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USGS2003

Resurvey of quality of surface water and bottom material of the Barataria Preserve of Jean Lafitte National Historical Park and Preserve, Louisiana, 1999-2000

The quality of water and bottom material in the Barataria Preserve of Jean Lafitte National Historical Park and Preserve, Louisiana, was surveyed from March 1999 to May 2000. Organochlorine, chlorophenoxy acid, and organophosphorus pesticides; polychlorinated biphenyls (PCB's); and trace elements were analyzed in surface water and bottom material from three sites previously sampled in a 1981-82 survey. Surface water at six sites was sampled and analyzed for selected nutrients and major inorganic ions based on their importance to human health, the health of the marshes of the Barataria Preserve, or their usefulness in tracking the circulation of Mississippi River water in the Barataria Preserve. Southern Louisiana was in a moderate to severe drought during most of the sampling period, which elevated salinity in the Barataria Preserve for at least 8 months. Specific conductance values were less than 3,000 µS/cm (microsiemens per centimeter at 25 degrees Celsius) in surface water throughout the Barataria Preserve from March through September 1999. Specific conductance values increased over the next 2 months and then remained between 5,000 and 6,000 µS/cm. The herbicide 2,4-D was detected in water at the two sites sampled in August 1999 but not at any site during the two other sampling times. Iron, manganese, and the trace elements copper, nickel, and zinc were detected in dissolved and whole-water samples at all three sites. Nitrite+ nitrate, as nitrogen, concentrations ranged from less than 0.002 to 0.19 mg/L (milligrams per liter). Ammonia, as nitrogen, concentrations ranged from less than 0.01 to 0.16 mg/L. Orthophosphate, as phosphorus, concentrations ranged from less than 0.002 to 0.14 mg/L. Calcium, magnesium, potassium, sulfate, and chloride concentrations in surface water were elevated due to the marine influence on the composition of surface water in the Barataria Preserve during the sampling period. Sulfate and chloride concentrations reached 379 and 2,830 mg/L, respectively. Polychlorinated biphenyls, chlordane, and DDT were detected in bottom material. Trace elements were detected in bottom material at all three of the sampled sites. Arsenic concentrations ranged from 4 to 9 µg/g (micrograms per gram) and lead concentrations from 20 to 31 µg/g. Mercury concentrations also were above laboratory reporting levels (LRL's) for bottom material at all three sites. The herbicide 2,4-D was detected in surface water during both surveys. Other organic compounds were not detected in surface water. Mercury and chromium were detected in surface water at all three sites during the 1981-82 survey but were below LRL?s during the 1999-2000 survey. Changes in chemical characteristics of bottom material occurred during the years between the 1981-82 and 1999-2000 surveys. DDT decreased in the bottom material at Bayou Segnette near Barataria. DDE, a degradation product, increased at this site, indicating that over time, DDT concentrations are decreasing in bottom material. PCB's were present in similar concentrations (Bayou Segnette near Barataria) or increased (Bayou Segnette 4.6 miles below Westwego) from 1981-82 to 1999-2000. Cadmium concentrations consistently decreased by half or more at all three sites from 1981-82 to 1999-2000. Mercury concentrations were consistently lower at all three sites in the 1999-2000 survey, but the differences from the 1981-82 survey were small. Chromium concentrations increased at two of the three sites from 1981-82 to the present survey. At the third site, no chromium value was available for the earlier survey. Concentrations of copper and nickel increased in bottom material at the two sites on Bayou Segnette, but decreased at Kenta Canal northwest of Westwego. Probable Effects Levels (PEL's) and Interim Sediment Quality Guidelines (ISQG's) concentrations, as tabulated by the Canadian Council of Ministers of the of the Environment, were used to assess the probability of biological impairment in the Barataria Preserve. PEL’s are concentrations of a chemical at or above which some biological impairment is likely. ISQG concentrations are those at or below which biological impairment is unlikely. Concentrations of 2,4-D and trace elements, when detected in surface water, were substantially lower than levels at which biological impairment could be expected. Concentrations of organic compounds in bottom material were at most less than 25 percent of PEL’s, and usually much lower. Arsenic, cadmium, copper, and lead concentrations in bottom material were generally slightly above or lower than ISQG concentrations in both surveys, although arsenic was as high as 53 percent of PEL’s at one site in the 1999-2000 survey. All other trace elements in bottom material were present in concentrations lower than ISQG concentrations.

Louisiana↗

USGS2024

The National Ocean Biodiversity Strategy

President Biden has been clear that the ocean is central to life on Earth. As he has proclaimed, “the ocean powers millions of jobs; feeds and sustains us; and is a rejuvenating source of inspiration, exploration, and recreation.” The Biden-Harris Administration has worked hard to fulfill the President’s goal to protect and conserve at least 30% of U.S. waters by 2030. The ocean faces increased threats from warming, overfishing, increased acidity, and loss of biodiversity. It is now more important than ever to sustain the many benefits that the ocean, coasts, and Great Lakes provide, including food, a favorable climate, recreation, physical and mental health, and for many, a sense of cultural identity. Ocean life represents an irreplaceable heritage, the foundation of a habitable planet, and a vast trove of resources. Keeping our ocean healthy requires reliable information on the changing status of these living organisms, the drivers of biodiversity change, and options for effectively addressing those drivers. Over 2 million species are estimated to live in the ocean, yet only about 240,000 species have been described by scientists. Most of the ocean’s benefits result from those diverse species interacting with one another and the environment they create. To protect and conserve the ocean, we as a nation need to make better use of existing knowledge and prioritize acquiring new biodiversity knowledge to enable better policy and management decisions. The ability to monitor ocean species and habitats has expanded dramatically over the past decade, with innovations in technology, genomics, taxonomy, big data management and sharing, artificial intelligence, and machine learning. Yet large fractions of the U.S. ocean remain almost unknown. The National Ocean Biodiversity Strategy (strategy) reflects the urgent need to leverage these advances. The goals of this strategy must be guided by the nation’s diverse voices and ways of knowing, in order to maximize effective and equitable stewardship of the ocean’s diverse life and its benefits to people. The strategy is intended as a guiding document for government to advance three overarching goals: ● Goal 1: Drive delivery of ocean biodiversity knowledge at the national scale. Objectives include developing an Implementation Plan for achieving the strategy’s three goals; establishing a coordination mechanism to manage the implementation; and documenting gaps in biodiversity knowledge and the benefits of ocean biodiversity to people and economies. ● Goal 2: Strengthen tools and institutions to deliver ocean biodiversity knowledge. Objectives include establishing a robust information pipeline to support indicators and dynamic maps of ocean biodiversity, from the coasts to the deep sea. This pipeline should include expanded observing systems and comprehensive data management; science and technology solutions to accelerate the availability of biodiversity information; and plans to leverage previous investments to rebuild and expand the nation’s human capital and infrastructure to sustain foundational taxonomy and biodiversity science. ● Goal 3: Protect, conserve, restore, and sustainably use ocean biodiversity. Objectives include expanding the collection, delivery, and use of biodiversity knowledge to inform actions that advance ocean protection, conservation, restoration, and sustainable development. Government should lead in establishing and incentivizing diverse partnerships across scales and sectors to implement those actions and should educate and involve the public to discover and value the nation’s diverse ocean life. Achieving these goals will require commitments across society: new federal and private investments, coordination across sectors to address climate and equity challenges, and engagement of Indigenous Knowledge holders and frontline communities as full partners throughout planning and implementation. The Subcommittee on Ocean Science and Technology (SOST) IWG-Biodiversity will begin developing an Implementation Plan to describe and direct specific actions to implement the strategy. Successful implementation of the strategy will harmonize and expand collection and delivery of timely knowledge on ocean life to all of society. The strategy will also enable evidence-based management and protection of the ocean. Advancing the strategy will build human and institutional capital and partnerships that support both existing mandates and new needs to rebuild and sustain biodiversity, achieve healthy ocean ecosystems, and manage living resources. Implementing the strategy will deliver knowledge for monitoring, modeling, forecasting, and assessments that support food security, public health, and cultural values, and that more effectively protect, conserve, and restore nature.

Report↗

USGS2026

Diverse novel and avian-associated viruses in the ileal viromes of northern mockingbird (Mimus polyglottos)

Viruses are the most abundant and diverse organisms on Earth, though only a small portion cause disease. Understanding viral diversity is key to understanding and predicting pathogen emergence and zoonotic spillover. Here, we use meta-transcriptomic sequencing to examine the viral communities in the ileum of 25 Northern Mockingbirds ( Mimus polyglottos ) from various locations across Texas. We assembled high-quality genomes of 43 viral species (40 species identified to 13 families, one to kingdom, and two to realm), 38 of which were novel. They tentatively represent avian- (n = 3), arthropod- (n = 21), plant- (n = 5) and fungi- (n = 4) associated, or other (n = 10) viruses. The arthropod-associated Dicistroviridae family was the most dominant, comprising known and potentially new species. Of potential epidemiological importance were three novel and avian-associated viruses: members of the families Hepeviridae and Picornaviridae , and a new Matryoshka RNA virus. The Matryoshka RNA virus 8 (MaRNAV-8) is sister to other Matryoshka RNA viruses, and its co-occurrence with haemosporida further supports the nested virus-parasite-vector-vertebrate host relationship of this group of viruses, with potential implications for parasite evolution, fitness and load and vector competence. The Picornaviridae virus is a member of an avian hepatovirus clade, found nested within a clade containing both the mammalian pathogens Hepatovirus A – I and the avian Tremovirus pathogens, suggestive of a newly discovered pathogen of Northern Mockingbird. Although the recovered Hepeviridae virus is of unknown pathology, its family members include the Hepatitis E viruses. With the great diversity and novelty described from ileal viromes, discriminating potential pathogens and commensal microbiota from viruses associated with food items remains challenging. A deeper understanding of virus transmission and the risk of potential zoonosis can be enhanced by tracking viruses through the food web and via inter-specific and predator-prey interactions, particular in areas subject to land-use change, where human-wildlife interactions are increased and the risks from emerging pathogens of veterinary and medical importance are more pronounced.

Texas↗

USGS1988

Effects of zinc smelter emissions on farms and gardens at Palmerton, PA

In 1979, before the primary Zn smelter at Palmerton was closed due to excessive Zn and Cd emissions and change in the price of Zn, we were contacted by a local veterinarian regarding death of foals (young horses) on farms near the smelter. To examine whether Zn or Cd contamination of forage or soils could be providing potentially toxic levels of Zn or other elements in the diets of foals, we measured metals in forages, soils, and feces of grazing livestock on two farms near Palmerton. The farms were about 2.5 and about 10 km northeast of the East stack. Soils, forages, and feces were greatly increased in Zn and Cd. Soil, forage, and fecal Zn were near 1000 mg/kg and Cd, 10-20 mg/kg at farm A (2.5 km) compared to normal background levels of 43 mg Zn and 0.2 mg Cd/kg, respectively. Liver and kidney of cattle raised on Farm A were increased in Zn and Cd, indicating that at least part of the Zn and Cd in smelter contaminated forages was bioavailable. During the farm sampling, we obtained soil from one garden in Palmerton within 200 m of the primary (West) smelter. The Borough surrounds the smelter facility in a valley. Because soil Cd was near 100 mg/kg, we sampled garden soils and vegetables from over 40 gardens in 6 randomly selected blocks and in rural areas at different distances from the smelter during September, 1980. All homes were contacted on each sampled block. Nearly all homes had some garden, while at least 2 appeared to grow over 50% of their annual vegetable and potato consumption. Palmerton garden soils averaged 76 mg Cd/kg and 5830 mg Zn/kg. Gardeners had been taught to add limestone and organic fertilizers to counteract yield reduction and chlorosis due to the excessive soil Zn. Gardens with over 5000 mg Zn/kg were nearly allover pH 7, and many were calcareous. Because the smelter had not yet ceased operations in 1980, crops could have been polluted by aerosol Zn and Cd emitted by the smelter. Crop Zn and Cd were extremely high, about 100 times normal Cd levels. In more distant gardens, soil metals were not so high, and gardeners had not added as much limestone. Bean rotated with the potatoes and leafy vegetables often suffered chlorosis and visible yield reduction. Potatoes contained up to 6 mg Cd/kg dry wt. compared to backgrournd 0.20 mg/kg DW. An estimate of potential Zn and Cd intakes due to the contaminated crops was made using the teen-aged male diet model, and average Cd intakes would be 250 ug/day if diets contained 100% locally grown leafy and root vegetables and potatoes. Gardeners were warned to restrict consumption of garden grown leafy and root vegetables and potatoes, and to apply 22 T/A of limestone to restrict Cd uptake. Use of improved adult diet models, and increased understanding of the effect of Zn on Cd bioavailability indicate that little Cd risk may result from consuming garden vegetables grown at Palmerton. Individuals appear to be protected because Zn accompanied crop Cd, they grew only small amounts of vegetables in most cases, and aerosol pollution of crops has ceased. Reduced Zn emissions, and Cu supplementation have prevented further health effects on foals or cattle. Detailed examination of these risks is needed to develop remedial measures for both farms and gardens in the Zn + Cd polluted soils near Zn smelters at many locations in the United States and other countries. Remedial actions are necessarary to prevent chronic Zn toxicity to crops and livestock, and minimize the risk of chronic Cd toxicity to humans who consume locally grown garden crops.

Pennsylvania↗

USGS2016

Total cylindrospermopsins, microcystins/nodularins, and saxitoxins data for the 2007 United States Environmental Protection Agency National Lake Assessment

Phytoplankton communities in freshwater lakes, ponds, and reservoirs may be dominated by cyanobacteria (also called blue-green algae) under certain environmental conditions. Cyanobacteria may cause a range of water-quality impairments, including the potential for toxin production. Cyanobacteria toxins (cyanotoxins) may adversely impact human and ecological health. Microcystins are considered to be one of the most commonly found classes of cyanotoxins in freshwater ecosystems, and as such were selected as a recreational indicator of water quality for the 2007 United States Environmental Protection Agency (EPA) National Lakes Assessment. However, much less is known about the occurrence of other classes of cyanotoxins in fresh surface water such as anatoxins, cylindrospermopsins, nodularins, and saxitoxins. The 2007 National Lakes Assessment followed a probabilistic study design and was directed by the EPA, in partnership with States, Tribes, and other federal agencies of the United States, to provide an assessment of water quality in the Nation’s lakes, ponds, and reservoirs based on trophic status, and ecological and recreational indicators. Integrated photic zone samples were collected by the EPA, U.S. Geological Survey (USGS), States, and Tribes in target water bodies, generally at their deepest point, and analyzed for microcystins by the U.S. Geological Survey. The USGS assisted with this survey by providing technical expertise and enzyme linked immunosorbent assay (ELISA) analysis of microcystins for all survey samples as an indicator for recreational water quality. A small subset of samples ( n =27) was analyzed by liquid chromatography tandem mass spectrometry (LC/MS/MS) by the USGS. Additionally, through partnership with the EPA National Health and Environmental Effects Research Laboratory (NHEERL), USGS analyzed all frozen samples by ELISA for two other classes of cyanotoxins, cylindrospermopsins and saxitoxins. Total cylindrospermopsins, microcystins, and saxitoxins were measured by enzyme-linked immunosorbent assay in a total of 1,331 samples from 1,161 lakes. Samples from this study had detection frequencies of 4.0, 32 (unweighted), and 7.6 percent, mean concentrations (detections only) of 0.56, 3.0, and 0.061 micrograms/L (μg/L), and maximum concentrations of 4.4, 230, and 0.38 μg/L for cylindrospermopsins, microcystins, and saxitoxins by ELISA, respectively in visit 1 and visit 2 samples. Microcystin ELISA results were categorized based on World Health Organization recreational surface-water guidelines for the relative probability of adverse health impacts because of microcystin exposure. The dataset described in this report is the first ever national reconnaissance of cyanotoxins in the United States. At least one microcystin congener was detected by LC/MS/MS in 52 percent of the 27 samples analyzed at a concentration greater than the LC/MS/MS minimum reporting level (MRL) of 0.010 μg/L and included detections for microcystin-LA, microcystin-LR, microcystin-LY, microcystin-RR, and microcystin-YR. Anatoxin-a, cylindrospermopsin, and nodularin-R were detected in 15 percent, 7 percent, and 4 percent of samples, respectively, at concentrations above 0.010 μg/L. Deoxycylindrospermopsin, domoic acid, lyngbyatoxin-a, microcystin-LF, microcystin-LW, and okadaic acid were not detected in the LC/MS/MS subset.

Data Series↗

USGS2003

Methodology for estimating times of remediation associated with monitored natural attenuation

Natural attenuation processes combine to disperse, immobilize, and biologically transform anthropogenic contaminants, such as petroleum hydrocarbons and chlorinated ethenes, in ground-water systems. The time required for these processes to lower contaminant concentrations to levels protective of human health and the environment, however, varies widely between different hydrologic systems, different chemical contaminants, and varying amounts of contaminants. This report outlines a method for estimating timeframes required for natural attenuation processes, such as dispersion, sorption, and biodegradation, to lower contaminant concentrations and mass to predetermined regulatory goals in groundwater systems. The time-of-remediation (TOR) problem described in this report is formulated as three interactive components: (1) estimating the length of a contaminant plume once it has achieved a steady-state configuration from a source area of constant contaminant concentration, (2) estimating the time required for a plume to shrink to a smaller, regulatoryacceptable configuration when source-area contaminant concentrations are lowered by engineered methods, and (3) estimating the time needed for nonaqueous phase liquid (NAPL) contaminants to dissolve, disperse, and biodegrade below predetermined levels in contaminant source areas. This conceptualization was used to develop Natural Attenuation Software (NAS), an interactive computer aquifers. NAS was designed as a screening tool and requires the input of detailed site information about hydrogeology, redox conditions, and the distribution of contaminants. Because NAS is based on numerous simplifications of hydrologic, microbial, and geochemical processes, the program may introduce unacceptable errors for highly heterogeneous hydrologic systems. In such cases, application of the TOR framework outlined in this report may require more detailed, site-specific digital modeling. The NAS software may be downloaded from the Web site http://www.cee.vt.edu/NAS/ Application of NAS illustrates several general characteristics shared by all TOR problems. First, the distance of stabilization of a contaminant plume is strongly dependent on the natural attenuation capacity of particular ground-water systems. The time that it takes a plume to reach a steady-state configuration, however, is independent of natural attenuation capacity. Rather, the time of stabilization is most strongly affected by the sorptive capacity of the aquifer, which is dependent on the organic matter content of the aquifer sediments, as well as the sorptive properties of individual contaminants. As a general rule, a high sorptive capacity retards a plume.s growth or shrinkage, and increases the time of stabilization. Finally, the time of NAPL dissolution depends largely on NAPL mass, composition, geometry, and hydrologic factors, such as ground-water flow rates. An example TOR analysis for petroleum hydrocarbon NAPL was performed for the Laurel Bay site in South Carolina. About 500 to 1,000 pounds of gasoline leaked into the aquifer at this site in 1991, and the NAS simulations suggested that TOR would be on the order of 10 years for soluble and poorly sorbed compounds, such as benzene and methyl tertiary-butyl ether (MTBE). Conversely, TOR would be on the order of 40 years for less soluble, more strongly sorbed compounds, such as toluene, ethylbenzene, and xylenes (TEX). These TOR estimates are roughly consistent with contaminant concentrations observed over 10 years of monitoring at this site where benzene and MTBE concentrations were observed to decrease rapidly and are approaching regulatory maximum concentration limits, whereas toluene, ethylbenzene, and xylene concentrations decreased at a slower rate and have remained relatively high. An example TOR analysis for petroleum hydrocarbon NAPL was performed for the Laurel Bay site in South Carolina.

South Carolina↗

USGS2020

Hydrogeology and shallow groundwater quality in the tidal Anacostia River watershed, Washington, D.C.

Groundwater hydrology and geochemistry within the tidal Anacostia River watershed of Washington, D.C. are related to natural and human influences. The U.S. Geological Survey, in cooperation with the District Department of Energy & Environment, began investigating the hydrogeology and groundwater quality of the watershed in 2002. Lithologic coring, groundwater-level and tidal monitoring, and water-quality sampling have been conducted to improve understanding of the groundwater-flow system, geochemistry, water quality, and the likely interaction between groundwater and the tidal Anacostia River. The flow and interaction of shallow groundwater with the tidal Anacostia River and other area streams are affected by diversions, pumping, land reclamation, and other human activities in this highly urbanized watershed. The tidal Anacostia River watershed is underlain by a wedge of unconsolidated sediments that is part of the Atlantic Coastal Plain Physiographic Province. These sediments form a system of confined and unconfined aquifers. The coarse sediments of the Potomac Group sand-dominated lithofacies form the Patuxent aquifer. The Patuxent aquifer crops out and subcrops in the northwestern part of the study area, but is confined to the southeast by the overlying Potomac Group clay-dominated lithofacies. Overlying the Potomac Group is a series of interbedded sands and clays that form an unconfined surficial aquifer system. Regional correlation in the unconfined surficial aquifer system is complicated by local heterogeneity in aquifer sediments. Local perched and semi-confined conditions occur in some areas. Recharge of the confined Patuxent aquifer occurs primarily in the outcrop and subcrop area, although some recharge may also occur through overlying confining units. Recharge to the unconfined surficial aquifer system occurs through infiltration of precipitation and possible artificial recharge from structures such as underground water or sewer pipes. In the Patuxent aquifer, hydraulic gradients indicate downward movement in the outcrop area, whereas hydraulic heads beneath the Anacostia River are higher than land surface, indicating an upward hydraulic gradient. In the unconfined surficial aquifer system, groundwater generally flows from upland recharge areas towards discharge areas near the Anacostia River and its tributaries. Groundwater from the confined part of the Patuxent aquifer also may discharge to the Anacostia River in locations where the overlying clay-dominated lithofacies of the Potomac Group is absent as a result of past geologic and (or) alluvial processes. Geochemistry and groundwater quality are affected by hydrologic conditions as well as anthropogenic influences. Local variability in groundwater quality reflects local variability in hydrogeologic conditions and sources of chemicals. Groundwater ranges from anoxic and iron- or calcium-bicarbonate type, to oxic with elevated nitrate. The occurrence and distribution of pesticides, volatile organic compounds, and other selected chemical compounds in groundwater reflect the multitude of sources common to urban areas, as well as variable hydrogeologic and geochemical conditions that affect their fate and transport in the environment. Overall, concentrations of only a few of the over 200 chemical constituents included in laboratory analyses exceeded regulatory standards or guidance values. These include tetrachloroethene and arsenic, which were each detected one time in different wells. There were also several detections of iron and manganese that exceeded regulatory standards or guidance values that are associated with reducing conditions in aquifer sediments.

Washington, D.C.↗

USGS2019

Wild canid distribution and co-existence in a natural–urban matrix of the Pioneer Valley of Western Massachusetts

Although development and urbanization are typically believed to have negative impacts on carnivoran species, some species can successfully navigate an urban matrix. Sympatric carnivorans compete for limited resources in urban areas, likely with system-specific impacts to their distributions and activity patterns. We used automatically triggered wildlife cameras to assess the local distribution and co-existence of Canis latrans (Coyote) , Vulpes vulpes (Red Fox), and Urocyon cinereoargenteus (Gray Fox) across the Pioneer Valley, MA, in relation to different levels of human development. We placed cameras at 79 locations in forested, altered, and urban land-use areas from September to November 2012 and accumulated 1670 trap nights. We determined site characteristics and detection rates for 12 other wildlife species for each camera location to develop a generalized linear model for the local distribution of each focal canid species across the study area. We also compared diel activity patterns among Coyotes, Red Foxes, and Gray Foxes, and calculated coefficients of overlap between each pair. The local distribution of Coyotes was positively associated with the detection rates of their prey and not associated with detection rates of sympatric carnivoran species. Red Foxes and Gray Foxes had negative relationships with the detection rate of Coyotes, and none of the 3 canid species showed a positive correlation with increased levels of urbanization. There was a high degree of temporal overlap in diel activity patterns and limited spatial overlap of our focal species, which suggests that any competition avoidance across our study area occurred at the spatial level. Coyotes fill the role of top predator in the Pioneer Valley, and likely have a negative impact on the local distributions of smaller canids, while their own local distributions seem to be driven by prey availability.

Massachesetts↗

USGS2018

Chemical and isotopic characteristics of methane in groundwater of Ohio, 2016

In 2016, the U.S. Geological Survey, in cooperation with the Ohio Water Development Authority, investigated the hydrogeologic setting, chemical and isotopic characteristics, and origin of methane in groundwater of Ohio. Understanding the occurrence and distribution of methane in groundwater is important in terms of public safety because methane in water wells can pose a risk of explosion. In addition, documenting the chemical and isotopic characteristics of methane in groundwater can make an important contribution to future stray gas investigations. Water samples were collected from 15 domestic water wells known to produce methane, which were in 12 counties in diverse parts of Ohio. The wells were 75–345 feet deep and tapped a range of aquifer types, including glacial deposits and bedrock of Upper Ordovician, Upper Devonian, Lower Mississippian, and Pennsylvanian ages. Although the hydrogeologic settings were varied, there was a broad similarity among the well sites in that the bedrock was predominantly shale and the glacial deposits were predominantly clay. The wells were sampled for dissolved inorganic constituents; dissolved organic carbon; methane and other dissolved gases; stable isotopes (carbon, hydrogen, and oxygen) of methane, water, and dissolved inorganic carbon; and carbon-14 of methane. Gas composition and stable isotopes of methane were used to differentiate thermogenic and microbial methane. The degree of fractionation of hydrogen and carbon isotopes was used to evaluate the pathway of microbial methanogenesis (carbon dioxide [CO 2 ] reduction or acetate fermentation) and the effects of secondary processes such as oxidation, mixing, and migration. The concentration of carbon-14 of methane was used to evaluate the relative age of the carbon source. The quality of water from the 15 wells differed greatly; water types ranged from CaMgHCO 3 to NaCl, and total dissolved solids concentrations ranged from 318 to 2,940 milligrams per liter (mg/L). Methane concentrations ranged from 1.2 to 120 mg/L. Of the 15 samples, 12 had methane concentrations greater than 28 mg/L, the level that can pose a risk of explosion. Of the 15 samples, 12 had chemical and isotopic characteristics or "signatures" consistent with microbial methane formed by CO 2 reduction. CO 2 reduction is commonly associated with microbial degradation of organic matter in anaerobic aquifers and with the formation of microbial shale gas and coalbed methane along margins of sedimentary basins. Two of 15 samples were interpreted as having a component of thermogenic methane based on the δ 13 C of methane (−50.96 and −47.74 parts per thousand [per mil]) and gas dryness (28 and 5). One of 15 samples (from the shallowest well) had chemical and isotopic characteristics consistent with methane oxidation by sulfate reduction based on light δ 13 C of dissolved inorganic carbon (−31.6 per mil) and evidence of sulfate reduction in terms of the odor and appearance of the water. For the 12 samples interpreted as microbial methane formed by CO 2 reduction, the δ 13 C of methane varied from −75 to −56 per mil. Multiple samples from the same aquifer demonstrated a general trend of increasing δ 13 C of methane with depth. Samples with lighter δ 13 C of methane (−75 to −62 per mil) were from shallower wells (or wells with shallow open intervals), and the isotopic signature of the water was consistent with modern or postglacial groundwater recharge. Three samples with heavier δ 13 C of methane (−61 to −56 per mil) were from deeper wells or more confined aquifers where the isotopic signature of water was consistent with older (glacial) recharge. In addition, δ 13 C of dissolved inorganic carbon was enriched (+12 to +18.9 per mil), and carbon-14 of methane was consistent with carbon associated with Paleozoic bedrock or older glacial deposits. These observations are generally consistent with increased Rayleigh-type fractionation at greater depths; however, other interpretations are possible. Isotopic signatures can be ambiguous, especially in areas with complex geologic histories that include multiple episodes of migration, mixing, and (or) oxidation. Many of the wells were in proximity to multiple potential natural and anthropogenic pathways of methane migration; however, it is not possible to determine if the methane in any of the wells is related to human activities based on the chemical and isotopic data collected for this study.

Ohio↗

USGS2008

Anthropogenic influences on the input and biogeochemical cycling of nutrients and mercury in Great Salt Lake, Utah, USA

Despite the ecological and economic importance of Great Salt Lake (GSL), little is known about the input and biogeochemical cycling of nutrients and trace elements in the lake. In response to increasing public concern regarding anthropogenic inputs to the GSL ecosystem, the US Geological Survey (USGS) and US Fish and Wildlife Service (USFWS) initiated coordinated studies to quantify and evaluate the significance of nutrient and Hg inputs into GSL. A 6??? decrease in ??15N observed in brine shrimp (Artemia franciscana) samples collected from GSL during summer time periods is likely due to the consumption of cyanobacteria produced in freshwater bays entering the lake. Supporting data collected from the outflow of Farmington Bay indicates decreasing trends in ??15N in particulate organic matter (POM) during the mid-summer time period, reflective of increasing proportions of cyanobacteria in algae exported to GSL on a seasonal basis. The C:N molar ratio of POM in outflow from Farmington Bay decreases during the summer period, supportive of the increased activity of N fixation indicated by decreasing ??15N in brine shrimp and POM. Although N fixation is only taking place in the relatively freshwater inflows to GSL, data indicate that influx of fresh water influences large areas of the lake. Separation of GSL into two distinct hydrologic and geochemical systems from the construction of a railroad causeway in the late 1950s has created a persistent and widespread anoxic layer in the southern part of GSL. This anoxic layer, referred to as the deep brine layer (DBL), has high rates of SO42 - reduction, likely increasing the Hg methylation capacity. High concentrations of methyl mercury (CH3Hg) (median concentration = 24 ng/L) were observed in the DBL with a significant proportion (31-60%) of total Hg in the CH3Hg form. Hydroacoustic and sediment-trap evidence indicate that turbulence introduced by internal waves generated during sustained wind events can temporarily mix the elevated CH3Hg concentrations in the DBL with the more biologically active upper brine layer (UBL). Brine shrimp collected during the summer/fall time periods contained elevated Hg concentrations (median concentration = 0.34 mg/kg, dry weight (dw)) relative to samples collected during the spring (median concentration < 0.2 mg/kg, dw). Higher Hg in brine shrimp during the summer and fall may reflect the higher proportion of adult brine shrimp during this time period, resulting in an increased time for bioaccumulation of Hg. Eared grebes (Podiceps nigricollis) consume brine shrimp from GSL during the fall molting period. Median Hg concentrations in eared grebe livers increased by almost three times during the 3-5 month fall molting period. Selected duck species utilizing GSL have consistently exceeded the US Environmental Protection Agency (USEPA) screening level for Hg (0.3 mg/kg Hg wet weight), resulting in the issuance of warnings against unlimited human consumption of breast muscle tissue.

Applied Geochemistry↗

USGS2010

Groundwater-quality data and regional trends in the Virginia Coastal Plain, 1906-2007

A newly developed regional perspective of the hydrogeology of the Virginia Coastal Plain incorporates updated information on groundwater quality in the area. Local-scale groundwater-quality information is provided by a comprehensive dataset compiled from multiple Federal and State agency databases. Groundwater-sample chemical-constituent values and related data are presented in tables, summaries, location maps, and discussions of data quality and limitations. Spatial trends in groundwater quality and related processes at the regional scale are determined from interpretive analyses of the sample data. Major ions that dominate the chemical composition of groundwater in the deep Piney Point, Aquia, and Potomac aquifers evolve eastward and with depth from (1) 'hard' water, dominated by calcium and magnesium cations and bicarbonate and carbonate anions, to (2) 'soft' water, dominated by sodium and potassium cations and bicarbonate and carbonate anions, and lastly to (3) 'salty' water, dominated by sodium and potassium cations and chloride anions. Chemical weathering of subsurface sediments is followed by ion exchange by clay and glauconite, and subsequently by mixing with seawater along the saltwater-transition zone. The chemical composition of groundwater in the shallower surficial and Yorktown-Eastover aquifers, and in basement bedrock along the Fall Zone, is more variable as a result of short flow paths between closely located recharge and discharge areas and possibly some solutes originating from human sources. The saltwater-transition zone is generally broad and landward-dipping, based on groundwater chloride concentrations that increase eastward and with depth. The configuration is convoluted across the Chesapeake Bay impact crater, however, where it is warped and mounded along zones having vertically inverted chloride concentrations that decrease with depth. Fresh groundwater has flushed seawater from subsurface sediments preferentially around the impact crater as a result of broad contrasts between sediment permeabilities. Paths of differential flushing are also focused along the inverted zones, which follow stratigraphic and structural trends southeastward into North Carolina and northeastward beneath the chloride mound across the outer impact crater. Brine within the inner impact crater has probably remained unflushed. Regional movement of the saltwater-transition zone takes place over geologic time scales. Localized movement has been induced by groundwater withdrawal, mostly along shallow parts of the saltwater-transition zone. Short-term episodic withdrawals result in repeated cycles of upconing and downconing of saltwater, which are superimposed on longer-term lateral saltwater intrusion. Effective monitoring for saltwater intrusion needs to address multiple and complexly distributed areas of potential intrusion that vary over time. A broad belt of large groundwater fluoride concentrations underlies the city of Suffolk, and thins and tapers northward. Fluoride in groundwater probably originates by desorbtion from phosphatic sedimentary material. The high fluoride belt possibly was formed by initial adsorbtion of fluoride onto sediment oxyhydroxides, followed by desorbtion along the leading edge of the advancing saltwater-transition zone. Large groundwater iron and manganese concentrations are most common to the west along the Fall Zone, across part of the saltwater-transition zone and eastward, and within shallow groundwater far to the east. Iron and manganese initially produced by mineral dissolution along the Fall Zone are adsorbed eastward and with depth by clay and glauconite, and subsequently desorbed along the leading edge of the advancing saltwater-transition zone. Iron and manganese in shallow groundwater far to the east are produced by reaction of sediment organic matter with oxyhydroxides. Large groundwater nitrate and ammonium concentrations are mostly limited to shallow depths. Most nitrate a

Professional Paper↗

USGS2013

Community exposure to tsunami hazards in California

Evidence of past events and modeling of potential events suggest that tsunamis are significant threats to low-lying communities on the California coast. To reduce potential impacts of future tsunamis, officials need to understand how communities are vulnerable to tsunamis and where targeted outreach, preparedness, and mitigation efforts may be warranted. Although a maximum tsunami-inundation zone based on multiple sources has been developed for the California coast, the populations and businesses in this zone have not been documented in a comprehensive way. To support tsunami preparedness and risk-reduction planning in California, this study documents the variations among coastal communities in the amounts, types, and percentages of developed land, human populations, and businesses in the maximum tsunami-inundation zone. The tsunami-inundation zone includes land in 94 incorporated cities, 83 unincorporated communities, and 20 counties on the California coast. According to 2010 U.S. Census Bureau data, this tsunami-inundation zone contains 267,347 residents (1 percent of the 20-county resident population), of which 13 percent identify themselves as Hispanic or Latino, 14 percent identify themselves as Asian, 16 percent are more than 65 years in age, 12 percent live in unincorporated areas, and 51 percent of the households are renter occupied. Demographic attributes related to age, race, ethnicity, and household status of residents in tsunami-prone areas demonstrate substantial range among communities that exceed these regional averages. The tsunami-inundation zone in several communities also has high numbers of residents in institutionalized and noninstitutionalized group quarters (for example, correctional facilities and military housing, respectively). Communities with relatively high values in the various demographic categories are identified throughout the report. The tsunami-inundation zone contains significant nonresidential populations based on 2011 economic data from Infogroup (2011), including 168,565 employees (2 percent of the 20-county labor force) at 15,335 businesses that generate approximately $30 billion in annual sales. Although the regional percentage of at-risk employees is low, certain communities, such as Belvedere, Alameda, and Crescent City, have high percentages of their local workforce in the tsunami-inundation zone. Employees in the tsunami-inundation zone are primarily in businesses associated with tourism (for example, accommodations, food services, and retail trade) and shipping (for example, transportation and warehousing, manufacturing, and wholesale trade), although the dominance of these sectors varies substantially among the 94 cities. Although the number of occupants is not known for each site, the tsunami-inundation zone contains numerous dependent-population facilities, such as schools and child daycare centers, which may have individuals with limited mobility. The tsunami-inundation zone includes a substantial number of facilities that provide community services, such as banks, religious organizations, and grocery stores, where local residents may be unaware of evacuation procedures if previous awareness efforts focused on home preparedness. There are also numerous recreational areas in the tsunami-inundation zone, such as amusement parks, marinas, city and county beaches, and State and national parks, which attract visitors who may not be aware of tsunami hazards or evacuation procedures. During peak summer months, estimated daily attendance at city and county beaches can be approximately six times larger than the total number of residents in the tsunami-inundation zone. Community exposure to tsunamis in California varies considerably—some communities may experience great losses that reflect only a small part of their community and others may experience relatively small losses that devastate them. Among 94 incorporated communities and the remaining unincorporated areas of the 20 coastal counties, the communities of Alameda, Oakland, Long Beach, Los Angeles, Huntington Beach, and San Diego have the highest number of people and businesses in the tsunami-inundation zone. The communities of Belvedere, Alameda, Crescent City, Emeryville, Seal Beach, and Sausalito have the highest percentages of people and businesses in this zone. On the basis of a composite index, the cities of Alameda, Belvedere, Crescent City, Emeryville, Oakland, and Long Beach have the highest combinations of the number and percentage of people and businesses in tsunami-prone areas.

California↗

USGS2016

Assessing the socioeconomic impact and value of open geospatial information

The production and accessibility of geospatial information including Earth observation is changing greatly both technically and in terms of human participation. Advances in technology have changed the way that geospatial data are produced and accessed, resulting in more efficient processes and greater accessibility than ever before. Improved technology has also created opportunities for increased participation in the gathering and interpretation of data through crowdsourcing and citizen science efforts. Increased accessibility has resulted in greater participation in the use of data as prices for Government-produced data have fallen and barriers to access have been reduced. The increase in participation in the production and in the use of data, defined as data democracy for this workshop, are having great impacts on economics and more generally on society. There is also a strong drive by governments around the world, as shown by the G8 Declaration in June 2013, to make public sector information and scientific data more widely accessible. These are respectively termed “open data” and “open research data.” This report summarizes discussion at the Workshop on Assessing the Impact and Value of Open Geospatial Information held at George Washington University in Washington, D.C. in October 2014. Workshop participants examined the consequences of expanding data democracy with a focus on its socioeconomic impacts. Evaluations were presented of state-of-the-art methods to assess these socioeconomic impacts, which included position papers and remarks by discussants. The workshop included discussions about the following topics: (1) increased and expanded information sources; (2) societal impacts, including approaches to economics assessments; (3) constraints to open access, including the demands for return on investment, specifications of intellectual property rights, and privacy issues; and (4) learning from the experiences of other data-rich domains, such as environmental management, internet businesses, health, and transportation. The workshop was a working meeting with strong participant engagement, leading to recommendations for action. The meeting included five topic-driven sessions and keynote presentations. Precirculated position papers for each panel session facilitated preparation and remarks by discussants. After the position papers are updated following the discussants’ remarks, it is planned to submit them for publication. The workshop included 68 participants coming from international organizations, the U.S. public and private sectors, nongovernmental organizations, and academia. Participants included policy makers and analysts, financial analysts, economists, information scientists, geospatial practitioners, and other discipline experts.

Open-File Report↗

USGS2002

Selected elements and organic chemicals in streambed sediment in the Salem area, Oregon, 1999

Analysis of streambed sediments in the Salem, Oregon, area showed anomalously large concentrations of some elements and organic chemicals, indicating contamination from anthropogenic and/or geologic sources. The streambed sediment sample from Clark Creek, an urban basin, had large concentrations of polycyclic aromatic hyrdocarbons (PAHs), organochlorines, cadmium, lead, and zinc. The sample from the East Fork of Pringle Creek, which is a mostly urban basin, had the highest concentrations of DDD, DDE, and DDT compounds. Aldrin was detected in streambed sediment at only one site, the East Fork of Pringle Creek. Ten of the 14 sites sampled had exceedances of the sediment quality guidelines of the Canadian Council of Ministers of the Environment (CCME), and 8 sites had exceedances of guidelines from the Puget Sound Dredged Disposal Analysis (PSDDA) Program. Trace element concentrations in the Salem area generally were similar to those found previously in the Willamette Basin and nationally. However, cadmium, lead, and zinc concentrations were larger in the sample from Clark Creek than for largest value for Willamette Basin data from earlier studies. Zinc concentrations in the sample from Clark Creek exceeded sediment quality guidelines from the CCME and PSDDA. p,p'-DDE, which is a persistent breakdown product of the banned organochlorine-insecticide, DDT, was detected at all sites. Total DDT (the sum of p,p'-DDD, p,p'-DDE, and p,p'-DDT) concentrations exceeded the PSDDA screening level at eight sites and exceeded twice the PSDDA maximum level at the East Fork of Pringle Creek. Cis- and trans- chlordanes were detected at about 80% of the sites. The concentration of total chlordane for the sample at Clark Creek was larger than for any sample from previous Willamette Basin studies. The largest concentration of dieldrin also was from the sample at Clark Creek, which was the only site that exceeded the CCME guideline for dieldrin. The high levels of contaminants in some Salem area streams indicates the need for further study to assess the biological effects of these contaminants. Future monitoring in the Salem area could include bioassays using benthic invertebrates and the measurement of organochlorine compounds, including DDT, DDE, DDD, and dieldrin in fish tissue. Because resident fish may be consumed by humans and wildlife, fish tissue analyses would be helpful to determine the health risk associated with fish consumption.

Water-Resources Investigations Report↗

USGS2007

WOVOdat design document: The schema, table descriptions, and create table statements for the database of worldwide volcanic unrest (WOVOdat Version 1.0)

WOVOdat Overview During periods of volcanic unrest, the ability to forecast near future activity has been a primary concern for human populations living near volcanoes. Our ability to forecast future activity and mitigate hazards is based on knowledge of previous activity at the volcano exhibiting unrest and knowledge of previous activity at similar volcanoes. A small set of experts with past experience are often involved in forecasting. We need to both preserve the knowledge the experts use and continue to investigate volcanic data to make better forecasts. Advances in instrumentation, networking, and data storage technologies have greatly increased our ability to collect volcanic data and share observations with our colleagues. The wealth of data creates numerous opportunities for gaining a better understanding of magmatic conditions and processes, if the data can be easily accessed for comparison. To allow for comparison of volcanic unrest data, we are creating a central database called WOVOdat. WOVOdat will contain a subset of time-series and geo-referenced data from each WOVO observatory in common and easily accessible formats. WOVOdat is being created for volcano experts in charge of forecasting volcanic activity, scientists investigating volcanic processes, and the public. The types of queries each of these groups might ask range from, 'What volcanoes were active in November of 2002?' and 'What are the relationships between tectonic earthquakes and volcanic processes?' to complex analyses of volcanic unrest to determine what future activity might occur. A new structure for storing and accessing our data was needed to examine processes across a wide range of volcanologic conditions. WOVOdat provides this new structure using relationships to connect the data parameters such that searches can be created for analogs of unrest. The subset of data that will fill WOVOdat will continue to be collected by the observatories, who will remain the primary archives of raw and detailed data on individual episodes of unrest. MySQL, an Open Source database, was chosen as the WOVOdat database for its integration with common web languages. The question of where the data will be stored and how the disparate data sets will be integrated will not be discussed in detail here. The focus of this document is to explain the data types, formats, and table organization chosen for WOVOdat 1.0. It was written for database administrators, data loaders, query writers, and anyone who monitors volcanoes. We begin with an overview of several challenges faced and solutions used in creating the WOVOdat schema. Specifics are then given for the parameters and table organization. After each table organization section, basic create table statements are included for viewing the database field formats. In the next stage of the project, scripts will be needed for data conversion, entry, and cleansing. Views will also need to be created once the data have been loaded and the basic queries are better known. Many questions and opportunities remain. We look forward to the growth and continual improvement in efficiency of the system. We hope WOVOdat will improve our understanding of magmatic systems and help mitigate future volcanic hazards.

Open-File Report↗

USGS2003

A Framework for Long-term Ecological Monitoring in Olympic National Park: Prototype for the Coniferous Forest Biome

This report is the result of a five-year collaboration between scientists of the U.S. Geological Survey Forest and Rangeland Ecosystem Science Center, Olympic Field Station, and the natural resources staff of Olympic National Park to develop a comprehensive strategy for monitoring natural resources of Olympic National Park. Olympic National Park is the National Park Serviceʼs prototype monitoring park, representing parks in the coniferous forest biome. Under the umbrella of the National Park Serviceʼs prototype parks program, U.S. Geological Survey and Olympic National Park staffs are obligated to: develop strategies and designs for monitoring the long-term health and integrity of national park ecosystems with a significant coniferous forest component. design exportable monitoring protocols that can be used by other parks within the coniferous forest biome (i.e., parks having similar environments), and create a demonstration area and ʻcenter of excellenceʼ for assisting other parks in developing ecological monitoring programs. Olympic National Park is part of the North Coast and Cascades Network, a network of seven Pacific Northwestern park units created recently by the National Park Serviceʼs Inventory and Monitoring Program to extend the monitoring of ʻvital signsʼ of park health to all National Park Service units. It is our intent and hope that the monitoring strategies and conceptual models described here will meet the overall purpose of the prototype parks monitoring program in proving useful not only to Olympic National Park, but also to parks within the North Coast and Cascades Network and elsewhere. Part I contains the conceptual design and sampling framework for the prototype long-term monitoring program in Olympic National Park. In this section, we explore key elements of monitoring design that help to ensure the spatial, ecological, and temporal integration of monitoring program elements and discuss approaches used to design an ecosystem-based monitoring program. Basic monitoring components include ecosystem drivers, (e.g., climate, atmospheric inputs, human pressures), indicators of ecosystem integrity (e.g., biogeochemical indicators), known threats (e.g., impacts of introduced mountain goats), and focal or ʻkeyʼ species (e.g., rare or listed species, Roosevelt elk). Monitoring system drivers and key indicators of ecosystem integrity provide the long-term baseline needed to judge what constitutes ʻunnaturalʼ variation in park resources and provide the earliest possible warning of unacceptable change. Monitoring effects of known threats and the status of focal species will provide information useful to park managers for dealing with current park issues. In Part I we describe the process of identifying potential indicators of ecological condition and present conceptual models of park ecosystems. In addition we report results from several workshops held in conjunction with Olympic National Park aimed at identifying potential indicators of change in the parkʼs ecosystem. First, we describe the responses of Olympic National Park staff to the generic question, “What is the most important resource to monitor in Olympic National Park and why?” followed by the responses from resource and land managers from areas adjoining the park. We also catalogue the responses of various expert groups that we asked to help identify the most appropriate system drivers and indicators of change in the Olympic National Park ecosystems. Results of the workshops provided the justification for selecting basic indicators of ecosystem integrity, effects of current threats to park resources, and focal resources of parks to detect both the currently evident and unforeseeable changes in park resources. We conclude Part I by exploring several generic statistical issues relevant to monitoring natural resources in Olympic National Park. Specifically we discuss trade-offs associated with sampling extensively versus sampling intensively in smaller geographic regions and describe a conceptual framework to guide development of a generic sampling frame for monitoring. We recommend partitioning Olympic National Park into three zones of decreasing accessibility to maximize monitoring efficiency. We present examples of how the generic sampling frame could be used to help ensure spatial integration of individual monitoring projects. Part II of the report is a record of the potential monitoring questions and indicators identified to date in our workshops. The presentation is organized according to the major system drivers, components, and processes identified in the intermediate-level working model of the Olympic National Park ecosystem. For each component of the park system, we develop the need and justification for monitoring, articulate park management issues, and describe key resources and ecosystem functions. We also present a pictorial conceptual model of each ecological subsystem, identify monitoring questions, and list potential indicators for each monitoring question. We conclude each section by identifying linkages of indicators to other ecological subsystems in our general ecosystem model, spatial and temporal contexts for monitoring (where and how often to monitor), and research and development needs. Part II represents the most current detailed listing of potential indicators—the material for subsequent discussions of monitoring priorities and selection of indicators for protocol development. Collectively, the sections of this report contain a comprehensive list of the important monitoring questions and potential indicators as well as recommendations for designing an integrated monitoring program. In Part I, Chapter 6 we provide recommendations on how to proceed with the important next steps in the design process: establishing priorities among the many possible monitoring questions and indicators, and beginning to research and design effective long-term monitoring protocols.

Information and Technology Report↗

USGS1999

The ecological condition of estuaries in the Gulf of Mexico

The Gulf of Mexico is a vast natural resource encompassing the coastal areas of western Florida, Alabama, Mississippi, Louisiana, and Texas, as well as a portion of Mexico. Many estuaries flow into the Gulf of Mexico and serve as nursery grounds for fish, habitat for a wide variety of wildlife, shipping routes, and a source of recreation. Estuarine-dependent species constitute more than 95 percent of the commercial fishery harvests from the Gulf of Mexico, and many important recreational fishery species depend on estuaries during some part of their life cycle. Gulf estuaries are diverse and productive ecosystems that provide a variety of valuable resources, including fish and shellfish, recreation, transportation, and water supply. Assessing the overall condition of Gulf of Mexico estuaries required incorporating data from other federal, state, and local monitoring programs to augment the information on ecological indicators collected by the U.S. Environmental Protection Agency’s (USEPA) Environmental Monitoring and Assessment Program (EMAP). The resulting document would provide a synthesis of the available knowledge about the condition of Gulf of Mexico estuaries. This document is intended for use by scientists and other citizens concerned with the ecological condition of estuaries, as well as by managers and lawmakers interested in the sustained use of estuaries for commercial and recreational purposes. It also addresses public concerns about the aesthetic quality of coastal areas vital to tourism and recreation. By producing this report on the ecological condition of estuaries in the Gulf of Mexico, we have taken one step in assessing the health of this environmental resource. We have produced an environmental “report card” to be used as a guide in the evaluation of management decisions and research directions. This report is organized in three parts: (1) an introduction that gives background information on the Gulf of Mexico, estuarine ecology, and the factors that impact estuaries in the gulf, (2) the main section on priority ecological indicators used to measure the condition of estuaries in the gulf and (3) an ecological report card that summarizes the data on ecological indicators and provides a rating of the condition of estuaries in each gulf state and for gulf estuaries overall. Many of the ratings were based on the percent area of estuaries in each state exhibiting degraded or adverse levels of an indicator. Eutrophication, a condition of high nutrients often resulting in low oxygen levels and other adverse effects, is an important water quality concern for estuaries along the gulf coast. The National Oceanic and Atmospheric Administration (NOAA) has compared the Gulf of Mexico to other coastal regions like the middle Atlantic and has ranked the Gulf of Mexico as having the highest number of point sources of nutrients and the highest percentage of land use devoted to agriculture. We evaluated monitoring data for nitrogen, chlorophyll, and dissolved oxygen as indicators of eutrophication. Although most of the estuaries exhibited high nitrogen or chlorophyll or low dissolved oxygen concentrations at least once during a survey, many times these conditions were observed in small rivers or bayous rather than in the entire estuary. Often, the percent area affected was low. The gulf estuaries had moderate conditions overall for nutrients and dissolved oxygen. Definite nutrient problems were observed in >25% of the estuarine area in Louisiana and Texas and definite dissolved oxygen problems were observed in Alabama. Contaminants in estuarine sediments provide evidence of the accumulation of chemicals from anthropogenic sources. We compared the concentrations of sediment contaminants to established guideline values to determine the proportion of estuarine area that could have potential adverse effects on living organisms. Although detectable levels of contaminants were measured in almost every estuary in the Gulf of Mexico, <25% of the estuarine area in all states had contaminant concentrations that exceeded these guidelines. Wetlands are integral parts of estuarine systems. Declining acreage means habitat loss that may be the result of commercial and residential development, hydrologic alterations, or dredge and fill operations. The Gulf of Mexico region contains more than 50% of the coastal wetland acreage in the U.S. and yet it also has the highest rate of coastal wetland loss. Nine of the top ten estuarine drainage areas ranked by total wetland area are in the Gulf of Mexico region. The most current estimates of total wetland loss over the past 200 years range from 41% to 54% for the gulf states. Although coastal wetlands continue to be altered or destroyed, some estimates indicate that the rate of loss has slowed. All gulf states were rated as having severe problems with wetland loss. The condition of benthic (bottom-dwelling) invertebrates, fish and shellfish, birds, and threatened and endangered species was used to evaluate the health of estuarine fauna. Degraded benthic communities inhabited <25% of the estuarine area in all gulf states except for Texas. Commercial fish and shellfish landings may be used as an indicator of population stability while fish biomarkers are used to measure the health of individuals in the population. Commercial landings of the top four fisheries (shrimp, menhaden, blue crab, and oyster) are stable in the gulf states while fish biomarkers indicate fair to poor fish health in Alabama and Texas and good fish health elsewhere. Coastal and marine bird populations appear to be in good condition throughout the gulf. Four threatened or endangered species inhabit coastal areas in the Gulf of Mexico: brown pelican, Gulf sturgeon, manatee, and Kemp’s ridley sea turtle. In general, populations of these species are in good to fair condition in the gulf states. Public health indicators include shellfish bed closures and chemicals found in edible fish tissue. Harvest of shellfish (primarily oyster in the Gulf of Mexico) is restricted or prohibited when concentrations of bacteria or other pathogens reach levels that could impair human health. The gulf states contain the most acreage of shellfish-growing waters in the U.S. but also have the most acreage restricted for harvest. All gulf states except Mississippi have >25% of their shellfish-growing waters restricted for harvest, mostly due to pollution from wastewater treatment plants or other upstream sources. Advisories may be issued that limit consumption when the concentrations of chemicals in fish tissue exceed levels known to be harmful to humans. Although seafood consumption advisories have been issued in all gulf states, the percent of the fish population with high concentrations of contaminants is relatively low in the gulf overall.

Alabama, Florida, Louisiana, Mississippi, Texas↗

USGS2008

Determination of human-health pharmaceuticals in filtered water by chemically modified styrene-divinylbenzene resin-based solid-phase extraction and high-performance liquid chromatography/Mass Spectrometry

In 1999, the Methods Research and Development Program of the U.S. Geological Survey National Water Quality Laboratory began the process of developing a method designed to identify and quantify human-health pharmaceuticals in four filtered water-sample types: reagent water, ground water, surface water minimally affected by human contributions, and surface water that contains a substantial fraction of treated wastewater. Compounds derived from human pharmaceutical and personal-care product use, which enter the environment through wastewater discharge, are a newly emerging area of concern; this method was intended to fulfill the need for a highly sensitive and highly selective means to identify and quantify 14 commonly used human pharmaceuticals in filtered-water samples. The concentrations of 12 pharmaceuticals are reported without qualification; the concentrations of two pharmaceuticals are reported as estimates because long-term reagent-spike sample recoveries fall below acceptance criteria for reporting concentrations without qualification. The method uses a chemically modified styrene-divinylbenzene resin-based solid-phase extraction (SPE) cartridge for analyte isolation and concentration. For analyte detection and quantitation, an instrumental method was developed that used a high-performance liquid chromatography/mass spectrometry (HPLC/MS) system to separate the pharmaceuticals of interest from each other and coextracted material. Immediately following separation, the pharmaceuticals are ionized by electrospray ionization operated in the positive mode, and the positive ions produced are detected, identified, and quantified using a quadrupole mass spectrometer. In this method, 1-liter water samples are first filtered, either in the field or in the laboratory, using a 0.7-micrometer (μm) nominal pore size glass-fiber filter to remove suspended solids. The filtered samples then are passed through cleaned and conditioned SPE cartridges at a rate of about 15 milliliters per minute. Excess water is eliminated from the cartridge sorbent bed by passing air through the cartridges, and the analytes retained on the SPE bed are eluted from the cartridge sequentially, first with methanol, followed by acidified methanol, and combined in collection tubes. This sample extract then is reduced from about 10 milliliters (mL) to about 0.1 mL (or 100 microliters) under a stream of purified nitrogen gas with the collection tubes in a heated (40°C) water bath. The reduced extracts then are fortified with an internal standard solution (when using internal standard quantitation), brought to a final volume of 1 mL with an aqueous ammonium formate buffer solution, and filtered through a 0.2-μm Teflon syringe filter as they are transferred into vials for instrumental analysis. Instrumental analysis by the HPLC/MS procedure permits determination of individual pharmaceutical concentrations from 0.005 to 1.0 microgram per liter, based on the lowest and the highest calibration standards routinely used. The reporting levels for this method are compound dependent, and have been experimentally determined based on the precision of quantitation of compounds from eight fortified organic-free water samples in single-operator experiments. The method detection limits and interim reporting levels for the compounds determined by this method were calculated from recoveries of the pharmaceuticals from reagent-water samples amended at 0.05 microgram per liter, and ranged between 0.0069 and 0.0142 microgram per liter, and 0.015 and 0.10 microgram per liter, respectively. Concentrations for 12 compounds are reported without qualification, and for two compounds are reported as qualified estimates. After initial development, the method was applied to more than 1,800 surface-, ground-, and wastewater samples from 2002 to 2005 and documented in a number of published studies. This research application of the method provided the opportunity to collect a large data set of ambient environmental concentrations and also permitted the collection of an extensive set of reagent blanks and spike quality-control (QC) samples. This multiple-year set of QC samples enabled further evaluation of method performance under multiple operator and multiple instrument conditions typical of routine laboratory operation. These results are an important part of the entire data set contained in this report because they document method performance over an extended time. Because sample matrix can substantially affect method performance, inclusion of environmental matrix-spike samples is required as a routine component of study plan quality control. Method performance has been measured by long-term tracking of observed recoveries from fortified organic-free water samples processed with environmental samples (laboratory reagent spikes), as well as by observed recoveries from multiple fortified environmental water samples. The fortified environmental samples included surface water, wastewater effluent-dominated surface water, and ground water, fortified at two environmentally relevant concentrations and corrected for ambient environmental concentrations. Because the responses of individual pharmaceuticals vary as a function of proton affinity, the ionization efficiency, and thus relative response, of each pharmaceutical, the quality-control surrogate compounds, and the quantitation internal standard can be suppressed or enhanced by the presence of the sample matrix. As a result, several quality-control sample types are required to properly interpret the ambient environmental concentrations of pharmaceuticals in aqueous samples. The quality-control sample types and results include laboratory reagent spikes and laboratory reagent blanks to provide insight into the performance of the method in the absence of a sample matrix, and matrix-spike recovery samples and replicate environmental samples, collected from representative sample matrix types within the aquatic system under study.

Techniques and Methods↗