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Water-quality characteristics and contaminants in the rural karst-dominated Spring Mill Lake watershed, southern Indiana

The Spring Mill Lake watershed is located in the Mitchell Plateau, a karst area that developed on Mississippian carbonates in southern Indiana. Spring Mill Lake is a reservoir built in the late 1930s and is located in Spring Mill State Park. Within the park, groundwater from subsurface conduits issues as natural springs and then flows in surface streams to the lake. From 1998 to 2002, surface and subsurface hydrology and water quality were investigated to determine the types and sources of potential contaminants entering the lake. Water samples collected during base flow and a February 2000 storm event were analyzed for selected cations, anions, trace elements, selected U.S. Environmental Protection Agency (EPA) primary and secondary drinkingwater contaminants, nitrogen isotopes, suspended solids, Escherichia coli, and pesticides. All of the water samples met the EPA drinking-water standards for inorganic constituents, except those collected at five sites in August 1999 during a drought. Nitrate nitrogen (NO 3 -N) concentrations were highest during base-flow conditions and displayed a dilutional trend during peak-flow periods. The NO 3 -N concentrations in water samples collected during the 2001 spring fertilizer applications tended to increase from early to late spring. All of the ?? 15 N values were low, which is indicative of either an inorganic source or soil organic matter. Storm discharge contained increased concentrations of total suspended solids; thus, storms are responsible for most of the sediment accumulation in the lake. E. coli levels in 24% of the samples analyzed contained a most probable number (MPN) greater than 235/100 mL, which is the maximum acceptable level set for recreational waters in Indiana. E. coli does appear to be a potential health risk, particularly at Rubble spring. The sources of E. coli found at this spring may include barnyard runoff from a horse barn or wastes from a wastewater treatment facility. The pesticides atrazine, metolachlor, acetochlor, and simazine were detected during the spring of 2001. Atrazine, metolachlor, acetochlor, and simazine are used to suppress weeds during corn and soybean production. Additional sources of atrazine and simazine may result from application to right-of-ways, orchards, and managed forest areas. ?? 2006 Geological Society of America.

Special Paper of the Geological Society of America↗

Water in the Great Basin region; Idaho, Nevada, Utah, and Wyoming

The Great Basin Region is defined to include the drainage of the Great Basin physiographic section (Fennman, 1931) in Idaho, Nevada, Utah, and Wyoming. In October 1966, the President’s Water Resources Council requested that a comprehensive framework study be made in the Great Basin Region under the leadership of the Pacific Southwest Interagency Committee. The study, which included evaluation of the water resources of the region and guidelines for future study and development, was completed June 30, 1971. Results of the study received limited distribution. The purpose of this atlas is to make available to the public the hydrologic data (including a general appraisal) that were compiled for the comprehensive framework study. Most of the work was done by a water-resources work group consisting of members from several Federal and State agencies under the chairmanship of Thomas E. Eakin of the U.S. Geological Survey. This atlas contains some data not included in the framework study. The data presented herein are reconnaissance in nature and should be used with discretion. The maps are highly generalized and are intended only to illustrate the regional distribution of the supply and general chemical quality of the water. Sources of more detailed information on the hydrology of specific parts of the Great Basin region are listed in the selected references.

Idaho, Nevada, Utah, Wyoming↗

Water levels of the Ozark aquifer in northern Arkansas, 2013

The Ozark aquifer is the largest aquifer, both in area of outcrop and thickness, and the most important source of freshwater in the Ozark Plateaus physiographic province, supplying water to northern Arkansas, southeastern Kansas, southern Missouri, and northeastern Oklahoma. The study area includes 16 Arkansas counties lying completely or partially within the Ozark Plateaus of the Interior Highlands major physiographic division. The U.S. Geological Survey, in cooperation with the Arkansas Natural Resources Commission and the Arkansas Geological Survey, conducted a study of water levels in the Ozark aquifer within Arkansas. This report presents a potentiometric-surface map of the Ozark aquifer within the Ozark Plateaus of northern Arkansas, representing water-level conditions for the early spring of 2013 and selected water-level hydrographs. The Ozark aquifer in Arkansas is composed of dolomites, limestones, sandstones, and shales of Late Cambrian to Middle Devonian age and ranges in thickness from approximately 1,100 feet (ft) in northwestern Arkansas to more than 4,000 ft in the west-central part of Arkansas. Most wells completed in the aquifer yield between 50 and 100 gallons per minute (gal/min), although some wells may yield as much as 600 gal/min. Water-level measurements were made in wells completed in the Ozark aquifer from February to May 2013. Hydrographs were constructed for nine wells that have water-level measurements with a minimum 20-year period of record. Water-level altitudes in wells used to construct the potentiometric-surface map range from about 1,159 ft to 313 ft above National Geodetic Vertical Datum of 1929 (NGVD 29). The highest water-level altitudes occur in Carroll and Washington Counties while water-level altitudes of less than 400 ft above NGVD 29 are mapped along the eastern and southeastern part of the study area in Independence, Lawrence, Randolph, and Sharp Counties. The lowest water level of 313 ft above NGVD 29 was measured in southwestern Randolph County. The direction of groundwater flow generally is affected by local topography, flowing from high altitudes toward stream valleys. In southern Baxter, eastern Fulton, Independence, eastern Izard, Lawrence, Randolph, and Sharp Counties, the groundwater flow is generally to the south and southeast. In western Fulton and Izard Counties, the groundwater flow is generally to the southwest. In Boone, Marion, Newton, Searcy, and Stone Counties, the groundwater flow is generally to the east and northeast. In eastern Benton, Carroll, Madison, and eastern Washington Counties, the groundwater flow is generally to the north and northeast. In western Benton and western Washington Counties, the groundwater flow is generally to the west and northwest. The general level and shape of the potentiometric surface has changed little since predevelopment. A comparison of the predevelopment potentiometric surface and the 2007, 2010, and 2013 potentiometric surfaces indicate general agreement between the mapped surfaces with the exception of parts of Benton, Boone, Marion, and Washington Counties. In Boone and northern Marion Counties in 2013, water levels have declined when compared to the predevelopment potentiometric surface, although the direction of flow is still to the northeast and north. In southern Marion County, water levels have declined when compared to the predevelopment, 2007, and 2010 potentiometric surfaces, although the direction of flow is towards and along the stream valleys. In western Benton and northwestern Washington Counties, water levels are similar when compared to the predevelopment potentiometric surface, and the direction of flow is to the west and northwest, similar to the predevelopment direction of flow. The mapped 2007 and 2010 potentiometric surfaces are very different from the mapped 2013 potentiometric surface in western Benton and northwestern Washington Counties. The mapped 2013 potentiometric surface in western Benton and northwestern Washington Counties follows the contours of the top of the formation, similar to the predevelopment potentiometric surface. Since 1975, water use in the Ozark aquifer has declined 45 percent, while water levels in Benton, Boone, Marion, and Washington Counties continue to decline. Nine hydrographs were selected as representative of the water-level conditions in their respective counties. Wells in Fulton, Izard, and Newton Counties (station names 20N08W27ABD1, 18N09W15BCB1, and 16N21W34ABC1, respectively) have water levels that are within the usual range of values for their respective counties. Wells in Boone, Marion, and Washington Counties (station names 18N19W19BCC1, 19N15W20ACC1, and 16N32W09ABD1, respectively) have water levels that have recently declined or are declining for the period of record. Wells in Benton, Carroll, and Sharp Counties (station names 19N29W07DAA1, 21N26W17BCC1, and 15N05W06DDD1, respectively) have water levels that have been rising recently.

Arkansas↗

Water-quality trend analysis and sampling design for streams in North Dakota, 1971-2000

This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the North Dakota Department of Health, to analyze historical water-quality trends in selected dissolved major ions, nutrients, and dissolved trace metals for 10 streams in southwestern and eastern North Dakota and to develop an efficient sampling design to monitor future water-quality trends. A time-series model for daily streamflow and constituent concentration was used to identify significant concentration trends, separate natural hydroclimatic variability in concentration from variability that could have resulted from anthropogenic causes, and evaluate various sampling designs to monitor future water-quality trends. The interannual variability in concentration as a result of variability in streamflow, referred to as the annual concentration anomaly, generally was high for all constituents and streams used in the trend analysis and was particularly sensitive to the severe drought that occurred in the late 1980's and the very wet period that began in 1993 and has persisted to the present (2002). Although climatic conditions were similar across North Dakota during the trend-analysis period (1971-2000), significant differences occurred in the annual concentration anomalies from constituent to constituent and location to location, especially during the drought and the wet period. Numerous trends were detected in the historical constituent concentrations after the annual concentration anomalies were removed. The trends within each of the constituent groups (major ions, nutrients, and trace metals) showed general agreement among the streams. For most locations, the largest dissolved major-ion concentrations occurred during the late 1970's and concentrations in the mid- to late 1990's were smaller than concentrations during the late 1970's. However, the largest concentrations for three of the Missouri River tributaries and one of the Red River of the North tributaries occurred during the mid- to late 1990's. Concentration trends for total ammonia plus organic nitrogen showed close agreement among the streams for which that constituent was evaluated. The largest concentrations occurred during the early 1980's, and the smallest concentrations occurred during the early 1990's. Nutrient data were not available for the early 1970's or late 1990's. Although a detailed analysis of the causes of the trends was beyond the scope of this report, a preliminary analysis of cropland, livestock-inventory, and oil-production data for 1971-2000 indicated the concentration trends may be related to the livestock-inventory and oil-production activities in the basins. Dissolved iron and manganese concentrations for the southwestern North Dakota streams generally remained stable during 1971-2000. However, many of the recorded concentrations for those streams were less than the detection limit, and trends that were masked by censoring may have occurred. Several significant trends were detected in dissolved iron and manganese concentrations for the eastern North Dakota streams. Concentrations for those streams either remained stable or increased during most of the 1970's and then decreased rapidly for about 2 years beginning in the late 1970's. The concentrations were relatively stable from the early 1980's to 2000 except at two locations where dissolved iron concentrations increased during the early 1990's. The most efficient overall sampling designs for the detection of annual trends (that is, trends that occur uniformly during the entire year) consisted of balanced designs in which the sampling dates and the number of samples collected remained fixed from year to year and in which the samples were collected throughout the year rather than in a short timespan. The best overall design for the detection of annual trends consisted of three samples per year, with samples collected near the beginning of December, April, and August. That design had acceptable sensitivity for the detection of trends in most constituents at all locations. Little improvement in sensitivity was achieved by collecting more than three samples per year. The sampling designs that were first evaluated for annual trends also were evaluated with regard to their sensitivity to detect seasonal trends that occurred during three seasons--April through August, August through December, and December through April. Design results indicated that an average of one extra sample per station per year resulted in an efficient design for detecting seasonal trends. However, allocation of the extra samples varied depending on the station, month, and constituent group (major ions, nutrients, and trace metals).

North Dakota↗

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in the Yuma Valley, Arizona, 1995

Because of concerns expressed by the U.S. Congress and the environmental community, the Department of the Interior began a program in late 1985 to identify the nature and extent of water-quality problems induced by irrigation that might exist in the western States. Surface water, bottom sediment, and biota were collected from March through September 1995 along the lower Colorado River and in agricultural drains at nine sites in the Yuma Valley, Arizona, and analyzed for selected inorganic and organic constituents. Analyses of water, bottom sediment, and biota were completed to determine if irrigation return flow has caused, or has the potential to cause, harmful effects on human health, fish, and wildlife in the study area. Concentrations of dissolved solids in surface-water samples collected in March generally did not vary substantially from surface-water samples collected in June. Concentrations of dissolved solids ranged from 712 to 3,000 milligrams per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water. Concentrations of chloride in 9 of 18 water samples and concentrations of sulfate in 16 of 18 water samples exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter for drinking water. Calcium and sodium were the dominant cations, and chloride and sulfate were the dominant anions. The maximum selenium concentration of 8 micrograms per liter exceeded the U.S. Environmental Protection Agency aquatic-life chronic criterion of 5 micrograms per liter. Concentrations of lead in 7 of 18 water samples and concentrations of mercury in 4 of 18 water samples exceeded the aquatic-life cronic criteria of 3.2 and 0.012 micrograms per liter, respectively. Concentrations of antimony, beryllium, cadmium, and silver in the water samples were below analytical reporting limits. Arsenic was detected in 3 of 9 bottom-sediment samples, and concentrations ranged from 11 to 16 micrograms per gram. Concentrations ofaluminum, beryllium, boron, copper, lead, and zinc were highest in samples from Main Drain at southerly international boundary near San Luis, Arizona. Selenium was detected in all bottom-sediment samples, and concentrations ranged from 0.1 to 0.7 micrograms per gram. Concentrations of cadmium, europium, homium, mercury, molybdenum, silver, tantalum, tin, and uranium were below analytical reporting limits in the bottom-sediment samples. Concentrations of trace elements in bottom-sediment samples were within the ranges found in a study of soils of the western United States and did not indicate a significant accumulation of these constituents. p,p'Dichlorodiphenyldichloroethylene (commonly referred to as p,-p'-DDE) was detected in one bottom-sediment sample at a concentration of 1.4 micrograms per gram. No other organochlorine compounds were detected in the bottom-sediment samples. DDE was present in all fish and bird samples. Almost one-half of the fish samples contained DDE residues that were two times higher than the mean calculated for a national study in 1984-85. Twenty-tree percent of the fish contained more than three times the national mean. Fish from downstream parts of the Main Drain had the highest concentrations of DDE. Although concentrations of DDE in fish and in bird carcasses and eggs were above background levels, residues generally were below thresholds associated with chronic poisoning and reproductive problems in figh and wildlife. Concentrations of 18 trace elements were detected in cattail (Typha sp.) roots, freshwater clam (Corbicula fluminea), fish, and bird samples. Selenium in most fish and in livers of red-winged (Agelaius phoeniceus) and yellow-headed (Xanthocephalus xanthocephalus) blackbirds was above background concentrations but below toxic concentrations. In contrast, selenium was present in a killdeer (Charadrium vociferus) liver sample at potentially toxic con

Water-Resources Investigations Report↗

Choosing indicators of natural resource condition: A case study in Arches National Park, Utah, USA

Heavy visitor use in many areas of the world have necessitated development of ways to assess visitation impacts. Arches National Park recently completed a Visitor Experience and Resource Protection (VERP) plan. Integral to this plan was developing a method to identify biological indicators that would both measure visitor impacts and response to management actions. The process used in Arches for indicator selection is outlined here as a model applicable to many areas facing similar challenges. The steps were: (1) Vegetation types most used by visitors were identified. Impacted and unimpacted areas in these types were sampled, comparing vegetation and soil factors. (2) Variables found to differ significantly between compared sites were used as potential indicators. (3) Site-specific criteria for indicators were developed, and potential indicators evaluated using these criteria. (4) Chosen indicators were further researched for ecological relevancy. (5) Final indicators were chosen, field tested, and monitoring sites designated. In Arches, indicators were chosen for monitoring annually (soil crust index, soil compaction, number of used social trails and soil aggregate stability) and every five years (vegetation cover and frequency; ground cover; soil chemistry; and plant tissue chemistry).

Environmental Management↗

Drainage areas for selected stream-sampling stations, Missouri River Basin

As part of the U.S. Geological Survey's (USGS) National Water-Quality Assessment Program (NAWQA), an investigation of the Missouri River Basin is being conducted to document trends in surface-water quality, specifically for trends in nutrients and suspended sediment. Surface-water samples were collected from streams at specific sampling stations. Water-quality characteristics at each station are influenced by the natural and cultural characteristics of the drainage area upstream from the sampling station. Efficient quantification of the drainage area characteristics requires a digital map of the drainage area boundary that may be processed, together with other digital thematic maps (such as geology or land use), in a geographic information system (GIS). Digital drainage-area boundary data for one stream-sampling station in the Missouri River Basin (MRB4) study area is included in this data release. The drainage divides were identified chiefly using 1:24,000-scale hypsography.

Colorado;Iowa;Kansas;Montana;Nebraska;North Dakota↗

Periphyton communities in streams of the Ozark Plateaus and their relations to selected environmental factors

During August through September of 1993- 95, 83 periphyton samples were collected at 51 stream sites in the Ozark Plateaus. These sites were categorized into six land-use categories (20 forest, 18 agriculture, 10 mining, 1 urban, 1 urban/ mining, and 1 mix), based on land-use percentages in the basin upstream from the site. Results indicate that periphyton communities of riffles of Ozark streams are affected by natural and land-use related factors. These factors include nutrients, dissolved organic carbon, alkalinity, canopy shading, suspended sediment, embeddedness, stream morphometry, and velocity. For several measures of periphyton communities, statistically significant (p<0.05) differences were found among sites assigned to agriculture, forest, and mining categories. Blue-green algae biovolume, relative abundance of blue-green algae, relative biovolume of diatoms, relative abundance of oligotrophic algae, relative abundance of tolerant taxa, and condition index values were among the measures that differed among land-use categories. Although no environmental factors were significantly correlated with total biovolume, several factors were significantly correlated with biovolume of blue-green algae or biovolume of diatoms. Biovolume of blue-green algae was correlated with percent agriculture land use. Biovolume of diatoms was correlated with orthophosphate, total phosphorus, alkalinity, velocity, embeddedness, and dissolved organic carbon. Diatoms often composed the largest percentage of the biovolume (relative biovolume). Diatom relative biovolume was much higher at mining sites (generally 75 to 90 percent of the total biovolume) than at forest or agriculture sites (generally 15 to 80 percent) and was correlated with several factors, including many land-use related factors. The diatoms Cymbella affinis and Cymbella delicatula and the blue-green algae Calothrix often were the most common (relative abundance and relative biovolume) algae in samples. Detrended correspondence analysis (DCA) and hierarchical cluster analyses results indicated differences among land-use category sites. The DCA results were correlated with a number of land-use related factors and channel morphometry. Grazers (specifically, snails and stonerollers) are related to periphyton biovolume and community composition. Total periphyton and diatom biovolume typically were highest at sites where snail density was lowest. Lower relative abundances of diatoms usually occurred at sites with higher snail densities and stoneroller relative abundances.

Arkansas, Kansas, Missouri, Oklahoma↗

Water-Table Levels and Gradients, Nevada, 1947-2004

In 1999, the U.S. Environmental Protection Agency began a program to protect the quality of ground water in areas other than ground-water protection areas. These other sensitive ground water areas (OSGWA) are areas that are not currently, but could eventually be, used as a source of drinking water. The OSGWA program specifically addresses existing wells that are used for underground injection of motor-vehicle waste. To help determine whether a well is in an OSGWA, the Nevada Division of Environmental Protection needs statewide information on depth to water and the water table, which partly control the susceptibility of ground water to contamination and contaminant transport. This report describes a study that used available maps and data to create statewide maps of water-table and depth-to-water contours and surfaces, assessed temporal changes in water-table levels, and characterized water-table gradients in selected areas of Nevada. A literature search of published water-table and depth-to-water contours produced maps of varying detail and scope in 104 reports published from 1948 to 2004. Where multiple maps covered the same area, criteria were used to select the most recent, detailed maps that covered the largest area and had plotted control points. These selection criteria resulted in water-table and depth-to-water contours that are based on data collected from 1947 to 2004 being selected from 39 reports. If not already available digitally, contours and control points were digitized from selected maps, entered into a geographic information system, and combined to make a statewide map of water-table contours. Water-table surfaces were made by using inverse distance weighting to estimate the water table between contours and then gridding the estimates. Depth-to-water surfaces were made by subtracting the water-table altitude from the land-surface altitude. Water-table and depth-to-water surfaces were made for only 21 percent of Nevada because of a lack of information for 49 of 232 basins and for most consolidated-rock hydrogeologic units. Depth to water is commonly less than 50 feet beneath valley floors, 50 to 500 feet beneath alluvial fans, and more than 500 feet in some areas such as north-central and southern Nevada. In areas without water-table information, greasewood and mapped ground-water discharge areas are good indicators of depth to water less than 100 feet. The average difference between measured depth to water and depth to water estimated from surfaces was 90 feet. More recent and detailed information may be needed than that presented in this report to evaluate a specific site. Temporal changes in water-table levels were evaluated for 1,981 wells with 10 or more years between the first depth-to-water measurement and last measurement made since 1990. The greatest increases in depth to water occurred where the first measurement was less than 200 feet, where the time between first and last measurements was 40 years or less, and for wells between 100 and 600 feet deep. These characteristics describe production wells where ground water is fairly shallow in recently developing areas such as the Las Vegas and Reno metropolitan areas. In basins with little pumping, 90 percent of the changes during the past 100 years are within ?20 feet, which is about the natural variation in the water table due to changes in the climate and recharge. Gradients in unconsolidated sediments of the Great Basin are generally steep near mountain fronts, shallow beneath valley floors, and depend on variables such as the horizontal hydraulic conductivity of adjacent consolidated rocks and recharge. Gradients beneath alluvial fans and valley floors at 58 sites were correlated with selected variables to identify those variables that are statistically related. Water-table measurements at three sites were used to characterize the water table between the valley floor and consolidated rock. Water-table gradients beneath alluvial fan

Scientific Investigations Report↗

Distribution of potentially bioavailable natural organic carbon in aquifer sediments at a chloroethene-contaminated site

The distribution of natural organic carbon was investigated at a chloroethene-contaminated site where complete reductive dechlorination of tetrachloroethene (PCE) to vinyl chloride and ethene was observed. In this study, operationally defined potentially bioavailable organic carbon (PBOC) was measured in surficial aquifer sediment samples collected at varying depths and locations in the vicinity of a dense nonaqueous phase liquid (DNAPL) source and aqueous phase plume. The relationship between chloroethene concentrations and PBOC levels was examined by comparing differences in extractable organic carbon in aquifer sediments with minimal chloroethene exposure relative to samples collected in the source zone. Using performance-monitoring data, direct correlations with PBOC were also developed with chloroethene concentrations in groundwater. Results show a logarithm-normal distribution for PBOC in aquifer sediments with a mean concentration of 187 mg/kg. PBOC levels in sediments obtained from the underlying confining unit were generally greater when compared to sediments collected in the sandy surficial aquifer. Results demonstrated a statistically significant inverse correlation (p=0.007) between PBOC levels in aquifer sediments and chloroethene concentrations for selected monitoring wells in which chloroethene exposure was the highest. Results from laboratory exposure assays also demonstrated that sediment samples exhibited a reduction in PBOC levels of 35% and 73%, respectively, after a 72-h exposure period to PCE (20,000 μg/L). These results support the notion that PBOC depletion in sediments may be expected in chloroethene-contaminated aquifers, which has potential implications for the long-term sustainability of monitored natural attenuation.

South Carolina↗

Variability in weather and site properties affect fuel and fire behavior following fuel treatments in semiarid sagebrush-steppe.

Fuel-treatments targeting shrubs and fire-prone exotic annual grasses (EAGs) are increasingly used to mitigate increased wildfire risks in arid and semiarid environments, and understanding their response to natural factors is needed for effective landscape management. Using field-data collected over four years from fuel-break treatments in semiarid sagebrush-steppe, we asked 1) how the outcomes of EAG and sagebrush fuel treatments varied with site biophysical properties, climate, and weather, and 2) how predictions of fire behavior using the Fuel Characteristic Classification System fire model related to land-management objectives of maintaining fire behavior expected of low-load, dry-climate grasslands. Generalized linear mixed effect modeling with build-up model selection was used to determine best-fit models, and marginal effects plots to assess responses for each fuel type. EAG cover decreased as antecedent-fall precipitation increased and increased as antecedent-spring temperatures and surface soil clay contents increased. Herbicides targeting EAGs were less effective where pre-treatment EAG cover was >40 % and antecedent spring temperatures were >9.5 °C. Sagebrush cover was inversely related to soil clay content, especially where clay contents were >17 %. Predicted fire behavior exceeded management objectives under 1) average fire weather conditions when EAG or sagebrush cover was >50 % or >26 %, respectively, or 2) extreme fire weather conditions when EAG or sagebrush cover was >10 % or >8 %, respectively. Consideration of the strong effects of natural variability in site properties and antecedent weather can help in justifying, planning and implementing fuel-treatments.

Idaho, Oregon↗

A comparison of high-resolution specific conductance-based end-member mixing analysis and a graphical method for baseflow separation of four streams in hydrologically challenging agricultural watersheds

Quantifying the relative contributions of different sources of water to a stream hydrograph is important for understanding the hydrology and water quality dynamics of a given watershed. To compare the performance of two methods of hydrograph separation, a graphical program [baseflow index (BFI)] and an end-member mixing analysis that used high-resolution specific conductance measurements (SC-EMMA) were used to estimate daily and average long-term slowflow additions of water to four small, primarily agricultural streams with different dominant sources of water (natural groundwater, overland flow, subsurface drain outflow, and groundwater from irrigation). Because the result of hydrograph separation by SC-EMMA is strongly related to the choice of slowflow and fastflow end-member values, a sensitivity analysis was conducted based on the various approaches reported in the literature to inform the selection of end-members. There were substantial discrepancies among the BFI and SC-EMMA, and neither method produced reasonable results for all four streams. Streams that had a small difference in the SC of slowflow compared with fastflow or did not have a monotonic relationship between streamflow and stream SC posed a challenge to the SC-EMMA method. The utility of the graphical BFI program was limited in the stream that had only gradual changes in streamflow. The results of this comparison suggest that the two methods may be quantifying different sources of water. Even though both methods are easy to apply, they should be applied with consideration of the streamflow and/or SC characteristics of a stream, especially where anthropogenic water sources (irrigation and subsurface drainage) are present.

Hydrological Processes↗

Determinants of reproductive costs in the long-lived Black-legged Kittiwake: A multiyear experiment

We studied reproductive costs of Black-legged Kittiwakes ( Rissa tridactyla ) in Prince William Sound, Alaska (USA) by removing entire clutches from randomly selected nests over four successive years, and then contrasting survival and fecundity of adults from manipulated and unmanipulated nests in each subsequent year. To elucidate mechanisms that lead to the expression of reproductive costs, we simultaneously characterized several behavioral and physiological parameters among adults in the two treatment groups. We also examined naturally nonbreeding adults that previously bred to determine their survival and future nonbreeding probabilities. Food availability varied during the study, being generally poor at the onset, and improving in later years. Adult nest attendance and body condition (assessed late in the chick- rearing period) varied accordingly among years, and between adults raising chicks and adults that had their eggs removed. Adults from unmanipulated nests incurred significant survival costs in all years, although fecundity costs were strongly expressed in only one of four years. Neither survival nor fecundity costs were strongly influenced by body condition or food availability, and no difference in reproductive costs was detected between the sexes. Although unmanipulated breeders survived at lower rates than manipulated breeders due to costs of reproduction, their survival rates were elevated compared to those of natural nonbreeders, presumably due to differences in individual ability. These findings indicate that models of adult survival must consider not only an organism's reproductive state, but also the factors that lead to that state. Although body condition appeared to be weakly related to survival, it was insufficient to explain the full magnitude of survival costs observed. We suggest that other parameters that were found to differ between treatment groups (e.g., rates of energy turnover, baseline levels of stress, and patterns of allocating body reserves) may be important mechanistic determinants of reproductive costs in kittiwakes, and potentially other long-lived species. Future efforts should move beyond simple assessments of body condition and toward more integrated measures of physiological condition when attempting to identify factors that influence how long-lived species balance the costs and benefits of reproduction.

Alaska↗

An annotated list of the mayflies, stoneflies, and caddisflies of the Sand Creek basin, Great Sand Dunes National Park and Preserve, Colorado, 2004 and 2005

The U.S. Geological Survey, in conjunction with the Great Sand Dunes National Park and Preserve and its cooperators, did an extensive inventory of certain targeted aquatic-insect groups in the Sand Creek Basin, Great Sand Dunes National Park and Preserve, to establish a species list for future monitoring efforts. Study sites were established to monitor these groups following disturbance events. Such potential disturbances may include, but are not limited to, chemical treatment of perennial stream reaches to remove nonnative fishes and the subsequent reintroduction of native fish species, increased public use of backcountry habitat (such as hiking and fishing), and natural disturbances such as fire. This report is an annotated list of the mayflies, stoneflies, and caddisflies found in the Sand Creek Basin, Great Sand Dunes National Park and Preserve, 2004 and 2005. The primary objective of the study was to qualitatively inventory target aquatic-insect groups in perennial streams, and selected unique standing-water habitats, such as springs, and wetlands associated with the Sand Creek Basin. Efforts focused on documenting the presence of aquatic-insect species within the following taxonomic groups: Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies). These insect orders were chosen because published species accounts, geographic distribution, and identification keys exist for many Colorado species. Given the extent of available information for these groups, there existed a potential for identifying new species and documenting range extensions of known species.

Data Series↗

Ground-water quality data in the Central Sierra study unit, 2006— Results from the California GAMA Program

Ground-water quality in the approximately 950 square kilometer (370 square mile) Central Sierra study unit (CENSIE) was investigated in May 2006 as part of the Priority Basin Assessment project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). This study was designed to provide a spatially unbiased assessment of the quality of raw ground water used for drinking-water supplies within CENSIE, and to facilitate statistically consistent comparisons of ground-water quality throughout California. Samples were collected from thirty wells in Madera County. Twenty-seven of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and three were selected to aid in evaluation of specific water-quality issues (understanding wells). Ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], gasoline oxygenates and degradates, pesticides and pesticide degradates), constituents of special interest (N-nitrosodimethylamine, perchlorate, and 1,2,3-trichloropropane), naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon], and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. In total, over 250 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-sixth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Results from field blanks indicated contamination was not a noticeable source of bias in the data for ground-water samples. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most constituents. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), and thresholds established for aesthetic concerns (Secondary Maximum Contaminant Levels, SMCL-CA) by CDPH. Therefore, any comparisons of the results of this study to drinking-water standards only is for illustrative purposes and is not indicative of compliance or non-compliance to those standards. Most constituents that were detected in ground-water samples were found at concentrations below drinking-water standards or thresholds. Six constituents? fluoride, arsenic, molybdenum, uranium, gross-alpha radioactivity, and radon-222?were detected at concentrations higher than thresholds set for health-based regulatory purposes. Three additional constituents?pH, iron and manganese?were detected at concentrations above thresholds set for aesthetic concerns. Volatile organic compounds (VOCs) and pesticides, were detected in less than one-third of the samples and generally at less than one one-hundredth of a health-based threshold.

California↗

Summary of the major water-quality findings from the Eastern Iowa Basins study unit of the National Water-Quality Assessment Program

An integrated assessment of the water quality in streams and aquifers in the Wapsipinicon, Iowa, Cedar, and Skunk River basins was conducted in 1996 through 1998 as part of the Eastern Iowa Basins (EIWA) study unit of the U.S. Geological Survey's National Water-Quality Assessment Program (NAWQA). The EIWA study unit is one of 59 study units across the Nation designed to assess the status and trends in the quality of the Nation's ground- and surface-water resources and to link the status and trends with an understanding of the natural and human factors that affect the quality of water. Over 90 percent of the land in the EIWA study unit is used for agricultural purposes, while forested areas account for only 4 percent and urban areas about 2 percent of the land. Surface-water samples were collected monthly and during selected storm events from six sites in medium-sized basins (125 to about 400 mi2) and five sites in large river basins (2,300 to 12,500 mi2). The medium-sized basins were selected to be representative of various physical features, hydrogeology, and agricultural landuse (row crops and concentrated animal feeding operations) that may affect water quality. The large river sites were selected to determine the integrated effects of combinations of landuse and hydrogeology on river-water quality. Ground-water samples were collected primarily from the alluvial aquifers because of the aquifers' direct hydraulic connection with rivers and streams and because alluvial aquifers are one of the most important sources for domestic, municipal, and industrial water supplies in the study area. Monitoring wells were installed in agricultural and urban areas of the alluvial aquifers to assess the quality of the most recently recharged water in relation to land use. Existing domestic wells screened in alluvial aquifers and the Silurian/Devonian aquifer were sampled to assess deeper and older ground water. Surface- and ground-water samples were analyzed for a wide variety of chemical constituents (major ions, nutrients, and pesticides) commonly associated with agricultural and urban activities. Because they were not expected to occur in rivers and streams, volatile organic compounds (VOC's), commonly comprising fuels, solvents, and other industrial compounds were only analyzed in ground-water samples. The age of the ground water, important information needed to relate ground-water quality to land use, was determined using both tritium and chlorofluorocarbons (Freon?) age-dating methods. Results from the EIWA NAWQA study build on previous and ongoing research and water-quality monitoring programs in Iowa and provide new insights into the relation between the quality of the State's water resources and human activities. The major findings from the study are listed below.

Iowa↗

Hybridization between historically allopatric Chinook salmon populations in the White Salmon River, WA

Chinook Salmon spawning in the White Salmon River consist of members of three historically distinct populations: spring Chinook Salmon, Tule fall Chinook Salmon and Upriver Bright (URB) fall Chinook Salmon. Previous work examined juveniles captured in 2006-2008 and reported hybridization between introduced URBs, and the native threatened Tules. Recent increases in nearby hatchery URB release numbers raised the question of whether hybridization rates were increasing. We estimated hybrid frequencies among juveniles collected in the lower White Salmon River between 2016 and 2019. We also evaluated the frequencies at which non-target fish and hybrids were incorporated into the broodstocks of adjacent hatcheries. We observed that frequencies of hybrids in juvenile samples from the White Salmon River were greater in 2017-2019 (17-32%) than they had been in 2006-2008 (4-15%), but that a few (2/9) comparisons exhibited overlapping confidence intervals, suggesting that the rate has increased over time, but also that more sampling is needed to understand the importance of year-to-year variation. Further, differences in the habitat following dam removal and in the sampling sites complicated interpretation of our results. Examination of broodstocks of nearby hatcheries revealed low rates (< 0.5%) of incorporation of non-target populations and higher rates (< 9.0%) of incorporation of hybrids into those broodstocks. The relative compositions of all hatchery and natural-origin collections were similar: most individuals were one of the two parental stocks, a very small fraction were F1 hybrids, and a larger minority fraction were back-crosses. This pattern, in the context of hybridization which we know has been happening for several generations, is consistent with a hypothesis of selection against hybrids in which F1 hybrids are less fit than backcross hybrids.

Washington↗

Age and growth of the kiyi, Leucichthys kiyi Koelz, in Lake Michigan

Ages were determined and individual growth histories were calculated from the examination and measurement of the scales of 1,649 kiyis captured at seven localities in Lake Michigan in 1931 and 1932. The numbers of individuals employed for the investigation of other phases of the life history (such as length-frequency distributions, length-weight relationship, and sex ratio) varied according to the amount of data available or required. Age-group IV was dominant in the 1931 collections from Racine, Port Washington, and Kewaunee, Wisconsin, and age-group V dominated the 1932 samples from the Fox Islands and from three localities southward of Manistique, Michigan. A trend was noticeable toward an increase in average age from south to north. Among the explanations suggested for the observed differences in age composition were: Variation with latitude in the natural span of life; differences in fishing intensity; fluctuations in the strength of year classes (to account possibly for the shift in the dominant age group from 1931 to 1932). The oldest male kiyi belonged to the VII group and the oldest female was a member of the X group. The possible distorting effects of such factors as gear selection traceable to differences in the mesh sizes of nets fished in 1931 and 1932, selection by nets on the basis of the condition (K) of the fish, and local variations in fishing intensity and hence in the selective destruction of rapidly growing individuals in the fishery were held to be sufficiently great to render doubtful the significance of most of the observed local differences in growth rate. Kiyis from all samples were combined to determine the general growth in length. The growth in weight of the Fox Islands fish, however, was considered separately as these fish were consistently lighter than kiyis of corresponding length from other localities. The Lake Michigan kiyi grows slowly, with the females growing slightly more rapidly than the males. The grand average calculated lengths indicated, for example, that the females did not attain a total length of 10 inches until the fifth year of life or the males until the sixth. Similarly, the calculated weight of 4 ounces was not reached until the fifth or sixth year (with the actual time varying with sex and locality). The season's growth of the kiyi probably begins sometime in May and most or all of the growth is completed by the end of August. The calculated lengths of the age groups exhibited large discrepancies that differed from “Lee's phenomenon” as ordinarily observed in that the data for the later rather than the earlier years of life were affected most severely. Chief among the factors held responsible for these discrepancies were gear selection and the selective destruction of the more rapidly growing individuals in the fishery. Errors inherent in the (direct-proportion) method of computing growth from scale measurements were considered to have been unimportant. The Lake Michigan kiyi exhibits growth compensation–the tendency for the smaller of the young fish to have the more rapid growth in the later years of life. Comparisons with the average lengths and weights of the age groups of the Lake Ontario kiyi given by Pritchard (1931) indicated the Lake Michigan fish to be the larger at the earlier ages (age-groups II and III) and the smaller at the later ages (age-groups IV to VI). The length-frequency distributions of the age groups exhibited extensive overlap. As many as eight age groups were represented in a single centimeter interval of length. The length frequencies and average lengths of all fish collected, arranged according to the mesh sizes of the gill nets by which they were captured, revealed that the selective action of these nets in the taking of kiyis was much more obvious in the numbers of fish in the catch than in their average size. As an illustration, in 1930–1931, the 2 3/4-inch mesh nets took fish that were only 0.1 inch longer than those in 2 1/2-inch meshes but captured less than one fourth as many. Gill nets fished in northern Lake Michigan in 1932 captured kiyis that averaged 0.2 to 0.4 inch longer than those taken in the same meshes in southern Lake Michigan in 1930–1931. Because of the more slender form of kiyis from the northeastern island region of Lake Michigan, data on the general length weight relationship were compiled separately for fish of that area and for those of the great central basins of the lake. In both regions the weight increased to a power slightly greater than the cube of the length. Available information on condition indicated that the coefficient (K) was higher in August and early September than in May, June, and July. Condition declined from early September to October and early November–the latter period the time of most active spawning. Spawning itself was accompanied by an additional loss of about 12 per cent of the body weight of females and of somewhat less than 2 per cent of the weight of males. Analysis of the variations of K within a group that was homogeneous with respect to age, sex, maturity, and time of collection revealed that a net of a particular mesh size tends to take the heavier of the shorter fish and the lighter of the longer fish within its range of effectiveness. Among fish of the same length the values of K tended to increase with increase in the mesh size of the nets employed for their capture. Practically all fish in the samples were mature (only 11 immature in more than 6,000). These “immature” fish were probably “non-functional” since all of them approached or exceeded the average length of the mature kiyis. Females were strongly predominant in the collections at all seasons but were relatively more plentiful during the summer (90 per cent of the total) than during the spawning period (75 per cent). Possible factors contributing to this predominance of females and to the change in the sex ratio at the spawning season were discussed. A decrease in the relative abundance of males with increase in age appears to be characteristic of the kiyi. This decrease indicates a differential mortality of th sexes (greater relative destruction of males in the spawning period when they are unusually abundant or a greater natural mortality rate for the males). Current fishery regulations on mesh size and closed seasons afford the kiyi good protection but offer no guarantee against depletion from too intensive fishing.

Transactions of the American Fisheries Society↗