits of pre-Cambrian age. The pitchblende at the Copper King mine is principally in the Copper King vein, a tight, hard breccia zone that cuts through both granite and the massive sulfide deposit. A small part of the pitchblende is in small fractures near the vein and in boxwork pyrite adjacent to the vein; the post-ore faults, close to their intersection with the Copper King vein, contain some radioactive material, but elsewhere, so far as is known, they are barren. The pitchblende in the deposit forms a steeply plunging ore shoot that has a horizontal length of more than 50 feet and a vertical height of about 85 feet. The thickness of the ore shoot averages about 2 feet, but it ranges from a feather edge to about 4 feet. The hard pitch-blende is intimately intergrown with siderite; other gangue minerals include pyrite, quartz, and finely comminuted fragments of the wall rocks. The vein was repeatedly reopened during mineral deposition as shown by several stages of brecciation and recommended by the vein matter. The pitchblende deposit probably formed at intermediate temperatures and depths and, according to the Pb/U ratio, is about 60 million years old--an early Tertiary age.

Colorado↗

USGS2009

The Iron Hill (Powderhorn) carbonatite complex, Gunnison County, Colorado — A potential source of several uncommon mineral resources

A similar version of this slide show was presented on three occasions during 2008: two times to local chapters of the Society for Mining, Metallurgy, and Exploration (SME), as part of SME's Henry Krumb lecture series, and the third time at the Northwest Mining Association's 114th Annual Meeting, held December 1-5, 2008, in Sparks (Reno), Nevada. In 2006, the U.S. Geological Survey (USGS) initiated a study of the diverse and uncommon mineral resources associated with carbonatites and associated alkaline igneous rocks. Most of these deposit types have not been studied by the USGS during the last 25 years, and many of these mineral resources have important applications in modern technology. The author chose to begin this study at Iron Hill in southwestern Colorado because it is the site of a classic carbonatite complex, which is thought to host the largest known resources of titanium and niobium in the United States.

Colorado↗

USGS2011

Petrologic, tectonic, and metallogenic evolution of the Ancestral Cascades magmatic arc, Washington, Oregon, and northern California

Present-day High Cascades arc magmatism was preceded by ∼40 m.y. of nearly cospatial magmatism represented by the ancestral Cascades arc in Washington, Oregon, and northernmost California (United States). Time-space-composition relations for the ancestral Cascades arc have been synthesized from a recent compilation of more than 4000 geochemical analyses and associated age data. Neither the composition nor distribution of ancestral Cascades magmatism was uniform along the length of the ancestral arc through time. Initial (>40 to 36 Ma) ancestral Cascades magmatism (mostly basalt and basaltic andesite) was focused at the north end of the arc between the present-day locations of Mount Rainier and the Columbia River. From 35 to 18 Ma, initial basaltic andesite and andesite magmatism evolved to include dacite and rhyolite; magmatic activity became more voluminous and extended along most of the arc. Between 17 and 8 Ma, magmatism was focused along the part of the arc coincident with the northern two-thirds of Oregon and returned to more mafic compositions. Subsequent ancestral Cascades magmatism was dominated by basaltic andesite to basalt prior to the post–4 Ma onset of High Cascades magmatism. Transitional tholeiitic to calc-alkaline compositions dominated early (before 40 to ca. 25 Ma) ancestral Cascades eruptive products, whereas the majority of the younger arc rocks have a calc-alkaline affinity. Tholeiitic compositions characteristic of the oldest ancestral arc magmas suggest development associated with thin, immature crust and slab window processes, whereas the younger, calc-alkaline magmas suggest interaction with thicker, more evolved crust and more conventional subduction-related magmatic processes. Presumed changes in subducted slab dip through time also correlate with fundamental magma composition variation. The predominance of mafic compositions during latest ancestral arc magmatism and throughout the history of modern High Cascades magmatism probably reflects extensional tectonics that dominated during these periods of arc magmatism. Mineral deposits associated with ancestral Cascades arc rocks are uncommon; most are small and low grade relative to those found in other continental magmatic arcs. The small size, low grade, and dearth of deposits, especially in the southern two-thirds of the ancestral arc, probably reflect many factors, the most important of which may be the prevalence of extensional tectonics within this arc domain during this magmatic episode. Progressive clockwise rotation of the forearc block west of the evolving Oregon part of the ancestral Cascades magmatism produced an extensional regime that did not foster significant mineral deposit formation. In contrast, the Washington arc domain developed in a transpressional to mildly compressive regime that was more conducive to magmatic processes and hydrothermal fluid channeling critical to deposit formation. Small, low-grade porphyry copper deposits in the northern third of the ancestral Cascades arc segment also may be a consequence of more mature continental crust, including a Mesozoic component, beneath Washington north of Mount St. Helens.

California, Oregon, Washington↗

USGS1968

Application of ultraviolet reflectance and stimulated luminescence to the remote detection of natural materials

Carbonate rocks and evaporite deposits commonly exhibit relatively high reflectance in the ultraviolet (<3600A), and some outcrops of these materials are selectively shown on ultraviolet imagery. Other materials which are commonly strongly imaged on ultraviolet imagery and photography include water, snow, concrete, and metallic objects, particularly aluminum. Outdoor tests of an active ultraviolet imaging system have demonstrated the feasibility of imaging ultraviolet stimulated luminescence of such minerals as talc, dolomite, and deweylite along quarry faces from distances of several hundred feet. The system features a cathode ray tube transmitter, an image dissector receiver, and a video monitor on which the distribution of luminescent material is imaged as the outcrop is scanned. A pulsed ultraviolet laser emitting at 3371A has been used successfully in the laboratory to stimulate phosphorescence of selected rock and mineral specimens and to discriminate between them on the basis of decay time which ranges from less than three to more than 10 microseconds. Initial results suggest that sodic feldspars have longer decay periods than calcic feldspars. Some granites also appear to have decay periods significantly different from other types of granite in the same locality. Outdoor tests with a high-resolution grating spectrometer were successful in detecting luminescent materials by means of the so-called "Fraunhofer line-depth method". This method is advantageous because it uses the sun so an ultraviolet source and therefore ifs independent of low-powered artificial sources such as cathode ray tubes, lasers, and mercury vapor lamps„ A Fraunhofer line- discriminator suitable for aircraft operation has been constructed, and initial on-the- ground tests are being performed on Rhodamine WT, a luminescent dye used by hydrologists and oceanographers in studies of current dynamics in streams and estuaries.

Open-File Report↗

USGS2014

A reconnaissance for signs of a Mississippi Valley-type lead-zinc mineralizing system on the eastern flank of the Rutbah Uplift, Anbar Province, Iraq

Reconnaissance field visits and rock sampling were conducted at eight geologically selected locations within Mesozoic rocks on the eastern flank of the Rutbah Uplift, Anbar Province, western Iraq, in an attempt to determine if these rocks have been affected by a Mississippi Valley-Type (MVT) lead-zinc mineralizing system. Samples subsequently were studied by carbonate mineral staining, transmitted and reflected light petrology, and scanning electron microscopy with semi-quantitative energy dispersive elemental analyses. Single samples were studied by each, inductively coupled plasma mass spectrometry analyses of trace elements and fluid inclusion microthermometry. Permissive evidence indicates that there has been a MVT system present, but none of the evidence is considered definitive.

Anbar Province↗

USGS2003

Origin and significance of postore dissolution collapse breccias cemented with calcite and barite at the Meikle gold deposit, Northern Carlin trend, Nevada

The final event in a complicated hydrothermal history at the Meikle gold deposit was gold deficient but caused extensive postore dissolution of carbonate, collapse brecciation, and precipitation of calcite and barite crystals in the resulting cavities. Although previously interpreted to be part of the Carlin -type hydrothermal system, crosscutting relationships and U-Th-Pb geochronology constrain this hydrothermal event to late Pliocene time (ca. 2 Ma), nearly 36 Ma after ore formation. Mineralogic, fluid inclusion, and stable isotope data indicate that postore hydrothermal fluids were reduced, H 2 S-rich, unevolved meteoric waters ((δ 18 O = -17‰) of low temperature (ca. 65°C). The δ 18 O values of barite and calcite indicate that these minerals were in isotopic equilibrium, requiring that barite SO 4 was derived from the oxidation of reduced sulfur; however, preexisting sulfides in breccia cavities were not oxidized. The δ 34 S (15‰) values of barite are higher than those of local bulk sulfide and supergene alunite indicating that SO 4 was not derived from supergene oxidation of local sulfide minerals. The 15 per mil δ 34 S value suggests that the H 2 S in the fluids may have been leached from sulfur-rich organic matter in the local carbonaceous sedimentary rocks. A reduced H 2 S-rich fluid is also supported by the bright cathodoluminescence of calcite which indicates that it is Mn rich and Fe poor. Calcite has a narrow range of δ 13 C values (0.3-1.8‰) that are indistinguishable from those of the host Bootstrap limestone, indicating that CO 2 in the fluid was from dissolution of the local limestone. These data suggest that dissolution and brecciation of the Bootstrap limestone occurred where H 2 S-rich fluids encountered more oxidizing fluids and formed sulfuric acid (H 2 SO 4 ). Intense fracturing in the mine area by previous structural and hydrothermal events probably provided conduits for the descent of oxidized surface water which mixed with the underlying H 2 S-rich waters to form the dissolving acid. The surface-derived fluid apparently contained sufficient oxygen to produce H 2 SO 4 from H 2 S but not enough to alter pyrite to Fe oxide. Although H 2 S is an important gold -transporting ligand, the temperature was too low to transport a significant amount of gold . The presence of analogous calcite - and barite -lined cavities in other Carlin -type deposits suggests that the generation (and oxidation) of H 2 S-rich meteoric waters was a common phenomenon in north-central Nevada . Previous sulfur isotope studies have also shown that the Paleozoic sedimentary rocks were the principal source of H 2 S in Devonian sedimentary exhalative-type, Jurassic intrusion-related, Eocene Carlin -type, and Miocene low-sulfidation gold deposits in the region. The similar sulfur source in all of these systems suggests that basin brines, magmatic fluids, and meteoric waters all evolved to be H 2 S-rich ore fluids by circulation through Paleozoic sedimentary rocks. Thus, although not directly related to gold mineralization, the recent hydrologic history of the deposit provides important clues to earlier ore-forming processes that were responsible for gold mineralization.

Nevada↗

USGS2014

Magmatism, metasomatism, tectonism, and mineralization in the Humboldt Range, Pershing County, Nevada

Introduction The Humboldt Range, Pershing County, Nevada, predominantly consists of Mesozoic igneous and sedimentary rocks that were modified several times by magmatism, metasomatism, and tectonism, and contain a variety of metallic (Ag, Au, Pb, Zn, Sb, W, Hg) and non-metallic (dumortierite, pinite, fluorite) mineral deposits (Knopf, 1924; Kerr and Jenney, 1935; Kerr, 1938; Cameron, 1939; Campbell, 1939; Kerr, 1940; Page et al., 1940; Johnson, 1977; Vikre, 1978; 1981; Crosby, 2012). Early Triassic Koipato Group volcanic rocks, which are widely exposed in the range, have been altered to quartz, muscovite (sericite), chlorite, pyrite, and other minerals during emplacement of Mesozoic intrusions and by crustal thickening. Most hydrothermal alteration of volcanic rocks and formation of mineral deposits involved externally derived water and other volatiles, although some volcanic strata were apparently altered by pore or dehydration water. Cospatial hydrothermal mineral assemblages and associations, produced by events widely spaced in time, are difficult to separate because of common mineralogy (quartz, sericite, and pyrite), partial to complete recrystallization, thermally compromised Ar geochronology, and lack of comprehensive investigations of volatile sources and deformational fabric. Distinguishing between metasomatic and metamorphic processes that affected rocks in the Humboldt Range is not straightforward.

Nevada↗

USGS1974

Mineral resources of Du Noir Addition, Washakie Wilderness area, Fremont County, Wyoming

The Du Noir Addition to the Washakie Wilderness area consists of 34,200 acres (13,840 hectares) of scenic mountainous terrain that adjoins the Teton Wilderness and Washakie Wilderness areas. The area was studied in 1973 by the U.S. Geological Survey and U.S. Bureau of Mines to evaluate its mineral, fuel, and geothermal energy potential. This evaluation is based on a search of the geologic literature, claim and production records, and fieldwork including mapping, inspection of claims and prospects, interpretation of aeromagnetic maps, and analyses of bedrock and stream-sediment samples. Flat-lying Eocene volcaniclastic rocks of the Absaroka volcanic field are exposed in about two-thirds of the Du Noir Addition. These volcanics unconformably overlie the deeply eroded, northwest-trending Du Noir anticline in which Paleozoic marine strata of Devonian through Permian age are exposed. Of lesser importance are small deposits of Eocene non-volcanic conglomerate, and basaltic intrusive and extrusive rocks of late Pliocene and possibly younger age. The results of this study indicate that the mineral, fuel, and geothermal potential of the Du Noir Addition are minimal. Low-grade copper-molybdenum mineralization occurs outside the addition, associated with intrusive rocks, but no indications of alteration or mineralization were found within the study area. Anomalous, but not economically important, concentrations of molybdenum and uranium were found in Permian and Eocene carbonaceous shales. Phosphate rock in the Phosphoria Formation occurs in beds too thin to constitute a resource. Large amounts of very pure limestone are present in the Madison Limestone, but equally pure limestone, much closer to transportation facilities, is found throughout this part of Wyoming. That part of the Du Noir anticline in the addition is too deeply eroded to be a likely reservoir of oil and gas. Present data indicates a low potential for geothermal energy in or near the addition.

Wyoming↗

USGS1989

Investigations of the characteristics, origin, and residence time of the upland residual mantle of the Piedmont of Fairfax County, Virginia

Undisturbed cores of upland regolith developed from a variety of crystalline rocks of the Piedmont province in Fairfax County, Va., have been obtained by using a combination of Shelby tubes, Denison sampler, and modified diamond core drilling. The core study correlated variations in chemistry, mineralogy, and texture with engineering properties throughout individual weathering profiles and contrasted these parameters among weathering profiles developed from various parent rocks. Coring sites were chosen to obtain a maximum depth of weathering on diverse lithologies. The rocks that were investigated included metapelite, metagraywacke, granite, diabase, and serpentinite. Four to twelve samples per core were selected for analysis of petrography, texture, clay mineralogy, and major-element chemistry. The number of samples was determined on the basis of (1) the thickness of the weathering profile (from about 1 m in serpentinite to more than 30 m in pelitic schist) and (2) megascopic changes in the weathering profile. Shear strength and compressibility were determined on corresponding segments of core. Standard penetration tests were performed adjacent to coring sites to evaluate in-place engineering properties. The regolith profiles on all rocks can be subdivided into soil, massive subsoil, saprolite, and weathered rock zones. Major differences in thicknesses of these zones are related to parent rock. Total regolith thickness is related to saprolite thickness. Saprolite is thickest on quartzofeldspathic metapelite, metagraywacke, and granite; thinner on diabase; and thinnest on serpentinite. Thickness of saprolite is related to rock structure and mineralogy. Geochemical changes of saprolite developed from each rock type follow predictable trends from fresh rock to soil profile, with increases in Ti, AI, Fe 3 +, and H 2 0+relative to absolute losses of Si, Fe2+, Mg, Ca, and Na. These variations are more pronounced in the weathering profiles above mafic and ultramafic rocks than in those above metagraywacke. Clay minerals in granite, schist, and metagraywacke saprolites are kaolinite, dioctahedral vermiculite, interlayered mica-vermiculite, and minor illite. Gibbsite is developed in near-surface samples of schist. Standard penetration test data for the upper 7 m of saprolite above schist, metagraywacke, and granite suggest alternations between stronger and weaker horizons that correlate with megascopic ally identified zones: soil, massive subsoil, and saprolite. The data correlate with density. Shear strength increases fairly regularly downward in the weathering profile. The engineering behavior of diabase saprolite is controlled by a dense, plastic, near-surface clay layer (montmorillonite and kaolinite) overlying rock that is weathered to a granular state (grus); the engineering properties of serpentinite are controlled by a very thin weathering profile. Similarities in regolith thickness, zonation, mineralogy, and chemistry of quartzofeldspathic rocks indicate the existence of fundamental geochemical and geomechanical controls on regolith evolution on the Piedmont upland. Data from the profiles of quartzofeldspathic regolith are used to construct a model suggesting the principal rate-control steps in the development and downwasting of the upland regolith. This model is consistent with available information about Piedmont hydrology and tectonic uplift.

Professional Paper↗

USGS1992

Host-rock controlled epigenetic, hydrothermal metasomatic origin of the Bayan Obo REEFe-Nb ore deposit, Inner Mongolia, P.R.C.

Bayan Obo, a complex rare earth element (REE) Fe Nb ore deposit, located in Inner Mongolia, P.R.C. is the world's largest known REE deposit. The deposit is chiefly in a marble unit (H8), but extends into an overlying unit of black shale, slate and schist unit (H9), both of which are in the upper part of the Middle Proterozoic Bayan Obo Group. Based on sedimentary structures, the presence of detrital quartz and algal fossil remains, and the 16-km long geographic extent, the H8 marble is a sedimentary deposit, and not a carbonatite of magmatic origin, as proposed by some previous investigators. The unit was weakly regionally metamorphosed (most probably the lower part of the green schist facies) into marble and quartzite prior to mineralization. Tectonically, the deposit is located on the northern flank of the Sino-Korean craton. Many hypotheses have been proposed for the origin of the Bayan Obo deposit; the studies reported here support an epigenetic, hydrothermal, metasomatic origin. Such an origin is supported by field and laboratory textural evidence; 232 Th/ 208 Pb internal isochron mineral ages of selected monazite and bastnaesite samples; 40 Ar/ 39 Ar incremental heating minimum mineral ages of selected alkali amphiboles; chemical compositions of different generations of both REE ore minerals and alkali amphiboles; and evidence of host-rock influence on the various types of Bayan Obo ores. The internal isochron ages of the REE minerals indicate Caledonian ages for various episodes of REE and Fe mineralization. No evidence was found to indicate a genetic relation between the extensive biotite granitic rocks of Hercynian age in the mine region and the Bayan Obo are deposit, as suggested by previous workers.

Applied Geochemistry↗

USGS1952

Preliminary summary review of thorium-bearing mineral occurrences in Alaska

Thorium-bearing minerals are known at 47 localities in Alaska. At these localities the thorium occurs as a major constituent or in minor amounts as an impurity in one or more of the following 12 minerals: allanite, columbite, ellsworthite, eschynite, gummite, monazite, orangite, parisite, thorianite, thorite, xenotime, and zircon. In addition other minerals, such as biotite and sphene, are radioactive and may contain thorium. Several unidentified columbate minerals with uranium or thorium and uranium as major constituents have been recognized at some localities. The distribution, by type of deposit, of the 57 thorium occurrences is as follows: lode - 3, lode and placer - 1, granitic rock - 3, granitic rock and related placer - 14, and placer - 26. Of the four lode occurrences only the radioactive veins at Salmon Bay in southeastern Alaska and the contact metamorphic deposit in the Nixon Fork area of central Alaska warrant further consideration, although insufficient data are available to determine whether these two deposits have commercial possibilities. The remaining occurrences of thorium-bearing minerals in Alaska are limited to placer deposits and disseminations of accessory minerals in granitic rocks. In most of these occurrences the thorium-bearing minerals occur in only trace amounts and consequently warrent little further consideration. More data are needed to determine the possibilities of byproduct recovery of thorium-bearing minerals from several of the gold and tin placers.

Alaska↗

USGS1983

Hashemite, Ba(Cr,S)O4, a new mineral from Jordan.

Hashemite, Ba(Cr,S)O4, the isostructural chromate analogue of baryte, has been found in west-central Jordan. It is associated with chromian ettringite, apatite and calcite in a phosphatic carbonate rock analogous to the Hatrurim formation in Israel. The mineral is orthorhombic, Pnma, with a 9.112(2), b 5.541(1), c 7.343(1) A, Z = 4. Strongest XRD lines are 3.516(100), 3.171(80), 3.669(60), 2.175(60), 2.150(45) A. Hashemite occurs as small, euhedral, dark brown, commonly zoned crystals with an average D 4.59 g/cm3 and H. 31/2. It is biaxial positive; dark varieties have alpha 1.952(2), beta 1.960(2), gamma 1.977(2); light varieties have alpha 1.810(2), beta 1.813(2), gamma 1.824(2), 2Vgamma 35o-57o.-J.A.Z.

American Mineralogist↗

USGS2018

Intermediate sulfidation type base metal mineralization at Aliabad-Khanchy, Tarom-Hashtjin metallogenic belt, NW Iran

The Aliabad-Khanchy epithermal base metal deposit is located in the Tarom-Hashtjin metallogenic belt (THMB) of northwest Iran. The mineralization occurs as Cu-bearing brecciated quartz veins hosted by Eocene volcanic and volcaniclastic rocks of the Karaj Formation. Ore formation can be divided into five stages, with most ore minerals, such as pyrite and chalcopyrite being formed in the early stages. The main wall-rock alteration is silicification, and chlorite, argillic and propylitic alteration. Microthermometric measurements of fluid inclusion assemblages show that the ore-forming fluids have eutectic temperatures between −30 and −52 °C, trapping temperatures of 150–290 °C, and salinities of 6.6–12.4 wt% NaCl equiv. These data demonstrate that the ore-forming fluids were medium- to high-temperature, medium- to low-salinity, and low-density H 2 O–NaCl–CaCl 2 fluids. Calculated δ 18 O values indicate that ore-forming hydrothermal fluids had δ 18 O water ranging from +3.6‰ to +0.8‰, confirming that the ore–fluid system evolved from dominantly magmatic to dominantly meteoric. The calculated 34 S H2S values range from −8.1‰ to −5.0‰, consistent with derivation of the sulfur from either magma or possibly from local volcanic wall-rock. Combined, the fluid inclusion and stable isotope data indicate that the Aliabad-Khanchy deposit formed from magmatic-hydrothermal fluids. After rising to a depth of between 790 and 500 m, the fluid boiled and subsequent hydraulic fracturing may have led to inflow and/or mixing of early magmatic fluids with circulating groundwater causing deposition of base metals due to dilution and/or cooling. The Aliabad-Khanchy deposit is interpreted as an intermediate-sulfidation style of epithermal mineralization. Our data suggest that the mineralization at Aliabad-Khanchy and other epithermal deposits of the THMB formed by hydrothermal activity related to shallow late Eocene magmatism. The altered Eocene volcanic and volcaniclastic rocks, especially at the intersection of subvolcanic stocks with faults were the most favorable sites for epithermal ore bodies in the THMB.

Ore Geology Reviews↗

USGS1956

Summary of reconnaissance for radioactive deposits in Alaska, 1945-1954, and an appraisal of Alaskan uranium possibilities

In the period 1945-1954 over 100 investigations for radioactive source materials were made in Alaska. The nature of these investigations ranged from field examinations of individual prospects or the laboratory analysis of significantly radioactive samples submitted by prospectors to reconnaissance studies of large districts. In this period no deposits of uranium or thorium that would warrant commercial exploitation were discovered. The investigations, however, disclosed that radioactive materials occur in widely scattered areas of Alaska and in widely diverse environments. Many igneous rocks throughout Alaska are weakly radioactive because of uranium- and thorium-bearing accessory minerals, such as allanite, apatite, monazite, sphene, xenotime, and zircon; more rarely the radioactivity of these rocks is due to thorianite or thorite and their uranoan varieties. The felsic rocks, for example, granites and syenites, are generally more radioactive than the mafic igneous rocks. Pegmatites, locally, have also proved to be radioactive, but they have little commercial significance. No primary uranium oxide minerals have been found yet in Alaskan vein deposits, except, perhaps, for a mineral tentatively identified as pitchblende in the Hyder district of southeastern Alaska. However, certain occurrences of secondary uranium minerals, chiefly those of the uranite group, on the Seward Peninsula, in the Russian Mountains, and in the vicinity of Kodiak suggest that pitchblende-type ores may occur at depth beneath zones of alteration. Thorite-bearing veins have been discovered on Prince of Wales Island in southeastern Alaska. Although no deposits or carnotite-type minerals have been found in Alaska, several samples containing such minerals have been submitted by Alaskan prospectors. Efforts to locate the deposits from which these minerals were obtained have been unsuccessful, but review of available geologic data suggests that several Alaskan areas are potentially favorable for carnotite-type deposits. The chief of these areas is the Alaska Peninsula-Cook Inlet area which encompasses most of the reported occurrences of the prospectors' carnotite-type samples. Alaska is also potentially favorable for the occurrence of large bodies of the very low-grade uraniferous sedimentary rocks, such as phosphorites and black shales. This type of deposit, however, has not received much study because of the emphasis on the search for bonanza-type high-grade ores. Uraniferous phosphorites similar to those of Idaho, Montana, and Wyoming occur in northern Alaska on the north flank of the Brooks Range; black shales comparable to the uraniferous shales of the Chattanooga formation of southeastern United States have been noted along the Yukon River near the international boundary. Placer deposits in Alaska have some small potential for the production of the radioactive elements as byproducts of gold- and tin-placer mining. the placer area believed to have the relatively greatest potential in Alaska lies in the Kahiltna River valley where concentrates are known to contain such commercial minerals as ilmenite, cassiterite, platinum, and gold in addition to uranothorianite and monazite. The possibilities of the natural fluids--water and petroleum--have not yet been tested in Alaska to any great extent. Studies of fluids are in progress to determine whether they may be used to discover and define areas potentially favorable for the occurrence of uraniferous lodes.

Alaska↗

USGS1987

Age of uranium mineralization at the Jabiluka and Ranger deposits, Northern Territory, Australia: New U-Pb isotope evidence

The Ranger and Jabiluka uranium deposits are the largest in the Alligator Rivers uranium field, which contains at least 20 percent of the world's low-cost uranium reserves. Ore occurs in early Proterozoic metasediments, below an unconformity with sandstones of the 1.65-b.y.-old Kombolgie Formation. This study has used U-Pb isotope data from a large number of whole-rock drill core samples with a variety of mineral assemblages and textures. Ranger samples indicate a well-defined age of 1,737 + or - 20 m.y., consistent with earlier suggestions of the antiquity of this deposit. This age is distinctly pre-Kombolgie, so the Ranger deposit cannot have been formed by processes requiring its presence. The age is consistent, however, with mineralization related to heating associated with either the emplacement of early postmetamorphic granites, or possibly, with intrusion of the nearby Oenpelli Dolerite. In contrast, data for the least-altered Jabiluka ores yield a concordia intercept age of 1,437 + or - 40 m.y.--significantly younger than the Ranger age and also younger than the Kombolgie Formation. This age may correspond to a regional thermal event, as indicated both by mafic dikes of roughly this age and a zircon lower intercept age from a nearby granite-gneiss. Thus our data indicate that there must be at least three distinct periods of major U mineralization in the Alligator Rivers uranium field (including the previously determined approximately 900-m.y. age of the Nabarlek deposit), despite the fact that all of the deposits share strong similarities in their host rock, mineralogy, alteration, and geologic setting.Both Ranger and Jabiluka reflect a common, profound isotopic disturbance at about 400 to 600 m.y. This disturbance, which was especially pronounced at Jabiluka, may correspond to the development of basins and associated basalt flows to the west and southwest, as suggested by Crick et al. (1980).

Economic Geology↗

USGS1999

Petrology and geochemistry of late-stage intrusions of the A-type, mid-Proterozoic Pikes Peak batholith (Central Colorado, USA): Implications for petrogenetic models

The ~1.08 Ga anorogenic, A-type Pikes Peak batholith (Front Range, central Colorado) is dominated by coarse-grained, biotite ?? amphibole syenogranites and minor monzogranites, collectively referred to as Pikes Peak granite (PPG). The batholith is also host to numerous small, late-stage plutons that have been subdivided into two groups (e.g. Wobus, 1976. Studies in Colorado Field Geology, Colorado School of Mines Professional Contributions, Colorado): (1) a sodic series (SiO2= ~44-78 wt%; K/Na=0.32-1.36) composed of gabbro, diabase, syenite/quartz syenite and fayalite and sodic amphibole granite; and (2) a potassic series (SiO2= ~ 70-77 wt%; K/Na=0.95-2.05), composed of biotite granite and minor quartz monzonite. Differences in major and trace element and Nd isotopic characteristics for the two series indicate different petrogenetic histories. Potassic granites of the late-stage intrusions appear to represent crustal anatectic melts derived from tonalite sources, based on comparison of their major element compositions with experimental melt products. In addition, Nd isotopic characteristics of the potassic granites [??(Nd)(1.08 Ga) = -0.2 to -2.7] overlap with those for tonalites/granodiorites [ca 1.7 Ga Boulder Creek intrusions; ??(Nd)(1.08 Ga) = -2.4 to -3.6] exposed in the region. Some of the partial melts evolved by fractionation dominated by feldspar. The late-stage potassic granites share geochemical characteristics with most of the PPG, which is also interpreted to have an anatectic origin involving tonalitic crust. The origin of monzogranites associated with the PPG remains unclear, but mixing between granitic and mafic or intermediate magmas is a possibility. Syenites and granites of the sodic series cannot be explained as crustal melts, but are interpreted as fractionation products of mantle-derived mafic magmas with minor crustal input. High temperature and low oxygen fugacity estimates (e.g. Frost et al., 1988. American Mineralogist 73, 727-740) support a basalt fractionation origin, as do ??(Nd) values for sodic granitoids [??(Nd)(1.08 Ga) = +2.2 to -0.7], which are higher than ??(Nd) values for Colorado crust at 1.08 Ga (ca -1.0 to -4.0). Enrichments in incompatible elements (e.g. rare earth elements, Rb, Y) and depletions in compatible elements (e.g. Cr, Sr, Ba) in the sodic granitoids compared to coeval mafic rocks are also consistent with fractionation. Accessory mineral fractionation, release of fluorine-rich volatiles and/or removal of pegmatitic fluids could have modified abundances of Ce, Nb, Zr and Y in some sodic granitoid magmas. Gabbros and mafic dikes associated with the sodic granitoids have ??(Nd)(1.08 Ga) of -3.0 to +3.5, which are lower than depleted mantle at 1.08 Ga, and their trace element characteristics suggest derivation from mantle sources that were previously affected by subduction-related processes. However, it is difficult to characterize the mantle component in these magmas, because assimilation of crust during magma ascent could also result in their observed geochemical features. The Pikes Peak batholith is composed of at least two petrogenetically different granite types, both of which exhibit geochemical characteristics typical of A-type granites. Models proposed for the petrogenesis of the granitoids imply the existence of mafic rocks at depth and addition of juvenile material to the crust in central Colorado at ~ 1.1 Ga.

Precambrian Research↗