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USGS2004

Hydrology and ground-water quality in the mine workings within the Picher Mining District, Northeastern Oklahoma, 2002-03

The Picher mining district of northeastern Ottawa County, Oklahoma, was a major site of mining for lead and zinc ores in the first half of the 20th century. The primary source of lead and zinc were sulfide minerals disseminated in the cherty limestones and dolomites of the Boone Formation of Mississippian age, which comprises the Boone aquifer. Ground water in the aquifer and seeping to surface water in the district has been contaminated by sulfate, iron, lead, zinc, and several other metals. The U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, investigated hydrology and ground-water quality in the mine workings in the mining district, as part of the process to aid water managers and planners in designing remediation measures that may restore the environmental quality of the district to pre-mining conditions. Most ground-water levels underlying the mining district had similar altitudes, indicating a large degree of hydraulic connection in the mine workings and overlying aquifer materials. Recharge-age dates derived from concentrations of chlorofluorocarbons and other dissolved gases indicated that water in the Boone aquifer may flow slowly from the northeast and southeast portions of the mining district. However, recharge-age dates may have been affected by the types of sites sampled, with more recent recharge-age dates being associated with mine-shafts, which are more prone to atmospheric interactions and surface runoff than the sampled airshafts. Water levels in streams upstream from the confluence of Tar and Lytle Creeks were several feet higher than those in adjacent portions of the Boone aquifer, perhaps due to low-permeability streambed sediments and indicating the streams may be losing water to the aquifer in this area. From just upstream to downstream from the confluence of Tar and Lytle Creeks, surface-water elevations in these streams were less than those in the surrounding Boone aquifer, indicating that seepage from the aquifer to downstream portions of Tar Creek was much more likely. Water properties and major-ion concentrations indicate that water in the mining area was very hard, with large concentrations of dissolved solids that increased from areas of presumed recharge toward areas with older ground water. Most of the ground-water samples, particularly those from the airshafts, had dissolved-oxygen concentrations less than 1.0 milligram per liter. Small concentrations of dissolved oxygen may have been introduced during the sampling process. The small dissolved-oxygen concentrations were associated with samples containing large iron concentrations that indicates possible anoxic conditions in much of the aquifer. Ground water in the mining district was dominated by calcium, magnesium, and sulfate. Sodium concentrations tended to increase relative to calcium and magnesium concentrations. Ground-water samples collected in 2002-03 had large concentrations of many trace elements. Larger concentrations of metals and sulfate occurred in ground water with smaller pHs and dissolved-oxygen concentrations. Iron was the metal with the largest concentrations in the ground-water samples, occurring at concentrations up to 115,000 micrograms per liter. Cadmium, lead, manganese, zinc, and the other analyzed metals occurred in smaller concentrations in ground water than iron. However, larger cadmium concentrations appeared to be associated with sites that have small iron concentrations and more oxygenated waters. This is noteworthy because the small sulfate and iron concentrations in these waters could lead to conclusions that the waters are less contaminated than waters with large sulfate and iron concentrations. Ground-water quality in the mining district was compared with subsets of samples collected in 1983-85 and in 2002.

Oklahoma↗

USGS1998

Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate (NO2+NO3-N) in ground water in the Idaho part of the upper Snake River basin

Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, cyanazine, metolachlor, and simazine. This study developed maps that the Idaho State Department of Agriculture might use to predict the probability of detecting atrazine and desethyl-atrazine (a breakdown product of atrazine) in ground water in the Idaho part of the upper Snake River Basin. These maps can be incorporated in the State Pesticide Management Plan and help provide a sound hydrogeologic basis for atrazine management in the study area. Maps showing the probability of detecting atrazine/desethyl-atrazine in ground water were developed as follows: (1) Ground-water monitoring data were overlaid with hydrogeologic and anthropogenic data using a geographic information system to produce a data set in which each well had corresponding data on atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Individual (univariate) relations between atrazine/desethyl-atrazine in ground water and atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth data were evaluated to identify those independent variables significantly related to atrazine/ desethyl-atrazine detections. (3) Several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected. (5) The multivariate models were entered into the geographic information system and the probability maps were constructed. Two models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected; one with and one without atrazine use. Correlations of the predicted probabilities of atrazine/desethyl-atrazine in ground water with the percent of actual detections were good; r-squared values were 0.91 and 0.96, respectively. Models were verified using a second set of groundwater quality data. Verification showed that wells with water containing atrazine/desethyl-atrazine had significantly higher probability ratings than wells with water containing no atrazine/desethylatrazine (p <0.002). Logistic regression also was used to develop a preliminary model to predict the probability of nitrite plus nitrate as nitrogen concentrations greater than background levels of 2 milligrams per liter. A direct comparison between the atrazine/ desethyl-atrazine and nitrite plus nitrate as nitrogen probability maps was possible because the same ground-water monitoring, hydrogeologic, and anthropogenic data were used to develop both maps. Land use, precipitation, soil hydrologic group, and well depth were significantly related with atrazine/desethyl-atrazine detections. Depth to water, land use, and soil drainage were signifi- cantly related with elevated nitrite plus nitrate as nitrogen concentrations. The differences between atrazine/desethyl-atrazine and nitrite plus nitrate as nitrogen relations were attributed to differences in chemical behavior of these compounds in the environment and possibly to differences in the extent of use and rates of their application.

Idaho↗

USGS2000

Design, revision, and application of ground-water flow models for simulation of selected water-management scenarios in the coastal area of Georgia and adjacent parts of South Carolina and Florida

Ground-water flow models of the Floridan aquifer system in the coastal area of Georgia and adjacent parts of South Carolina and Florida, were revised and updated to ensure consistency among the various models used, and to facilitate evaluation of the effects of pumping on the ground-water level near areas of saltwater contamination. The revised models, developed as part of regional and areal assessments of ground-water resources in coastal Georgia, are--the Regional Aquifer-System Analysis (RASA) model, the Glynn County area (Glynn) model, and the Savannah area (Savannah) model. Changes were made to hydraulic-property arrays of the RASA and Glynn models to ensure consistency among all of the models; results of theses changes are evidenced in revised water budgets and calibration statistics. Following revision, the three models were used to simulate 32 scenarios of hypothetical changes in pumpage that ranged from about 82 million gallons per day (Mgal/d) lower to about 438 Mgal/d higher, than the May 1985 pumping rate of 308 Mgal/d. The scenarios were developed by the Georgia Department of Natural Resources, Environmental Protection Division and the Chatham County-Savannah Metropolitan Planning Commission to evaluate water-management alternatives in coastal Georgia. Maps showing simulated ground-water-level decline and diagrams presenting changes in simulated flow rates are presented for each scenario. Scenarios were grouped on the basis of pumping location--entire 24-county area, central subarea, Glynn-Wayne-Camden County subarea, and Savannah-Hilton Head Island subarea. For those scenarios that simulated decreased pumpage, the water level at both Brunswick and Hilton Head Island rose, decreasing the hydraulic gradient and reducing the potential for saltwater contamination. Conversely, in response to scenarios of increased pumpage, the water level at both locations declined, increasing the hydraulic gradient and increasing the potential for saltwater contamination. Pumpage effects on ground-water levels and related saltwater contamination at Brunswick and Hilton Head Island generally diminish with increased distance from these areas. Additional development of the Upper Floridan aquifer may be possible in parts of the coastal area without affecting saltwater contamination at Brunswick or Hilton Head Island, due to the presence of two hydrologic boundaries--the Gulf Trough, separating the northern and central subareas; and the hypothesized Satilla Line, separating the central and southern subareas. These boundaries diminish pumpage effects across them; and may enable greater ground-water withdrawal in areas north of the Gulf Trough and south of the Satilla Line without producing appreciable drawdown at Brunswick or Hilton Head Island.

Florida, Georgia, South Carolina↗

USGS2001

Ammonia in ground water from the Mississippi River alluvium, Fort Madison, Iowa

The U.S. Geological Survey, in cooperation with the City of Fort Madison, conducted a study of the potential sources and possible processes that might produce ammonia in ground water from the Mississippi River alluvium near Fort Madison, Iowa. High ammonia concentrations of 3.0 to 6.4 milligrams per liter were detected in water produced from municipal well Fort Madison #4 from 1992 through 1996. Total organic carbon concentrations of about 5 milligrams per liter were also reported during the same time period. Water-level measurements from two municipal wells and one well at Iowa State Penitentiary were used to determine that the general direction of ground-water flow during the two days of sampling was from northeast to southwest toward wells Fort Madison #4 and Fort Madison #5. Continuous pumping of other nearby wells probably influenced the direction of ground-water flow on these days. Because of a till confining unit separating the Mississippi River and the alluvial aquifer, it is uncertain to what extent induced recharge occurs to the alluvial aquifer from the river. Water samples were collected from three municipal wells, two industrial wells, one watersupply well at the Iowa State Penitentiary, one domestic well, two creeks, and the Mississippi River. Tritium analytical results indicate that the time of recharge was after 1953 for water from the municipal wells (where tritium samples were collected). The ammonia concentration, 5.1 milligrams per liter, was considerably higher in ground water collected from well Fort Madison #4 compared to samples collected from other wells. The dissolved organic carbon concentration was also highest in ground water collected from well Fort Madison #4 (5.5 milligrams per liter) although samples from other wells were also relatively high, 2.6 to 5.3 milligrams per liter. The most likely process producing the high ammonia concentration in ground water in the vicinity of well Fort Madison #4 is decomposition of organic matter (ammonification). Nitrogen isotope values, when compared to nitrogen isotope values found in ground water in the vicinity of some of the other wells, indicate the possibility that a higher percentage of the ammonia found in ground water in the vicinity of well Fort Madison #4 may be from human and(or) other animal wastes. Higher concentrations of dissolved phosphorus, orthophosphate, and a higher chloride-to-sodium mole ratio found in ground water sampled from well Fort Madison #4 could be indicative of a sewage or septic source. Potential sources include existing or abandoned septic systems, leaking sanitary sewer lines, commercial or residential waste-disposal sites, and agricultural runoff upgradient from well Fort Madison #4, or possibly, bed sediments of the Mississippi River.

Iowa↗

USGS2006

Studying ground water under Delmarva coastal bays using electrical resistivity

Fresh ground water is widely distributed in subsurface sediments below the coastal bays of the Delmarva Peninsula (Delaware, Maryland, and Virginia). These conditions were revealed by nearly 300 km of streamer resistivity surveys, utilizing a towed multichannel cable system. Zones of high resistivity displayed by inversion modeling were confirmed by vibradrilling investigations to correspond to fresh ground water occurrences. Fresh water lenses extended from a few hundred meters up to 2 km from shore. Along the western margins of coastal bays in areas associated with fine-grained surficial sediments, high-resistivity layers were widespread and were especially pronounced near tidal creeks. Fresh ground water layers were less common along the eastern barrier-bar margins of the bays, where sediments were typically sandy. Mid-bay areas in Chincoteague Bay, Maryland, did not show evidence of fresh water. Indian River Bay, Delaware, showed complex subsurface salinity relationships, including an area with possible hypersaline brines. The new streamer resistivity system paired with vibradrilling in these investigations provides a powerful approach to recovering information required for extension of hydrologic modeling of shallow coastal aquifer systems into offshore areas.

Delaware, Maryland, Virginia↗

USGS1959

The relation between fresh and salty ground water in southern Nassau and southeastern Queens counties, Long Island, New York

An investigation of the geology and ground - water conditions in a part of southwestern Long Island , including the construction of 8 deep and 5 shallow test and observation wells, has been completed by the Geological Survey in cooperation with the Nassau County Department of Public Works and the New York State Water Power and Control Commission. In this area are four main water -bearing units of Late Cretaceous and Pleistocene age. Ground water having a higher than normal salt content is encountered in some wells that penetrate the upper three units. Although the presence of this water constitutes a potential threat, existing fresh - water supplies apparently are in little immediate danger under present conditions. The " salty " ground water has chloride concentrations ranging from about 40 to 18,000 ppm (parts per million), generally more than about 2,000 ppm. It occurs in several bodies, seaward of and beneath the fresh water in the respective aquifers, and is in contact with the fresh water through zones of diffusion. The largest salt- water body, confined under artesian pressure, is in the Jameco gravel and the Magothy (?) formation beneath extreme southwestern Nassau County and adjoining southeastern Queens County . This body is thought to have occupied a substantial part of its present extent since at least 1895. It probably has been and is now encroaching, very slowly, because of increased pumping from the fresh - water bodies and possibly as a result of a postglacial rise of sea level. The rate of encroachment under present conditions probably is less than 100 feet per year. Application of the Ghyben-Herzberg principle to compute depths to the contact between salty and fresh ground water was found to give erroneous results. More accurate depths and a clearer understanding of the relation between heads in adjoining bodies of fresh and salty ground water are obtained by use of a formula adapted from one given by M. King Hubbert.

New York↗

USGS1999

Characterizing hydrology and the importance of ground-water discharge in natural and constructed wetlands

Although considered the most important component for the establishment and persistence of wetlands, hydrology has been hard to characterize and linkages between hydrology and other environmental conditions are often poorly understood. In this work, methods for characterizing a wetland’s hydrology from hydrographs were developed, and the importance of ground water to the physical and geochemical conditions in the root zone was investigated. Detailed sampling of nearly continuous hydrographs showed that sites with greater ground-water discharge had higher water tables and more stable hydrographs. Subsampling of the continuous hydrograph failed to characterize the sites correctly, even though the wetland complex is located in a strong regional ground-water-discharge area. By comparing soil-moisture-potential measurements to the water-table hydrograph at one site, we noted that the amount of root-zone saturation was not necessarily driven by the water-table hydrograph but can be a result of other soil parameters (i.e., soil texture and associated capillary fringe). Ground-water discharge was not a significant determinant of maximum or average temperatures in the root zone. High ground-water discharge was associated with earliest date of thaw and shortest period of time that the root zone was frozen, however. Finally, the direction and magnitude of shallow ground-water flow was found to affect the migration and importance of a geochemical species. Areas of higher ground-water discharge had less downward penetration of CO 2 generated in the root zone. In contrast, biotically derived CO 2 was able to penetrate the deeper ground-water system in areas of ground-water recharge. Although ground-water flows are difficult to characterize, understanding these components is critical to the success of wetland restoration and creation efforts.

Wisconsin↗

USGS1997

Evaluation of the U.S. Geological Survey Ground-Water Data-Collection Program in Hawaii, 1992

In 1992, the U.S. Geological Survey ground-water data-collection program in the State of Hawaii consisted of 188 wells distributed among the islands of Oahu, Kauai, Maui, Molokai, and Hawaii. Water-level and water-quality (temperature, specific conductance, and chloride concentration) data were collected from observation wells, deep monitoring wells that penetrate the zone of transition between freshwater and saltwater, free-flowing wells, and pumped wells. The objective of the program was to collect sufficient spatial and temporal data to define seasonal and long-term changes in ground-water levels and chloride concentrations induced by natural and human-made stresses for different climatic and hydrogeologic settings. Wells needed to meet this objective can be divided into two types of networks: (1) a water-management network to determine the response of ground-water flow systems to human-induced stresses, such as pumpage, and (2) a baseline network to determine the response of ground-water flow systems to natural stresses for different climatic and hydrogeologic settings. Maps showing the distribution and magnitude of pumpage and the distribution of proposed pumped wells are presented to identify areas in need of water-management networks. Wells in the 1992 U.S. Geological Survey ground-water data-collection program were classified as either water-management or baseline network wells. In addition, locations where additional water-management network wells are needed for water-level and water-quality data were identified.

Water-Resources Investigations Report↗

USGS2004

Source and Movement of Ground Water in the Western Part of the Mojave Desert, Southern California, USA

Delta oxygen-18 and delta deuterium composition of precipitation and water from wells in the Mojave River and the Morongo ground-water basins in the western part of the Mojave Desert show that ground-water recharge occurs primarily from winter precipitation near low-altitude passes in the San Bernardino and the San Gabriel Mountains?as opposed to runoff from higher altitudes in the mountains. The resulting deuterium composition of the ground water, about -64 per mil, contrasts sharply with the isotopic composition of water from wells recharged by runoff from higher altitudes of the San Gabriel and the San Bernardino Mountains, about -84 per mil. These differences define the 3-dimensional movement of ground water between aquifers especially downgradient from faults that act as barriers to ground-water flow. Water recharged from runoff in the mountains farther to the east in the Mojave Desert plots to the right of the meteoric water line and after accounting for evaporative effects had an isotopic composition lighter than present-day precipitation.

Water-Resources Investigations Report↗

USGS2005

Hydrogeology and quality of ground water in the upper Arkansas River basin from Buena Vista to Salida, Colorado, 2000-2003

The upper Arkansas River Basin between Buena Vista and Salida, Colorado, is a downfaulted basin, the Buena Vista-Salida structural basin, located between the Sawatch and Mosquito Ranges. The primary aquifers in the Buena Vista-Salida structural basin consist of poorly consolidated to unconsolidated Quaternary-age alluvial and glacial deposits and Tertiary-age basin-fill deposits. Maximum thickness of the alluvial, glacial, and basin-fill deposits is about 5,000 feet, but 95 percent of the water-supply wells in Chaffee County are no more than 300 feet deep. Hydrologic conditions in the 149-square mile study area are described on the basis of hydrologic and geologic data compiled and collected during September 2000 through September 2003. The principal aquifers described in this report are the alluvial-outwash and basin-fill aquifers. An estimated 3,443 wells pumped about 690 to 1,240 acre-feet for domestic and household use in Chaffee County during 2003. By 2030, projected increases in the population of Chaffee County, Colorado, may require use of an additional 4,000 to 5,000 wells to supply an additional 800 to 1,800 acre-feet per year of ground water for domestic and household supply. The estimated specific yield of the upper 300 feet of the alluvial-outwash and basin-fill aquifers ranged from about 0.02 to 0.2. Current (2003) and projected (2030) ground-water withdrawals by domestic and household wells are less than 1 percent of the estimated 472,000 acre-feet of drainable ground water in the upper 300 feet of the subsurface. Locally, little water is available in the upper 300 feet. In densely populated areas, well interference could result in decreased water levels and well yields, which may require deepening or replacement of wells. Infiltration of surface water diverted for irrigation and from losing streams is the primary source of ground-water recharge in the semiarid basin. Ground-water levels in the alluvial-outwash and basin-fill aquifers vary seasonally with maximum water levels occurring in the early summer after snowmelt runoff peaks. Because of the drought during 2002, relatively large declines in ground-water levels occurred in about one-half of the monitored wells. Differences in water-level altitudes in shallow and deep wells indicate the potential for downward flow in upland areas and support results of preliminary cross-sectional models of ground-water flow. The apparent mean age of ground-water recharge ranged from about 1 to more than 48 years before 2001. The older (pre-1953) water was from wells that were located in ground-water discharge areas. Ground-water flow in the Buena Vista-Salida structural basin drains eastward toward the Arkansas River and, locally, toward the South Arkansas River. Ground water in the alluvial-outwash and basin-fill aquifers generally is calcium-bicarbonate water type with less than 250 milligrams per liter dissolved solids. Nitrate concentrations generally were less than 1 to 2 milligrams per liter and do not indicate widespread contamination of ground water from surface sources.

Scientific Investigations Report↗

USGS1984

Maps showing ground-water levels, springs, and depth to water, Basin and Range Province, Oregon

This report on ground-water levels, springs and depth to ground water in the Basin and Range province of Oregon (see index map) was prepared as part of a program of the U.S. Geological Survey to identify prospective regions for further study relative to isolation of high level nuclear waste (Bedinger, Sargent, and Reed, 1984), utilizing program guidelines defined in Sargent and Bedinger (1984). Also included in this report are selected references on pertinent geologic and hydrologic studies of the region. Other map reports in this series contain detailed data on ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources.

Oregon↗

USGS1993

Geology and ground-water resources in the Zebulon area, Georgia

The current (1991) surface-water source of drinking-water supply for the city of Zebulon, Pike County, Georgia, no longer provides an adequate water supply and periodically does not meet water-quality standards. The hydrogeology of crystalline rocks in the Zebulon area was evaluated to assess the potential of ground-water resources as a supplemental or alternative source of water to present surface-water supplies. As part of the ground-water resource evaluation, well location and construction data were compiled, a geologic map was constructed, and ground water was sampled and analyzed. Three mappable geologic units delineated during this study provide a basic understanding of hydrogeologic settings in the Zebulon area. Rock types include a variety of aluminosilicate schists, granitic rocks, amphibolites/honblende gneisses, and gondites. Several geologic features that may enhance ground-water availability were identified in the study area. These features include contacts between contrasting rock types, where a high degree of differential weathering has occurred, and well-developed structural features, such as foliation and jointing are present. High-yielding wells (greater than 25 gallons per minute) and low-yielding wells (less than one gallon per minute) were located in all three geologic units in a variety of topographic settings. Well yields range from less than one gallon per minute to 250 gallons per minute. The variable total depths and wide ranges of casing depths of the high-yielding wells are indicative of variations in depths to water-bearing zones and regolith thicknesses, respectively. The depth of water-bearing zones is highly variable, even on a local scale. Analyses of ground-water samples indicate that the distribution of iron concentration is as variable as well yield in the study area and does not seem to be related to a particular rock type. Iron concentrations in ground-water samples ranged from 0.02 to 5.3 milligrams per liter. Both iron concentration and well yield vary substantially over a relatively small area. Implementation and Verification of a One-Dimensional, Unsteady-Flow Model for Spring Brook near Warrenville, Illinois By Mary J. Turner, Anthony P. Pulokas, and Audrey L. Ishii Abstract A one-dimensional, unsteady-flow model, Full EQuations (FEQ) model, based on de Saint-Venant equations for dynamic flow in open channels, was calibrated and verified for a 0.75-mile reach of Spring Brook, a tributary to the West Branch Du Page River, near Warrenville in northeastern Illinois. The model was used to simulate streamflow in a small urban stream reach with two short culverts, one with overbank flow around the culvert during high flows. Streamflow data were collected on the reach during three high-flow periods. Data from one period were used to calibrate the model, and data from the other two periods were used to verify the model. Stages and discharges over the periods were simulated, and the results were compared graphically with stage and discharge data collected at 10 sites in the study reach. Errors in simulated stage and discharge were small except when debris, not represented in the model, clogged the culvert. The effects of changes in physical and computational model parameters also were studied. The model was insensit'lve to replacement of measured cross sections with interpolated cross sections, especially if the measured thalweg elevation was preserved. Variation of the roughness, slope, and length of the culvert over-bank section, as well as the chosen representative measured cross section, caused only slight changes in the simulated peak stage and discharge. Changes in the modeled culvert area caused large differences in the simulated highflows in the vicinity of the culvert, whereas simulated low flows were unaffected. At all flows, the misrepresentation of the culvert area caused the simulated water-surface elevations to deviate from the measured elevations, especially on the falling

Georgia↗

USGS1984

Maps showing ground-water levels, springs, and depth to water, Basin and Range Province, Nevada

This report on ground-water levels, springs and depth to ground water in the Basin and Range province of Nevada (see index map) was prepared as part of a program of the U.S. Geological Survey to identify prospective regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984), utilizing program guidelines defined in Sargent and Bedinger (1984). Also included in this report are selected references on pertinent geologic and hydrologic studies of the region. Other map reports in this series contain detailed data on ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources.

Nevada↗

USGS2001

Low-Level Volatile Organic Compounds in Active Public Supply Wells as Ground-Water Tracers in the Los Angeles Physiographic Basin, California, 2000

Data were collected to evaluate the use of low-level volatile organic compounds (VOC) to assess the vulnerability of public supply wells in the Los Angeles physiographic basin. Samples of untreated ground water from 178 active public supply wells in the Los Angeles physiographic basin show that VOCs were detected in 61 percent of the ground-water samples; most of these detections were low, with only 29 percent above 1 mg/L (microgram per liter). Thirty-nine of the 86 VOCs analyzed were detected in at least one sample, and 11 VOCs were detected in 7 percent or more of the samples. The six most frequently detected VOCs were trichloromethane (chloroform) (46 percent); trichloroethene (TCE) (28 percent); tetrachloro-ethene (PCE) (19 percent); methyl tert-butyl ether (MTBE) (14 percent); 1,1-dichloroethane (11 percent); and 1,1,1-trichloroethane (TCA) (11 percent). These VOCs were also the most frequently detected VOCs in ground water representative of a wide range of hydrologically conditions in urban areas nationwide. Only two VOCs (TCE and PCE) exceeded state and federal primary maximum contaminant levels (MCL) for drinking water in a total of seven samples. Because samples were collected prior to water treatment, sample concentrations do not represent the concentrations entering the drinking-water system.Ground water containing VOCs may be considered to be a tracer of postindustrial-aged water-water that was recharged after the onset of intense urban development. The overall distribution of VOC detections is related to the hydrological and the engineered recharge facilities in the Coastal Los Angeles Basin and the Coastal Santa Ana Basin that comprise the Los Angeles physiographic basin. Most of the ground-water recharge occurs at engineered recharge facilities in the generally coarse-grained northeastern parts of the study area (forebay areas). Ground-water recharge from the land surface is minimal in the southwestern part of the basins, distal from the recharge facilities, where clay layers impede the vertical migration of ground water (pressure areas).VOCs are not uniformly distributed over the study area. Most of the wells with multiple VOC detections, which also have the highest concentrations, are in the forebay areas and are clustered proximal to the recharge facilities. In addition, the number of VOC detections and VOC concentrations decrease beyond about 10-15 kilometers from the recharge facilities. The distribution of individual VOCs is also related to their history of use. MTBE traces ground water recharged during about the last decade and is detected almost exclusively in the forebay areas. Chloroform, which has been used since the 1920s, is more widely distributed and is detected at the greatest distances from the recharge facilities.Downward migration of VOCs from the land surface may be a viable process for VOCs to reach aquifers in parts of the forebay areas, but there is little indication that the same process is active in the pressure area. The lack of contrast in the number of VOC detections between wells of different depths over most of the study area suggests that the downward migration from the land surface is not a dominant pathway for VOCs to travel to the capture zones of public supply wells. Isolated occurrences of multiple VOC detections and high concentrations of VOCs in individual wells may indicate rapid vertical transport from a localized source. Stable isotope data indicate that ground water containing VOCs is a mixture of local precipitation and runoff with water that is isotopically lighter (more negative) than the local sources. The isotopically lighter water could either be Colorado River water or State Water Project water, both of which are imported to the basin and used as a source of recharge to the ground-water flow system. The stable isotope data support the interpretation that VOCs in ground water are associated with the engineered recharge facilities.Two of the most frequently detecte

Water-Resources Investigations Report↗

USGS1987

Hydrogeology and water quality of areas with persistent ground-water contamination near Blackfoot, Bingham County, Idaho

The Groveland-Collins area near Blackfoot, Idaho, has a history of either periodic or persistent localized groundwater contamination. Water users in the area report offensive smell, metallic taste, rust deposits, and bacteria in water supplies. During 1984 and 1985, data were collected to define regional and local geologic, hydrologic, and groundwater quality conditions, and to identify factors that may have affected local groundwater quality. Infiltration or leakage of irrigation water is the major source of groundwater recharge, and water levels may fluctuate 15 ft or more during the irrigation season. Groundwater movement is generally northwestward. Groundwater contains predominantly calcium, magnesium, and bicarbonate ions and characteristically has more than 200 mg/L hardness. Groundwater near the Groveland-Collins area may be contaminated from one or more sources, including infiltration of sewage effluent, gasoline or liquid fertilizer spillage, or land application of food processing wastewater. Subsurface basalt ridges impede lateral movement of water in localized areas. Groundwater pools temporarily behind these ridges and anomalously high water levels result. Maximum concentrations or values of constituents that indicate contamination were 1,450 microsiemens/cm specific conductance, 630 mg/L bicarbonate (as HCO 3 ), 11 mg/L nitrite plus nitrate (as nitrogen), 7.3 mg/L ammonia (as nitrogen), 5.9 mg/L organic nitrogen, 4.4 mg/L dissolved organic carbon, 7,000 micrograms/L dissolved iron, 5 ,100 microgram/L dissolved manganese, and 320 microgram/L dissolved zinc. Dissolved oxygen concentrations ranged from 8.9 mg/L in uncontaminated areas to 0 mg/L in areas where food processing wastewater is applied to the land surface. Stable-isotope may be useful in differentiating between contamination from potato-processing wastewater and whey in areas where both are applied to the land surface. Development of a ground-water model to evaluate effects of land applications of organic wastewater and organic solute loading rates on subsurface water quality is not feasible at this time.

Idaho↗

USGS1956

Ground-water data collected in the Missouri River basin units in Kansas during 1955

Ground-water studies in the Missouri River Basin were begun by the United States Geological Survey during the fall of 1945 as a part of the program for development of the resources of the basin by the U.S. Bureau of Reclamation and other Federal Agencies. The studies of the ground-water resources in the part of Kansas that lies within the Basin have been coordinated with the cooperative program of ground-water studies already being carried on in Kansas by the U.S. Geological Survey, the Kansas State Geological Survey, the Division of Sanitation of the Kansas State Board of Health, and the Division of Water Resources of the Kansas State Board of Agriculture. Areas in which ground-water data have been and are being collected are the following: Almena Unit in Norton and Phillips Counties; the Bostwick Unit in Jewell, Republic, and Cloud Counties; the Cedar Bluff Unit in Ellis, Rush, and Trego Counties; the Glen Elder Unit in Mitchell County; Kanopolis unit in Ellsworth, McPherson, and Saline Counties; Kirwin unit in Phillips, Smith, and Osborne Counties; St. Francis unit in Cheyenne County ; the Webster Unit in Osborne County; and the Wilson Unit in Lincoln County. Data relating to the Ladder Creek project in Greeley, Gove, Lane, Logan, Scott, Wallace, and Wichita Counties will be published later in a separate report. This report is the ninth of a series of annual reports on ground-water in the nine above-named units in Kansas and contains the data collected during 1955. The first report of the series contained the data collected prior to and through 1947. An index to the data contained in this and previous reports is given in table 1.

Kansas↗

USGS1955

Ground-water data collected in the Missouri River basin units in Kansas during 1954

Ground-water studies in the Missouri River Basin were begun by the United States Geological Survey during the fall of 1945 as a part of the program for development of the resources of the basin by the U.S. Bureau of Reclamation and other Federal Agencies. The studies of the ground-water resources in the part of Kansas that lies within the Basin have been coordinated with the cooperative program of ground-water studies already being made in Kansas by the U.S. Geological Survey, the Kansas State Geological Survey, the Division of Sanitation of the Kansas State Board of Health, and the Division of Water Resources of the Kansas State Board of Agriculture. Areas in which ground-water data have been and are being collected are the following: the Almena Unit in Norton and Phillips Counties; the Bostwick Unit in Jewell, Republic, and Cloud Counties; the Cedar Bluff Unit in Ellis, Rush, and Trego Counties; the Glen Elder Unit in Mitchell County; Kanopolis unit in Ellsworth, McPherson, and Saline Counties; Kirwin unit in Phillips, Smith, and Osborne Counties; St. Francis unit in Cheyenne County; the Webster Unit in Osborne County; and the Wilson Unit in Lincoln County. Data relating to the Ladder Creek project in Greeley, Gove, Lane, Logan, Scott, Wallace, and Wichita Counties will be published later in a separate report. This report is the eighth of a series of annual reports on ground-water in the above-named units in Kansas and contains the data collected during 1954. The first report of the series contained the data collected prior to and through 1947. An index to the data contained in this and previous reports is given in table 1.

Kansas↗

USGS1952

Ground-water data collected in the Missouri River basin units in Kansas during 1951

Ground-water studies in the Missouri River Basin were begun by the United States Geological Survey during the fall of 1945 as a part of the program for development of the resources of the basin by the U.S. Bureau of Reclamation and other Federal Agencies. The studies of the ground-water resources in the part of Kansas that lies within the Basin have been coordinated with the cooperative program of ground-water studies already being made in Kansas by the U.S. Geological Survey, the State Geological Survey of Kansas, the Division of Sanitation of the Kansas State Board of Health, and the Division of Water Resources of the Kansas State Board of Agriculture. Areas in which ground-water data have been collected for the Missouri Basin program include the Almena Unit in Norton and Phillips Counties; the Bostwick Unit in Jewell, Republic, and Cloud Counties; the Cedar Bluff Unit in Ellis, Rush, and Trego Counties; the Glen Elder Unit in Mitchell County; Kanopolis unit in Ellsworth, McPherson, and Saline Counties; Kirwin unit in Phillips, Smith, and Osborne Counties; the Ladder Creek project in Greeley, Gove, Lane, Logan, Scott, Wallace, and Wichita Counties; the St. Francis unit in Cheyenne County; the Webster Unit in Osborne County; and the Wilson Unit in Lincoln County. Data relating to the Ladder Creek project will be published later in a separate report. This report is the fifth of a series of annual reports on ground-water in the above-named units in Kansas and contains the data collected mostly during 1951. An index to the data that were collected and presented in the 1947, 1948, 1949, 1950, and 1951 reports is given in table 1.

Kansas↗