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At least 1,171 records · Page 65Linked to original sources

Intercontinental convergence of stream fish community traits along geomorphic and hydraulic gradients

Community convergence across biogeographically distinct regions suggests the existence of key, repeated, evolutionary mechanisms relating community characteristics to the environment. However, convergence studies at the community level often involve only qualitative comparisons of the environment and may fail to identify which environmental variables drive community structure. We tested the hypothesis that the biological traits of fish communities on two continents (Europe and North America) are similarly related to environmental conditions. Specifically, from observations of individual fish made at the microhabitat scale (a few square meters) within French streams, we generated habitat preference models linking traits of fish species to local scale hydraulic conditions (Froude number), Using this information, we then predicted how hydraulics and geomorphology at the larger scale of stream reaches (several pool-riffle sequences) should quantitatively influence the trait composition of fish communities. Trait composition for fishes in stream reaches with low Froude number at low flow or high proportion of pools was predicted as nonbenthic, large, fecund, long-lived, nonstreamlined, and weak swimmers. We tested our predictions in contrasting stream reaches in France (n = 11) and Virginia, USA (n = 76), using analyses of covariance to quantify the relative influence of continent vs. physical habitat variables on fish traits. The reach-scale convergence analysis indicated that trait proportions in the communities differed between continents (up to 55% of the variance in each trait was explained by "continent"), partly due to distinct evolutionary histories. However, within continents, trait proportions were comparably related to the hydraulic and geomorphic variables (up to 54% of the variance within continents explained). In particular, a synthetic measure of fish traits in reaches was well explained (50% of its variance) by the Froude number independently of the continent. The effect of physical variables did not differ across continents for most traits, confirming our predictions qualitatively and quantitatively. Therefore, despite phylogenetic and historical differences between continents, fish communities of France and Virginia exhibit convergence in biological traits related to hydraulics and geomorphology. This convergence reflects morphological and behavioral adaptations to physical stress in streams. This study supports the existence of a habitat template for ecological strategies. Some key quantitative variables that define this habitat template can be identified by characterizing how individual organisms use their physical environment, and by using dimensionless physical variables that reveal common energetic properties in different systems. Overall, quantitative tests of community convergence are efficient tools to demonstrate that some community traits are predictable from environmental features.

Virginia↗

Interaction of beaver and elk herbivory reduces standing crop of willow

Populations of beaver and willow have not thrived in riparian environments that are heavily browsed by livestock or ungulates, such as elk. The interaction of beaver and elk herbivory may be an important mechanism underlying beaver and willow declines in this competitive environment. We conducted a field experiment that compared the standing crop of willow three years after simulated beaver cutting on paired plants with and without intense elk browsing (∼85% utilization rate). Simulated beaver cutting with intense elk browsing produced willow that was small (biomass and diameter) and short, with far fewer, but longer, shoots and a higher percentage of dead biomass. In contrast, simulated beaver cutting without elk browsing produced willow that was large, tall, and leafy, with many more, but shorter, shoots (highly branched) and a lower percentage of dead biomass. Total stem biomass after three years was 10 times greater on unbrowsed plants than on browsed plants. Unbrowsed plants recovered 84% of their pre-cut biomass after only two growing seasons, whereas browsed plants recovered only 6%. Thus, the interaction of beaver cutting and elk browsing strongly suppressed the standing crop of willow. We predict that a lack of willow suitable as winter food for beaver can cause beaver populations to decline, creating a feedback mechanism that reduces beaver and willow populations. Thus, intense herbivory by ungulates or livestock can disrupt beaver–willow mutualisms that naturally occur in less competitive environments.

Ecological Applications↗

Comparing marine and terrestrial ecosystems: Implications for the design of coastal marine reserves

Concepts and theory for the design and application of terrestrial reserves is based on our understanding of environmental, ecological, and evolutionary processes responsible for biological diversity and sustainability of terrestrial ecosystems and how humans have influenced these processes. How well this terrestrial -based theory can be applied toward the design and application of reserves in the coastal marine environment depends, in part, on the degree of similarity between these systems. Several marked differences in ecological and evolutionary processes exist between marine and terrestrial ecosystems as ramifications of fundamental differences in their physical environments (i.e., the relative prevalence of air and water) and contemporary patterns of human impacts. Most notably, the great extent and rate of dispersal of nutrients, materials, holoplanktonic organisms, and reproductive propagules of benthic organisms expand scales of connectivity among near-shore communities and ecosystems . Consequently, the "openness" of marine populations, communities, and ecosystems probably has marked influences on their spatial, genetic, and trophic structures and dynamics in ways experienced by only some terrestrial species. Such differences appear to be particularly significant for the kinds of organisms most exploited and targeted for protection in coastal marine ecosystems (fishes and macroinvertebrates). These and other differences imply some unique design criteria and application of reserves in the marine environment. In explaining the implications of these differences for marine reserve design and application, we identify many of the environmental and ecological processes and design criteria necessary for consideration in the development of the analytical approaches developed elsewhere in this Special Issue.

Ecological Applications↗

Determining origin in a migratory marine vertebrate: a novel method to integrate stable isotopes and satellite tracking

Stable isotope analysis is a useful tool to track animal movements in both terrestrial and marine environments. These intrinsic markers are assimilated through the diet and may exhibit spatial gradients as a result of biogeochemical processes at the base of the food web. In the marine environment, maps to predict the spatial distribution of stable isotopes are limited, and thus determining geographic origin has been reliant upon integrating satellite telemetry and stable isotope data. Migratory sea turtles regularly move between foraging and reproductive areas. Whereas most nesting populations can be easily accessed and regularly monitored, little is known about the demographic trends in foraging populations. The purpose of the present study was to examine migration patterns of loggerhead nesting aggregations in the Gulf of Mexico (GoM), where sea turtles have been historically understudied. Two methods of geographic assignment using stable isotope values in known-origin samples from satellite telemetry were compared: 1) a nominal approach through discriminant analysis and 2) a novel continuous-surface approach using bivariate carbon and nitrogen isoscapes (isotopic landscapes) developed for this study. Tissue samples for stable isotope analysis were obtained from 60 satellite-tracked individuals at five nesting beaches within the GoM. Both methodological approaches for assignment resulted in high accuracy of foraging area determination, though each has advantages and disadvantages. The nominal approach is more appropriate when defined boundaries are necessary, but up to 42% of the individuals could not be considered in this approach. All individuals can be included in the continuous-surface approach, and individual results can be aggregated to identify geographic hotspots of foraging area use, though the accuracy rate was lower than nominal assignment. The methodological validation provides a foundation for future sea turtle studies in the region to inexpensively determine geographic origin for large numbers of untracked individuals. Regular monitoring of sea turtle nesting aggregations with stable isotope sampling can be used to fill critical data gaps regarding habitat use and migration patterns. Probabilistic assignment to origin with isoscapes has not been previously used in the marine environment, but the methods presented here could also be applied to other migratory marine species.

Ecological Applications↗

Changing restoration rules: exotic bivalves interact with residence time and depth to control phytoplankton productivity

Non-native species are a prevalent ecosystem stressor that can interact with other stressors to confound resource management and restoration. We examine how interactions between physical habitat attributes and a particular category of non-native species (invasive bivalves) influence primary production in aquatic ecosystems. Using mathematical models, we show how intuitive relationships between phytoplankton productivity and controllable physical factors (water depth, hydraulic transport time) that hold in the absence of bivalves can be complicated—and even reversed—by rapid bivalve grazing. In light-limited environments without bivalves, shallow, hydrodynamically “slow” habitats should generally have greater phytoplankton biomass and productivity than deeper, “faster” habitats. But shallower, slower environments can be less productive than deeper, faster ones if benthic grazing is strong. Moreover, shallower and slower waters exhibit a particularly broad range of possible productivity outcomes that can depend on whether bivalves are present. Since it is difficult to predict the response of non-native bivalves to habitat restoration, outcomes for new shallow, slow environments can be highly uncertain. Habitat depth and transport time should therefore not be used as indicators of phytoplankton biomass and production where bivalve colonization is possible. This study provides for ecosystem management a particular example of a broad lesson: abiotic ecosystem stressors should be managed with explicit consideration of interactions with other major (including biotic) stressors. We discuss the applicability and management implications of our models and results for a range of aquatic system types, with a case study focused on the Sacramento-San Joaquin Delta (California, USA). Simple mathematical models like those used here can illuminate interactions between ecosystem stressors and provide process-based guidance for resource managers as they develop strategies to augment valued populations, restore habitats, and manipulate ecosystem functions.

Ecosphere↗

One Health: A perspective from wildlife and environmental health sectors

Loss of biodiversity, habitat fragmentation and pollution, and subsequent degradation of natural environments threaten the range of ecosystem services that support all life on this planet. These changes, among others, are also driving the emergence of infectious diseases, with negative health outcomes for humans, animals, and our shared environment. Historically, interventions aimed at human and agricultural health issues did not always integrate wildlife or environmental health as part of the solution, which has resulted in unintended consequences. One Health recognises the interdependence of humans, animals and their shared environment, and provides a conceptual framework for developing interventions that optimise outcomes for human, animal and environmental health. However, there is a need to clearly articulate the core values, goals, and objectives of One Health for all relevant sectors in order to maximise synergies for communication, coordination, collaboration, and, ultimately, for joint actions on disease control and prevention. Application of systems and harm reduction approaches, focusing on the socio-economic and environmental determinants of health, and ensuring good governance and effective leadership will also maximise the opportunities to develop ‘win-win-win’ solutions to global health and environmental challenges. These solutions would help propel One Health forward to reach its full potential and truly optimise health outcomes for all.

Scientific and Technical Review↗

The A and m coefficients in the Bruun/Dean equilibrium profile equation seen from the Arctic

The Bruun/Dean relation between water depth and distance from the shore with a constant profile shape factor is widely used to describe shoreface profiles in temperate environments. However, it has been shown that the sediment scale parameter (A) and the profile shape factor (m) are interrelated variables. An analysis of 63 Arctic erosional shoreface profiles shows that both coefficients are highly variable. Relative frequency of the average m value is only 16% by the class width 0.1. No other m value frequency exceeds 21%. Therefore, there is insufficient reason to use average m to characterize Arctic shoreface profile shape. The shape of each profile has a definite combination of A and m values. Coefficients A and m show a distinct inverse relationship, as in temperate climate. A dependence of m values on coastal sediment grain size is seen, and m decreases with increasing grain size. With constant m = 0.67, parameter A obtains a dimension unit m1/3. But A equals the water depth in meters 1 m from the water edge. This fact and the variability of parameter m testify that the Bruun/Dean equation is essentially an empirical formula. There is no need to give any measurement unit to parameter A. But the International System of Units (SI) has to be used in applying the Bruun/Dean equation for shoreface profiles. A comparison of the shape of Arctic shoreface profiles with those of temperate environments shows surprising similarity. Therefore, the conclusions reached in this Arctic paper seem to apply also to temperate environments.

Journal of Coastal Research↗

Sedimentary facies of iron-formation

The sedimentary iron -formations of Precambrian age in the Lake Superior region can be divided on the basis of the dominant original iron mineral into four principal facies : sulfide, carbonate, oxide, and silicate. As chemical sediments, these rocks reflect certain aspects of the chemistry of the depositional environments. The major control, at least for the sulfide, carbonate, and oxide types, probably was the oxidation potential. The evidence indicates that deposition took place in restricted basins, which were separated from the open sea by thresholds that inhibited free circulation and permitted development of abnormalities in oxidation potential and water composition. The sporadic distribution of metamorphism and of later oxidation permits description of the primary facies on the basis of unoxidized, essentially unmetamorphosed material. The sulfide facies is represented by black slates in which pyrite may make up as much as 40 percent of the rock. The free-carbon content of these rocks typically ranges from 5 to 15 percent, indicating that ultra-stagnant conditions prevailed during deposition. Locally, the pyritic rocks contain layers of iron -rich carbonate. The carbonate facies consists, in its purer form, of interbedded iron -rich carbonate and chert. It is a product of an environment in which oxygen concentration was sufficiently high to destroy most of the organic material but not high enough to permit formation of ferric compounds. The oxide facies is found as two principal types, one characterized by magnetite and the other by hematite. Both minerals appear to be of primary origin. The magnetite-banded rock is one of the dominant lithologies in the region; it consists typically of magnetite interlayered with chert, carbonate, or iron silicate, or combinations of the three. Its mineralogy and association suggest origin under weakly oxidizing to moderately reducing conditions, but the mode of precipitation of magnetite is not clearly understood. The hematite-banded rocks consist of finely crystalline hematite interlayered with chert or jasper. Oolitic structure is common. This facies doubtless accumulated in a strongly oxidizing, probably near-shore, environment similar to that in which younger hema-titic ironstones such as the Clinton oolite were deposited. The silicate facies contains one or more of the hydrous ferrous silicates (greenalite, minnesotaite, stilpnomelane, chlorite) as a major constituent. Granule structure, similar to that of glauconite, is typical of some varieties; others are nongranular and finely laminated. The most common association of the silicate rocks is with either carbonate- or magnetite-bearing rocks, which suggests that the optimum conditions for deposition ranged from slightly oxidizing to slightly reducing. The relationship between the iron -rich rocks and volcanism, stressed by many authors, is considered by the writer to be structural, not chemical: in the Lake Superior region both iron -deposition and volcanism are believed to be related to geosynclinal development during Huronian time. In Michigan, the lower Huronian rocks are iron -poor quartzite and dolomite-typical "stable-shelf" deposits; much of the upper Huronian consists of iron -poor graywacke and slate with associated volcanic rocks -a typical "geosynclinal" assemblage. Thus the iron -rich beds of the middle Huronian and lower part of the upper Huronian were deposited during a transitional stage in structural history. The major environmental requirement for deposition of iron - formation is the closed or restricted basin; this requirement coincides in time with what would be a normal stage in evolution of the geosyncline: namely, structural development of offshore buckles or swells that subsequently develop into island arcs characterized by volcanism.

Lake Superior↗

Some aspects of the geochemistry of sphalerite, Central City District, Colorado

Detailed studies of sphalerite , as a part of a larger study of the Central City district , Colorado , have been undertaken to learn something of the physico-chemical environment of ore deposition. More than 90 samples have been analyzed by chemical and spectrochemical methods and these data are interpreted in the light of experimental information. Sphalerite is a widespread and moderately abundant constituent of the gold- and silver-rich veins of the district . It was deposited during one stage of mineralization, in all environments of the concentrically zoned district except in the core. On a district -wide basis it occurs in three mineral assemblages: sphalerite -pyrite- chalcopyrite-tennantite-galena, sphalerite -pyrite-tennantite-galena, and sphalerite -pyrite-enargite-tennan-tite-galena. Quartz and, locally, other gangues are present.The sphalerite samples contain from 12 to 0.05 weight percent iron and detectable amounts of a restricted suite of minor elements, principally manganese, cadmium, copper, and lead. Manganese correlates directly with iron content, but the other minor elements have random correlations.The iron content of Central City sphalerite is interpreted to be mainly a function of activity of sulfur and temperature. Total pressure and minor elements that may enter the structure of either sphalerite or coexisting pyrite are thought to have negligible effects on the amount of iron in the sphalerite .The iron content of the sphalerite and fluid inclusion studies indicate that mineralization occurred over a temperature range from at least 620° C to about 150° C. In general, the temperatures tended to decrease from the vicinity of the central zone outward toward the peripheral zone. The thermal pattern, however, was complex, and marked by local irregularities.The activity of sulfur decreased with temperature, but to an extent such that more sulfur-rich mineral assemblages could form toward the margins of the district .The minor-element content of the sphalerite is governed by the activities of the various components and by the ability of the host mineral to accomodate it. Manganese varies widely because (1) it is geochemically much more abundant than is zinc and (2) it can also enter other minerals on a large scale. Conversely, because the amount of cadmium is small relative to that of zinc and because it enters only sphalerite in quantitatively significant amounts in hydrothermal environments, the cadmium content of sphalerite is constant. The copper content of the sphalerites is low and in good agreement with recent experimental data of Priestley Toulmin 3d.

Colorado↗

Studies of fluid inclusions; [Part] 2, Freezing data and their interpretation

Aqueous and non-aqueous inclusions in 84 samples of various minerals from a wide range of geologic environments were studied with the freezing stage in order to gain an insight into the range of concentrations and compositions of fluid inclusions . Inclusions in most Mississippi Valley-type ore minerals contain highly concentrated saline solutions, showing freezing temperatures between -23.4° and -10.5° C; minerals from ore deposits of more typically hydrothermal affiliations mainly show temperatures of -9.4° to nearly 0° C; and inclusions in quartz crystals from sedimentary, metamorphic, and igneous rock environments show a wide range of freezing temperatures. Inclusions in pegmatite minerals in particular vary over a wide range, from the most concentrated solutions found in any inclusion (> 40% salts) to fairly dilute solutions (< 5% salts). Most inclusions in quartz from Swiss Alpine-type veins, and from Brazilian quartz veins and pegmatites, show freezing temperatures in the range -8.5° to - 2 .5°, and considerable free C02. Other geologic environments sampled include Colombian emerald, pegmatitic topaz and fluorite, the Triassic traprock zeolite assemblage, and sedimentary halite beds. Not all the phenomena exhibited by inclusions at low temperature are completely understood at present but several crystalline hydrate phases, such as NaCl-2H,0 and CO,-5%H,0 (structural formula 8C02-46H20), are shown to be stable in inclusions of appropriate composition even at temperatures above 0° C, and probably exist in the inclusions in natural rocks in polar regions. More significantly, the formation and recognition of such phases aid in establishing the gross composition of individual inclusions far too small for chemical analysis. The data obtained are useful in a variety of ways, such as: discriminating among gas, liquid, and supercritical fluid , and among liquid water, liquid oil, and liquid C02 in inclusions ; improving precision of the pressure corrections applied to inclusion filling temperature determinations; proving the general lack of leakage into or out of inclusions ; estimating the minimum pressure at the time of deposition of certain samples; verifying the lack of extraneous solid crystallization nuclei in the inclusions and hence their formation from exceedingly quiet, clean solutions; determining the total equivalent NaCl concentrations and some information concerning the composition of the fluids from which ores have formed; and determining changes in the composition of the fluids bathing a single crystal during its growth, and at certain times throughout its history.

Economic Geology↗

Genesis of the Spar Lake strata-bound copper-silver deposit, Montana: Part I. Controls inherited from sedimentation and preore diagenesis

Mineable zones of the Spar Lake deposit occur where argentiferous copper sulfides and native silver formed cements and replaced certain earlier cements and clasts in the gently dipping middle quartzite beds of the upper member of the Revett Formation, middle Proterozoic Belt Supergroup. The copper sulfides and native silver are part of a large, zoned system of authigenic ore and gangue minerals at Spar Lake. Mineral zone boundaries of ore and gangue phases cross all five stratigraphic units of the upper member.Deduced depositional environments for the host sedimentary rocks include beach and near-shore slope environments for the lower quartzite beds and subtidal(?) channels for the middle quartzite beds. The deposit must be epigenetic because mineral zone boundaries cross every facies in the sequence of beach and nearshore slope sediments.Mineral zonation has been mapped, and seven major associations, each named for its most abundant sulfide and/or most characteristic gangue cement, are recognized. Zones that appear to be developed on a regional scale include, in spatial order, pyrite-calcite, chalcopyrite-ankerite, and the lavender (hematitic) zone. Minor concentrations of base and precious metals occur along boundaries between the hematite and chalcopyrite-ankerite zones, and between the chalcopyrite-ankerite and pyrite-calcite zones; however, at the major concentrations of metals in the Revett Formation, including the Spar Lake deposit, additional mineral zones are developed between the chalcopyrite-ankerite and pyrite-calcite regional zones. Mineral zones at the deposit are, from northwest to southeast: pyrite-calcite, galena-calcite, chalcopyrite-calcite, bornite-calcite, chalcocite-chlorite, and chalcopyrite-ankerite. Gangue minerals, including carbonates, Fe-Ti oxides, chlorite, barite, authigenic feldspars, and apatite, are zonally distributed with boundaries parallel to the sulfide-mineral zone boundaries. Bornite-calcite and chalcocite-chlorite zones form ore grades in certain, but not all, quartzite intervals.As observed at unmetamorphosed deposits where sulfide-mineral zonation is similar, some pyrite-calcite-zone minerals were probably replaced by galena-calcite-zone minerals, which were probably succeeded, in sequence, by minerals of the chalcopyrite-calcite, bornite-calcite, and chalcocite-chlorite zones. This inferred paragenesis suggests that the chalcocite-chlorite zone is more proximal to the source of ore solutions than the galena-calcite or pyrite-calcite zones. The subeconomic chalcopyrite-ankerite zone, found farthest to the southeast at the Spar Lake deposit, was apparently even more proximal to the source than ore. Ore deposition took place during diagenesis from solutions that migrated upward and laterally through the sediments from a southeasterly source.The distributions of mineral zones and ore grades were controlled by two factors, one inherited from sedimentation and the other from preore diagenesis. All mineral zones spread out within coarser grained portions of quartzite units, suggesting that lateral migration of ore solutions was controlled by primary permeability of the sediments. However, high grades of copper and silver are found only in certain of the coarser grained beds. The distributions of higher grades suggest that ore mineral abundances reflect the abundances of preore diagenetic phases which were involved in the ore precipitation reactions. Preore reactant phases were evidently more abundant in sandstones deposited in subtidal(?) channels (the ore-grade middle quartzite beds) than in sandstones deposited in beach and nearshore slope environments (the lower quartzite beds). The identity of the reactant phases and the processes that resulted in their concentration at the site of later ore deposition remain unknown, although a preore sulfide- and hydrocarbon-bearing pore fluid appears to be the best hypothesis as to the identity of the reactants.

Economic Geology↗

Secondary precious metal enrichment by steam-heated fluids in the Crofoot-Lewis hot spring gold-silver deposit and relation to paleoclimate

The Crofoot-Lewis deposit is an adularia-sericite-type (low-sulfidation) epithermal Au-Ag deposit, whose well-preserved paleosurface includes abundant opaline sinters, widespread and intense silicification, bedded hydrothermal eruption breccias, and a large zone of acid sulfate alteration. Radiogenic isotope ages indicate that the system was relatively long-lived, with hydrothermal activity starting around 4 Ma and extending, at least intermittently, for the next 3 m.y.Field evidence indicates that the surficial zone of acid sulfate alteration formed in a steam-heated environment within an active geothermal system. A drop in the water table enabled descending acid sulfate waters to leach Au and Ag from zones of low-grade disseminated mineralization, resulting in the redistribution and concentration of Au and Ag into ore-grade concentrations. These zones of secondary Au-Ag enrichment are associated with opal + alunite + kaolinite + montmorillonite + or - hematite and were deposited in open space fractures at, and within a few tens of meters below, the paleowater table.The stable isotope systematics of alunite and kaolinite in the steam-heated environment are relatively complex, due to variations in the residence time of aqueous SO 4 that formed from the oxidation of H 2 S prior to precipitation of alunite, and the susceptibility of fine-grained kaolinites to hydrogen isotope exchange with later waters. Most of the alunites are enriched in 34 S relative to early sulfide minerals, reflecting partial S isotope exchange between aqueous SO 4 and H 2 S. About half of the alunites give reasonable calculated delta 18 O (sub SO 4 -OH) temperatures for a steam-heated environment indicating O isotope equilibrium between aqueous SO 4 and water. The delta D (sub H 2 O) values of the hydrothermal fluids varied by almost 60 per rail over the life of the meteoric water-dominated system, suggesting significant climate changes.Mineralization is believed to have resulted from large-scale convection of meteoric water controlled largely by basin and range fractures and a high geothermal gradient with H 2 S for Au complexing derived from organic matter in basin sediments. A wet climate resulted in the formation of a large inland lake which provided abundant recharge water for the hydrothermal system. A fluctuating water table controlled by changing climatic conditions enabled steam-heated acid sulfate fluids to overprint lower grade mineralization resulting in ore-grade precious metal enrichment.

Economic Geology↗

Benthic foraminifera from a relict flood tidal delta along the Virginia/North Carolina Outer Banks

Examination of benthic foraminifera from six vibracores collected from a relict flood tidal delta near the Virginia/North Carolina border documents the assemblages associated with a former inlet and provides geologic evidence of this former inlet that once defined the boundary between Virginia and North Carolina along the Outer Banks. Three distinct foraminiferal assemblages were identified. The oldest assemblage contained abundant and diverse forms, dominated by Elphidium excavatum and several other calcareous species typical of shallow nearshore areas. Sediment immediately below and above this diverse calcareous assemblage was barren or nearly barren of foraminifera. A medium-salinity agglutinated marsh assemblage characterized mainly by Trochammina inflata with fewer Tiphotrocha comprimata overlies the uppermost barren unit. The core top assemblage was dominated by low-salinity marsh species Jadammina macrescens, Miliammina petila and Miliammina fusca. A comparison of these vertically-stacked assemblages with the modern geographic distribution of assemblages in the Outer Banks estuarine system and on the nearby continental shelf reveals a succession of depositional environments proceeding from estuarine and flood tidal delta to medium salinity marsh to lower salinity marsh. These changes in depositional environments reflect a rapid and dramatic increase in salinity caused by the opening of an inlet followed by a gradual decrease in salinity due to inlet shoaling and eventual marsh colonization of the flood tidal delta. These changes cannot be determined through sedimentological studies alone; micropaleontological analysis is required. We conclude this distinctive trend of changing depositional environments constitutes paleontological evidence of the origin and evolution of Old Currituck Inlet that breached the barrier spit prior to 1585AD, actively built a flood tidal delta for more than 145 years, and then closed in 1731AD allowing the flood tidal delta to become colonized by marsh species.

North Carolina, Virginia↗

Sequestration of phosphorus by acid mine drainage floc

Solubilization and transport of phosphorus (P) to the water environment is a critical environmental issue. Flocs resulting from neutralizing acid mine drainage (AMD) were tested as a possible low-cost amendment to reduce the loss of soluble P from agricultural fields and animal wastewater. Flocs were prepared by neutralizing natural and synthetic solutions of AMD with limestone, lime, ammonium hydroxide, and sodium hydroxide. Phosphorus sequestration was tested in three distinct environments: water, soil, and manure storage basins. In water, flocs prepared from AMD adsorbed 10 to 20 g P kg −1 dry floc in equilibrium with 1 mg L −1 soluble P. Similar results were observed for both Fe-based and Al-based synthetic flocs. A local soil sample adsorbed about 0.1 g P kg −1 , about two orders of magnitude less. The AMD-derived flocs were mixed with a high-P soil at 5 to 80 g floc kg −1 soil, followed by water and acid (Mehlich-1) extractions. All flocs performed similarly. About 70% of the water-extractable P was sequestered by the floc when applied at a rate of 20 g floc kg −1 soil, whereas plant-available P only decreased by about 30%. Under anaerobic conditions simulating manure storage basins, all AMD flocs reduced soluble P by greater than 95% at a rate of 0.2 g floc g −1 rainbow trout ( Oncorhynchus mykiss ) manure. These findings indicate that AMD flocs could be an effective agent for preventing soluble P losses from soil and manure to the water environment, while at the same time decreasing the costs associated with AMD treatment.

Journal of Environmental Quality↗

Proactive aquatic ecotoxicological assessment of room-temperature ionic liquids

Aquatic environments are being contaminated with a myriad of anthropogenic chemicals, a problem likely to continue due to both unintentional and intentional releases. To protect valuable natural resources, novel chemicals should be shown to be environmentally safe prior to use and potential release into the environment. Such proactive assessment is currently being applied to room-temperature ionic liquids (ILs). Because most ILs are water-soluble, their effects are likely to manifest in aquatic ecosystems. Information on the impacts of ILs on numerous aquatic organisms, focused primarily on acute LC50 and EC50 endpoints, is now available, and trends in toxicity are emerging. Cation structure tends to influence IL toxicity more so than anion structure, and within a cation class, the length of alkyl chain substituents is positively correlated with toxicity. While the effects of ILs on several aquatic organisms have been studied, the challenge for aquatic toxicology is now to predict the effects of ILs in complex natural environments that often include diverse mixtures of organisms, abiotic conditions, and additional stressors. To make robust predictions about ILs will require coupling of ecologically realistic laboratory and field experiments with standard toxicity bioassays and models. Such assessments would likely discourage the development of especially toxic ILs while shifting focus to those that are more environmentally benign. Understanding the broader ecological effects of emerging chemicals, incorporating that information into predictive models, and conveying the conclusions to those who develop, regulate, and use those chemicals, should help avoid future environmental degradation.

Current Organic Chemistry↗

Insecticide contaminations in wetland habitats and their effects on fish- eating birds

An unusual mortality of fish-eating birds occurred at the Tule Lake National Wildlife Refuge in California between 1960 and 1962. Over 1100 dead birds of ten species were found during that period. Investigations of the mortality indicated that birds died as a result of their exposure to toxaphene, which was applied to adjoining agricultural areas, transported to the refuge in waste irrigation water, and accumulated in fish eaten by the birds. Toxaphene was used in agriculture for only 3 years, 1958-60, and by 1962 residues were no longer found in the marsh habitat. However, results also showed that a potentially hazardous contamination of DDT and its metabolites was present in the birds and the environment. Studies were, therefore, continued to determine the food-chain relationships of DDT in marsh ecosystems, and the effects of the insecticide on birds. Sampling for insecticide residues was undertaken at four waterfowl refuges, each representing a somewhat different set of environmental conditions. DDT residues in water at each refuge were found to be relatively low, but filtered samples showed that residues in suspended material were 10 000 to 20 000 times as great as those in the filtrate. Much of the suspended material was organic matter, which is an important source of energy for the ecosystems. In environments with invertebrates, DDT residues were relatively low in sediments and high in fish, while residues in vegetation were highest where invertebrates were absent. Results suggest that organic materials and invertebrates can be important factors in determining the fate and involvement of insecticides in aquatic environments. Studies of the movements, exposure to pesticides, productivity, and longevity of individuals in three nesting colonies of White Pelicans were begun in 1962 to depict the relationships of pesticides to a migratory population of birds dependent upon wetland habitats. To date there is no evidence that the exposure of pelicans to DDT is influencing the population dynamics of the birds.

California, Oregon↗

Interactions of an insecticide with competition and pond drying in amphibian communities

Amphibian populations are often imbedded in agricultural landscapes. Therefore the potential for contamination of their habitat is considerable. Our study examined the effects of an insecticide (carbaryl, a neurotoxin), on larval amphibian communities experiencing natural stresses of competition for resources, predation, and pond drying. In a set of experimental ponds, tadpoles of three anuran species (southern leopard frog [ Rana sphenocephala ], plains leopard frog [ R. blairi ], and the Woodhouse's toad [ Bufo woodhousii ]) were added to 1000-L ponds containing leaf litter, plankton, two newts ( Notophthalmus viridescens ), and four overwintered green frog ( R. clamitans ) tadpoles. We manipulated the overall tadpole density (low or high), pond hydroperiod (constant or drying), and chemical exposure (0, 3.5, 5.0, or 7.0 mg/L carbaryl) of the ponds. We measured mass, time, and survival to metamorphosis to determine treatment effects. Carbaryl positively affected Woodhouse's toad survival, although it had a negligible effect on both leopard frog species. Tadpole density interacted with the chemical treatment: Proportionately more Woodhouse's toads survived to metamorphosis in high-density environments than in low-density or control environments. Greater survival may be an indirect effect of increased algal food resources from carbaryl exposure. Most newts lost mass over the course of the experiment, although ponds with drying hydroperiods and high anuran density were the least favorable environments. Overwintered green frogs exposed to carbaryl had longer larval periods on average than did green frogs in control ponds. Our study demonstrated that even sublethal, short-lived contaminants can alter natural communities in ways that cannot be predicted from simple, one-factor studies.

Missouri↗

Diatoms and tonsteins as paleoenvironmental and paleodepositional indicators in a Miocene coal bed, Costa Rica.

The Venado Formation is composed of more than 300 m of mudstone, siltstone, sandstone, limestone, volcaniclastics, and coal beds. The coal beds are of unknown lateral extent and mainly occur in the middle part of the formation. Diatoms are a useful microscopic tool for identifying the depositional environments. They indicate that swamp environments were intermixed with lacustrine environments during the formation of the peat deposit or that the coal records environmental changes through time. -from Authors

Palaios↗