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Timescales for migration of atmospherically derived sulphate through an alpine/subalpine watershed, Loch Vale, Colorado

Sulphur 35, a cosmogenically produced radioisotope with a short half‐life (87 days), was measured in snowpack during 1993–1997 and at four locations within the Loch Vale watershed during 1995–1997. The four sites include the two main drainages in the watershed, Andrews Creek and Icy Brook, a small south facing catchment flowing into Andrews Creek (Andrews Spring 1), and a similar north facing catchment flowing out of a scree field into Icy Brook (Spring 19). Concentrations ranged from a high of almost 50 mBq/L for a sample from Spring 19 in June 1996 to a concentration near the detection limit for a sample from Andrews Creek in April 1997. Sulphur 35 concentrations were normalized to sulphate (as mBq/mg SO 4 −2 ) and were decay‐corrected to a Julian day of 90 (April 1) for each year. Snowpack had the highest 35 S concentration with an average concentration of 53 mBq/mg SO 4 −2 . Concentrations in the streams were much lower, even when corrected for decay relative to JD 90. The large 35 S concentrations found in Spring 19 were the result of increases in concentration due to sublimation and/or evapotranspiration and were lower than snowpack when normalized to sulphate. Using 35 S concentrations found in snowpack as of JD 90 as a beginning concentration, the fraction of sulphate in streamflow that was derived from atmospheric deposition within the prior water year was estimated. For Icy Brook and Andrews Creek the fraction of the sulphate in streamflow derived from that year's snowpack and precipitation was low prior to the beginning of the main spring melt, reached a maximum during the period of maximum flow, and decreased as the summer progressed. A calculation of the seasonal flux indicated that about 40% of the sulphate that flowed out of the watershed was derived from atmospheric sulphate deposited during the previous year. This suggests that more than half of the sulphate deposited in the watershed by atmospheric processes during the previous year was removed during the following summer. Thus sulphate retention in alpine watersheds like Loch Vale is very limited, and changes in sulphate deposition should be quickly reflected in stream chemistry.

Colorado↗

Southern (California) sea otter population status and trends at San Nicolas Island, 2020–2023

The population of southern sea otters ( Enhydra lutris nereis ) at San Nicolas Island, California, has been monitored annually since the translocation of 140 southern sea otters to the island was completed in 1990. Monitoring efforts have varied in frequency and type across years. In 2017, the U.S. Navy and the U.S. Fish and Wildlife Service initiated a southern sea otter monitoring and research plan to determine the effects of military readiness activities on the growth or decline of the southern sea otter population at San Nicolas Island. The southern sea otter is the only subspecies of sea otter in California (hereafter, “sea otter"). The monitoring program, at its basic level, includes seasonal surveys of population abundance, distribution, and foraging activity. From 2020 to 2023, we measured a 10-percent per annum increase in population abundance (95-percent confidence interval =0–20 percent), with 146 total individuals as of April 2023. Coinciding with the recent population growth, the sea otter distribution, which previously tended to concentrate on the island’s west end during 2003–2006 before shifting toward more use in the north and south sides during 2017–2019, appears to have shifted again during 2020–2023 to concentrate at the island’s east end. Forage data were collected between February 2020 and April 2023. There was a total of 773 forage dives in 60 forage bouts, with most of the identified prey on successful dives (n=401) recorded as sea urchins (66 percent), followed by bivalves (15 percent), snails (12 percent), and crabs (5.2 percent). Two lobsters and three abalone also were identified among the sea otter prey. Estimates of energy intake rates averaged 14.0 kilocalories per minute (95-percent confidence interval =10.8–17.2 kilocalories per minute). Monitoring data from the past two decades indicate that sea otters at San Nicolas Island have maintained a steady pattern of energy intake and population growth characteristic of a robust population, including a sixfold growth between 2000 and 2023. There was no conclusive evidence of density-dependent effects based on these patterns; however, estimates of energy intake rates for 2020–2023 were slightly lower than previous estimates from 2017 to 2019. Additionally, subtidal monitoring results at four sites around San Nicolas Island indicated that counts of purple sea urchins ( Strongylocentrotus purpuratus ) have increased between 2003 and 2023, whereas sea otter foraging surveys completed during the same period revealed that some sea otters have shifted toward higher consumption of purple sea urchins and bivalves compared to red sea urchins ( S. fransicanus ), which generally are the preferred larger prey of sea otters. These results contribute to the understanding of population dynamics and to the conservation and planning of future monitoring and research of sea otters at San Nicolas Island.

California↗

Time scales of change in chemical and biological parameters after engineered levee breaches adjacent to Upper Klamath and Agency Lakes, Oregon

Eight sampling trips were coordinated after engineered levee breaches hydrologically reconnected both Upper Klamath Lake and Agency Lake, Oregon, to adjacent wetlands. The reconnection, by a series of explosive blasts, was coordinated by The Nature Conservancy to reclaim wetlands that had for approximately seven decades been leveed for crop production. Sets of nonmetallic porewater profilers (U.S. Patent 8,051,727 B1; November 8, 2011; http://www.uspto.gov/web/patents/patog/ week45/OG/html/1372-2/US08051727-20111108.html.) were deployed during these trips in November 2007, June 2008, May 2009, July 2009, May 2010, August 2010, June 2011, and July 2011 (table 1). Deployments temporally spanned the annual cyanophyte bloom of Aphanizomenon flos-aquae and spatially involved three lake and four wetland sites. Spatial and temporal variation in solute benthic flux was determined by the field team, using the profilers, over an approximately 4-year period beginning 3 days after the levee breaches. The highest flux to the water column of dissolved organic carbon (DOC) was detected in the newly flooded wetland, contrasting negative or insignificant DOC fluxes at adjacent lake sites. Over the multiyear study, DOC benthic fluxes dissipated in the reconnected wetlands, converging to values similar to those for established wetlands and to the adjacent lake (table 2). In contrast to DOC, benthic sources of soluble reactive phosphorus, ammonium, dissolved iron and manganese from within the reconnected wetlands were consistently elevated (that is, significant in magnitude relative to riverine and established-wetland sources) indicating a multi-year time scale for certain chemical changes after the levee breaches (table 2). Colonization of the reconnected wetlands by aquatic benthic invertebrates during the study trended toward the assemblages in established wetlands, providing further evidence of a multiyear transition of this area to permanent aquatic habitat (table 3). Both the lake and wetland benthic environments substantively contribute to macro- and micronutrients in the water column. Wetland areas undergoing restoration, and those being used for water storage, function very differently relatively to the established wetland within the Upper Klamath Lake National Wildlife Refuge, adjacent Upper Klamath Lake. Developing long-term management strategies for water quality in the Upper Klamath Basin requires recognition of the multi-year time scales associated with restoring wetlands that provide natural, seasonal ecosystem function and services.

Oregon↗

Detection and measurement of land subsidence and uplift using Global Positioning System surveys and interferometric synthetic aperture radar, Coachella Valley, California, 2010–17

Groundwater has been a major source of agricultural, recreational, municipal, and domestic supply in the Coachella Valley of California since the early 1920s. Pumping of groundwater resulted in groundwater-level declines as large as 50 feet (ft) or 15 meters (m) by the late 1940s. Because of concerns that the declines could cause land subsidence, the Coachella Valley Water District (CVWD) and the U.S. Geological Survey (USGS) have cooperatively investigated subsidence in the Coachella Valley since 1996. Importation of Colorado River water to the southern Coachella Valley began in 1949, resulting in a reduction in groundwater pumping and a recovery of groundwater levels during the 1950s through the 1970s. Since the late 1970s, the demand for water in the valley increased to the point that groundwater levels again declined in response to increased pumping and, consequently, increased the potential for land subsidence caused by aquifer-system compaction. Several management actions to increase recharge or to reduce reliance on groundwater have been implemented since as early as 1973 to address overdraft in the Coachella Valley. The implementation of three particular projects has markedly improved groundwater conditions in some of the historically most overdrafted areas of the valley: (1) groundwater substitution with surface-water imports since 2006 using Colorado River water through the Mid-Valley Pipeline project, which was expanded through 2017; (2) budget-based, tiered rates since 2009; and (3) managed aquifer recharge at the Thomas E. Levy Groundwater Replenishment Facility since 2009. Global Positioning System (GPS) surveying and interferometric synthetic aperture radar (InSAR) methods were used to determine the location, extent, and magnitude of the vertical land-surface changes in the Coachella Valley during 2010–17, updating 1993–2010 information presented in previous USGS reports. The GPS measurements taken at 24 geodetic monuments in August 2010 and September 2015 indicated that the land-surface elevation was stable at 17 monuments but changed at seven monuments during the 5-year period. Subsidence ranged from 0.17 to 0.43 ±0.09 ft (52 to 132 ±28 millimeters, or mm) at three monuments, and uplift ranged from 0.11 to 0.18 ±0.09 ft (33 to 54 ±28 mm) at four monuments between 2010 and 2015. At two of the monuments that subsided, the subsidence rates decreased between 2010 and 2015 from those computed between 2005 and 2010. Data prior to 2010 were not available for the third monument that subsided; thus, the 2010–15 subsidence rate could not be compared to an earlier period. At three of the monuments that uplifted between 2010 and 2015, data collected in 2005 and 2010 indicated stability. Data prior to 2010 were not available for the fourth monument that uplifted; thus, the 2010–15 uplift rate could not be compared to an earlier period. InSAR analyses for December 28, 2014–June 27, 2017, indicated that the land surface uplifted as much as about 0.20 ft (60 mm) near the Whitewater River Groundwater Replenishment Facility in the northern Coachella Valley and subsided as much as about 0.26 ft (80 mm) in the La Quinta area and less in Palm Desert, Indian Wells, and other localized areas in the southern Coachella Valley. These areas were identified as subsidence areas in previous reports covering periods during 1993–2010. The comparison of 2014–17 subsidence rates with those derived for 1995–2010 generally indicated a substantial slowing of subsidence, however. Analyses of deformation in the northern Coachella Valley were not included in the previous reports, so a comparison to deformation during the earlier period could not be made. Water levels in wells near the subsiding geodetic monuments, in and near the three subsiding areas shown by InSAR, and throughout the valley generally indicated seasonal fluctuations and longer-term stability or rising groundwater levels since about 2010. These results mark a reversal in trends of groundwater-level declines during the preceding decades. This trend reversal provides new insights into aquifer-system mechanics. Although many areas have stopped subsiding, and a few have even uplifted, the few areas that did subside during 2010–17—albeit at a slower rate—indicate a mixed aquifer-system response. Subsidence when groundwater levels are stable or recovering indicates that residual compaction may have occurred. At the same time, coarse-grained materials and thin aquitards may have expanded as groundwater levels recovered. The continued valley-wide stabilization and recovery of groundwater levels since 2010 likely is a result of various projects designed to increase recharge or to reduce reliance on groundwater.

California↗

Bioavailability and toxicity models of copper to freshwater life: The state of regulatory science

Efforts to incorporate bioavailability adjustments into regulatory water quality criteria in the United States have included four major procedures: hardness-based single-linear regression equations, water-effect ratios (WERs), biotic ligand models (BLMs), and multiple-linear regression models (MLRs) that use dissolved organic carbon, hardness, and pH. The performance of each with copper (Cu) is evaluated, emphasizing the relative performance of hardness-based versus MLR-based criteria equations. The WER approach was shown to be inherently highly biased. The hardness-based model is in widest use, and the MLR approach is the US Environmental Protection Agency's (USEPA's) present recommended approach for developing aquatic life criteria for metals. The performance of criteria versions was evaluated with numerous toxicity datasets that were independent of those used to develop the MLR models, including olfactory and behavioral toxicity, and field and ecosystem studies. Within the range of water conditions used to develop the Cu MLR criteria equations, the MLR performed well in terms of predicting toxicity and protecting sensitive species and ecosystems. In soft waters, the MLR outperformed both the BLM and hardness models. In atypical waters with pH <5.5 or >9, neither the MLR nor BLM predictions were reliable, suggesting that site-specific testing would be needed to determine reliable Cu criteria for such settings. The hardness-based criteria performed poorly with all toxicity datasets, showing no or weak ability to predict observed toxicity. In natural waters, MLR and BLM criteria versions were strongly correlated. In contrast, the hardness-criteria version was often out of phase with the MLR and, depending on waterbody and season, could be either strongly overprotective or underprotective. The MLR-based USEPA-style chronic criterion appears to be more generally protective of ecosystems than other models.

Environmental Toxicology and Chemistry↗

A Review of Land-Cover Mapping Activities in Coastal Alabama and Mississippi

INTRODUCTION Land-use and land-cover (LULC) data provide important information for environmental management. Data pertaining to land-cover and land-management activities are a common requirement for spatial analyses, such as watershed modeling, climate change, and hazard assessment. In coastal areas, land development, storms, and shoreline modification amplify the need for frequent and detailed land-cover datasets. The northern Gulf of Mexico coastal area is no exception. The impact of severe storms, increases in urban area, dramatic changes in land cover, and loss of coastal-wetland habitat all indicate a vital need for reliable and comparable land-cover data. Four main attributes define a land-cover dataset: the date/time of data collection, the spatial resolution, the type of classification, and the source data. The source data are the foundation dataset used to generate LULC classification and are typically remotely sensed data, such as aerial photography or satellite imagery. These source data have a large influence on the final LULC data product, so much so that one can classify LULC datasets into two general groups: LULC data derived from aerial photography and LULC data derived from satellite imagery. The final LULC data can be converted from one format to another (for instance, vector LULC data can be converted into raster data for analysis purposes, and vice versa), but each subsequent dataset maintains the imprint of the source medium within its spatial accuracy and data features. The source data will also influence the spatial and temporal resolution, as well as the type of classification. The intended application of the LULC data typically defines the type of source data and methodology, with satellite imagery being selected for large landscapes (state-wide, national data products) and repeatability (environmental monitoring and change analysis). The coarse spatial scale and lack of refined land-use categories are typical drawbacks to satellite-based land-use classifications. Aerial photography is typically selected for smaller landscapes (watershed-basin scale), for greater definition of the land-use categories, and for increased spatial resolution. Disadvantages of using photography include time-consuming digitization, high costs for imagery collection, and lack of seasonal data. Recently, the availability of high-resolution satellite imagery has generated a new category of LULC data product. These new datasets have similar strengths to the aerial-photo-based LULC in that they possess the potential for refined definition of land-use categories and increased spatial resolution but also have the benefit of satellite-based classifications, such as repeatability for change analysis. LULC classification based on high-resolution satellite imagery is still in the early stages of development but merits greater attention because environmental-monitoring and landscape-modeling programs rely heavily on LULC data. This publication summarizes land-use and land-cover mapping activities for Alabama and Mississippi coastal areas within the U.S. Geological Survey (USGS) Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazard Susceptibility Project boundaries. Existing LULC datasets will be described, as well as imagery data sources and ancillary data that may provide ground-truth or satellite training data for a forthcoming land-cover classification. Finally, potential areas for a high-resolution land-cover classification in the Alabama-Mississippi region will be identified.

Open-File Report↗

Distribution, abundance, and breeding activities of the Southwestern Willow Flycatcher at Marine Corps Base Camp Pendleton, California—2021 annual report

Executive Summary The purpose of this report is to provide the Marine Corps with an annual summary of abundance, breeding activity, demography, and habitat use of the endangered Southwestern Willow Flycatcher ( Empidonax traillii extimus ) at Marine Corps Base Camp Pendleton (MCBCP). Surveys for the flycatcher were completed at MCBCP between May 5 and July 31, 2021. All of MCBCP’s historically occupied riparian habitat (core survey area) was surveyed for flycatchers in 2021. Additionally, one-fifth of the non-historically occupied riparian habitat (non-core survey area C) was surveyed for flycatchers. Twenty-four transient Willow Flycatchers of unknown subspecies were observed on five of the seven drainages surveyed in 2021. No Willow Flycatchers were detected at French or Las Flores Creeks. Transients occurred in a range of habitat types, including mixed willow ( Salix spp.) riparian, riparian scrub, willow-sycamore ( Platanus sp.) dominated or oak ( Quercus spp.) sycamore-dominated riparian, and non-native-dominated riparian habitat. Exotic vegetation, primarily poison hemlock ( Conium maculatum ), was present in most flycatcher locations. The resident population of Southwestern Willow Flycatchers on MCBCP declined 50 percent, from two individuals in 2020 to one individual in 2021. In 2021, the resident Southwestern Willow Flycatcher population on MCBCP consisted of one unpaired female occupying one territory. No males were observed in 2021. The resident flycatcher population was restricted to the Santa Margarita River, and distribution was limited to the Pueblitos breeding area. The resident flycatcher territory was located in mixed willow riparian habitat. Nesting was initiated in late May and continued into late July. Two nesting attempts were documented, neither of which were successful. Infertile eggs likely accounted for both nest failures. No instances of Brown-headed Cowbird ( Molothrus ater ) parasitism were observed. The female flycatcher placed her nests in native sandbar willow ( Salix exigua ) and used the same nest location for both nesting attempts. Of resident birds that were present at MCBCP in 2021, 100 percent were banded in previous years; no unbanded birds were detected. Of the two uniquely banded adult flycatchers (one male, one female) present during the 2020 breeding season, 50 percent (one female) returned to MCBCP in 2021. The banded female returned to the same breeding area and territory she occupied in 2020. Neither of the two nestlings banded in 2020 returned to MCBCP in 2021, and neither were detected off Base. From 2000 to 2021, adult over-winter survival of Southwestern Willow Flycatchers on MCBCP was 60±3 percent (mean±standard error [SE]), and first-year survival was 20±3 percent. A conspecific attraction study that used automatic playback units to broadcast flycatcher vocalizations in order to encourage flycatchers to settle on MCBCP was initiated in 2018 and repeated annually through 2021. The single resident flycatcher (female) detected in 2021 settled close to an automated playback unit.

California↗

Elk monitoring in Mount Rainier and Olympic National Parks: 2008-2017 synthesis report

In 2008, the U.S. Geological Survey (USGS) began collaborating with the National Park Service (NPS)-North Coast and Cascades Network (NCCN), the Muckleshoot Indian Tribe (MIT), Puyallup Tribe of Indians (PTOI), and Washington Department of Fish and Wildlife (WDFW) to develop a standard survey protocol for monitoring long-term changes in the abundance, distribution, and population composition of elk on key summer ranges within Mount Rainier National Park (MORA) and Olympic National Park (OLYM). In MORA, surveys were conducted in two trend count areas (TCAs) that correspond with primary summer ranges used by the North Rainier Herd, which winters outside the park to the North, and the South Rainier Herd, which winters outside the park primarily to the South. In OLYM, we defined five TCAs including an Olympic Core TCA (hereafter, Core TCA) that encompasses summer ranges on the flanks of Mount Olympus, and four TCAs that encompass other primary summer ranges throughout the park. The standard protocol allows for estimating aerial survey detection biases and adjusting raw survey counts to account for elk that were likely present but not seen during surveys. Previously, we developed a suite of aerial-bias-correction models for use in estimating aerial detection biases and adjusting raw counts of elk in MORA based on sighting conditions related to elk group size, vegetation density, lighting conditions, elk movement, as well as combinations of these and other factors. The models were based on independent sighting records of elk groups by front-seat and back-seat observer pairs in a helicopter, including detection records of some radio-collared elk groups. Here, we analyze results of the first 10 years of elk monitoring in MORA (2008-2017) and 8 years in OLYM (2008-2015). In a previous report covering surveys conducted from 2008-2011, data were not sufficient to model detection biases of aerial surveys conducted in OLYM; hence, analyses of elk population trends were based on counts adjusted for detection biases in MORA, whereas trends in OLYM were based on raw, unadjusted counts (Griffin et al. 2013, Jenkins et al. 2015). Our objectives for the current summary were to: (1) incorporate additional data to update aerial-bias-correction models previously developed for use in MORA to include corrections for aerial detection bias in both MORA and OLYM, (2) examine trends in elk abundance, distribution, and population composition estimates for subalpine summer ranges within MORA and OLYM, and (3) estimate effects of seasonal variation and weather on elk abundance and population composition estimates for subalpine summer ranges in both parks.

Washington↗

Environmental Setting and Effects on Water Quality in the Great and Little Miami River Basins, Ohio and Indiana

The Great and Little Miami River Basins drain approximately 7,354 square miles in southwestern Ohio and southeastern Indiana and are included in the more than 50 major river basins and aquifer systems selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Principal streams include the Great and Little Miami Rivers in Ohio and the Whitewater River in Indiana. The Great and Little Miami River Basins are almost entirely within the Till Plains section of the Central Lowland physiographic province and have a humid continental climate, characterized by well-defined summer and winter seasons. With the exception of a few areas near the Ohio River, Pleistocene glacial deposits, which are predominantly till, overlie lower Paleozoic limestone, dolomite, and shale bedrock. The principal aquifer is a complex buried-valley system of sand and gravel aquifers capable of supporting sustained well yields exceeding 1,000 gallons per minute. Designated by the U.S. Environmental Protection Agency as a sole-source aquifer, the Buried-Valley Aquifer System is the principal source of drinking water for 1.6 million people in the basins and is the dominant source of water for southwestern Ohio. Water use in the Great and Little Miami River Basins averaged 745 million gallons per day in 1995. Of this amount, 48 percent was supplied by surface water (including the Ohio River) and 52 percent was supplied by ground water. Land-use and waste-management practices influence the quality of water found in streams and aquifers in the Great and Little Miami River Basins. Land use is approximately 79 percent agriculture, 13 percent urban (residential, industrial, and commercial), and 7 percent forest. An estimated 2.8 million people live in the Great and Little Miami River Basins; major urban areas include Cincinnati and Dayton, Ohio. Fertilizers and pesticides associated with agricultural activity, discharges from municipal and industrial wastewater-treatment and thermoelectric plants, urban runoff, and disposal of solid and hazardous wastes contribute contaminants to surface water and ground water throughout the study area. Surface water and ground water in the Great and Little Miami River Basins are classified as very hard, calcium-magnesiumbicarbonate waters. The major-ion composition and hardness of surface water and ground water reflect extensive contact with the carbonate-rich soils, glacial sediments, and limestone or dolomite bedrock. Dieldrin, endrin, endosulfan II, and lindane are the most commonly reported organochlorine pesticides in streams draining the Great and Little Miami River Basins. Peak concentrations of the herbicides atrazine and metolachlor in streams commonly are associated with post-application runoff events. Nitrate concentrations in surface water average 3 to 4 mg/L (milligrams per liter) in the larger streams and also show strong seasonal variations related to application periods and runoff events. Ambient iron concentrations in ground water pumped from aquifers in the Great and Little Miami River Basins often exceed the U.S. Environmental Protection Agency Secondary Maximum Contaminant Level (300 micrograms per liter). Chloride concentrations are below aesthetic drinking-water guidelines (250 mg/L), except in ground water pumped from low-yielding Ordovician shale; chloride concentrations in sodium-chloriderich ground water pumped from the shale bedrock can exceed 1,000 mg/L. Some of the highest average nitrate concentrations in ground water in Ohio and Indiana are found in wells completed in the buried-valley aquifer; these concentrations typically are found in those parts of the sand and gravel aquifer that are not overlain by clay-rich till. Atrazine was the most commonly detected herbicide in private wells. Concentrations of volatile organic compounds in ground water generally were below Federal drinking-water standards, except near areas of known or suspected contamination. Evaluation of fish and macroinvertebrate community performance in streams and rivers draining the Great and Little Miami River Basins indicates that most streams meet basic aquatic-life-use criteria set by the Ohio Environmental Protection Agency for warmwater habitat. Stream reaches whose biological community performance meet aquatic-lifeuse criteria defined for exceptional warmwater habitat are found in Twin Creek, the Upper Great Miami River, the Little Miami River, and the Whitewater River Basins. Other streams have exhibited significant improvements in biological community performance (and water quality)'that are attributed primarily to reduced pollutant loadings from wastewater-treatment plants upgraded since 1972. Four hydrogeomorphic regions were delineated in the Great and Little Miami River Basins based on distinct and relatively homogeneous natural characteristics. Primary features used to delineate the hydrogeomorphic regions include bedrock geology, surficial geology, physiography, hydrology, soil types, and vegetation. These four regions Till Plains, Drift Plains/Unglaciated, Interlobate, and Fluvial are used in the Great and Little Miami River Basins study to assess the influence of natural features of the environmental setting on surface- and ground-water quality.

Indiana, Ohio↗

Surface-water quality at fixed sites in the Western Lake Michigan Drainages, Wisconsin and Michigan, and the effects of natural and human factors, 1993-95

Streamwater samples were collected from April 1993 through July 1995 at 11 fixed sites in the Western Lake Michigan Drainages Study Unit of the U.S. Geological Survey's National Water-Quality Assessment Program. Water samples were collected monthly at all Fixed Sites, and an additional two to four samples were collected each year during periods of high flow. Streamflow was monitored continuously at the Fixed Sites for the duration of the study period. This report describes field techniques used to collect the water samples, and the analytical methods used for laboratory analyses, statistical analyses of the data, and an attempt to determine the effect of natural and anthropogenic factors on concentrations of nutrients and selected major ions and suspended solids. Locations of eight of the Fixed Sites were selected to represent areas with unique combinations of land use/land cover, surficial deposits, and bedrock geology and are referred to as 'indicator sites.' The remaining three sites were located near the mouths of major rivers and are referred to as 'integrator sites.' The integrator sites represent a large part of the total flow from the Study Unit to Green Bay and western Lake Michigan, and drain various combinations of land use, bedrock, and surficial deposits. These data indicate that land use and surficial deposits may be the primary factors affecting nitrate and total phosphorus concentrations in this Study Unit. Median concentrations of nitrate at the forested sites were less than the National Median Concentration (NMC), and those at urban fixed sites were similar to the NMC. Median nitrate concentrations at the Tomorrow River, North Branch Milwaukee River, and Duck Creek agricultural indicator sites were twice the NMC, but median concentrations at the remaining agricultural indicator sites were similar to the NMC. Nitrate concentrations at one agricultural indicator site exceeded the U. S. Environmental Protection Agency (USEPA) maximum contaminant level in three run-off samples in the growing seasons of 1994 and 1995. Median concentrations of total phosphorus at the forested indicator sites were below the NMC. Tomorrow River was the only agricultural indicator site where the median total-phosphorus concentration was less than the NMC; median concentrations at the remaining agricultural Fixed Sites were similar to the NMC and exceeded 0.1 mg/L, the USEPA suggested total-phosphorus concentration in flowing water. The USEPA recommends that total-phosphorus concentration not exceed this limit to discourage excessive aquatic plant growth in flowing waters. Median total-phosphorus concentration at the urban indicator site was less than the urban NMC. Median concentrations for both nitrate and total phosphorus at the mouth of the Fox River and the Milwaukee River integrator sites were similar to the NMC for the dominant land use, agriculture, within their basins, and were lower than that at the Menominee River integrator site with a dominant forest land use. During this study, potassium concentrations were generally highest in areas of clay-dominated surficial deposits, silica was generally highest in areas of sandy surficial deposits, iron generally highest in areas of igneous/metamorphic bedrock, and calcium generally highest in areas of carbonate bedrock. The highest median fluoride concentration occurred at an urban site that receives treated water.

Michigan, Wisconsin↗

To burn or not to burn Oriental bittersweet: A fire manager's conundrum

Oriental bittersweet ( Celastrus orbiculatus ) is an introduced liana (woody vine) that has invaded much of the Eastern United States and is expanding west into the Great Plains. In forests, it can girdle and damage canopy trees. At Indiana Dunes, we have discovered that it is invading non-forested dune habitats as well. Anecdotal evidence suggests that fire might facilitate its spread, but the relationship between fire and this aggressive invader is poorly understood. We investigated four areas important to fire management of oriental bittersweet, each of which we will briefly summarize here. 1) What fire temperatures cause seed mortality? For seeds, temperatures above 140°C for three minute or more kills the embryo. For fruits, temperatures above 140°C kill the seeds inside after five minutes. While oriental bittersweet fruits ripen in October and November, the seeds are not dispersed until later in the early to mid December. Thus fall fires will not have any impact on the seeds unless perhaps if they are near the ground. Late winter and early spring fires are likely to kill seeds in the top litter at least. Thus spring fire can reduce the pool of seeds available to germinate. 2) Does fire modify habitat susceptibility to invasion? We found that post fire environment had no effect on the emergence and survival of oriental bittersweet, except that the tallest plants, after two years since sowing, were in the control plots. Highest establishment occurred in mesic silt loam prairie and oak forest. Survival was greatest in mesic prairie and greatest biomass occurred in the oak forest. 3) Both fire and cutting can cause oriental bittersweet to resprout and root sucker. Does the resprouting response differ between these two treatments and can a combination of cutting and pre- or post-fire treatment facilitate its removal? Cutting sometimes increased stem density between one and two times, but burning increased density by two or more times depending on the maximum fire temperature and duration. Cutting in early July reduced total nonstructural carbohydrates by 50% from normal July levels and 75% below dormant season levels. Thus burning established populations will only serve to increase their local density. 4) How does oriental bittersweet abundance vary with fire regime and can we predict the abundance of this species in a fire mosaic landscape based on fire return interval and time since last fire? At the landscape scale, we can predict the presence and abundance of oriental bittersweet, but have less success predicting its cover and distribution. The presence of oriental bittersweet was significantly negatively influenced by canopy closure, burn frequency, and distance to roads and railroads. In plots where C. orbiculatus was present, abundance was significantly greater in plots with low to moderate burn frequency, and marginally (p = 0.056) lower in plots with greater canopy cover. Both cover and distribution of C. orbiculatus was not significantly affected by the measured variables. These results suggest the frequent fire may be effective in preventing the establishment of oriental bittersweet.

Indiana↗

Water-the Nation's Fundamental Climate Issue A White Paper on the U.S. Geological Survey Role and Capabilities

Of all the potential threats posed by climatic variability and change, those associated with water resources are arguably the most consequential for both society and the environment (Waggoner, 1990). Climatic effects on agriculture, aquatic ecosystems, energy, and industry are strongly influenced by climatic effects on water. Thus, understanding changes in the distribution, quantity and quality of, and demand for water in response to climate variability and change is essential to planning for and adapting to future climatic conditions. A central role of the U.S. Geological Survey (USGS) with respect to climate is to document environmental changes currently underway and to develop improved capabilities to predict future changes. Indeed, a centerpiece of the USGS role is a new Climate Effects Network of monitoring sites. Measuring the climatic effects on water is an essential component of such a network (along with corresponding effects on terrestrial ecosystems). The USGS needs to be unambiguous in communicating with its customers and stakeholders, and with officials at the Department of the Interior, that although modeling future impacts of climate change is important, there is no more critical role for the USGS in climate change science than that of measuring and describing the changes that are currently underway. One of the best statements of that mission comes from a short paper by Ralph Keeling (2008) that describes the inspiration and the challenges faced by David Keeling in operating the all-important Mauna Loa Observatory over a period of more than four decades. Ralph Keeling stated: 'The only way to figure out what is happening to our planet is to measure it, and this means tracking changes decade after decade and poring over the records.' There are three key ideas that are important to the USGS in the above-mentioned sentence. First, to understand what is happening requires measurement. While models are a tool for learning and testing our understanding, they are not a substitute for observations. The second key idea is that measurement needs to be done over a period of many decades. When viewing hydrologic records over time scales of a few years to a few decades, trends commonly appear. However, when viewed in the context of many decades to centuries, these short-term trends are recognized as being part of much longer term oscillations. Thus, while we might want to initiate monitoring of important aspects of our natural resources, the data that will prove to be most useful in the next few years are those records that already have long-term continuity. USGS streamflow and groundwater level data are excellent examples of such long-term records. These measured data span many decades, follow standard protocols for collection and quality assurance, and are stored in a database that provides access to the full period of record. The third point from the Keeling quote relates to the notion of ?poring over the records.? Important trends will not generally jump off the computer screen at us. Thoughtful analyses are required to get past a number of important but confounding influences in the record, such as the role of seasonal variation, changes in water management, or influences of quasi-periodic phenomena, such as El Ni?o-Southern Oscillation (ENSO) or the Pacific Decadal Oscillation (PDO). No organization is better situated to pore over the records than the USGS because USGS scientists know the data, quality-assure the data, understand the factors that influence the data, and have the ancillary information on the watersheds within which the data are collected. To fulfill the USGS role in understanding climatic variability and change, we need to continually improve and strengthen two of our key capabilities: (1) preserving continuity of long-term water data collection and (2) analyzing and interpreting water data to determine how the Nation's water resources are changing. Understanding change in water resources

Circular↗

Factors affecting food chain transfer of mercury in the vicinity of the Nyanza site, Sudbury River, Massachusetts

The influence of the Nyanza Chemical Waste Dump Superfund Site on the Sudbury River, Massachusetts, was assessed by analysis of sediment, fish prey organisms, and predator fish from four locations in the river system. Whitehall Reservoir is an impoundment upstream of the site, and Reservoir #2 is an impoundment downstream of the site. Cedar Street is a flowing reach upstream of the site, and Sherman Bridge is a flowing reach downstream of the site. Collections of material for analysis were made three times, in May, July, and October. Sediment was analyzed for acid-volatile sulfide (AVS), simultaneously-extracted (SEM) metals (As, Cd, Cr, Hg, Pb, Sb, Zn), and total recoverable Hg. The dominant predatory fish species collected at all sites, largemouth bass (Micropterus salmoides), was analyzed for the same suite of metals as sediment. Analysis of stomach contents of bass identified small fish (yellow perch Perca flavescens, bluegill Lepomis macrochirus, and pumpkinseed Lepomis gibbosus), crayfish, and dragonfly larvae as the dominant prey organisms. Samples of the prey were collected from the same locations and at the same times as predator fish, and were analyzed for total and methyl mercury. Results of AVS and SEM analyses indicated that sediments were not toxic to aquatic invertebrates at any site. The SEM concentrations of As, Cd, and Cr were significantly higher at Reservoir #2 than at the reference sites, and SEM As and Cd were significantly higher at Sherman Bridge than at Cedar St. Sediment total Hg was elevated only at Reservoir #2. Hg was higher at site-influenced locations in all fish species except brown bullhead (Ameiurus nebulosus). Cd was higher in bluegill, black crappie (Pomoxis nigromaculatus), and brown bullhead, and Cr was higher in largemouth bass fillet samples but not in whole-body samples. There were no seasonal differences in sediment or prey organism metals, but some metals in some fish species did vary over time in an inconsistent manner. Predator fish Hg concentration was significantly linearly related to weighted prey organism methyl Hg concentration. Largemouth bass Hg was significantly lower at Reservoir #2 in our study than in previous investigations in 1989 and 1990. High concentrations of inorganic Hg remain in river sediment as a result of operation of the Nyanza site, and fish Hg concentrations in river reaches downstream of the site are elevated compared to upstream reference sites. However, the differences are relatively small and Hg concentrations in largemouth bass from the site-influenced locations are no higher than those from some other, nearby uncontaminated sites. We hypothesize that this results from burial of contaminated sediment with cleaner material, which reduces bioavailability of contaminants and possibly reduces methylation of mercury.

Environmental Monitoring and Assessment↗

Groundwater discharge by evapotranspiration, Dixie Valley, west-central Nevada, March 2009-September 2011

With increasing population growth and land-use change, urban communities in the desert Southwest are progressively looking toward remote basins to supplement existing water supplies. Pending applications by Churchill County for groundwater appropriations from Dixie Valley, Nevada, a primarily undeveloped basin east of the Carson Desert, have prompted a reevaluation of the quantity of naturally discharging groundwater. The objective of this study was to develop a revised, independent estimate of groundwater discharge by evapotranspiration (ET g ) from Dixie Valley using a combination of eddy-covariance evapotranspiration (ET) measurements and multispectral satellite imagery. Mean annual ET g was estimated during water years 2010 and 2011 at four eddy-covariance sites. Two sites were in phreatophytic shrubland dominated by greasewood, and two sites were on a playa. Estimates of total ET and ET g were supported with vegetation cover mapping, soil physics considerations, water‑level measurements from wells, and isotopic water sourcing analyses to allow partitioning of ET g into evaporation and transpiration components. Site-based ET g estimates were scaled to the basin level by combining remotely sensed imagery with field reconnaissance. Enhanced vegetation index and brightness temperature data were compared with mapped vegetation cover to partition Dixie Valley into five discharging ET units and compute basin-scale ET g . Evapotranspiration units were defined within a delineated groundwater discharge area and were partitioned as (1) playa lake, (2) playa, (3) sparse shrubland, (4) moderate-to-dense shrubland, and (5) grassland. Groundwater ET is influenced primarily by phreatophytic vegetative cover, salinity of soil and groundwater within the playa, depth to groundwater, solar radiation, and air temperature. The annual groundwater contribution to site‑scale ET ranged from 24 to 61 percent of total ET at vegetated sites and 4 to 15 percent of total ET at playa sites. Mean annual ET g from vegetated sites ranged from 53 millimeters (mm) (0.17 foot [ft], 7.3 percent vegetative cover) to 225 mm (0.74 ft, 24.8 percent vegetative cover). Cumulative liquid‑water fluxes in the unsaturated zone indicate that ET g at vegetated sites was influenced primarily by plant transpiration. Binary mixing analyses of oxygen-18 isotopes in groundwater and shallow soil water indicate that plants predominantly use groundwater throughout the year. Groundwater fractions in greasewood stem water varied seasonally and ranged from 0.63 to 1.0. Mean annual playa ET g ranged from about 11 mm (0.04 ft) at the inner playa site (near-surface volumetric water content of 37–53 percent) to about 20 mm (0.07 ft) at the outer playa site located within 2 kilometers of the playa edge (near-surface volumetric water content of 25–38 percent), but playa ET g estimates were within the probable error (plus or minus [±] 20–23 mm; 0.06–0.08 ft). Varying playa ET g was influenced predominantly by salinity rather than depth to groundwater. Osmotic resistance and physical impediments to ET (such as surface salt crusts and salt precipitate in the soil pore space) increased with increasing salinity toward the playa center, whereas vapor pressure decreased. Mean annual basin-scale ET g totaled about 28 million cubic meters (Mm 3 ) (23,000 acre-feet [acre-ft]), and represents the sum of ET g from all ET units. Annual groundwater ET from vegetated areas totaled about 26 Mm 3 (21,000 acre-ft), and was dominated by the moderate-to-dense shrubland ET unit (54 percent), followed by sparse shrubland (37 percent) and grassland (9 percent) ET units. Senesced grasses observed in the northern most areas of the moderate-to-dense ET unit likely confounded the vegetation index and led to an overestimate of ET g for this ET unit. Therefore, mean annual ET g for moderate-to-dense shrubland presented here is likely an upper bound. Annual groundwater ET from the playa ET unit was 2.2 Mm 3 (1,800 acre-ft), whereas groundwater ET from the playa lake ET unit was 0–0.1 Mm 3 (0–100 acre-ft). Oxygen-18 and deuterium data indicate discharge from the playa center predominantly represents removal of local precipitation-derived recharge. The playa lake estimate, therefore, is considered an upper bound. Mean annual ET g estimates for Dixie Valley are assumed to represent the pre‑development, long-term ET g rates within the study area.

Nevada↗

Water resources on and near the Nottawaseppi Huron band of Potawatomi indian tribal lands, Calhoun County, Michigan, 2000-03

The Nottawaseppi Huron Band of Potawatomi Indians in Calhoun County, Michigan is concerned about the water quality and quantity of streams in and around tribal lands and of shallow ground water. The tribe wanted to establish a database that included streamflow, stage, and water quality of local streams and quality of ground water from wells belonging to the tribe and its members. Concerned about the effects of long-term agricultural activity and increasing numbers of singlefamily dwellings being constructed within the watershed both on and off the reservation, the tribe wants to develop a water-resources management plan. U.S. Geological Survey (USGS) measured streamflow and installed staff gages tied into local datum on three tributaries of the St. Joseph River that cross tribal lands. Water-quality samples were collected from the sites under a variety of flow regimes from spring to fall during 2000-03. Stage-streamflow rating curves were constructed for Pine Creek and Athens & Indian Creek Drain after a number of discharge measurements were made and a thorough basin analysis was completed. Daily streamflow for Pine Creek near Athens was estimated for the period from May 2000 through September 2003. USGS collected 12 water samples at Pine Creek near Athens, Athens & Indian Creek Drain, and an unnamed tributary to Pine Creek during October 2000 through September 2003. Physical properties were measured, and the streams were sampled for major ions, nutrients, trace elements, caffeine, and herbicides/pesticides and their breakdown products (degradates). The tribe also measured physical properties weekly at the three sites during each growing season for the study period. Surface water at the three sites can be classified as hard, with calcium carbonate concentrations exceeding 180 milligrams per liter (mg/L). Concentrations of calcium, magnesium, chloride, and dissolved solids are typical of the area. There were 68 detections of 17 pesticides, degradates, and caffeine. Atrazine and metolachlor were detected in all samples, and the atrazine degradate deethylatrazine was detected in all samples from Pine Creek and Athens & Indian Creek Drain. Another atrazine degradate (2-hydroxy-atrazine, or OIET) was detected five of the six times that it was included in the analyses. A single sample collected from Athens & Indian Creek Drain in May 2001 had relatively higher concentrations of acetochlor, atrazine, CIAT (deethylatrazine), and diuron than the other sampling sites did during the study. Analysis for various species of mercury was completed on samples collected at Pine Creek and Athens & Indian Creek Drain in July 2003, and results were similar to those typical of unimpaired streams in the Midwest. None of the surface-water sites had major ion, nutrient, or trace-element concentrations that exceeded Michigan Department of Environmental Quality standards for nonpotable surface water. USGS also collected 11 ground-water samples from 7 wells on or adjacent to the traditional reservation in 2003. Two wells were sampled twice, and a single well was sampled three times, in order to document any chemical changes that might have occurred as a result of aquifer recharge, which most typically occurs in late winter to spring in the southern Lower Peninsula of Michigan. Samples were analyzed for 184 pesticides and degradates and caffeine. There were five detections of four pesticides or degradates, but none of the detected chemicals are included in current U.S. Environmental Protection Agency drinking-water standards. The remaining 181 analytes were below laboratory reporting limits.

Michigan↗

A Precipitation-Runoff Model for the Blackstone River Basin, Massachusetts and Rhode Island

A Hydrological Simulation Program-FORTRAN (HSPF) precipitation-runoff model of the Blackstone River Basin was developed and calibrated to study the effects of changing land- and water-use patterns on water resources. The 474.5 mi2 Blackstone River Basin in southeastern Massachusetts and northern Rhode Island is experiencing rapid population and commercial growth throughout much of its area. This growth and the corresponding changes in land-use patterns are increasing stress on water resources and raising concerns about the future availability of water to meet residential and commercial needs. Increased withdrawals and wastewater-return flows also could adversely affect aquatic habitat, water quality, and the recreational value of the streams in the basin. The Blackstone River Basin was represented by 19 hydrologic response units (HRUs): 17 types of pervious areas (PERLNDs) established from combinations of surficial geology, land-use categories, and the distribution of public water and public sewer systems, and two types of impervious areas (IMPLNDs). Wetlands were combined with open water and simulated as stream reaches that receive runoff from surrounding pervious and impervious areas. This approach was taken to achieve greater flexibility in calibrating evapotranspiration losses from wetlands during the growing season. The basin was segmented into 50 reaches (RCHRES) to represent junctions at tributaries, major lakes and reservoirs, and drainage areas to streamflow-gaging stations. Climatological, streamflow, water-withdrawal, and wastewater-return data were collected during the study to develop the HSPF model. Climatological data collected at Worcester Regional Airport in Worcester, Massachusetts and T.F. Green Airport in Warwick, Rhode Island, were used for model calibration. A total of 15 streamflow-gaging stations were used in the calibration. Streamflow was measured at eight continuous-record streamflow-gaging stations that are part of the U.S. Geological Survey cooperative streamflow-gaging network, and at seven partial-record stations installed in 2004 for this study. Because the model-calibration period preceded data collection at the partial-record stations, a continuous streamflow record was estimated at these stations by correlation with flows at nearby continuous-record stations to provide additional streamflow data for model calibration. Water-use information was compiled for 1996-2001 and included municipal and commercial/industrial withdrawals, private residential withdrawals, golf-course withdrawals, municipal wastewater-return flows, and on-site septic effluent return flows. Streamflow depletion was computed for all time-varying ground-water withdrawals prior to simulation. Water-use data were included in the model to represent the net effect of water use on simulated hydrographs. Consequently, the calibrated values of the hydrologic parameters better represent the hydrologic response of the basin to precipitation. The model was calibrated for 1997-2001 to coincide with the land-use and water-use data compiled for the study. Four long-term stations (Nipmuc River near Harrisville, Rhode Island; Quinsigamond River at North Grafton, Massachusetts; Branch River at Forestdale, Rhode Island; and Blackstone River at Woonsocket, Rhode Island) that monitor flow at 3.3, 5.4, 19, and 88 percent of the total basin area, respectively, provided the primary model-calibration points. Hydrographs, scatter plots, and flow-duration curves of observed and simulated discharges, along with various model-fit statistics, indicated that the model performed well over a range of hydrologic conditions. For example, the total runoff volume for the calibration period simulated at the Nipmuc River near Harrisville, Rhode Island; Quinsigamond River at North Grafton, Massachusetts; Branch River at Forestdale, Rhode Island; and Blackstone River at Woonsocket, Rhode Island streamflow-gaging stations differed from the observed runoff v

Scientific Investigations Report↗

Relations of biological indicators to nutrient data for lakes and streams in Pennsylvania and West Virginia, 1990-98

The Clean Water Action Plan of 1998 provides a blueprint for federal agencies to work with states, tribes, and other stakeholders to protect and restore the Nation's water resources. The plan includes an initiative that addresses the nutrient-enrichment problem of lakes and streams across the United States. The U.S. Environmental Protection Agency (USEPA) is working to set nutrient criteria by nationwide nutrient ecoregions that are an aggregation of the Omernik level III ecoregions. Because low levels of nutrients are necessary for healthy streams and elevated concentrations can cause algal blooms that deplete available oxygen and kill off aquatic organisms, criteria levels are to be set, in part, using the relation between chlorophyll a and concentrations of total nitrogen and total phosphorus. Data from Pennsylvania and West Virginia, collected between 1990 and 1998, were analyzed for relations between chlorophyll a , nutrients, and other explanatory variables. Both phytoplankton and periphyton chlorophyll a concentrations from lakes and streams were analyzed separately within each of the USEPA nutrient ecoregions located within the boundaries of the two states. These four nutrient ecoregions are VII (Mostly Glaciated Dairy), VIII (Nutrient Poor, Largely Glaciated Upper Midwest and Northeast), IX (Southeastern Temperate Forested Plains and Hills), and XI (Central and Eastern Forested Uplands). Phytoplankton chlorophyll a concentrations in lakes were related to total nitrogen, total phosphorus, Secchi depth, concentration of dissolved oxygen, pH, water temperature, and specific conductivity. In nutrient ecoregion VII, nutrients were not significant predictors of chlorophyll a concentrations. Total nitrogen, Secchi depth, and pH were significantly related to phytoplankton chlorophyll a concentrations in nutrient ecoregion IX. Lake periphyton chlorophyll a concentrations from nutrient ecoregion XI were related to total phosphorus rather than total nitrogen, Secchi depth, and pH. In all cases, Secchi depth was inversely related to the chlorophyll a concentrations in a lake. Nutrient ecoregion VIII had too few samples for any type of analysis. Streams within the different nutrient ecoregions had many variables that were significantly related to periphyton chlorophyll a concentrations. These variables consisted of total nitrogen, total phosphorus, drainage area, percent forest cover, several macroinvertebrate indices, pH, basin slope, total residue, total suspended solids, and water temperature. Nutrients were not significantly related to periphyton chlorophyll a in streams within nutrient ecoregions VII or IX but were in nutrient ecoregion XI. Drainage area, percent forest cover, and several invertebrate indices were significant variables in nutrient ecoregion VII. Percent forest cover and several invertebrate indices had a negative relation with chlorophyll a concentrations in these streams. Percent forest cover and basin slope had a negative effect on periphyton in nutrient ecoregion IX streams. Light availability was more critical to periphyton growth in streams than nutrients. Ecoregion XI had enough samples to do seasonal analyses. Summer-season periphyton chlorophyll a concentrations in nutrient ecoregion XI streams were positively related to total phosphorus and drainage area but negatively related to percent forest cover. Summer-season phytoplankton in streams was related to different variables within the same nutrient ecoregion. Both total nitrogen and total phosphorus were positively related with chlorophyll a concentrations as well as basin slope, total residue, and total suspended solids but negatively related to pH. The winter stream phytoplankton chlorophyll a concentrations were related to water temperature only.

Water-Resources Investigations Report↗

Limnology of Blue Mesa, Morrow Point, and Crystal Reservoirs, Curecanti National Recreation area, during 1999, and a 25-year retrospective of nutrient conditions in Blue Mesa Reservoir, Colorado

The U.S. Geological Survey and the National Park Service conducted a water-quality investigation in Curecanti National Recreation Area in Colorado from April through December 1999. Current (as of 1999) limnological characteristics, including nutrients, phytoplankton, chlorophyll-a, trophic status, and the water quality of stream inflows and reservoir outflows, of Blue Mesa, Morrow Point, and Crystal Reservoirs were assessed, and a 25-year retrospective of nutrient conditions in Blue Mesa Reservoir was conducted. The three reservoirs are in a series on the Gunnison River, with an upstream to downstream order of Blue Mesa, Morrow Point, and Crystal Reservoirs. Physical properties and water-quality samples were collected four times during 1999 from reservoir, inflow, and outflow sites in and around the recreation area. Samples were analyzed for nutrients, phytoplankton and chlorophyll-a (reservoir sites only), and suspended sediment (stream inflows only). Nutrient concentrations in the reservoirs were low; median total nitrogen and phosphorus concentrations were less than 0.4 and 0.06 milligram per liter, respectively. During water-column stratification, samples collected at depth had higher nutrient concentrations than photic-zone samples. Phytoplankton community and density were affected by water temperature, nutrients, and water residence time. Diatoms were the dominant phytoplankton throughout the year in Morrow Point and Crystal Reservoirs and during spring and early winter in Blue Mesa Reservoir. Blue-green algae were dominant in Blue Mesa Reservoir during summer and fall. Phytoplankton density was highest in Blue Mesa Reservoir and lowest in Crystal Reservoir. Longer residence times and warmer temperatures in Blue Mesa Reservoir were favorable for phytoplankton growth and development. Shorter residence times and cooler temperatures in the downstream reservoirs probably limited phytoplankton growth and development. Median chlorophyll-a concentrations were higher in Blue Mesa Reservoir than Morrow Point or Crystal Reservoirs. Blue Mesa Reservoir was mesotrophic in upstream areas and oligotrophic downstream. Both Morrow Point and Crystal Reservoirs were oligotrophic. Trophic-state index values were determined for total phosphorus, chlorophyll-a, and Secchi depth for each reservoir by the Carlson method; all values ranged between 29 and 55. Only the upstream areas in Blue Mesa Reservoir had total phosphorus and chlorophyll-a indices above 50, reflecting mesotrophic conditions. Nutrient inflows to Blue Mesa Reservoir, which were derived primarily from the Gunnison River, varied on a seasonal basis, whereas nutrient inflows to Morrow Point and Crystal Reservoirs, which were derived primarily from deep water releases from the respective upstream reservoir, were steady throughout the sampling period. Total phosphorus concentrations were elevated in many stream inflows. A comparison of current (as of 1999) and historical nutrient, chlorophyll-a, and trophic conditions in Blue Mesa Reservoir and its tributaries indicated that the trophic status in Blue Mesa Reservoir has not changed over the last 25 years, and more recent nutrient enrichment has not occurred.

Water-Resources Investigations Report↗