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At least 1,189 records · Page 66Linked to original sources

Greenhouse gases generated from the anaerobic biodegradation of natural offshore asphalt seepages in southern California

Significant offshore asphaltic deposits with active seepage occur in the Santa Barbara Channel offshore southern California. The composition and isotopic signatures of gases sampled from the oil and gas seeps reveal that the coexisting oil in the shallow subsurface is anaerobically biodegraded, generating CO 2 with secondary CH 4 production. Biomineralization can result in the consumption of as much as 60% by weight of the original oil, with 13 C enrichment of CO 2 . Analyses of gas emitted from asphaltic accumulations or seeps on the seafloor indicate up to 11% CO 2 with 13 C enrichment reaching +24.8‰. Methane concentrations range from less than 30% up to 98% with isotopic compositions of –34.9 to –66.1‰. Higher molecular weight hydrocarbon gases are present in strongly varying concentrations reflecting both oil-associated gas and biodegradation; propane is preferentially biodegraded, resulting in an enriched 13 C isotopic composition as enriched as –19.5‰. Assuming the 132 million barrels of asphaltic residues on the seafloor represent ~40% of the original oil volume and mass, the estimated gas generated is 5.0×1010 kg (~76×109 m 3 ) CH 4 and/or 1.4×1011 kg CO 2 over the lifetime of seepage needed to produce the volume of these deposits. Geologic relationships and oil weathering inferences suggest the deposits are of early Holocene age or even younger. Assuming an age of ~1,000 years, annual fluxes are on the order of 5.0×107 kg (~76×106 m 3 ) and/or 1.4×108 kg for CH 4 and CO 2 , respectively. The daily volumetric emission rate (2.1×105 m 3 ) is comparable to current CH 4 emission from Coal Oil Point seeps (1.5×105 m 3 /day), and may be a significant source of both CH 4 and CO 2 to the atmosphere provided that the gas can be transported through the water column.

California↗

Looking for age-related growth decline in natural forests: unexpected biomass patterns from tree rings and simulated mortality

Forest biomass growth is almost universally assumed to peak early in stand development, near canopy closure, after which it will plateau or decline. The chronosequence and plot remeasurement approaches used to establish the decline pattern suffer from limitations and coarse temporal detail. We combined annual tree ring measurements and mortality models to address two questions: first, how do assumptions about tree growth and mortality influence reconstructions of biomass growth? Second, under what circumstances does biomass production follow the model that peaks early, then declines? We integrated three stochastic mortality models with a census tree-ring data set from eight temperate forest types to reconstruct stand-level biomass increments (in Minnesota, USA). We compared growth patterns among mortality models, forest types and stands. Timing of peak biomass growth varied significantly among mortality models, peaking 20–30 years earlier when mortality was random with respect to tree growth and size, than when mortality favored slow-growing individuals. Random or u-shaped mortality (highest in small or large trees) produced peak growth 25–30 % higher than the surviving tree sample alone. Growth trends for even-aged, monospecific Pinus banksiana or Acer saccharum forests were similar to the early peak and decline expectation. However, we observed continually increasing biomass growth in older, low-productivity forests of Quercus rubra, Fraxinus nigra, and Thuja occidentalis. Tree-ring reconstructions estimated annual changes in live biomass growth and identified more diverse development patterns than previous methods. These detailed, long-term patterns of biomass development are crucial for detecting recent growth responses to global change and modeling future forest dynamics.

Minnesota↗

Adaptive inference for distinguishing credible from incredible patterns in nature

Strong inference is a powerful and rapid tool that can be used to identify and explain patterns in molecular biology, cell biology, and physiology. It is effective where causes are single and separable and where discrimination between pairwise alternative hypotheses can be determined experimentally by a simple yes or no answer. But causes in ecological systems are multiple and overlapping and are not entirely separable. Frequently, competing hypotheses cannot be distinguished by a single unambiguous test, but only by a suite of tests of different kinds, that produce a body of evidence to support one line of argument and not others. We call this process "adaptive inference". Instead of pitting each member of a pair of hypotheses against each other, adaptive inference relies on the exuberant invention of multiple, competing hypotheses, after which carefully structured comparative data are used to explore the logical consequences of each. Herein we present an example that demonstrates the attributes of adaptive inference that have developed out of a 30-year study of the resilience of ecosystems.

Ecosystems↗

Statistical, economic and other tools for assessing natural aggregate

Quantitative aggregate resource assessment provides resource estimates useful for explorationists, land managers and those who make decisions about land allocation, which may have long-term implications concerning cost and the availability of aggregate resources. Aggregate assessment needs to be systematic and consistent, yet flexible enough to allow updating without invalidating other parts of the assessment. Evaluators need to use standard or consistent aggregate classification and statistic distributions or, in other words, models with geological, geotechnical and economic variables or interrelationships between these variables. These models can be used with subjective estimates, if needed, to estimate how much aggregate may be present in a region or country using distributions generated by Monte Carlo computer simulations.

Bulletin of Engineering Geology and the Environmen↗

Assessing climate-change risks to cultural and natural resources in the Yakima River Basin, Washington, USA

We provide an overview of an interdisciplinary special issue that examines the influence of climate change on people and fish in the Yakima River Basin, USA. Jenni et al. (2013) addresses stakeholder-relevant climate change issues, such as water availability and uncertainty, with decision analysis tools. Montag et al. (2014) explores Yakama Tribal cultural values and well-being and their incorporation into the decision-making process. Graves and Maule (2012) simulates effects of climate change on stream temperatures under baseline conditions (1981–2005) and two future climate scenarios (increased air temperature of 1 °C and 2 °C). Hardiman and Mesa (2013) looks at the effects of increased stream temperatures on juvenile steelhead growth with a bioenergetics model. Finally, Hatten et al. (2013) examines how changes in stream flow will affect salmonids with a rule-based fish habitat model. Our simulations indicate that future summer will be a very challenging season for salmonids when low flows and high water temperatures can restrict movement, inhibit or alter growth, and decrease habitat. While some of our simulations indicate salmonids may benefit from warmer water temperatures and increased winter flows, the majority of simulations produced less habitat. The floodplain and tributary habitats we sampled are representative of the larger landscape, so it is likely that climate change will reduce salmonid habitat potential throughout particular areas of the basin. Management strategies are needed to minimize potential salmonid habitat bottlenecks that may result from climate change, such as keeping streams cool through riparian protection, stream restoration, and the reduction of water diversions. An investment in decision analysis and support technologies can help managers understand tradeoffs under different climate scenarios and possibly improve water and fish conservation over the next century.

Washington↗

Projected changes in wildlife habitats in Arctic natural areas of northwest Alaska

We project the effects of transitional changes among 60 vegetation and other land cover types (“ecotypes”) in northwest Alaska over the 21st century on habitats of 162 bird and 39 mammal species known or expected to occur regularly in the region. This analysis, encompassing a broad suite of arctic and boreal wildlife species, entailed building wildlife-habitat matrices denoting levels of use of each ecotype by each species, and projecting habitat changes under historic and expected accelerated future rates of change from increasing mean annual air temperature based on the average of 5 global climate models under the A1B emissions scenario, and from potential influence of a set of 23 biophysical drivers. Under historic rates of change, we project that 52 % of the 201 species will experience an increase in medium- and high-use habitats, 3 % no change, and 45 % a decrease, and that a greater proportion of mammal species (62 %) will experience habitat declines than will bird species (50 %). Outcomes become more dire (more species showing habitat loss) under projections made from effects of biophysical drivers and especially from increasing temperature, although species generally associated with increasing shrub and tree ecotypes will likely increase in distribution. Changes in wildlife habitats likely will also affect trophic cascades, ecosystem function, and ecosystem services; of particular significance are the projected declines in habitats of most small mammals that form the prey base for mesocarnivores and raptors, and habitat declines in 25 of the 50 bird and mammal species used for subsistence hunting and trapping.

Alaska↗

Assimilation efficiency of rainbow trout fed natural diets

Assimilation efficiency is a critical assumption of stable isotope mixing models and bioenergetics models, yet few studies examine how assimilation efficiency influences modeling inferences. We conducted laboratory experiments to determine rainbow trout ( Oncorhynchus mykiss ) assimilation efficiencies. Assimilation efficiency averaged 55.8% (SE ± 0.90) and 64.5% (SE ± 1.98) at the 10% and 25% ration levels, respectively, and did not differ significantly. Caloric energy egested in feces was not significantly different between ration levels. Caloric energy excreted in ammonia and urea was significantly different between the ration levels, with a higher amount at the 25% ration level. Absorption efficiency was significantly greater at a higher ration level. Percent energy egested in feces was significantly greater at lower ration levels. Percent energy excreted as ammonia and urea was high compared to previous studies and did not differ significantly by ration level. Our estimates of assimilation efficiency of rainbow trout (56% and 65%) were lower than some previously reported estimates, and our estimates of energy losses (feces and ammonia) were higher than some previous estimates. As knowledge of species-specific assimilation efficiencies increases, our ability to draw strong inferences and improve the accuracy of model predictions will improve.

Environmental Biology of Fishes↗

Forest fire, thinning, and flood in wildland-urban interface: UAV and lidar-based estimate of natural disaster impacts

Context Wildland-urban interface (WUI) areas are facing increased forest fire risks and extreme precipitation events due to climate change, which can lead to post-fire flood events. The city of Flagstaff in northern Arizona, USA experienced WUI forest thinning, fire, and record rainfall events, which collectively contributed to large floods and damages to the urban neighborhoods and city infrastructure. Objectives We demonstrate multi-temporal, high resolution image applications from an unoccupied aerial vehicle (UAV) and terrestrial lidar in estimating landscape disturbance impacts within the WUI. Changes in forest vegetation and bare ground cover in WUIs are particularly challenging to estimate with coarse-resolution satellite images due to fine-scale landscape processes and changes that often result in mixed pixels. Methods Using Sentinel-2 satellite images, we document forest fire impacts and burn severity. Using 2016 and 2021 UAV multispectral images and Structure-from-Motion data, we estimate post-thinning changes in forest canopy cover, patch sizes, canopy height distribution, and bare ground cover. Using repeat lidar data within a smaller area of the watershed, we quantify geomorphic effects in the WUI associated with the fire and subsequent flooding. Results We document that thinning significantly reduced forest canopy cover, patch size, tree density, and mean canopy height resulting in substantially reduced active crown fire risks in the future. However, the thinning equipment ignited a forest fire, which burned the WUI at varying severity at the top of the watershed that drains into the city. Moderate-high severity burns occurred within 3 km of downtown Flagstaff threatening the WUI neighborhoods and the city. The upstream burned area then experienced 100-year and 200–500-year rainfall events, which resulted in large runoff-driven floods and sedimentation in the city. Conclusion We demonstrate that UAV high resolution images and photogrammetry combined with terrestrial lidar data provide detailed and accurate estimates of forest thinning and post-fire flood impacts, which could not be estimated from coarser-resolution satellite images. Communities around the world may need to prepare their WUIs for catastrophic fires and increase capacity to manage sediment-laden stormwater since both fires and extreme weather events are projected to increase.

Arizona↗

Wildlife as valuable natural resources vs. intolerable pests: A suburban wildlife management model

Management of wildlife in suburban environments involves a complex set of interactions between both human and wildlife populations. Managers need additional tools, such as models, that can help them assess the status of wildlife populations, devise and apply management programs, and convey this information to other professionals and the public. We present a model that conceptualizes how some wildlife populations can fluctuate between extremely low (rare, threatened, or endangered status) and extremely high (overabundant) numbers over time. Changes in wildlife abundance can induce changes in human perceptions, which continually redefine species as a valuable resource to be protected versus a pest to be controlled. Management programs thatincorporate a number of approaches and promote more stable populations of wildlife avoid the problems of the resource versus pest transformation, are less costly to society, and encourage more positive and less negative interactions between humans and wildlife. We presenta case example of the beaver Castor canadensis in Massachusetts to illustrate how this model functions and can be applied. ?? 2005 Springer Science + Business Media, Inc.

Urban Ecosystems↗

Natural disturbance shapes benthic intertidal macroinvertebrate communities of high latitude river deltas

Unlike lower latitude coastlines, the estuarine nearshore zones of the Alaskan Beaufort Sea are icebound and frozen up to 9 months annually. This annual freezing event represents a dramatic physical disturbance to fauna living within intertidal sediments. The main objectives of this study were to describe the benthic communities of Beaufort Sea deltas, including temporal changes and trophic structure. Understanding benthic invertebrate communities provided a baseline for concurrent research on shorebird foraging ecology at these sites. We found that despite continuous year-to-year episodes of annual freezing, these estuarine deltas are populated by a range of invertebrates that represent both marine and freshwater assemblages. Freshwater organisms like Diptera and Oligochaeta not only survive this extreme event, but a marine invasion of infaunal organisms such as Amphipoda and Polychaeta rapidly recolonizes the delta mudflats following ice ablation. These delta sediments of sand, silt, and clay are fine in structure compared to sediments of other Beaufort Sea coastal intertidal habitats. The relatively depauperate invertebrate community that ultimately develops is composed of marine and freshwater benthic invertebrates. The composition of the infauna also reflects two strategies that make life on Beaufort Sea deltas possible: a migration of marine organisms from deeper lagoons to the intertidal and freshwater biota that survive the 9-month ice-covered period in frozen sediments. Stable isotopic analyses reveal that both infaunal assemblages assimilate marine and terrestrial sources of organic carbon. These results provide some of the first quantitative information on the infaunal food resources of shallow arctic estuarine systems and the long-term persistence of these invertebrate assemblages. Our data help explain the presence of large numbers of shorebirds in these habitats during the brief summer open-water period and their trophic importance to migrating waterfowl and nearshore populations of estuarine fishes that are the basis of subsistence lifestyles by native inhabitants of the Beaufort Sea coast.

Estuaries and Coasts↗

Seismic reflection characteristics of naturally-induced subsidence affecting transportation

High-resolution seismic reflections have been used effectively to investigate sinkholes formed from the dissolution of a bedded salt unit found throughout most of Central Kansas. Surface subsidence can have devastating effects on transportation structures. Roads, rails, bridges, and pipelines can even be dramatically affected by minor ground instability. Areas susceptible to surface subsidence can put public safety at risk. Subsurface expressions significantly larger than surface depressions are consistently observed on seismic images recorded over sinkholes in Kansas. Until subsidence reaches the ground surface, failure appears to be controlled by compressional forces evidenced by faults with reverse orientation. Once a surface depression forms or dissolution of the salt slows or stops, subsidence structures are consistent with a tensional stress environment with prevalent normal faults. Detecting areas of rapid subsidence potential, prior to surface failure, is the ultimate goal of any geotechnical survey where the ground surface is susceptible to settling. Seismic reflection images have helped correlate active subsidence to dormant paleofeatures, project horizontal growth of active sinkholes based on subsurface structures, and appraise the risk of catastrophic failure. ?? China University of Geosciences (Wuhan) and Springer-Verlag GmbH 2009.

Conference Paper↗

Identifying natural and anthropogenic variability of uranium at the well scale, Homestake Superfund site, near Milan, New Mexico, USA

The San Mateo Creek Basin in New Mexico, USA is located within the Grants Mineral Belt-an area with numerous uranium (U) ore deposits, mines, and milling operations. Six monitoring wells set in an alluvial aquifer near the Homestake Mining Co. Superfund site in the lower San Mateo Creek Basin were logged with a suite of borehole geophysical tools including spectral gamma-ray (SGR), vertically profiled with passive samplers for U and selenium (Se) concentrations, and purged sampled for same constituents. The integrated approach allowed for an assessment on the role of heterogeneity (both physical and chemical) in determining U concentrations in groundwater. Uranium, as measured with SGR logging, is ubiquitous in the alluvial aquifer and the underlying Chinle Group. Aqueous U concentrations appear to be inversely related to thorium (Th) concentrations, as measured by the SGR log, indicating the possibility that U is bound in or adsorbed to clays in the aquifer. The stratigraphy of the alluvium likely plays a role in elevated concentrations of aqueous U. Interbedded clay and sand layers allow for the mobilization of U in oxic sandy layers from U adsorbed in sediments in reduced clay layers. The stratigraphy also plays a role in the degree of mixing of groundwater in the formation and well. Mixing can obscure the ability to identify U sources. Mixing is exacerbated by the relatively long screens (> 20 ft long or > 6.1 m) of the monitoring wells.

New Mexico↗

The nature, distribution, and origin of gas hydrate in the Chile Triple Junction region

A bottom simulating reflector (BSR) is regionally distributed throughout much of the Chile Triple Junction (CTJ) region. Downhole temperature and logging data collected during Ocean Drilling Program (ODP) Leg 141 suggest that the seismic BSR is generated by low seismic velocities associated with the presence of a few percent free gas in a ??? 10 m thick zone just beneath the hydrate-bearing zone. The data also indicate that the temperature and pressure at the BSR best corresponds to the seawater/methane hydrate stability field. The origin of the large amounts of methane required to generate the hydrates is, however, problematic. Low total organic carbon contents and low alkalinities argue against significant in situ biogenic methanogenesis, but additional input from thermogenic sources also appears to be precluded. Increasing thermal gradients, associated with the approach of the spreading ridge system, may have caused the base of the hydrate stability field to migrate 300 m upwards in the sediments. We propose that the upward migration of the base of the stability field has concentrated originally widely dispersed hydrate patches into the more continuous hydrate body we see today. The methane can be concentrated if the gas hydrates can form from dissolved methane, transported into the hydrate zone via diffusion or fluid advection. A strong gradient may exist in dissolved methane concentration across the BSR leading to the steady reabsorbtion of the free gas zone during the upward migration of the BSR even in the absence of fluid advection.

Earth and Planetary Science Letters↗

Retention of lead during oxidative ashing of selected naturally occurring carbonaceous substances

The amount of lead retained in the ash of lead-bearing carbonaceous material is essentially independent of the method of ashing. Samples containing lead in the range of 0.00X to 0.X per cent were ashed by ignition in a high-oxygen atmosphere and were also wet-ashed. The lead in the ash was determined colorimetrically. Results were the same by both methods, but the time required is 3 to 10 times less for the dry-ashing method.

Geochimica et Cosmochimica Acta↗

Some natural variations in the relative abundance of copper isotopes

The relative isotopic abundance of copper has been measured in a number of minerals and a few plant materials. Suites of samples from Michigan and the Colorado Plateau have been examined in more detail to determine if local variations due to isotopic exchange or diffusion could be found. The relative isotopic abundance of copper in specimens from several other localities was also determined. The variations noted were small but in some cases were felt to be significant because they were larger than the experimental error (0·1 per cent in the ratio). A total spread of −1 to +8 parts per mil compared to the standard was found in the specimens tested.

Geochimica et Cosmochimica Acta↗

The contribution of humic substances to the acidity of colored natural waters

An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated.

Geochimica et Cosmochimica Acta↗

Thermal stability of hydrocarbons in nature: Limits, evidence, characteristics, and possible controls

Numerous petroleum-geochemical analyses of deeply buried, high-rank, fine-grained rocks from ultra-deep wellbores by different investigators demonstrate that C 15 + hydrocarbons (HCs) persist in moderate to high concentrations at vitrinite reflectance ( R 0 ) values of 2.0–5.0% and persist in measurable concentrations up to R 0 = 7.0–8.0%, at which point the thermal deadline for C 15 + HC's is finally approached. Qualitative analyses have been carried out on 1. (1) high-rank gas condensates which have been exposed to the HC-thermal-destructive phase, 2. (2) bitumens from high-temperature aqueous-pyrolysis experiments in the HC-thermal-destructive phase, and 3. (3) bitumens from high-rank, fine-grained rocks near the HC-thermal-destructive phase. These analyses clearly demonstrate that well-defined compositional suites are established in the saturated, aromatic, and sulfur-bearing aromatic HCs in and near the HC-thermal-destructive phase. On the other hand, accepted petroleum-geochemical paradigms place rigid limits on HC thermal stability: C 15 + HCs begin thermal cracking at R 0 values of 0.9% and are completely thermally destroyed by R 0 = 1.35%; C 2 -C 4 HC gases are thermally destroyed by R 0 = 2.0% and methane is thermally destroyed by R 0 = 4.0%. Furthermore, published data and observations in many HC basins worldwide support these models; for example, 1. (1) sharp basinal zonations of gas and oil deposits vs. maturation rank in HC basins and 2. (2) decreasing C 15 + HC concentrations in some fine-grained rocks at ranks of R 0 ≥ 0.9%. The fact that observed data (C 15 + HCs thermally stable to R 0 = 7.0–8.0%) is so far removed from predicted behavior (C 15 + ) HCs expected to be thermally destroyed by R 0 = 1.35%) may be due to 1. (1) a lack of recognition of some important possible controlling parameters of organic matter (OM) metamorphism and too much importance given to other assumed controlling parameters; and 2. (2) assigning HC distribution patterns in petroleum basins to HC thermal cracking when such patterns may be due to other causes. In the first case, laboratory experiments strongly suggest that the presence of water, increasing fluid pressures, and closed systems (product retention) all suppress OM metamorphic reactions. Conversely, the absence of water, low fluid pressures, and open systems (product escape) all promote OM metamorphic reactions. These experiments also demonstrate that OM metamorphic reactions proceed by reaction kinetics greater than first order. Thus, the effect of geologic time appears to have been over-estimated in OM metamorphism. In the second case, the strong decreases in C 15 + HC concentrations in fine-grained rocks with Type III OM over R 0 = 0.9−1.35% are most probably due to intense primary migration and loss of HCs to drilling muds during the trip uphole in drilling operations. Data from coals demonstrate that these decreases in HC concentrations cannot be due to C 15 + HC thermal destruction. Oil deposits are generally found at shallow depths in basins, and “dry gas” (methane ≤ 98% of all HC gases) deposits are found at the greatest depths. This HC distribution pattern would be caused by methane, generated during the late stages of C 15 + HC generation, flushing oil (including C 2 –C 4 HC gases condensed into the liquid phase) out of deep basinal traps by Gussow's (1954) principle of differential entrapment. Hence, only “dry gas” deposits are left in the basin deeps. Oil emplacement processes in traps during expulsion and secondary migration could also contribute to the HC distribution pattern observed in petroleum basins.

Geochimica et Cosmochimica Acta↗