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At least 1,189 records · Page 66Linked to original sources

Buddingtonite, ammonium feldspar, in the Phosphoria Formation, southeastern Idaho

Buddingtonite is distributed widely in the rocks of the Meade Peak Member of the Phosphoria Formation in southeastern Idaho and occurs in amounts up to about 50 percent. Most of the buddingtonite is in the middle mudstone interval of the member between two phosphate-rich intervals. The composition of the buddingtonite, in terms of a buddingtonite K-feldspar series, shows an apparent range of Bd 82 KF 18 to Bd 13 KF 87 , and compositions of Bd 72 KF 28 to Bd 50 KF 50 may be the most common. The predominant silicate mineral suite consists of buddingtonite-albite-illite. Albite is present in amounts up to about 20 percent. Buddingtonite may have developed directly from volcanic glass in the presence of abundant ammonium, derived from the decomposition of organic matter, in interstitial waters, or it may have formed at some later diagenetic stage from other products of volcanic glass alteration, such as montmorillonite or zeolites.

Idaho↗

High arsenic concentrations and enriched sulfur and oxygen isotopes in a fractured-bedrock ground-water system

Ground water with high arsenic concentrations (up to 26.6????mol L- 1) has sulfate enriched in 34S and 18O in the fractured-bedrock, ground-water system of the Kelly's Cove watershed, Northport, Maine, USA. The ranges of sulfur and oxygen isotope values in aqueous sulfate, ??34S[SO4] and ??18O[SO4], at the Kelly's Cove watershed are + 3.4 to + 4.9??? and - 2.0 to + 6.7???, respectively. These isotope values are strikingly similar to those of the Goose River, Maine watershed which has ??34S[SO4] and ??18O[SO4] ranges of + 3.7 to + 4.6 ??? and - 2.6 to + 7.5???, respectively. In both systems, high arsenic concentrations occur with high ??34S[SO4] and ??18O[SO4] values, yet redox conditions and underlying rock types are quite different. The isotope values of sulfide minerals, ??34S[min], from four bedrock cores vary over short distances and range from - 5.1 to + 7.5???. The ??34S[SO4] values are controlled by the ??34S[min] values with minor input of atmospheric SO4. The much narrower range in ??34S[SO4] values than ??34S[min] values is probably due to sufficient ground-water mixing at a scale greater than the ??34S[min] variability. The ??34S[SO4] values are about 2??? higher than the average ??34S[min] value and fall within the range of ??34S[min] values, indicating only minor fractionation due to bacterial reduction of SO4. The highest ??18O[SO4] values were measured in the downgradient, confined, arsenic-rich ground water. High ??18O[SO4] values there cannot be due to aeration by atmospheric oxygen, but may arise from reoxidation of reduced SO4 products. The enrichment factors of ??18O in SO4 compared to H2O, + 7.2 to + 15.5???, in the Kelly's Cove ground water and the negligible 34S enrichment is very similar to those derived from experimental data of anaerobic sulfide oxidation in the presence of Mn and Fe oxides. Sea level at the Kelly's Cove watershed was approximately 80??m above present sea level about 13 000??years before present, imposing reducing conditions on that area of the watershed. Sea level dropped approximately 60??m below present sea level about 11 000??years before present, allowing for possible oxidation of sulfide minerals and precipitation of arsenic in ferric oxyhydroxides during aeration of the ground-water system. Under present redox conditions, there is evidence that bacteria reduction of ferric oxyhydroxides releases arsenic. The fractionation of 18O in the SO4 during anaerobic oxidation of sulfide in the presence of Mn and Fe oxides and subsequent release of arsenic during Mn and Fe oxide reduction may explain the relationship between high arsenic concentrations and elevated 18O[SO4] at Kelly's Cove. ?? 2007 Elsevier B.V. All rights reserved.

Chemical Geology↗

Emplacement and differentiation of the york haven diabase sheet, Pennsylvania

Many of the high-Ti quartz-normative tholeiitic intrusive sheets in the early Mesozoic rift basins of the Eastern USA exhibit lateral differentiation from mafic cumulate units, through diabase, to relatively evolved iron-rich rock types. We have investigated a representative example in detail, the York Haven sheet in the Gettysburg basin of south-central Pennsylvania. It ranges in thickness from 330 m to 675 m, and we have sampled it from base to top along four separate stratigraphic sections evenly spaced over the extent of the intrusion. The easternmost section (York Haven) is entirely basaltic bronzite cumulate (average 15 vol. % bronzite), whereas the westernmost (Reesers Summit) consists of diabase and low-MgO diabase with a middle to upper 'sandwich zone' of ferrogabbro. The intervening sections feature rock types transitional between the two end-member sequences. Chemically, the rock series shows a gradual east to west depletion of compatible elements (Mg, Ca, Ni, and Cr), and enrichment of incompatible elements [Ti, Fe, Na, K, P, Cu, Zr, Th, Ta, Hf, Sb, Cs, As, platinum group elements (PGEs), and rare earth elements (REEs)].We suggest two main processes for the trends observed in the York Haven sheet. First, flow differentiation during ascent and lateral injection of the parental magma produced a tongue of basaltic bronzite cumulate that thins from southeast to northwest and passes laterally into diabase, and, at the distal end of the intrusion, into low-MgO diabase. Then, in the latter stages of crystallization, densitydriven hydrothermal fluids transported incompatible elements westward, into structurally higher parts of the intrusion. Reaction of this residual aqueous fluid with partly crystallized low-MgO diabase produced a zone of ferrogabbro rich in hydrothermal replacement products (e.g., Cl-amphibole, biotite, ferrohypersthene, and skeletal ilmenite) and precipitates (e.g., quartz, fayalite, Cl-apatite, sulfides, and PGE minerals). © 1993 Oxford University Press.

Pennsylvania↗

Geophysical and geologic maps of Mountain Pass and vicinity, California and Nevada

U.S. Geological Survey Scientific Investigations Map 3412 is a series of products that consists of geophysical and geologic maps of Mountain Pass and vicinity, California. Maps A and B (red outline in above map image) are gravity and aeromagnetic maps, respectively. The map series was begun as part of an effort to study regional crustal structures as an aid to understanding the geologic framework and mineral resources of the southeast Mojave Desert. Mountain Pass resides within the southeast Mojave Desert, and it is host to a one of the world’s largest rare earth element carbonatite deposits. The deposit is found along a north-northwest- trending, fault-bounded block that extends along the eastern parts of the Clark Mountain Range, Mescal Range, and Ivanpah Mountains. This Paleoproterozoic block is composed of a 1.7-Ga metamorphic complex of gneiss and schist that underwent widespread metamorphism and associated plutonism during the Ivanpah orogeny. The Paleoproterozoic rocks were intruded by a Mesoproterozoic (1.4 Ga) ultrapotassic alkaline intrusive suite and carbonatite body. The intrusive rocks include, from oldest to youngest, shonkinite, mesosyenite, syenite, quartz syenite, potassic granite, carbonatite, carbonatite dikes, and late shonkinite dikes. Each map in the series provides the basis for geophysical and geologic interpretations of the Mountain Pass carbonatite terrane. Combined, they provide a comprehensive framework of the regional subsurface geologic structure of the area. Together, they form the first publicly available series of geophysical and geologic maps of this part of the southeast Mojave Desert.

California, Nevada↗

Field-trip guide to mafic volcanism of the Cascade Range in Central Oregon—A volcanic, tectonic, hydrologic, and geomorphic journey

The Cascade Range in central Oregon has been shaped by tectonics, volcanism, and hydrology, as well as geomorphic forces that include glaciations. As a result of the rich interplay between these forces, mafic volcanism here can have surprising manifestations, which include relatively large tephra footprints and extensive lava flows, as well as water shortages, transportation and agricultural disruption, and forest fires. Although the focus of this multidisciplinary field trip will be on mafic volcanism, we will also look at the hydrology, geomorphology, and ecology of the area, and we will examine how these elements both influence and are influenced by mafic volcanism. We will see mafic volcanic rocks at the Sand Mountain volcanic field and in the Santiam Pass area, at McKenzie Pass, and in the southern Bend region. In addition, this field trip will occur during a total solar eclipse, the first one visible in the United States in more than 25 years (and the first seen in the conterminous United States in more than 37 years). The Cascade Range is the result of subduction of the Juan de Fuca plate underneath the North American plate. This north-south-trending volcanic mountain range is immediately downwind of the Pacific Ocean, a huge source of moisture. As moisture is blown eastward from the Pacific on prevailing winds, it encounters the Cascade Range in Oregon, and the resulting orographic lift and corresponding rain shadow is one of the strongest precipitation gradients in the conterminous United States. We will see how the products of the volcanoes in the central Oregon Cascades have had a profound influence on groundwater flow and, thus, on the distribution of Pacific moisture. We will also see the influence that mafic volcanism has had on landscape evolution, vegetation development, and general hydrology.

Oregon↗

Geologic framework for the national assessment of carbon dioxide storage resources—Atlantic Coastal Plain and Eastern Mesozoic Rift Basins

This chapter presents information pertinent to the geologic carbon dioxide (CO 2 ) sequestration potential within saline aquifers located in the Atlantic Coastal Plain and Eastern Mesozoic Rift Basins of the Eastern United States. The Atlantic Coastal Plain is underlain by a Jurassic to Quaternary succession of sedimentary strata that onlap westward onto strata of the Appalachian Piedmont physiographic province and generally thicken eastward toward the present-day Atlantic coastline and onto the present-day continental shelf. Although no significant petroleum discoveries have been made on the coastal plain, the deep saline aquifers of the region appear to contain porous strata (potential reservoirs, or “storage formations”) that are overlain by fine-grained, laterally continuous strata (potential seals), which are prospective CO 2 sequestration targets. For the Atlantic Coastal Plain, we identify two storage assessment units (SAUs), both of which consist of Cretaceous strata. The two SAUs are the Lower Cretaceous Composite SAU C50700101 and the Upper Cretaceous Composite SAU C50700102. The Eastern Mesozoic Rift Basins are a chain of generally southwest- to northeast-trending, elongate sedimentary basins that either underlie the Atlantic Coastal Plain or crop out within adjacent geologic provinces to the west. Similar to the Atlantic Coastal Plain, there has been no significant oil and gas production from any of the basins, although there is a proven petroleum system in several of them. At least three of these basins appear to contain potential storage formations overlain by potential seal units. Most of the other basins were not assessed because a storage and (or) seal formation could not be established in the timeframe of the assessment, often because of the paucity of subsurface data for these basins in comparison to other petroliferous basins of the United States. Thus, we present information supporting one quantitative assessment in the Newark basin, as well as information supporting two nonquantitative assessments, one for strata in the Gettysburg basin and the other for strata in the Culpeper basin. We briefly discuss six other basins within the Eastern Mesozoic Rift Basins that were not assessed. For all SAUs, we discuss the areal distribution of suitable CO 2 reservoir rock. We also describe the overlying sealing unit and the geologic characteristics that influence the potential CO 2 storage volume and reservoir characteristics. These characteristics include storage formation depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this chapter, the geologic information included herein was used to calculate the potential storage space in the SAUs.

Atlantic Coastal Plain and Eastern Mesozoic Rift B↗

Geohydrology, geochemistry, and numerical simulation of groundwater flow and land subsidence in the Bicycle Basin, Fort Irwin National Training Center, California

Groundwater pumping from Bicycle Groundwater Basin (referred to as Bicycle Basin) in the Fort Irwin National Training Center, California, began in 1967. From 1967 to December 2010, about 46,000 acre-feet of water had been pumped from the basin and transported to the Irwin Basin. During this time, not only did water levels in the basin decline by as much as 100 feet, the quality of the groundwater pumped from the basin also deteriorated in some wells. The U.S. Geological Survey collected geohydrologic data from existing wells, test holes, and 16 additional monitoring wells installed at 6 sites in Bicycle Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including electrical, gravity, and seismic refraction surveys, were completed to help determine the geometry of the structural basin, delineate depths to the interface between Quaternary and Tertiary rocks, map the depth to the water table, and used to develop a geohydrologic framework and groundwater-flow model for Bicycle Basin. Water samples were used to determine the groundwater quality in the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicated that presentday precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicated that most of the groundwater in the basin was recharged prior to 1952 and had an apparent age of 15,625–39,350 years. Natural recharge to the basin was not sufficient to replenish the groundwater pumped from the basin. Interferograms from synthetic aperture radar data (InSAR), analyzed to evaluate land-surface subsidence between 1993 and 2010, showed 0.23 to 1.1 feet of subsidence during this period near one production well north of Bicycle Lake (dry) playa. A groundwater-flow model of Bicycle Basin was developed and calibrated using groundwater levels for 1964– 2010, and a subsidence model using land-surface deformation data for 1993–2010. Between January 1967 and December 2010, the simulated total recharge from precipitation runoff and underflow from adjacent basins was about 5,100 acre-feet and pumpage from the Bicycle Basin was about 47,000 acrefeet of water. Total outflows exceeded natural recharge during this period, resulting in a net loss of about 42,100 acre-feet of groundwater storage in the basin. The Fort Irwin National Training Center is considering various groundwater-management options in the Bicycle Basin. The groundwater-flow model was used to (1) evaluate changes in groundwater levels and subsidence with the addition of capture and recharge of simulated runoff in retention basins (scenario 1) for predevelopment through 2010; (2) simulate a base case (scenario 2) for reference; and (3) compare projections of alternative future pumping strategies for 2011–60 (scenarios 3–5). Model results from the runoff-capture simulation (scenario 1) indicated that total recharge, including runoff captured using retention basins, locally increased water levels, which partially offset, but did not mitigate, groundwater depletion associated with pumping. Groundwater-storage depletion in scenario 1 was about 14 percent less than without runoff capture. Simulated-drawdown results in model layer 1 in the eastern part of the basin indicated that, because of the captured runoff, simulated heads were as much as 100 feet higher in December 2010 than prior to the onset of development in 1967. In contrast, simulated drawdown for model without runoff capture indicated that, without captured runoff, simulated heads for December 2010 in this area were 80–90 feet lower than during the predevelopment period. Subsidence was mitigated slightly in scenario 1 compared to without runoff capture; the largest decrease in subsidence at observation sites was about 0.07 feet.

California↗

Natural aggregates of the conterminous United States

Crushed stone and sand and gravel are the two main sources of natural aggregates. These materials are commonly used construction materials and frequently can be interchanged with one another. They are widely used throughout the United States, with every State except two producing crushed stone. Together they amount to about half the mining volume in the United States. Approximately 96 percent of sand and gravel and 77 percent of the crushed stone produced in the United States are used in the construction industry. Natural aggregates are widely distributed throughout the United States in a variety of geologic environments. Sand and gravel deposits commonly are the results of the weathering of bedrock and subsequent transportation and deposition of the material by water or ice (glaciers). As such, they commonly occur as river or stream deposits or in glaciated areas as glaciofluvial and other deposits. Crushed stone aggregates are derived from a wide variety of parent bedrock materials. Limestone and other carbonates account for approximately three quarters of the rocks used for crushed stone, with granite and other igneous rocks making up the bulk of the remainder. Limestone deposits are widespread throughout the Central and Eastern United States and are scattered in the West. Granites are widely distributed in the Eastern and Western United States, with few exposures in the Midwest. Igneous rocks (excluding granites) are largely concentrated in the Western United States and in a few isolated localities in the East. Even though natural aggregates are widely distributed throughout the United States, they are not universally available for consumptive use. Some areas are devoid of sand and gravel, and potential sources of crushed stone may be covered with sufficient unconsolidated material to make surface mining impractical. In some areas many aggregates do not meet the physical property requirements for certain uses, or they may contain mineral constituents that react adversely when used as concrete aggregate. In areas where suitable natural aggregate is not available or accessible, it may become necessary to improve the quality of existing aggregate, to import aggregate from outside the area, or to substitute artificial aggregate for natural aggregate. In most cases, all of these alternatives add substantially to the cost of the final product. Even though an area may be blessed with an abundance of aggregate suitable for the intended purpose, existing land uses, zoning, or regulations may preclude commercial exploitation of the aggregate. This report also discusses the aggregate industry in general terms, including exploration, mining, and processing, as well as aggregate production rates. Proper long-range planning based on an understanding of the aggregate industry can help assure adequate supplies of aggregate.

conterminous United States↗

California State Waters Map Series — Drakes Bay and vicinity, California

In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow (to about 100 m) subsurface geology. The Drakes Bay and Vicinity map area is located in northern California, about 30 km north of San Francisco and about 65 km south of Fort Ross. The map area is in the northern part of the Gulf of the Farallones National Marine Sanctuary, and it includes all or parts of four California Marine Protected Areas. The largely undeveloped onshore part of the map area, which occupies much of the southern and southeastern parts of the Point Reyes peninsula, is used primarily for grazing, as well as recreation, as it is home to the Point Reyes National Seashore. The triangular Point Reyes peninsula, which lies completely west of the San Andreas Fault Zone, is bounded by the steep terrain of Inverness Ridge along its northeastern margin, Tomales Point at its northernmost tip, Point Reyes at its southwesternmost point, and Bolinas at its southern end. The landscape in between includes (from southeast to northwest) the sandy beaches along Drakes Bay, the estuaries of Drakes Estero and Estero de Limantour, and the long, windswept Point Reyes Beach, which is backed by an extensive dune field. The seafloor in the map area generally extends from the shoreline to water depths of about 40 to 50 m, except for the area south of the Point Reyes headland where water depths reach 60 to 70 m. This bathymetric gradient south and west of the Point Reyes headland is related to north-side-up motion along the Point Reyes Fault Zone. Except for the bathymetric gradient across the Point Reyes Fault Zone, the bedrock platform in the nearshore and inner shelf areas (50 to 60 m depth) is relatively flat (less than 1.0°) and is overlain by sand-sized to coarser grained sediment. Finer grained sediments are found in water depths greater than 60 m south of the Point Reyes headland, but they also extend into shallower (less than 40 m) water within Drakes Bay. Surficial and shallow sediments were deposited in the last about 21,000 years during the approximately 125-m sea-level rise that followed the last major lowstand associated with the Last Glacial Maximum, at which time the entire Drakes Bay and Vicinity map area was emergent and the shoreline was about 30 km south and west of the present-day shoreline. Tectonic influences that impact the shelf morphology and geology in the map area are related to local faulting, folding, uplift, and subsidence. Offshore of the Point Reyes headland, granitic basement rocks are offset vertically about 1.4 km along the Point Reyes Fault Zone; this uplift, combined with west-side-up offset on the San Andreas Fault Zone, has resulted in uplift of the Point Reyes peninsula and the adjacent shelf. Late Pleistocene uplift of marine terraces on the southern Point Reyes peninsula suggests active deformation of offshore structures west of the San Andreas Fault Zone. Pervasive stratal thinning within inferred uppermost Pliocene and Pleistocene deposits above the west strand of the Point Reyes Fault Zone suggests Quaternary active shortening of the curvilinear, northeast- to north-dipping Point Reyes Fault Zone. Lack of clear deformation in the uppermost Pleistocene and Holocene deposits suggests that activity along the Point Reyes Fault Zone has ceased or slowed since about 21,000 years ago. Seafloor habitats in the Drakes Bay and Vicinity map area range from unconsolidated continental-shelf sediment to hard substrate. Rocky-shelf outcrops and rubble are considered to be promising potential habitats for rockfish and lingcod, both of which are recreationally and commercially important species. Circulation over the continental shelf in the map area is dominated by the southward-flowing California Current, the eastern limb of the North Pacific Gyre. Associated upwelling brings cool, nutrient-rich waters to the surface, resulting in high biological productivity. The current flow generally is southeastward during the spring and summer; however, during the fall and winter, the otherwise persistent northwest winds are sometimes weak or absent, causing the California Current to move farther offshore and the Davidson Current, a weaker, northward-flowing countercurrent, to become active. Sediment transport in the map area largely is controlled by surface waves and tidal currents in the nearshore and, at depths greater than 20 to 30 m, by tidal and subtidal currents. In the map area, nearshore littoral drift of sand and coarse sediment is to the south, owing to the dominant west-northwest swell direction, and scour from large waves and tidal currents removes and redistributes sediment over large areas of the inner shelf. Tidal currents are particularly strong over the shelf in the map area, and they dominate the current regime in the nearshore. Further offshore, bottom currents generally flow to the northwest, distributing finer grained sediment accordingly.

California↗

Geologic Map of Oasis Valley Spring-Discharge Area and Vicinity, Nye County, Nevada

This map report presents the geologic framework of an area in southern Nye County, Nevada, that extends from the southern limit of the Oasis Valley spring-discharge site, northeastward to the southwest margin of the Pahute Mesa testing area, on the Nevada Test Site. This map adds new surficial mapping and revises bedrock mapping previously published as USGS Open-File Report 99-533-B. The locations of major concealed structures were based on a combination of gravity and magnetic data. This report includes a geologic discussion explaining many of the interpretations that are presented graphically on the map and sections. Additional discussion of the geologic framework of the Oasis Valley area can be found in an interpretive geophysical report and in a geologic report (USGS Open-File Report 99-533-A that was a companion product to the previously published version of this map. The map presented here covers nine 7.5-minute quadrangles centered on the Thirsty Canyon SW quadrangle. It is a compilation of one previously published quadrangle map and eight new quadrangle maps, two of which were published separately during the course of the study. The new bedrock mapping was completed by S.A. Minor from 1991 to 1995, by C.J. Fridrich from 1992 to 1998, and by P.L. Ryder from 1997 to 1998. New surficial-deposits mapping was completed by J.L. Slate and M.E. Berry in 1998 and 1999. The new bedrock and surficial mapping is partly a revision of several unpublished reconnaissance maps completed by Orkild and Swadley in the 1960's, and of previously published maps by Maldonado and Hausback (1990), Lipman and others (1966); and Sargent and Orkild (1976). Additionally, mapping of the pre-Tertiary rocks of northern Bare Mountain was compiled from Monsen and others (1992) with only minor modification. The cross sections were drawn to a depth of about 5 km below land surface at the request of hydrologists studying the Death Valley ground-water system. Below a depth of about 1 kilometer, surface constraints offer only faint guidance, and the deep interpretations shown are constrained primarily by geophysical data, and are model-dependent. The estimated thickness of the Tertiary volcanic and sedimentary strata is shown on the cross sections with an overlain blue line, which has a very rounded form because it was modeled from gravity data. Several small faults that appear on the map were omitted from the cross sections for the sake of clarity. Within the Oasis Valley basin alone, the pattern of domino-style faulting shown on the cross sections is based on an interpretation of aeromagnetic data, but is strictly schematic.

Scientific Investigations Map↗

Titanium mineral resources in heavy-mineral sands in the Atlantic coastal plain of the southeastern United States

This study examined titanium distribution in the Atlantic Coastal Plain of the southeastern United States; the titanium is found in heavy-mineral sands that include the minerals ilmenite (Fe 2+ TiO 3 ), rutile (TiO 2 ), or leucoxene (an alteration product of ilmenite). Deposits of heavy-mineral sands in ancient and modern coastal plains are a significant feedstock source for the titanium dioxide pigments industry. Currently, two heavy-mineral sands mining and processing operations are active in the southeast United States producing concentrates of ilmenite-leucoxene, rutile, and zircon. The results of this study indicate the potential for similar deposits in many areas of the Atlantic Coastal Plain. This study used the titanium analyses of 3,457 stream sediment samples that were analyzed as part of the U.S. Geological Survey’s National Geochemical Survey program. This data set was analyzed by an integrated spatial modeling technique known as Bayesian hierarchical modeling to map the regional-scale, spatial distribution of titanium concentrations. In particular, clusters of anomalous concentrations of titanium occur: (1) along the Fall Zone, from Virginia to Alabama, where metamorphic and igneous rocks of the Piedmont region contact younger sediments of the Coastal Plain; (2) a paleovalley near the South Carolina and North Carolina border; (3) the upper and middle Atlantic Coastal Plain of North Carolina; (4) the majority of the Atlantic Coastal Plain of Virginia; and (5) barrier islands and stretches of the modern shoreline from South Carolina to northeast Florida. The areas mapped by this study could help mining companies delimit areas for exploration.

Scientific Investigations Report↗

Geologic features and ground-water storage capacity of the Sacramento Valley, California

The Sacramento Valley constitutes the northern and smaller arm of the Central Valley of California. It is about 150 miles long by about 30 miles wide; and its area is about 5,000 square miles. The Sacramento Valley is drained by the Sacramento River, the largest in California, which rises west of Mount Shasta and flows southward to join the San Joaquin River near Suisun Bay and discharges through San Francisco Bay to the Pacific. Most of the valley floor is suitable for growing crops, and under irrigation the land is highly productive. The Sacramento Valley is underlain by sediments transported from the surrounding mountains by the Sacramento River and its tributaries. The floor of the valley slopes southward from about 300 feet above sea level at the north end near Red Bluff to sea level at Suisun Bay. The Sutter Buttes, which are erosional remnants of an old volcano rise to 2,132 feet above sea level near the center of the valley. The valley floor is not a featureless plain but is characterized by various types of topography, which have been assigned to four principal groups: 1, low hills and dissected alluvial uplands; 2, low alluvial plains and fans; 3, flood plains and natural levees; and 4, flood basins; a fifth and relatively minor group consists of the tidal Islands of the Sacramento-San Joaquin Delta, which are south of the principal area of investigation. The rocks that underlie the Sacramento Valley and the bordering mountains range from crystalline rocks of Paleozoic and Mesozoic age to unconsolidated alluvium of Recent age. These rocks have been subdivided into 20 geologic units which may be assigned to 2 broad categories: rocks that yield little water and rocks that yield water freely. The rocks of the first category are chiefly marine sedimentary rocks of Late Jurassic, Cretaceous, and Early Tertiary age and a basement complex of pre-Tertiary crystalline rocks. The rocks of the second category consist predominantly of nonmarine valley-filling sediments of late Tertiary and Quaternary age, which constitute the principal ground-water reservoir in the Sacramento Valley. The rocks that yield little or no water includes the following geologic units: 1, Basement complex of the Sierra Nevada (pre-Tertiary); 2, Shasta series (Lower Cretaceous); 3, Chico formation (Upper Cretaceous); 4, Paleocene series; 5, Eocene series (in part, water yielding); 6, basalt (Tertiary); 7, sedimentary rocks of volcanic origin on the west side of the Sacramento Valley (Tertiary, in part water yielding) ; 8, intrusive rhyolite and andesite and vent tuff of the Sutter Buttes (Pliocene); and 9, tuff-breccia of the Sutter Buttes (Pliocene, in part water yielding). The rocks that yield water freely, comprises the following geologic units: 1, Volcanic rocks from the Sierra Nevada (Eocene to Pliocene; in part yield little or no water); 2, Tuscan formation (Pliocene; in part yield little or no water); 3, Tehama formation (Pliocene); 4, Tehama formation and related continental sediments, undifferentiated (Pliocene and Pleistocene); 5, Laguna formation and related continental sediments (Pliocene and Pleistocene); 6, fanglomerate from the Cascade Range (Pleistocene); 7, Red Bluff formation (Pleistocene); 8, Victor formation and related deposits (Pleistocene); 9, alluvial-fan deposits (Pleistocene and Recent); 10, river deposits (Recent); and 11, flood-basin deposits (Recent). The volcanic rocks from the Sierra Nevada consist chiefly of andesitic and rhyolitic detritus. Most of these volcanic rocks are fragmental and were deposited either as mudflows or by streams. Their permeability is extremely variable, the poorly consolidated sandstone and conglomerate strata locally yield water copiously to wells, but the interbedded fine-grained and cemented strata are virtually impermeable and act as confining layers. The Tuscan formation, which occurs in the northeastern part of the valley, consists of fragmental andesitic and basaltic mate

Water Supply Paper↗

Geochemical characterization of tarballs on beaches along the California coast. Part I - Shallow seepage impacting the Santa Barbara Channel Islands, Santa Cruz, Santa Rosa and San Miguel

Tarballs are common along the southern California coastline. This study investigates tarballs from beaches along this coastline, with a focus on Santa Cruz, Santa Rosa, and San Miquel Islands in the Santa Barbara Channel. The tarballs were fingerprinted using biomarker and stable carbon isotope parameters, and then grouped according to genetic similarities. The data show that the tarballs are of natural and not anthropogenic origin and that all originate from source rock within the Miocene Monterey Formation via shallow seeps offshore. Sterane biomarker parameters were found to vary widely in the sample set. Biodegradation, especially of the regular steranes, is the primary process impacting the biomarker distributions in a large group of samples. The most common tarball occurrences appear to come from offshore seepage near the west end of Santa Cruz Island. Another major group most likely was transported north from near Santa Monica Bay. Several individual occurrences of some of these tarball groups also were found on beaches as far north as Pt. Reyes and as far south as San Diego, indicating significant long-distance dispersal by ocean currents. This study begins a library of tarball fingerprints to be used as a database to help distinguish between natural and anthropogenic tar occurrences all along the California coast, and to compare shallow seepage with future samples of deeper production oils from the same area.

Organic Geochemistry↗

Geochemical analysis of Atlantic rim water, Carbon County, Wyoming: New applications for characterizing coalbed natural gas reservoirs

Coalbed natural gas (CBNG) production typically requires the extraction of large volumes of water from target formations, thereby influencing any associated reservoir systems. We describe isotopic tracers that provide immediate data on the presence or absence of biogenic natural gas and the identify methane-containing reservoirs are hydrologically confined. Isotopes of dissolved inorganic carbon and strontium, along with water quality data, were used to characterize the CBNG reservoirs and hydrogeologic systems of Wyoming’s Atlantic Rim. Water was analyzed from a stream, springs, and CBNG wells. Strontium isotopic composition and major ion geochemistry identify two groups of surface water samples. Muddy Creek and Mesaverde Group spring samples are Ca-Mg-SO4–type water with higher 87Sr/86Sr, reflecting relatively young groundwater recharged from precipitation in the Sierra Madre. Groundwaters emitted from the Lewis Shale springs are Na-HCO3–type waters with lower 87Sr/86Sr, reflecting sulfate reduction and more extensive water-rock interaction. To distinguish coalbed waters, methanogenically enriched d13CDIC was used from other natural waters. Enriched d13CDIC, between −3.6 and +13.3‰, identified spring water that likely originates from Mesaverde coalbed reservoirs. Strongly positive d13CDIC, between +12.6 and +22.8‰, identified those coalbed reservoirs that are confined, whereas lower d13CDIC, between +0.0 and +9.9‰, identified wells within unconfined reservoir systems

Wyoming↗

Stratigraphy and palaeoclimatic significance of Late Quaternary loess-palaeosol sequences of the Last Interglacial-Glacial cycle in central Alaska

Loess is one of the most widespread subaerial deposits in Alaska and adjacent Yukon Territory and may have a history that goes back 3 Ma. Based on mineralogy and major and trace element chemistry, central Alaskan loess has a composition that is distinctive from other loess bodies of the world, although it is quartz-dominated. Central Alaskan loess was probably derived from a variety of rock types, including granites, metabasalts and schists. Detailed stratigraphic data and pedologic criteria indicate that, contrary to early studies, many palaeosols are present in central Alaskan loess sections. The buried soils indicate that loess sedimentation was episodic, or at least rates of deposition decreased to the point where pedogenesis could keep ahead of aeolian input. As in China, loess deposition and pedogenesis are likely competing processes and neither stops completely during either phase of the loess/soil formation cycle. Loess deposition in central Alaska took place before, and probably during the last interglacial period, during stadials of the mid-Wisconsin period, during the last glacial period and during the Holocene. An unexpected result of our geochronological studies is that only moderate loess deposition took place during the last glacial period. Our studies lead us to conclude that vegetation plays a key role in loess accumulation in Alaska. Factors favouring loess production are enhanced during glacial periods but factors that favour loess accumulation are diminished during glacial periods. The most important of these is vegetation; boreal forest serves as an effective loess trap, but sparsely distributed herb tundra does not. Thus, thick accumulations of loess should not be expected where tundra vegetation was dominant and this is borne out by modern studies near the treeline in central Alaska. Much of the stratigraphic diversity of North American loess, including that found in the Central Lowlands, the Great Plains, and Alaska is explained by a new model that emphasizes the relative importance of loess production factors versus loess accumulation factors.

Quaternary Science Reviews↗

Petroleum geology and resources of the Amu-Darya basin, Turkmenistan, Uzbekistan, Afghanistan, and Iran

The Amu-Darya basin is a highly productive petroleum province in Turkmenistan and Uzbekistan (former Soviet Union), extending southwestward into Iran and southeastward into Afghanistan. The basin underlies deserts and semideserts north of the high ridges of the Kopet-Dag and Bande-Turkestan Mountains. On the northwest, the basin boundary crosses the crest of the Karakum regional structural high, and on the north the basin is bounded by the shallow basement of the Kyzylkum high. On the east, the Amu-Darya basin is separated by the buried southeast spur of the Gissar Range from the Afghan-Tajik basin, which is deformed into a series of north-south-trending synclinoria and anticlinoria. The separation of the two basins occurred during the Neogene Alpine orogeny; earlier, they were parts of a single sedimentary province. The basement of the Amu-Darya basin is a Hercynian accreted terrane composed of deformed and commonly metamorphosed Paleozoic rocks. These rocks are overlain by rift grabens filled with Upper Permian-Triassic rocks that are strongly compacted and diagenetically altered. This taphrogenic sequence, also considered to be a part of the economic basement, is overlain by thick Lower to Middle Jurassic, largely continental, coal-bearing rocks. The overlying Callovian-Oxfordian rocks are primarily carbonates. A deep-water basin surrounded by shallow shelves with reefs along their margins was formed during this time and reached its maximum topographic expression in the late Oxfordian. In Kimmeridgian-Tithonian time, the basin was filled with thick evaporites of the Gaurdak Formation. The Cretaceous-Paleogene sequence is composed chiefly of marine clastic rocks with carbonate intervals prominent in the Valanginian, Barremian, Maastrichtian, and Paleocene stratigraphic units. In Neogene time, the Alpine orogeny on the basin periphery resulted in deposition of continental clastics, initiation of new and rejuvenation of old faults, and formation of most structural traps. A single total petroleum system is identified in the Amu-Darya basin. The system is primarily gas prone. Discovered gas reserves are listed by Petroconsultants (1996) at about 230 trillion cubic feet, but recent discoveries and recent reserve estimates in older fields should increase this number by 40 to 50 trillion cubic feet. Reserves of liquid hydrocarbons (oil and condensate) are comparatively small, less than 2 billion barrels. Most of the gas reserves are concentrated in two stratigraphic intervals, Upper Jurassic carbonates and Neocomian clastics, each of which contains about one-half of the reserves. Reserves of other stratigraphic units?from Middle Jurassic to Paleogene in age?are relatively small. Source rocks for the gas are the Lower to Middle Jurassic clastics and coal and Oxfordian basinal black shales in the east-central part of the basin. The latter is probably responsible for the oil legs and much of the condensate in gas pools. Throughout most of the basin both source-rock units are presently in the gas-window zone. Traps are structural, paleogeomorphic, and stratigraphic, as well as a combination of these types. The giant Dauletabad field is in a combination trap with an essential hydrodynamic component. Four assessment units were identified in the total petroleum system. One unit in the northeastern, northern, and northwestern marginal areas of the basin and another in the southern marginal area are characterized by wide vertical distribution of hydrocarbon pools in Middle Jurassic to Paleocene rocks and the absence of the salt of the Gaurdak Formation. The other two assessment units are stratigraphically stacked; they occupy the central area of the basin and are separated by the regional undeformed salt seal of the Gaurdak Formation. The largest part of undiscovered hydrocarbon resources of the Amu-Darya basin is expected in older of these assessment units. The mean value of total assessed resources of the Amu-Darya basin is estimated

Bulletin↗

Geologic map and digital database of the Porcupine Wash 7.5 minute Quadrangle, Riverside County, southern California

This data set maps and describes the geology of the Porcupine Wash 7.5 minute quadrangle, Riverside County, southern California. The quadrangle, situated in Joshua Tree National Park in the eastern Transverse Ranges physiographic and structural province, encompasses parts of the Hexie Mountains, Cottonwood Mountains, northern Eagle Mountains, and south flank of Pinto Basin. It is underlain by a basement terrane comprising Proterozoic metamorphic rocks, Mesozoic plutonic rocks, and Mesozoic and Mesozoic or Cenozoic hypabyssal dikes. The basement terrane is capped by a widespread Tertiary erosion surface preserved in remnants in the Eagle and Cottonwood Mountains and buried beneath Cenozoic deposits in Pinto Basin. Locally, Miocene basalt overlies the erosion surface. A sequence of at least three Quaternary pediments is planed into the north piedmont of the Eagle and Hexie Mountains, each in turn overlain by successively younger residual and alluvial deposits. The Tertiary erosion surface is deformed and broken by north-northwest-trending, high-angle, dip-slip faults and an east-west trending system of high-angle dip- and left-slip faults. East-west trending faults are younger than and perhaps in part coeval with faults of the northwest-trending set. The Porcupine Wash database was created using ARCVIEW and ARC/INFO, which are geographical information system (GIS) software products of Envronmental Systems Research Institute (ESRI). The database consists of the following items: (1) a map coverage showing faults and geologic contacts and units, (2) a separate coverage showing dikes, (3) a coverage showing structural data, (4) a scanned topographic base at a scale of 1:24,000, and (5) attribute tables for geologic units (polygons and regions), contacts (arcs), and site-specific data (points). The database, accompanied by a pamphlet file and this metadata file, also includes the following graphic and text products: (1) A portable document file (.pdf) containing a navigable graphic of the geologic map on a 1:24,000 topographic base. The map is accompanied by a marginal explanation consisting of a Description of Map and Database Units (DMU), a Correlation of Map and Database Units (CMU), and a key to point-and line-symbols. (2) Separate .pdf files of the DMU and CMU, individually. (3) A PostScript graphic-file containing the geologic map on a 1:24,000 topographic base accompanied by the marginal explanation. (4) A pamphlet that describes the database and how to access it. Within the database, geologic contacts , faults, and dikes are represented as lines (arcs), geologic units as polygons and regions, and site-specific data as points. Polygon, arc, and point attribute tables (.pat, .aat, and .pat, respectively) uniquely identify each geologic datum and link it to other tables (.rel) that provide more detailed geologic information.

California↗

Geology of the Mineral and Lake Anna West Quadrangles, Virginia

This map product is a cooperator series publication and, as such, does not have a specific abstract. Geologic mapping for this map product was completed between 2014 and 2017, with most of the field work occurring between January 2016 and May 2017. Numerous foot traverses were completed along creeks and roads throughout the field area; the shore of Lake Anna was accessed by kayak to provide additional data. Distributions of soil units were considered when assigning bedrock type in areas where outcrop was lacking and helped to distinguish fluvial terrace deposits. Hill-shade raster images created from LiDAR datasets and geophysical data sets proved useful in the field to trace bedrock and surficial units. GPS location control and field data were collected and recorded in digital databases using a variety of geologic mapping applications for an iPad 3rd Gen Model A1403 and Motion C5v tablet using Fieldmove 2013.1. Structural measurements were also plotted on field maps. Data collected included lithology and the orientation of foliations, folds, lineations, joints, and faults. Representative rock samples of significant formations were thin-sectioned for petrographic analysis; a few samples from these and surrounding quadrangles were analyzed for zircon U-Pb geochronology and geochemistry.

Virginia↗